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Pickling and passivation

Stainless steel can corrode in service if there is contamination of the surface. Both pickling and passivation are chemical
treatments applied to the surface of stainless steel to remove contaminants and assist the formation of a continuous
chromium-oxide, passive film. Pickling and passivation are both acid treatments and neither will remove grease or oil. If
the fabrication is dirty, it may be neccesary to use a detergent or alkaline clean before pickling or passivation.

Pickling

Pickling is the removal of any high temperature scale and any adjacent low chromium layer of metal from the surface of
stainless steel by chemical means.

Where the steel has been heated by welding, heat treatments or

other means, to the point where a coloured oxide layer can be
seen, there is a chromium depleted layer on the surface of the
steel underneath the oxide layer. The lower chromium content
gives lower corrosion resistance. To restore the best corrosion
resistant performance, the damaged metal layer must be
removed, exposing a fully alloyed stainless steel surface.
Mechanical removal may leave abrasive or other particles
embedded (interfering with corrosion performance) or may be
impractical, so chemical means are usually employed.

Procedures incorporating pickling solutions of nitric (HNO3)

and hydrofluoric (HF) acids remove the scale and the
underlying chromium depleted layer and restore the corrosion
resistance. Pickling solutions also remove contaminants such as
ferrous and ferric oxide particles. Pickling solutions other than
mixtures of nitric and hydrofluoric acids exist and can be used for specialised applications.

Pickling pastes, where the solution is mixed with an inert carrier, are commonly used to treat selected areas such as
welds.

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Pickling involves metal removal and a change or dulling in the visual brightness of the metal.

Electropolishing is a useful alternative to pickling. Metal removal is achieved, but usually results in a bright, smooth and
more highly corrosion resistant finish.

Passivation

Passivation is the treatment of the surface of stainless steels,

often with acid solutions (or pastes), to remove contaminants and
promote the formation of the passive film on a freshly created
surface (eg through grinding, machining or mechanical damage).

Common passivation treatments include nitric acid (HNO3)

solutions or pastes which will clean the steel surface of free iron
contaminants. Care must be taken in selecting and using
passivation treatments to ensure the selected treatment will target
the contaminant. Passivation will also aid in the rapid
development of the passive oxide film on the steel's surface.
Passivation does not usually result in a marked change in
appearance of the steel surface.

Both pickling and passivation solutions can employ dangerous acids that can damage both the operator and the
environment if not handled correctly. Stainless pickling acids are highly corrosive to carbon steel.

It is essential that all acids are thoroughly removed by rinsing the component after completing the process. Residual
hydrofluoric acid will initiate pitting corrosion.

It may be advantageous to neutralise the acid with an alkali before the rinsing step.

ASTM A380 Standard Practice for Cleaning, Descaling and Passivation of Stainless Steel Parts, Equipment and Systems
is a valuable source of information on pickling and passivation treatments. Other sources of information may be obtained
by contacting ASSDA.

The corrosion resistance of the stainless steel is affected by the roughness of the surface after polishing, with a marked
decrease of the corrosion resistance as the surface roughness increases above a Ra value of about 0.5 micrometres. This
roughly corresponds to the surface produced by grinding with 320 grit abrasives.

Either passivation or electropolishing can be used to improve the corrosion resistance of mechanically polished surfaces.

Safety

Pickling and passivation use strong acids, and normal precautions for safety should be followed. Consult Materials
Safety Data Sheets and product packaging for detailed advice.

Further sources of information on both pickling and passivation can be obtained by contacting ASSDA.

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