8 Thermodynamics ~ | KerchofTs equation ze) Deve showing variation ont of entaipy of reaction with temperature ‘ (0) Colcstete the percentage Mydrotysis of socum acetate in 0.1 N schition at 25 °C trom the following ky gate cosurning Tat the nat a completely diasocisted Dissociation covaten of ; i an 118010", tonic product of water = 1.02 « 107" sociation constant of acetic ackd st 26 °C = “ya! a2 Denve any two of the following thermodynamic retatons % ¥ 5 = nk? ta 2 — a” % ™, Roe) (8) +2 . @cr ar), (ler), omy " ‘ om aS =Cy = ~aS Multiple Choice Questions ' o 4, According to the second law of thermodynamics heat is partly converted into useful work and part of it (a) becomes kinetic energy —_—_(b) become electrical energy (c) 8 eiways wasted (@) None 1. itis impossible to reduce the temperature of any system to absolute zero by any process, The statement * (a) Zero law of thermodynamics (©) First law of thermodynamics {c) Second law of thermodynamics (4) Third law of thermodynamics 3. An isolated system is one which can exchange (@) Energy but not matier with the surroundings —_(b) Matter but not energy with its surroundings {c) Neither energy nor matter with its surroundings (d) Both energy and matter with ite surroundings 4. When a gas is subjected to adiabatic expansion, it gets cooled due to (a) Falls in temperature (©) Decrease in velocity (c) Energy used in doing work — (d) Loss of kinetic energy 5. ina adiabatic process (a) P ressure is maintained constant — (b) The gas is isothermally expanded (©) There is perfect heat insulation _(d) System exchanges heat with surrounding 6. The temperature of the system decreases in an (a) Adiabatic expansion (b) Isothermal expansion (0) Adiabatic compression () ‘compression 7. An ideal gas is allowed to expand under adiabatic conditions, What is zero for (@) AS=0 ©) aG=0 (©) aT =0 (@) None 5. The heat change in a chemical réaction at constant pressure is @aw . AE © Pay @ As : eel such a process ?(nance of he reactants £06 OUI. (2 Fras and final entaipy change of he rwecton {@ Ctierert intermediate e9cors 2 a , Mer. 1216 (ch, Ste), (a). 71d). 4a). ).. 10%) 2a6 Wer. 20, He) Mi 48{a), 19(0), 20(0), 241c), Z2tp), 2c) 4Hia), 1540), 164C), 1718). ‘2Bic), 27%), 2816), 29), wid)