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Question

Answer
Step 1
(a)

Write the expression for the fugacity coefficient of a pure gas using generalized correlations.

…… (1)

Here, , temperature is T, and gas constant is R, system pressure is P, low pressure for an ideal gas is ,
fugacity of pure species in the vapor phase is , and molar volume of pure species is .

Step 2
Write the expression of molar volume by setting the mole fraction of species 1 equal to unity.

…… (2)

Substitute the value of from Equation (2) in Equation (1) and integrate it.

…… (3)

Simplify Equation (3) and let .

…… (4)

Step 3
Express the expression for fugacity coefficient for species in the vapor .

…… (5)

Substitute the value of from Equation (4) in Equation (5).

…… (6)

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Step 4
Substitute for , for , 50 atm for P in Equation (6).

Hence, the fugacity coefficient for species in the vapor is .

Step 5
Write the expression for the fugacity coefficient of a vapor mixture using equation of state.

…… (7)

Here, mole fraction of species 1 is and volume of species 1 is .

Write an expression for extensive volume.

…… (8)

Here, constants for species 1, 2, and 3 are respectively.

Differentiate Equation (8).

Step 6
Substitute the value of in Equation (7).

…… (9)

Integrate Equation (9) to find

…… (10)

Step 7
Substitute for , for , 50 atm for P in Equation (10).

Hence, the fugacity coefficient of species in the mixture is .

Step 8
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4/8/2021 https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhd…

(b)

Write the equilibrium state for vapor and liquid.

Calculate the fugacity coefficient for species in the vapor.

…… (11)

Here, mole fraction of vapor species 1 is .

Rearrange Equation (12) to find .

…… (12)

Substitute 15 atm for , 0.93 for , and 50 atm for P in Equation (12).

Hence, the mole fraction of vapor species 1 is .

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