iPus JEE Advanced 2018 Paper 1 & 2 Solved Papers Years JEE ADVANCED JEE ADVANCED JEE MAIN (AIEEE) JEE MAIN (AIEEE)disha + This section contains SIX (06) questions. + Fach question has FOUR options for correct answor(s), ONE ORMORE THAN ONE of these four option(s is (are) correc option(s) + For each question, choose the correct option(s) to answer the question. + Answer toeach question will be evalu following marking scheme according to the Full Marks : +4 If only (all) the eorzect option(s) is (are) chosen, Partial Marks : 43 1€ all the four options are correct but ONLY three options are chosen Partial Marks : 42 If tree of more aptions ar ONLY two options are chosen, both of which are correct options, Partial Marks : +1 If wo or more options are eorrect but ONLY one option is chosen and itis a correct option, Zero Marks : 0:1f none of the options is chosen (ie. the question is unanswered), Negative Marks : -2In all other eases, + For Example: If first, third and fourth are the ONLY three correct options for-a question with second option being an incorrect option; selecting only all the three correct options will result in 4 marks, Selecting only two of the three ‘options (eg. the first and fourth options), without selecting any incorrect option (second optian in this ease), will result in +2 marks, Selecting only one of he three correct options (cither first or third or Fourth option), without selecting any incorrect option (second option in this case), will resulcin 1 marks, Selecting any incorrect option(s) (second option in this case), with or without selection of any carrect option(s} nar. willresult in -2 The potential energy ofa particle of mass froma fixed point Q is given by Vir) = &r positive constant of appropriate dimensions. This particle ismovingin acircular orbit of radius R about the point O. Ir vvis the speed of the particle and L is the magnitude of its, angular momentum about O, which of the following statements is (are} true? wy v= Se = SonkR? @) Le Consider a body of mass 1,0 kg a rest at the origin at time (=0.A force F = (a 7+) isapplied on the hody, where PAPER-1 = 1.0 No! and B= 1.0.N, The torque acting on the boxy about the ox statements is (are) true’? nat time! Osis @ . Which of the following (a) Le Nn (B) The torque % isin the direetion ofthe unit vector + & (© Thewiosiyutebodyats=tsis 9 Hi2h l r= Lsis 2 é (D) Themmagnitade ofisplaccment of the box uniform capillary tube of nner radius ris dipped vertically eh Jhave the water surface in the beaker, ito. beaker filled with water. The water rises toa hi ins the capillary Cube The surface tension water iso. The angle of contact between water and the wall ofthe capillary tube is 8, Ignore the mass of water in the meniscus. Whieh of the following statements is (are) true? (A) For a given material of the capillary tube, lkdecceases with inerease in r (8) For a given material of the capillary tube, fis independent of (C) Ifthis experiments performed in a lift going up with a constant acceleration, then fr decreases 's proportional t contact angle @ In the figure below, the switches 5, and S, are closed simultaneously at ¢ = 0 and a cu Circuit. Both the batteries have the same mi ent starts to flow in d tude of the electromotive force fem) and the polarities are as indicated in the figure, Tgnore mutual inductance between the inductors. The current / in the middle wire reaches its ranienum magnitude /,,. al ime ?= +. Which of the following, statements is (are) true? y > 5 A) Ing = v (BY Mya = \ L 2 © «42 Dy) ena z R ‘Two infinitely lon bt wires lie in the xy-plane alon the lines x ==2R, The wire located at x= +Rearries a constant current /, and the wire located al.c=—R carries constantdisha current J, Acizeular loop of radius Ris suspended with its, V3R )and in a plane parallel tothe xy-plane. This laop carries @ constant current I in the clockwise sn from abave the loop. The current in the Wire is taken to be positive if itis in the +7. direction Which of the following statements regarding the magnetic field B is (are) rue? direction us (A) IFA, = then B cannot be equal to zero atthe origin 00,0) - B) IF, > Oand/,<0, then # can be equal to zero at the in<0,0,0) © MA, O has a uniform magnetic field #)¢ andthe region y= Ohas another uniform magnetic field Byé A positively charged particle is projected from the origin ale 10, asshown inthe figure, Neglect 2 he positive y-axis with s ed yy wvity'in this problern,Ea Let = The the ti from below for the first time, IB 1e when the particle crosses the x-axis 4B, the average speed ofthe particle, in mis-4, along the eaxisia the time interval Tis 4 cs 13, Sunlight ofintensity 1.3 kW m *isincident normally ona thin convex lens of focal length 20 em. Ignore the energy Joss of light due tothe Tens and assume that the lens aperture size is much smaller than its focal length, The average intensity of ight, in kW m 2, atadistance Jens on the other side is 14, Twoconducting cylinders of equal lengtl but different radii are connected in series between two heat baths kept at lempetatures 7, = 300 K and 7, = 100K, ay sltown in the figare, The radius of the bigger cylinder is twice that of the smaller one: nd the thermal conductivities of the materials of the sm ler and the larger cylinders are K, and K, respectively. Ifthe temperature at the junetion of the two -ylinders in the steady state is 200 K, then KK. Iasulacing materia YT x K I Z + This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions. + Bach question has FOUR options. ONLY ONE of these four options corresponds to the correct answer + For each question, choose the option corresponding 0 the corcect answer. + Answer to each question will be evaluated accord the following marking schem Full Marks : «3 1f ONLY the correct option is chosen, Zero Marks : OF none of the options is chosen (is, the question is unanswered) As: 11 Neva other cases, PARAGRAPH* netic theory, the electric and mi Therefo .gnetie quantities must also be tela «questions below, [E] and [B] stand for dimensions of electric and i fields respectively, while [éq] and [jp] stand for nsions of the permittivity and perm respectively. [Z] and [7 respectively. All the quantities a Inclectroma are related to each other and m netic phenom he dimensions af el bility of free space are dimensions of length and time aivon in Sl units. 15, Therelation between [2] and [B]is () (é)=18 10100 ® (wu) © (ele) rr! ©) (EF BIE Ur 16, Therelation between (6) and [1] is CA) igh = FER? BY Ligh bl OP EF © yl bP PET? ©) (aller WP ny PARAGRAPH“ Ifthe measurement ervors in all the independent quantities are known, then itis possible to determine the error in any depenclent quantity truncating the expansion atthe first power ofthe error, For example, are Ax, Ay This is done by che use of series expansion and consider the relation 2= a/y. I'the ervors in x, y and and Az. respectively, ther The to first power in Ayiy, is 1 = (Avy). Therelative: ude, So the error in z will above derivation makes the assumption that Axis 1 Ayly at 1. Therefore, the higher powers of these quantities are ted ) Consider the ratio r to be determined by (+a) measuring a dimensionless quantity a. IF the error in th easurement of wis Na (Aafa 3 s.T; 48 (A) P54Q52R 56S 53 B) P3.Q52R 4S 1 © P52Q53R5ES8 54 DO) P92:Q53 R481 One mole of 8 monatomic ideal gas undergoes four thermodynamic processes as shown schematically in the PV-diagram below isobaric, one is isochoric adiabatic, Match the processes mentioned in List with lhe corresponding statements in List-I Among these four processes, one is cone ‘is isothermal and one is 18, 7 3P, P Lst-t ust Pen process | 1. Workdne by the gasis zero Qa. In process I 2. Temperature of the gas remains unchanged R. ln process IIL 3. Noheat is exchanged between the gas and its surrexndings In process 1V 4. Werkdonebythe gasis6P, V0 (A) P+ 4;Q 33 R51 S 32 B) PHEQ53R 92S 94 © P+3Qo4R ONS 92 D) P+ Q54:R 92851 In the List-I below, four different paths of @ particle are vem as functions of time, In these functions, «and Bare positive constants of appropriate dimensions and a # B In 2 on the particle is either zero oF conservative, In Lisl, i each ease, the force acts physical quantities of t rationed fis the linear momentum, L is the angular momentum about the origin, Kis the kinetic U is the potential energy and E is the total each path in List-T with those quantities in List-I1, which fare conserved for that path, usta Q. FH =acosit F Bsineat 5 RH(= coset i+sinot jy K Feat i+ (A) P> 1,2, (BH) P4123, © P23, D) P1,2,disha 8 ,2) [all other pi de df ke athe ‘We know that, [Fl= = 2) AO). gr Also. ‘ameter remaining constant] a ar 2 | Further iit i th an acceleration ‘a 5 then g eases, ‘olential energy, \ 1/2.given oe Potential energy, Vi = KrI2gi Also his not proportional to'0! but he cos 0 For r=, F=kR Here Ly y= 1, let Also F (circular motion) m2 R Angular momentum & Given P= tie j ai dis at ati aj “R 8, e Thisisthetime when | ismaximum > re ci] Y[ M202) Ao 7 Further Ix =) -e a vf - (17,19) ‘nae B93 ere F(t jie Big a Ira k aR 4) IF J, = fy then themagneli elds due to / and = i(0-0)- f0-0) +4{ 7-7) 1, a origin “O" will cancel oul each other. But the magnetic field at ‘O° dueto the circular loop will be 11g present, Therefore’A\ iscorrrt IF > Oand fy «0, then the magnetic field due 10 lil=3 Nm both current willbe in + Zdirection andl add-up. The 20s magnetic field due tocurrent|will be in - Zdirection and if its magnitude Is equal to the combined magnitudes of f, and i, then can be ero at the origin. Therefore option 'B iscorrect ‘We know that A= i increases, h decreasesEa IA Boyt ey me it vav= tat me _ , The object distance d f Va eb ie. Vat final result is (0) 2s Ms proprton to, ancncant propel (A.c)Ne.ateparlcese 222, 2g J onset lead He 2p BuIA S0Tse net eae 3x 839+ 30=5%50.7+5¢ Also Fl Bale 83940 88.9 +3e=5%50 20-18 = 0-09cn 3. (A.B) Ansording to Gauss’ Lay 1 far B oso1s09-516 22-6540 Blectictx, ¢= > gy= > thx 2 Reino") = 0 bad Also'V = vi. = 500 x 0.664 ms"! = 33: Further electri field is perpendicular to the wire therefore 7 (6.30) Impulse = Change in linear momentum Itsz-compenent wil sod i, 5 ms J= ty OF Vp= S=5q = 25m Alo V=yyet + Sayer = ds= yet dt s= peta = yell e1) =25% 4x 063-630 4D) Theimage of AB will be A'B'as.AB lies bate and focus, Further as the object is moved towards th ‘he Image also moves away,2 ia K.E jg = (240mg) = 120 mg 200 wr 625x1.6x10 9 Ya? or 2 Fm? = 120mg 2409 Force = Rate of change of linear momentum = N\/2/mk iy 2 240g 200 Pin? o 4 - « Jonata rs } 30m gator © VPI 10 x1.6x1077 x50 39 ag 30m 8 25x1 6x10 [eo K=eVie=1.6 «10-19 = V= 500) 9 (2.00) Given E = sin 1081 7 24.00 Feta 14 (300) AE,, = 74B4 AE, , 1 11 aédt _gsintoo0r? [1-1] ces 1362[ 4-2 aes 8, eanioour} 1362]1-7) and fora dipole = “5 2k. and fer Further for an infinite Long line charge E [cost 0001 1000 gf costo00r) ve =~ FL 1000 |, infinite plane charge E = Vr =| c0s1000 x cos0 10. (656) Weknowthat CO = NBAI, co 10x02 NBA ~ 50x2=10"*x Further for agalvanometer IyxG-(-lps 01x50 50 . 1-01" 9 " Weknow thatal= 2 Weknow that a= “7, 6 @ ve (4% Zt é NW YWoVR OT The third marking of vernier scale will coincide wth te 2h 8 main scale because least counts 01 mm. 7 2. (900.00) eT ey we - a wherey = y Process 2 is isobaric therefore W = P(V, ~ V,) mR -3r) ‘P,Vp-V) = &P 9 css 3 sIs0chore therefore W ~ PV ~ V, ajar @ } 244 Further a =n¢,aT ess 4 is isothermal therefore temperature is constant, Au=0 9003Ea 18. (A) Po» ¥ = Sp = al-+pf which isconstan Further P= mv is constant 1 and K = Smv?is constant 2 (eu, eu Fei SiS j (. 4 Iseonstant) ary?) =) U= constant AlsoE = K+ U E = constant a oor alsin or) 1+ Beo(cos oA) a p i =-w'fecost i+Psin wf] =-0'r Also ¢=PxF=0 (-.Fand F areparallel) au =-[Pa= + fmotra Alsor = fa'cos of sin’ of r=! 13 As the force i nergy remains constant. nial therefore total al-osinoti+ coseat €., spead is constar © sattcoset ; a= % --ao?leose! + sine] po PxFoo Forces central in nature Uand K are also constant a -mjp)ai-+pipar . =O" AU= -[ Fa = ~mfBj-Cal-+popar . 7EThis section contains 6 qu ns. Each question has 4 options (A), (B), (©) and (D). ONE or MORE THAN ONE of these four options is (are) correct 1 ne compouncls) which generate(s} N, gas upon thermal clecamposition below 300 °C is (are) (A) NH.NO, ©) (NH, © Batty. ©) Maj carbonyl compounds is (are) Atomic numbers Fe (A) Talal number of valence st Metal-carbon bond srengthens when the oxidation state of he metals fowexed (D) The carbonyl C-O bond weak slat of the mela snr eas Based onthe compounds of group 15 elements, the correct. ements) is (are) (A) 1,0, is more bosicthan N,O, NE, ismore covalent nan Bi (© Peels at ewer temperature than NH, (©) TheNAN single bond is stronger than the P-P single bond en the oxidation. Inthe following reaction sequence, the correct siructure(s) of X is (are) 1 (8) Meg ; oll A) oO M Yon Mi wn he reaction (s) leading to the formation of 1,3 Strimathylben zane is (ar PAPER-1 HL 6. reversible eyclic process for an Ideal gas is shown below. Here, P. and T are pressure, volume and temperature, respectively, The thermodynamic parameters q, w, Hand U are heat, work, enthalpyand internal energy. respectively. APLVi.T) CPT: B (PVT) The correct option(s) I (are) (A) dac= AUge and ia = P3V,-V,) (B) Wige =P,AVg—W)) ar Gag = AH (OAM ¢ AU, aNd ge = AU () ge = AHge and AH py, > AUsa, is seetion contains 8 questions. The an: a NUMERICAL VALUE, to @ach question 7. Among the species cilamagnetic species i. H atom, NO, monomer, ©,” (superoxide), dimeric sulphur in vapour phase, Mn,0,, (NH,),{FeCH, (NH,)(NICI,] K MnO, K,Cr0, 8, Theammonia prepared by reating ammonium sulphate with calcium hydroxide is completely usedbby NICL, GH,O to form @ stable coordination compound, Assume that both the ven below, the total number ofEa reaclions are 100% complete sulphateand 952 gf NICI,6H,0 are used in theppreparation the combined weight (in grams) of gypsum and the nickel ammonia coordination compound thus produced 11584 g of ammonium is. (Atomic weights in g mol; H=1,N=14,0=16,$=32, (C1=35.5, Ca= 40, Ni=59) 9. Consider an jonic solid MX with NaC! structure, Construct anew structure (Z) whose unit cell is constructed from the Lnit cell of MX following the sequential instructions given below. Neglect the charge balance (Remove all the anions (X) except the central one (i) Replace all the face centerad cations (M1) by anions (X) (ii) Remove al the corner cations (M) (hy) Replace the central anion () with cation (M) The valueot | ube of ction J” 2 1S__. 10. For the electrochemical cell Mg(s) | Mg? (ag, 7 M4} Cu fag, 1M) | Cuts) the standard emf of the cell is 2.70 V at 300 K. When the soncentration of Mg?* is changed to xM, the cell potential anges o 2.67 V al 300 K. The value of xi = b oH © ©) CD b PARAGRAPH “A: ‘An organic acid P (C, H.,0,) can easily be oxidized toa dibasic, acid whieh reacts with ethylane glycol to produce a polymer dacron. Upon ozonalysis, P gives an aliphatic ketone as one of the products. P undergoes the following reaction sequences to furnish R via Q. The compound reactions to produce S. There are Iwo questions based en PARAGRAPH “A*, the question wis one of thers) yHPac 2)NHt ) HPA 3. BesMaOH 2) S0Cl, {HCL KOH,A 3) MeMabr, CaCl, 5) Hy Pac 4) Nab This section contains 6 qu question has 4 options (A), (8), (©) and (0). ONE or MORE THAN ONE of these four options Is (are) correct 1. The correct option(s) regarding the complex [Co(en}(NFH,)(H,0)]® (en = H,NCH,CH,NH,}is (are) (A) Ithas tuo geometrical isomers (@)_Itusll have three geometrical isomers bidentate “en is replaced by two cyanide ligands tis paramagnetic I absorbs light al longer wav [Cofen)(NH) 2. The correct option(s) to distinguish nitrate salts of Min? o gh as compared to and Cu” taken separately s (are) (A). Mn? showsthe characteristic green colour in the lame test (B) Only Cu shows the formation of precipitate by passing H,Sin acidic meaium (© Only Nin? shows the formation of precipitate by passing H,Sin faintly basic medium 18 16 ‘The compound Ris ‘COH (A) ‘The compound $ Is ) ® Nt mt H oO Fy WN S (©) Cu2+/Cu has higher reduction potential than Nan®-IMvin (measured under similar conditions) Anilinereacts with mixecacid (ome. HNO, end conc. H,S0,) al 288 K to give P (51 96),C (47%) and R (2%). The rnajar product(s) of the following reaction sequence is (are) 1,0 pyran ysartc R28 a: ‘nano, scir2 5)E1OH, A be pr Br Aer . wf ~’ 8 C 1] Boe oer br Br . Br C 5 o [9 BNA Br osEa 4. The Fischer presentation of D-glucose is given below 10 OH OH Hi H,0H cose The correct structure(s) of f-L-glucopyranse Is (are) 4 Hoy GH ® Ne HOA ® bu A Chor ih \0H i © HO\oHHO/ © hoa For a first order at constant volume.and 300 K, the total pressure a the beginning (t= 0) and at time tare P, and P,, respectively. Initially, only. is. present with concentration [A], and t,. isthe timerequired for the partial pressure of Ato reach 1/3'%of ls inilial value “The correct option(s) is (are) (Assume that al these gases gases) , eo oN o > UHH Tin [ak 6. For areaction, A — P, the plots of [A] and [P] with time at temperatures T, and T, are given below. This section contains 8 questions. The answer to cach questi isaNUMERICAL VALUE 7 The fatal number of compounds having at least one bridging oxo group among the mol is_____N,0,, NOs, P,O,. P.O, H,S,0,,H,S,0, 8 Galena (an ote) is partially oxidized by passing air through ital high temperature. Aer some time, the passage ofa cules given below HP... H,P.O, 9, HQ ( 7 stopped, but the healing is continued in a closed furnae such that the contents undergo-seif-reduction. The weight (inkg) of Posproducad par kgof O, consumed is, (Atomic weignts in g mol”: C 2, Pb= 207) To measure the quantity of MnCl, dissolved in an aqueous solution, itwas completely converted to KMNO, using the reaction, Ma, + K,S,0, H,0-> KMnO, + H,S0, + HCI (equation not balanced) Jrops of concentrated HC! were added to this solution and gently warmed. Furthe oxalic acid (225 mg) wasadded in portions till the colour of the permanganate ion disappeared. The quantity of MnC|, {in mg) present in the initia! solution is__ (Atornic weights in gmor-!: Ma 5.5) For the given compaund X, the total number of optically ve slereo isomers is = This type of bord indicates thal the configuration atthe specific carbon andthe AL geometry of the deuble be t = Thisty indicates al the configuration a the specific carbon andthe geometry x ofthe double bond is NOT fixed 1g reaction sequence, the amount af D (i from 10 moles of acetophenone is 1,C=12,N=14,0=16, corresponding to the product in each (Atomic Br = 80, The yield (36 ghts ing mol: H step is given in the parenthesis) 20 Ca 8 430" (60%) Bikon Bile The surface of copper gets tarnished by the formation of copper oxide. N, gas was passed to prevent the formation during heating of copper at 1250 K. However, the N, ges contains 1 mole % of water vapour as impurity. The waler vapour oxidises copper as pert jon given below: 2Cu(s) + H,0(@) >Cu,013) + H,(@) Pj, isthe minimum partial pressure of H, (Inbar) needed to prevent the oxidation at 1250 K, The value of Info.) is (Given: total pressure 8JK-'mol immiscible ALI250K 2 Cu(s) + 40,.) R (unive UG) and al gas canstan!) 0 semutualiy »Cu,0(), AG* =-78,000J mol ~1,78,000) mol” (Gisthe Gibbs energy) HQ) + ¥20,{9) + H,0%9): acEra 13, Consider the following reversible reaction, A(@) + B(@)-2AB(O) ‘The activation energy ofthe backward reaction excoeds that ofthe forward reaction by 2RT (in J mol!) If the pre-exponential factor ofa forward reaction is times that of the reverse reaction, the absolute walue of AG {in J mor" forthe reaction t 300K is, (Given: In(2) = 0.7, RT = 2500 J mol" at 300 K and Gis the ibs energy) 18, Consider an electrochemical cel AGS) | A" (aq, 2M) |B aq, 1M) | B(S) Taevalueot AFF ferthe call reaction is icethat of AG" at 300K. Iftheernfof the ellis zero, the AS® (in JK"? mo!) ofthe cell reaction per mole af B formed at 300 K is, (Given: In(2) = 0.7, R (universal gas constant) = 8.3) K-! mol H, S and G are enthalpy, entropy and Gibbs energy, respectively) \ IFT, > T the correct statements) are) (Assume AH and AS" ae independent of temperature and th Fatioof Ink at T, tolnk at T, is greater than. Here H S,G and K are enthalpy, entropy, Giobs energy and equilibrium constant, respectively) (A) AHP <0, a8"<0. (8) AG" <0,aH' >0 (© aGr<9.as0 ace Thissection contains 6 questions of MATCHING TYPE, contains ‘wo tables each having 3 columns and 4 rows. Based on each table, there are three questions. Each question has four options (A), (8), (©) and (0) ONLY ONE of these four option iscorrect. 15. Match each sel of hybrid orbitals from LIST1 with complex(es) given in LIST-II ist-| List I Po dsp 1. [FeF,J a 2. [Ti(h,o),C1 R pe 3. (Cr(NH), 8. Psp 4. [FeChy 5. NCO}, 6. [NI(CN)F The correc! option is (A) P504,6:82,35 © P5.6:0-4R-3 541.2 © PHO4,5:/R152.3 ©) P-4,6:0-5,6:R-1,2:53 16. 18 The desired product X can be prepared by reacting the ‘major product ofthe reactions in LIST-1 with one or more appropriate reagents in LIST-II. (given, order of migratory aptitude: ary! > alkyl > hyn 9 Pho 7 OH Ms Ph x List <1 List: Ph HOS! Me Pp Ton + H80, 1 OH Me nn No Oe OH HNO, 2 IAQINHYJOH Me oh nol ph Rw [0H +H,S0, 3. Fehling olution Me Ph ely 5. Ph” Jon +AgNO, 4. HCHO. NaOH 5. nab The corret option is (A) P41) 0-2,3:/R-1,4;5-3,4 @B) P4503, 4:R4, 5:53 P-1, 5; 0-3, 4: R-5; $-2,4 © P-1.5:02,3:R4,5'523 LISTeI contains reactions and LIST. contains major products Lis i Po Aona* Per > Pome! > Roky, +NaoMe > | 7 S. shona® MeB > Match the reaction in LIST-I with one or more products in LIST-Il and choose the correct option, (A) PA,5:O-2: R-3Sed (8) PA, @02:R-45-3 ( P1,4.01,2:R3,454 (D) P45 Q4:R4 S34ia ‘8 of, aregiven in LIST-I, The effects of dilution of the solutions on [H" 18. Dilution processes of itferent aqueous solutions, with wa are given in LIST (Note: Degree of dis concentration of Hons) LIST usta P. (10 mL of 0.1 MNaQH + 20 mL of0.1 Macetic: value of (H*] does not change on dilution diluted to 60. mL QO. (20mLof 0.1 MNaQH + 20 mL of 0.1 Macetic: diluted to 80mm R(20mLof 0 MHCI + 20m of0.1 Mammonia solution) 3. the value of [Ht] changes ta two tims ofits intial diluted to 80m value on dilution acid and weak base is < gree of hydrolysis af salt <<1; [H"] represents the tion (a) of id) 2. thevalue of [Ht] changes tohalfofitsinitial valueon dilution 1 S10 mL saturated solution of N(OH), in equilorium 4 the value of [Ht] changes tom times ofits intial value with excess solid Ni(OH),isiluted to 20 mL on dilution Golid Ni(OH, is till present ator citution) 5. the valuecof (H"} changes to J3 times ofits initial valueon dilution Match each process given in LIST-I with oneor more effect(s) in LIST-II. The correct option is A) P40.2:R3S4 B) PA 03:R253 © P1:04:R5:8-3 ©) P4O5;R4:/S1disha 20 (A) NHNOy —rapgsPNLO 4 2H,0 NO ee >No +Op ® (ited, 04 +4H1,0 (© Ba(Ny)2 —9>Ba+3Ny ©) MaNp oreo N Hence only (NH,),Cr0, and Ba(N. gas on heating below 300°C an provide N, (A) [(Fo(CO,)] & [NK{CO),] comple thelr valence shel Due to strong ligand fleld, carbonyl complexes are predominantly low spin complexes. (© Aselectron density increases on metals (ith lowering oxidation state on metals), the exlent of synergic bonding increases. Hence M-Cbondstrength increases (2) White positive charge-on metals increases and the ex: tent of synergic bond decreases and hence C-O bord becomes stronger. shave 18-olectronsin, (A) Besic character of oxides increase on moving down the ‘oup therefore BI,O, is morebbasic than NO, Covalent nature depends on électronegatlvity ditferoncebotween tonded atoms. In NF, Nand F are nnan-melalsbut in BIF,, Bis metal hile Fis nan metal therefore NF, isrmore covalent than BIF, In PH, hydrogen bonding Is absent but in NH, hyirogen bonding is present, therefore PH, boils at lower lemperature than NIH, (©) Due to small size in N-N single bond Ip. ~ Ip repulsion ismmoce than P-P singlebond therefore N-NI single bond is weaker than the P-P single bond. saya — Me ao “ Me ‘00H aes COL Hoo a cho © Zoi one “CHO ¢Clemmen A~C = isochorie process A-B isothermal B-C = Isobar dae = AU pe hae Ci isesg Aaroh (0.204 2NHy NiGly,6H0+6NHs ->[Ni(NH3}4 ]Cl2+6H20 s62g-4mole mole (MA=252) ‘nie » Total mass = 12% 172 + 4 232 = 2992g (3) Asper given information, catians form fer lattice and anions occupy all the octahedral voids 0 MX ‘ormula WX ions 4 ons After step | ions 1 ion After step tl Tin 4 fons. Atterstep III ion — 4 fons, AftersteptV tion 3 lons so ratio of NO anions _ 8 No.of cations (0) Mg(s)—>Mg?* (aq) +26 13. Cu? (aq) +22” —>Cu6s) Mg(s) + Cu" (aq) —»Mg”* (aq) + Cu(s) an Fos = Caan Linx aF €= 2067-27-81, oF 003-0 —inx Bar 1500 23 ine x=10 (222) Py=Star P= bar VjrimV,=3mé T,=400K —T,=300K “aR "2" 300R bei VeG-0) ny, xR my, xR “My Me 300R (3= x) ante vet 1 (®) 9» atexets g =|] -222 (19) Py=0'9X a PeXe 45-2005) + pi 8) Pb =70 225 =20X,q + 70( 50x 4-475 Voxio® =447<10°MEra 4. From graph Far salvent "XAT yy.=362~260=2 ATugg = Myer * Ki Farsolvent'Y' AT yy,= 368-367 AT oy = Mncr® Keg Diviaiing equation (1) by (2) Given solute $ dimerizesin solvent. Hence 28) 9S, (a a? CHO np ‘AcONa Lo Br Comcn he Ore 16.) ‘acon 2 (1-72) Toons =[1- 22 | Ropes Myx) = ‘ Given ATy 93 = 37a) H “OONa COOHia rs 7 AB 6) Sol. 17 & 18 CrHi02 01, Paper -2 nas 2 geomelrical isomers _ Nt ‘ LS) Le UT Nou, al Ann, ull have three geometrical Isomers Hof HS, HAART ZEN] [Ha 760 wn7T New| | ne“ Pwd NH. NH.{en)(NH,),(H,O))" Is diamagne (©) [Cofen)(NH.),]* has larger gap between e, and, than en){NH4),( HON} So [Cafen)(NH.),(+,0) at longer wavelength as compared to [Co(en)(NH.),]** 2 (B.D) (A) Cu* shows characteristic green colour in the flame test whereas Mn? shows the pale colour in flame (8) Only Cu can give black precipitate of CuS in acidic medium on passing H,S. (©) Both Cu and Mn®* show the formation of precipitate by passing H.§ In faintly basic r D) Eeyericy (+ OS4VN> Ef, 24 yy, & 1-18) as par electrochemical series. wi NH ro No, a) are. N03, a or “~ No, oO J inn ox 24 absorbs lightEa 4, O) Structure of B-L-glucopyranose is Aig) Fite, 9A4(q) Clg) V =constant,T =300K <0 P, te thy (Po tet Py-x 2x x So, Pr=P=-x12x1x=Py0 x or or ett 2 kt in 2Fy ~InGGPy-) 3P-P ° of ln(aP,-P.)=—kt + In 29, Graph between In(3P,— P) vs ‘tis a straight line with negative slope ii Sinc2rale constant is a constant quantity and independent H,8,0)-HO— ir OH of inital concentration 0 Sograph (A) and (D) are correct raph (A) and (D) a oe & Ao t H,S,0, = HO—$—S—OH On increasing temperature, concentration of product é i eases ° action isexothermic > AH"<0 B (647) Ink. > IE Inky, = INK, 50, Ky, > Ky PUS + ,—> Pb+ SO, ink, 2 10 No, of moles of ©, = Inky, Als bh 2 inky, 7) ; ocmesi. 12 or Tinks, > Tylney, 2 -RTyInky, >-RTpInKy Moles of formad = “7 AG), DEMnO, + AK,SO, + 6H,SO, + AHCI ..(1) 2KNINO, + 5H,C;0, +3H,S0,—> K,SO,+ 2MNnSO, + 8H,0 +10CO, (2) Massof ox: of oxal 30 ton (2) Milimoles of KIinO,, used to act with oxalic acid = 1 (mmole H,C,0, = 2m moleor Kn) and milimoles of Nn, required initially ‘Mass of MnCl, required intially = 1 x 126= 126mg (Molar mass of MnCl, = 126) o (695) Molesof D formed = 100.6 «0.5 «05x 1=15 Mass of D formed = 15 « 330= 495 q (146) (9 2Cu(s)+405(q—+Cu,0(9 :AG" = -78 ksimol 1“ {id Ha4Q)+502(@—1,0(9), AG” = 178 kafmol (i) Gi) then, 2Cu(6)-+H0 (J —+Cu,0 9) + Hy(9) =-78+178= 100 Kulm = 10° smo for the aboue reaction (Py AG= AG’ + RTin} hia | To pravent the abave reaction: AG20 G+ RTIn “e "Rive R 250In| Fy 10 +8 «1 (InP, ~InPy Ph, Now, THIN sc) Oot Puzo = Xi,0 * Prt =10~2In10 5-10-2623 (Given Ind =2.3) InP, 210-46 InPy, 2-146 Minimum InP, 14.6 2% Eq = Eg ART & AAA, Now. Rate consiant of forward reaction ky = Ape™Fa"!® Rate constant of reverse reaction Ky ~ Aye"Fas!®™ Equiliorium constant Kt Mtg tha Baile Ky Ap K TIRT _ ga 2500 n (42 -25004(n 4+ ne?) 2500 (1.42) 003.4 =-850 io (1.62) AG) [AP (@q, 24) |B (aq, 1M) |B 3) Reactions AA" 00°) 2 B24 2ne 9B action 20462" 328" 2B e-e- Sling 2 oe RT) AE an” Ip? con yp? FT pe=Bhing 2a Now AG*~-2nF nd ~-RTIng AG® = AH? ~ TAS* = 24G*~TAS* (Given AH? = 2AG") Tas" =AG* ase SG RTM ping = 8.3 2% 07 =-11,62JK" mor° @ © P-60 4.5:R 2.3 oF >, Fe’ = cf & F> Isweak field ligand Hybridization is spo (high spin complex) (Ti(H,O},Cl,], TH? = 3a (No effect of ligand field strength) Hybridization is as 3 [Cr(NH),F*. Cr = 36° (No effect ofligand field strength) Hybridization is osp* 4 (FeCl |, oP & Ch Is weak tel ligand Hybridization isso! 5 Ni (CO), Ni=3e°8.CO Is strong eld ligand Hybridization isso 6 [NI(CN) I>, Ni = 30° & CN is strong field ligand Hybridization is ag? © 0 5 POF cH Ph ‘OH Hy © OH " PR NH. hy » wn Hy ‘OH HC Ph OH Ph Ph ch < uso, PME mn ul xX 104, OH me OH Q 27 Nagar, p nin, py Ph ‘ag(nni) 0H Oi “oH(8) P=1,4;0-2R-4:5, CH, 28 rh Hy ff _tagtuyton ff Leann pp k m \ Lon Me —9, He — x “MeOH CH Me He br (©) P-1.0-5: R-4:5. ° NaOH + CH,COGH—>CH,COONa+H,0- mmole 10x01 2001 Immo =2mmoi Solution contains 1m, mol CH,COOH & 1 m.mob CH,COONa in 30mL solution, Itisa Buffer solution. Hence pH does not change with aitution @ NaOH + CH.COGH—>CH,COONe + H,0- mmole 20x01 20x01 Feng souion a Son Solution contains 2 m. mol of CH,COONA in 40 mL. solution (salt of weak acid and strong base) For salts of weak acid and strong base Kuk [Ha = * COndilution uploao mL, newconc. willbe iKyKa ciaEa ® Hel NH, — > NH,CI mmole 200.1 2001 =2mmol—=2mmol Solution contains 2m. mol of NH,CI in 4D.mL solution: (salt of strong acid and weak base) or salts of strong acid and weak base Ik Onallution upio80mL, new cone. will be= 29 [KC heii TH Tpoa™ Ky? a (S)_ Ni(OH),{s) — Ni +204 it is sparingly soluble salt On dilution [OH] cone. in saturates! solution of Ni(OH), remains consta [Hye = CH7)PAPER-1 This section contains 6 questions. Each question has four options (A). (B), (C)and (0), ONE or MORE THAN ONE of these four options is (are) correct For a non-zero complex number z, let arg(z) denote the principal arg iment with —1 and g:l8»R be two non-constan differentiable functions. I Pa) = (2-9) g(x) forall xe R hen which of the following f(2)>1=log.2 ©) gil) <1-log.2Ea 6. Let: 0,20)» be a continuous function such that, fadeto aes [Te nna for all e[0,:0) . Then, which of the following staternent (3) is (are) TRUE? (A) Thecurve y= (x) passes through the point (1, 2) (8) Thecurve y= F(2) passes through the point (2, -1) (© Thearea of theregion fone lOtxR: ays yew? (0) Thearea of theregion {@melOMeR: (as ysvI- 0 | Is Soa This section contains B questions. The answer to each question isa NUMERICAL VALUE. For each question, enterthe correct numerical value (in decimal notation, truncated/rounded-off to €(.625,7.00,-0.33,~ 30, 30.27,~127 30) secondidecimal pl 7. The value of ((log 9)7)!99210929) 5 (/7)!847 is 8 Trenumber of 5 digit numbers which are divisible by ,valth cigits rom the set {1, 2,3, 4.5) andlthe repetition of agit is allowed, is Let X be the sat consisting of the frst 2018 terms of the arithmetic progression 1, 6,11... and Y bethe et consisting of the first 2018 terms of thearithmetie progression 9, 16, 23 ‘Then, the number of elements inthe set XUY is 10. The number of real solutions ofthe: quation sint| oe" (4 ® cos $f 4 Se) 1 Iying nthe interval ( iagintheinaval{—!.} i (Here, the Inverse trigonometlc functions sine and cos-lxassume values in| — | and (0, x}. respectively) | -E.5 | end. 2 respectively This sa 31 For each positive integer 0 let 1, 2.4 y= avy 2).daer For xcIR lel [2] be the greatest intager less than or equal toc IF Lim y= C, then the value of [4) Is Let 4 and 5 be two unit vectors such that 3-6 =0. For some x yeTR, let C= 20+ yb-+(a8) Pe 2 and he vector ¢ i inclined al the same angle « tooth aand B, then the value of 8 cas? «is Let 3, 8 ¢ be three non-zero real numbers such that the sfac0s «+ 2bsin x= 6 xe =. Then, the value al roots wand with a+ ‘farmer F, hasa land in the shape ofa triangle with vertices alP(0,0), 01, 1) and R 0). From this land, aneighbouring farmer Flakes ay theregion which lis bebween the side PQ anda curveofthefarm y= x? (n>). Ifthearea ofthe region taken away by the farmer ; Is exactly 30% of the area of APOR, then the value of is = 5 tion contains 2 paragraphs, Ba ed on each paragraph, thereare 2 questions. Each question has four options (A), (B), (C) and (D} ONLY ONE of these four options is carrect lu PARAGRAPH She the circle in the xy-plane defined by the equation wpe 4. Lot E,E,and FF, be the chords of $ passing through the point Pj(1, 1) and parallel to the xaxis and the axis, respectively. Let G,G, be the chord af 5 passing through ,and having slope -1. Let the tangents to Sat € and & mel at E,, the tangents to Sat F, and meet al F, and the tangents to Sat G, and G; meet at he points E,, Fy and G, lie on the curve (A ye4 BH 44? 16 © -ay-ay=a O ysEra 16. Let Pbea point (eS with both coordinatesbeing 17. positive, Let the tangent to $ at P intersect the coordinate axesat the points Mand N. Then, the mid-point ofthe line the ci segment NIN must lie onthe cun A) (ty? =3y we Pay © #1¥ D) r+y-¥r/ RAGRAPH -A, There are five students Sy, S, for them the 5, and S, im a music class and are five seals R,, R,, Ry, Ry and Re arranged in a row, where initially the seat R,isallotted tothe student 5, /= 1,2, 5, 4,5, Bul, on the examination day the five students arerandamly he five seats 32 The probability tha (on examination day, the student S, gets the previously alloted seat R,, and NONE of the remaining students gets the seat previcusy alloted to him! heris ® a 7 © wo For /=1, 2,3,4, et T,denote the event that the students 5, and S,, , do NOT sit adjacent to each other an the day of the examination, Then, the probability of the eventEa Eero 33 PAPER - 2 This section contains 6 questions. Each question has four options (),(6) pions is (ae) con and (0). ONE or MORE THAN ONE of these four a For anypasitve integer define f,: (0, «) > 0 =h5 xe (0.2) (Here, the inverse rigonometricfunction tan" xassumes| | valuesin{ Thon. which ofthe following statements) is (ore) TRUE? w >} tan? (f(0)) = 55 (1+ F (0) sec? (440)) = 10 ae asitive integer m, lim tan (f(a) = 2 (© Foranyrix x (©) Foranytixed postiveinteger m, tim s0c2(%, (2) =1 Let Te the line passing through the points Pf=2, 7) and 2,5). Let F, be theset ofall pairsof circles (5, 8) such that 7's tangent to S; at Pand tangent to S, at O, and also such that S, and 5, touch each other ata point, say, ML Let E, bette set representing the locus of Mas the pair (S,. 5) vatiesin F, Lelthe el ofall straight ine segments joining apalr of distinct points of &, and passing through the poin (1,1) be &,, Let E, be the set ofthe mic points ofthe line segments in the sét F.. Then, which of the following statement(s is (are) TRUE? (A) Thepoint (-2, 7) les in &, 8 The point lies in E hy (©) Thepoint (0.2) does nor 2 Let Spe the set of al column matrices | b | such that b, La] »,, by, € land the system of equations (in real variables) w-2y+ 22 by has at least one solution. Then, which of the Following syster(5 (in real variables) has (have) at Least one solution (A) xe dys dz by, ay 52= b, and x4 2y+62= Dy xe ya 32= by, Se+2y+62= band -2x- y-32= by (1 2y-B2= by, 2x dy 10z= by and x- 2y+ 5 z= by (xs 2y+82=b), 24+ 3z= A and x+ dy-Bz- 6; Consider hy Is tangent to stralc Hines, each of wh both the circle a? + these lines intersect at the point Q. Consider the ellipse ise center sat theo igin O(0, 0) and whose semi-major axis is 2. Ifthe length of the minor axis ofthis ellipse is ~ and the parabola y? = 4% Let V2, thenwhich ofthe following talement(s) is fare) TRUE? (A) For the ellipse, the eccentricity is and the length of the lalus rectum is 1 (©) For the ellipse, the eccentricity is 1 and the length of z 1 the latusrectumis 1 (©) The area of the region bound: bythe ellipse between 1 thelines x= Land x= 1is and x= Tis 1 6 Let s, be non-zero complex numbers and be the set solutions 2= 24 iy (x,y. €R, f= A) ofthe equation s+ 17 + 7=0, where 7 = x~ i Then, which following statement(s) Is (are) TRUE? (A) If has exactly one element, then |3 [4 ©) If |g =|4,then £ hasinfinitely manyelements (©) The number of elements in Lin {z:[2-1 + f= 5}is at most 2 of the (©) If Las more than one element. then L has infinitely many elementsEra 6 Leth. fupsint~ F()sin x bea twice differentiable function such that lim sin? xfor all £ (0,2). iF (=) = then unin oft fallowing ttre is er) TRUE? w fF) W cy ry 2 forall x= (0.2) (©) Thore exists « & (0s) such that (a= This section contains 8 questions, The answer to each question IsaNUMERICAL VALUE. Furcach question eter the cor numerical value (in decimal notation, truncated/rounded-off to the scanddecimal place: eg. 6.28, 7.00,-0.33,~ 30, 3022,—127.30) 7 The value of tre integral iy 8 (G07) 8. Let Pea matrix oforder 3 3 such that all the entries in P are from the set {-1, 0, 1). Then, the maximum possible value of the determinant of Pis Let Xbea sat with exaclly 5 h exaclly 7 elements, Ifcis the number of one-one functions from to ¥and B isthe number of onto functions from Yto nents and Vbe a set X-then thevalue af 25 (B ~ a) is 10, Let (: RR bea differentiable function with /(0} 0. Y= (satisfies the differential equation Y os syesy-2) FZ -2ssney-a then the value of lim FU is 11. Let R-+ bea differentiable function with F(0) satisfying the equation Foxe W= Af D+ (0) AU forall x yeR hen, the value of log, (F(4) is 12, Let Pea point in the first acta Vand hse ira plane x+ y=3 (that i, the line segment QI perpendicular lo the plane x + y= 3 and the mid-point of PQ lies in the plane x4 y= 3) lies on the axis. Let the distance of Ptrom the svaxisibe 5. IF's the image of Pin the xyplane, then the length of PRs. 13 34 Consider the cube in the first octant with sides OP, OQand OR of length 1, along the axis, yaxis and z-axis, respectively where O(0,0,0) is theorigin be the centre of the cube and Tbe the vertex of the cube opposite to the origin Qsuch that Stieson the diagonal OT. If p= SP, 7 SR and = ST, then the valve of [Kp a) x (PT) Is Let Xa COE + 09G)? + BCP? 4 + 100% Cg where 99C, re {1, 2,--, 10) denote binomial cootficionts Then, the value ot x is 1130 Eero eins This section contains 4 questions, Ear ists: LIST-L an question has 2 matching LIST- 11. Four options are given representing matching of elementsfrom LIST-land LIST- II. Gnlyone of these four optic 15, matching = [rer Let E, = {xe sin wea,(5) ‘sa real number (Hore, the inverse triganometri ncton sin~ assunssvatasin| 72) Let f: £; + R be the function defined by £40) =1og,{ 2) and g: be the function dened by 900 = sin" og { LIST. The rangeof fis The range of gcontains Thedomain of Fcontains Thedomain of gis16. v Re option is Pod O42 Rot Sot P43 Q+3 R96 So5 Pod O+2 Rot Soe Pod O53 Rob S55 Ina high school commit has tobe formed from 2 group of 6 boys M,, My, M,, My, Me, M, and 8 giels G,, G, Gy (Let a be the total number of ways in which the committee can be formed such that the committas has Smembers, having exactly 3 boys and 2 gis (Let a be the total number af we commie can be formed such that the committas has at leest 2 members, and having an equal number of boys and girls Let a, be the total number of ways in which the committe can be formed such that the committee has Smemibers, atleast 2 of hem being girls ys In which the a () Let a4 be the total number commie can be formed such that the committes has 4 members, having atleast 2 girls and such that both M, and G, are NOT in the commie together. List-1 LIST-I1 Thevalueot a, Is 1. 1% The value of as 2 The value of as 31 he value of as 2 5. Jr 6461 he-correct option is: Q) P94 O96 R52: S31 @ Pot +4 Roz 593 @Q P34 O56 R95 So? () P+4 Q+2 R>3; S> tet 1% 4 1, were» b> 0, beahypestotain the -xyplane whose conjugate axis LMsublendsan angleof 60° al one of its vertices AM. Let the area of the iriangle £.A¢Vbe a3. Lust. u re length of theconjugateaxisof His 1. 8 he eccentricity of His a4 aa The di botween the faci of His a he length of the latus rectum of fis a4 naAA and f, RR be functions O 4 W=sin [sin] fisdiscontinuous at f= 0 © anf )onatae = Pim sang 4 —arg 4 —arg 4 +99 72 = 2m, multiple of 2x (©)istrue o » alQ- a) ker (2- aaa) > > 2,2, 2, Z,areconcyclic. ez lies on acre (D)is false 2 @,C,D) 2 2 £ Pa? = OR? — PR’ roy (A) 00830°= S55 gg _, M3 _ (ov3}? +10? PR? 2" aeiov3x10 > PR? = 100 or PR=10 2? =£0=30" {A) is false ) Area of POR= 1 POXARxsin3O 1 1 = 1 x10V3 x10x 4 = a5! 3 *1ON3 x10 5 = 25¥3 Also 2 R= 180" 20° (B)istrue. rhe NE 288 5 MOSM) WHYS 2449 C2 3Q2— ov3-15, (isirve abe _10V% 1010 R 0 5 4A Ax 25y Areaofcircumcircle= 2R? = 100% )istrue co (A). Direction ratios of line of intersection of two planes wil be given by 7x F 1 1201 dr’ of ine of intersection of P, and P, are 1, =1, 1 2: (A) is false ©) Given tine can be written as 4 3. 3 Glearly this line is parallel to lineof intersection of P, and P, isfatse IPOs th between P, and P, then o_ (2xtete2e Met) 31 . Yove 62 0-0 Hence (C) is true (©) Equation of plane P 1Wr-4)- 1-2) #12 +2)=0 o x-yi ze Distancaof (21,1) from P, (piste.Ea 4 (ABD) (A) f(x) being twice differentiable it is continuous but can’t be constant throughout the domain, pcan find xe (r,s) such thal f(8} ison one Hence (A) Is true (8) ByLagrange’s Mean Value theorem for fin [4 0) there exists ee (-4,0) such that Fg) Lt O-4) 4) (fo —F¢-8) > IF) Ife) 1 -F > IFG)I<1 @Bistre. (© IF we consider (x) = sin(B5.) then f (2) satisfies the given condition [F(O? +0F (0) But lim (sin VB5x) does not exist (C)istialse (OD) Letus consider g(x) = [FO]? +1 007? By Lagrange's Mean Value theorem [roo|<1 et for same 4 =(-4,0) ‘Also |f(x))|s2 as 94) 55, for same x <(0.4) ix) has maxima in Cx, 4) Say at esuch that gi(a)-O and gfa)>85 G(@)=0 => 2F(@)E(@)=2F aE" (a) =O = Wa)lt(o) «(ell =0 IF F(a) <0 (0) =F? and (F(a) 24 . g(a) =85 (isnot possible.) Hence f(a) -+F"(a)=0 for a € (K),x5) € 6 (O)stue 5 BO Given #%¢x) =ellld-900) o') 6 37 > F(x) =e gx) Integrating bath sides, we got 40) gy gt e409 01? 46 = of ge0t0 22 a e@e2 and 9 M2 = -f(2)1-In2 and g(t) =1-In2 (2) and (C} are True Bo (=e feta > (x)= 2eve" [etre > FG) = 240 [Fete dt +e%le FOO] 10) = eff 14 ax 4 08) = (0) 21) = 2-3 ts. alinear differential equation [pael 28" = go? fe (2-3) Solution: f(x) xe ® 89 en 3) 3 K FQ) =-x4 54 400” P00) =x 41400 From jfinition of function, f(0) = 1 Tec = ceO f= 1-x Clearly curve y= 1 ~X, does not pass through (1, 2) but it passes through (2, ~ 1)Era (A) s falseand (8) istrue Also the area ofthe region B Texs ys Vix Isshown in the figure, is given by a A Area of quadrant - Area AQAB dame? Later = 2 4 2 4 (©) isttucand (b)isfalse 1 Toa 992) 1921929) ( = (log, 9)! i097 57 = (Jog, 8)980 9 ela? 24x 228 8 (625) Thelast digs, in 5-< be 12, 26,32, 440152 ‘Also each of the first three digits can be any of {1,2,3,4,5} 1 nce 5 options for each of the first three digits and 5 options for last 2-digits Required number of § digit rumbersare 25 ji number divisible by 4, can wen sequences upto 2018 t 6.11.16, 0086 aN 9,16,23, sony 4128 The common terms are msare 16,15, 86, upton terms, where J, > 16+ {n=1)35 < 10086 > 3-19 < 10086 =n0X) +n) =X} 2018 + 2018-288 = 3748 x) fe ) 2 incl) * ioo!| 22 —* 10, @ sin) PO. 2 | asi es ' 2 2 Tox Tex 2a 2x 38 web? 1a) x(x 2x x?) pe OE 20 x(2—3x-x") ° =x M02 29422) 292-379] = ae edd 2x? 8x2] 0 > x= O0r x + 242+ Bx—: Gay) wie eserep() log y,= — >> lag) te oe (nse7"} noe wk log(t + x}ox-=Petog(1+x))} = [' ax Jia Pxtogtt 0], ~ | OTe lag2 —[x -log]1+« fh, (og 21+ log2=2log2-1 = log 4-loge=log | 5 4 4 u-4 stg 1 (3) Given |a|=|6|=1, & makesangle with bath 4 ang B Also, ¢=xa -ybraxb Ed = 2cosa — x= 2c0s0 GB =2cua => y= 2c0s0 e? =€.¢=|(2c0su)8 + (2cosa)i +a>bfda 39 > (@P = Aco? we 4cos? ae ja xb? 3 = beBcostast (+ [deb] = t1xsin90"=1) Bos?u=3 13, (0.5) Given that the equation ve an 3 acasx + sin x has two roots a and, such that e+ B= 2 3 ard Jf acosp +2b3inp =< Equation of Ey itoet tion (0) rom (1) we get Equation of F, F, :x= sarang eqinton (2) om (1) 429 edteedGs Gonvye? 3 a (cos a -cos fi) = 2b (sin «e-sin f) By symmetry, tangents at will meet | -PazsnttBsn Beare on y-axis and tangents al F, and F, will mect “2 a on axis x 8.1) &F, «(Ly = -2V3a sinZ+ ab . 1) &F=(.¥3) Equation of tangent at E, : 3x +y = -Waxte moo Equation of tangentat F, = x+v3y=4 Points €5(0.4) and (4.0) blogs Tangentsat G, and G, arex = 2ani ya 2 intersecting each other at G (2, 2). Clearly E,,F; and lean thecurvex + y=4 “ @ & (©) Let point Pe (2 cos, 2 sin 0) ’ Tangent at P: xeos0 4 ysin 0= 2 Ayan) Mid point of MN = | 5 -Sp P00) Ray For locust mid point (x,y) of MIN, 30 4 shatcdrea = 22 -av(aran) sino Vn = fon Seton a 02 ety) 4 7. (A) No. of doarrangements for 4 students - nat, afl 1, 2) Saar at at = 2447-9 Total no. of arrangements of seating of 5 stu on =5t=120 93 20 40 quired probability:Ea 18 Total cases = 6! =120 Favourable cases 13524] 7 reqquited probabilily = 535 go Paper - 2 cn ) F900 = Stan 1 ABD) Ia = tan Roa i A 3 = fyO=tan = fh) z z Ts (cen? 14x? and f,(0) = tare)». tan2(tan-Tn) = n2 (A) Dian? = Sy? = = 55 i 6 © vd (0) 11+ @=—, se0”(f, (0)) = sec? (tan (n)) = 1+? > WO FO) 40 +E (O))-s0r? (0) =1 Saag onetqm-frew ‘ (©) firm tant, (0) = tim 0 ©) tim see?(F, 00) lim 1+ tan? (F, (8) Oo becOmmon tangent Prada! axis) Here, AP= AQ= AM locus of M isa circle having PQ asits diameter andis given as Ey (-2) 042) + (y- My +5) =Oand x-# 42 and itscantreis{0, 1) Locus of B (midpoint) isa circlehaving RC as its diameter and is given as E,:xQ-1) +-1=0 ‘Now, after checking all the tions, we get (0) isthecorrect option (A.C, D) Here. Q0 for atleast one solution, we have y= y= Ay > by + Thy =13by 0 (@) aro Tike equations have unique solution Option (AA) is correct (Azo The equations have unique solution option (D} is correct ©a-o s equations are x-2y+ $2 =-b, 2 by x-2y+62- 22 x-2y+5z=b3 The planes given in option (c) are paralle! so they must be pincidentEquation (ii) satisfies equation (i) Option (C) is correct 3 1 (@)a-|5 2 6-3 2 2-0 3 1 a4 Also y= 2 2 6)b,=0 1a For infinite solutions, A, and a, mustbe 0 1b 3 5b, 6-0 2b 3 2 + Bp + 3D, = Owhich does not satisfy (i) forall by, by by sooption (B) is incorrect Ac) > m=41 ‘ommon tangents are ye=x Hand y=-x-1 05 (1.0) Equation of ellipse is. 2 and latussectum = 41 (cD) szvizer=0 @ sz+tz+T=0 O} Adding ()) and (i), we get +S)e+(s+D2+(¢ Subtracting (i) from (i) (96De-nN-0 Q Exquation (1) and (2) represent sat of ines. For equation (1) and (2) to have unique solution, we nave: o a e gel is sat ssl Onn solving the above equation we g Ite |s Option (A) is correct For equation (1) and ¢ wehi lo have infinitely many solutions, us and W-Tresr-sr=sresr-Tr-Tr > W-ar > test [Tr -Isi 7] = ItirHsir] = [tes ~ If |t) =|} lines will be parallel for sure but may fent (|. does nat have infinitely many solutions) (C): Locus of 7 isa null set or singleton set or a line, in all the will intersect given circleat most two points, () Inthiscase locus oFZ isa lino soL. has infinto elements, ases IEra 6 C.D) (x)sint-F()sinx tim £02 six asim te0st FQ) sink 2 (Using LHospital’s Rule) = ()e0s -F{x)sIinx = sin? ff°Cx)sinx F(x) 083) _ w= mt Te FO RR 2 a1 42 ® fhe)=-xsinx as sinx> x =xsin there exist 0. <(0, x) for which F{a)-0 (0) Here, F(x) =-2e05x-+ xsinx and f ny a) 42 (14 vB)ax a ney)? (nt » [0+x)? 0-x) v3ax t-ne Lorn? -j— Now put >t 1 feeb = (1+V3}(V3-1) = 8 (4) Suppose P by by ay (O365- 364) + 8g (06, ~ bye) Maximum value can be 6 when a, = 1 ad bye = iC = ByCy = 1 & Dye So, {b,6) (bya) (Dye5) = = 1 and (jC) (O46) (090)) = 1 has two values 1/and -1 2 = by Therefore b,b,b3¢ ich is not possible Contradiction also occurs if, = Ig = Dye = Bye) = 1 & byt, = B. 7 For maximum value tobe 5 ane of theterms shouldbe zero but this Ill make 2 terms zero therefore answer should not be 5. As] =4 Hence maximum value the determinant of P= 4da 43 2 (19) <8 and n(¥)=7 1B Fo DeTOOr gD ooFy) 0 Number of one-one function = c= 7C, «5! After pulling x = y =0, we get and Number of onto function ¥ to Xs given as ' F(0) =217(0)140) > #0) - 1 F()=1] b Now puting y = 0 in equation (1), we gat \ | £0) =F) £70) +0) F(0) 100) = FW= [> (0) = 1andt”(0) = 4) = logit) = +10g,¢ = fh)= = 1) =02 ( f(=1) > lag tFO))=F > log) =2 2. (8). Suppose coordinates of Pare (a So. coordinates of Qare( are (a,b,c), Here, PO is perpendicular tothe planex + y= 8 So, PQ is parallel tothenormal of glven plane a. and coordinates of R ie (ai + bj) is parallel to i+ > a=b ‘Asmid-point of PO lies in the plane x + y=3, sa ald Sarb-6=2 s_|y = titer 3 @a5-9- > x2 mn|—8) xr e.uheresis cansanto = Pear = ee 6 a4") 9 > 4 ye 5 Hence, PR=[2c]=8 tegration 808 > y As,f(0) -0 + 0-04 + e=0 2.0.1.0 PY 2| _ a Therefore, oa ) ae? opin 0 soe ow.o0 tim |SEDR2| im 206 ara PC x bray fz 0.0.) > 5 lim f¥)-2=0 > fim (0.0.1)Era 44 i 1 Here, p= $B = 1d aos yat Str. +j-k 2), 4 j Tallea 2 pga injvi 2 ig eititk z ijt moa A) ean) (0) so, pxq=t]r 2i+2i i+) Foe, 010.) a xg ae (e290) a a2 / a(x) =sin-"( age 5] o j \ 7 . J 16. (C)_ Here, a committee has to be formed form a group of 6 and, F x a4 Boys and girls, ad Total number of ways for selecting exactly 3 boys and 2gits=!C,*8C, = 20 x 10= 200-0 Hence, (fx dq) x (F< 1) [Gxd x “4, Total number of least 2 members ys for selecting of boys and girls " (OC, x3C)) =461 =a ing 5 members having 8x3, = Total number of ways for ss atleast 2gitls = "'C, 381 =a Total number of ways for selecting 4 memebrs having at least 2 girls IM and G, are not selected together =n(M; selected & G, nat selected) + n(G C,-B1 = My dy 81= 189-0 +1006 9)?Ea ‘Area of ALM! v3 (given) > LLM xON =4V3 2 4ab=2 ngth of the conjugate axis of H = 2b = 4 oL_b ON a = Th 2 riclyof H= e = Fy and The distance between the foci aH = 2a¢ DVT % 8 20% and length of latus ractum of H — axd ae 18, (0) h Sh h [tim sinx lim | Det 2 f= tim | no] hoo Lixo x vinien does not exit 45, Sofor (P), (2) is correct. win] BINA), _ x w5OL “tar he x Hin | tacts |= tie lim wat) | x | ee tan tx which does not exist, so for Q, (1) is correct lim. F3(9) = lim sin(log, b+ 21 0 x90 ifx 505 (x42) 92 = loge (x +21-> loge 2<1 > 0« im sintiog, (x +2) im [sin(loge(« fs@)= 0 ¥xe[-1,e"?-2) wae (1, e292 FyQ)=0 vee G1. e!-2) ‘Sofer (R), (4) iscorrect. (<2sin 2) = tin x2{ sin ti £462) = tim{ x?sin4) = tim x2(sin4)=0 1 TN Oe) 7 resial 1 | 0 , tim 2 — jim psinf 1} =o ag) ‘4 1 1 P46) =-c05+2K8in 4, x20 which cloes not exist Sofor (8), (3) iscorrect