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  • Organic Reagents List and Their Function

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    Manu Manohar
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    This gives the reagents of organic chemistry

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    This gives the reagents of organic chemistry

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    223 views18 pages

    Organic Reagents List and Their Function

    Uploaded by

    Manu Manohar
    This gives the reagents of organic chemistry

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 18
    LIST OF IMPORTANT REAGENTS FOR COMPETITIVES AND THEIR USES: Sener mca - Se ee poses A, Se cs iol meme jo —CH ck 0, ares “Geleene (deuterwedl: nh poder = tee | aie — + HEX, r . “eg aa eORIOEM, It feapacto ‘iptemna " ima AY RON RON os Hoffmann Bromamide reaction a aT a sx aj ee aE ee sci ae tae (or te) | [Con Git] Connors Reoclon iit or | Bakparaketopenaion won| faa (Elimination) ‘oth Gmina & vical aides are conwertedt Alby. as ee Tas ean % tram [eran Aq NaOH | AsastrongBare | 7 merino “ ‘acids to give-salts” ne 0 On? ate acid cere at peel OH OP ce Aarus 108 ‘on hele Salt Phenol ore soba i wae) Asa nacoophletn ROX + :OH——> ROH + 2X coverings one Heloakere ——__anie_._t FECT iver | Ce Ratocton ay ieee H/inaar Pa: B2S0sin | of alyes eapemeieiy, on airline se aan yy aba |Dakaonenaion ze Tan {€limination) wb bbw Femara omaene| — OF — a Co + 200 aT HE | Convers Rar zara ee eco tA wom Ee OS ane _ {cernante) i 7H Tear Syne we yet b on Mundie | Allenrorationes | ¢—caauc cry rin Hyo—EE— AF onpound we 7 en, compounds yoo on tne eH em | Racin o inion) | wore 131 ‘ene = Cem st) a me eda PE ene, cn a us BO enaame ca HCMCH+ HOH ——+ H—CH=CH—O# —> CHCH=0 Fence HOt ane ‘Asildelgde 04 ‘exyencit+ HoH + crn — CO— HY a sor pestene yes to Codon amounts ‘Gigante eaent mex ‘aevering Cartons toAkaol: preparing Aan arin st ferones Talon her Caer oro Scie elon ore ere tng lg eons) pe. + -=OO~ me = fey ‘coho! oo ow + ROH ‘nang | RAO Ti? ACOH =e Aas Beene | OO = = eT = ca | ‘ii — | Converting Aedes oH or Ketones to Alkanes = ames yarazone Alkane Baer Uehtor eat) ore ‘eoct with anes to sive mixture of mone by successive plement of hydrogens (re rete! substation) HoH, cron, ‘nd polyhaloaikanes | Chane RTE CneHe, Os cHewenp, + Propane 8 cugnpiey— > auouae + a cmb ars lesatane ont no ’ cHgHe4, crrgsu, os ends, eet wt alter veil ates foowing ant Fd lignes roe to form tata ele ‘ones ra FRx eae wih 3 product at Cand ‘[Additon os major produc ot 40°C Betedenetoundergo L2Addiion os major we 1 sacetion Bare | nition SS 1 2aoTielogen eat 7 + Het ee “nA as “Selectvebromination . ‘tole and bene postion nes = ot cree Nos hase andsecondary | gn s.0h i choheltotete | monn ete | nnn omen ge ad rane o wy Serpe Tain, | Convert alkenes te | $C, =Chiy= ARNO, + A11,O— 3CIIg—Clly + 2NnD, +2KOTT {cata cnt atts} hese a Aatne) | undergina sm ot a Bocyers | adton — SHEKMIOL c,-e-cy trons a Propylene gh ie [eee = oS hecufeu sexton Alkaline) ‘leah to ketone 85, Ne se on Age ak ing, — ano 3s Se HD TIO SGT TR ae cmt | eine be by Cay [etree bi aeyer’s | oddltion Eyeneetyeat oe ests KOS ey, cic cmeraaa ie = =< Sonne oo sn cahen, ond —o0 oe. ee camer elects a ocd and rym on BE crn EO stot cunt So —OL “ho a cman 7 ona oa i — imaryanines ‘Oddaton Wi ENO, 7 | comer toeieytes | «cc AH, 10) wai OOH IS. Cy EDN ctivanine ital chon: deen thes depen | imac athe ines ondionty KMOH and proven eth ting primry, seaeery seconde otetery cee respectively Gell F Ne ager R CCOTN MSO” ba bw en baeate§ 105 Hy O-GCH-EH, GHCOON | HOOE THT, ‘hones Roving CH onde ond oxides 0 Garbonric acid | sexing gtns terre ose ia norco vcard parte sce medium Dut reects wit RCH RC-OH Conver one gers awatones t cic cite —>| — 29roRopropane Locimcnmcn=8r 1LBromopropane ver Rasta ex00s5 - Seminal ies aay HX — ot x stow tk alkyne trans-iny\ halide ominat éhatide: Conver arta a Metcanesend | SQ SO Ag AN hae + Proceeds va prctoaten tense q = Pre & may ers clave is ay : *Asoadondvden oH wiloavettie etl to nse BTR |e ae ‘Nhyies nea ee NS {Srphen retin) see YN oe we ON, > Te TP Farnal—|eaveres = = enrne Sine nee J €] Wed P/T | Conve GdoNRane | RI Redan RATS Convert NO FRETLERATD CARROT ivorsbnsee Phemyconiamne va anv Aeohol foivan =, paseo chy ketones, vere sean |p pore BSEs apr tor A A nooo ar M2, pacts, TH Red | Canver ATE ok + OHO ROH aka! fetus 21 Dey AGO Convert Allyl Halide tokther ce ARO" convert primary alcoho! to ‘aldehyde, Secondary to ketone and tertiary to alkene RCHLOH— SY RCHO Regie Gait Ra cute Fon tse Convert ethane to methanol Hy 2cH, + 0; Convert AryTiedide to Birery! (Ullmann reaction) ¢ 7 one LY ry. X=1,Br Peis Nore: Reoction of SOC is seme PO, Convert Alcohol to Chloroaikane CHCHOH + PC, —2> cH/cHLCI + POG + HCI ‘Convert Carboxyiie (cid to acid chloride o r i RCOH + PCs —® RGGI +HCI + POC; Convert Amide to ete 5a PoC, SH: ono”! ‘Aldehydes ond ketones to geminal olides \ \7 + PCI; ——> te Tans Converting Ketoximes toAmide (Beckmann ren) a Ta diy ether conver: Holoalkanes to Grignerd's reagent Convert Ketones Si Pinnacol HO, on wa" 10 "Qn = She Orin afore q = ‘meter metiyone = seo fh roupsertachesto ao or ee of’ {cor cooR, ew te ba Sem Be | yy sae te meat, [A oon RK CHy — CHyCO3H_ a o ok trane-2-butone ‘ridin of etonae ecortchetonerto ster ore esters (uectones) oa ae ae chy i ‘CHM nocd (coro ‘onpound contening 0 oF ‘nore oH or CO ‘groups cttached adjacent to each other undergo CL tteavage to get oxidise to acids or ‘carbonyl compounds Be 3 on wie AAAS Ge a i p OH OH —NalOy rt oy AR Se + 18 Prop borane [oc (on cnicie » 9H Kem Ee oe aT Aavioson ic +B /THE > (Ol. CHY + AeRO,AWOH aan a CREA OR THES TCA THB FARO CHT, Baie tonnes ite ternal 1, CHP CH HH, — Cry CH, CH, SEE, cH, CHAE + ctpcmcn, eaer,cH,0H + 0H, AHO cert “cH, CHB aes voter, creer 0 ones arto compounds mn ae x = resend [cont eneeta | carbryeace Tar inayat secondo ha te Aiehyes nd eons respect TREN | Corio Par and Scans aha atshyter od fetoes speci env Aner Gabon ects 90%, 2H¢008 ‘plo te due tnd Gai, | Comat Beant 7 ro entre YE a, — | Loe | ‘ansrsGocsete | CHO “COO nod I comet ce cow, =", nom, 1 1 cx,04 coon tones wil ley slo ous nto as i cabehyertes, Tan Rioerta | CH-CO Gee 9 CH COOH HOOE HCH, Corben acé gta tae inne ed | Conver inary | RaicoH> ROH iver | lethal todarand | R

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