(6)

Reaksi titrasi: MnO−

4 + 5Fe
2+
+ 8H+ → Mn2+ + 5Fe3+ + 4H2 O
5 mol Fe2+
Perbandingan mol: 1 mol MnO −
4
1 mol
Mol KMnO4 = 5 mol ek
× 0,1065 N × 36,4 × 10−3 L = 7,76 × 10−4 mol
Mol Fe2+ = 5 × mol KMnO4 = 5 × 7,76 × 10−4 mol = 3,88 × 10−3 mol
berat Fe2+ 3,88 × 10−3 mol × 55,847 g/mol
%Fe = × 100% = × 100% = 21,93%
berat sampel 0,9882 g

(7)
a. Reaksi setengah sel: MnO− + −
4 + 4H + 3𝑒 → MnO2 (𝑠) + 2H2 O
b. Normalitas larutan:
𝑛 = 3 (jumlah elektron terlibat)
N = M × 𝑛 = 0,0250 mol/L × 3 ek = 0,0750 mol ek/L = 0,0750 N
c. Reaksi dalam basa:
MnO− −
4 + 𝑒 → MnO4
2−

𝑛=1
N = M × 𝑛 = 0,0250 mol/L × 1 ek = 0,0250 N

(8)

5As2 O3 + 4MnO− +
4 + 9H2 O + 12H → 10H3 AsO4 + 4Mn
2+
4 mol KMnO4
Perbandingan mol: 5 mol As2 O3
0,2068 g
Mol As2 O3 = 197,841 g/mol
= 1,045 × 10−3 mol
4
× 1,045 × 10−3 mol
Molaritas KMnO4 = 5 42,50 × 10−3 L
= 0,0197 M
Setengah sel MnO4 : MnO−
− −
4 + 5𝑒 →Mn2+
N = M × 𝑛 = 0,0197 M × 5 ek = 0,0985 N

(9)
Mol I2 berlebih = 12 × 0,0120 M × 38,65 mL = 0,2319 mmol
Mol I2 total = 0,0500 M × 10 mL = 0,5 mmol
Mol I2 bereaksi = mol I2 total − mol I2 berlebih = 0,5 mmol − 0,2319 mmol = 0,2681 mmol
Reaksi asam askorbat dengan I2 :
I2 + C6 H8 O6 → C6 H6 O6 + 2HI
Mol asam askorbat = mol I2 bereaksi = 0,2681 mmol
Jumlah asam askorbat (mg asam askorbat per mL sirup):
mol asam askorbat × Mrasam askorbat 0,2681 mmol × 176,126 g/mol
= = 0,236 mg/mL
Vsampel 200 mL