Which of the fotlowing techniques or proc esses may be used to separate a mixture of plantpigmentsintoitsindividval components? (A) Fractionaldistitiation (B)__Solventextraction (©) Paperchromatography (D) Centrifugation ‘The rate of a chemical reaction does NOT. dependonthe (A) concentration of the reactants (B) presence of a catalyst (C)__ temperature of the reacting system (D) energy change associated with the reaction ‘Which of the following compounds may be conveniently prepared by precipitation? (A) Bariumsulphate (B) —Sodiumsulphate (C) Copper It) sulphate (D) Magnesium nitrate Which of the atoms represented below by theirelectronicconfiguration will mostreadily formapositiveion? 2 By 2, © 2 W) 2 Particles in a solid cannot move about be- cause the (A) forces of airaction are very strong (B) _ particlesare tightly packed together (©). paniclescannotbeeasily compressed (D) _ particleshaveahighdensity 6. Which of the foliowingean behave both asan oxidizingagentandareducingagent? (A) Concentrated sulphuric acid (B) Acidified potassium permangate (VIN) solution (C) Chlorine gas (D) Hydrogen gas ‘The followingchromatogram is obtained from the paper chromatography of a mixture of dyes and four separate dyes. ° ° ° ° ° ° ° Mixture Dyel yell DyelII_Dye IV ‘Themixturecontains dyes (A) Land Ilonly (B) Land Ilfonly (C) II, Wand lV only (D) 1. fland1V only Which of the following aqueous solutions contains | mole of hydrogen ions? (A) 1d of 1.0 mol dm H,SO, (B) 1 dm of | moldm* CH,COOH (C) 2dm' of 0.5 mol dm\H.SO, (D) — 2dm*of 0.5 mol dm* HCI GO ON TO THE NEXT PAGE 4 110. i. ‘When iron (IU) sulphate reacts with aqueous potassiumiodide,abrowncolorationofiodine isproduced. Which of the following deduc- tionsis correct? (A) Tron({I1) sulphate isa reducing agent. (B) _Theiodide ion has been oxidised to iodine. (©) Theiron Itt) sulphate has lostelec trons. (D) __ Theiodideion has gainedelectrons. ‘Sodiummetal contains I. Navionsand mobileelectrons. Il, Nationsandmobileelectrons. II. cations which repel each other. IV. anions which repel each other. (A) TandItonly (B) __IandIVonly (© Mandionly (D) MandIVonly Which of the following statementsare true? Isotopes of anelementcontain 1. thesamenumberof protons TL thesamenumberof neutrons. Ul. differentnumbersofelectrons. IV. thesamenumber of protonsaselec- trons (A) Land only (B) Land IV only (© Mand tttonly (D) Hand IV only 0121201012005 2. 13. 14. 15. Which of the following processes suggests that matieris made up of minute particles? (A) __ Diffusion (B) — Capiltarity (C) Evaporation (D) Distillation Items 13-14 referto the following alcohols. 1 CH,OH I. CH,CH,OH I | CH,CH,CH,OH IV. CH,CHOHCH, ‘Thetwoalcohols withidentical molarmasses (A) Land ttt (8) Wandin (©) Mandlv (D)Mandiv Which alcohol contains thesame numberof carbon atoms as methane? (A) ui (B) It © it o WV Which of the following statements about chemical reactionsis NOT correct? (A) Energy is given out when bonds break and taken in when bonds form. (B) _ Chemicalreactionsinvolvethemak- ingand breakingof bonds. (©) Endothermic reactions take energy fromthesurroundings. (D) _Exothermicreactions giveenergy to thesurroundings. GO ON TO THE NEXT PAG!17. 18, 19. Liem 16 refers to 1 mole of EACH of the 20. followingacids. iy sHIsG, 1 CH,CooH tm. (COOH), Iv. HNO, © Which wo of the above acids require more than one mole of NaOH(aq) for complete neutralization? (A) Tand IL (B) land I © Mand HE ) Hand IV 2. Items 17-18 refer to the following types of substances. Each may be used more than once, once or not a all to answer the items below. (A) Salt (B) Base © Alkali ) Acid Which ofthe above substances is the oxide of ametal? supplies protons as the only positive ions in aqueous solutions? In which of the following processes is frac- tional distillation NOTused? (A)__ Refiningoferudepetroleum re (B) Separation of methanol from a methanol-watermixture (©) Conversion of alkanes into unsatu- rated compounds (D) Separation ofliquidairintonitrogen andoxygen eaten. 01212010F 2005 Which tw6 of the following are true about electrons, protonsand neutronsin an atom? 1. Protonsand neutronsare found inthe nucleus. U. Electrons can be found anywhere outside the nucleus. I. Thenumberofprotonsalwaysequals, the number of neutréns. IV, Thenumberofprotonsalwaysequals the number of electrons. (A) Land Mit (®B) — Tand1V (©) Mandir @) — WandIv Which ofthe followingis NOT amixture? (A) Steet @) Brass © Solder (D) Mercury Items 22-23 refer to the following sets into which elements may be placed. (A) Group Lelements (B) — Group2clements (©) Thehalogens (D) — Thetransitionelements Select the set of elements which BEST fits the following descriptions. Each set may be used more than once, once or not at all to answer the items below. Which setofclements has molecules which containtwoatorns? has atoms with 2 electrons in their outer , shells? GO ON TO THE NEXT PAGE, |24. 26. “5 Which of the following factors would NOT be expected to determine whether a particu- lar cation would be discharged during elec- trolysis? (A) The position of the cation in the electrochemical series (B) ‘The concentration of the cation in solution (©) Theinertness of theelectrode (D) — Thetemperature ofthe solution Which of the followingreactionsinvolveoxi- dation and reduction? 1. Mg(s)+2H*(aq)—>Mg™(aq)+H,@) a Mg(s) + 4H* + 2NO, (aq) > Mg"(aq) + 2NO,(g) +2H,0(1) m1. (aq) + $03 (aq) > BaSO,(s) IV. Zn(s)+Cuaq) >Zn™(aq)+Cu6s) (A) Llandillonly (B) II, land TV only (© — Llfand IV only (D) [land 1V only Crystals of sodium chloride are BEST re- ferred to as (A) molecularerystals, (B) —_ macromolecularcrystals (© metalliccrystals (OD) ionicerystals 0121201072005 21. 28. 29, rey i ee Study the following thermochemical equa- tion. X+Y=Z,AH=-BkI mol” Which of the following ways can be used to compute the value ~ B kJ? 1. Theenergy of Zminustheenergy of Xand ¥ Il, The energy of X and Y minus the energy of Z III, Thesumoftheenergies of X, Y and Zz (A) only (B) Land Lonly (© Monly (D) Mand Iffonly FeCl, and FeCl, are two chlorides of iron. Whichofthefollowing tatementsaboutthese two chlorides of iron are true? I. Theoxidation stateofironis different inthe wo chlorides. TI, Thepercentageofiron by massinthe twochloridesis different. IIL, Thecolours ofthe aqueous sotutions of the two chlorides are different. IV. The aqueous solutions of the two chlorides do not conductelectric- ity. (A) Land only (B) and lV only (©) 1,Mand Ifonly (D) —H,Mland TV only ‘Sulphuricacid formsthe sodium salts NaHSO, and Na,SO,. Its basicity is therefore A 1 @) 2 © 3 © 4 GO ON TO THE NEXT PAGEBarium (Ba) isanelement in Group! of the periodic table. It reacts with cold water to give hydrogen andanother substance of for- moa (A) BaO (B) Bao © B20 (Dd) Ba(OH), ‘tems 31 - 32 refer to the following chemi calls. (A) Zinccarbonate (B)—-Magnesiummetal (©) Bariumnchloride (D) __Phenolphthalein In answering items 31 - 32, a particular choice from the above may be made more than once, once or not at all Which of the chemicalsabove 31. canbe used in an acid-base titration to show that the reaction has been completed? 32. inaqueoussolution, producesa white precipi- 33. tateon reaction with sulphuric acid? item 33refersto the table below which gives themeltingand_boilingpointsofthechlorides offourelements | mp. of bp. of Element | chloride/K | _chloride/K ————F 1 | 210 453 i 248 348. m | 973 | 1693 v 193) 333 Which of these elements would MOST likely formachloride thatisionic in nature? (A) Tony (B) only (© — Monly {D) — TVonly 0121201012005 35. 36. 37. Items 34 - 35 refer to the following terms. (A) Isomers (B) Polymers (©) Allowopes (D) Isotopes Matcheachofthe followingdescriptions with oneofthetermsabove, Each option may be used more than once, once or not atall Solid formsofa givenelement whichdifferin physical properties ‘Compoundshaving the same molecular for mulabutdifferentstructural formulae », Which ofthe followingelementsreacts most vigorously with H(aq)ionstogivehydrogen gas? (A) Zine (B) Lead © tron (D) Copper Potassium isametal. From thisinformation ONLY itmay bededuced that potassium (A) issoft (B) __ isveryreactive (©) hasalowmeltingpoint (D) _ isagoodconductorofelectricity GOON TO THE NEXT PAGE39. 40. 4. 4 Item 38 refers to the Haber process for the productionof ammonia accordingtotheequa- tion 92 kJ mol" N,(g) + 3H,(g) > 2NH(g) 4 The catalyst used in this process is (A) iron (B) nickel (© platinum (D) —_vanadium(V)oxide ‘Whencopper (II) carbonateisheatedalonein a dry test tube a gas is evolved and a black residue is formed. This gas is expected to (A) relightaglowingsplint (®) — tumrediitmusblue (© decolourizeacidified aqueous potas- sium manganate (VT) (D) forma white precipitate with aque- ouscalcium hydroxide Which of the following aquieous solutions will produce a blue precipitate with aqueous so- diumhydroxide? (A) Caleiumnitrate (B) Iron (I) nitrate ©) Copper(it)nitrate (D) — Aluminiumnitrate Which ofthe following gases areclassified as pollutants ofthe air? I. Nitrogen I, Carbonmonoxide MI. Hydrogen TV. Sulphurdioxide (A) Land Ill only (B) and IVonly (© [Mand tttonly (D) [land IV only 42. eet Smee. Many fertilisers contain ammonium salts be- cause these salts, (A) areall very soluble in water (B)__improvethe textureofthe soil (©) dissolvetogiveacidiesolutions which keep away pests (D) area source of nitrogen which is essential to plant growth 43. Which of the following neither reacts with 44, 4s. water, nor displaces hydrogen from dilute hydrochloricacid? (A) Calcium (B) ‘Zine (©) Copper (D) tron In the reaction between zine and ditute sul- phuricacid (A) wateris formed (B) ~aninsoluble saltis formed (C) _neutralisationoceurs (D) _ oxidationand reductionoccur Which of the following are arranged in order of increasing particle size? (A) Colloids, solutions, suspensions (B) Solutions, suspensions, colloids (C) __Suspensions,colloids, solutions (D) Solutions, colloids, suspensions GO ON TO THE NEXT PAGE tii“Be Items 46-48 refer to the following organic 50. Which of the following is NOT true of all compounds. homologousseries of compounds? (A) Bihanol ‘The members ofthe series have (B) Ethene (Cy Ethanoicacid (A) thesame functional group (D) _ Ethylethanoate (B) —thesame general formula (©) similarchemical properties Inansweringitems46-48aparticularchoice (DB) thesameempirical formula from theabovemay be made more thanonce, eonsROLOe Tete once, or notat all : : . S1. | Whichofthefollowingtypesofpolymersmay Which ofthe organic compounds be derived from compounds like the one below? 46. undergoesaddition reactions? : i 47. is immiscible with water and is sweet- H-C~ Coo smelling? | NH, 48. reacts with hydrogen o produce an alkane? (A) Polyamide B) Polyester (C)__ Polyalkene 49. Thecompoundethene is described asbeing, (D) Polysaccharide - unsaturated, This means that the SMOG (A) carbonatomsinethenearelinkedby _§2, ‘The process by which large molecules of singlebonds hydrocarbons are broken up intosmallermol- (B) molecule has insufficient hydrogen eculesiscalled atoms (©) carbon atoms in the molecule are (A) saponification very rexctive (B) cracking (BD) moleculecontainsat leastone double (C) polymerization bond (D) condensation 53. The fermentationof sugars, using glucose as the substrate, can be represented by the equation (A) GH,,0, + 60, ~> 6CO, + 6H,0 B) GH,,0,+ CHO 8O HS, + H,0 ‘ (© — GH,,0, > 2C,H,0H +2C0, . (DP) 6CO, + 6H,O > C,H,0, + 60, ent GOON TO THE NEXT PAGE 012120101F2005 ceaue rap ope yy Tr?) )34, 55. 012120102005, Spirit lamp RR | ee Aqueotis calcium hydroxide Which of the following BEST describes what will be observed inthe U-tube and the test tube at the end of the investigation? ) (B) © ) U-tube ‘Test tube Colourless liquid Carbon dioxide Water White precipitate Colourless liquid White precipitate Water Carbon dioxide Ifthe ice were removed, which of the following wouldrepresent the equation forthe reaction? (A) ®) © ) 2.C,H,OH(aq) + 7 0,(g) > 4 CO, (g) +6 H,0 (1) 2H. CH,OH(I) +7 0,(g) > 4 CO, (g) +6 H,0 (g) 2.CH,OH(aq) + 7 0,(g) > 4 CO, (g) + 6 HO (aq) C\H,OH(aq) + 7 0,(2) > 4 CO, (g) +6 H,0 (2) : GO ON TO THE NEXT PAGE87. -10. The functional group present in carboxylic Item $9 refersto the following information acidsis Chlorine is bubbied into aqueous potassium H iodide mixed with a few drops of aqueous starch, in the apparatus shown below. ( -c=0 —— on I ®) -Cc=0 H | KI (aq) + starch} © -C-oH | H 59. Whatwill be thecolourof the solution in the fr test tube when the chlorine stream has ? i stopped? © - ‘i =C-OH (A) Yellow-green (B)—_Red-brown H (© Yellow-greenthenred-brown ©) Bhe Whichcompoundis NOT considered tobea polymer? (GO eolsner faethe parcel racer (A) Aminoacids —CHXCH,CHXCH,CHXCH,CHXCH,- (B) Starch (©) Proteins ‘The formulaof the monomer would be (D) _ Polyamides (A) XCH,CHX The major natural source of alkanes and ® cHecHx alkenesis : © CHCH,Xx (A) petroleum (B) natural gas ©) ch=cHx (©) theearth’s crust (DP) theatmosphere IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TE