Holcim Supplier: Name: Holeim (Us) Inc. ‘Address: 201 Jones Road Waltham, MA 02451 Telephone: __ (781) 647-2307 Material: Section | — Identification MATERIAL SAFETY DATA SHEET Portland Cement Emergency Contact Information: (CHEMTREC) Health 1-800-424-9300 ‘Transportation 1-800-424-9300 many products, Individual constituents wil vary. Product Codes: Portland Cement Type I 1A, I A, Il IIA, IV, IVA, V, VA, White Cement. CSA Type GU, MS, HE, LH, HS. This MSDS covers (aypsum), Formula: This product consists of finely ground Portland cement clinker mixed with @ small amount of calcium sulfate Chemical Fam the majority ofthis produet hemical compounds. Calcium silicate components and other calcium compounds containing iron and aluminum make up Hazardous Ingredients Chemical Name and Synonyms: Portland cement. Portland cement is also known as hydraulic cement Section Il - Components ‘Component (%) ‘CAS No. ‘OSHA PEL (8-hour TWA" ‘ACGIH TLV Porland cement (100) 5907-154 15 magi (7) 5 mel (A) None “Tr-calcium silicate (20-70) 12168-853, 18 magi? (1); mglm? (R)® None? Di-caleium slicate (10-60) 10034.7-2 15 mgin® (1), 5 moi (Ry None? TTetra-calolum- aluminoerrite | 12068-36-8 18 mgimn® (1); mgim® (R)* None? 618) Gypsum (Calcium Sulfate)" 19997-24.5 15 mlm’ (7); 5 mol’ (R) 40 mgim* (7) 210) ‘Tr-caoium Aluminate (1-18) 12042-78-3 45 malin? (7); § mol? (Ry None? Limestone (Calcium 1917-663 15 majtn® (7); 5 mol (R) 40 mgim* (7 Carbonate (0-20 eae a Magnesium oxide (0-4) 1308-48-4 48 mgt? 40 magi? () Nuisance Dusts (Particulates None 415 malin® (7); § mel? (Ry None’ not otherwise regulated) Crystalline Siica (Quartz)* 14808-60-7 | 10 malin? (R) (percent slica +2) 0.025 mgim*(R) 1) 30 mg/m? (7) (percent siica + 2) symbology Uso: ()= Measured a inhalale faction of the aerosol (S08 2010 ACGIH-TLV Booklet fr Adiional Information) Revision Date: February 24, 2077 's Paulos Not Oherviso Rogualed (PNOR); or ACGII's Parculaes Nol Otherwise Classifed (PNOC) (©) = Forparteuiate mater conaining no asbestos and <1% crysalin sic, Trace constituents: Cement s made from materials mined from the eat end processed using energy provided by fuels, Adional matrias, such as {iy ash, kn dus and slag may also be Introduced into the cement manufacturing proces. A chemical analysis of cemeni may reveal Wace amounis of ‘naturaly occuring but potently harefUl chemical compounds such a ree crystaline slic, organic compounds, petassium and sodium compounds, heavy metals including cadmium, chromium (cluding hexavalent chyomlu),rikel andlead. Other Wace constiuarts may Include calcum od (also ‘own ata Ime or quick ime) and organic compounds frm grinding ads suchas amine acetate als, lols and 1,2-eaneo, * Us, Occupational Safty and Heath Adminstatlon (OSHA) pais exposure mis (PELs) ar bases en Occupations Stay and Healt Standards (20 (GF 1910-1000-1052)estatshe a the me Us MSDS Was lst upieg * american Conference of Goverment nua Hygienists (ACGIH) tveshol it values (TLV) were taken fom the 2010 publication ofthe Guo fo ecupatona Exposure Valves etabished a ne Ue Dis MSOS was as updated. Ary component wih ne deed TLV delgat Is ated as “none Osi standards 28 CFR 19101000 Tale 2-1), defined thasecomeonans as et cr nusance cuss, whethor mineral, oan, o organ, rt sted speatcaly by substance name In Tale Z-1 ar covered by PNOR at Which fo sare a the neo ulsance dua ilo Table Zot ACGIH as PNOC. This product and various fomulalion of is generic component ae ls known by various synonyms si ate asignd varius CAS numbers, Ths MSOS does ot attr tit apostle syeonyms, choral formulatons or utp CAS nurbor assigned to subancos ns calgary of compounds. 5 The Nationa sta for Oceuptiona Safely and Heals (NIOSH econmend exposure im (REL) fe based on tme-welghed average (TA) concentration for up ia 1oour workday during a 0-nour workwook Fortis cherical NIOSH REL i 00s mgm respvable quart Jus Page 1 of 4BSS CTL Uke RCCL lily ‘Emergency Overview. Parland cement fs ight gray, off white or white powder that poses lite immedite hazard. It isnot combustible or explosive ‘Acingle short-term exposure fo he dry powder not tely to cause serous harm. However, exposure of euficient duration to weet potand cement can cause serous, potential meversbie seve (ekin or eye) destruction n the form of chemical (east) burns, ‘The same type of bssue destruction can oocur i wel of most area ofthe body are exposed for sufiient duration to dry potland cement. Porland cement contains Wace amguns of hexavalent chromium which has an OSHA Permissible Exposure Limit (PEL) (8-hour time weighted average) of 5 pg/m’, an OSHA Action Level of 2.5 igi’, and an ACGIH TLV of 10 g/m’. Potential Health Effects + Relevant Routes of Exposure: Eye contac, skin contac, inhalation, and ingestion + Effects resulting from ey e contact: Exposure to atorne dust may cause Immediate or delayed ination oF inflammation. Eye contact wih larger amounts of dry powder or splashes of wel Portand carent may cause eflecs ranging from moderate eye ination to chemical burns and bindness. Such exposures require immediate frat aid (e0e section IV) and medical atention to Prevent signieant damage tothe eye. + fects resulting fom skin contact: Discomfort or pein cannot be reled upon to alert a person to a hazardous skin exposure Consequently, the only effecive means of avolting skin inury of less involves minmizing skin contact, pateualy contact wth ‘wet coment. Exposed persons may nt fel disconton unt hrs afer the exposure has ended and significant injury has occed Expose to dry Portland cement may cause drying ofthe skin with consequent mi rtaion or more significant effects atrbutabie to aggravation of other condone, Itant dermatiis may be caused by the physleal properies of cement including aka and Abrasion. Dry potland cement contacting wet skin or exposure to mols of wet pottand cement may cause more severe skin fetes ncuding thickening, eracking or fssuring ofthe skh. Prolonged exposure can cause severe skin damage inthe form of (caustic) chereal bums. Some Inchiduais may exhibt an allege response upen exposure to porland cement, possibly de to {race amounts of comium. ‘The response may appear in @ variety of forms ranging fom « mid rash to severe skin ulcers, Persons already sensitized may react to the fst contact wih te product. Other persons may experience this effect ater years of contact wth portand cement products, + Eifects resutng rom inhalavon: Portland cement may contain vace amoun's of fee cvstaline slice. Prolonged exposure to resprable fee crstaine silea can aggravate olher ung condiions and cause slicosis, a deablng and potertaly fatal lung Gsease andlor other dueases,_ Risk of jury or csease depends on duralon and degree of exposure, (Also see “Carcinogenie polenta’ below.) Some studies have shown thal exposure to respirable crystaline slica (without slicosi) ofthat the disease Silicosis may be associated with the increased incdence of several autoimmune disorders ach es scleroderma (thickening ofthe skin), systemic lupus, enthematosus, yheumatod aris and deases affecing the Kidneys, slicosis creases the risk of {uberoulosis and some studies have shown an increased incidence of chronic Kidney disease and and-elage renal disease In Workers exposed to respirable crystaline sllca, Exposure lo Poland cement may cause iain fo te moist mucous membranes ofthe nose, threat, and upper respiratory system, K may also leave unpleasant Geposts in the nose + Btfets resulting from ingestion: Ahough small quanttes of dust ae not known to be harmful effects are possible it targer uanties are consumed. Porland cement shoul not be eaten + Carcinogen potenti: NTP, OSHA, oF IARC has not lsted Portland coment as a carcinogen. it may, however, contin trace ‘amounts of substances Ited as carcinogens by these organizations. Crystaline sllea and hexavalent chomium which may be presen! in portané cement in small amounts, have Been listed by |ARC and the NTP as a known human carchogen (Group I + Mocical conditions which may be aggravated by inhalation or dermal exposure Pre-existing upper respiratory and lung diseases ‘Unusual (hyper) sensitivity to hexavalent chromium (chromium’®) salts, Sod cizal Eyes. Immediately fush eyes thoroughly with water. Continue flushing eye for atleast 15 minutes, including under li particles. Call physician immediatly, ‘Skin: Wash skin with cool water and pH-neutral soap ora mild detergent. Seek medical treatment in all cases of prolonged exposure to wet coment, wet cement mixtures, wet concrete liquids from fresh cement produc, or prolonged wet skin exposure to dry coment Inhalation of Airbome Dust: Remove to fresh air. Seek medical help f coughing or other symptoms do nat subside. (Inhalation of gross ‘amounts of portland cement requires immediate mecical attention) Ingestion- Do not induce vomiting. If conscious, have ine vitim drink plenty of water and call a physician or poison contol immesiatey. Section V - Fire & Explosion Data Flash point: ‘None ‘Autoignition temperature: ‘Not Combustibie Lower Explosive Limit ‘None Upper Explosive Limit ‘None Extinguishing media ‘Not Combustible Unusual fie & explosion hazards ‘None Hazardous combustion products: ‘None Special fie fighting procedures: None. (Although portiand coment poses no freelated hazards, a self-contained breathing ‘apparatus Is recommended to limit exposure to combustion products when fighting any fre.) Page 2 of 4Erol Ce eee od Collect dry material using a sco0p. Avoid actions that cause dust fo become aborne. Avoid Inhalation of cust and contact with skin Wear appropriate personal protective equipment as described in Section Vil Scrape up net meteral and place in an appropriate container. Aw the material o "dry" before disposel. Do not attempt to wash portland cement down drains. Dispose of waste material according to focal, state, and federal regulations. Section Vil - Handling & Storage Keep portiand cement dry until used, Normal temperatures and pressures do not affect the material. Prompily remove dusty clothing or clothing which Is wet with cement ids and launder before reuse, Wash thoroughly after exposure fo dust or wet cement mixtures oF fulds, Section VIII - Exposure Control/Personal Protection ‘Skin Protection: Prevention fs essential to avoiding potertialy severe skin inury, Avoid contact with unhardened wet portland cement products. If contact occurs, prompily wash affected area with soap and water. Where prolonged exposure to unhardened portland ‘cement products might occur, wear impervious clothing and gloves to prevent skin contact. Where required, wear sturdy boots that are Impervious to water to eliminate foot and ankle exposure. Do not rely on barrier creams; barrier creams should not be used in place of gloves. Periodically wash areas contacted by dry portland cement or wet cement or concrete with @ pH neutral soap. Wash again at the end of the work. Ifinttalion occurs, immediately wash the affected area and seek treatment. If clothing becomes saturated with wet conerete it should be removed and replaced with clean, dry clothing Respiratory protection: Avoid actions that cause dust fo become alrbomme. Use local or general ventlation to control exposures below applicable exposure limiis, Use NIOSH/MSHA-approved (under 30 CFR 11) or NIOSH-approved (under 42 CFR 84) respirators in poorly ventilated areas, if an applicable exposure limit is exceeded, or when dust causes discomfort or intation. (Advisory: Respirators fd fitere purchased ater July 10, 1998, must be cerliied under 42 CFR 64,) Respirators should be used in accordance with the OSHA Rospiratory Protection Standard, 29 CFR 1910.134, Ventilation: Use local exhaust or general dilution ventilation to control exposure within applicable limits. Eye Protection: In conditions where user may be expased to splashes or putts of cement, wear safety glasses with side shields or goggles that meet the ANSI 287.1 standard. In extremely dusty or unpredictable environments, wear unvented or indirectly vented goggles to avoid eye iitation oF injury. Contact lenses should not be worn when working with portiand cement or fresh cement products. Section IX - Physical & Chemical Properties Appearance! Gray, off white or white powder Vapor Pressure: ‘Not applicable Odor [No distinct dor \Vapor density Not applicable Physical state: Solid (gourier) Boling point ‘Not applicable (L.., > pH (in water) t2t0 13 000°C) Solubily in water: Slighty (0.1 fo 1.0%) Meting point: ‘Not applicable (Non Evaporation Rate: ‘Not applicable combustible ‘Specific gravity (H20 = 1.0) 3.15 EST eS CDN RCE Stablly: Stable Incompatbilly: Wet portland coment is alkaline. As such ts incompatible wih acids, ammonium sats, and aluminum metal. Coment dissolves n hydrofuri act, producing corsive silicon totratuoride gas. Conelions te avoid: Unintentional contac wth water. Hazardous decomposition: Willnot sponteneousty occur. Adding water produces (caustic) calcium hydroxide as a rst of hydration Hazardous polymalzaion. Will nal occur Section XI - Toxicological Information Fora description of avaiable, more detailed toxicological information, contact Holt (US) Inc. (in Section 1) Section XII - Ecological Information Ecotoxicty: No recognized unusual taxialy to plants or animals Relevant physical and chemical properties: Sea Saations IX &X Disposal Dispose of waste material according to local, state, and federal regulations. (Since portiand cement is stable, uncontaminated material may be saved for future use.) Dispose of bags in an approved landfil or incinerator o o i o 3 x Page 3 of 4Hazardous materials description/proper shipping name: Hazard class: Identification class: Required label text Hazardous substances/reportable quanties (RQ) Section XIV - Transportation Data Portland cement is not hazardous under U.S. Department of Transportation (O07) regulations ‘Not applicable ‘Not applicable ‘Not applicable ‘Not applicable Section XV - Other Regulatory Information ‘Status under USDOL-OSHA Hazard Communication Rule, 29 CFR. 910.1200: Status under CERCLA/Supertund, 40 CFR 117 and 302: Hazard Category under SARA (Tite Il), Sections 311 & 312: ‘Status under SARA (Tite Il) Section 313: Status under TSCA (as of May 1997) ‘Status under the Federal Hazardous Substances Act ‘Status under California Proposition 65: PPorland coment is considered a ‘hazardous chemical” under this regulalion, and should be pat of any hazard ‘communication program. Not listo. Portland coment qualffes as @ “hazardous substance" with dolayed health effects Not subject to reporting requirements under section 313. ‘Some substances in portland cement are on the TSCA Jnvantory ist. Portland coment isa “hazardous substance” subject to ‘statutes promulgated under the subject act. Portland cement contains chemicals (crystalline slica and trace metals) known to the State of Caliiomia fo cause ‘cancer, bith defects or other reproductive arm. California Jaw requires the manufacturer to give the above warning in the absence of defilive testing (0 prove that the defined risks do not exist. Status under Canadian Environmental Protection Act Not sted. Workplace Hazardous Material Infomation System (Canada): Portland cement is considered fo be a hazardous material under the Hazardous Product Act as dofined by the Controlled Products Regulations (Class & - Corrosive ‘Materiel and is therefore subject tothe labeling and MSDS requirements of the Workplace Hazardous Materials Information System (WHIMS). Tse PAA el iia elect Revision Date: February 24, 2011 Reviewed by: James Joyoe, Corporate Manager ‘Occupational Health, Safety, and Securily Approved by: Russell Wiles, Senior Vice President Human Resources ‘Other important information: Portland cement should only be used by knowedgeable persons. While the Information provided in the ‘material safely data sheet s believed to provide @ useful summary ofthe hazards of portland cement as its commonly used, the sheet ‘cannot anticipate and provide all ofthe information that might be needed in every situation. Inexperienced product users should obtain proper training before using this product. ‘A-key to using the product safely requires the user to recognize that portland cement chemically reacts with water, and that some of the Intermediate products ofthis reaction (Hat is, those present while @ portland cement product is "setting") pose a more severe hazard than does poriand cement ise. These hazards include potential injuries to eyes and skin, ‘The data furnished in this sheet do not address hazards that may be posed by other materials mixed wit portiand cement to produce Portland cement products. Users should review other relevant material safety data sheets before working wit this porland cament or vith portland cement products, including, for example, portiand cement concrete, SELLER MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THERE OF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY HOLCIM (US) INC., EXCEPT THAT THE PRODUCT SHALL CONFORM TO CONTRACTED SPECIFICATIONS, Page 4 of 4