Kinetics Practice Name. 1B Chem 1 1 |. Which of the following is (are) important in determining whether a reaction occurs? 1. Bnergy of the molecules Tl. Orientation of the molecules A.Lonly CB» Vand It B. II only D. Neither I nor Il 2. Consider the reaction between solid CaCOs and aqueous HCI. The reaction will be speeded up by 3 an increase in which of the following conditions? 1. Concentration of the HC] = I, Size of the CaCO; particles 1, Temperatud A. lonly C.— Mand II only Excess magnesium was added to a beaker of aqueous hydrochloric acid on a balance. A graph of the ‘mass of the beaker and contents was plotted against time (line 1). 144 He) > MG) AGS Mass Leter What change in the experiment could give line 2? |. The same mass of magnesium but in smaller pieces 4 I. The same volume of a more concentrated solution of hydrochloric acid. W— TL, A lower temperature A. Lonly C.— Monly B. _Ionly @ None of the above4, The rate of a reaction between two gases increases when the temperature is increased and a catalyst is added. Which statements are both correct for the effect of these changes on the reaction? Increasing the temperature Adding a catalyst, A Collision frequency increases Activation energy increases ‘Activation energy increases Activation energy does not chang ‘Activation energy increases Collision trequeney increases 5. Which of the following is (are) altered when a liquid at its boiling point is cons ested 16 3» same temperature? 1, The size of the molecules Il, ‘The distance between the molecules. Y~ IIL, The average kinetic energy of the molecules A. Lonly Cc. Moly OC only D. Land Honly 6. Based on the definition for rate of reaction, which units could be used for a rate? A. mol/L Lisee B. mol/see CD revise 7. Which of the quantities in the enthalpy level diagram below is (are) affected by the use of a catalyst? Enthalpy Time A. only CP ‘mart ony a B. Mlonly D. Mand Ill only 8. In the Haber process for the synthesis of ammonia, what effects does the catalyst have? Rate of formation of NHy(g)_| Amount of NH3(e) formed A Increases Increases B Increases Decreases oO Tnoreases No change D. No change Increases9. Which statement is correct about the behavior of a catalyst in a reversible reaction” A. It decreases the enthalpy change of the forward reaction B. It increases the enthalpy change of the reverse reaction. oO It decreases the activation energy of the forward reaction. D. It increases the activation energy of the reverse reaction. 10. Which statement is correct for a collision between reactant particles leading to a reaction? ‘A. Colliding particles must have different energy. B. All reactant particles must have the same energy © cotiaing particles most havea kinetic energy her than the aetivationenersy D. _ Colliding particles must have the same velocity. IL. Which change of condition will decrease the rate of the reaction between excess zine granules and dilute hydrochloric acid? ‘A. increasing the amount of zine B. increasing the concentration of the acid pulverize the zine granules into powder oO decreasing the temperature 12. The table shows the concentrations of reactants and products during this reaction. 2A+B>C+2D [A] mo¥L [B] molt [C] molt {D]_ molt. at the start 6 3 0 | 0 after | min) 4 2 1 2 | ‘The rate of reaction can be measured by reference to any reactant or product, Which rates ane correct for this reaction? 1. rate=-2 mol/Lemin for A U min for B Mm. foro A. Land Il only C. Mand tit only13. _ In general, the rate of a reaction can be increased by all of the following except. A. increasing the temperature, creasing the activation energy. C. increasing the concentration of reactants. D. increasing the surface area of the reactants rik reel ft. 14. At 25°C, 100 enesof | 0-snabdsm’ hydrochloric acid is added to 3.5 g of magnesium carbonate. If the sample of magnesium carbonate is kept constant, which conditions will not increase the initial rate of reaction? Volume of HCI (mL) Concentration of HCI (M) ‘Temperature (°C) 200 10) 25 100 20 . 25 c 100 10 35 D. 200 20 25 15. Which statement is correct with regard to the catalyzed and un reaction? calyzed pathways for a A. The enthalpy change of the catalyzed reaction is less than the enthalpy change for the uncatalyzed reaction. B. The enthalpy change of the catalyzed reaction is greater than the enthalpy change for the uncatalyzed reaction, @ ‘The enthalpy change of the catalyzed reaction is equal to the enthalpy change for the uatalyzed reaction, D. The activation energy of the catalyzed reaction i uncatalyzed reaction. seater than the activation energy for the 16, Which changes increase the rate of a chemical reaction? 1. Increase in the concentration of an aqueous solution“ 1, Increase in particle size of the same mass of a solid reactant ML. Increase in the temperature of the reaction mixture, ™™ A. Land fl only C. Mand HI only CD banat onty D. AMand ut