Test - 7 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

TEST - 7 (Paper-I)

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 31. (1) 61. (3)
2. (4) 32. (1) 62. (1)
3. (2) 33. (3) 63. (2)
4. (1) 34. (1) 64. (4)
5. (2) 35. (1) 65. (2)
6. (2) 36. (2) 66. (3)
7. (3) 37. (1) 67. (2)
8. (4) 38. (2) 68. (1)
9. (3) 39. (1) 69. (2)
10. (4) 40. (2) 70. (1)
11. (3) 41. (2) 71. (2)
12. (2) 42. (3) 72. (1)
13. (2) 43. (4) 73. (1)
14. (3) 44. (1) 74. (2)
15. (1) 45. (1) 75. (4)
16. (1) 46. (4) 76. (1)
17. (1) 47. (4) 77. (3)
18. (3) 48. (2) 78. (1)
19. (3) 49. (4) 79. (2)
20. (3) 50. (3) 80. (3)
21. (2) 51. (4) 81. (1)
22. (3) 52. (3) 82. (3)
23. (3) 53. (2) 83. (2)
24. (3) 54. (2) 84. (2)
25. (1) 55. (1) 85. (1)
26. (4) 56. (2) 86. (1)
27. (1) 57. (2) 87. (3)
28. (1) 58. (2) 88. (4)
29. (4) 59. (1) 89. (1)
30. (4) 60. (2) 90. (3)

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All India Aakash Test Series for JEE (Main)-2014 Test - 7 (Paper-I) (Answers & Hints)

PART - A (PHYSICS)
1. Answer (1) 6. Answer (2)
hreal
happ =
μ

10
dz 20 3
∴ ∫ ⎛ z
= ln = 5 cm
⎞ 1.63 2
0 1.63 ⎜ 1 + ⎟ d
⎝ 20 ⎠ O
+ –
2. Answer (4)
4
The plane of the mirror and incident ray must be μ=
3
perpendicular to each other.
3. Answer (2)
R = 80
4
1−
⇒ f = 40 cm 1 4 3
− =
v 3( −d ) ⎛ d ⎞
Sun rays fall normally to the mirror which converges ⎜− ⎟
them to focus. For water surface ⎝ 2⎠

1 μω 1 − μω
− =
v u ∞ ⇒ v =−
3d
2
μ 20
⇒ v = μ = 413 = 15 cm
ω 7. Answer (3)
4. Answer (1)
⎛ y2 ⎞ 1 1 1
R R v i = − ⎜⎜ 2 ⎟⎟ v 0 − =
f1 = , f2 = − ⎝x ⎠ v −60 24
μ1 − 1 μ2 − 1
1 ⎛ μ − 1 ⎞ ⎛ μ2 − 1 ⎞
= 1 −
∴ Feq ⎜⎝ R ⎟⎠ ⎜⎝ R ⎟⎠ = −
(40)2
×9 ⇒ v = 40
(60)2
(μ1 − μ2 ) R
= μ1 μ2 = –4 cm/s
R
8. Answer (4)
R
∴ Feq =
μ1 − μ2 1
∝ ( Z – 1)
2
λ
5. Answer (2)
2
⎛ Z –1 ⎞
= 4=⎜ ⎟ ⇒ Z = 37
⎝ 19 – 1 ⎠
60º 30º 60º
30º
30º 9. Answer (3)
10. Answer (4)

Dλ1 Dλ2
μ= 3 4× = 6×
d d

1sin60 = 3 sinr 2 2 860

λ2 = × λ1 = × 430 =
∴ r = 30° 3 3 3
∴ Angle between reflected and refracted ray = 90°. = 287 nm
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Test - 7 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

11. Answer (3) ⎛

2
4 ⎞
Inet = ⎜ I0 + I0 ⎟
P ⎜ 9 ⎟⎠
⎝
y 25
= I0
9
15. Answer (1)
θ
S1 A0 A0
3λ S2 At = 10
=
2 1024
D
S1P – S2P = 3λcosθ = 2λ
4096
∴ Price = = 4 Rs
2 D 1024
⇒ cos θ = =
3 D + y2
2
16. Answer (1)

⇒ 5D2 = 4y2 17. Answer (1)

18. Answer (3)
5
∴ y= D At closest approach there velocity will be equal to v.
2
mP.u = mPv + 4mP.v
12. Answer (2)
4
d = 1 mm, D = 2 m ⇒ v= u
5
DΔx
y= 1 1 ⎛4 ⎞ 1
2
⎛ 4 ⎞ K .2e
2 2
d mP u 2 = mP ⎜ u ⎟ + 4mP ⎜ v ⎟ +
2 2 ⎝5 ⎠ 2 ⎝5 ⎠ r
10 −3 2 × Δx
= 5Ke 2
2 10−3 ⇒ r =
mP .u 2
10 −6 ⎛ 1⎞
Δx = = ⎜n − ⎟λ 19. Answer (3)
4 ⎝ 2⎠
For n = 1, λ = 500 nm 1240
E= = 4.5 eV
13. Answer (2) 275
Each photon shares half the energy ∴ KE of emitted electrons = 4.5 – 3 = 1.5 eV.

135 λdB = 10 Å
So E = MeV
2 20. Answer (3)
n1
hc 135
Now, = × 106
λ 2 θ
⇒ λ = 18.37 × 10–15 m θ
n2
= 18.37 fm
–θ
90

14. Answer (3)

Due to reflection from water surface, wave suffers an n3
additional phase change of π. From Snell's law,
2π n1sinθ = n2 ... (i)
Δφ = × 5 = 5π
2 n1sin(90 – θ) ≥ n3
∴ Net Δφ = 5π + π = 6π n1cosθ ≥ n3 ... (ii)
⇒ Waves are reaching in phase Squaring and adding,
n12 ≥ n22 + n32
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All India Aakash Test Series for JEE (Main)-2014 Test - 7 (Paper-I) (Answers & Hints)

21. Answer (2) ⇒ h′ = 4h = 4 × 160 m

= 640 m
⎛ –13.6 ⎞ ⎛ –13.1 ⎞
E2 – E1 = ⎜ ⎟–⎜ ⎟ = 10.2 eV ∴ Increase in height = 640 – 160 = 480 m
⎝ 4 ⎠ ⎝ 1 ⎠
24. Answer (3)
⇒ First excitation potential = 10.2 V
Separation = f0 + 4f + fe
22. Answer (3)
= 180 + 4 (3.5) + 5
ΔVi = 20 × 10–3 v, ΔIb = 20 × 10–6A,
= 199 cm
ΔIC
25. Answer (1)
= 2 × 10–3 A
λ
ΔIC 2 × 10−3 For first diffraction minima, sin θ =
gm = = −3
= 0.1 Ω−1 d
ΔVi 20 × 10
λ
23. Answer (3) ⇒ sin30 =
5
d = 2Rh = 2.5 cm
26. Answer (4)
d h
∴ =
d′ h′ 27. Answer (1)
28. Answer (1)
h′
⇒ 2= 29. Answer (4)
h
30. Answer (4)

PART - B (CHEMISTRY)
31. Answer (1) 34. Answer (1)
H
:

A= N (Syn) B= N (Anti)
:
CHO CH2OH COO H H H
(Major) (Minor)
–
OH
2 + 35. Answer (1)
Conc.
*
H
O
M M dil OH–
Equivalent mass of benzaldehyde = + =M H H
2 2 Δ
O O
(A)
32. Answer (1) H
Loss of marked H as H+ makes (A) aromatic.
O
36. Answer (2)

is most reactive due to small size of ring CH2CHO

which increases strain in ring and make it to have X=

ion
low Ea and high reactivity. CH2CH2OH uct
red
H Oxidation
33. Answer (3) LA
(KMnO4)
COOH
In reaction carbanion formation takes place which is
betterly stablize in case of third iodination

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Test - 7 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

43. Answer (4)

CONH2 COOH
CHO CH2OH
Y= dil
reduction H+
LAH

CN COOH
CH3 CH3
Oxidation dil
(KMnO4)
H+
COOH

O O
C C=O COOH
COOH
H2O
(Terphthalic acid) 2

44. Answer (1)

37. Answer (1)
Gabriel phthalimide synthesis follows SN2 pathway
hence it is fastest for CH3Br.
Br
(i) Mg
45. Answer (1)
(ii) Dry ether
(iii) H2O ArSO2Cl O
H OH
O NH2 N – S – Ar
(A)
H O
–
OH
38. Answer (2)
O
39. Answer (1)
N – S – Ar
Formic acid is stronger acid than Benzoic acid O
(Soluble)
40. Answer (2)
46. Answer (4)
OH
Electron withdrawer on diazonium salt and other
Δ
O O O strongly activated benzene ring favours the coupling
reaction.
Reaction goes through cyclic intermediate
47. Answer (4)
41. Answer (2)
Quaternary ammonium hydroxide is an ionic
O hydroxide hence it is as strong base as KOH.
has Cl as good leaving group hence its rate
Cl 48. Answer (2)
of reaction is maximum 49. Answer (4)
42. Answer (3) 50. Answer (3)
51. Answer (4)
O O O
In highly acidic medium all – NH 2 groups get
O dil OH OH protonated.
H
H2SO4
OH O 52. Answer (3)
53. Answer (2)
Since (OH) group is not present hence it does not
If C1 – C1 linkage is there than for both glucose and
respond Victor Mayer test.
galactose anomeric carbon atoms are in acetal link-
age hence produces non reducing sugar.
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All India Aakash Test Series for JEE (Main)-2014 Test - 7 (Paper-I) (Answers & Hints)

54. Answer (2) 55. Answer (1)

Carbohydrate with minimum number of carbon atoms is 56. Answer (2)
CHO 57. Answer (2)
58. Answer (2)
H OH
59. Answer (1)
CH2 OH 60. Answer (2)

PART - C (MATHEMATICS)
61. Answer (3) 64. Answer (4)
Mean = 4 Either the number ends with (1, 3) or (7, 9)
So, possibilities are
1+ 2 + 6 + x + y
⇒ =4
5
1×3 1 × 13 1 × 23 - - - - - 1 × 93
⇒ x + y = 11 ... (i)
Variance = 5.2

12 + 22 + 62 + x 2 + y 2
⇒ − (mean)2 = 5.2 91 × 3
5
⇒ x2 + y2 = 65 ... (ii) 100 × 4 × 2 = 800 numbers

From (i) and (ii) we get 800 800

Probability = =
x = 4, y = 7 201 × 201 40401
62. Answer (1) 65. Answer (2)
L and W can be filled at 14 places in 2 14 ways iˆ j k
∴ n(S) = 214 1 2 3 .(3iˆ + jˆ )
Now 13 L's and 1W can be arranged at 14 places in D .C −1 2 1
14 ways, hence n (A) = 14 Let θ = =
|D ||C | 16 + 16 + 16 9 + 1
14 7
∴ P = 14 = 13 −4
2 2 =
63. Answer (2) 30

a = –4
a b
Δ= 66. Answer (3)
c d
Suppose a, b and c are the components
Δ = ad − bc ⇒ ad − bc = 0 a2 + b2 + c2 = (63)2

a −b c
0 × 0 − 0 × 0⎫ = = =λ
⎪ 3 2 6
⇒ 1× 1 − 1× 1 ⎬
2 × 2 − 2 × 2⎪⎭ ⇒ 9λ2 + 4λ2 + 36λ2 = 632
⇒ λ2 = 81
⇒ 0 × 0 – 0 × (1, 2)
⇒ λ = ±9
⇒ 0 × (1 × 2) – 0 × (1, 2)
Since a = 3λ < 0 as the line makes an obtuse angle
⇒ (1 × 2) – (2 × 1) with x-axis,

31 λ = –9
Required probability =
81 Components are –27, 18, –54
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Test - 7 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

67. Answer (2) 70. Answer (1)

→ → →
→ → → → → → → →
( p× iˆ)2 = ( p× iˆ).( p× iˆ) | α |2 + | β |2 +2 α . β− (| α |2 + | β |2 −2 α . β )
→
= c12 + b12 [where p = a1iˆ + b1 jˆ + c1kˆ ] → →
4 α.β
So, the given expression is equal to
71. Answer (2)
2( a12 + b12 + c12 ) + 0 + 0 + 0
f ( x )dy = yf ′( x )dx − y 2 dx
→
⇒ 2 p2 = 32
yf '( x )dx − f ( x )dy
⇒ − dx = 0
68. Answer (1) y2
→ → → → → → → → → →
(a × b ).(a × c ) = ( a × b ). u is where u = a× c
⎛ f (x) ⎞ ⎛ f (x) ⎞
d⎜ ⎟ − dx = 0 or, d ⎜ − x⎟ = 0
→ → → → → → → ⎝ y ⎠ ⎝ y ⎠
⇒ a .( b× u ) = a .[ b× (a× c )]
72. Answer (1)
→ → → → → → →
= a .[(b . c ) a − (a . b ) c ] put y2 sin x = v
→ → → → → →
= a .[( b . c ). a] [∵ a . b = 0] Then 2y
dy
sin x + y 2 cos x =
dv
dx dx
→ → →
= a2 (b . c )
1 dv
So, the given equation becomes = sin x cos x
→ → → → → 2 dx
Also (a× b ).(a× ( b × c )) = 0
⇒ dv = 2 sin x cosx dx, Now integrate
69. Answer (2)
15 = 5×3 ⇒ v = sin2 x + c i.e. y2 sin x = sin2x + c
115 = 5 × 23
π
. put y = 1, x = ⇒c=0
2
.
. Out of 103, 143, 163, So, y2 = sin x
. 203, 223, 263, 283,
73. Answer (1)
all are prime no
515 = 5 × 103
except 143 Put x = sinθ and y = sinφ
615 = 5 × 123
715 = 5 × 143 ⇒ cosθ + cosφ = a(sinθ – sinφ)
815 = 5 × 163
θ+φ θ–φ
915 = 5 × 183 ⇒ 2cos cos
2 2
1015 = 5 × 203
Divisible by 3
1115 = 5 × 223
θ+φ θ–φ
1215 = 5 × 243 ⇒ 2a cos sin
2 2
1315 = 5 × 263
1415 = 5 × 283 ⇒ 8 – φ = 2cot–1a
1515 = 5 × 303 ∴ sin–1x – sin–1y = 2cot–1a
9
Required probability = 1 1
16 – .y 2 = 0
⇒ 2
1– x 1– 42

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All India Aakash Test Series for JEE (Main)-2014 Test - 7 (Paper-I) (Answers & Hints)

74. Answer (2) 78. Answer (1)

dy ⎛x−y ⎞ ⎛x+y⎞ First if we arrange the given values in ascending
= sin ⎜ ⎟ − sin ⎜ 2 ⎟ order of magnitude.
dx ⎝ 2 ⎠ ⎝ ⎠
dy x y 7 5 1 1
⇒ = −2cos sin x − , x − 3, x − , x − 2, x − , x + , x + 4, x + 5
dx 2 2 2 2 2 2
y x
⇒ cosec .dy = −2cos dx 1
2 2 x −2+ x −
∴ Median = 2 = x−5 =M
On integrating both sides
2 4
y x
log tan = c − 2 sin
4 2 9 7 5 3 3 7 21 25
∴ | xi – M |= , , , , , , ,
75. Answer (4) 4 4 4 4 4 4 4 4

f '( x )
3f ( x ) = f '( x ) ⇒ 3 = ∴ M .D ( M ) =
5
f (x) 2
Integrating we have
79. Answer (2)
3 x + C1 = log f ( x ) 2
P( A ∩ B) =
Put x = 0 15
2
C1 = log4 ⇒ P ( A ).P (B ) =
15
log f(x) = log 4 + 3 x
2
f ( x ) = 4.e 3 x ⇒ (1 – P(A)) P(B) =
15
f (2) = 4.e 6
2
76. Answer (1) ⇒ (1 − x )y =
15
A × (A × X) = A × B
2
(A.X)A – (A.A)x = A × B y − xy = …(i)
15
2A – |A|2x =A×B
1
2A − A × B P( A ∩ B ) =
Hence ⇒ x = 6
| A |2
77. Answer (3) 1
⇒ P ( A ).P (B ) =
xy = 4 6
dy
Let m1 = for required family of curves at (x, y) 1
dx ⇒ x(1 − y ) =
6
dy
Let m2 = for the hyperbola xy = 4
dx 1
⇒ x − xy = …(ii)
6
⇒ m1m2 = −1
From the equation (i) and (ii)
dy ⎛ 4 ⎞ dy x 2
⇒ × ⎜ − ⎟ = −1 ⇒ = 1
dx ⎝ x 2 ⎠ dx 4 x= +y
30
x2 ⇒ 30y – y – 30y2 = 4
⇒ dy = dx
4
⇒ (6y – 1)(5y – 4) = 0
3
x
y = +c 1 4
12 ⇒ P(B) = or
6 5
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Test - 7 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

80. Answer (3) 85. Answer (1)

Prime numbers in 1 to 20
(L1 . L1) (L2 . L2 ) − (L1 . L2 ) (L1 . L2 )
2, 3, 5,, 7, 11, 13, 17, 19
The no's in 1 to 100 having sum of their digits is ⇒ (L2 . L22 ) (1 − cos2 θ)
prime
= (L1 × L2 )2
1 to 9 → 4 50 – 59 → 4
9 – 19 → 4 60 – 69 → 3 86. Answer (1)

20 – 29 → 5 70 – 79 → 3 87. Answer (3)

30 – 39 → 4 80 – 89 → 3 P(A ∪ B) = 1

40 – 49 → 4 90 – 99 → 3 is true because A and B are exhaustive

Total = 37 no's But P(A ∪ B) = P(A) + P(B) – P(A ∩ B) = 1 is true

for exhaustive events A and B.
37 88. Answer (4)
Probability =
100
→
81. Answer (1) | a |= 1 is a sphere

c = b × a = ziˆ − xkˆ x2 + y2 = 1 is a circle

89. Answer (1)
82. Answer (3)
A(o, b, c )& B(a, o, c )
1
There are 8-octants, so, the probability will be
8 & O(0, 0, 0)
83. Answer (2) A.o + B.b + C.c = 0 (1)

dx 1 A.a + B.o + C.c = 0 (2)

=y+ 2
dy y Solving (1) and (2), we get

A B C
y2 1 ⇒ = = =λ
x= – +c bc − O ac − O O − ab
2 y
⇒ A = λbc, B = λac,C = −λab
13 1 29
= – 1+ C ⇒ C = Required equation is
3 2 6
bcx + acy – abz = 0
y 2 1 29
∴ x= – + put a = 1, b = 1, x =1 we get
2 y 6
x+y–z=0
⇒ 6xy = 3y3 – 6 + 29y Statement - 1 & Statement - 2 are correct and
⇒ 3y3 + 29y – 6xy = 6 statement 1 is correct explanation of statement - 1
84. Answer (2) 90. Answer (3)

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