Ep 1

ln ( k 1 ) p=lnA −
R T
r =(k 1) p p H (1) 2

r =(k 1)c C H 2

−E c

(k 1)c = A c e RT

d (ln ( k 1) c ) −Ec
=
1 R
d( )
T
pH
CH = 2

2
RT
(k 1 )c
r= p (2)
RT H 2

( k 1 )c =( k 1 ) p RT ( 3 )

Diferenciando logarítmicamente:

d (ln ( k 1) c ) d (ln ( k 1 ) p ) d (lnT )

= +
d ( T1 ) d
T
1
( ) ( )
d
1
T
−Ec −E p
= −T
R R
Ec =E p + RT