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Dinitrogen tetraoxide, N2Ou, and nitrogen dioxide exist in equilibrium. This is represented by the reaction below: 2NO2(g) = N2Oa(g) AH = -57 kJ molt Which conditions give the greatest percentage of NO2 at equilibrium? high pressure and high temperature low pressure and high temperature high pressure and low temperature 0 oD Pb low pressure and low temperature Which statement below best describes a dynamic equilibrium? A the rate of the forward reaction is equal to the backwards reaction, and the concentrations of reactants and products is constant the rate of the forward reaction is equal to the backwards reaction in a closed system, and the concentrations of the reactants and products are equal the rate of the forward reaction is equal to the backwards reaction in a closed system, and the concentrations of the reactants and products is constant the rate of reaction changes in either direction to counteract a change in conditions An equilibrium is set up in a closed container between equal volumes of gaseous reactants A and B to form a gaseous product C. The total pressure within the container at 50°C is 3 atm. A(g) + B(g) = 2C(g) The equilibrium partial pressure of A at 50°C. is 0.5 atm What is the partial pressure of C at this temperature? 25 2.75 1 0 0o DW D> 2 Ethanol is manufactured by reacting steam with ethene. C2Ha(g) + H20(g) = C2HsOH(g) AH = -45 kJ molt What would increase the equilibrium yield of ethanol in this process? oo DW D> adding a catalyst adding an excess of steam increasing the pressure increasing the temperature Propyl ethanoate is formed in an esterification reaction. How can the value of the equilibrium constant Ke be increased? Propan-1-ol + ethanoic acid = propyl ethanoate + water AH= -10 kJ molt increasing the temperature A B_ adding a catalyst C increasing the pressure D lowering the temperature In the reaction where gaseous iodine reacts with hydrogen, an equilibrium is established at 450°C. The reaction is exothermic Hag) + k(g)= — 2HI(g) colourless purple —_ colourless. Which change in conditions will cause the purple colour of the equilibrium mixture to become paler? decrease in pressure decrease in temperature increase in pressure 0 oOo DO > increase in temperature For the equilibrium 2A(g) + B(g) = 2C(g) AH = +6.5 kJ mol ~, what will change the value of Kp? adding a catalyst decreasing the pressure increase the pressure 0 Oo WwW > increasing the temperature Sulphuric acid is manufactured via a series of reactions in the Contact process. The reaction for the main reaction is shown below. 2S02(g) + O2(g) = 2S03(g) AH= -197 kJ mol" Which statement about the reaction is correct? 090 DO > iron is used as a catalyst increased temperature gives a higher yield of SOz increased temperature gives a higher yield of SOs increased pressure gives a higher yield of SOz At 450°C the value for Ke for the below reaction is 60 H2(g) + lag) = 2HI(g) The equilibrium moles of Hz and Iz are 2 mol and 0.3 mol, respectively. How many moles of HI(g) is present at equilibrium? 0.001 36 0 Oo BD > 0.1 Ethyne and hydrogen are formed from methane, and a dynamic equilibrium is established. 2CH.(g) = 3H2+C2H2 (g) What are the units for Kc? mol dm? A B_ mol dm® Cc mol dm? D mol* dm? Upon heating, dinitrogen tetroxide will dissociate into nitrogen dioxide. N2Oa(g) = 2NOz2(g) At a particular temperature, the equilibrium partial pressure of nitrogen dioxide was 0.67 atm and dinitrogen tetroxide 0.33 atm. What is the numerical value of Kp at this temperature? A 1.36 B 049 Cc 065 D = 2.03 ‘The table gives the concentrations and pH values of the aqueous solutions of two ‘compounds, P and Q. Either compound could be an acid or a base. Pp a concentration | 2 mol dm 2 mol dns pH 9 6 ‘Student X concluded that Q isa strong acid ‘Student ¥ concluded that the extent of dissociation is lower in Qaq) than in P(aq). Which of the students are correct? A Xonly B Yonly © both x and ¥ D neither X and Y

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