Seamed CansearnereC 2 some Basic Concepts of Chemistry ome Concentration Units pianos () Molarity (49 11s the moles of solu ‘one litre of solution us =2 n= Number of moles of solute (= Volume of solution in litre) = Molarity (1) x Volume (J) = n (moles of solute) Ir volume is in mL; ‘MI’ millimoles {fed (g/ee) is density ofa solution and it contains x % of solute ‘of molar mass 44, its molarity can be worked out as 1) Molality (m) itis the number of motes of solte resent in 1.0 kg of solveit Moles of solute (ny eS Walp GFarce ex 1000 | _Weight of solvent in gram ore nite neaatizeconcentation unt, independent of temperature ‘hile molarity depends on temperature OP We toe tober of een enuivetents of solute in one litre of solution, 1 = Gram equivalents of solute (Eqy ‘Volume of soluti We Prsctlesr tr). te fen of antes ofa Particular component in a mixture as © ppm (parts per million) Strength tis defined as Pans of solute present in (10° part) of solution, * Dilution Formula Ifa concentrated solution is diluted, following formula work Equivalent Concept, Neutralisation and Redox Titration st + Equi Weight Equivalent weight of an htrtbymemnvcoies i ug 8.0 g of oxygen or 35.5 g of chlorine ivan weight fsa (EW) Pyeott Molar mass = We poave or nse) laa €g. Equivalent weight M ney caci, = acl. cach = 5 Alx(80,), = Mf 6 Molar mass. Basicity (i) Equivalent weight of acids g. Equivalent weight - HC1= A (basicity = 1: 1:80, = tasty 1490, usciy =>) ae (1) San wig fh = Me €g. Equivalent weight NwoHt-ar exon, =A, on, al + The number of gram-equivalents (Eq) Equivalent = Weight of compound _|__ Equivalent weight — Equivalent weight * Mole Equivalent Relationship in a given weg (w) of sample, number of moles (nm) and number of ‘equivalents (eq) are related as wSeamed CansearnerSeamed CansearnerP q 6 Some Basic Concepts of ‘Chemistry Limit your answer ‘4 Inthe analysis ofS gsample of edgar amc ofclondes 46, Accouns or the fotowing Lin of slum abd potassium i obtained, which weighs 118g sentences, “Atomic wei Subsequent treatment ofthe mixed chlorides with aver mio, fractional” ves 0.2451 g of slvr chloride. What isthe percentage nr ‘47. Nanurally occurring boron consists of two sium oxide and potassm oxide inte sample? iere wig, 47- 45. ‘The vapour density (hydrogen = 1) of a mixture co sisting of natural boron is 10.81. Caleulate the ma ot NO; and NiO, 6 38.3 a 267°C: Calule he meee ‘note in natural boron. my soles of NO; in 100 pot the mixture 0979, 54) Topic2 Equivalent Concept, Neutralisation and Redox Titration Objective Questions I (Only one corect option) 4. From the following stat incorrect statement 9 Dee men's regarding H,03 choose the react completely (2015 Main) pean 4 ha (9) Itcan act only as an oxidising agent @2 2 Ox bo (b) It decomposed on exposure to light 4 Pp inO, that will be (©) Ithas to be stored in Plastic or wax lined gl bottles 9. The number of moles of KMnO, needed 5 dark a react with one mole of sulphite ion in acidic solution. (A) It has to be kept away from dust A 3 4 wr — 2 Consider a tiration of potassium dichromate solution wid Bs ss oa ss acidified Mohr's. salt indicator. The number of moles of Mohr's salt equired per 10. For the redox reaction ‘mole of dichromate is (2007, 3m) MnO, +C,07 +H” —+ Mn?” +00; «fg (3 (4 ws (6 The correct coefficients of the reactants forthe balan 3. In the standardisation of Na,S,0, using K,C0, by Feaction are i ; todometry, the equivalent weight of K3Cr,0, is (2001, 1m) MnO; C0; Hi mg {@) (molecular weight)/2 @ 2 5 16 a () (molecular weights ®) 16 5 2 (©) (molecular weighty’3 © $s 16 2 (d) same as molecular weight @ 2 16 s 4 The reaction, 3C1O(aq) —4 C105 (ag) + 2C1-(an) is en 44. ‘The volume strength of 1.5 N H,0, is (0950, example of (2001) 48 (84 ()3.0 (80 (a) oxidation reaction 12. The oxidation number of phosphorus in Ba(HPO;h | Ue gemeetion reaction @s (+2 (c) disproportionation reaction Ci ut (4) decomposition reaction : 5. An aqueous solution of 6.3 g oxalic acid dihydrate is made up 1" ata is hai oF its 10250 ml. The volume of 0.1 N NaOH required to completely boy aie deat ae ‘neutralise 10 mL of this solution is (2001, 1m) . nee (@)40mL (6) 20mL—(e) 10mL_— (4) 4 mL. (©) MnO; (d@) Mno} 6. Among the following, the species in which the oxidation. number ofan element is+6 . ©2000) _Gtiective Question 1 daeSeamed CansearnerSean Cans