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Article history: CdS is a II IV family semiconductor chalcogenide that has been deposited on amorphous glass substrates
Received 8 June 2020 as thin films form with various solution (precursor) volume (5, 10, and 15 mL) by employing a cost-
Received in revised form 13 August 2020 effective spray technique using a nebulizer. The effect of the varying quantity of coating solution on the
Accepted 25 August 2020
structural and optoelectronic properties has been studied. The X-ray diffraction (XRD) patterns reveal the
Available online 28 August 2020
polycrystalline nature of CdS with a hexagonal structure with preferential orientation along the c-axis.
Atomic force microscope (AFM) demonstrated the film prepared with a 10 mL solution possesses uniform
Keywords:
coating with spherical shaped nanograins. Energy dispersive X-ray analysis (EDX) reveals the coated
CdS thin film
Precursor volume
film contains Cd and S elements. The direct bandgap values decreased with the increase in precursor
Spray pyrolysis volume and reached a minimum value for the film prepared with a 10 mL solution. Photoluminescence
Spherical nanograins (PL) spectra revealed the two emission peaks in which a sharp dominant peak at 470 nm and a peak
Photo-sensor with a shoulder at 620 nm. The CdS film coated with a precursor spray volume of 10 mL resulted in
better photo-sensitivity characteristics of the responsivity of 1.01 AW−1 , detectivity of 2.21 × 1012 Jones,
photo-sensitivity of ∼4.9 × 103 , and external quantum efficiency (EQE) of 257 %. The film-coated with a
solution volume of 10 mL was found to have good optical characteristics which make them suitable for
photo-detector applications.
© 2020 Elsevier B.V. All rights reserved.
1. Introduction there is a huge need for reliable and rapid response semiconduc-
tor devices that could work with self-powered [1,4–6]. Group II–VI
In the modern world, there is a huge demand for sophisticated chalcogenide metal compounds have been attracting the modern
optoelectronic devices for day-to-day life, industries, education world due to their wide variety of applications like solar cells, LEDs,
field, and research organizations, etc. [1–3]. But with these photodetectors, optoelectronic devices, and so on [7–9]. Among dif-
demands, the utilization of power consumption is also rapidly ferent chalcogenide compounds, Cadmium sulfide (CdS) is a special
increased. It is well known that the power issue is the biggest class of material that possesses a wide direct bandgap for many
unsolved problem for the modern world. In the context of this, photo-sensing and optoelectronics applications. It provided a direct
bandgap of 2.4 eV with a low recombination rate for photogen-
erated carriers [10]. In addition to this, CdS is a wider studied
material for the modification of different physical and photode-
∗ Corresponding author at: Research Center for Advanced Materials Sci- tector properties with different dopants and different preparation
ence(RCAMS), King Khalid University, Abha 61413, PO Box 9004, Saudi Arabia. conditions [11–13]. There are huge reports are available on the
∗∗ Corresponding author at: Arul Anandar College, Madurai, 625514, India.
different growth methods of CdS viz., CBD [14], thermal [15],
E-mail addresses: valanroyal@gmail.com (S. Valanarasu),
vangaganesh@gmail.com (V. Ganesh).
electro-deposition [16], electron beam evaporation [17], Sol-gel
https://doi.org/10.1016/j.sna.2020.112306
0924-4247/© 2020 Elsevier B.V. All rights reserved.
2 I.L.P. Raj, S. Valanarasu, K.H. Prasad et al. / Sensors and Actuators A 315 (2020) 112306
Table 1
Film thickness and structural parameters of CdS thin films.
5 460 41 0.311
10 510 58 0.212
15 490 53 0.259
Fig. 3. AFM 3D images of the CdS thin films prepared at different precursor solution
volume (a) 5 mL, (b) 10 mL and (c) 15 mL.
Fig. 7. (a) Schematic diagram of CdS photosensor, Semi-log I-V characteristics of the fabricated CdS photo sensor measured in dark and illumination conditions at a bias
voltage between -5 and 5 V prepared using different precursor solution volumes (b) 5 mL, 10 mL, and (d) 15 mL.
Table 2
Comparison of the photosensor parameters of current work with the previous CdS photodetectors.
Sample Responsivity (AW−1 ) External quantum efficiency (EQE) (%) Detectivity (Jones) Rise time Fall time Ref.
and recombination; however, the slow rate of up and down in the device’s photo-detection mechanism and recombination process.
system is attributed to traps and impurities. The rise and fall times The experimental data were fitted by the polynomial equation: y =
of the present work are comparable with earlier reports by Li et al. A + Bxn and the fitted parameters are shown in Fig. 8(d). The expo-
[54] and An et al. [55]. nent n is found to be 1.01, 1.78, and 0.99 for CdS films fabricated
Fig. 8(d) shows the relationship between the photocurrent and using 5, 10, and 15 mL coating solutions, respectively. Among them,
the incident light intensity. To study the quantitative dependence the device fabricated with a 10 mL solution is found to be a max-
of the photocurrent with respect to illumination intensity, the pho- imum value of 1.78. It indicates that the film prepared with a 10
togenerated current as a function of light intensity can be fitted by mL solution displays fewer defects resulting in reduced CdS thin
a simple power law [56]. Different semiconductor processes such film trap resulting in improved performance of CdS photodetectors
as electron-hole pair generation, trapping and recombination are compared to other volumes prepared to film.
explained by non-unity exponent curve. The experimental results
were fitted by using the equation [57]: 4. Conclusions
Iph = ˛ϕn (8)
CdS thin films were coated with different solution volumes
Where ␣ is a scaling constant, is the light power, and n an (5–15 mL, in steps of 5 mL) using a cost-effective nebulized spray
exponent. The exponent ‘n’ value offers information about the pyrolysis method. The XRD studies disclosed that all the fabricated
I.L.P. Raj, S. Valanarasu, K.H. Prasad et al. / Sensors and Actuators A 315 (2020) 112306 7
Fig. 8. Plots of current vs. time of the CdS thin films using different precursor solution volumes (a) 5 mL, (b) 10 mL and (c) 15 mL, and (d) A plot of fitted (solid line)
photocurrent as a function of illumination intensity of the CdS thin films with different precursor solution volumes.
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Algarni, S. AlFaify, A significant enhancement in visible-light photodetection Dr. M.S. Revathy has completed her Ph.D. in Anna Uni-
properties of chemical spray pyrolysis fabricated CdS thin films by novel Eu versity in 2016. She has done M.Sc., M.Phil Physics in
doping concentrations, Sens. Actuators A Phys. 301 (2020) 111749–111761, Mother Teresa Women’s University, Kodaikanal. Currently
http://dx.doi.org/10.1016/j.sna.2019.111749. working as an Assistant Professor in the Department
[54] Ludong Li, Zheng Lou, Guozhen Shen, Hierarchical CdS nanowires based rigid of Physics, School of Advanced Sciences, Kalasalingam
and flexible photodetectors with ultrahigh sensitivity, ACS Appl. Mater. Academy of Research and Education, Krishnankoil, Sriv-
Interfaces 7 (2015) 23507–23514, http://dx.doi.org/10.1021/acsami.5b06070. illiputhur, Tamil Nadu, India. She has published several
[55] Qinwei An, Xianquan Meng, Pan Sun, High-performance fully nanostructured papers in national and international journals. Her current
photodetector with single- crystalline CdS nanotubes as active layer and very research interest includes thin films, nanomaterials, solar
long Ag nanowires as transparent electrodes, ACS Appl. Mater. Interfaces 7 cells, Conducting polymer electrolyte, and gas sensing.
(2015) 22941–22952, http://dx.doi.org/10.1021/acsami.5b06166.
[56] Y. Ye, L. Dai, X. Wen, P. Wu, R. Pen, G. Qin, High-performance single
CdSnanobelt metal-semiconductor field-effect transistor-based
photodetectors, ACS Appl. Mater. Interfaces 2 (2010) 2724–2727, http://dx.
doi.org/10.1021/am100661x. Dr. N. Chidhambaram received his Ph.D. degree in Physics
[57] N.I. Najm, H.K. Hassun, B.K.H. al-Maiyaly, B.H. Hussein, A.H. Shaban, from Bharathidasan University, Tiruchirappalli, India in
Highlyselective CdS: Ag heterojunction for photodetector applications, in: 2018. He is currently working as an Assistant Professor of
AIPConference Proceedings, AIP Publishing, 2019, pp. 020031–020041, http:// Physics, Rajah Serfoji Government College (Autonomous),
dx.doi.org/10.1063/1.5116958. Thanjavur, India. He has published several research papers
in the peer-reviewed journals of international repute. His
Biographies research interests focus on metal oxides, carbonaceous
materials, photocatalysis, and optoelectronic devices.