Cata ty srs ees CH - 6294 + Tetbocturetyon of Cetrty 6's * Mode. *h chon “(° catalysts 1 Clewifestvon » Hetero ALOUD - Lomo Photo cetaliysis ~ tps involed ~ Finety cs = Meche Stone concept a Cataryst contept > enwrgeties or electrome Yeorsous . lt trout Gs 2 - chagceters ze ton tht + impodinnt Crernjcel recchions > Cindi impogtant réechons -UNOkL erie winner reathons ) Book > Sree ~ a seg Cpa tty J Hagen rraurrane ov hetero eed pho'toatsy+i) haersth and SiVasancer, - Vishur 2 (cetrty sis prnceles /agpliceborns) sus fac, Oo name maleate . Cals ys by & Riche! don th + Neiman (homo: ongOVy Getrty sis and “ oe eel appl ecation ‘) - GC pond CheteRo now Catetasrs prnciple s angh appli cebon 5 -GeC bord Cea tetgirs by me tel ) p concept Ff tsverdntt ( dea a tags 4 tard bs) chor hen - pads & mulkeshier cl Lt is heat of ft oe provides tools for ehheb anol “selectively ma i : andl theca! Chenu onal Hot ¢ Yule in chomilel bans {ote bon, -A Ac-A 7S, 24 8 S055 b mew —Y bord bey, Bim te baad Lmpasstnence Most industriel san tresis anol reat ett biologi Gok, neections Yequire Cote st + Envdonmental pro tecbon- (Gerhard ert, Goo P(won nobel pnre) A 8 HE WR Ke by usi eetalys ts ‘» _ Severn ental chon, we. Can coment fhe toc onithes in @rinkn lls buy’ conepounds _ - n On. Ree 5 N2 (O+ Or PELE (On | ca& aero aoe | oe of inuctiad reactions quart ze eis newlig devel ca ei eae 2 om ° pe je Y P| ey. - net history / Gencred hasac e7sae ok catatyupe reachons ' + 1836 % Berabits mtwduced thif ROC “Catal 53° to explain van0iw olecompori ion | veackod Aw vanou, tenspimabons ‘ He astumeg thst the tg thy st posites special powers tyt in fleende “agbenity of Chemie substances” ‘ IBAS. Ostwald he dlepinect Cetrtast a a fubstarte Hot “aleleretes | ¢ endGh rtcebon wr thoctt agpeebyp tre pos bor of CeuiLibrivyn CK) i -——— ‘ ov, (007, 6 Ke tp about how much %4 chan € PO leeded - Cr taba Used 9 1F decrease Le tye © KuUnea fy Ke (equals brivm tb reach i Ctetist main —uncha in the COUR fg ob Hachon, but aoropic fom tan ss Charge. +R Greactant ) s & Satease Cat-R (shart Lireo) S& protect if tong Lived ia Hen it is th Trin we have ty do. Calleol 7 someting + _ At Catada st ; = te fk Poisoning =E ‘VSUUEEEELELEECELELLDEEE Cert 4 ° | Rate of reaction 15 indliperteat of mo Ewe sala of catalyst, but now | on conc. a ety st when t is two Smalh 0h J conc. Cont IS equsd te (eoneparvble to) reactants. poxrcle site - more e bre when nn olividedl ( moke. Sud fa ce area) thug Pt wilt hare a lump o ruth less acby a cou Cloidel spe pa of - a ca st 1s fr a: t in ts achon . rie it elintinetes vnolartedk SIAL Procucts when SEVER Rh Products V2 Poss, ble fom same reactant + than peerfic A eatalyst fen lovee the actyrabon Cnty 2 a pect fic path path — Sebechvi eye iL wt P1 fate st is om ve dL Spe tele and’ dire pr fereAy ce HQ lor’ se 6 a Spy. - reackhon in a spee fe This pro per ty sit colle “sp ecifits ty wh(Catalyst 1s Habherod Catalyst it “cally a vegebon one, it will 5s Cyt ze Het rae bon ternp ture - alters the chen CL alwa « Cha vate 6 woulgl cant iS ib a (ately st ob Catetyst autcrer fabateric + Pos/bve catalysis °b Fe Na(g) + 3Hrlg) => 2NH3 lg.) sNagabre - et 4 abgsis . faecal = ‘att gerekeron *f $ Un do fA Whe reachon without but Somebryes the torre cen be pluysi by heat (vise in drempd) Henca. actinty rey be Basie Teams a ites reacbon nome Colla net fears bAe 4re Chot o » Bh, » tant a yeeetion thet possitete) Weasel in ith user if reacton as f(t annn na © A Aeorea sod § st Ineree ses fre ate. Haben’s procecs st etards fre date of ea chon “auetanilide” 2H202(—_> dno 10, “yetasds the reacKon” dbang Qa OUR fe of heuer. — echo Ww PEN One °F ho peta)C7TCttts CTTTITT t ree PEC CC Ce TT Ly Cacho, ts a6 a Cotalyst fog the 8eDon “s d a (at) 2KMn0y+ SHrCr0y + 3H2S0U —> YP IOG + KaSQy 78420 + 1000, » paomotors/ — sorretbres phe prSence activators of Sore ofhrer Substance, (eo- catalysts) wr ch are nol cotelg st: drempelves but increa$e rh efpuieney of & & ut.» such subslorty Inet actyate #R Gt st we CeuecL pkom otors, Mo acts aS Pkormotnr for Fe 17 Haber pronss (N#A3) + Loh bitors ~ (@ st porson) In ned ‘ate the preven ce ob Smetk Fart 6 impuri b€a in the rec cbiop tubs tances makea aT Ce st inachre such Substances are colle ca ty tic poison * [inhibi tors. As,03 Poisons the pletnteed hes bs “used ap Cattty st in He ; manu facurir H2S0u by _ natural Lontemet's pro ies» RR. , ‘ . Modd o achon o6 Carta ly sis In an indugtial Veeco Y dreke art mo © than one @tatyst . é Surtality Oh Catalyst PY an incturbtel € Process —clepends on following 3 PROPER tO) © ER activity € me uw ) Stlctnity C fon Specific proctuct ) e Un) Stebitety "dea chverbon Wwhaviot ) : : VAAL oo rot Acompase denne the S rtgction 7 35A2 products We , . : ‘ 2 errs Bomnea vf Cotetct & ¢ EO Actwity- Rete $6 1abor PRL in tre e Prarie ra Ce st ot @ parkuar © 7 ab, aa) PRbfaR 7 8 meertgo of how regebon POCA In tho a «4 a : Pitre of cotal. : ot A parbetar erepety 6 M4 ot 5 = i Rote Oly rection £25t, oe “¢ € i ‘ eS feat « A ~y i when to Nad Prootu ee nA fh : > Grete In tng Oy: . why . HE be the Prac g p JP. erero) CONT: TedW » tml bis Be. ian cas KVE (cay er kighee etee Ss dy vate constant clependlenca 2 eno erent BREE ae. 4 oe Amount ve recctorte = MA0- 7A ~~ small “chinge ~ ole art mok Spo dt ea ane = 4 0f rtectOn is by wore Ga” Tf bre “intewaf i small, phe “Protee : . will be ess ola 2 os App = rate of reebon retluct ) Ca at es pattie, Point of views rR chon rate, nrg the is Gleuteted SS. Mme rvak 96 cherye of aroun t of reactant jt Bg A with bime “iclebre te rection volume ov TSS ot cotelyst pa sae pl say um parte catalyst colely st aD She! 8g Ra prt Jf‘ Sy cake owe Uh) Rocetin VoL (rare) rrass Of A= converted emrounl oprertamt XL cota t vole OK cetalylt mes Ome aly U} if) A POE @ aspree — 016 cote tay aot rere2: OL Gol and Fd ane mOLg ji na &) LE tral on Bre wher tre mas of cotayse | of €tctast stovient thon m0? amount : ae eG proctuct Calviget S Cbbcint cetalysct is expensive aTiangbon meleA oct af 2 eutyst Sfourcl ower in eatth hua re {000 a \ {Highly dicho peste Ak not WA ® a celeb , {tay con “He © Tarpon metals acting aw cote & ae mae SHfensive than ein elerregts bey | these Chments ane sal ea not Ara lebki easily 0-67, found taeth’s Cus ; “iaP and f %& not cater jn \ . Ok Cherrepn ts at - ant mE erpinsig 7% Catalyst bub - Br mw . wid in green cenit anol ae | 2 In tem * Pk femal kine AS p Rate of *echion y ( a © tetiog STREAY* Finck ort Tree tment “Kn, oona 2 and OBp homogpmouy 7 TON ANCE By bettepren gt Lyre itt foke Stare Me f Ke vate wonstent e y Rete constant depend) on ternperctre no (Dret Arletion ) : mo brA 4 FP = ay t ' = d (naro-nA) (hg.o-ng) Ree ent <) ou it 3 oh (nao- May? (3d ado.) 2 a Te tempercturt alopandence o rate Cons tant is per by Pv beri eqULe 07 ~ - Ea/RT 2 k= Ae nd tnk= dna Ea » RT 2 log k= loqA — EA = 2303 RT rarbsolicle Lemp (k} 7 Ea: Actiation’ Z tog Ke Specific vate’ cons rt 3 : , 2 A> Arvkenivs constant [he veney 2 5 factor loted to stenc sith a factor hoflision Keprenty _ 8 a Pe ae | \ tree 18 no Tl etfectie allitionPIPES 2 in) bp a mablude _inuob Spas Ae ani bo bemicel eeubon 1, 90 55088 to opt WI & Crenu oe Emi lo4 Ko L tT VT i 1044 . E9/7.303R * oq k =“(L)7 titit vere “ere lo Terre cts? inereesen »make catlian »mero toile pe the vate constant shag-t Cie up intemeligg t= YE Ea aufiate Sa al erotgy [ ured SS eee Sa Enag An eer meyer oi “ cae FEO ag subse af Me tbe Sabot] an fa He ve, Cos ca Re aes i Reeibor ee “4 om @ m buck pain netebion Poth pred Th of weckon lige by olny acetates aLETT EPP TPES SPAR PREC EGS EEES pcevale conglen “will be folie p Eyothouwnic: patel he hao less e a Loruparad to reectan py Endosharnyl + proouuct har moAg oer tg then ree tan) then net wll be ablacbhsol* Conuept of actration Rog ctant ten not be treet tonvec tea into product » at Ms* VachitreLye gactain amount of ty (&) Hen atactent reanargeok ‘te efron promt Ea 4 = ate of reckon uv Ea is always Ve. AH= + In la-basiore lf AP Tt this reeeton dy rot take plece Hen het At het 2P (érco) a- coh A= P+ hert (Exo) In etofr@enu'c : Lf hegt J gen, we produc comec tea ty reacten at RT, So ice is yea so thot + ote Hel is veg Ure to C40y Ihre ba (thal cand fre vest ar oth _k :jhe Bot Carty st is Pore thot Aosived Comertioe at a lo den TOWo rot waeds cor eng D, Ynchts Gn che hed. Carnpig out dsackratin, Mealcerants rr ce Lolasts in pilot Plants. > Cotely st docateges me barrieh, rt prourkes the — alttinete path of lovee ong f ff Ff A or actration os compqnad s oncetryzad vee con. 5 e Te patemeter thet WSenke, acbvty of } COtday st = & G) TOF (Terns over OLN e Gia TON (Turns over rureek ed TOF Se Tt quentfie He Spake aetiity o & ie St Cn t& fr 2 EPecsfired ree 4 olf real Yeetion Corelban . S it "s defined a5 e ; ° "Numer of cetady tye Clos pea gS vnit celbigit, Sound Pear vnit tme” a eS TOF = Rate of reecban = nyotir/me & . Amount of Colatiyst rrotés 7 < [2 styl 9s! § “ anne a - a hones ano a af TOR = lo ige et Fl 4 a 10-07% Sets ee Cenzame) p “P) nhe provictes $4 tg of 7 =5° Stleebuidy (s aa mm Ree a ena Tese ae ppropnate to ue ih nctaten 9 4s - O-leyclis ea loos = Leyele S32 2 2 =o N specifies He maumom Vid thet Gn be meade Of 4% cetaty st for 4 Put Kn Onder degrred concibon 3 TES aefiredt! as SS Netalybe cycles eccunirg at a SS cacelig ie Eee Cen te upto +e cong = of activity” — S23 . - tye + JON= TOF FM bine of Cotatyre 2 2 gl & See b eka See Ga JON= No unit eg 2 TON= lo’ 107 (Suitatele in laborators) SS ) iA (dosieot product ) ] Px P ap lle/ A r { wn vecekion Pr product 21 puied : ciate Prod? Pe 9 ection RS Ie, tueuilmt Bf veacton is ji it of ba stoichiometry > seclectiitg=4 & Be When valet ($ Ade ty 1 > Cetalyst 5 Slectre @, Cetalyst form more PP and less i and Pr Pl qe eetatyst i Seleetre i e 1 “tt is tht faction of the spat & metemal thet © meet to Fh@ e clesireot product (P)” 1 It Fives infolrreton about the courte &§ action Grolicetor7 about pathwasy\ e & = Amount of alecreol product q Recctart quertty af rerobon SY ° ¢ h 2 p: 1 (Aware) a (haem re eed Ga al Proclucts J vill § it Non-nA hp for) al 1 el means side reckon § a ' TAD Plele al i « i Lf no ompsnp 3 Selecbie product a f 7 No sicle_yeechon al i 2 (007, product al 2H 4 +H20 (ite thanize bor ) &| SONS CHa oH ( iLetharal Legriraci) Wine a Crflapen Hho (fihex Tropck) © at [(o%5co0 (onion catbite)] S OH off . Tolstoy éeg Tet Selectivity Con be intieelad by cytelyst oe) Stabidi ef 7? has 3 types - Chun ea Theumal Life me of ™ -Mechoniad J ce trlyst free ltox Ss 2 ° Ceniial > Ce talyst claw not peemenen es welt wrth reechant an ] prod ct > amerme > ginny het Ado rol decompose a 9 Mecheniel 9 by stig 4 moka gas S32 7 prt ig Factors affects Stabid, ‘ Pecormpos' on 3 ce tlys can clecompose re auirg 4 CAbon VSI SHES on He = co ttyst » courMyst site not Sa ova it de Vebivaté, S35 poisoning 2 forerqnr parties inteeect to with attlg sE Unxpurjty) e| - a. ovbyity av function 2f wre Cetatyst not f ‘ Prot +| . ; steele deonep dread >) oily meesurcaA by me cuAdop eae UtRegoregation of ¢ falys-t * oes b facia important bez iE is > diffiult to sepayete the olesired pUecluct from side proctucts “Tf Shuctre of prolucts ae farce thin it 1's ffiult tw Sepato te > Stebi Lity In We Ma mot Lp) Selectivity 7 f tebidr by 7 Debvita J h tems ok importance, Ont Cass ifigion of angst: VE Meee nt aol of fin We Gn Adami, Cin on oti ent bay) 7 Stwetu aus = aon oe - Usa 0 z L > Stale 'e pcg le ue a tg ais oR 6 of “ghey 3 the hae . Ae yea ad pe Ue PAA. ala alae ole b na anna naon! = Sup partca | on vane nid ca helyits ? hint Pelogencouy : hy ft Thasoli solid-state ee 65 balay ses — Cotalysts. £2 9 Hamtaagencour @ Hebergencous Sa colate sts a Lips ts S22 ee aud’ > base. cetatygds Buk cetaty sts ; J on Ht -OH™ > suppai ted Cotalyst = Transition met (fired beck reectvys) Ss Conepound’ ce segs ig ablaches C2 on 4H tre’ . sudface of the ba Reoe tor, be YZ Za oe PET in expensive Seppert SW a “ae S @ or pot t Pee @ He terogenizet Homogaro . © uy cotelys t~ me MOK SP ne vedpoct with nebonel cepa » DE Rast s o2ganometellic and come fproup phic cen form Qink S2 Sa i. sino tt ? r Speclato® tigard. : 1 wich do not take peck in ecbhor oie ded (Eneynee) __ = = a “= pe @ B10 Cotrtyst— boty = bL acidy+ tvansiton eps Nomegtrenn NL npoande &4 Fhodivn Cathongh conte len’? mine m Oro ees tn ep Troy a arxjanometedl’e in ng tre , contro! ei» meth § © Suroundeol by proteins a “homogeneous > Ce ents & Kea pice in a) unityam qe of Liquial e. AMS , ; dey ane Useectly well ep ae fret hen col Ss ‘omporarde 0 w-otdinebor ey, Onplerer Ty ~ 0 thay D4 e-Fher- wr fh 1eekants 3 ARE melee fan clitpersee > 2 in te. Lecce, medium a) : Me thoancous De preety Krehf Se Phaser. Ctelurts aie SXy Lb i) ear Coo twety a WL Salida / Liquids at 7 PE O% PA Nets ak Usa for oudetbon of — Qa NH3 NYNG2 Xa (ituath’s py, Obs Fal hardens; Pretrr) Ss 7? Si Cow Be chiki. Adee Ss pp ted, tity) Ns (So-904 ) Siligg Ad, = endl ing, one te ’ (0-2 -) a) Seed yeeWeretogercoug—> PL Rh nets fy cndidebor ok NH to ni rtyous ~ (Ocbaald poten) 8 | ? Anoxy oun 0% ey stelline atuniro GLIKS ti CS ct big Pole fracbions aman w Ao molecels ob olla dh jn G2. Coz they ane paganino adds find Of thine UK dive m Ct, Some AL chon bound to CU menpbrane.5o ~ Peg are Somewhere bi” homogeneous andl ma cyosloprc he te w4eno casts i tncgmed ate dmving fore &. for bielogauck reacbons, Qualities “Trey have remo Keble IRecbvbOr ank ' Selec whe Cgtalant > dtronmpose Hr Or 107 bres fut& then nena ce beets 1 Dey abe uot Uke arganomd elle compound, they ive mete! Suvvourdedl by protein. + Mages adrantetten rue. thot He waek m mill condrbions i in_10r7 _ deriper ce Od Bala, aqusour Sotuhon, PH ne py F tbe * Disodvonteges.— ea aeLu, " pologicae . Enaagas adviirg forte fox bologi kahOn rR G e, , peel (27 ingide {Ao becly » No dis adranaper incl ’ ‘ hen ue isolate then hove « “ata 0 bid teoinalo , tee hove 7 rien " tages eq cay 7 ~ N2ymey At ve Sensitive ci visteple moto Kle-s wich z Autrwoyed in extreme conditions , thea furcbo Welk jn m Pa § pgsiolencoty & condition At hoger Pll Yan Win el clidute Setuton. a ~ Hey ae ex oncive j a duct t& Vee i” pure fem. = Homo i) Netecogeneore, 4 “ign nae Henndnea we ee PRS0 borechyiey “High ae of * Sulla Heachion ¢ 8 disper A . "a Cali bit Mahe 8 is ctivitg fA brit 4 mals Ok” Cotaty et a ‘Hig mobid ; a L 7 4 teas % t eA hey al FP aah faymn Ors sue faey evarlebt § atl dire bons MOK8 Cott icin Loith : Swhetate mobiles14 ayy ul “ eign mobili SP “(lbw Cetaly ft te. Cone mitt Reebor londibon) es 3 : have fagh g <2 en 9 => Ss suss chence | f Clot | C formebor) | of ch me tof 2 16 diff4erl jee radyeo See cen Aonete em densi a = t metalico chore ” Sob spectatvr Ligand das the ne Y ae ok ie =p n Sug Elutror alent Ss S - Bulky f tigand ste 9 fo rector Lig — lerkeser. (steric bulk) inepaore ses jo. soment cn | ig 80 be change | —-—_— ad ty my nd we yst aaK hovagpi aig Seluctty cor be fies mde pale . Homogenc ow) Ce falas ak wntvilea msintg by ine bOS apd don by melt/as tranc pal atlacheo Yee }f quied quict No tre wagted “in diss ly subg trate metenat ‘ban spo t | Mechanism: * Moke unde chood in hom ogereoun Cetalipsin| ba both Gawd Ave fala tb tke vy "B44 t_ take iliformokay about intermediate . cnt path fall we bat a Ta > We have tenu, Cnit of ght Ot OAanometedlic ‘Bee tb ae Lonspyse IS spect tinekes ston +3 + In he keLogerwauy We mates The bansport mattX&, It tate te «HE cell it /struidy rein hetnicas I engineer; Seton oO Nok welt unelosstoad , CU fiat tp Study Nrechearism Ona Scence, 2? 200% bi gh Ley, ete is Peat ne © &. o © NLP LP LP LD PLT all PLIPLP PPPa 2 > Sato a + Deachravon of > Cael st on 3 > possible ened SE ? Possiete : y cae Fo a» foiong girs Ue » sin third Lmade) 1 es, } dupes Tousen 3 loss o “Lomegar 3 abe surfarr VO son 9 — sen modifi so i oosi el > 2 ysl b) 3 went Ke > z » diggivelt Separebion | + au sepagebon > ok st “1 “Lect ano need > 4 aisbLLOebon of sepatebon. 3 >SoWent etracton | + flee oti (aye coeyst) >? Sen enchant - entn ton (sme » — Phometopepy catalgs ) > = not possi ble. Ce st recy cliref > : 1G possible oh » > Moke loss of 5 low mn hates oF recus ; neg Guth pre _ 7 eh >> bss appliekle | mole. pliclete bo ee i< highly eC Re? ih ech 4 Glo” do Ty (PPA) scl + He ste t= * H-H A [Ibe] . ee pe—Fe~ ‘ eof i ts rae ioe q L¥ Cpph3) CL 14 e / a £ [oxidity® acliliéon) uy Metal Sholld have SS vacant sitet A 2) Metal should be e7 vith i-€ low onideto7 state dissoqabye Chen Sopbdn) lectue #04 teh oe raat cag alysis: . Some of fe SI y ate tole Chemicon int patete oot Sb . 7 Hem ae prygsi@k in notee 6 1¢ meens thet “afart from actie/ Aemicel reaeskion & é her tof S AtB ~~ em LREAROO 9D Pn a naan em ow ta RR, f. Ps LLLP LLY Pf?_ dikpuion 4 sta bry metre! ty eeyst Se - acllaxpbon Grecetert tos - desSOrptiorn (product Big Pure factors He impor ent: a) ay j | | | jason Pap bovrdny © : a3 layer oO i pore (hypothetical | > \ fe me : 2 - Eyes) lin [ (Stace v° aifgyin s dager . (otcetant i iffy) Ss 1 Dison of sl bef motenedl roeh tre boury (ogee to fhe Colertg st Surface vd ‘ 2- Dik-trwion Of statt me ten int? He bie (p. phon) 3. AdSapbion 6 Stathig mectenal on the inneg sut face of pores. A and B veactants get clunusarp te P& four recon. Atel wrmilel reachon on the ce betast Sua fale. ih ot = Desoaption of prod ct 5 from _thé. Ce balyst surface gs Diffusion 06 Products Cut Of fAs pores i = TEHETUCTTTT = TUE&>3 Lure ts awa om = 7 Di kpwron o yooluie at ad eer ee bound (aye es Hho. qa phone. ; se] A1B — f _ és Step 4 deperc on 3 and S) theriuise. A action will vot take le te. Theze > 3 seeps will conitrtute the — prilobnebis eng of He reebon and these steps a» shold be yate oletentinan’e skeps .. Lites 6, 7_ ake banspaxt proper be," Ty WG AO not ingpact the ce baby be So aut Lf thn steps ae oo es Convunure, en we ‘cap L buck a fo canes ob fo Cabeby st Me 7 The” steps Called Maccatinebics Sn To &hhana te aj ark Mh Cat Peet be prcuabteg HR AS. TE pore cftwion par ty >? be ~ thhence, we hare to gerd Sa ie Ceatatyst.} te Increese the Seeface Sa Aka. ; e— Wmpanson bo 5b anpanson & dep 5 - eae. Meter, No - No ee of ters | - Ribbon fae Kg Satp, Lure the = 7 ditcabee “¢ 4 “4 su fae ot Ss = Metel Should have = Acti lortre, trouth Sed one Srte, Sho: w coogdinagreig 9 | PORE on late Sagrm; —~ 3 59 a ta og ne &3 other use = . Deere Ss IAD brebs ems steps as ee 2, ~s Ge Ss me. Raney cle 4 AM a) fusion, Sono of La har to «4 > grind 7 Sue face > ri a on a) t We oud a aly st ome Metal and Unseturetser Lacnc) >inkeehon 7 rechOn e. $j beaure 4 wil¢ | qertiorte vacent | sitts = Molular ¢o-otdlindoy ~ Adsorpbon of rq of Small moktcutes ngturd , tat 16 0 Suth an Ho Clea physio sarpbary die to yan walt in tetection : 4 motel inthats ae M-| wrth ¢/\ H bond of Ae HH (not. @ stroy bord ) o “tet So flus 1S the physicsd u ackaspry, : aed Pbon. > not rey Mah 2 @ shorg CHa \ - oudetre addition |- if 4 get adore , with +he foarution of moe close to ce talybe Chenti ud bond. Suh fac > chen sorption ©--@ i At s cay eH (chencicet adsargtion ) = m~ -We have echieh chonice) Inveetion reaction ot | eton blw A and B Nuclto philic (eectophili| AFR chenisoption, on —ractions tater | the catalyst sucrace so PMO i ae ae a, RSBook for inane mau 7 Ir (misclet ana Tack) (Jom Hulke) When Hey Ade in cis, Joe Desaxphon and Hey hl Caute aikRuion 0 and Aim proctnct product awe hy yecductive fom IM efredgrt elianipeton itt d mn 3m? 4 dl wn, CHs-H B- -eli nuneton © ? H m-occt ‘ae ener wrin metal hay an keys vacant Obit og hag P caxbon (H) Plysioscnpto n. VS Cherny . OMe. “Opvon fet een Is cameot p Vande adixption ( (pei angi r® y hal “of A ula 10 ke Jin ts t— ei See y rt ig La Olean aptt “syp HAH) Magy = ae ee Mt 6 almost equek to bert of fu sion of SP ine areyfy —peoueleal in the form of vee 3 het 0 a Specific quanta of wigit e&3 Subttante ty ‘cher its Stete Ks fam oe > Liquic u 7 ater = es water 0k g/mol a) » ChuneiSopbon jg, a Chemiced bond blu Gig Catalyst and Hee strebry rnetenied . Shs xt is “much clover» iOn/e ar wWrrent : in net, Con be an em bansfa. SP Wo cm bart KK in ply Si0SoX bon) 2 cs Example [Chenu soption _ ( prysidsorpbon ——> Hus is ty jLpnun SS (a re is he ot ort S oe fous ternperction. &3 _»___ ; Bon Siosaupbon = De 5, iat 02 xz eae pine peieigtols here Acted se 7 Kaurer pr acbvation Se is 330K Gmoi 4 it, i is (owe CR Walb & 9 -In combustion, at (ow tenpeechue rect released put We pro@n cen ut S340 bGmerr’ be 2apidlg inoreese oe —— Saat ne fenepecabera - os __ lacBration! banyiex must be. orossed) at cree4444 > pode —heet in ehrenti@pron, but cf ape bv muh hel) reechon con & mi Wrerse. Actyertion a iG eguired Sd | Get WwW stat He jection. ~~ & « both Of them depend On PREM, more bl PAUL mle will be the adtoytn pe eo. 9 Pp 9 8 5 mths We Ake ey ° 9 formed in Pie s2 serprion t sh A notin cheng in Se Fardlamentak laws o Chemisoptsdrn ro : BQ 2 faus P| aD) Freundlich wry ery Caz abPp 1 xi Mechanisms of Heteho genous Catrlyeoh rea chions:- Ag + Bg — Ce Bimaleulad yar phant recchor on he tthogenuw ce bese sur face Langorwir - HinShed Machsmim [ E v@ vO —— A L chonvorfy eat eS t Ahenb* —A v eqsntontt ,olesop or ———t_t—_ Botn A ond fb chowld chums Sompt Mechanism No nbed Of botr Paticad chennyso phon _® Ax SSS log — Ridont PPP hhh & ™ DPPPP POD HHO MH {2 fs Ix Pp ?Ce sere Fy —~ —————__ ~~ ___ Con 1h > Wee , 2 = 2 A as Ertys Hr 9 Cong No necad o a wu t chernus0 pin Pas ? Pye fa ea c~» 2 >> any 1 of frum iS — both of paul Chenutoppeal es Chenrisorpted a a MH presiae is of Ce, = Aor what hap per Cae wD He vate? Sas > S32 7 Lecturer 05° cays reps Tega a origede a had of fie Ae Se 2 cic | yes (i a is ees <~ 3 alec 7 Coty be cou ob Irene moe ndQs 6 as e AE gone pee ee rele ted te Phorediynsau AspeSTR TT I mohlonulcleat- a beckon AC —» P Ng 4 8g —2 Pe (binuclear /bimolewelat 9Rs phase Rector) i ‘Atleast one of the eectant mut Unde cao hemes S00 phon. *ha should have to Chentsnp on he & falyat . ii ee be SA exten medium n dott ‘¢ binalivp Strength is . : optrum - Ar Be + Chemisorpthon and (ZEAE ‘ OSS O¢;4. bo = é when both ir ees Pl Chomriso Ae ae ole i 0 jaro. AA & ee lengoul ie 5) hetelogeneoii cetely st: mech s » Active “Cenbes | If Aand B acho . /& (M Gen“t foro ee Set opet 5 balay We reult 9 zl ieee tito base «SiGe actie Ce PRAENL a7 Gre tal Sik foon +S, Hetero bo Teeth nt Re V8 on ete : aimmo level 2 seochon) yt show etal st - haTid a es ASS ens AY Be al aks po 6 8 JAA pe usin = es 3 wakehegf ek 5 ee ts 2 a +29 a a) on Celelpse ss z Tr E = Potential {~~ Ea react’on al / ogee thallp Nag, tN sugfa mvt, hegt is A gam s sate pw as desorption velta Leak enorprg t . Reaction exotehanC A* conrdirate, r€acthon Ea,o = Actration of homo: OUD one SQA, qe Pas reco ion Ea = tre acbva cata Ear > Ppatort ecb raton enetyy ety zal ach Ov) % “9 zy) = panston state G Gg” Phase +eCb0n Zr tranvbon: state off Sux face Kocbon Aug = reecbon, en thelpa f,< bao 2 ce st (owers tha ackrabon net Chenisorvppon, Abe lov€Red > alinary ¢ enothound’, 4a wnrvegt A into 0%) the ot Ea,l is abtocked wuuith is cllbet rer actiation dhe lant Peek should never + be whee KR MGI, whi Lt would ‘pe dit pat to atc He. product: ft is silechad sbowly. :A TEAC TANGA TANT MR tt mmm Ee = Deeper, undoserding of Colabye cbonl= ¢ Reactivity of subsbratea- S = : Lkones > Blebylones 7 Aeros 7 alberta 7 NC pad tbstentey 7 Or polit Sutssten emu 'Sarp b¢ ” Fox Ure shength oh Chemwioiption 0 rg meee? IRE fotlnwif Se wore “ pur Or7Or.Hr7 C47 CO7 H27 Cr 27N2 More reechre is he gay, mace sborply ik bindn, netirde hay 21 € » PND GL LS) PS I DD MP 4 have make “4 ta sotiiane mes 3 e~ oO) in bondire, Bet x aay beading sg oo Stor, so flne Hs bondi with Cetatgst ce 7 surfrte iS not He moltede Soove, Tt hw : 5 bondh (3 bonds) co it is a s, stele mole ute Urethane ) Pl + polar substances will_absaebed quite, © hecoune heir ate pDler, blu tig 9) end Hr, HU wilh be ~hencitorbad & Quucpeliy — se ee ae o‘Ons = id ‘tang on yore, Nz tae? ttt t | The elecbongaty ty aipperen le eet, eas Separe tor ~ Hrs a So, polamtey mater the moleutes yeec dit. s | » Omy b Vv reactive , Why P Became its hao unpairtol elec bors ~ unpaired (réachre UZ A electron ) Awe PSR LL m L / 7p" ze 7 me a / 097 Nv ua onggen > autyere > 2 lone pains (2 dorble bor ) Ubere 2 L doukle bond , » CO and Nr are isoelechowre | ae d electrons, quite stele sope of har Conpae Ha ev i ions - Ser! atk he ode Fe a teting at fhe Georg, ciahams we Study He tahoe ep a ote entyfes obec Bra (2 OCUpieok — moto H (5 oF Te dy L, Homo “is aveetee tron 6 wen 6 > in “eee *b, fe Pia v a en ee in d ob; ~ £| 1 hee apy i YY Tedd he % tw Hag (o tue Tay 2p $0 3 nian Scientist 2 Or. into rihengy to TY, 8 ee b» ect I se Cen be Reclirced. or ral ate J ‘ In Cate of 0, the & Kerr byt i the COVER cions on aan h, ‘ soe 7 * Reactivity of motah. : 1 es 7 7 Metet Groups % Gar GH Go H, GQ py, ee w ee Tze it, x eS Os2ho Ni, CO + _o in fre P9261) Phifd, Pt, 4 + Lr Py > ocd cs (Bs) Mn. + + + + Be ce) Aly Au t+ + + 2 Earp li,n> K t+ + - = 6 tag 67.90 Ag, 2n »TrSiy PT? GeoSn, Phas, + - H 4 eo Sb, Bi } Ss «G e oe 4-8 periodic table rr Ys ee lstven - ae oniect >? a ot oe Pp trax a Se hae aA ahita oad a ona _ i lugh A dXbtal active. Wren ee fore fod left to ght) the Ad oepyted enikhy Aecreg Sy. “bez nucl2ag chakpe Sc 7Zn ‘cb G7 noble metalo of q -lo $3. 2. Anownel lohan “t (dS) tol") frp half Fuh ag al ake. Eg OL pee a - -2-- 7 3 es fe = By > Non-noble mately 4-10 Group _ Ss tas] = SBOE coy Redisorprion pk — Chantenpiy et Oy “Gi Guy to Ar anh. | 4 + 4+ eeI i TL Ln S ane oli taly (naamet element’), tree a om od Fok cfrouusorpb oa : A dubited choulok ee. ere fA keatk®, Chemusaaption ‘ é Newt we shall Congider we bindlire of crruj(al — Specicy bo ne e met sua face mn more deteil, é startin? with sintple Hetmod namie ¢ Considece bars 7 Adsaxpton is er enotheuc e protss in WIA bindive fran % & ari$e bw #2 WiRboe moloulos ¢ ond the sutface atoms 0 He cotety st Tae adsarphon nth HL wie olepenoh maink © on he Strevy th of Chinuied J « bondire tw dhe” gay mole cures ana the — Cetalyst: tty At th same time, GUN a Ok freedom of Hw mole ules dude when Ft leame the ye phare armel Te re on the Catalin st Therefire 1s abe. Si it ten “4 titan & of pp Pom 2 aS LPmn —_— > nts), a reacbon e&nbopy vatres wr U net Se US oh lee Vv Pe tly wX- vr &3 a n iv d more at reloeseol > igh chentisoipbin te < he 2 PA a Jnecene oliyramasealy feasible a eo acliacpbon prods, he © Gibbi Pe tymae @ 4 Onekpi, should be regabre. ~ Al 2 AH-TAS —_, 7 s% ay 1f room temp T= 300K Soe obulis 6 5 45> enbopy 3 hun Ais chenysocped, Ag of feedorn decreesen, * AS get! Le => é My 3s nopebik » A % bound to ~c Suk face, lon ranclorn neq, He from feectent fo | aa ct a. a val) Cf 4S dty nol venes a much S38 Pe valve off 4H “au a ime, 2 — Shove Chenu Lapbon, lu’ 4s (cre 7 uv ¢ (p wibinee chenysowthor ee vale). La kth eclues C2 not (theull fe -v€) _° Moga HR mace fescibidity cxefore * fox the Chenu Srp bon 6 § He uv oe reectant A, “2 . gies 8 ad = oo Se oma1 Ys pI TV aun a Bs SN AKAN a \ 4 a N\ R n a i db Xa’ yg Yo yunuaPusyve Ul Syms waned yt Pures mL sua Y yfin ein z b pw p a, SL! te Sloman yan dan -muayPaya DMobny Fd Uo dumm Yo} SAlod sua} 2072 oy} v0 qpucg dqyn va fu oy 4m yaw Yt!m sangjzo voadrosimays yom ayow —— ; i} yy a Harrie - S 2 anv 1 RR OT ua 26) 9 ud D)vfan: “7 whims LLL SEs 9a HI x { \ “prune pee apg) aus AYYVOs po Ss & °°? a 3 £ 2 om ® cae ft “Oo - Jo Gouoq ye UY) UL oA et Ot aNiibiengs myodosr / ~oymaow— Yovpe as mb, wk poysmbug.sne 24 YD) Kanacd 20 9551q - Hondlasmon to cafe paurwreund omy, py pu eeepowell 1712) TH Je 2 vaglororinp = 99 nang iW SoH Jolla gn- = HT “HMPL-0) wadigee Suebos'd u0dyosmmnp 21 0 | (lowell h- = dav 6 wezgo) E fens See eayisuot], wogdrorarstnd wag de osha ile BK — THK < COBO Le 6-9 : : Ve Gp % (ut) MUA 45 gg NS Z 7 7 WN In-H Eine)? HY, Z : © qoulgg.st- = OV 3p (390-0 908 )49h- gy HHH JN -H & IN* (6)*H Ty Dv mp Yo uka wWruqe wu Peayyorpo s uabouphy ay} yAhier ws yaa Ma x Yo yo. mt { Tdhuowa NO au rt -Apu0g by BE MO? IPM ayo “yim Migs SVYY)I0 p te vhs V5h7%] 29 Dy HO Popo syimucbse} pape apous ve VI yo FMYOw a oFvoupe ey Jo Hog yk YOM Mc = WYVsrumnp w4q2120551q - Wy © pqvos~4 17 9-1 ob) tH © peniospyey Spreanue : By =e “a Losneayg) Cp ow Pumuyg ey 2078 ppPay———— oy ‘veboyph, =F “eSinu eI on pee 1 bynes to ey —o hen eu prn Fe. [vey “pully 912 4 ! 4 2OSDY Gy Vaya 5) webaphay eo wt, Youu) AO 7 Uppy pers st ok Ben 2 2) NIU Joxujbagiz « Shmep By Hravo puree ee WI aa WIA el, Se oe ph QD Hagen A 4nd an ay DD snp uw m- st Adaguq ok CHOU woldy Mo PRA way olla 91 - a! Pay 51 Psu 4 ° 3. 170 Mogdyeinmn jorw O3 S30 Abyouy wat ‘eyme 9 hao eds Mh p pn Jutod nus vet Basan es Sy eS Ve youspo4 ou) Pagy ek, PMoponat oso ‘sy VI Jo mows rus 6wu7 6.9 7.6 wag dros arshaad et, 1 avd Sayer} wy LRAT AIAG ae ek, afras iy vo fps, dry? +H crag ypoe ne vr ge bot — List “uaqrey 10) Vir voy cam rage Pw my Oy it 70 9) ~? Devs oat ~~ S (vos 4 Q0¢ YAW) > — wopdrvor radu © FF prSplva youn Sy wo W ‘5 iB (quay, M tu ey = 2 o. ety L ¢ b N27 - N74 es yn 9—9W-9o- Hoe? + o-ow-0- + edly Ho” Sor*H a 7 5s SEC AAS Sy ean G ? ; | on EW SAH Lk yb fon hx ety | alee a4 77H i geulP 9 — j Vo. we doy oy suaqaa) € Yon» es Cosrae " TH) ~~ 7H bi phi nyse “ a 57 0B) 9400) oyyo Ml es, pr P05 wry) wydwor paw 3 - 4 tw - ' wow Ww eS Uns Lom w- > i we hwo HW 4a of yn \ a by ) spy poatTer pains age alto ured in boordlive 2 CO con make bee wt Ip 2 Melafy and Cupping we three metel, 3 Binding modin o, “pe | % 6 “porn ia we | Wt Eps tncg 7 fn-0- 20-9 ag j ty CO + th —» CHZOH ’ If ve aad Zn, reeehn lecorves fare Se ) walle, mtd >a @ a fo lod, os ey SW atgtagin . 1 > Complore 3 | Prysiosouption Poy cold — oh =e 8 Ut onidabine <3 jl ne se, Wh nation Se Chereisoxption ee ure siclenis — a hyde Pe | iy "yas it conep lon, ty fw \ aie . 3 Ms 1 2 2 > pee Lol Pog “y 7 re Pe te 2a Ta eke Hw = 4€e ele bounol_ ¢ Ae at *pecien a - — Ws = so; bound Aagostie ie spreity mtx chon - fh Axed adkaxption (eqimol hee Qasd wi it be eet: So Can't “1? connect wih — HL, ne 0 Haat ao vale is lon om i" > ,Ww TF the pond byw pe and H WS sonic, ae motel wilt lo +5 then is “ve. The is known a clotted dine shows thet 3 centred Le bond n in tees and case it metal ee ™ma comple Ti is e- Aeguents so it Wa interects with” te hydtagen of matt aye gatagen Of matcy Nabe of Ggando on matel surface, 8 : G é es ( . re bend CB 2060ens! Bou clecy CO 1960, 1220en7! hee, of (0 TR bands of, ethylene Comploney . bon 18) PRES Palsion Neon om Vers lor] 2480 igi Vcxe Lena’ 1510 1507 * free Athbor 2200 ux) « fre 16 40er? we “pe >) 8 Ades OL Mae esi be de ey alo- lo; Deeon plo The> —_e >a ue, ~ Go ts 9 es ce ms) < AHE — lonolenction, fe valee — Cree sey daucto the e° density Shr be de metal,so C-C VYesn vibeete eesi So. he value of feguen A deegles. So, asqanane talli os hu rs aot im vrder Steunolinp tee Be coal Loncept: lectu ye OF Decompls/tion or formic aid/ bo lean plo Gir 4 i co 5 ON 7 Hr + COv oy LIOZZE TIK] of | 3s* 1 a | Ge S00 Sse 250 Joe 350 uw 4S0 SHE (alma) Role bre acvity of metelr for the fyrmicacd a2 & furetion dd Lompasikxon of of hee of fornchion -of metal _fnateyWs re chon etd Tne met Sy important, 4 of arenes) fenuic acid is Li COA, erga, { Exon | ib procluces S36 Glmet oF H2 gy) Tus ~ 3834 is 3 andl a hee. trey 29 Ue much a compared to Yao Ho thet Y P 1S peasent in & biy tybindor. H-H ~ tatalagy) | ron-polat> no inttectin biw Hr, 56 “pe ad i bar ae not ose wilh ech ofher, pe tee tele abot OF Space to pu , - anol TE iS alse — {umnable- Cot vat \ feshly prepare ond ae). Pp = J motel foirrete is Prepared wus i we dong ‘6 chomiSorped on the @ St Surface, | cn so We SHE Con be Kock Hs using WMO im WHC oto é 5 n 8 ond Kak met Sunete is eySnod a Moe motels axe not pre a 4Tre & : AML Is 3505 wlth iS an ore PP? iat chy b+ Sk valve) Hire metelo reeure low Se . oe , Eloment on the £ Saas + Ste aghe ; hWLed Wish 1 atte —) oe moe an ee SOR IS nde ~The [en CON NS are on ne 2G Mae bop ok yelleno™ mn the £0 pot Vallens Sa « Kea ay LocCQUClIted i494 cttre me meta) on fhe top ake veke enpentive. Prarona Sgnters Example vane A Had (Nr °X NHS) we donot want a sbory or weak it OS Sop, pRooug t ; tf ioe | velcsed Nine She 2NH3 2- Stenc (Geomebre) onepts » ponasrty and surface of solid » Sten’ “Factor » Balandin * TRL multiplet Treaty” Si poirrt adlospbor _ miitpoin t. adseepbory - Geometric conte pendence. - rT a | hole mechani degenkt ; Ty, alec awaft J é B powsity 4 pace size and Sutfan 9 d al ie ep f ¢ e Sten c 4 meens thet + Gnolede has aint factor ty be aalsorhedl on WE Cotalyst in such & menneR thet it! fits pho om He suk face, 8 Hen FE Cem Be we Aeedi. activated. de re The multiplet they pus U4 Peasy is based on Sbuchcal and Tae vty Le con bguactions J consider wtons. = So tf one actre conte Aen Spe stele feet iS n0t mPpatant Jt a! it mmportent » miltipl pont ae “AX tion. TRE Show be & ae acblutad adiokpbon on Me ce telat Bog SuRfac@d-*Actre conde, shola LE s! avenged in a pac bar wang ust so W’eetent Cen Chemisoxp ~ 3 ge ts af ss » Geometne qeomne Ok Keetiné Ks or" correspondem (@ Cotrty sts Sugface x ~@ showlA cortYponol a au with Cech o ~~ Ss So OR Unde stendiry the steric 3 facto, Sevehah | Concepts Shout. ke tept in nund , wuita include HdLattin, free vekemeey, planes digs eb etc we have 14 bkavis Latter and 7? ve systems, To unde tand tre Suh co of “Cotedyst the concepts Ke cid, Od “f tus Chagacteniration of solic Coteyst Suiface * Corcept, of ache ant, fte velenioy ath ebcton Aeftets bees ts : le 2 pe 6, lane , in Ces Torr cape “IF % F : Simple ace Bod Conteted copie chit. Mabie 4 vr | le ‘ mn Simple Bony contend tebegonl be al hensfonal hen 7 8 4 le OMhovhomic (simple. BC» Base ants, FC). Lhowbohadgal, Monahinic (Sintple 4. Tachi rm base conta) 4 3Thene, sh Cs tals Cue hay * 6 Steble ape help in wing U Vo asbec, a=A YX: 40° Derydtagenaton of cyclohexane lathle Body nthe Facecon tea) er ani (EW) Te Olam 0-304, ea Aq 9-289 rea Og 0-260 Mask mk Oi pet ays Ack ot Pa* 0274 Lea RM eo fa” tec a-Co¥ o162 — “pe <—e faces nine “pe ane “pe . hanagoral close 9 paektie (hep) She my 0320», “pe Zr 0-312 “he o-298 Pa Ti O29) ~ 8 $276 “7S an 0k ‘3 Rut 0-166 By -Co* a2 : ie 0 24 i)4 + Metaly dnst Cotala ze phe dehychoogenstbinn of cyclone. Scierbst — staclied tant aa Close partect metala locd to Colaltre jhe regction. In dose prckieg , the is lem spaces Left, on chonulby, we eaplein ie by tdéen loorayebdn 2 . Ba AB 8 atoms are aincetty centered nr telecprp the @Vter atom So YON=8 Moge CN» mare wil be re Chole pact + Faw N= !2 untied she nal CN 212 do packirg and hep ae cose packed mae. i) con Work behar Ww & @ st. “When the bondlery th 5 blw 0276 0-24), Hern reechon (5 cg tal sect bw Hus Ire T Jetha plants mitfe atta, «surface. op cube (100) x “falace prism (0) i So, Fu* Octahedgon surface uv) Z| fal EAS i) (io) au) 6 Xuentabon of places 1m lath Ce, Pay « 2dsind=nd 7 ai How We reechon in Aiffetont pene, tae rie acknty con bo Cn t- he don Fftent: fag “Phase Con en poled Na | | Mee, named the sutfacta af oo} ete : Strauch tre Plerez AR THEY Haney telly abo fice | ON¢CN tation? ®- How tw 4et miler jn . aoe wing % epee Saystellpetld aus agg Paratlep au He af length. 24 & plane mACepts it fs Cyt te aus then Pno tou durs busy (10) ¥ tous Rulon Miller Indicer - Sedect augin - Dhaw oly luc Arey [vec tors (pple aus ) parelel. ty unit Cll Ape bapth (anal lory tho) -Find out, how naw aney/ vectors inthlepts me hagas to fh resseok - The i oh vec 1S a fedlions of be anak lerp is (factonal intercepts) / a7 Reeiphocel of factioneL “intcycopts (okies See plane mates With the ky sted ° anes) iS Miler Indicen Of the & plan® Lin small baactetr) ~&ike (O01) Atos. \ > Z E « CHC MD Sire sur Ale J exposed 1p preset and exsilg = con be - charectenved LLEED : mae » Moltucte, adhlocted on tha. Hate Con be bad oletteted . eo . 1 ena of indurbicl J Commence o4) =) cats pil Contr eupetimen te 62 ef cori = a” eoekagt ep J ne 2 pontal Memon | oh tel SOLD tuctar veroton w late “eb pat ca) plas wm more eebre pee Gen we ea hove arr Ce tebyst? woluch prolsses ee ae p loca Yop Jorn a. varity Sonu. fasrbans 0 E dol: The. repeuntsror o> Tho nam of a a TLK: ro fre ama epic tae che4S de = 1 atom * Adatom wich is on the Sut face OF Me lethee, it ha CN: 4, tots AHORA ty Lovet side. + Step adgtom + oNe 2 ° sep abm : Ne 47> 2 fe rabycen ink atom: N= 3 L free vacoencitn ? Ar a cubic sqs tem, CN=6, So > vadencita au peent im Kink atom. “SuUefawe atom : ON= 5G he ScAp - Ww or St key Doherty + tom the Aethite O% Sucface. tf Cebon # missinp, anohee pont anjon w mussre td “baling tke Oreeet, Sug fae “> b mote it neybel ve aso have imupurjtica Sou 16 Musing, Cytloact w impuckity Cw chit ge_imcpuds ey) py Frenkel Ae fect S : Jon is not lo le ty massing [ iororeal, rt is Usloce tedmt sobal ste oa Decompon tien ok UbON lacetonitila) on Ni Ua {acm vs* (io) sexface of NM bom Se a | es a ) ‘ ey I-2 ‘fe 90°). aewonpas, 6on ea dle conepesibon ta Roason ? i a " n/t j ~s _ e_hew NC -~ ae s a @ t — Se b | ea ' £, —s = (44) > ey smoot surface, So len decornpas en ws (lO) 2 it Sis S tapped sucface » £0 bal in WS coe UB vw Heh vy WV - both ate interecbrp » $0 cue bo . - Wis 1 son, more rekob'on wall OCU | > Elect and their inf Were, Stuyewt alloy Gt" Type of multiplicity fk icon ahi formegon Poltoriep metal ath ae 4ov 2s Styud7e > [ow moderate moderate. Laker ingens ple Se? Kuctute | udetare ape large ey kage sa Gn Abe sensrbreer a) Fox sbuctue sensibre, madagete che a - N (hucbare 6 surface hao I 1 : mupact on Wed ee eat : ond Ste eb beets bs -j in Sbuctuee” “sen sibie achons. c teed f you increere He surface , the coe we eho L acti noes but in st senwibre, & Crea coreletion b/w is be say and Sut-face ep t as a2 quire ‘et eee nob surface ates “pe fe cal of the be receanch iS to Ue Gath metho | wih oPptnuire the Pleduetion og YS deSireh phoauet wrth — Anetect anak PT chop rttad Crindgst: é 2 E legen ty: “pe Rolebonghy, ita Cle Stu Dome, __t Oy nt eae and the ectinity 3 in teemediotes” Sua Lone - Re we donot See 4re Luaface dra bMchue in Ra 5) We feu ann Me bee benae, ~ Strchetey. Sa Flay ; vy Ha, © Redon Coley st Vs Low'c bbyst = Ae SS a. aeT27TiV772 Catalyst - Reolon ath Conepriny of fice Solid) tet exuibit electicl zorductin ty, “9 hare mobile e7. Lome. Cgtréyyt :- ; told ev, v4 ace mnpule tos a ag arid bare cot gs ts En» ero Tt of Redon cetatysts ~ : wie b «Semicond *t : spel met/ bs J v] fonplerts ee fee” hare fee em whee ee wt increrce 1e tenepege tuxe os fe Ss fT of ionic Cotas sts SS ces (103 ma ms lassifitabon of solid state Gielysts ag MAssificabo rw oy oak x to. conde tol m3 7 a5 londucbity q-% ~ 4 Ranfe | io’ so" 102-161 | Jo" lo Denn! 2 Gncrecses withl) Yes, biw mete!| yes but at i ectvon aS di anol adsorbate hegh bmp Gel Soe e bansitben metd/ Si-G a sho Eoin ag BD Sr sulle etompl Numerdus Netalloida, _ - SHochjamaticType of e- transfer reacbons “aceptng keehons 2 &° flows Gon 2- Donor yeecbans Ce tata st & Stubs trate 2, Ctalyce Su face\e | oe SEP molewule HeGbions Subsbak is attopbet the e- 2 Colle ay alep tox donot reeobons ee A) Donok. raction 2” agg one tet by Subsbace , j~e fu bwin (Ow TE : Hy a . on on Hittin tit FF é ié ff ff “e i e S ~ (cecil?€ ~e BA ti f © 7 ) EEC Ce CELE t at lectuce # OF Electric stub, of TM:- NM nd —y dA Band The potertiof of Clecten, is chatcefen ier ° by “fermi level, 7 7 : win comespord, Seti Vy im ROM w Hy tp the a oa ee elec bone Cok i OL Sysat poterbet off eo utd ond e- holy BES, work furebon we, imeretser for ebb en gat Zn low elocboposi tre Transibon mete urth Heir & bards We i exelent cetalysts , bor ion tanght, 4 > ed J Ane clo cre Sea Wf ? wlan, tena ; acon affini ty ; elacboreptnity “& Inbrcering site Aso dlecreeien , £0 fi ppgaele to Kore. e- fom ight ide motes, al Odpitel hightd end 9 exiy by remove Tita stale = tend ty loie elecbonswin Ukt side mote 7 mode elecbo posite valor at Star Feami level:-qe (clo wo thet hav much Spe Q.wre a band 1s filed The sepats tion ep big inerBeo a Foe >@@aw Aad wor ws [eect OOOO we "He for Se, Saket bons 2O@OOo eps Ti ete ymr OO O® ‘pe A> Vornre fortu t Sco Ti v Gy mp aepton Sa ea less in Cate of ee De in? torupletiig (plled SRI atAN spo So feemi and “ope RL OF Lu | tn boun toucheg : wee at tn! de). "pe ow 7 Dep: nition = ex The poterbial enthfy of 7 4s ‘le = chee tener by fem level” Ai ¢ WR KUN = Effect of adsorption — A Wo; IC Land etion pando, function forpader ¢ [es band (90) valour birok| EF" 4) No_actoiption b) Acceptor Epi = Fema eve{ Es Feng ener pyve Wil th wren wt apply potential, e- mac fom valence pand “ty tondue bar band, netef stagts tonductrp. Q.wren lonductdr is easy? Vaknce band biggeé o& SAU ¢ Fowbidelkn band sholol be melt , re wot feinchon in metals js about “4ey” A> cep t& adiathate. whith atepts te @- fom the Cotatyst- D> DonodA aclarbate +which no e- to @ratg st: In Ce of A, the valence banc r¢ yeduted (or e7 Be taken from st wile in DP, ib inte, coz (€ UME, en tom alsorba te. dazge » b02 qo Caplgic Proper of metals |. Ro of d- band fling :- Hydrogenation of Ob fhene. Lo Relate §] Fe activity] 4 Ni 3 06 O72 OF OF Ho land f-lbingHettt? TH case 6 Fo, Coy Ni, Cu, most pig Pauling of A “ourtal is in Cu, dt ane awa minimum 1s in fe d& Me actin efremis: of} Co 1% man fo» this icecbon he d-oubrtal fLlirg Should be a. Ine din 0 dese wilt meotiv” Chemitorpbon. T° chat There Show be a cee tain bane flip. Sp cleus 2 ef te 2- Ngoogarthon “> A-chakacter. & (ignra) “s is Of seuien bon Of ethenc) we cata Danae °b. chaccctet Cea be bd vceplined bg usirg the epucbon — 3- ALL At &= no. ok bonds =x 100 es cna g boncling e~ + metallic obi taly =“ HU 7% ss has Gp Exam FA nickel »a & vale of Up: been Calelgtea and ides Vly ey 0) Haat ‘ ake found for Ru and’ Rh (507) aly ali 38 yo we od chaag ER a t : : +5 motel © bonding \ttt? lip ] fouling celeuleted the % od chagecter wal ~ (ada 2 nobel prizen 1 in fila og tutg. Sap chamistyy , an one in poe of peace ) ‘bon Sth d chats 1 rClebed to au lmoe a opbimm dna dimensions of en/t : ieopbon > wChate ctet 2 (eae conslan€ 66 cowl s. bre. Se — doueaser ) So swall Lethe >On stere — effect» so Serie factor OF Bh na) e 3 bs be iL hay high ol-chatecter, bodR i & catalyst % >e 3- Alloyin os Alloy: “D homopneous min tere of me tls ie and a= b an “9 fig: \ S Exanpleo “& 2 a) Higetiogenatin rea cions; (Donog, edorbat) ) up 8-10 of pekwodic : male (fe, Mr Triad ) Group Il me taly (C.Ag, Ac) My Mitte, Net Fe b) decomposition of Hrb2 ; (Acteptor aclson/a te) f wis tHBesa dono Hs 2 sigma don Ps — q uf te have, 1004, Ni, then if you have - I O74 Ny and 107 lau ,d band 7 oe foumed, is ol band fillipe inereele ay of dlecreeter tincrersed' < pee Tf You have’ $07 Nip 20% ke, ther 18 10OZNi hay mone 6g OL “PS end Sd 80:20» IDON; han more ple p. Thdusbial plo bly. Pe CH - CH, oe CH=CH Gags 7 "of 3n case op hydta veo eet - fo paren tig megin cae Of acteptor adfarbrte » Nit Cy Spa will OL. a Proeter coteOyst . Hide Ss is Acteptor, so more ote (Leng (eal, &s ty bet e- Sharinep: is ~F stndustyal vow to bine Rulds, dere 5 phoebe Orly Chh= Cth is foemede —~ &é— fap MOL HA? e& Hy 2 Cora adtorpate vit Aontle 3 m~, yna elocbon aensity bd motel, 30 we hare to mucese HL ol FU | bon) 3 ob & talgst 59 th cen t henson’ Gs Po fee Ry - at » Os-d® , 60 we hare to i wad at Aad to imcrcese baad A piling as . ia ep Semi conductors ‘4 Supsience thet have — Londacckanie_ “ pom 102— 1071 Ohmlemn! , e7 pansfer : maces from met > adlarbate increeSca wih ote ae Lnbinsic Atzhe [2G] Condsacbor bard X CAD bic i bE Gen be caleule tee. hole vain pad Wirt specta. ols “P ls at b but UV= WS Tr© tntnsic Semilordurtow av Tre pree form ok Sevujlorcluc Dr + Ge. at Absotute eho, OK Pent bond Bat at wom 7 the ene enough te Cen i Spar, holed ane ka ted Excitation. , _ SuPSBn C(diamed ) gr Ge_ Sn (4x24) Thee ar ob tuo types —_— <= Exntinsc Sennicorolic tory L Trrpured form (opirf) 9b mcreepe cone ne GolAS» elf Ge=We-, we cen 40 nand p doping “yp . QO hee Oa ©: » hole Cordlactty 66 Lenicorauc tors Emateton enekpy | ev a Ptpe poeeeryay at éQ.which 1) He Rat conductor? Sn Gx because Conduction bang ae. ae Smallot 2 50 1b Conoluerts easi > Babine feGins towel 14 . poinlrel et bn acceptor eed. | . Y Fegan lev fe, > Valloner banct > nae. 3 n-bype p-type > DonodX7 As > Lem > fedmilevela tes about pre pi ib « Upto donor wwe. b 1s Small when dis iq ewer donor. 15 holes intoduced introduced > & > > 5 > 5 5 > — , lectuee# IO. Tranvben Meta — based some YN PY 4 20% A ~ e _ pee Zn,,,,0 — pe Smitonduct® »Zn0 1H" Be 2ene, OF —> [ 2Zn+ Lory 2e- J “Se : ce ‘ed nef !Or et e- z ~~ P type semiconduchos , NiO Nino Se Cnebed) a) 3. yf and sulphides We Sbockiometyle Ss a Ltn bike Ss aA kel natal ae ets but “banter txy meth oxides and Si lice ARO non « Shochiome bic. The bo o pet (em) ._? "Or Bees : Go “outh ub “ee me = in } 2 ium is Sy a fo 4 Gent nf tl We hae Sy Omg MRL Znc. of ~ NW Pe seritonduertpR rruyt nave 4 e- S then motenial thet ic me ti pee fame wok 9 *asaetctd train Sip zyt's Ne “hype mepucites ad « Some 6 Wa Nj a, +3 Nyt3 9 i punt e eRebion. betes > MPUNItY So it a oP See mpi c= “ he| Gnito14 holy 2 there. ve rh how bansihon metals wich VE preeeo€ in 1ALiY Hidde | highest onudebon State, pein ouideg and © Sulphide corll uke, M bpe senutonductors. Sua % Z2n0, 2n~ is mn its hightet Of fe ¢2_ $0 16 Gon 90 & el, meeng 1b hw WM wtfpe Of nnpurita Tidz Te Oxniderbon State 0 | is the waht OS , So-it Cen be w NPY pe Serytonductor. | “Vos | ue ouidebon ste is +8, 16 iS also wtype semitondu coh. - | fe? , Mo etc con meke type Semitarduc | | CCE T Ty is 44. Hes ee (low OS metab) Nit? but 1b Con qe ® +3 So it w P wr it oe ro t +3, S80 P-type Cut! , fe2* etc Ud entonp lop on Pty pe. WONT WWE Doping in TM based semitonductors P-type: ib. same Cr) ipa ty (rN) fame watt) 2. Vw__ > lLonduchvity: ue ae decrersing tre holla So ead Conducta olf cre lea uy art € Ne Or —y Or + Vem Add CL, mi? gece tm Nite balance tre Chu Cr li) > morerser tre *ve Charge Of Srutortuctor e 4ilt) mepucrity * Lim Niu) framewack) Netto NB YO. + 2€- —7 O77 aendllciea $4_ Ds Ineree yor, cor thre holes ORR) 4 ch op the “pen, de hey, ee bel pace of *, Sito a of bust U is tt So there is a hole N-type: Zo COW impunity : Cin @ (42) famewor t) 2ntt—y Zt 0° 9. Wy On + 2e- Tote ovesedl barf. NORplea Coz of Cy ZR, 2) > Cond chy B badreg The keratin inbecre ge, Zr"! har eartya_elecbon tA, So NM Inepuarby inrreesey, type fy © bie geceecees| | » UCU inepugity Gn 2n (Il) framework ) Zt!» Zt Aa, nic Dy wack) 7 07 Wy Ort Le- d¢d¢ditdi? © 3 moc brity: Me concuctn ty decreeter ae G2 ch ig now t& UW Causey Fug Mecrerse in" tre chatee tee of Senu- Corea h., 50. It is balgnceot hes an by eth Epi. | 4 4 | hatoo el. Effect of Adsatpbon -— tet ~ tf apa is ue iieel on the Z2no, ~~ conduactiuty is lOwEeRAd be CAKE i “~- omgyer acts & an electron accep tot | Zn*t 02 Stns 0 id “ Pr Chamusoifeed badiogen acts a Ah elocbon tk) —— Aonor and Woke: the epSulctariy s pe Atcopoline te He reachon I zat sore th 22+ of Tt Zu qi aA Fox a patyge Senui consluctod Like Nii 7 + Ine ttt of ony sn by “The lathen Zp! vy 6 ‘deceived Brasans ai ~~ PUN 4 Se ANitt+ 0. —7 YM? 407> ~ “RP? cider The COMPAR bon of MH OL motoude on S39 in in leth len he boven OF O° 'ON5 39 sit Weel» bo tro foumekion of | 4 Ni? ay ions lech of wide pre nse to ® ouidor & posibre hole, whos Mobily >. valor m the lithe is tesponsy ale R oo sit He obsorred Conds Cty ey Type cond Adsoxption 06 He on NiO one nna i Hint; Ni3t > contact m3» Nao rere + ot | NP rot Hy = Mts on — hele, oereg Saag NN 0.7 Al ceptor aolSocbak - | isan aaa | GA Netype.. Oy fs Or chev Orepatave Car & philic) +1 2, hay 3 make @- 50 tb aceept fom RU, ome - be ren e- and tea ty Omari On | | | Ads 6 Se i Wi Re ineweag, Bet chin, the Came ty YALL Now we 5 he behaviour » non- SHochiomalyc Conse (OL oxide : eteC a > | & ‘ Tues ae a 3 n- type bh jons owes aes ez zZno0, (40 site ouidor wrth Ti02)Tthdr, vacant the CeOr sitet ye T4peo & ae obs 4 lowers He ee ob Lorolu clit ; ° INHER S29 nae oe 6 eondauctiu iy = louvers AM oAp bor ob nal, Ov, NLO & Cony increesey hats boy mn ok he 00 conductinty het ogeroup Realy Sis 1) Detompasstion % V20 NO —? Wo 4 Ov p-type 00r 20, N79) Feo tke hole, IncreesZ conteselSaty he LrE0S& Crdlucty 4 inCree {27 mene loners conduct as Seny Conductors and Pejr vole in(> - Ouds 4 z — eam lunes Mechanism Nr0 + C- —>» Mt Oads Sas + No —> Nit Qt e Crate ade teaminne Step) (Slow step) W042 Lod 7 Nid 7 (wOe2ZCrr02) | PLupe & | Wet Oh way Seniiton ductor is Used) \ 10 moe e- Spoon the os te i OUa maudemant: Tt happen he fein devel of ce ee omen | thet the aacetion_pa | “bo bed o fone thoy ob ote” a dor en Perents e- Gen IC Frege. te wf Wed) i and lordluetor 2) Synthesis of Q2 ne dono 70410. + 10, Misi Sen accep ton : Porar ster (9) Co + Aspe chep tm 4a, Mecho A_5 Slow, Us] = Core ca “ep Ors {eq Conds + Oia, oyddcttda? HOARE Lhe - ~ guide tion of (OQ with me tel i oni de Co tals ts Gtalyst fa Kj/mol 0 NiO () e e Ga mere seb Doped with 03m) 2 metas Noes Ho DS bp with UOX mig BO 7 etna Pa in e430 en) Ue 2 tele tite D vol Hh G20r 84 Sep ee Ss phoped wi te UOL lp) By N78 Uy! Doped puneg dacrersen Semel on moe&e Fa ln Kine hes TRE aGhON rrecheniim Cen er bom cotelyst to Claéyst for tha. 4 OT a) type 2 en Serijtonducto. onder % Support matinee ') Donok. tesctons P-type Sernitonducbors 2) Acceptar Mectors “type Ler Condtue Con - lecRe# UW Add base catelyst tokitors __ Jsoketors. niketors., not | Gk TM _semterductrs tc$4822 VE Con mosese the corduchuity by aa do ond ineatasing tentpery tute an pe ey vey =e Tis a “de lommon, hog ‘ou oat ast in edow + => pe-oh—£4 ee yar Severe OtheL ey es "39 lo: Omang ce of aA Peiod of feRiods. wel NaO. 0, Aids , SiO, POS , ete not TMs) The eagle onidyy are mmmy basic, AlL,Oz is cuephetenc end th oma BL atidic. onde, (uniting Prncuple WS aeidic. Ipagie Contep ts ) 7 ad yee oer 3 Q. How dda audity Pitene fe e omy ou ee Ot Sm gy May Ale wy > AA (A, id a Bronsted acct as ZAK, At allt Contre ey Flere suelau gig lis call Protoni orntty co) a) oe y ee UL Common jin ns ve ~~Bronsted add: It is proton donow ~ pee — kis acd: Et 1S €> par acleptr ate = Alhoz is ll, sydro hel me beng Pte attract eo didn Wal nh oy and OH Lesugy, Iho oer O- ety a fag 2 PRon Steck base 1 athacts protons eran we heet alunune at 100¢ it Couple cody Sadnyalatel 1t has Lewis ed base add bate and ink ValuynZ ob stard Bd rid Gr eluek ‘onc or Ma 2- Adoapton stumes ~ pot some basic choniiah 1-€ P if, Wh, quinine etc > cheney sopbor wee din i i i less » OMe" 7 (Bs ete aciof Cente ) are se 5 2. IR studve, on oy Alx+ =? Aint 4 Py Nosy + Py es + Ree base cormplen V Ca. lyse! (lewis aud Contes) > PRE EHHE . ® | SH > a “en ER. is prtsent %it Gh HooNe ooh on Safe ny Zonta ae ~» NOStNg A poe Se, . oy | os . OL Gf o ire 4 ory ; ty case of Sica, Bronsted! acids Redonihetes, Gd. 6 w aadie as 3 acthe acd as Gms MT Ascting oy Alurni nosilic tes tp \ oth ° ' ! Sidr), OH, -0-Si- 0- Al-—0- -0 ' ! ! my o 6 0 ay + Some Silicg js pleted b alumninds bh AL hang femal “@ op ' nd wiih Ur aah bor cobort omy PA row Rebkon. rf thong. alone’ ep Cebons ang PRabony, then an 3s a mt pom ve on Tp Ss “FH ! = one Fy jan be = AL 6 Sse AL Cesiteg Femoved i wan rag ~~ An Conbart Alo Cuhibit pen, 120» aluriinosidj PROnouiregl, 8 “ano idicgte, Cen be Op ltingd in toms 6 eMOMbeA wate gn the Sule ee S Hoot a 3 . -Sinm0-Al- Si-O NEL “3 { | L Seow na “Es / PORTE Gantt @n form a Yt bono with free ue pau ob to jon Mt a Sarms. bre, pkoton cen reeet with free Ef pair free gphbouering 0 atm So formebon oh = © parka! bind result! in & bhonsted aud antre ° . Chen lorpbon of amMMOHf{a réq HoH NH 7 =o Alc + NH3—— 0-AL—O- / So it Ulows +he Ponrounced rede 7 bronstea aid eulbrp (on adltorp ban ob uel on osilicetto to be understood we dl B - -o- AlL-O~ + Ha —a 7 OT ALO | i ° l | Debydeston of Og auic moleulty O CtHhr=CHy CHy CH2OH oe Hare Hhanal Fry CH CHOC 3CHe 6‘ Huet Cn Heel a Bo" Gb = U4 ' Hl wh = Met ef | i 4 FS My AL Pro PAL AL 8 @ Mechanism: WE > decboplile Y= OH CH =yat Ms ye Poe ete JALAL RLS we decent mechanism Choth reectants we Aoi sorp ted ) Basic Ca dees Wa y-H o oy oN aon TM = O= — Mt y Ibu | base. ata on s Hh Sk “A 0 Gn Aso het&ro. Cleave ean acidop —— 1AeedC OcielS Land Acolpol, + a (Me™ O¥] + Hx — [me =] Wak 4 oR =o- Mg ZZ sooty — + ROH —» ~ ~0-M 0- =thg Fok fro teactons Altea aig ind Te coed se | saetedndddddd i é * Active delyg e “hig ho, Lepr PRE tome RE” A-but rl aS P| why Dow. activation at higher te Ro ted >inuke ay dobry x leon, inerteses ase sbength ok m4 * . hy de ted MPD Sborf base 2 daiwa a, poker (very week pronsted G0’ Jomenrertor of butene = «photon Con be eas. RN a an removed ~ fiom a-buteng (‘0 2r-buterd mires acid Colum ar Concpared a gu te propor. oS zur Say eo u 1-propert Wa AHS wluth photon is mosey afl AAG rermoved? S chakecte, nok au’ cha ct& Uhord largin if adie @ factot) which is Store bag? (ao 7 MgO Down Ht Group, basic chatact& mrereesen Poroun sobids: Zeokitts » pore as Unf GUO ky wr th. M0 tontBining Ukeb and Ukeline art motels| | | | | | “The interion Of He pokan with Atom Std rs - Ctevas SCele dinensions are Co selec =a SUA {acer 4 “4 Cindi . Mmner poAL Stuc ture ole pen 2 on the toncposrber of weoliter. “f Say 2 Leokit vo “i . =~ qn ! fo \ © + Ty pes ALD 0 = Si -0- Al—0 = S.>0 Al rm i 2 ° i Eng -In = XS ¢ 7) Mere are porta which contain aliteli my Advant and afkeling egtth matuy Say 1. Goo = z- gh M?M%,5 [CALL dx (S02) 4- CHro) 2] oe 3. Con Sok ~~. A whore MF ond MF ate altel alteline 9 | aus eakth metal, tre indian x and denody fhe owde varabloy Loa So § i 2 {S no. 6h mole uct, of wa keg Ss t uit ob Wg aki son The Composition no SSS ee, Charectimred by the Si/ ‘BL cone So rai or by ‘ho molag Yeto (Yy t Pp 2. 5 —— aol Key Me Sidr ——____ Sidu_+ Afov P : ALO; : L 2 - have commen Ks. s + To balane We (=) ch ee © alteli moter ate. _ aie Poa, S93 ga vor A OnVUBVGwveEVVUVVYUwBYse st CEUs vod CCC CKCEE ESE .Etevtite 72: Role in cotatysis Reectant sh CInduptn at Cetaty s/s) 2 Leobites afg mai his tinguisheot ida qeorve op theY eabibes end ¢ + Typer o nq apexbere m”m 20 te, (4 & 10, 12° rps) sin inc sig , Sinte (9625 Mobil or Lerpor tabon BStartagee of wobtes i Goa rode bk; in Pheete 605 Ze PPT 4 4- Auaitg bo Hur od aids (pentasils @ Fayquts possi 6 -bigh ieee aude 4. Payreistn of Zeolites selechity YS phocluct shape eee, pe & chcmel. 3. Controlled intoxpoxtion of aad enbG poser 6 ) s- Lngexbon 0 Ceistab acbie fons lectute + OF Reanaininp OK lattices ‘to bite at plan’ a be ee = ovigin? es ca, 0). : vor ees Suge bar 7 on sidePlane A if on fom bottom es Aioar a3 € Plene B 424 0 TE ongan fiom “bettom Plene c 4 a a; © if on%n I! o i | fom bolton Plane D ayaa snc lear ern 6 0 6 | bottom Hydtoqenabon o; plea d a Hf Gs WS lam Ni Ni Wy : _ a A ELLE Sbuc tug Sens py C4 ctOn me > aes Gigi, a, do‘ne¢ wnttysect) charge Gti te plone, tg Change, eg SULfale ~s > =e bulk Sag PK interioy” SS Se ~~ bo wy Soa™~o pe — —= pe . Ni- susfacn MinG-Oy Bindi Alyse —~ a teow f angle 4 feet Bry 029r] | tose | Seevlesterp | tow A Fo3cnm Uo} lite) 123° VOL KEN bush Spe Adlorption of efrere on Nicke€ vy assagateady xg alociakin Kactent borde rerrain intact Bag C24 bards wp le Should be 1045° > hen . it meens it is wee stble Ca¥horm Ss Lf chencisqapbon rs Stor , the - Ls eet ie locore Soe ee ot oe. Ay “3 phe piped. we Use argyle te fret out : the at °6 Sh oF ts LENE Cniter. for ¢xposeo) a vaca’ CN: 5 XN -™ mM jem, LM ii tee, — Y cee nv’ Trt eess 3 ~~ \tut it > fore 100 cr Oey fee (oe onit Coy CoN) Meiqhb, Contant 12 4 | fice valeriey o q | entre active leche & hi 7 . prtn 4 fon ote may : Sem Bot 4 he faked back: a (lo) any On of . any One with bE Cleulptey = 5 7 4q Ize Textual and sbuce ARCAENLS Hoy % @ Beys bs osurkice Chage ctey istic re to AAD pop Sof 4 metened bes ila ks he he aca ye MOS Re mor its vrex uni ce Yo 4 PO Sie Cons & cha ecter saree 9 hone ss and bet Surfa ce. fece Soe _-- tele me, mye ick omy biol oy “6 urfe ap Some & le omy may \- STI : ~~ 2- Al —» oo 3- SE oO 4 TEN ™ ug 5 LE S39