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Post Curing Thermoset Resins

In the past, we’ve discussed the importance of temperature control when


casting with thermoset resins. In this article, we will focus on the post cure
process for molds or parts made with thermoset resins.

What is post-curing?
Post curing is the process of exposing a part or mold to elevated
temperatures to speed up the curing process and to maximize some of the
material’s physical properties. This is usually done after the material has
cured at room temperature for at least 12 hours. In general, thermoset
materials will achieve full cure at room temperature over a period of 7-10
days. After a full cure is achieved at room temperature, post curing will
have no e ect on the material’s properties.

Why is post curing necessary?

Post curing will expedite the cross-linking process and properly align the
polymer’s molecules. Much like tempering steel, post curing thermosets can
increase physical properties (e.g., tensile strength, exural strength, and heat
distortion temperature) above what the material would normally achieve at
room temperature.

Post curing is extremely important when an application requires secondary


machining.
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Fred DeSimone of Hapco says, “Post curing your parts prior to machining is
critical to ensure dimensional stability, particularly when trying to maintain
tight tolerances.  Elevated temperature acts as a catalyst to complete the
cross-linking process and stabilizes the cured plastic so that it does not
continue to creep over time. Although most thermosets will appear to be
cured after several hours at ambient room temperature, the reality is that it
can take up to two weeks for the material to fully cure.  If secondary
machining is completed during this time on non-post cured parts, they can
either shrink or grow out of speci cation while the polymerization process is
still occurring.”

How should I post cure my parts?

An oven is best for applying uniform heating, but we don’t recommend using
the one in your kitchen. Applying too much heat to some materials may
result in dangerous fumes being emitted or a material may melt, ruining
your oven. Digital, vented lab ovens are ideal for post curing parts and
molds; however, this can also be done in an X-Series Molding Chamber.
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During elevated temperatures, thin-walled parts may bubble or deform.


Keeping them in the mold or using a xture during post cure is
recommended. Make sure that anything you place in an oven can take the
heat.

Is there an ideal post cure temperature?


Generally speaking, rigid materials are post cured at 175F for 8-24 hours and
exible materials at 140F for 8-24 hrs. Be aware that post cure temperatures
vary for di erent materials. Please review the Material Handling & Safety
Notes supplied with your speci c Hapco products, or contact Hapco’s
Technical Support for more information.

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Resources
Blog
FAQ
Videos
Glossary
SDS Library
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Viscosity Chart
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Hardness Chart
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Request a Quote
Technical Support

Recent Posts
Filters: A Key Tool in the Fight Against Covid-19
River Cribbage Board Using Hapco Resins
Casting a Clear Sculpture Using Hapco Materials, Equipment, and Expertise – Part 2
Casting a Clear Sculpture Using Hapco Materials, Equipment, and Expertise – Part 1
A Helpful Guide to Processing High Viscosity Resins

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