You are on page 1of 26

Andean Past

Volume 5 Article 17

1998

Lithic Provenience Analysis and Emerging Material


Complexity at Formative Period Chiripa, Bolivia
David L. Browman
Washington University, St. Louis, dlbrowman@artsci.wustl.edu

Follow this and additional works at: http://digitalcommons.library.umaine.edu/andean_past


Part of the Archaeological Anthropology Commons, and the Architectural History and Criticism
Commons

Recommended Citation
Browman, David L. (1998) "Lithic Provenience Analysis and Emerging Material Complexity at Formative Period Chiripa, Bolivia,"
Andean Past: Vol. 5, Article 17.
Available at: http://digitalcommons.library.umaine.edu/andean_past/vol5/iss1/17

This Article is brought to you for free and open access by DigitalCommons@UMaine. It has been accepted for inclusion in Andean Past by an
authorized administrator of DigitalCommons@UMaine.
LITHIC PROVENIENCE ANALYSIS AND EMERGING MATERIAL COMPLEXITY
AT FORMATIVE PERIOD CHIRIPA, BOLIVIA

David L. Browman
Washington University - St. Louis
Introduction tions. The Formative Period occupation of the
site may be defined by 28 dates from 5 radio-
Technical analyses of lithic artifacts from carbon labs and 1 TL lab, listed in Table 1.
the Formative Period component of Chiripa, Christine Hastorf and her students have re-
on the south shore of Lake Titicaca, Bolivia, cently begun a new series of excavations at the
indicate a number of items of non-local pro- site. Additional dates no doubt will be forth-
venience. Among the items originating from commg.
considerable distances, up to 300-500 Ian
from the site, are copper ores from the arid The ceramics from Kidder's excavation
Pacific coast, obsidian from the punas of Are- were analyzed by K. L. Mohr for her Master's
quipa and Puno, sodalite from Cochabamba, thesis. She proposed three phases: Pre-Mound
and basalt from Lake Poop6. Construction or Sub-House level, 1400-900 b.c. (un-
stone employed in the facing. and temple calibrated); Lower House level 900-600 b.c.;
walls, weighing up to 4.5 tons, may have been and-Upper House level 600-100 b.c. (Layman
extracted from quarries as far as 80 Ian distant and Mohr 1965:200; Mohr 1966:3). Recently,
by water. The identification of the systems by she has renamed these phases Early, Middle,
which the Chiripa inhabitants obtained these and Late Chiripa (Mohr"Chavez 1988:18).
materials may serve to clarify the integration
of the Chiripa polity with its neighbors, and its Chiripa ceramics, when fIrst reported,
contributions to the development of the subse- were unique in having fiber temper, mainly
quent Tiwanaku federation. ichu grasses (Stipa sp. and Festuca sp.). Thus,
for many years, fiber tempered wares in the
The setting and chronology south-central Andes were characterized as
being derived from Chiripa, an interpretation
Chiripa is an Upper Formative, or an Ini- now fortunately mainly abandoned. In our
tial Period and Early Horizon phase occupa- excavations, we identified a non-fiber tem-
tion and temple site on the south end of Lake pered ware component pre-dating the fiber
Titicaca in Bolivia, at 3835 m or 12,580 ft temper phases. New phase names taken from
elevation (Figures 1, 2, and 3). During the the local landowners of the site were em-
later Tiwanaku federation period, the site was ployed to facilitate distinction between pre-
re-utilized. Initial test excavations were con- . fiber tempered and fiber tempered phases and
ducted by W. C. Bennett (1936); A. Kidder II to include other new archaeological elements
(1956) carried out subsequent excavations; in their definition. -

and the current report is based on a joint


American-Bolivian project in 1974-75 di- The traits defining these phases are de-
rected by the author and Gregorio Cordero rived from ceramic (Browman 1980), ar-
Miranda (Browman 1978a, 1989a, 1989b). chaeobotanical (Browman 1989b), zooarchae-
ological (Browman 1989a), and architectural
The first series of radiocarbon determina- (Browman 1978a) criteria. For example, the
tions for Chiripa was a suite of 14 dates sub- Condori phase (1350-850 b.c.) is defmed in
mitted by Kidder from his excavation units in part by such ceramic traits as grit-tempered
the upper levels of the mound (Ralph 1959:56- (sand and crushed sandstone with micaceous
57). An additional 14 radiocarbon assays and inclusions) ware, neckless ollas, rare decora-
10 thermoluminescence determinations have tion of red slips and occasional incised de-
been run on samples from the 1974-5 excava- signs, and vessels with round bases and basal

ANDEAN PAST 5 (1998):301-324.


ANDEAN PAST 5 (1998) -302

lugs. The shift from Condorill (1350-850 southern lake basin Formative Period sites
b.c.) to LluscolIl (850-650 b.c.) can be identi- such as Chissi and Titimani also have subter-
fied by new vessel and temper categories, but ranean temples. The mound began as a rather
it is equally as evident in the archaeobotanical typical sort of accretional habitation site,
record (Browman 1989b:142), where a second where centuries of refuse accumulation along
chenopod species is added (provisionally with the disaggregation of adobe and/or tapia
identified as caniwa as well as quinoa), ama- mud construction resulted in an accumulated
ranth first appears, and some more minor deposition rising three to four meters above,
weedy taxa first occur. It can also be identi- the surrounding fields. Evidence from our test
fied zooarchaeologically as part of a pattern cuts, supplemented by data from Bennett's and
displaying a shift to greater dependence on Kidder's work, indicate that the north side, and
lacustrine species. Fiber temper, which may at least portions of the east and west sides of
first appear late in Condori/IB, becomes a sig- this mound (if not the entire mound), were
nificant ware in LluscolIl (850-650 b.c.), later faced and enclosed with a stone wall, re-
along with the addition of such traits as ring sulting in a roughly rectangular ground plan
bases and flat-bottomed vessels. Classic configuration (Figures 2 and 4). This event
Chiripa style decorations typify Mamani/IIIA occurred near the beginning of Mamani/IIIA,
(650-350 b.c.), the period of first temple con- based on evidence from one of our test units
struction and the appearance of the double which cut the north wall (Unit I, Figure 2).
wall . bin-storage houses; and at the end of Half a meter on the inside of the base of this
MamanilIlIB (350-50 b.c.), Tiwanaku I-like wall is the oldest radiocarbon assay of 1530
ceramics are first identified. b.c. :!::180, while the stratum on the exterior
associated with the wall construction trench
Correlation . between 'Mohr Chavez's has a TL assay of 640 b:c. :!::390 and a 14Cas-
phases and the Condori, Llusco and Mamani say of350 b.c.:!::155.
phases is aided by the fact that our project de-
liberately placed excavations (Unit II, Figure My initial interpretation was that the visi-
2) below Kidder's House 2 and 3, and Lower ble subterranean temple (Figures 3 and 5) was
and Sub-lower Houses 1 and 2, which are the constructed at this point as well. Much of the
basis of Mohr's three ceramic phases. Eight of construction stone from Chiripa has been
the radiocarbon determinations for Condori robbed and recycled in lat~r sites in the area.
and Llusco phases were derived from samples Opportunistic samples were taken from the
in Unit II under the Sub-lower houses. The remaining stone, and submitted to Dr. Ernest
assignment of the "pre-mound" Pennsylvania Ehlers for x-ray diffraction (XRD) and thin-.
dates as CondorilIB is based on their ap- section microscopic analyses. Three different
proximate stratigraphic location in this same building stone materials were identified: ande-
excavation unit. Inspection of the ceramics
. site, limestone, and sandstone. No geologic
illustrated by Mohr (1966) suggests that her origin voucher specimens were taken, as at
Early (or Pre-Mound), Middle (or Lower that point we had no idea where quarries
House), and Late (or Upper House) Chiripa might be located.
ceramic phases are roughly equivalent to Con-
dorilIB, LluscolIl-Mamani/IIIA, and Mamani/ Andesites were rare in our sample and
IIIA-IIIB. were confined to only a few small-sized quar-
ried stones. Three major areas of andesites are
Building stone and construction phases near the "Little Lake" or Lago Pequeno sec-
tion of Lake Titicaca. There are also some
Chiripa architecture is significant, in terms minor outcroppings south of Tiwanaku (Fig-
of our current knowledge of Titicaca basin ure 1). Based on the specific inclusions and
Formative villages, in having a rectangular characteristics of the specimens submitted for
stone-faced mound on which first domestic analysis, Dr. Ehlers indicated that they were
dwellings, and later a subterranean temple most similar to the andesites described for a
were constructed. It is not unique: other source near the town of Copacabana (Newell
303- Browman: Formative Period Chiripa

1949; Mogrovejo Terrazas 1970). While vis- sampled were 4.5 and 3.3 tons, while the two
ual inspection of the map suggests that, as the largest limestone ashlars sampled were 2.5
crow flies, it is only 30 Ian to this andesite and 1.7 tons. These are the largest remaining
source, because of local topographic features, stones in the temple floor plan map (Figure 3).
the stone source is most readily reached by a Weights were determined by computing the
lake voyage of about 80 Ian to a quarry on the volume of the whole ashlar, multiplied by the
north side of the peninsula. There is presently specific gravity determined from a sample of
no evidence that andesite was transported by that ashlar.
the more direct route over the intervening high
hills. There are three major sandstone forma-
tions around the "Little Lake" (Newell 1949),
Analyses of andesites associated with as illustrated in Figure 1: the Cabanillas (of
Ponce Sangines's Tiwanaku III (a.d. 133-374) which only a portion near Cumana Island is
and IV (a.d. 375-724) phases at the site of Ti- included on the map), the Taraco (along the
wanaku indicated that these construction Taraco peninsula just south of Chiripa), and
stones also were quarried from the Copaca- the Puno (along the south side of the Little
bana peninsula, from the Yunguyo and Copa- Lake). Because of the proximity of the Taraco
cabana area sources illustrated in Figure 1 Formation to Chiripa, I initially assumed that
(Mogrovejo Terrazas 1970:251; Ponce Sangi- all the sandstones would prove to be derived
nes and Mogrovejo Terrazas 1970:274). from this source. Based on inclusions in the
Ponce Sangines (1970a:75, 142, 146, 1971:90) samples, however, Ehlers indicated that in ad-
reports blocks as heavy as 11 to 16 tons were dition to Taraco materials, sandstones from
first rafted by balsas (lake boats made from the Puno Formation were utilized as well, a
bundles of totora, a cattail-like reed) from Co- source which for Chiripa would be most effi-
pacabana, through the straits of Tiquina, to the ciently exploited via water transport. Signifi-
prehistoric lake port of Iwawe some 95 km by cantly, much of the sandstone employed later
water, and then dragged another 22 Ian over- at Tiwanaku (a.d. 500-1100) also came from
land from Iwawe to Tiwanaku. Movement of the Puno Formation (Avila 1971:226; Casta-
these massive blocks on and off the balsas, nos 1971:212; Urquidi 1971:234).
without .capsizing, was difficult; several ash-
lars, lost in off-loading, help define the quay Limestone construction blocks from
and pier of the Iwawe port. . Chiripa were quarried at' some distance, be-
cause there are no nearby sources on the pen-
Limited observation of the shoreline di- insula. XRD and thin-section microscopy of
rectly in front of Chiripa failed to reveal any the limestone samples submitted to Dr. Ehlers
evidence of similar off-loading patterns. for analysis indicated that these limestones
There is a linear levee or aqueduct which runs were all from the Copacabana Formation.
from the mound area north to the lake (Graf- This Formation crops out along a fault line
fam 1990:138-150). This seems to be the which abuts the south side of the Straits of
logical route for transport of the stone from Tiquina on the Copacabana Peninsula and runs
the lake to the temple. If dock facilities existed south through Cumana Island. Because For-
at Chiripa, they may have been somewhat re- mative Chiripa ceramics had been reported by
moved from the immediate foreshore, or may Bennett and others on sites on Cumana Island,
have existed at a different lake level; we know my original interpretation was that limestone
that in the last 50 years, Lake Titicaca levels was quarried on the island, and transshipped
have varied more than 5 meters. by the balsas to the shores below Chiripa. But
Chiripa wares also have been identified from a
The most common building stones re- number of sites on the Copacabana peninsula
maining at Chiripa were limestone and sand- by Gregorio Cordero Miranda, John Hyslop,
stone. Centuries of stone-robbing prevent ac- Karen Mohr Chavez, Sergio Chavez, Charles
curate reconstruction of importance. The two Stanish, and others. Neither area of limestone
largest sandstone ashlars opportunistically outcropping can be specifically identified as
ANDEAN PAST 5 (1998) -304

the source at this point, but access to either Bennett and Kidder, there was evidence of a
requires water transport of the construction later Tiwanaku Period retaining wall, with
stone. Ponce Sangines (1970a:62) reports that vertical ashlars set at intervals, with the
limestone employed at the site of Tiwanaku smaller rectangular stone laid between them
comes from this same Formation, which also (Figure 5), very typical of "Classic" Tiwanaku
occurs at some isolated outcrops in the Pampa architecture at the Tiwanaku type site. (By
Koani and Tambillo area (two of which are 1974, utilization of the site by the current vil-
shown in Figure 1). Thus the Tiwanaku ma- lage residents as an adobe fabrication "mine"
sons seemed to have continued exploitation of had left the stones from this wall in a dis-'
the same sources of limestone as the Chiripa turbed array.)
masons.
The extant, visible semi-subterranean tem-
While some of the sandstone may have ple in the center of the Chiripa mound, meas-
come from deposits directly behind Chiripa, uring 21.3 m by 22.6 m, employed vertical
other sandstone blocks came from Puno For- ashlars along with horizontally laid smaller
mation deposits 20-30 km by water to the stones. Most of the 1,450 cubic meters of fill
southwest. The limestone blocks came from removed from this temple was disturbed, but
Copacabana Formation sources 20-40 km by near the base of the walls we recovered some
water to the northeast and the andesite appears intact zones and floors of Tiwanaku III refuse,
to have derived from a quarry to the north indicating a Tiwanaku III (a.d. 133-374) Pe-
which is most readily reached by a water route riod. of construction for this version of the
of 80 km in length. These data indicate that temple. During cleaning of the temple floor,
the masons of the semi-subterranean temple at we sank a test cut in the northeast comer to
Chiripa did not have a single.preferred source, assess floor construction sequences. Much to
but rather secured building stone from a wide our surprise, we found evidence of an earlier,
number of sites around the "Little Lake", no deeper temple wall set back almost half a me-
doubt in part based on ease of access to the ter from the later Tiwanaku phase temple
shore. At this point in the analysis, it seemed walls (Figure 6). Evidence of this earlier tem-
that the pattern of quarrying andesite, sand- ple also appears in profiles of Bennett's test
stone, and limestone blocks of substantial size trench. Steel rod probes at half a dozen places
had first" been initiated during the Mamani around the perimeter of the Tiwanaku III
IlIA or Classic Chiripa phase, and continued phase temple suggest that this earlier structure
unchanged on into Tiwanaku Period construc- was probably similar in outline to the Ti-
tions. wanaku phase building, but slightly larger,
roughly 23 m by 24.5 m. Ceramics recovered
As work continued, it became possible to from the test cut in the northeast comer indi-
differentiate some construction techniques of cated the earlier structure was Classic Chiripa
Chiripa masons from those of Tiwanaku ma- or Mamani phase. Alan Sawyer (1981), who
sons.1 The Mamani phase retaining wall on worked as a member of Kidder's project, re-
the north side of the mound, as exposed in our ported that portions of the walls of the upper
test cuts, as well as in Bennett's work, con- Chiripa houses uncovered in their excavations
sisted of relatively small, partially coursed had been leveled off, and the houses packed
rectangular blocks (Figure 4). In unpublished with backfill from temple construction. These
. photographswhich GregorioCorderoMiranda data indicate that the second, Tiwanaku phase,
provided, as well as in the excavation cuts of temple was constructed after the abandonment
of the mound, with the mound top leveled off
and a new retaining wall constructed around
IClassic Tiwanaku style temple construction involves the exterior.
vertical ashlars with various types of coursed infilling.
For examples, see Manzanilla's work (1992) at the The evidence of two distinct periods and
Akapana, or Ponce's various publications on the Kala- styles of temple construction and mound fac-
sasaya. ing raised the question whether the magnitude
305- Browman: Formative Period Chiripa

of long-distance transport of massive building local sandstones from the hills behind the site
stone initially posited for Mamani phase in were used, and andesites likely from the Co-
fact pertained to that period or to the later Ti- pacabana quarry 80 km by water to the north
wanaku rebuilding. Most of the large ashlars were also employed. Because the style of
of limestone and sandstone that we had sam- construction of the second subterranean tem-
pled were the vertical ashlars of the typical ple at Chiripa is similar to the Tiwanaku III
Tiwanaku style construction. On the other phase Semisubterranean Temple at the pres-
hand, a 0.6 ton, Pajano style sandstone mono- tigous center of Tiwanaku, it is not surprising
lith (Browman 1978b; Cordero Miranda that the materials utilized closely match those
1977), characteristic of Mamani phase sites previously identified for the developing capi-
around the Little Lake, was found recycled as tal. The sandstone from the Puno Formation,
a vertical ashlar in the later Tiwanaku style which is closer to the Tiwanaku center, might
temple, with its decorated side buried facing have been brought to Chiripa by masons and
the wall fill and its undecorated backside their crews coming from Tiwanaku to super-
showing. Thus we know that at least some vise the temple's construction.
large sandstone ashlars were quarried in Ma-
mani III times. The only andesite pieces Metal and ores
which can securely be placed as Mamani
phase are small (under 20 kg); and unfortu- A total of 31 gold, copper, and tin-copper
nately, none of the large limestone ashlars we bronze metal and copper-mineral items were
sampled could be definitively associated with recovered during our Chiripa excavations.
the earlier constructions. Nonetheless, the Silver is known from Formative Period levels
Mamani phase Chiripa residents were quarry- at Tiwanaku but was not recovered in our test
ing substantial quantities of stone. Although units. Although gold has been reported from
most of the wall stone subsequently has been Formative Period sites elsewhere in the south
robbed, the few remaining sections of the Ti- central Andes as early as 2,000 b.c., the only
wanaku Period temple indicate that approxi- gold from stratigraphic contexts found in our
mately 200 tons of stone were required for that Chiripa work came from Tiwanaku III con-
temple building. If the earlier temple is of the texts; Bennett (1936) also reported finding
same magnitude, as our probes suggested, then gold in Tiwanaku Period burials at the site.
it also required roughly the same quantity of Copper ore and copper artifacts, however,
quarried stone. The Mamani Period exterior were recovered from the earlier Chiripa
facing walls of the mound may have required phases: two items from Condori IB contexts
as much as 5 to 10 times more stone, depend- (1250-850 b.c.) and one from Mamani IIIB
ing on height and dimension estimates, and components. In addition, Bennett (ibid:433)
whether they enclosed all four sides or not. A excavated a Classic Chiripa phase burial
similar quantity should be projected for the which had copper, stone, and bone beads
Tiwanaku Period facing walls. around each ankle. Thus, we have good evi-
dence for copper metal use during the Forma-
A revised construction sequence model tive Period.
would suggest that the Mamani Chiripa build-
ers at 600 b.c. were principally using sand- Gold and copper metal artifacts, as well as
stone, along with minor amounts of other a number of the turquoise and sodalite items,
building stone. The Tiwanaku III Period were recovered from the 1,450 cubic meters of
Chiripa area residents, who rebuilt the temple disturbed temple fill excavated. While 95% of
ca. a.d. 300-400, chose or found themselves the artifacts from the temple fill were Mamani
forced to secure the large vertical ashlars from or Classic Chiripa, the other 5% included Ti-
more diverse sources. Limestone blocks came wanaku III, IV and V, Inca, Colonial, and
from the Copacabana Formations 40 Ian to the even 20th century artifacts. It is tempting to
east. Some sandstones were acquired as far as assume that because most diagnostic artifacts
30 Ian away from the Puno Formations at the in the temple fill are Mamani phase-related, it
southwest end of the Little Lake. In addition, is therefore likely that most of the metal arti-
ANDEAN PAST 5 (1998) -306

facts could also be Mamani phase. However, tion of brochantite and antlerite with the For-
the disturbed nature of the deposit makes this mative occupations, with local ores appearing
an uncertain proposition. only in the later phases, suggested a possible
initial development of this technology in
During recent historic periods, copper was northern Chile, with a subsequent adaptation
extracted from several mines in the Titicaca of the technology by the altiplano cultures.
Basin. Four mines are known in the immedi- This interpretation seems to be reinforced by
ate Chiripa/Tiwanaku vicinity (Ponce Sangi- Ruppert's (1982, 1983) identification of the
nes and Mogrovejo Terrazas 1970:220-223), known turquoise sources as also North Chil-'
so the early occurrence of copper in the ean.
Chiripa site seems reasonable. The ores from
the local mines are carbonates including azu- Analyses conducted on our other Bolivian
rite and various copper sulfides. However, by samples replicated the pattern observed at
XRD and microscopy, Ernest Ehlers identified Chiripa. We secured two copper ore samples
copper ore samples from the Condori IB and from the Formative Period sites of Chullpa-
disturbed temple fill as being brochantite, and pata and Santa Lucia in Cochabamba while we
he also identified as brochantite a Formative were collecting comparative ceramics speci-
specimen from Kidder's excavation provided mens from cuts made by William Kornfield,
by Alan Sawyer at my request (Ehlers, report and two additional samples were acquired
of June 15, 1976). Brochantite is aform of from the Putuni and Pumapunku structure ar-
copper mineral which only occurs in ex- eas ~t the Tiwanaku site. The ore sample from
tremely arid areas. In reviews of the geologi- Chullpapata included a mix of brochantite and
calliterature, both Ehlers (personal communi- antlerite, and the sample from Santa Lucia was
cation, June 15, 1976) and Heather Lechtman brochantite. Antlerite, .like brochantite, was
(personal communication, April 25, 1977)'re- only known from arid areas such as the north
ported that the closest known sources for this Chilean coast according to the sources avail-
mineral are along -the Pacific Coast, from a able to Lechtman and Ehlers in 1975. Hence
series of mines in the north Chilean desert the two ore samples from the Cochabamba
along the Tarapaca-to-San-Pedro-de-Atacama area appeared to reinforce a possible pattern of
axis, as well as in some of the southern Peru- initial association of Chilean ores with For-
vian mines in the Arequipa area, although it as mative Period sites in Bolivia. The ore sample
not as typical of the Peruvian mineral beds. from the Putuni temple/palace area of Ti-
wanaku included antlerite, brochantite, and
There also is evidence of exploitation of cuprite, while the second sample from the
local copper ores at Chiripa. A Tiwanaku Pe- Pumapunku temple/palace area was brochan-
riod ore sample from our excavations at tite. These data, taken in conjunction with the
Chiripa was identified as azurite by Ehlers. information from Chiripa, suggested that if
One specimen of azurite ore was identified antlerite and brochantite were in fact most
among the Chiripa samples from Kidder's ex- typical of copper sources from the arid north
cavation, supplied to Ehlers at our request by Chilean coast, that as early as 1200-1000 b.c.,
Alan Sawyer. In an earlier XRD analysis on a Chile was a significant supplier of such ores to
sample from Tiwanaku, malachite was identi- the Bolivian altiplano and valleys, and the
fied (Sawyer, personal communication, Janu- coastal sources continued being important un-
ary 29, 1975). These findings suggest that til a.d. 500 if not later. Locally available Titi-
local Titicaca basin ore sources were being caca basin ores, such as azurite and cuprite, at
exploited by the first centuries A.D., if not least in our extremely small sample, do not
earlier. With copper ores readily available in seem to have begun to be extensively ex-
the immediate area and exploited during Ti- ploited until perhaps as late as 100 b.c.-a.d.
wanaku and later phases, the occurrence of 100, a surprising situation, considering Ponce
apparent Pacific coast copper ores, such as Sangines's argument in several publications
brochantite and antlerite, seemed almost a that an indigenous copper smelting industry
"coals to Newcastle" situation. The associa-
307- Browman: Formative Period Chiripa

was well entrenched in this part of the alti- copper ores of brochantite could thus derive
plano by 1200 b.c.2 either from the coastal Chilean-Peruvian
sources or the Corocoro area, although the
After presenting this model of Formative Formative Period antlerite ores presumably
utilization in the Bolivian altiplano of copper indicate coastal origin. Thus Chiripa might be
ores from North Chile in several papers, I now obtaining at least part of its copper minerals
have new evidence which will require modifi- from the Corocoro source area, but it appears
cation of this hypothesis. While brochantite that the Formative Cochabamba sites might
and antlerite are most typical of Chilean mines still be characterized as securing copper mate,:,
300 to 500 km southwest of Chiripa, at least rials from Chile.
brochantite is found as a less common copper
mineral at the Bolivian mine of Corocoro, Beads and pendants: cbrysocolla, sodalite
only 100 air km south of Chiripa.3 Formative and turquoise

Of the 24 beads and pendants recovered in


2Much of Carlos Ponce Sangines'model of extensive
.
our excavations, 16 were blue and green,
copper utilization by 1200 b.c. isJ:>asedupon material mainly copper-mineral based stone. This
which he identified as "escoria" or copper slag at the blue-green mineral group was initially divided
site of Wankarani, in a level dated between 1210 b.c. into three categories in the field: malachite,
and 800 b.c. However, Marc Bermann (1995) reports turquoise, and sodalite. These artifacts remain
that. from his Wankarani culture site .at La Joya, he in the national museum in La Paz. However,
submitted 34 samples of "scoria" apparently identical to some of the items were damaged by the
Ponce's. material, which Bermann thus assumed was workmen during excavation (the National Mu-
copper slag. Test results indicate that none of these seum-trained crew insisted that Bolivian
samples proved to have any copper. Rather they appear regulations required picks and shovels, rather
to be a type of natural pyroclastic tufa. Thus the basis than trowels), and the resulting small chips
for an extensive early copper smelting industry in the recovered were thus available for analysis.
early formative period of .the Bolivian altiplano seems
now very much open to question. True "chemical" turquoise is a specific
crystalline compound of copper, but "cultural"
3Richard H. Sillitoe, Consulting Economic Geologist of turquoise may include a wide range of other
London, who has written extensively on the copper copper-bearing blue and green stones, such as
industry of the Andes, has offered some fine-tuning malachite, azurite, chrysocolla, and the like.
suggestions. He writes (Personal communication, Feb- Four turquoise artifacts were recovered in our
ruary 22, 1992): Chiripa excavations; the three artifacts for
"Brochantite and antlerite only form by oxidation which samples were available were identified
of chalcocite in the presence of pyrite. Chalcolite nor- as true chemical turquoise. No published
mally forms by supergene enrichment in arid to semi- identification or characterization of Andean
arid climatic regions. The major chalcocite zones turquoise sources was available for the geo-
(blankets) in northern Chile (e.g. Chuquicamata) and logical consultants of the project when they
Southern Peru (e.g. Cerro Verde in Arequipa) were
generated in the Oligocene-mid Miocene (25-15
m.y.a.), and were then fossilized by intensifying aridity Cuprita), which is not linked to intrusive activity but
(hyperaridity). The brochantite and antlerite formed in generated in red clastic sediments by migration of cen-
oxidized zones above, and at the same time as, the nate brines. Moreover, brochantite is reported as an
chalcocite blankets. 'oxidation production of chalcocite at Corocoro.
"Hydrothermal copper deposits related to intrusive "So you have two options: brochantite from Coro-
activity on the Bolivian altiplano (e.g. La Joya) were coro or brochantite from Chile/Southern Peru. The
only emplaced after the cessation of this major chalco- former seems more likely, although pre-Colonial ex-
cite-forming event, so are unlikely to contain brochan- ploitation of oxide copper (including brochantite) was
tite and antlerite. However, chalcocite (with local py- widespread at Chuquicamata. I'm not sure about Cerro
rite) formed as a bynogene (primary) ore mineral at Verde."
Corocoro (and nearby smaller deposits, e.g. Chacritas,
307- Browman: Formative Period Chiripa

was well entrenched in this part of the alti- copper ores of brochantite could thus derive
plano by 1200 b.c.2 either from the coastal Chilean-Peruvian
sources or the Corocoro area, although the
After presenting this model of Formative Formative Period antlerite ores presumably
utilization in the Bolivian altiplano of copper indicate coastal origin. Thus Chiripa might be
ores from North Chile in several papers, I now obtaining at least part of its copper minerals
have new evidence which will require modifi- from the Corocoro source area, but it appears
cation of this hypothesis. While brochantite that the Formative Cochabamba sites might
and antlerite are most typical of Chilean mines still be characterized as securing copper mate-
300 to 500 km southwest of Chiripa, at least rials from Chile.
brochantite is found as a less common copper
mineral at the Bolivian mine of Corocoro, Beads and pendants: cbrysocolla, sodalite
only 100 air km south of Chiripa.3 Formative and turquoise

Of the 24 beads and pendants recovered in


2Much of Carlos Ponce Sangines' model of extensive our excavations, 16 were blue and green,
copper utilization by 1200 b.c. is J:>asedupon material mainly copper-mineral based stone. This
which he identified as "escoria" or copper slag at the blue-green mineral group was initially divided
site of Wankarani, in a level dated between 1210 b.c. into three categories in the field: malachite,
and 800 b.c. However, Marc Bennann (1995) reports turquoise, and sodalite. These artifacts remain
that from his Wankarani culture site at La Joya, he in the national museum in La Paz. However,
submitted 34 samples of "scoria" apparently identical to some of the items were damaged by the
Ponce's material, which Bermann thus assumed was workmen during excavation (the National Mu-
copper slag. Test results indicate that none of these seum-trained crew insisted that Bolivian
samples proved to have any copper. Rather they appear regulations required picks and shovels, rather
to be a type of natura~pyroclastic tufa. Thus the basis than trowels), and the resulting small chips
for an extensive early copper smelting industry in the recovered were thus available for analysis.
early formative period of the Bolivian altiplano seems
now very much open to question. True "chemical" turquoise is a specific
crystalline compound of copper, but "cultural"
3Richard H. Sillitoe, Consulting Economic Geologist of turquoise may include a ~de range of other
London, who has written extensively on the copper copper-bearing blue and green stones, such as
industry of the Andes, has offered some fine-tuning malachite, azurite, chrysocolla, and the like.
suggestions. He writes (Personal communication, Feb- Four turquoise artifacts were recovered in our
ruary 22, 1992): Chiripa excavations; the three artifacts for
"Brochantite and antlerite only fonn by oxidation which samples were available were identified
of chalcocite in the presence of pyrite. Chalcolite nor- as true chemical turquoise. No published
mally forms by supergene enrichment in arid to semi- identification or characterization of Andean
arid climatic regions. The major chalcocite zones turquoise sources was available for the geo-
(blankets) in northern Chile (e.g. Chuquicamata) and logical consultants of the project when they
Southern Peru (e.g. Cerro Verde in Arequipa) were
generated in the Oligocene-mid Miocene (25-15
m.y.a.), and were then fossilized by intensifying aridity Cuprita), which is not linked to intrusive activity but
(hyperaridity). The brochantite and antlerite fonned in generated in red clastic sediments by migration of cen-
oxidized zones above, and at the same time as, the nate brines. Moreover, brochantite is reported as an
chalcocite blankets. oxidation production of chalcocite at Corocoro.
"Hydrothennal copper deposits related to intrusive "So you have two options: brochantite from Coro-
activity on the Bolivian altiplano (e.g. La Joya) were coro or brochantite from Chile/Southern Peru. The
only emplaced after the cessation of this major chalco- fonner seems more likely, although pre-Colonial ex-
cite-fonning event, so are unlikely to contain brochan- ploitation of oxide copper (including brochantite) was
tite and antlerite. However, chalcocite (with local py- widespread at Chuquicamata. I'm not sure about Cerro
rite) fonned as a bynogene (primary) ore mineral at Verde."
Corocoro (and nearby smaller deposits, e.g. Chacritas,
ANDEAN PAST 5 (1998) -308

conducted their studies in 1975; thus a place to be from Cerro Sapo. Bennett (1936:433)
of origin could not be determined. However, reported excavating a flexed burial from Clas-
since that time, Ruppert (1982:73, 1983:102) sic Chiripa deposits, "around each ankle were
has conducted a series of trace element analy- beads of lapis-lazuli, bone and copper". As
ses and believes that the cultures of Northwest sodalite is locally mis-named lapis-lazuli, pre-
Argentina and Bolivia, including Tiwanaku, sumably these anklet beads also are sodalite.
obtained the greater part of their turquoise
from deposits in northern Chile: from the Ehlers analyzed three additional sodalite
Chuquicamata area, including the mines of samples that we had collected: one each from'
Chuquicamata, EI Abra, and EI Salvador; from the Tiwanaku phase deposits of Tiwanaku, the
a presumed mine east of Arica; and from still , Tiwanaku phase deposits at Lukurmata, and
unknown other Chilean mines. The Chiripa the Formative Period midden of Chullpapata,
materials no doubt were obtained from these Cochabamba. XRD tests on these samples
same North Chilean turquoise mines. indicated Cerro Sapo origin. Sawyer (per-
sonal communication, January 29, 1975), has
The class of six items field-categorized as documented sodalite from in his collections
"malachite" proved to be a variety of copper- from Tiwanaku through XRD, and Ponce
based minerals other than malachite, when Sangines has reported in a number of publica-
appropriate thin-section and XRD analyses tions on other samples of Cerro Sapo sodalite
where performed on samples submitted. Two from Tiwanaku. At this point, all chemically
of these samples were identified as chryso- identified samples of sodalite from the Boliv-
colla -- one from Mamani/IIIB strata deposits, ian altiplano have proved to be from the Cerro
and the other from the temple fill. The initial Sapo source. Ruppert (1982:74, 1983:103)
chemical analysis of the chrysocolla suggested reports that the sodalite from prehistoric sites
that the mineral was in two phases, most typi- near Andahuaylas and in the Asia Valley in
cal of an artificial process, such as faience fab- Peru, as well as the Quiani complex of Arica,
rication in Egypt. . This tentatively was pro- Chile, are also from Cerro Sapo; some of these
posed by Ehlers as possible evidence for a samples are associated with deposits believed
previously unreported technology, but subse- to date back almost four millennia, suggesting
quent analyses by Zimmerman and Ehlers in- that the trade in sodalite from Cerro Sapo pre-
dicated that the samples had not been heated d~tes the origins of Chiripa by half a millen-
prehistorically, and that the two phases were mum or more.
due to natural processes. Another sample of
the field category "malachite" was identified Trade in Cerro Sapo sodalite items thus
as chlorite and calcite, and a fourth as cuprite. has a long duration in the Bolivian altiplano.
Fragments were not available for the other two Sodalite was exchanged on a continuing basis
items, so the complete re-definition of the between the Cerro Sapo source in the '
field category "malachite" may be even Ayopaya area of Cochabamba 225 air km east
broader. of the Titicaca basin and other Andean centers
for minimally 2,500 years (based on Chiripa
In order to assist in verifying the six so- data) and more than 4,000 years (based on
dalite artifacts collected for evaluation, I ob- external reports), and continued to be a sig-
tained a voucher piece of sodalite from the nificant jewelry item through Tiwanaku V oc-
Cerro Sapo mine in Cochabamba, which was cupations or later, or at least as late as a.d.
used for the type material against which 1100. Turquoise, chrysocolla, and other cop-
Ehlers tested the sodalite category materials per mineral-based artifacts may be part of the
by XRD. The two sodalite fragments tested evidence relating to other exchange networks,
from our Chiripa excavations (one from a such as with the Arica area in northern Chile
Mamani Period stratum and the other from 300 air km southwest, or the Chuquicamata
temple fill) were from Cerro Sapo. A sodalite area of Chile 500 air km south-southwest.
sample provided by Alan Sawyer from Kid- Although the earliest stratified samples of tur-
der's Chiripa excavations also was determined quoise, sodalite, and chrysocolla are only from
309- Browman: Formative Period Chiripa

the Mamani component deposits (650-50 b.c.), Querimita vitreous basalts utilized as hoes
the fact that copper ores were securely identi- from Wankarani through Imperial Tiwanaku
fied from the Condori/IB levels (1250-850 (or later) Periods, or from as early as 1200 b.c.
b.c.) indicates that the Titicaca shore inhabi- through at least a.d. 1100, from sites in La Paz
tants were participating in the trade in blue and Oruro departments. In the Little Lake ba-
and green mineral beads and pendants by then, sin, these basalts previously had not been re-
if not earlier as suggested by evidence from covered in any dated contexts earlier than ca.
other localities. 300 b.c. The Condori and Mamani samples
suggest that the vitreous basalt industry of the
Tools: obsidian and vitreous basalt Lake Poop6 area was involved as a significant
component of a long distance trade network
Chiripa Formative Period projectile points, with the Titicaca basin (and probably also
knives, drills, scrapers, and other stone tools with Cochabamba). Vitreous basalt hoes were
were manufactured from a variety of crypto- observed during our surveys of the Formative
crystalline materials, including various cherts, mounds at Chullpapata and Santa Lucia in as-
quartzite, and obsidian. Stone hoes and an sociation with materials dating from as early
adze-like form were manufactured from vitre- as 1200 b.c.
ous basalt. Stone bowls, mortars, pestles, and
other grinding stones were manufactured from Obsidian materials from Chiripa were
several other stones, whose identification in analyzed by Ehlers, Richard Burger, and Larry
the field was not secure; these items remain in Haskin. Inopportunely, Ehlers's analysis of
Bolivia. Only the materials of volcanic origin, the first sample (C5) in 1976 using X-ray fluo-
obsidian and basalt, can currently be identified rescence (XR.F) was before Burger and
as to source. Asaro's seminal article. on Peruvian and Bo-
livian obsidian was published (1977, 1979).
Samples of two of the 16 artifacts of vitre- The XR.F-determined composition of this
ous basalt, a hoe from Condori/IB (1250-850 sample proved to be different than the XRF
b.c.) and a hoe fragment from Mamani/IIIB analyses published earlier by Avila (1975a,
(350-50 b.c.), were taken by Gregorio Cordero 1975b) for Bolivian obsidians. Hence Ehlers
Miranda, Director of the Museo Nacional de reported that sample C5 was from a different
Arqueologia, a.n:dco-director of the project, obsidian source than the Formative Sora Sora
and Luis Girault, of the Centro de Investiga- or later Tiwanaku obsidians that Avila had
ciones Arqueol6gicas en Tiwanaku, for pet- analyzed. But Burger and Asaro subsequently
rographic analysis in the national museum observed (1977:6) that "there are disturbing
laboratory in La Paz for verification of field differences between our XR.Fresults and those
identification. Cordero and Girault reported of Avila, although the samples analyzed from
(personal commuriications, June 1975) that Tiwanaku and Sora Sora were taken from the
. these two artifacts were confirmed to be vitre- same obsidian fragments used in the study of
ous basalts from Cerro Querimita, in the Lake Avila." Thus the non-comparability of Ehlers'
Poop6 area, Oruro.4 Marquez et aZ. (1975) and Avila'sXR.F results may be methodologi-
and Ponce Sangines (1970b) report Cerro cal, rather than the documentation of a new
obsidian type.
4Petrographic laboratory procedures for identification Burger and Asaro characterized 21 sam-
of the basalts at the National Museum in 1974 are the ples of obsidian from Bolivia by XR.F and
same as those described by Marquez et ai. (1975). NAA (neutron activation analysis): 3 samples
Characterization was limited to a few elements. While from Formative Sora Sora, 2 samples from
this is less extensive than current NAA trace element Kallamarka (a Tiwanaku administrative site
analyses, recent NAA work reported for Cruro has with Tiwanaku III, IV, and V materials) and
shown these petrographic analyses, so far, to be quite 16 samples from Tiwanaku itself. These sam-
adequate for the characterization of Cerro Querimita as ples proved to be from a source they define as
contrasted to other possible vitreous basalt sources. the Titicaca Basin Type. This obsidian type
ANDEAN PAST 5 (1998) -310

also is very common in sites from Arequipa Type is especially common in the Chucuito
and Puno Departments in Peru. Because this archaeological sites tested over the last few
obsidian was particularly common along the years and I suspect that its source should lie in
Sicuani-Puno axis, and was utilized in Peru as that area."
early as 1200 b.c. at Pikicallepata, and as late
as A.D. 1500 at Sillustani, Burger (Burger and The fifth obsidian analysis was conducted
Asaro 1977:37) posited a possible origin on a flake recovered from a Condori IB com-
somewhere in Puno Department. Subse- ponent (1250-850 b.c.) float sample. Haskin,
quently Burger (personal communication, analyzed this sample, C4, using NAA. The
April 21, 1980), suggested that "I now think results from this NAA work (Table 2) were
that the actual mine may be in Arequipa". unlike any of the NAA analyses by Burger and
This prediction has been borne out as Sarah Asaro, suggesting a previously unknown
Brooks recently has located the Titicaca Basin source. Thus stratified Chiripa Formative Pe-
Type source at a quarry in the Colca valley in riod obsidian artifacts come from at least three
Arequipa.5 different sources.6

Burger subsequently tested three addi-


tional samples (C1, C2, and C3) from the 6Michael D. Glascock of the Missouri University Re-
Chiripa project, using XRF. Two of the sam- search Reactor (MURR) has been conducting the analy-
ses of obsidian from various Titicaca basin sites for
ples(C2 from a Mamani IIIB component, 350-
Martin Giesso. Glascock recently reviewed my obsid-
50 b.c., and C3 from disturbed' temple fill)
ian data from Chiripa as part of the background for that
proved to be of the Titicaca Basin Type; the
project. While he concurs that samples C2 and C3 are
third sample, C1, from a Condori IB compo-
from the Titicaca Basin Type source, with respect to the
nent (1250-850 b.c.) was of the Tumuku Rare
identification of C 1 being TUmuku Type, he notes the
Type (Burger 1977). In his 1977 technical paucity of infonnation in the literature on the charac-
report, Burger observed that the Tumuku Rare terization of this type, and thinks that we need more
Type is not infrequent in sites in the Chucuito supporting data for a sure detennination. Sample C4
area and other parts of the southern highlands, does not match any of the types he had tested to that
and should therefore be considered a major point (Glascock, personal communication, March 4,
rather than a rare type. The source of the Tu- 1994). Sample CI derives from the probable Tumuku
muku Type was suggested to be near the Peru- Rare Type, from a source possibly in the Puno region;
Bolivia border on the west side of Lake Titi- samples C2 and C3 derive from the Titicaca Basin Type
caca in the 1977 report; in his 1980 communi- from the Colca valley source in Arequipa; C4 comes
cation (Burger, April 21, 1980), he refined that from a previously unidentified source. Thus there are
hypothesis, suggesting that "the Tumuku Rare clearly 3 different obsidian sources. The XRF work by
Ehlers on sample C5 did not match any of the XRF data
published by Avila (1971, I975a, 1975b), so he sug-
5 After the original draft of this paper was submitted, gested that this sample was an unknown. As noted,
Sarah Osgood Brooks (personal communication, June other labs have had problems replicating the results of
19, 1995) reported discovering two obsidian quarries in Avila. I do not have a copy of the XRF profile by
the Colca Valley in 1994, while conducting research for Ehlers, so it is not possible to compare it with more
her Ph.D. dissertation (Brooks 1998) at the University recent studies. Thus, I cannot say whether it is yet an-
of Wisconsin-Madison. NAA analyses of the obsidian other previously undefmed source or not, and hence
samples conducted by Michael D. Glascock, Missouri whether there are three or four different obsidian
University Research Reactor, indicated that the Cotal- sources represented in our excavation work at Chiripa.
lalli Quarry samples are "a perfect match" for the Titi- Glascock and Giesso (1994) have also recently
caca Basin-type of obsidian (Glascock to Brooks, conducted some additional analyses of Titicaca Basin
August 22, 1994). For further infonnation, see Brooks obsidians. They identified 10 different obsidians: 5
et ai. (1997:449). Richard Burger and colleagues have fairly common, and 5 with one example only. One of
also identified the Colca Valley as the source of the the common types is Tiwanaku A, with no known
"Titicaca Basin"-type obsidian. See Burger et ai. source, which appears from visual inspection to most
(1998) in this volume. likely be from the same source as Burger's Tumuku
Rare Type. Sora Sora obsidian, a common type in later
311- Browman: Formative Period Chiripa

Burger (1977) observed that "the discov- Paz in April of 1995 are currently in prog-
ery of Tumuku Type obsidian in the early lay- ress.8 Ehlers tested one archaeological sample
ers of Chiripa had not been anticipated. It from a Condori/IB component (1250-850 b.c.)
suggests that early patterns of obsidian utili- and Gundersen tested a second sample from a
zation near Lake Titicaca may have been very Mamani/IIIB component (350-50 b.c.). The
different than in later times." The subsequent first sample, examined by Ehlers in 1976 us-
defmition of yet another new type of obsidian ing XRF techniques, was tentatively identified
in the Condori layers supports this proposi- as katawi, a calcium carbonate preparation,
tion. It appears that initially Chiripa may have frequently consumed with chenopod grains.
been utilizing more local sources (the Tumuku The identification is listed as "tentative" be-
source and the new type), and that later, ex- cause in 1976 I had no expectation of recov-
ploitation of these sources was supplanted by ering such materials in prehistoric context, and
the Titicaca Basin source, 325 air Ian west in thus had limited comparative materials. The
the Colca valley of Arequipa Department, second sample studied by Gundersen in 1987
Peru.Chiripa may well have been one of the using both XRD and XRF was more securely
nodes on a network, which could have in- identified as. katawi (see discussion in Brow-
volved Tumuku and Titicaca Basin Type ob- man and Gundersen 1993). While katawi may
sidians passing south to Lake Poopo in ex- have been derived from local sources, many of
change for items such as Cerro Querimita vit- the other comestible earths consumed in the
reous basalt and Uyuni salar salt blocks mov- Titicaca basin in historic and current times are
ing north.7 . not local, and may originate from areas up to
500 Ian distant. The katawi evidence appears
Comestible earths to establish the antiquity of geophagy in the
Andes at least two millennia earlier than pre-
Two samples of comestible earth, one viously documented.
from a broken pot and one from a feature,
were recovered nom the Formative Period Final comments
levels at Chiripa. With the aid of James Gun-
dersen, several of the more than 25 comestible Locational patterns based on elemental
and medicinal earths utilized in ethnohistoric analyses of various mineral artifacts suggest a
and modem Titicaca basin households have substantial area for resource exploitation.
been chemically characterized (Browman and Some of the temple building stone, up to 4.5
Gundersen 1993); additional work on samples tons in weight, came from a quarry source
collected in the local markets in Oruro and La more than 80 Ian north by water; some early
copper ores appear to originate from mines of
the Pacific Coast region of southern Peru or
basin sites, is not present in our Chiripa sample. Giesso northern Chile, 300 to 400 air Ian west and
secured three additional samples from Chiripa (cultural southwest; turquoise is identified as coming
associations unknown) which all were identified as the
from the Chuquicamata mines 500 air Ian
Titicaca Basin type. While these new samples do not south-southwest or from a hypothesized mine
change the number of obsidian sources known for in the Arica area 300 air Ian southwest; so-
Chiripa, they indicate that, as with other Titicaca Basin
sites such as Lukunnata, Tiwanaku, and Khonko
dalite artifacts came from Cerro Sapo mines
Wankani, the Titicaca Basin type seems to be the most
225 air Ian east in the Ayopaya area; obsidian
came from at least 3 sources, one of which has
commonly exploited source.

7Waldo Avila (personal communication, July 1975), 8A new series of earth samples was collected in the
believed he could identified Titicaca basin obsidian special pharmaceutical markets in La paz and Oruro in
types from "Mound culture" (e.g., Wankarani) sites in April of 1995. Dan Kremser, Microprobe Specialist,
Oruro. Work in progress by Martin Giesso will no Department of Earth and Planetary Sciences, Wash-
doubt help in the evaluation of this model of obsidian ington University, is conducting XRD, EDS, and other
trade. analyses of these samples.
ANDEAN PAST 5 (1998) -312

been identified as a quarry 325 air kIn west in pack-harness toggles were retrieved, indicat-
the Colca valley of Arequipa Department, ing llama pack usage.
Peru; basalt hoes originated from Cerro
Querimita 325 air kIn south on the southwest The larger building stone of the temples
shores of Lake Poopo, and so on. and retaining walls at Chiripa appears to have
been transported via a second mechanism, that
A regional system in scarce resource ac- of balsa totora-reed boats. Zooarchaeological
quisition appears to functioning across the analyses of the Chiripa assemblage reveal an
altiplano during the second and first millennia increasing focus on lacustrine resources, in-.
B.C. and was part of the basis for integrating cluding aquatic birds, various fishes, and har-
the local level political elements.9 This ex- vesting of comestible algae and duckweeds,
change structure, which is argued to have in- during the first millennium B.C., indicating
volved movement of goods by balsa boats and intensified utilization of balsas for extraction
llama caravans, must be included in any study of materials. Analyses by Horn (1984) have
examining the evolution of the complexity of shown that the specific species of fish and
Titicaca Basin societies. aquatic birds recovered in the Chiripa zooar-
chaeological samples are the same as those
Llama caravans are the local mechanism taken by the contemporary Um fishing coop-
through which the lighter weight mineral eratives on Lakes Titicaca and Poop6 that he
items identified here most likely were mobi- studied.
lized, e.g., the copper ores and m~tal; sodalite,
turquoise, and chrysocolla jewelry; obsidian The mineral goods discussed all appear to
hunting, shearing, and butchering tools; basalt have been traded at least as early as 1200-
agricultural hoes; and at least some of the me- 1000 b.c. (the limit of project evidence avail-
dicinal and comestible earths. Llamas were able - see footnote 9), ahd to have maintained
important in the Formative phases at the a significance in the economy of the altiplano
Chiripa site: a hig4 frequency of llama bones outlasting anyone particular regional political
were found in all levels (Browman 1989a; group. These mineral items continued to re-
Kent 1982); llama dung was an major fuel tain importance as culturally-defined status
source (Browman 1989b); several hundred markers (such as the sodalite, turquoise,
bone weaving tools were recovered, suggest- chrysocolla, and metals), or as necessary raw
ing a major wool textile industry; and bone materials for the primary ,exploitation of the
local resource base (such as the obsidian and
basalt). They persist over long periods as im-
portant trade goods, and some of them may
9Reconstruction of the magnitude, duration, and func- possibly even develop into mercantile com-
tion of the regional resource procurement networks is modities during Tiwanaku federation phases.
deliberately limited to the evidence from the Chiripa
excavations. Climatic evidence, discussed in a paper The acquisition of construction blocks of
currently in preparation, suggests the potential for a sandstone, limestone, and andesite seems to
rather dramatic reorganization of the Titicaca Basin mirror these long-standing regional patterns, at
about 4,000 years ago. In other areas of the Andes, a smaller scale. There was a long history of
preceramic resource procurement systems have greater quarrying and transporting building stone
time depth, and from studies on the Archaic Period in from quarries around the Little Lake, as re-
the southern sierra of Peru, might well be extended vealed by the origins of construction materials
here. The evidence is not yet available to ascertain from Chiripa, as well as other sites. At
what impact the reorganization of the Titicaca basin Chiripa, the earliest evidence comes from a
economies four millennia ago might have had on the few samples in the Mamani phases. Such
caravan. systems. During the first millennium B.C., a transport becomes a particularly notable com-
number of local level polities developed at places like ponent of the subsequent Tiwanaku phases
Sillumoqo, Chiripa, Chissi, Tiwanaku, and the like. both at Chiripa and other sites (Ponce 1970a,
The explication of the political interaction between 1971, Ponce and Mogrovejo 1970), and con-
these polities is beyond the scope of this paper.
313- Browman: Formative Period Chiripa

tinued on through the Inca Period. In a sense, Acknowledgements


one could argue that the activity continued
into the early Colonial and Republican Peri- The technical analyses upon which the
ods, because the built stone ruins of the pre- arguments in this article are based were
Columbian sites were employed as stone provided by a number of specialists, whom I
sources for the impressive Catholic cathedrals acknowledge with great gratitude. XRD and
at places like Laja and La Paz, the cobble thin-section analysis of construction stone
stones and foundation stones for residences in samples were conducted by Ernest G. Ehlers,
La Paz, and later even as construction stone Department of Geology and Mineralogy, Ohio
for the late 19th century railroad bridges. State University. XRF and NAA analyses of
obsidian samples were conducted by Ehlers,
The current understanding of ceramic pat- Richard L. Burger, Department of Anthro-
terns of the Bolivian altiplano points to a pology, Yale University, and Larry A. Haskin,
sharing of specific ceramic vessel shape, deco- Department of Earth and Planetary Sciences,
ration, and fabrication traits among discrete Washington University. XRF, XRD, TL, and
clusters of communities around the Lago Pe- SEM microprobe analyses of copper,
queno during the first millennium B.C., which turquoise, sodalite, and chrysocolla materials
appear to define a series of polities. One of were conducted and evaluated by Ehlers,
the more general traits associated with Chiripa Heather N. Lechtman, Department of
ware is fiber temper; because fib~r temper was Metallurgy and Material Sciences, M.LT., and
first identified in the archaeological record at David W. Zimmerman, Center for
Chiripa by Bennett, the occurrence of fiber Archaeometry, Washington University. XRF,
temper wares from as far south as Northwest XRD, and EDS analyses of comestible earths
Argentina, east in Cochabamba, and west in were done by Ehlers, 'James N. Gundersen,
northern Chile and far southern Peru, has often Department of Geology, Wichita State
been linked with {::hiripa-- but at this point University, and Daniel Kremser, Department
fiber temper is such. a general Titicaca basin of Earth and Planetary Sciences, Washington
Formative trait that simple observation of its University. These analyses were conducteq
occurrence is not sufficient to document an intermittently as I provided samples to these
actual linkage with the Lago Pequeno polity. consultants from 1976 through 1995; thus
Rather, the accident of archaeological discov- results represent the "state of the art" for that
ery which led to fiber tempered wares first analytical technique when conducted.
being described at Chiripa has led to undem-
onstrated lists of associations. On the other The integration and interpretation of the
hand, the trace elements analysis of the technical analyses has been done solely by
Chiripa mineral samples demonstrates early Browman. While none of this paper would
relations between Chiripa (Figure 7) and sites have been possible without the superb
to the east in Cochabamba (sodalite), to the assistance and contributions of these
south at Corocoro (copper) and as far as Lake colleagues, all syntheses and the responsibility
Poop6 (basalt), to the southwest in northern for any errors resulting from them, are mine
Chile (copper minerals, turquoise), and to the alone.
west at Colca in southern Peru (obsidian).
These associations allow us to verify and re- The excavation work for this project was
fine some of the linkages previously predi- funded under NSF grant BNS 7401258. Sup-
cated on ceramic arguments, and to begin to port for radiocarbon and thermoluminescence
outline the basis of the political economy re- assays, and for part of the technical analyses,
sulting in the subsequent Tiwanaku hegem- has been provided by three Washington Uni-
ony. versity Faculty Research grants. Ehlers, Gun-
dersen, Haskin, Kremser, and Zimmerman
provided additional technical support from
their own programs, without which assistance
this paper would have been the poorer. In
ANDEAN PAST 5 (1998) -314

Bolivia, the help provided by Carlos Ponce 1978b Toward the Development of the Tiahuanaco
Sangines, Director of the Instituto Nacional de (Tiwanaku) State. In Advances in Andean Archae-
ology, edited by David L. Browman, pp. 327-349.
Arqueologia, and Gregorio Cordero Miranda, The Hague: Mouton Press.
Director of the Museo Nacional de Arqueolo- 1980 Tiwanaku Expansion and Altiplano Economic
gia and Bolivian co-director of the Chiripa Patterns. Estudios Arql.(eo/6gicos5: 107-120.
project, eliminated many logistical problems 1989a Origins and Development of Andean Pas-
and allowed the smooth functioning of the ex- toralism: an Overview of the Last 6,000 Years. In
cavations. The assistance of Waldo Parra The Walking Larder: Patterns of Domestication,
Pastoralism, and Predation, edited by Juliet Clut-,
Velasco on Figure 2, Clark L. Erickson on the ton-Brock, pp. 256-268. London: Unwin Hyman.
development of Figures 4 and 5, and Carol 1989b Chenopodium cultivation, lacustrine resources
Diaz-Granados Duncan on the re-drafting all and fuel usage at Chiripa, Bolivia. In New World
figures, is gratefully acknowledged. Paleoethnobotany, edited by Eric E. Voight and
Deborah M. Pearsall, pp. 137-172. Special Issue,
Missouri Archaeologist 47. Columbia: Missouri
References Cited Archaeological Society.
Browman, David L. and James N. Gundersen
Avila Salinas, Waldo 1993 Altiplano Comestible Earths: Prehistoric and
1971 Estudio comparativo por difracci6n de rayos X Historic Geophagy of Highland Peru and Bolivia.
de las areniscas de Pumapunku. In Procedencia de Geoarchaeology 8(5):413-425.
las areniscas utilizadas en el Templo precolombino Burger, Richard L.
de Pumapunku (Tiwanaku), by Carlos Ponce San- 1977 X-Ray Fluorescence Analysis of Obsidian Ar-
gines, Arturo Echazu, Waldo Avila Salinas, and tifacts from Chiripa, Bolivia. Technical report on
Fernando Urquidi Barrau, pp. 219-228. La Paz: file, Department of Anthropology, Washington
Academia Naciona1 de Ciencias de Bolivia, Publi- University, S1.Louis.
caci6n 22. Burger, Richard L. and Frank Asaro
1975a Elementos trazas de algunas obsidianas bo- 1977 Trace Element Analysis of Obsidian Artifacts
livianas. La Paz: Centro de. Investigaciones Ar- from the Andes: New Perspectives on Pre-Hispanic
queol6gicas, n.s. Publicaci6n 4, Instituto Nacional Interaction in Peru and Bolivia. Berkeley: Law-
de Arqueologfa. rence Berkeley Laboratory, Report LBL-6343.
1975b Amilisis espectrograftco semicuantitativo de 1979 Analisis de rasgos significativos en la obsidi-
algunas obsidianas de Bolivia, Argentina, PerU y ana de 10s Andes Centrales. Revista del Museo
Chile. La Paz: Centro de Investigaciones Ar- NacionaI43:281-326.
queologicas, n.s., Publicaci6n 14, Instituto Na- Burger, Richard L., Frank Asaro, Guido Salas, and Fred
cional de Arqueologfa. Stross
Bennett, Wendell C. 1998 The Chivay obsidian Source and the Geologi-
1936 Excavations in Bolivia. Anthropological Pa- cal Origin of the Titicaca basin Type Obsidian Ar-
pers, American Museum of Natural History tifacts. Andean Past 5:203-223.
35:329-507. Castanos Echazu, Arturo
Bermann, Marc 1971 Estudio petrografico comparativo de las
1995 Formative Period Settlement Hierarchy and areniscas de Pumapunku. In Procedencia de las
Political Economy in La Joya, Oruro. Paper pre- areniscas uti/izadas en el templo precolombino de
sented at the 60th annual meeting, Society for Pumapunku (Tiwanaku), by Carlos Ponce Sangi-
American Archaeology, Minneapolis, Minnesota, nes, Arturo Castanos Echazu, Waldo Avila Salinas,
May 1995. and Fernando Urquidi Barrau, pp. 207-218. La
Brooks, Sarah O. Paz: Academia Nacional de Ciencias de Bolivia,
1998 Prehistoric Agricultural Terraces in the Rio Publicaci6n 22.
Japo Basin, Colca Valley, Peru. Unpublished Cordero Miranda, Gregorio
Ph.D. Dissertation, Department of Geography, 1977 Descubrimiento de una estela litica en Chiripa.
University of Wisconsin-Madison. Expected De- In Arqueologia en Bolivia y Peru. La Paz: Jor-
cember 1998. nadas Peruano-Bolivianos de Estudio Cientffico
Brooks, Sarah 0., Michael D. Glascock and Martin del Altiplano Boliviano y del Sur del Peru 2:229-
Giesso 232.
1997 Source of Volcanic Glass for Ancient Andean Glascock, Michael D. and Martin Giesso
Tools. Nature 386:449-450 (April 3, 1997 issue). 1994 New Perspectives on Obsidian Procurement in
Browman, David L. the Titicaca Basin, Bolivia. Paper presented at the
1978a The Temple of Chiripa (Lake Titicaca, Bo- 29th International Symposium on Archaeometry,
livia). In El Hombre y la Cultura Andina, Volume May 9-14, Ankara, Turkey. Proceedings in press,
2, edited by Ramiro Matos Mendieta, pp. 807-813. Ay Melek Ozer, editor.
Actas y Trabajos del III Congreso Peruano del Graffam, Gray C.
Hombre y la Cultura Andina. Lima: Editora La- 1990 Raised Fields Without Bureaucracy: An Ar-
sontay. chaeological Examination of Intensive Wetland
315- Browman: Formative Period Chiripa

Cultivation in the Pampa Koani Zone, Lake Titi- 1970b Las culturas Wankarani y Chiripa y su rela-
caca, Bolivia. Ph.D. dissertation, Department of cion con Tiwanaku. La Paz: Academia Nacional
Anthropology, University of Toronto. Ann Arbor: de Ciencias de Bolivia, Publicacion 25.
University Microfilms. 1971 Examen arqueologico de las ruinas precolom-
Horn, Darwin D. binas de Pumapunku. In Procedencia de las
1984 Marsh Resource Utilization and the Ethnoar- areniscas utilizadas en el templo precolombino de
chaeology of the Uru-Murato of Highland Bolivia. Pumapunku (Tiwanaku), by Carlos Ponce Sangi-
Ph.D. dissertation, Department of Anthropology, nes, Arturo Castanos Echazu, Waldo Avila Salinas,
Washington University, St. Louis. Ann Arbor: and Fernando Urquidi Barrau, pp. 13-205. La Paz:
University Microfilms. Academia Naciona1 de Ciencias de Bolivia, Publi-
Kent, Jonathan D. cacion 22.
1982 The Domestication And Exploitation of the Ponce Sangines, Carlos and Gerardo Mogrovejo TeITa- .
South American Camelids: Methods of Analysis zas
and Their Application to Circum-Lacustrine Ar- 1970 Iwawe y Copacabana. In Acerca de la proce-
chaeological Sites in Bolivi'a and Peru. Ph.D. dis- dencia del material /ftico de los monumentos de
sertation, Department of Anthropology, Washing- Tiwanaku, by Carlos Ponce Sangines and Gerardo
ton University, St. Louis. Ann Arbor: University Mogrovejo TeITaZas,pp. 261-274. La Paz: Aca-
Microfilms. demia Nacional de Ciencias de Bolivia, Publi-
Kidder II, Alfred cacion 21.
1956 . Digging in the Titicaca Basin. University Mu- Ralph, Elizabeth K.
seum Bulletin (University of Pennsylvania) 1959 University of Pennsylvania Radiocarbon Dates
20(3):16-29. III. Radiocarbon 1:45-58.
Layman, Frederick C. and Karen L. Mohr Ruppert, H.
1965 Petrographic Analysis of Pottery from Chiripa, 1982 Zur Verbreitung und Herkunft von TOrkis und
Bolivia. Proceedings of the Pennsylvania Acad- Sodalith in Praekolumbischen Kulturen der Kor-
emy of Sciences 39:220-225. dilleren. Baessler Archiv, Beitrage zur Volker-
Manzanilla, Linda kundeN.F.30:69-124.
1992 Akapana. Una piramide en el centro del 1983 Geochemische Untersuchungen an TOrkis und
mundo. Mexico D.F.: Instituto de Investigaciones Sodalith aus Lagerstlitten und Praekolumbischen
Antropologicas, Universidad, Nacional Aut6noma Kulturen der Kordiller~n. Berliner Beitrage zur
de Mexico. Archaeometrie 8:101-210.
Marquez Ostria, Jorge, S. Kussmaul, and P. K. Hoer- Sawyer, Alan R.
mann 1981 House Structures at Chiripa, Bolivia. Paper
1975 Estudio petrog,.afico del Cerro Querimita y su presented at the 21st Annual Meeting of the Insti-
comparaci6n con artefactos /fticos. La Paz: Centro tute of Andean Studies. Berkeley, California.
de Investigaciones Arqueologicas, Publicacion 7, Stuiver, Minze and Paula J. Reimer
Instituto Nacional de Arqueologia. 1986 A Computer Program for Radiocarbon Age
Mogrov~QTeITazas,G~ardo Calibration. Radiocarbon 28(2B): 1022-1030.
1970 Estudio geol6gico petrografico. In Acerca de Urquidi Barrau, Fernando
la procedenda del material Utico de los monu- 1971 Geoquimica de las artmiscas de Pumapunku.
mentos de Tiwanaku, by Carlos Ponce Sangines In Procedencia de las areniscas utilizadas en el
and Gerardo Mogrovejo TeITazas,pp. 189-258. La templo precolombino de Pumapunku (Tiwanaku),
Paz: Academia Nacional de Ciencias de Bolivia, by Carlos Ponce Sangines, Arturo Castanos
Publicaci6n 21. Echazu, Waldo Avila Salinas, and Fernando Ur-
Mohr Chavez, Karen L. quidi Barrau, pp. 229-240. La Paz: Academia Na-
1966 An Analysis of the Pottery from Chiripa, Bo- ciona} de Ciencias de Bolivia, Publicacion 22.
livia: a Problem of Archaeological Classification
and Inference.. Unpublished Master of Arts thesis,
Department of Anthropology, University of Penn-
sylvania, Philadelphia.
1988 The Significance of Chiripa in Lake Titicaca
Basin Developments. Expedition 30(3): 17-26.
Newell, Nonnan D.
1949 Geology of the Lake Titicaca Region, Peru
and Bolivia. Geological Society of America Mem-
oir 36. New York: Geological Society of America.
Ponce Sangines, Carlos
1970a Examen arqueologico. In Acerca de la proce-
dencia del material /ftico de los monumentos de
Tiwanaku, by Carlos Ponce Sangines and Gerardo
Mogrovejo TeITazas, pp. 11-188. La Paz: Acade-
mia Nacional de Ciencias de Bolivia, Publicacion
21.
, --/

CHIRIPA and TIWANAKU STONE SOURCES


o .10 20 30
. Km.
Scale

LAGO

KEY:
. .-. ANDESITES

edit
_
m LIMESTONES

SANDSTONES

· SETTLEMENTS

Figure 1. Location of Chiripa and the major stone sources near Chiripa, around the "Little Lake"
portion of Lake Titicaca.
317- Browman: Formative Period Chiripa

MAIN HOUSE
TENNIS
COURT
....
III
III
a:
....
II)

III
Q
;;

SOCCER
FIELD

+ DATUM STAKE
OLD EXCAVATED AREAS
c::::!J MODERN ADOBE WALLS
'-14 E-W GRID LINES
A-J N-S GRID LINES
CONTOUR INTERVALS O.50m.
'_III RECENT EXCAVATIONS

SCALE
~ I !
O' 2 '4 t .. II

Figure 2. Contour map of the Chiripa mound site, showing locations of the 1974-75 excavation
units I, II, and III.
ANDEAN PAST 5 (1998) -318

r--~--\ , II, ,II, 1r-------


, \ \
mq il:::)

~
I \ \ I I I I
\ +~oo 1+IE8
l+ ID8 O
b7 ):J
HC8
~\G8
'UI'
i ~
\ ~
\
i 0
1,
I I
I ,D ~ \.
II
I
I D
0 \1
I

\~ \ II . II ' ;jI'J
,fJ

~
i 1 \ I 1 .

.. . II 0
~
.
\cP
.""'\
i
\

;'0 ~~ ii
II
It I d II
11.11
~ ,
I.
II
I I

~
J L .

,r ,' \
G7 i + F7 + E7 + 07 +C

\ S \ i r l r Cordero

, _nD
\ ! I
I
I I
I I
I
! I
II
I I
I I
II
II
II
II
O& lf ,
\
\
Stela

-', 1L J. L <21
-:!:.~
.
1+f.!
II
l+f!
II I
,' II
+IQ!> t...c.! -j I
I
~
~.Up..,
+ G5
:
:

.
I I
"
1111
II
J L
+ F5
.'

.
I I
1I

~II ___~
+ E5
. ~
I I
I I
:i
II O 1
+ 05
~'\)
oo + C5
I
I
I
I
~

I
~'=J-~--ll I I l.1 rI l I :-~
I I
B.M.#18 I I .' '1 I I I G l'--. I
(j) '-l
.
~t""f)
t:l:
I I
J".!___~C?~
II"~~_J
. I I I I
! ~~~--
~ I
II

~+.-G~-'7-- :f{.Q O C4--


O -,
: : !J
~-'-O'rn-rt rb-~4J I I II
D4
I

~Q
I
L
,:
II II
+1
4 ;
1I II
'+
:
II II
- ..+03
I i
II
-,+C3
J

G3 F3 E3'
o 2 3 4 5
Scale f I
+C5 Control Points

- Cut Boundaries
Temple Wall Continuation
c:::Jao Remaining Building Stone

Figure 3. Plat map of the excavation of the Tiwanaku phase temple, showing location of re-'
maining wall and of abandoned robbed asWars.
.-
I.H

1.0
I

~
c
~
~
.§.
~
!~.
~
[
r").
Figure 4. Idealized reconstruction of the Mamani phase houses, mound facing wall and temple at.Chiripa. Based on a composite of ::s-o
....
information from Bennett, Kidder and our excavations. Some retaining walls omitted for clarity. ~
'6'
t:!
~
~
~
~
~
>
00
-3
(JI
----
....
\C
\C
00
"-'

Figure 5. Idealized reconstruction of the Tiwanaku IIIphase temple at Chiripa, showing vertical ashlar construction technique. I
W
N
o
VJ
N
-
I

.. NORTH SCALE:
-=
Ito LakeTltlcaca o 1 2 3 4 Sm.
350 meters I
Eatlrnatod
0'11I1081
wall Holght
'I
MQ.OEItIt SUItF1!CE
~3837 m. I ! ~
,C'

C'

Chlrlpa
Temple
Wall

i Chlrlpa
Facing ~
i Wall
i
I ~
i §'.
.J
G'13 G.12 G.11 G.10 G9 G.8 G.7 ~
~
~
....
~.
~
~~
-.
C
~
Figure 6. Composite 30 m. cross-section, showing relationship of the Mamani phase (Classic Chiripa) facing wall and temple wall to 9
the subsequent Tiwanaku III phase constructions. Note relative position of the two temple walls and facing walls. Simplified section ::;.
based on profiles from Bennett, Kidder, and our excavations. ~.
~
ANDEAN PAST 5 (1998) -322

. .
Scale 0 200 300 km

BENI
LA PAZ

CHUQUISACA

ANTOFAGASTA

Figure 7. Approximate locations of the major sources for the long distance procurement at
Chiripa.
323- Browman: Formative Period Chiripa

Table 1. Chiripa radiocarbon and thermoluminescence determinations.

Phose Lab Number Uncalibrated Calibrated


CondorillA Beta-31291 1530 b.c. :i: 180 1820 B.C. :i: 220
(1350-1250 be) GX-4057 1260 b.c. :i: 170 1500 B.C. :!: 200
RL-496 1240 b.c. :i: 120 1500 B.C. :i: 130
WU-TU9A 900 B.C. :i: 430 900 B.C. :i: 430
CondorilIB WU-TU9B 1380 B.C. :i: 500 1380 B.C. :i: 590
(1250-850 be) P-129 1290 b.c. :i: 130 1545 B.C. :i: 145
RL-495 1220 b.c: :i: 120 1430 B.C. :i: 120
P-145 1020 b.c. :!: 120 1180 B.C. :i: 140
RL-494 900 b.c. :i: 110 1040 B.C. :i: 130
RL-493 870 b.c. :i: 110 1010 B.C. :i: 120
WU-TU9C 510 B.C. :i: 370 510 B.C. :i: 370
Llusco/II WU-TU9D 1050 B.C. :i: 450 1050 B.C. :i: 450
(850-650 be) RL-491 950 b.c. :i: 140 1095 B.C. :i: 175
RL-492 860 b.c. :i: 180 1015 B.C. :i: 205
GX-3596 435 b.c. :i: 165 575 B.C. :i: 215
WU-TU9E 100 B.C. :i: 310 100 B.C. :i: 310
Mamani/IIIA GX-3595 775 b.c. :i: 100 . 900 B.C. :i: 90
(650-350 be) WU-TU9F . 640 B.C. :i: 390 640 B.C. :i: 390
P-126 600 b.c. :i: 116 670 B.C. :i: 150
P-115 518 b.c. :i: 133 625 B.C. :i: 145
"
GX-4059 510 b.c. :i: 165 590 B.C. :i: 180
wu- TU9I 470 B.C. :i: 365 470 B.C. :i: 365
GX-4058 350 b.c. :i: 155 360 B.C. :i: 180
P-125 346 b.c. :i: 114 355 B.C. :i: 165
P-l24 341 b.c. :i: 115 355 B.C. :i: 165
P-142 .331 b.c. :i: 113 345 B.C. :i: 165
1-8314 285 b.c. :i: 240 260 B.C. :i: 280
Mamani/IIIB P-116 427 b.c. :i: 110 470 B.C. :!: 90
(350-50 be) P-143B 368 b.c. :i: 113 435 B.C. :i: 95
WU-TU9G 330 B.C. :i: 340 330 B.C. :i: 340
P-141 325 b.c. :i: 116 300 B.C. :i: 130
Beta-31290 290 b.c. :i: 90 265 B.C. :i: 65
P-I44 243 b.c. :i: 111 275 B.C. :i: 115
P-143A 227 b.c. :i: 112 265 B.C. :!: 115
WU-TU9H 40 B.C. :i: 300 40 B.C. :i: 300
P-117 a.d. 13 :i: 104 A.D. 35 :i: 115
P-118 a.d. 22 :i: 105 A.D. 181 :i: 31
WU-TU9J A.D. 160 :i: 270 A.D. 160 :i: 270

* All radiocarbon determinations (b.c., a.d), except P-143A, on charcoal. Calibrated determinations (B.C., A.D.)
based on Stuiver and Reimer J986, 20 year average statistic, method B. TL determinations (WU-TLxxx) are cali-
brated in sidereal years. Assignment to phases based on stratigraphic and cultural associations.
ANDEAN PAST 5 (1998) -324

Table 2. Trace element composition of the unknown obsidian, second millennium B.C. Chiripa.
(Sample in direct association with assay RL-493, see Table 1. Data from analyses by Larry D.
Haskin conducted in 1986. Sample irradiated at the Missouri University Research Reactor, Co-
lumbia.)

As 11.1 :f: 0.4


Ba 440:f: 20
Br 1.8 :f: 0.2
CaO (%) <1.0
Ce 68.9 :f: 1.0
Co 0.14 :t 0.03
Cs 15.0 :f: 0.3
Eu 0.26 :f: 0.02
FeO (%) 1.19 :t 0.03
Hf 7.7 :f: 0.3
La 33.7
Lu 0.673 :t 0.015
NaiO (%) 4.50 :t 0.05
Nd 29 :t 4
Rb 180 :f: 8
Sb . 1.23:t 0.05.
Sc 2.73 :f: 0.05
Sm 6.41 :t 0.11
Ta 1.00 :t 0.05
Tb 1.13 :t 0.06
Th 17.5 :t 0.4
U 7.5 :f: 0.3
W 3.0 :t 0.6
Yb 4.44 :f: 0.07
Zr 270 :t 60

You might also like