Time allowed: 03 hours Note: (i) Attempt Fiv i Not i nga oo ti l carry equal marks. ic UNIVERSITY OF PESHAWAR B.A/B.Sc (PART-II) ANNUAL EXAMINATION (2013) mn in which question ssession of mobile phones & other electronic de- vices is strictly prohibited in the examination hall & can lead to cancellation of paper and examination. 1) Define /explain/compare the following appropriate exam- ples where needed. eS ormad py 2) = 3) b. 4 = i ii. 5) a. i. b. iil. Principle of microscopic reversibility . Hydroxylation Cc. Polymerization . Sytzeff rule 6 No bond resonance Conformations g. Diastereomers . Racemization i Diazo coupling Tautomersim Define conformational isomerism? Explain conforma- tional energy diagram for n-butane. Explain the stability of 1,3-dimethylcyclohexane. a. Describe the effect of substituent group on the reactiv- ity of benzene with suitable examples. Explain the following reactions with-mechanism (i) Acylation of benzene (ii) Nitration of nitrobenzene Give detailed description of any two of the mee Cannizaro reaction Pipacole-pinacolone rearrangement Oxymercuration-demercuration of we com How oe can be pr ® Nitriles aan) idecili. Alkenes eae or the preparation of amines. Aner wing reactions: 7) a. 8) a. 9) +CO; 1c ? Hy? RCHO + CH,OH —»? S004 _,9 CH,COCH, +OH™ —>?—%2 4? ~< + Bro RCOOAg + Br, 2424? Define reaction mechanism. Explain the differ:nee be- tween SN, and SN) with suitable examples. Explain and compare the acidity of a carboxylic acid with phenol. Write two methods for the preparation of carboxylic acids. . Write two methods for the preparation of phenol. Draw the structures of the following: Picric acid ii. Benzal chloride i. 5-hydroxy-3-oxohexal iv. Salicyclic acid Phenanthrene . Write IUPAC names of the following: com St OUTS