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Bio-based Building Blocks and

Polymers in the World


Capacities, Production and Applications:
Status Quo and Trends towards 2020

PP EPDM PE
PVC
PET
Propylene MEG
PBAT PMMA PBT PU
Vinyl Chloride Ethylene Teraphtalic acid
SBR
PET-like
Methyl Metacrylate
Ethanol p-Xylene
PU
Sorbitol Isobutanol THF PBS
Isosorbide PEF
PC
Glucose
PHA 1,4 Butanediol
1,3 Propanediol

PTT Lactic acid Succinate


Adipic Superabsorbent Polymers
PLA
Acid Starch
Saccharose 3-HP
HMDA
PU Lysine Lignocellulose
Acrylic acid
Natural Rubber
PA Caprolactam
Plant oils
Fructose

Glycerol Fatty acids


HMF

FDCA

Epichlorohydrin

Polyols Diacids (Sebacic acid) Other Furan-based polymers


Natural Rubber
Starch-based Polymers
Lignin-based Polymers
Cellulose-based Polymers
PHA
Epoxy resins PU
PU PA

Authors: Florence Aeschelmann (nova-Institute),


Michael Carus (nova-institute) and ten renowned international experts
This is the short version of the full maket study (474 pages, 3,000 €).
Both are available at www.bio-based.eu/markets.
Bio-based Building Blocks and Polymers in the Worldwww.bio-based.eu/markets www.bio-based.eu/markets Bio-based Building Blocks and Polymers in the World

Bio-based polymers – Production capacity will triple from 5.1 million tonnes in 2013 to 17
Imprint Order the full report million tonnes in 2020. Bio-based drop-in PET and the new polymers PLA and PHA show the
fastest rates of market growth. The lion’s share of capital investment is expected to take place
Bio-based Building Blocks and Polymers The full report can be in Asia. The 5.1 million tonnes bio-based production capacity represent a 2% share of overall
in the World – Capacities, Production and ordered for 3,000 € structural polymer production at 256 million tonnes in 2013. The bio-based polymer turnover
Applications: Status Quo and Trends toward plus VAT at was about €10 billion worldwide in 2013.
2020 www.bio-based.eu/markets
Two years after the first market study was The nova-Institute carried out this study in
Publisher All nova-Institute graphs can be downloaded released, Germany’s nova-Institute is publishing collaboration with renowned international experts
Michael Carus (V.i.S.d.P.) at http://bio-based.eu/graphics/#top. a complete update of the most comprehensive from the field of bio-based building blocks and
market study of bio-based polymers ever made. polymers. The study investigates every kind
nova-Institut GmbH All European Bioplastics graphs can be This update will expand the market study’s range, of bio-based polymer and, for the first time,
Chemiepark Knapsack downloaded at including bio-based building blocks as precursor several major building blocks produced around
Industriestraße 300 http://en.european-bioplastics.org/press/ of bio-based polymers. the world.
50354 Hürth, Germany press-pictures/labelling-logos-charts
BIO-BASED STRUCTURAL POLYMERS CURRENT BIO- PRODUCING LOCATIONS PRODUCTION
michael.carus@nova-institut.de BASED CARBON COMPANIES IN 2013 CAPACITIES IN
CONTENT* IN 2013 AND AND UNTIL 2013 (TONNES)
Authors of the short version UNTIL 2020 2020
Florence Aeschelmann (nova-Institute) Cellulose acetate CA 50% 17 20 850,000
florence.aeschelmann@nova-institut.de,
Michael Carus (nova-Institute)
Epoxies – 30% – – 1,210,000
Ethylene propylene diene EPDM 50% to 70% 1 1 45,000
Layout monomer rubber
Norma Sott
Polyamides PA 40% to 100% 9 11 85,000
Edition Poly(butylene adipate-co- PBAT Up to 50%** 4 5 75,000
2015-05 terephthalate)
Polybutylene succinate PBS Up to 100%** 10 11 100,000
Polyethylene PE 100% 1 1 200,000
Polyethylene terephtalate PET 20% 5 5 600,000
Polyhydroxyalkanoates PHA 100% 14 16 32,000
Polylactic acid PLA 100% 28 34 195,000
Polytrimethylene terephthalate PTT 27% 1 2 110,000
Polyurethanes PUR 10% to 100% 7 7 1,200,000
Starch Blends*** – 25% to 100% 15 16 430,000
Total 112 129 5,132,000
* Bio-based carbon content: fraction of carbon derived from biomass in a product
(EN 16575 Bio-based products – Vocabulary)
** Currently still mostly fossil-based with existing drop-in solutions and a steady upward trend
*** Starch in plastic compound
Table 1: Bio-based polymers, short names, current bio-based carbon content, producing companies with locations and
production capacities in 2013

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Polymers worldwide, bio-based shares (2013)

Polymers***
Total ca. 393 million t
bio-based:
32.5 million t
(8.3% of total)

Rubber products Functional and structural Man-made fibres


Total 26.5 million t (2012) polymers*** Total 55 million t (2013)
bio-based: Total 314 million t (2013)* bio-based: 6 million t (2013)
11.3 million t (2012) bio-based: 15.2 million t (11% of total)
(43% of total) (4.8% of total) ca. 95% not covered by polymer statistics

Functional polymers*** Structural polymers***


Total 58 million t (2013)* 256 million t total (2013)*
bio-based: bio-based:
10 million t (2013) 5.2 million t (2013)
(17% of total) (2% of total)

Paper starch Linoleum


PE & PET
8 million t (2013) 100,000 t
Starch Blends
Bio-based PLA
Bio-based PHA/PHB
functional polymers
structural polymers
for paints, coatings, PA
5.1 million t
adhesives and others CA
(2013)**
2 million t ...

(*): Data from PlasticsEurope 2014. Original data show 299 million tonnes for 2013 in total. With the same shares
as 2011 (PlasticsEurope 2012) this would mean: 251 million tonnes structural polymers and 48 million tonnes
functional polymers plus bio-based polymers (nova 2015); (**): nova-Institute 2015; (***): Polymers covering
ⓒ –Institute.eu|2015 thermoplastic and thermosets; Different additional sources, like International Rubber Study Group Full study available at
(www.macplas.it, 13-07-10), The Fiber Year 2014 (14-05) www.bio-based.eu/markets

Figure 1: Polymers worldwide, bio-based shares (2013)


Figure 2: Global production capacities of bioplastics (European Bioplastics 2014)
Share of bio-based polymers in the total
polymer market Bio-based polymers Drop-in bio-based polymers such as polyethylene
Rather than simply listing the usual structural This study focuses exclusively on bio-based In 2014, for the first time, the association terephthalate (PET) and polyethylene (PE) lead
polymers, Figure 1 gives an overview of all kinds building block and polymer producers, and “European Bioplastics” used nova-Institute’s this category. Drop-in bio-based polymers
of polymers, including rubber products, man- the market data therefore does not cover the market study as its main data source for their are chemically identical to their petrochemical
made fibres and functional polymers. This figure bio-based plastics branch. We must clearly recently published market data. For European counterparts but at least partially derived from
includes bio-based shares at different levels. differentiate between these two terms. A polymer Bioplastics’s selection of bio-based polymers, biomass. European Bioplastics uses plastic as
The bio-based share for structural polymers, is a chemical compound consisting of repeating which differs from nova-Institute’s selection, a synonym for polymer.
which are the focus of the study, is 2%. For structural units (monomers) synthesized through bio-based polymers production capacities are
polymers overall, however, the bio-based share a polymerization or fermentation process, projected to grow by more than 400% by 2018.1 The global capacities in 2013 and 2018 have
is even higher (8.3%) because of the higher bio- whereas a plastic material constitutes a blend The graph in Figure 2 shows European been split by material type in Figures 3 and
based shares in rubber (natural rubber) and man- of one or more polymers and additives. Bioplastics’s growth projection of bio-based 4 respectively. Bio-based PET is the overall
made fibres (mainly cellulosic fibres). In 2011, polymers production; by 2018, these could market leader and is expected to grow at a quick
these shares were 1.5% and 8.2% respectively. Table 1 gives an overview on the covered bio- grow by over 400%, or from 1.6 million tonnes rate, from 37% in 2013 to 74% in 2018. As a
The bio-based share is clearly growing at a faster based polymers and the producing companies in 2013 to 6.7 million tonnes in 2018 in absolute consequence, the bio-based non-biodegradable
rate than that of the global polymer market. with their locations and production capacities terms. The market is clearly dominated by polymers market is expected to grow strongly as
in 2013. bio-based and non-biodegradable polymers. well since bio-based PET is part of this category.

 arket data graphics are available for download in English and German: http://en.european-bioplastics.org/
1 M
press/press-pictures/labelling-logos-charts

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In 2013 a distant second behind bio-based PET Figures 5 and 6 show the main results of nova-
was bio-based PE, which was closely followed Institute’s survey. Production capacity of bio-
by polylactic acid (PLA), starch blends and based polymers will triple from 5.1 million tonnes
biodegradable polyesters such as polybutylene in 2013 to nearly 17 million tonnes by 2020. The
succinate (PBS) and poly(butylene adipate-co- production capacity for bio-based polymers
terephthalate) (PBAT). However, in 2018, PLA boasts very impressive development and annual
would be second, followed by biodegradable growth rates, with a compound annual growth
polyesters, starch blends and bio-based PE. rate (CAGR) of almost 20% in comparison to
This means that PLA’s production capacity could petrochemical polymers, which have a CAGR
increase more than bio-based PE’s. between 3–4%. Due to their broader scope,
nova-Institute’s projected production capacities
European Bioplastics’s selection of bio-based are much higher than those projected by
polymers and time span differ from nova- European Bioplastics.
Institute’s. nova-Institute decided to cover
further bio-based polymers by including bio- The 5.1 million tonnes bio-based polymer
based thermosets (epoxies, polyurethanes (PUR) production capacity represent a 2% share of
and ethylene propylene diene monomer rubber overall structural polymer production at 256 million
(EPDM) and cellulose acetate (CA) until 2020. tonnes in 2013 and a bio-based polymer turnover
of about €10 billion (5 Mio. t (production capacity)
x €2.50/kg (estimated average bio-based polymer
price) x 0,8 (capacity utilization rate)).

Figure 3: Global production capacities of bioplastics 2013 (by material type) (European Bioplastics 2014)
Bio-based polymers: Evolution of worldwide production capacities
from 2011 to 2020
20

million t/a
15

actual data forecast

10

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020

Epoxies PUR CA PET PTT PEF EPDM

PE PBS PBAT PA PHA Starch PLA


Blends

© -Institut.eu | 2015 Full study available at www.bio-based.eu/markets

Figure 4: Global production capacities of bioplastics 2018 (by material type) (European Bioplastics 2014) Figure 5: Bio-based polymers: Evolution of worldwide production capacities from 2011 to 2020

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This bio-based share of overall polymer Polyurethanes (PUR) can be 10% to 100% bio-
production has been growing over the years: it based. PUR are produced from natural oil polyols Selected bio-based polymers: Evolution of worldwide production
was 1.5% in 2011 (3.5 million tonnes bio-based (NOP). Bio-based succinic acid can be used to capacities from 2011 to 2020
for a global production of 235 million tonnes). replace adipic acid. The global PUR market 3

million t/a
With an expected total polymer production of (including petro-based PUR) is continuously
about 400 million tonnes in 2020, the bio-based growing but the bio-based PUR market is
share should increase from 2% in 2013 to more expected to grow faster. 2.5

than 4% in 2020, meaning that bio-based


production capacity will grow faster than overall Cellulose acetate (CA) is 50% bio-based. 2
production. This market is similar to that of epoxies: well actual data forecast
established, for example cigarette filters are
1.5
The most dynamic development is foreseen made from CA, with small growth.
for drop-in bio-based polymers, but this is
closely followed by new bio-based polymers. Polyethylene terephthalate (PET) is currently 1
Drop-in bio-based polymers are spearheaded 20% bio-based and produced out of bio-based
by partly bio-based PET, whose production monoethylene glycol (MEG) and terephthalic
0.5
capacity was around 600,000 tonnes in 2013 acid (TPA) as a drop-in bio-based polymer.
and is projected to reach about 7 million tonnes TPA is currently still petro-based but subject to
by 2020, using bio-ethanol from sugar cane. ongoing R&D. Bio-based TPA can be produced
2011 2012 2013 2014 2015 2016 2017 2018 2019 2020
Bio-based PET production is expanding at at pilot scale. Most bio-based PET and MEG are
high rates worldwide, largely due to the Plant produced in Asia. Bio-based PET is one of the PTT PEF EPDM PE PBS

PET Technology Collaborative (PTC) initiative leaders of the bio-based polymers market and is PBAT PA PHA
Starch
PLA
Blends
launched by The Coca-Cola Company. The slated to become the bio-based polymer with the © -Institut.eu | 2015 Full study available at www.bio-based.eu/markets
second most dynamic development is foreseen biggest production capacity by far. This is largely
for polyhydroxyalkanoates (PHA), which, contrary due to the Plant PET Technology Collaborative
to bio-based PET, are new polymers, but still (PTC) initiative launched by The Coca Cola Figure 6: Selected bio-based polymers: Evolution of worldwide production capacities from 2011 to 2020
have similar growth rates to those of bio-based Company.
PET. PLA and bio-based PUR are showing Polytrimethylene terephthalate (PTT) is Ethylene propylene diene monomer rubber
impressive growth as well: their production Bio-based epoxies, PUR, CA and PET have huge 27% bio-based and made out of bio-based (EPDM) is made out of bio-based ethylene
capacities are expected to almost quadruple production capacities with a well established 1,3-propanediol (1,3-PDO) and currently petro- and can be 50% to 70% bio-based. Specialty
between 2013 and 2020. market in comparison with other bio-based based TPA. PTT is similar to PET since both chemicals company Lanxess is currently
polymers. However, other bio-based polymers have TPA as precursor. Bio-based PTT and 1,3- producing bio-based EPDM in Brazil. The market
Here are some details on each bio-based listed on Figure 6 show strong growth as well. PDO are produced by one leading company, is small and is not expect to grow in the coming
polymer covered in the report: Figure 6 shows the evolution of worldwide DuPont. The market is well established and is years.
production capacities only for selected bio- not expected to grow much.
Epoxies are approximately 30% bio-based based polymers (without bio-based epoxies, Polyethylene (PE) is a 100% bio-based drop-in
(only bio-based carbon content2 considered in PUR, CA and PET). Some of these polymers are Polyethylene furanoate (PEF) is 100% bio- polymer. The bio-based building block needed is
this report) and are produced out of bio-based brand new bio-based polymers. That is why their based and is produced out of bio-based bio-based ethylene, which is made out of sugar
epichlorohydrin. The market is well established markets are smaller and need to be developed 2,5-furandicarboxylic acid (2,5-FDCA) and MEG. cane. Brazilian petrochemical company Braskem
and is not expected to grow much since epoxies correspondingly. PEF is a brand new polymer, which is expected produces bio-based PE in Brazil. Bio-based PE
have already long been partly bio-based. to enter the market in 2017. Just as PTT, PEF has been on the market for a few years but its
is similar to PET. Both PEF and PET are used production capacity has hitherto remained the
in bottle production, however PEF is said to same. Further developments have been slowed
have better properties, such as better barrier down because of the shale gas boom.
properties, than PET. Technology company
2 B
 io-based carbon content: fraction of carbon derived in a product (EN 16575 Bio-based products from Avantium is heavily involved in the development
biomass– Vocabulary) of PEF and is planning to introduce PEF to the
market in 2017.
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Polybutylene succinate (PBS) is biodegradable Nevertheless PHA producers and several new Bio-based building blocks as a precursor Bio-based MEG, L-lactic acid (L-LA), ethylene
and currently mostly fossil-based but could in players are optimistic and see potential in PHA. of bio-based polymers and epichlorohydrin are relatively well established
theory be 100% bio-based. PBS is produced Therefore, production capacity is expected to For the first time, the production capacities of on the market. These bio-based building blocks
from 1,4-butanediol (1,4-BDO) and succinic acid. have grown tenfold by 2020. some major building blocks have been reported cover most of the total production capacity. They
Both building blocks are available bio-based but in the market study. The total production capacity are expected to keep on growing, especially
1,4-BDO is not commercially available yet; this Starch blends are completely biodegradable and of the bio-based building blocks reviewed in bio-based MEG and ethylene, whereas L-LA
is expected in 2015. PBS is currently produced 25% to 100% bio-based, with starch added to this study was 2 million tonnes in 2013 and is and bio-based epichlorohydrin are projected to
exclusively in Asia. It is expected to grow and one or several biodegradable polymers. Many expected to reach 4.4 million tonnes in 2020, grow at lower rate. However, the most dynamic
profit from the availability and lower cost of bio- players are involved in the production of starch which means a CAGR of almost 12%. The developments are spearheaded by succinic acid
based succinic acid. blends but Italian company Novamont is currently most dynamic developments are spearheaded and 1,4-BDO. Both are brand new drop-in bio-
market leader. The market is expected to keep by succinic acid and 1,4-BDO, with MEG as a based building blocks on the market. The first
Poly(butylene adipate-co-terephthalate) (PBAT) on growing, with production capacity projected distant runner-up. Figure 7 shows the evolution facilities are currently running and more will be
is also currently mostly fossil-based. PBAT is to double between 2013 and 2020. of worldwide production capacities for some built in the coming years.
produced from 1,4-BDO, TPA and adipic acid. major building blocks.
PBAT is biodegradable. PBAT can theoretically Polylactic acid (PLA) is 100% bio-based
be up to 50% bio-based since bio-based adipic and biodegradable but only under certain
acid is not available yet. It is still at the research conditions: PLA is industrially compostable.
stage. PBAT has mostly been produced by one Produced by numerous companies worldwide, Selected bio-based building blocks: Evolution of worldwide
big company, BASF, but a new player, Jinhui with NatureWorks as market leader, PLA is the production capacities from 2011 to 2020
ZhaolongHigh Technology, entered the market most well established new bio-based polymer. 6

million t/a
and another one, Samsung Fine Chemicals, However, the PLA market is still expected to
which has a relatively small production capacity grow further, with a projected fourfold growth
at the moment, is planning to extend its between 2013 and 2020. PLA can already be 5

production capacity. found at near-comparable prices to fossil-based


polymers. 4
Polyamides (PA) are a big family since there are actual data forecast
many different types of polyamides. This explains In short, the most dynamic development is
3
the wide range of bio-based carbon content: from expected for bio-based PET, with a projected
40% to 100%. Polyamides are generally based production capacity of about 7 million tonnes
on sebacic acid, which is produced from castor by 2020. Second in the drop-in polymers group 2
oil. Evonik has recently developed a polyamide are bio-based polyurethanes. Regardless, new
based on palm kernel oil. The market, which is bio-based polymers such as PLA and PHA
1
expected to grow moderately, is headed by one are showing impressive growth as well: PLA
big player, Arkema. production capacity is expected to almost
quadruple and PHA production capacity is
2011 2012 2013 2014 2015 2016 2017 2018 2019 2020
Polyhydroxyalkanoates (PHA) are 100% bio- expected to grow tenfold between 2013 and
based and biodegradable even in cold sea 2020. MEG L-LA Ethylene Epichlorohydrin Succinic acid

water. PHA are produced through a fermentation 1,4-BDO 1,3-PDO Lactide 2,3-BDO 2,5 FDCA D-LA
process mainly by specific bacteria. Many Detailed information on the development of bio- © -Institut.eu | 2015 Full study available at www.bio-based.eu/markets
different companies are involved in the based PET and PLA and other polymers can be
production of PHA. The market is currently very found in the full report.
small but is expected to grow tremendously. The Figure 7: Selected bio-based building blocks: Evolution of worldwide production capacities from 2011 to 2020
joint venture Telles, set by Metabolix and ADM
in 2006, aimed at big capacity but hardly sold
any PHA and subsequently collapsed in 2012.
PHA are brand new polymers, which means
their market still needs time to fully develop.

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Here are some details on each bio-based building Succinic acid is a very versatile building block.
block covered in the report: Bio-based polymers such as PBS can be made
of succinic acid but also other bio-based building
Monoethylene glycol (MEG) is one of PET’s blocks such as 1,4-BDO. It can be used as well
building blocks. Bio-based MEG is a drop- in PUR to replace adipic acid. However, the
in which is mostly produced in Asia. The very market still has to be developed. Petro-based
fast increase in bio-based PET production has succinic acid is not a big market since petro-
had a considerable impact on the production based succinic acid is relatively expensive. Bio-
capacities of bio-based MEG. Bio-based PET based succinic acid is actually cheaper than its
actually leads the bio-based polymers group, petro-based counterpart. The first facilities have
which is largely due to the Plant PET Technology been running since 2013 and the next ones are
Collaborative (PTC) initiative launched by The already in the pipeline.
Coca-Cola Company.
1,4-Butanediol (1,4-BDO) is also a versatile
L-Lactic acid (L-LA) is PLA’s building block, building block. At the moment no facility able
together with D-lactic acid (D-LA). Both are to produce commercial quantities is running but
optical isomers of LA. L-LA is much more common the first one is expected in 2015. 1,4-BDO can
than D-LA since D-LA is more complicated to directly be produced from biomass or indirectly
produce. Lactide is an intermediate between LA from succinic acid. Since bio-based succinic is Figure 8: Global production capacities of bioplastics in 2013 Figure 9: Global production capacities of bioplastics in 2018
and PLA. It can be bought as such to produce relatively new to the market, this partly explains (by region) (European Bioplastics 2014) (by region) (European Bioplastics 2014)
PLA. A lot of different companies are involved in why 1,4-BDO is still not commercially available.
this business worldwide since most LA has long 2,3-Butanediol (2,3-BDO) is another isomer of
been used in the food industry as, among other butanediol. Global Bio-Chem Technology Group, Investment by region market shares are expected to shift dramatically.
things, a food preservative, pH regulator and based in China, is currently producing 2,3-BDO, Most investment in new bio-based polymer Asia is predicted to experience most of the
flavouring agent. The production capacities do which they obtain by processing corn. capacities will take place in Asia because of developments in the field of bio-based building
not only include LA used for polymer production, better access to feedstock and a favourable block and polymer production, while Europe and
but also for the food industry. It is estimated 1,3-Propanediol (1,3-PDO) is one of PTT’s political framework. Figures 8 and 9 show the North America are slated to lose more than a
that more than a half of LA is used by the food building blocks. 1,3-PDO is mostly produced 2013 and 2018 global production capacities half and just over three quarters of their shares,
industry. from corn by DuPont. The market is well for bio-based polymers repartitioned by region. respectively.
established and is not expected to grow much. European Bioplastics published these market
Ethylene is PE’s building block. Bio-based data, which take into account fewer types of Production capacities in Europe
ethylene is currently made from sugar cane in 2,5-Furandicarboxylic acid (2,5-FDCA) can be bio-based polymers than nova-Institute. Due to Figure 10 shows the evolution of production
Brazil. Further developments have slowed down combined with MEG to produce polyethylene the complexity of the manufacturing value chain capacities in Europe without bio-based
because of a sudden extreme price drop in petro- furanoate (PEF). 2,5-FDCA is a brand new structure of epoxies, PUR and cellulose acetate, thermosets (epoxies and PUR) and cellulose
based ethylene that happened due to the shale building block which is expected to come to the the repartitions by region cannot be reliably acetate.
gas boom. market in 2017. Avantium is deeply involved in determined for all bio-based polymers. As a Europe’s position in producing bio-based
2,5-FDCA but others are also showing interest. result, a graph representing the repartition by polymers is limited to just a few polymers. Europe
Epichlorohydrin is one of the building blocks of region with nova-Institute’s scope is not provided has so far established a solid position mainly
epoxies. Glycerin, which is a by-product of the Detailed information on the development of bio- in the report, but only for the subgroup selected in the field of starch blends and is expected
production of biodiesel, is used as feedstock. based building blocks can be found in the full by European Bioplastics. to remain strong in this sector for the next few
report. years. Nevertheless, a number of developments
Europe’s share is projected to decrease from and investments are foreseen in Europe. PLA
17.3% to 7.6%, and North America’s share is production capacities, especially starch blend
set to fall from 18.4% to 4.3%, whereas Asia’s production capacities, are predicted to grow. The
is predicted to increase from 51.4% to 75.8%. growth of these increased production capacities
South America is likely to remain constant with for starch blends can be traced back to Italy’s
a share at around 12%. In other words, world Novamont, a leading company in this field.

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One noteworthy finding of other studies is that of inter alia bio-based PA, PUR and thermosets. Market segments used in many different other market segments.
Europe shows the strongest demand for bio- However, only few specific, large-scale plans for The packaging industry consumes most petro- Figures 11 and 12 show the global production
based polymers, while production tends to take bio-based building blocks incorporating concrete based polymers. For bio-based polymers, the of bio-based polymers by market segment in
place elsewhere, namely in Asia. In Europe, plans for the production of bio-based polymers same trend can be observed: the major part of 2013 and in 2018.
bio-based polymer production facilities for have been announced to date. this as rigid packaging (bottles for example) and
PLA are not only small in size but also small in The European Union’s relatively weak position in the rest as flexible packaging (films for example). The order of importance of the market segments
number. On the other hand, bio-based PA and the production of bio-based polymers is largely These uses cannot come as a surprise, since is expected to stay approximately the same
CA production is based in Europe and is likely the consequence of an unfavourable political bio-based PET is one of the biggest bio-based between 2013 and 2018. Rigid packaging is
to continue supplying for the growing markets framework. In contrast to bioenergy and biofuels, polymers in terms of capacity and is mostly supposed to keep its first place by growing
of the building and construction and automotive there is no European policy framework to support used for the production of bottles. On the other tremendously with an almost sevenfold growth
sectors. Europe does have industrial production bio-based polymers, whereas bioenergy and hand, the packaging industry has a considerable in only five years. This is again due to the very
facilities for PBAT which is still fully fossil-based. biofuels receive strong and ongoing support interest in biodegradability since packaging is fast development of bio-based PET. However,
However, judging by industry announcements during commercial production (quotas, tax only needed for short times but in big quantities, the automotive sector is projected to gain
and the ever-increasing capacity of its bio- incentives, green electricity regulations, market which contributes to the accumulation of waste. faster importance than consumer goods and
based precursors, PBAT is expected to be introduction programs, etc.). Without comparable It should be understood that not all bio-based agriculture sectors. Automotive is actually the
increasingly bio-based, with a projected 50% support, bio-based chemicals and polymers will polymers are biodegradable but some important second most dynamic after rigid packaging and
share by 2020. Housing the leading chemical suffer further from underinvestment by the private ones are, e.g. PHA, PLA and starch blends. is followed by electronics, a sector which is still
corporations, Europe is particularly strong and sector. It is currently much safer and much more This feature is also interesting for agriculture very small, followed by textiles, which is already
has great potential in the fields of high value fine attractive to invest in bio-based polymers in Asia, and horticulture applications (mulch films for well established on the global market.
chemicals and building blocks for the production South America and even North America. example). However, bio-based polymers are also

Bio-based polymers: Evolution of production capacities in Europe


from 2011 to 2020 (without thermosets and cellulose acetate)

1000000 1
million t/a

800000 0.8

actual data forecast

600000 0.6

400000 0.4

200000 0.2

0
2011
2011 2012
2012 2013
2013 2014
2014 2015
2015 2016
2016 2017
2017 2018
2018 2019
2019 2020
2020

Starch Blends PLA PBAT PEF PA

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Figure 10: Bio-based polymers: Evolution of production capacities in Europe from 2011 to 2020 (without thermosets and Figure 11: Global production capacities of bioplastics 2013 (by market segments) (European Bioplastics 2014)
cellulose acetate)

14 © 2015 nova-Institut GmbH, Version 2015-05 © 2015 nova-Institut GmbH, Version 2015-0515
Bio-based Building Blocks and Polymers in the Worldwww.bio-based.eu/markets www.bio-based.eu/markets Bio-based Building Blocks and Polymers in the World

Figure 13 shows the worldwide shares of bio- are clearly not a market leader in terms of
based polymers production in different market capacities – but depending on future policy on Worldwide shares of bio-based polymers production in different
segments in 2013 and 2020 for nova-Institute’s plastic microparticles, mulch films and other market segments in 2013 and 2020
scope of bio-based polymers (with thermosets biodegradable applications could grow strongly.
and cellulose acetate). Functional polymers are used for coatings, 2013 2020
adhesives, paint and ink applications, which 1%

The same statement can be made regarding require relatively small quantities of polymers. 2%
11%
the packaging sector: packaging (rigid and 15% 14%
flexible together) is the leader, with a clear 4% 40%
9% 13%
advantage for rigid packaging, which is slated
to grow strongly. On the other hand, automotive, 16% 2%
18% 2%
building and construction, textiles and consumer
16%
goods are much bigger because bio-based 18%
2% 6%
epoxies, polyurethanes and cellulose acetate 3% 8%
52%
are used in these sectors. The smallest market
segments are agriculture and functional. In
Packaging - rigid Packaging - Textiles Agriculture and Consumer
agriculture, applications are mostly limited to (incl. food serviceware) flexible (incl. non-woven and fibres) horticulture goods

biodegradable polymers (mulch films), which


Functional Automotive Electrical and Building and Others
and transports electronic (incl. casing) construction

© -Institut.eu | 2015 Full study available at www.bio-based.eu/markets

Figure 13: Worldwide shares of bio-based polymers production in different market segments in 2013 and 2020

Content of the full report The “trend reports” section contains a total of
This 500-page report presents the findings of eleven independent articles by leading experts
nova-Institute’s market study, which is made up in the field of bio-based polymers and building
of three parts: “market data”, “trend reports” and blocks. These trend reports cover in detail every
“company profiles”. recent issue in the worldwide bio-based building
The “market data” section presents market block and polymer market.
data about total production capacities and the The final “company profiles” section includes
main application fields for selected bio-based company profiles with specific data including
polymers worldwide (status quo in 2013, trends locations, bio-based building blocks and
and investments towards 2020). Due to the polymers, feedstocks and production capacities
lack of 100% reliable market data about some (actual data for 2011 and 2013 and forecast
polymers, which is mainly due to the complexity for 2020). The profiles also encompass basic
of their manufacturing value chain structure information on the companies (joint ventures,
(namely thermosets and cellulose acetate) or their partnerships, technology and bio-based
pre-commercial stage (CO2-based polymers), products). A company index by bio-based
this section contains three independent articles building blocks and polymers, with list of
by experts in the field who present and discuss acronyms, follows.
their views on current and potential market
development. However, this part not only covers Updates to the report
bio-based polymers, but also investigates the nova-Institute will provide annual updates of
current bio-based building block platforms. the report based on the existing report and the
Figure 12: Global production capacities of bioplastics 2018 (by market segments) (European Bioplastics 2014) continuously updated data. The trend reports will
be updated every second year at least.
16 © 2015 nova-Institut GmbH, Version 2015-05 © 2015 nova-Institut GmbH, Version 2015-0517
Bio-based Building Blocks and Polymers in the Worldwww.bio-based.eu/markets www.bio-based.eu/markets Bio-based Building Blocks and Polymers in the World

Table of contents 5 Plastic bags – their consumption and 9 Bio-based building blocks – 12.6 GreenPremium price ranges – the full
(474 pages and 202 tables and figures) regulation in the European market Rainer Busch picture
and beyond – Constance Ißbrücker, (18 pages, 27 tables and figures) 12.7 Examples of GreenPremium Prices
1 Executive summary Kristy-Barbara Lange and 9.1 Introduction 12.8 Main drivers for emotional and strategic
(26 pages, 16 tables and figures) Hasso von Pogrell 9.2 Selected monomers performance
1.1 Introduction (12 pages, 3 tables and figures) 9.3 Perspectives 12.9 GreenPremium in the automotive sector
1.2 Study background 5.1 Introduction 12.10 Some actors fail to receive a
1.3 Methodology 5.2 Common types of carrier bags 10 Asian markets for bio-based chemical GreenPremium
1.4 Main results 5.3 The bio-based plastics alternative – building blocks and polymers – 12.11 GreenPremium for Biofuels?
1.5 Content of the full report commercially available Wolfgang Baltus 12.12 Summary – GreenPremium prices along
1.6 Authors of the study 5.4 The bag market in Europe and beyond (36 pages, 33 tables and figures) the value-added chain from bio-based
1.7 Figures 5.5 European regulation on lightweight 10.1 Introduction chemicals to products
plastic bags – a complex negotiation 10.2 Asian markets for bio-based polymers 12.13 References
Market data process 10.3 Asia-Pacific region in numbers
2 Market data 5.6 Possible bag market developments in 10.4 Feedstock – Key to success in Asia- Bio-based plastics and environment
(28 pages, 44 tables and figures) EU Member States Pacific 13 Environmental evaluation of bio-based
2.1 Bio-based Building Blocks 10.5 Policy development polymers and plastics – Roland Essel
2.2 Bio-based Polymers 6 Bagislation in Europe – a (good?) case 10.6 Market growth factors and Christin Liptow
for biodegradables – Harald Käb 10.7 Selected biopolymer families – (20 pages, 14 tables and figures)
3 Qualitative analyses of selected bio- (8 pages, 7 tables and figures) limitations, challenges and chances in 13.1 Introduction
based polymers Asia-Pacific 13.2 Results from recent life cycle
(12 pages, 6 tables and figures) 7 Standards, norms and labels for bio- 10.8 Case Study: The National Bioplastics assessments
3.1 Cellulose Acetate (CA) based products – Lara Dammer and Roadmap in Thailand – Situation and 13.3 Feedstock supply and use of by-
3.2 Carbon dioxide as chemical feedstock: Michael Carus outlook after 6 years in operation products
Polymers and plastics from CO2  (8 pages, 6 tables and figures) 13.4 Genetically modified organisms
3.3 Thermosets 7.1 Introduction 11 Brand views and adoption of 13.5 Biodiversity
7.2 Activities of CEN/TC 411 bio-based polymers – Harald Käb 13.6 Land use
Trend reports 7.3 Bio-based labels in Europe (26 pages, 19 tables and figures) 13.7 Conclusion
7.4 Certification of the sustainability of wood 11.1 Introduction – Why read this?
Policy on bio-based polymers as a raw material – FSC and PEFC 11.2 Summary 14 Microplastic in the environment –
4 Policies impacting bio-based plastics 7.5 New certification systems for 11.3 Brand Strategies – Branch Aspects sources, impacts and solutions –
market development – Dirk Carrez, sustainable biomass 11.4 Individual Brand Strategies (selection, Roland Essel
Jim Philp and Lara Dammer 7.6 References alphabetic order) for packaging (8 pages, 4 tables and figures)
(40 pages, 6 tables and figures) applications 14.1 Introduction
4.1 Introduction Bio-based building blocks and polymers market 11.5 Summary table 14.2 Defining microplastic
4.2 Policy issues 8 Bio-based polymers, a revolutionary 14.3 Sources of microplastic
4.3 Bio-based plastics within a bioeconomy change – Jan Ravenstijn 12 GreenPremium prices along the value 14.4 Impacts of microplastics
4.4 General bioeconomy strategies and (70 pages, 11 tables and figures) chain of bio-based products – 14.5 Can bio-based plastics be a solution?
policies 8.1 Introduction Michael Carus, Asta Eder and 14.6 Conclusions
4.5 References 8.2 Market trends Janpeter Beckmann 14.7 References
8.3 Technology trends (16 pages, 6 tables and figures)
8.4 Environmental trends 12.1 Initial questions
8.5 Selected bio-based polymer families 12.2 Methodology
8.6 Customer views 12.3 Definition of “GreenPremium” prices
8.7 New business concepts 12.4 GreenPremium prices do exist
8.8 New value chain 12.5 Results of the LinkedIn survey in the
8.9 Lessons learnt bio-based community
8.10 Acknowledgements
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Company data 15.38 Jiangsu Clean Environmental 15.79 Surakshit Parivar Biotech Pvt. Ltd. Authors of the study
15 Company profiles Technology Co., Ltd. 15.80 Synbra Technology B.V.
(129 pages, 96 company profiles) 15.39 Jinhui Zhaolong High Technology Co., 15.81 Teijin Limited Florence Aeschelmann (MSc)
15.1 AnoxKaldnes Ltd. 15.82 TerraVerdae BioWorks Inc. (Germany), materials engineer, is
15.2 Anqing Hexing Chemical Co., Ltd. 15.40 Kaneka Corporation 15.83 The Dow Chemical Company a staff scientist in the Technology
15.3 Arizona Chemical Company LLC 15.41 Kingfa Sci. & Tech. Co., Ltd. 15.84 The Woodbridge Group & Markets department at nova
15.4 Arkema SA 15.42 KNN Bioplastic 15.85 ThyssenKrupp AG Institute. Her main focus is on bio-
15.5 Attero 15.43 LANXESS AG 15.86 Tianan Biologic Material Co., Ltd. based materials, especially bio-based polymers.
15.6 Avantium Technologies B.V. 15.44 Limagrain Holding S.A. 15.87 Tianjin GreenBio Materials Co., Ltd. She is well acquainted with the global market
15.7 BASF SE 15.45 Lukang Pharmaceutical Co., Ltd. 15.88 TMO Renewables Limited for bio-based polymers and building blocks as
15.8 Bayer MaterialScience 15.46 Mango Materials 15.89 ttz Bremerhaven she is one of the authors of the market study
15.9 Bio-on Srl 15.47 Meredian Holdings Group 15.90 Uhde Inventa-Fischer AG “Bio-based Building Blocks and Polymers in the
15.10 BioAmber Inc. 15.48 Merquinsa S.A. 15.91 Veolia Water Technologies World – Capacities, Production and Applications:
15.11 BioBased Technologies LLC 15.49 Metabolix Inc. 15.92 Verdezyne, Inc. Status Quo and Trends Towards 2020”. She is
15.12 BioMatera Inc. 15.50 Mitsubishi Chemical Corporation (MCC) 15.93 Wuhan Sanjiang Space Gude Biotech also in charge of the overall organization of the
15.13 Bioplastech Ltd. 15.51 Musashino Chemical Laboratory, Ltd. Co, Ltd. International Conference on Bio-based Materials.
15.14 BIOTEC Biologische Naturverpackungen 15.52 Myriant Corporation 15.94 Yunan Fuji Bio-Material Technology Co.,
GmbH & Co. KG 15.53 Nafigate Corporation Ltd. Michael Carus (MSc) (Germany),
15.15 Braskem S.A. 15.54 Nantong Jiuding Biological Engineering 15.95 Zhejiang Hangzhou Xinfu physicist, founder and managing
15.16 Cargill Inc. Co., Ltd. Pharmaceutical Co., Ltd. director of the nova-Institute, has
15.17 Cathay Industrial Biotech, Ltd. 15.55 NatureWorks LLC 15.96 Zhejiang Hisun Biomaterials Co., Ltd. worked in the field of Bio-based
15.18 Cellulac 15.56 Newlight Technologies LLC Economy for over 20 years. This
15.19 Chengdu Dikang Biomedical Co., Ltd. 15.57 Novamont S.p.A. 16 Company product index includes biomass feedstock, processes,
15.20 China New Materials Holdings Ltd. 15.58 Novomer Inc. (9 pages) bio-based chemistry, polymers, fibres and
15.21 Chongqing Bofei Biochemical Products 15.59 Paques composites. His work deals with market analysis,
Co., Ltd. 15.60 PHB Industrial S.A. 17 List of acronyms techno-economic and ecological evaluation as
15.22 Corbion Purac 15.61 Plaxica Ltd. (3 pages) well as the political and economic framework
15.23 DaniMer Scientific LLC 15.62 PolyFerm Canada Inc. for bio-based processes and applications (“level
15.24 DSM N.V. 15.63 PTT MCC Biochem Co., Ltd. playing field for industrial material use”). Carus is
15.25 DuPont 15.64 Rennovia Inc. part of an extensive, worldwide network, which
15.26 DuPont Tate & Lyle Bio Products 15.65 Reverdia enabled nova-Institute to make use of leading
Company, LLC 15.66 Rodenburg Biopolymers B.V. experts in the field for its market study.
15.27 Evonik Industries AG 15.67 Roquette
15.28 Far Eastern New Century Corporation 15.68 Samsung Fine Chemicals Co., Ltd. Wolfgang Baltus (PhD) (Thailand)
15.29 Futerro 15.69 Shandong Fuwin New Material Co., Ltd. worked for BASF for 15 years and
15.30 Galactic 15.70 Shanghai Tong-Jie-Liang Biomaterials was responsible for the business
15.31 Genomatica, Inc. Co., Ltd. development of environmental
15.32 Global Bio-Chem Technology Group 15.71 Shantou Liangyi friendly coatings in Asia. From 2008
Co., Ltd. 15.72 Shenzhen Bright China Biotechnological until 2014, Baltus worked for the National
15.33 Henan Jindan Lactic Acid Technology Co., Ltd. Innovation Agency (NIA) in Bangkok. In October
Co., Ltd. 15.73 Shenzhen Ecomann Biotechnology Co., 2014, he started work as a consultant for the
15.34 Hubei Guangshui National Chemical Ltd Precise Corporation, a group of Thai companies
Co., Ltd. 15.74 Showa Denko K.K. specialized in the field of electrical power
15.35 Hunan Anhua Lactic Acid Company 15.75 Solvay SA distribution equipment, project and service for
15.36 India Glycols Limited 15.76 Succinity GmbH substations, renewable energy and supervisory
15.37 Indorama Ventures Public Company 15.77 Sulzer Chemtech AG systems. His main target is to assist Precise get
Limited 15.78 SUPLA Material Technology Co., Ltd

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a foothold in the biorefinery business, introducing Dirk Carrez (PhD) (Belgium) is one of Kristy-Barbara Lange (Germany) Jan Ravenstijn (MSc) (The
smart community concepts in Thailand. the leading policy consultants on a is Deputy Managing Director at Netherlands) has more than 35
He is regarded as one of the leading experts on Bio-based Economy in Brussels. He European Bioplastics and heads years of experience in the chemical
bio-based polymer markets and policy in Asia. was Director Industrial Biotechnology the communications division of the industry with Dow Chemical and
at EuropaBio, the European association. Since 2010 she has DSM, including 15 years in executive
Howard Blum (BSChem, MBA) Association for Bioindustries, until 2011. He been responsible for all of the association’s global R&D positions in engineering plastics,
(Philadelphia-USA) is a B2B chemical is now Managing Director of Clever Consult, communications, internally and externally, thermosets and elastomers. He is currently a
industry professional with more Brussels. In 2013 he became the Executive including media relations and corporate visiting professor and consultant to CEOs of
than 30 years experience working Director of the new industrial association BIC publishing. Since she joined managing team in biopolymer companies and has published several
in the chemical and polymer field. (Bio-based Industries Consortium), which is early 2015, her further focus areas now include EU papers and articles on the market development of
Previously with Conoco Oil, Chem Systems and the private partner in the Biobased Industries policy and membership development. She holds bio-based polymers. Jan Ravenstijn is regarded
Kline, he now runs his own firm Chemicals & Initiative (BBI JU), a new PPP between the a Master of Political Sciences from Heidelberg as one of the world’s leading experts in his field.
Plastics Advisory, focusing on biopolymers and EU Commission and more than 70 bio-based University, Germany. Before joining European
biorenewable solutions. The firm’s mission is economy companies. Bioplastics, Kristy worked in international PR- Hasso von Pogrell (Germany) has
to provide business development services for agencies for several years, with a focus on the been Managing Director of European
quickly identifying new markets, technologies and Constance Ißbrücker (Germany) infrastructure and (renewable) energy industry Bioplastics since March 2009.
opportunities, with ‘real-time’ implementation to has been working as Environmental sectors. Upon completion of his education
speed up the marketing and sales process and Affairs Manager for European in Germany and a two-year term of
minimize revenue-limiting activities. Bioplastics since February 2013. She Jim Philp (PhD) (France) is a military services, he studied Economics at the
His clients include multi-national companies that is responsible for issues related to the microbiologist who has been a University of Cologne, where he graduated in
require assistance in market and technology compostability, sustainability, and standardization policy analyst at the Organisation 1994.
analysis, new business development and project of bioplastics. Constance Ißbrücker holds a for Economic Cooperation and He began his political career as a lobbyist
management. In addition to the chemical and degree in chemistry from the University of Jena Development (OECD) in Paris in 1995, when he joined the Germany
plastics industry, he has assisted clients from the in Germany with a specialization in Bioorganic since 2011, where he specializes in industrial Industry Association for Optical, Medical and
oil & gas, catalysts, packaging, automotive and and Macromolecular Chemistry. Before joining biotechnology, synthetic biology and biomass Mechatronical Technologies. There he was
healthcare-pharma industry sectors. the association she worked in different research sustainability. He has been an academic for responsible for public relations and economics.
groups at universities in Berlin and Jena. Her about sixteen years, researching environmental After a two-year stint as General Manager at
Rainer Busch (Dr.rer.nat.) (Germany) is research background is in polysaccharide and industrial biotechnology: bioremediation, the Federal Association of the German Medium
a chemist with 24 years of experience chemistry, in particular cellulose dissolution, biosensors, wastewater science and and Large Retail Enterprises, he returned to
in the chemical industry. He worked modification and analytics. engineering. He was involved in various UK the industry sector. As Head of Department for
in various positions in R&D with government initiatives in biotechnology, such as Foreign Affairs at the Association of the German
Dow Chemical, mainly in technology Harald Käb (PhD) (Germany) is a Biotechnology Means Business, and BioWise. Construction Industry and Assistant Director of
scouting and intellectual asset management. chemist and has an unblemished He was coordinator of the LINK Bioremediation the European International Contractors (EIC), he
After his industrial career, he founded a 20-year “bio-based chemistry Programme, at the academic-industrial interface, served the construction industry for seven years
consulting firm and focused on the chemical and plastics” track record. From for about six years. He spent a total of eight and from 2000 to 2007. He directed the affairs of the
aspects of the industrial material use of biomass. 1999 to 2009 he chaired the board a half years working as an oil biotechnologist for Association of the German Sawmill Association
He is currently scientific advisor to the leading and developed “European Bioplastics”, the Saudi Aramco in Saudi Arabia, investigating field as its Managing Director between 2007 and
edge cluster BioEconomy in central Germany association that represents the bioplastics problems related to chemistry and microbiology, 2009.
and also visiting professor at the paper centre industry in Europe. Since 1998 he has been and developing biotechnology solutions for
Gernsbach near Karlsruhe (Germany). Rainer has working as an independent consultant, helping improved oil recovery and exploitation. He has
published and co-authored several papers and green pioneers and international brands to authored over 300 articles. In 2015 he was
articles on the use of renewable resources in the develop and implement smart business, media inducted into Who’s Who.
chemical industry. and policy strategies for bio-based chemicals
and plastics.

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Sustainability

Political Framework &


Strategy
System Analysis
Dissemination &
Strategic Consulting
Marketing Support Raw Material Supply
B2B communication Availability & Prices
Conferences & Workshops Sustainability
Marketing Strategies Bio-based Economy
Bio-based Chemicals & Materials •
Biorefineries • Industrial Biotechnology
Environmental
Carbon Capture & Utilization
Evaluation Techno-Economic
Evaluation (TEE)
Life Cycle Assessments (LCA)
Process Economics
Life Cycle Inventories Market Research
Target Costing Analysis
Meta-Analyses of LCAs Volumes & Trends
Competition Analysis
Feasibility and
Potential Studies

Technology & Markets

nova-Institute
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and independent institute in 1994. It is located Chemiepark Knapsack
in the Chemical Park Knapsack in Huerth, which Industriestraße 300
lies at the heart of the chemical industry around 50354 Hürth, Germany
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For the last two decades, nova-Institute has T +49 (0) 22 33 / 48 14-40
been globally active in feedstock supply, techno- F +49 (0) 22 33 / 48 14-50
economic and environmental evaluation, market
research, dissemination, project management contact@nova-Institut.de
and policy for a sustainable bio-based economy. www.nova-institut.eu

Key questions regarding nova activities


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