UNIVERSITY OF PESHWAR B.A/B.Sc.(PART-II) ANNUAL EXAMINATION (2016) PAPER: CHEMISTRY (C) Time Allowed: 03Hours Max Marks.30 Note:.(i) Attempt any Five questions .All questions carry equal marks, (it) Possession of mobile phone & other isa fs IS strictly prohibited in the examination Rial nee of paper and i a atom . (a) Name a on aly ind According to IUPAC itt _ \¢ j % (iii), CHy-CHCH=CH, CH; CHCH,CH, . CH (b)Draw Structure for the following: (i) 2-bromo-4methy 1-3 -hexane. (ii)(z)-1,2-dichloro -3-ethy 1-4 -methy’ 1-2 -Pentene, (iii) (E)-1,2,dibromo -3-Isopropy 1-2-hexene. (03) ii. (a) Draw the resonance contributing structures for the following and compare their stability. ‘ [ OH (i) CHyCCHCH-CH {il (itl) CHy-CN-CHy 1 | CH, CH;. (b)What product be obtained from the reaction of 1,3- butadiene with one equivalent of HBr. (03) iii. Explain why Markonikove's rule is followed in reaction “A” but to in reaction “B” ? (03) (a)CH»=CHP+HF CH;CHF; (b) CHy=CHCF;+HF FCH)CH;CF; iv. Explain the difference between Resonance and Mesomeric effect with examples. ((6) v. Explain how | sa can be ae TE (a) sual Hy (b) CH,CH,CH,CH;CN (co) CH,CH=CH-CH; Vi. Justify the following with reasons, (a) Phenol is more acidic then ethanol. (02) (b) Methylbromide under SN’reaction while ter.butyle bromide undergoes SN’ reaction .(02) (c) Addition of HBr to 1-Butene in the presence of H,0,does not follow Morkonikov’s Rule,(02) vi. How the following compounds could be prepared form benzene? (a) Benzaldehyde. (02) (b) Benzoic Acid. (02) (c) Aniline, (02) vii, Complete the following reactions with detailed mechanis. "| CHyC-OH « HOCH CHyCHsCH Cont CO, (b) NOs ALBr, +CH;Br eet adie Benzene, OC ix, Explain the difference between optical and geometrical Isomerism with examples.’ (06) xX. Sugeest mechanism forthe following two elimination ions, agi? o ott % > i CH; OH cy, CH; | HB Cly-C- 0-0 le i cal CH; CH,