Chemistry Practice Paper Chapters- All Std 12 Date:31/03/21 100marks Board practice Test ‘Time-03 Hours Section A. © Choose correct answer from the given options. [Each carries 1 Mark] [50] 1. The melting points of ionic solids are 10. a (A) Normal (B) Very high (©) Abnormal (D) Low In a cep arrangement, atoms A are present at corners and B are at face-centred. If two atoms from the corners are missing, the formula of the compound will De ...u.- A) AB, (B) AB, (C)A,Byy (D) AB, FexO contains one Fe(lll) for every three Fe(II). What is x ? 2 8 3 5 wa Bs OF O35 Sodium metal exists in bec unit cell. The distance between nearest sodium atoms is 0.368 nm. The edge length of unit cell is... (A) 0.368 nm (B) 0.184 nm (© 0425 nm (D) 0575 nm Pickup the correct formula of potash alum. (A) K,S0, Al(S0,)3° 24 H,0 (B) K,S0, Al(O,)2° 24,0 (© K,SO,-Al,(SO,)3° 12 H,0 (D) KO, Al(S0,), 12,0 The total pressure for volatile components A and B is 0.02 bar at equilibrium, If the mole fractions at component A is 0.2, then, what will be the partial pressure of component B ? (A) 0.02 bar (B) 0.04 bar (©) 0.016 bar (D) 0.2 bar What will be the osmotic pressure of 5 % W/V sugar solution of 150°C temperature ? (A) 5.07 atmosphere (B) 5.70 atmosphere (C) 7.5 atmosphere __(D) 3.55 atmosphere ‘An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels becaust (A) it gains water due to osmosis. {B) it loses water due to reverse osmosis. (© it gains water due to reverse osmosis. {D) it loses water due to osmosis. Which of the following aqueous solutions should have the highest boiling point ? (A) 1.0 M NaOH (B) 1.0 M Na,SO, (©) 10M NH,NO,; —(D) 1.0 M KNO, Standard reduction potential of half-cells are given as follows Zn?* + 2e- > Zn, E° = -0.76V Fe® + 26> > Fe, E? = -0.44V What is the emf of following reactions ? Zing) + Fe(agy* > Zag"? + Fees (A) -1.20V (B) +1.20V (©) +0.32V (@) -0.32V What is the ratio of Al, Cu and Na when 3F current is pass through different electrolytic solution of molten Al,0g; aqueous CuSO, and molten NaCl ? (A) 3:4:6 (B) 2:1:6 (© 3:2:1 (D) 2:3:6 Electrode potential for Mg electrode varies according to the equation : 059, Eyez ang = BS eng, ~ 22 tog ig?tiag = Pxie2tiig 2 8 Mg?) ‘The graph of Ey26)yyg logiMg’") is t + 5 z ws B® 4 a Ra13. 4 16. 7. 18, 19. 20, 2, 2B. loging!) > loging?) > ; é {J IN oO4 ™ 4 Tog ToT Using the data given below find out the strongest reducing agent. 2° coe FSot teats 7 158V5 BG, gy 7 1860 FO yy S1SIV; Eo, = -0.74V ‘an ce or (a) Cr (B) Cr (©) c+ (D) Mn?* What is the SI unit of reaction rate ? (A) mol sec"? (B) mol m- sec? (©) mol dm sec (0) mol lie In the presence of a catalyst, the heat evolved or absorbed during the reaction ..... (A) increases (B) decreases (© remains unchanged (D) may increase or decrease Rate law for the reaction A + 28 — C is found to be Rate = k [AI[B] Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be (A) the same (B) doubled (© quadrupled (D) halved Which of the following process does not occur at the interface of phases ? (A) Crystallisation (B) Heterogeneous catalysis (©) Homogeneous catalysis (D) Corrosion Method by which lyophobic sol can be protected. (A) By addition of oppositely charged sol (B) By addition of an electrolyte (© By addition of lyophilic sol () By boiling Which of the following is an example of emulsion ? (A) Fog (B) Cheese (©) Smoke (D) Butter Which of the following is not a favourable condition for physical adsorption ? (A) High pressure (B) Negative AH. (©) Higher critical temperature of adsorbate (D) High temperature Zone refining is based on the principle that... (A) Impurities of low boiling metals can be separated by distillation. (B) Impurities are more soluble in molten metal than in solid metal. (© Different components of a mixture are differently adsorbed on an adsorbent. (D) Vapours of volatile compound can be decomposed in pure metal. Extraction of gold and silver involves leaching the metal with CN ion. The metal is recovered by (A) Displacement of metal by some other metal from the complex ion. (B) Roasting of metal complex. (© Calcination followed by roasting (D) Thermal decomposition of metal complex. Which of the following are peroxoacids of sulphur ? (A) H,SO, and H,S,0, (B) H,S0, and H,S,0, (© H,S,0, and H,S,0, (D) H,S,0, and H,8,0; Which of the following is isoelectronic pair ? (4) ICL, Clo, (B) BO; , Br} (© ClO,, BrE (D) CN, 0,26. 2m. 29, 31. 32. In the preparation of compounds of Xe, Bartlett had taken O} [PtF,I” as a base compound. This is, because . (A) Both O, and Xe have same size. (B) Both O, and Xe have same electron gain enthalpy. (© Both ©, and Xe have almost same ionisation enthalpy. (D) Both Xe and O, are gases. Electronic configuration of a transition element X in (+3) oxidation state is (Ar]3d°, What is its atomic number? (A) 25 (B) 26 © 27 (D) 24 Which of the following is diamagnetic ? (a) Cu (B) Zn** (©) Co* () Ni Which of the following complex does not show geometrical isomer ? (A) [CrOX,)* {B) [Co(NHy)3(NO,)3) (©) (Co(NH,),ClJ* ——(D) [Fe(NH}(CN),]- A chelating agent has two or more than two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent ? A) S,0%- (B) Oxalato (© Glycinato (D) Ethane-1,2-diamine ‘The major product in the given reaction will be.... Br cH, I I CHy-CH-CHCH +CHty- C-O"K* —> CH (A) CH, - CH = CH - CH, (®) CH, = CH - CH, - CH, (© GHy-GH-cH,~CH, 0 nyc-Lcny ay CH,-CH-CH;CH are formed in | equal amounts. ° (D) CH, - CH = CH - CHy and ,c--cH, cH, In which of the following molecules carbon atom marked with asterisk (*) is asymmetric ? ho oR ff roa roa on SoCs HcHs Br Br Hs CoHs ow ww A) ©, Gi, (ii), (iv) 8) @, Gi), Gil) ©) Gi, Gid,tiv) @) @, Gi, Gi What is ‘A’ in the following reaction ? +HCI—>A a, cy) @)3. 37. at. 1H, - CH- CH © ) Arrange the following in decreasing order of their Sy2 reactivity : @ Oeen,a Gi) (E> c=crtcxy,— ch (i) HC = CH_-CH,~ Cl (iv) CH,CH,CH,CL ) Gv) > Gi) > @ > Gi ®) (> (> Gi) > Gy (© @> Gi) > Civ) > Gi) ©) Gii)> Gi) > @> Ww The alkyl halides are best prepared from ... (a) Alcohols (B) Alkenes (© Ethers (D) Alkanes OH + (CH,CO),0 NaOH, x; what is x ? (A) Phenyl acetate (B) Phenyl benzoate (C) Phenoxy benzene _(D) Toluene CH,CH,OH can be converted into CH,CHO by . (A) Catalytic hydrogenation (B) Treatment with LiAlH, (©) Treatment with pyridinium chlorochromate _(D) Treatment with KMnO, Which of the following species can act as the strongest base ? “0. (A) °0H (B) SOR (C) °0C,H; () iv How many alcohols with a molecular formula C,H,,0 are chiral in nature ? al B)2 3 4 Addition of water to alkynes occurs in acidic medium and in the presence of Hg2* ions as a catalyst. Which of the following products will be formed on addition of water to but-I-yne under these conditions. Op i i IL (A) CH-CH;-CH)- C-H (B) CHy~CHy~ C-CHy i i i (©) CH ~CH - C -OH + CO, (D) CH3-C-OH+H-C-H In Clemmensen reduction carbonyl compound is treated with .. (A) Zine amalgam + HCl (B) Sodium amalgam + HCI (© Zine amalgam + nitric acid (D) Sodium amalgam + HNO, Which product is formed when the compound ©py-eno is treated with concentrated aqueous KOH solution ? ‘ z w BO )-cho ® Cr s0-08° 4 Oren ° 9 + +. + Ts + © BC )-C-oK'+ BC )-ok o pes + Ops Which of the following is the correct order of acidic strength ? (A) CH,COOH > CICH,COOH > Cl,CHCOOH > Cl,-C-COOH (B) Cl;-C- COOH > Cl,CH- COOH > Cl-CH,COOH > CH,COOH (©) CH,COOH > Cl,-C- COOH > ClCH: COOH > Cl-CH,COOH (D) CH,COOH > CICH,COOH > Cl,- CH COOH > Cl,-C- COOH43. 47. 49. 1 Which of the following is a 3° amine ? (A) 1-methyleyclohexylamine (B) Triethylamine (O tert-butylamine (D) N-methylaniline Amongst the following, the strongest base in aqueous medium is ... (A) CH;NH (B) NC ~ CH,NH, (© (CHy),NH (D) gH; - NH - CH, ‘The source of nitrogen in Gabriel synthesis of amines is . (A) Sodium azide, NaN. (B) Sodium nitrite, NaNO, . (© Potassium cyanide, KCN (D) Potassium phthalimide, C,H,(CO),NK ‘The best reagent for converting, 2-phenyl-propanamide into 1-phenylethanamine is (A) excess H,/Pt (B) NaOHIBr, (©) NaBH,/methanol —_(D) LiAlH,/ether Which of the following pai represents anomers ? cHO CHO CHO cHO H OH OH #1 7 ‘OH HO a OH HOH H AG HOR oa H OHH OH 1H OH HO W () H——0H HH —0H By. OH HO H CHLOH CHOW (CH,OH CH,OH H- OH HO: H H OH HO, H iH. OH i OH H. oH | HO H HO: HO HO. Ho HO: HO oH OH H- OH H- ‘OH H OH | HO H | © 4 in Oy H CHLOH CHLOH CH,OH CH,OH Nucleic acids are the polymers of .. (A) Nucleosides (B) Nucleotides (©) Bases (D) Sugars The total number of chiral carbons in cyclic structure of glucose is / are = we (B) 3 o4 5 DNA and RNA contain four bases each. Which of the following bases in not present in RNA ? (A) Adenine (B) Uracil (© Thymine (D) Cytosine Section B Write the answer of the following questions. (Each carries 2 Marks} 16) If the radius of the octahedral void is r and radius of the atoms in close-packing is R, derive relation between rand R. Arrange the following metals in the order in which they displace each other from the solution of their salts. Al, Cu, Fe, Mg and Zn. A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is (i) doubled (ii) reduced to half ? Why is adsorption always exothermic ? In what way is the electronic configuration of the transition elements different from that of the non- transition elements ? Giving examples, differentiate between ‘roasting’ and ‘calcination’ ‘The two strands of DNA are not identical but are complementary. Explain Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.10. u 12, 13. 4 7. 18, [Section C Write the answer of the following questions. [Each carries 3 Marks] 1s) Out of C,H,CH,Cl and C,H,CHCIC,H,, which is more easily hydrolysed by aqueous KOH. Calculate packing efficiency in body-centred cubic structure CCloulate the cell potential for Qu plate kept in 02 M CuSO, solution. (E+ q,2+ = 034V] Explain giving reasons : () Transition metals and many of their compounds show paramagnetic behaviour. i) The enthalpies of atomisation of the transition metals are high. ‘Transition metals and their many compounds act as good catalyst. Draw the structures of optical isomers of : @ (Ce(C,04),1° i) [PtCl,(en),]?* (iii) (Cr(NH,),C1,(en))* Draw the structures of major monohalo products in each of the following reactions oH @ Cy +S0Cl, ——> cH heat O + Be. “Gv light” Write the answer of the following questions. (Each carries 4 Marks] 16) [Section D How many mL of 0.1 M HCI are required to react completely with 1 g mixture of Na,CO, and NaHCO, containing equimolar amounts of both ? In a reaction between A and B, the initial rate of reaction (ry) was measured for different initial concentrations of A and B as given below A/mol 1! 0.20 0.20 0.40 Bimol L7 0.30 0.10 (0.05 ry mol Ls [5.7 x 10° [5.07 x 10% [1.43 x 104 What is the order of the reaction with respect to A and B ? On heating compound (A) gives a gas (B) which is a constituent of air. This gas when treated with 3 moles of hydrogen (H,) in the presence of a catalyst gives another gas (C) which is basic in nature. Gas C on further oxidation in moist condition gives a compound (D) which is a part of acid rain. Identify compounds (A) to (D) and also give necessary equations of all the steps involved. Explain the following terms with example. () Bidentate ligands (ii) Tridentate ligands (iii) Tetradentate ligands (iv) Pentadentate ligands