4.1: Rate of a Chemical Reaction 2017 1. Forarescton 1A —> 26 ate of dsppesrance of A isrelated to rate of appearance of Bby the expression wd{A) _1 [8] afl _ alB) One ra Oe a -d{Al_ alB] Oe ae (Karnataka CET, AEEE 2008) 2016 2. 34 —> 28, rate of reaction, + ae ‘is equal to 3 o 34 1d{A) © 244 @ 4 (Warmataka CEN) 2015 3. inthe reversible ration, 2NO; 38, if the rate of formation of B is.xmole/L, the rate of consumption of is () x (b) 3x72 (©) 2x3 @) 3x (W&KCEN 5. 100m’ of | M CH,COOH was mixed with 100 cm’ of 2. MCH,OH to form an estet. The change in the initial rate if each solution is diated with equal volume of water would be @ 4 times ()'0.25 times © 2etimes @ 05 times. (Kamatata CEN 2013 $B Consier tne following reaction for INO, + Fri) —> 2NO2F i, The expression for the rate of reaction in terms ofthe rate of change of partial pressures of reactant and product isare (a) rate =~ Ydp(NOY] (b) rate = "Aldp(NO,)dt] (©) rate =~ ‘Afdp(NO.Fydi] (@ rate= Aldp(NO,Fy/dt] 2012 ald) 7, The initial rate, -“7> at ¢= 0 was found to be (WB JE) 2.6 107 mol L's for the reaction +28 > Products The inal ate, - 1, ati=0is (@ 0.10 mol L's! (b) 2.6% 10? mol L's ©) 5.2% 10? mol Ls" (@) 6510? mol Ls (AMU (Enger) 8, For the reaction given below, ” SB + Brig + GH) 3Bryp #3HLO ‘The rate of formation of Bry is related to rate of consumption of Br” by the following relation 5dr] @ wy) Ae) __alBr) a3 dt at dt © SAC] B38 ‘The relation in between ky; ky and ky is (@) 2k 0) ki=h=k (@) none of these. ‘WU (Eng) 10, In a restion, 24 + B > 448, the eactant B will disappear ot () halfthe rate as A will decrease (b) the same rate as'4 will decrease (©) twice the rate as 4 will decrease (@ halfthe rate as 8 will form. 2010 ‘IL. Ina catalytic experiment involving Haber’s process Nag, + 3a) > INF. the rate of reaction was measured as Rate = [NH,] = 2.0 « 10 Ms", Ifthere were no side reactions, what was the rate of reaction expressed in terms of N;? W&KCEDo @)y hx 104 Ms (0) 4x10“Mst © S<10°Ms" (@) 1x10°Mst (&KCED 2009 12, Inthesynthesisofammonie romnitrogenandhydrogen gases, if 6 x 10 mole of hydrogen disappears in 10 minutes, the number of moles of ammonia formed {in 0.3 minutes is (@) 18x10? (b) 1.210% (©) 4107 (@) 3.6 10° &K CED) 2008 13, Inthe reaction 34 —> 28 rate of reaction + 22 ig equal to a a -idAl 24) Oa Osa 2aldl 3.44 @ 7g WBE)EEEIWNNATIONS L dA) _1d{3) 2 1 2d 7d 4d ae ay: Ae), 3.8) 3 dt 2 dt 3 dt dt A, 3 9 :NATENOH Rate of wacion aC al-pnog (820 oo Rat ofdiapeance of NO, = ROA) a4nogP 24 1N2041 4. (©): Forthe reaction, 24—> 3B idja]_148) Rateof reaction = 3-5-5 gp day = Raccreamepionot a{ Al} Be a) 3 5. ():CH,COOH+ CH,OH —> CH,CDOCH, + 1,0 iw 2M = HCH,COOMICH, OH] =Pxcacafforaonot (2) =2k ‘When solstion is diluted with equal volime of wate concentation is reduced io hal. k 13. @):In renction,34—> 28 di) 3a 2 aa) 2a} a 3a Rate of reaction 6 @@ 7. (914 +20 products 26x10? mol L* 4) a a} al dt AB) 2a 26x10 =52x10° molt st 8 (@):SRF +BrOs + 6H —> 3Br, +3H,0 15) ary a5 idfar} 3 a apr] de 9. (4):For equation, N05 —* 2NOp +50) 16 (@):24+3—> AB ‘The rate of disappearance of reactant wl be aa} dB) dh ld dd aN] 1 @) at, AINO}} _ 24f0,] dt aN} a 3d de Rate with respect to Na will be 2x10" Ms 12, (b):N;+3E,—> 2NH, Uhl, Mt (NH), a then in 03 min= 3 [NHJ =0.4 107 10=4 x10? Ta 10 min, ro. of moles of NH; =4 » 107 43210 03 i Ms" 1x10" Ms 10 1210?