® Solution SS CHM102A Write down Roll no and Section before you start answering Write answers only inside the space provided Total Points: 25; Time: 30 mins. Name: AK RP Roll No: 7-75 Atomic No: Cre243 Ir-773 Ni-28; F-9. Total Pages: 4 4. Sight down the C2 - C3 bond and draw Newman projection formulas for the a) Most stable conformation of 2,2-dimethylbutane b) Two most stable conformations of 2-methylbutane ) Most stable conformation of 2,3-dimethylbutane [ve pantie] movi) Mark: 5 a) cha, 0 h oe [2 mare | ev, 4, "2 ») Cha, CBs e cHs | a c+) H cK ci, i 3 Cn, 2 Ch cw u a eS) H aNCHM102A Write down Roll no and Section before you start answering Write answers only inside the space provided ‘Total Points: 25; Time: 30 mins. Total Pages: 4 2. The compounds below are all well-know compounds with important biological activity. The S enantiomer is the active substance in each case. Identify stereogenic center and draw S isomer for each compound Mark: 5 Coxvvect SteNEBZene Cemrew > O'S Covveu B-—p Stvnttrye — 2.0 ibuprofen o NA Hers Fone Nay adrenaline 9 Wo Rough work ¥ Othev possible Answers 4 ¥ CH NACH. — Hoye CH (p 0), Av ou Ar cnycrmesCHM102A Write down Roll no and Section before you start answering Write answers only inside the space provided ‘Total Points: 25; Time: 30 mins. Total Pages: 4 3. (a) The chromatographic purification of 1.0 g of ethyl R-()-lactate with an ‘enantiomeric excess (e.e.) of 85% yields the enantiomeric pure (-)-enantiomer. How many grams of the (-)-enantiomer were separated? (considering no loss of material during the purification process) Mark: 5 0-858 0 = 100% Bus O425 5 4 - enantiomer [2 maori] | Zero may or ony othey valane | (b) Calculate the actual number(s) of stereoisomers for 1,2-dimethylcyclopropane and draw their structures. Thyee Stertowemers 2 met o> os ® %s e's crs ie Cha, = AS hy Chy 7 mars for Covet | Rough work the +3 mars er caves ver Sa Chun | oa enact tow wo U cone meso Qed Oe er Sty carer ) mesd Ara One aft : solid] hashed weages ch. thot (o ane ok | 3CHM102A Write down Roll no and Section before you start answering Write answers only inside the space provided 25; Time: 30 mins. ‘Total Pages: 4 Total Points: 4. Ao values (cm ~') for the four complexes are 13100, 22000, 27000 and 41200. These are not in the same order as the complexes listed in the table below. Put appropriate value against the complex and also fill the other columns. Mark: 10 ‘complex | Ao | Electronic Number of unpaired configuration in terms | electron Of tag and ey (consider high-spin and low- : spin possibilities) (CrFs} 22 000 toy : e0 ie [Ir(CN)e™ z 41200 bays e4° a [NiFel* i 13100 tye e,> 2 [re] ° 2} 000 | tyt gf o L i L aa [Lmao each) oa may each) [os way kK eock ) Rough Work