2 & none. sh Haloatkanes and —_arlaareoet Hato contacnd hystoecnrtons aaa Geta classed fo fo hoo. Abphakt Hakper — horned and akomartte Aategen —_ component. ye They xe obfachet y a Gere ee MIE atoms — by —halegins adore, Tay aan glaritite CY dob © halodtana — @hatealtenes —-_ © Aaealkyore, @Haloaloss, They in hampers otearacedy g Airs au. clamifidd 1 mane, ott _ oe payrareger COS teton ee) Compounds lepencting epee ComeAnee day Stee Ore, deo or more dal CHisel Cmenohaatond » GRx Goan a ttvens? (rer ah CTethvate ealduee) Hato alkanes’ ally! haired aw guedee — CRRA Pkegory (1 Sesoestoney QD ae tending C2) ctewmdas a atone ‘Heapecttvoty one te : owt a » tod Se tw ‘ aout awd) ( get anes ) foe — aed) ane tober y aay eS ety! peep @ Halealkenss Cetkenyt hairs 64 OUg emt toty ) OR Fen te oy (Udo ertvnete) (ly? beamed ) fs Hata etapa’ C faltyeyt texte» Gy. Cn tel Cini) ey, Lo Momatic hate, Compounds @ They axe. beer chssfiey 2 1 tev0 - ® Nuchor halegen destuakves Cowl hates © Se chain halogens cleatvaktes Caraleye Aabields) @ Nudear hatign ouaxvakues ( awl Aatutle}) Here halogen, ater ep) ow erecly, atlathed be ‘They ate. frst Classiyed o> ded monohalo arenes dxchalogn arent, — bethaloarents ek CI] a ct i em lid monchaloarenes Diralearene Tathaloarene + ® Side chaty ale Aexvakies Caralkiyt haletly Hexe he legend atom) ch atlached do dus geile Chasn conbon covoytng — te aey! gooup. om q os” a a axomokec yh benagt chloxde Bengal otcchloncé Bergotarchiexdle : Clossifcasion based on hygfextlzadcon. gcstow bonded to Jotoms | compounds Contagas Cx bong Cis "8 (Keb c,e2 On Cop —x bong , bong C~X bong Hp X Ons @Compds emtasiing iS ee ec eee These one find. clossifiid om to @ aks halide @ allyte house © beng y tee haltde . ®D Plkyl howe (_haloakane Ply hotwte — oe. fede. & lle’ hate Classifiid do do If ang@ Alig _habedes « @ Tw these. cases , the halogen atom B altached tow spa hgbotclined. corbow Atoms coluth 3 nent to @ carbon — carbon clouble bong Callgatc Corbon)) e Cts Ho—=cH—clbX C ® Bemytie habe - Tu fesse rates , the halogen atom & atladey to @ spi hytratelexed — anobon atom erect £0 Qn asomvatic xing (4 Bengylte carbon) on sf cs or ie: bemge(F Gengyt 2 beryyl C22) ® Compocuncls contasning C—K bond . 2. These compounds ave Just classified 4 to O vingl patrole @ Pag! bale » @Vingl —_ hakde tere. ha logens adoro A adacheol ¢o one G the Colbow atoms of the. carbon — carton clouble bord: eg CH, ==CH—X S Ge a Poy! habkde A how LoyCop. ‘Cuscth ct By tbc —cm & cfr tp eC ay & is at eae! Chey Ug —ev —~cho Rednghilene nlerccle (Gerretschiede Che — Ch Rethglene Licchrlooccta| te We —cithabite) Cer cH@IC’ (Cd clkg= cho} Clg —cH —Ch Br clo cla cHels veel 2 Oh ow Bor fom Nomendaguxe - RACERS gent, FoRAc name beh Boome! a (Get common a Deopme) CI m= Deheome borgene Gm) | 4” chucotolane. Coa) 1, 3 -Diboome dengena (Trac) | Broa 2- edt oy a-ch lore delene ip gine Tako mo bongene femmes) Kc Clg cl 15 3,5- Trbboomoboyene Os (p00)“ GOCuse Hee Sousteal formula, of al & stoaetucal” 6% ‘omens thot hove Cg Hy Bo Case Popa Gy names and also classify them as f, 2° o £ Gey Page 264-285) @ Gee #: @ 2- chloao ~ 8- meds pentane ® x Chievo —4-ednyleyclo hexane © 4- teot » Byutg!— 3-/edlokeptare @ V4-Bibsemo bat -2-ere © IH Bromo —4- geo. ebaidyl —9-meteyt benzene * Natuse 3 c—x bond Sti ralegen cb more —_eleetoonegaktve than ‘ce’, the bonded. pars g & beer cartow and x hes claret to ‘% atom. Bs a result Aatogen gels a shpat seg) negadtve —choage (8 and — condor get ys a ane chaage (89 ie c—¥* bord 8 poloadsed. On movthg Feors F@&e 2 Clectooncgatiutty dlecreases , ‘tharcfore poladtty ¢ CX bord and hence the ddpolemement — lerseasen Bat fox. clipelenroment- % Clgr SB het dower tran that~4 ae Pithough the magnitude g ut Chaageow =F? ahin & higher dha that of cl atom , dus do He small sie Sf —'F atom, §—0-£ bond chslance 3 80 small — chat the poodust 4, Chaage and uistance 4-2 — chipolemoment 3" Tower. On mourg foo F to Ff, SRL AcxensD dhantre C-xX bond len ge rheveasn foom C-F to ct and bond ersthotpy decreaso .Ww 4; Pavange CHF, CHacl, chsBe, CT 1 the incveastig cade © Potaatiy. © cLipole monreot- © bond lengits — @_ bond andaolpy . Metheds Prepaxation 4 Foom alcohols . Tovolves thie. cleavage g Con bom) ORES CE EAN ET halegoy acl Pand 2 alkyl ehlortdes canbe prepared by bvcatig dey hydeogen, chloricle trough a, Sdlution Q aleohol = oe by heating @ soluktong alcohol tm conantvated aqueous autd, th presen 3 abhyteous Xn. — Greovek _pooesss Chg oh + Hel @) Hees Cle +20 Gusot + Hel @ey Pbby- t Zoek, Q@rby. Finch. helps he Cleavageg C—O bond.) £ aleohols yeart wits cone Hel ab de absence B Knthe te af op + # dooney eevee Ol, yan) Alkyl-Geomides Cboomoaltanss) can fe prepared ettinn by weffuscing — a Suutfable. alcoho ae HBe (48%) 08 heakry wolf O» ralsotuve gy Bo” "Kd MSO ey Ocks cp on + Abe —Rebor MoS 0p. dilte) (2) Ma Be +h2 804 O85 NaHS%y +185 (site pecposalrir 180) Cl3cls of 4 HB2 —S_,@ Todoalkanes ose Prepared — by heading — ateohels wolhe Nel/ KT im ast phosphor acid . 2 HD» Nat, Py Na+ b,Poq Cols Of + HD As cust rH 20 (Catsow + NaPansPy a Gis? + NabaPe +40), CPosletd 3 HsPo% , 28% — ctunlt be used why 2) The ordug seartody 2 HX focoaeds eleoke ‘sn HI Harr Hh - Thy because % the gollors veasow. Dus fo tie bi oe gy TP, bond endialpy B HT — bond % vegy low. Theoefore HE caw be broken doww easily . The ot penekochy g aleohels focvands AXeg) O Srey lh + why 2 In Salecho/ , dur de fe +7 effet (elector releasing, +Trduckde effect) C-0 bond 3 bagily poled. Theodore. it can be hooker clown easily. Moyeover) 0222s porching carbocatton — foomecl C3 - corbocators) & haghly stable (due Ay per — coringation eect and +Defpfect) - The stabil 3 Carbom#fon ”. cohereas) ty ef aledhol = i. aes & ose tues © Renciton worth _phesphoous _ halides @ whe Pels- © wits Prls ©8 Gut PBs ® Pa + 6 Bog ——5 4-PBog . @wete Pls Pan bDr > Ply @_ boits $0Cl C qtxony! chloste) This & tha best metre! foo “he peeporation op alley! chtnide - Ds da gite — paodaucts Hel and $Q5 being — gases thay excope , leaving iekeid oo alkye hott 4h pure stato. Aryl hatiis C 7) cant be obtouried by renting Phenol Cpr) betty Halogen avis op phaspheous halen eg D 2 From hydrocarbons @ Ry free cada’ halgenakton ( substetubnc cemthesd Fra yackical — chloatnak'on O% beominaken of allleanes ques a complen mixture of and — poly halealkanes, utah ty as pure compounds . an one fsomeste monc— aiffreult to sepovate Consequentty , the yield oF compound % Joco. ha CHa +o weeks Cl-# Cache. + CHels + CCly CHSC CI. Cl ph Cle ch ca clad + Cl3—clecH mony , o (he casey subsitunis, vows Hd s>2> a> Docinak’on & movying out 4o — prosenw B an om Lek Hes /HI03c 7). Chey Py EET +E SHI + ML03—_¥ 37> 4.34120" ® From alkenes. © Adcuiton hydoegen Walsteo C Hel, Hao, HD Che —=cla + Hel pee CH3—CH== CHa It Bx Clb — ch —=Ch a 4Bo Perera pepo» (Cia pect) OAddoifon g halogens . Clz——cHa, +Be2 Sct 5 Reddath boown colon 4 Boa of chschoagad dine fo formals 3 cofeusless udcewal — eibpomide « Thestfore dont Leoehnd Can be used as a best $F unsaturation (to cetect the Presence eh = = bond ty an organic compouncl) © by halogen, exchange todealkane cow be obtained by bveatilg §— b20mo~ % chlozealkane — witty @ — goludtong Na? co acetone oh eaehanae SELLE S 2 s and R~ x Bo RB+ Nay ( yacl,m) Thad kenthh 5 called Finkel ste’ zeachbn »CHa + war 22h cus 7 +vack SS Chg Ge + Wat Aube CYT 4 WABy Than seakon based on dhe foe teak Nal és soluble in Bares acetone hub Nakr and Nak wt ; Thee. efriliateuro Shife ro foe foredaed Lives C back evored Acactrow can be prevented). ( kuehakiert parepe) Plkye fluatle connot be pupawd by clveet” eplucxnakes g alkanes. However, flucaoalkanee Cao be obtained by treating — alky! halides catty salts Suth os — AgF , Hy Fo » Co 08 Sbfg- This veackln B& Kroww Os Susarts seactron. Cus Bo + Ag ——y CHBF + Ag Be 2 Cosh + Hg,F2 ——? 2C2HsF + HBCly. Preparation Haloorenes - © By rect — halegenakor. — Klecleephaiit. sub veaehe=- Pagt chicatlo an be, peepoted by Creokeg §— avomake hgdrocorbons — usite «Ch. Presene g leo auds oy of fe sue of “Alcls 0 els Fad 4D The abhsna 4 Sunkghr - ut Lp Ree Gree aur CG! Be Pagl bomidis can be oblosned by txcaling avomolic. hycuventhry se +t Baz th proseneg R ov RBo Ol Ge es PT fio) +HBo - femp 3/0-320k