“MINERAL EXPLORATION
| RECENT STRATEGIES
ey
Editors, ‘
S.Rajendran, K.Srinivasamoorthy and S.Aravindan
Department cof Earth Sciences, Annamalai University
t ‘Annamalai Nagar - 608 002, Chidamabaram
Tamil Nadu, India
2007
| \ New India Publishing Agency
‘ Pitam Pura, New Delhi- 110 088
hney
‘Mineral Exploration : Recent Strategies, 2007
Ezs.: & Rajendran et.al, pp. 63-76
"New india Publishing Agency, New Delhi
6
Chrysoberyl from Southern
Tamil Nadu of South India, with
Implications for Gondwana Studies
G. Manimaran, Deepak Bagai and P. T. Roy Chacko
ABSTRACT
We report here the occurrence of chrysoberyl bearing gem pegmatites of Southern
India. The Pan-African Chrysoberyl mineralization is associated with intrusive
event of grey pegmatites within granulite facies parametamorphic aluminous
khondalites. Lithological and structural controls of chrysoberyl mineralization,
are discussed. The chrysoberyl occurrences in southern India, southern
Madagascar and Sri Lanka provide strong evidence for India-Sri Lanka-
Madagascar juxtaposition in the East Gondwana assembly with the Achankovil
Shear Zone of Southern India one side extending into Ranotsara Shear Zone in
‘Southern Madagascar and other side into southern tip of Sri Lanka.
INTRODUCTION
Southern Tamil Nadu in South India is among the historically reported
Gondawana fragments for gem exploitation and exploration. Among the
important gemstones found in the regions are alexandrite and cymophone
varities of chrysoberyl (locally known as Kalakkad diamonds) and pink
sapphire. The other semiprecious stones recovered from this region are ruby,
greenberyl, aquamarine, green and golden zircons, topaz, kornerupine, bluish
spinel, aimandine and pyrope garnets, blue and green apatites, moonstone64 Mineral Exploration
variety of feldspars, smoky quartz, amethyst, rosy quartz and blue and violet
cordierites.
In this communication, we report occurrence, lithological and structural
controls of chrysoberyl bearing pegmatites of southern Tamil Nadu. Based
on correlations with similar occurrences recently reported from Madagascar
and Srilanka, we evaluate the juxtaposition models on India, Sri Lanka,
‘Madagascar within the East Gondwana reassembly. .
GEOLOGICAL SETTING
The Achankovil shear zone is 8-25km wide sinistral tectonic zone trending
WNW-ESE to NW-SE direction and running across the southern end of the
Southern Granulite Terrain of south India for a length of 210km from west
coast to east coast of South India (Katz, 1978; Drury and Holt, 1980;
Manimaran, 1995; Janardhan, 1999, Ramakrishnan, 2003). The Achankovil
shear zone (ASZ) and Kerala Khondalite Belt (KKB - Ponmudi unit) of
Tamilnadu region is essentially a khondalitic (gneissic) and charnockitic terrain
(Fig.1). Interlayered pelitic gneisses, are common in charnockites. Migmatitic
and sheared cordierite gneisses essentially occur in ASZ. The khondalites
(quartzofeldspathic gneiss with biotite, garnet, sillimanite, graphite + cordierite)
are with enclaves of garnet biotite gneisses, cordierite gneisses, calc-silicate
tocks and quartzites. Enclaves of veins and bands of basic granulites are
common in both charnockites and khondalites. Abundance of intrusive
pegmatites, veins of pyroxenites and hornblendites, granites and linear,
incipient charnockitic zones are common in ASZ and KKB. A northern
massive charnockite occurs to the north of Achankovil shear zone. A southern
massive enderbite occurs to the south of KKB in Nagercoil unit. The over
printed NW-SE sinistral Achankovil shear zone features on NW - SE dextral
Tenmalai Shear Zone are well documented. Atleast two periods of cordierite
formation, two periods of charnockite formation, two periods of granite
intrusions and two periods of grey and pink pegmatites are delineated from
the ASZ and KKB regions of Tamil Nadu (Manimaran, 1995; Manimaran
and Roy chacko, 1996). The general strike of the lithounits is NW-SE to WNW-
ESE and dips SW to SSW or NE with steep to low angles.
GEOCHRONOLOGY
Zircon evaporation age (cluster) for a metasedimentary gneiss from
Nellikkala quarry of Kerala at 895 and 913Ma (Barrlett et al., 1998) could be
the age of D1 and is related to earliest cordierite-K-feldspar mineralization of
the Achankovil Metasediments, The NW-SE striking cordierite- bearing
charnockite and the adjoining cordierite bearing dextrally sheared graniticChrysoberyl from Southern Tamil Nadu of South India 65
TI] Phanerozoie cover
Corre goes
Meta
(Khondatte 61)
Granite /Syente
‘Shear Zone. sic and ip of folaton
= shear sense
Fig. 1. Schematic geological map of the Kerala Khondalite Belt of Southem india showing
locations of chrysobery! occurrences. 1. Ermalpuram, 2. Papankulam, 3. Kalakkad,
4. Perumaikulam, 5. Ervadi, 6, Mudavankulam and 7. Papanasam. Sinistral Achankovil
Shear Zone and dextral Tenmalai shear zone are also shown.
gneiss of Tenmalai-Ambasamudram area are formed during Tenmalai
shearing of D2. Iyer and Santosh [quoted by Ravindrakumar, 1988] reported
an age of 670Ma (Whole rock Rb-Sr) for cordierite gneiss from Chenganur
along Tenmalai Shear Zone; 640+ 29Ma U-pb zircon dating of Chenganur
granite (Bindu et al. 1996) and 678 Ma Rb-Sr whole rock isochron age of
Cordierite bearing charnockites from Southern Kerala [Santosh and Drury,
1988) could be the age (ca.670-630 Ma) of shearing of Tenmalai dextral shear
zone. The charnockites of 550 Ma, 560 Ma and 539 Ma ages are reported
from Ponmudi and Nellikkala by Buhl, (1987); Chaudhary et al. (1992);
Santosh (1996) respectively Zircon overgrowth dating of Achankovil
‘metasediments falling between 600 and 530+21 Ma reported by Bartlett et al.
(1998) attest an age of ca.600-550 Ma for sinistral Achankovil Shear Zone of
D3. The late D3 granite of ASZ zone yields an age of 520415 Ma and 550 Ma
(Odom, 1982; Soman et al. 1983). Recently, Santosh et al (2005) studied the
U-Pb electron microprobe age for zircon and monazite from Pathanapuram
granite occuring in the central domain of the Achankovil shear zone. They
reported 961-1149 Ma oldest zircons with younger overgrowths at 540 - 560
Ma and monzite core age of 526 - 574 Ma, with rim age of 506-539 Ma. From
Monazite U-Th age, Braun et al (1998) dated the pink coloured syenogranitic66 Mineral Exploration
pegmatites, 10km NE of Kottavattam of ASZ and a quartzmonzonitic
pegmatite, 2km northeast of Trivandrum as 462431 Ma and 474+22 Ma
respectively. Cenki et al (2004) pointed out that the KKB dominated by Nd.
Model ages range between 2.0 and 3.0 Ga, but in Achankovil Zone Middle
Proterozoic Nd model ages (1.3 - 1.6 Ga) were recognized from charnockite
and cordierite bearing gneisses. The peak metamorphism occurred between
590 and 550 Ma, as recorded by U-Pb dating of monazite from charnockites
and gamet-biotite gneisses, Rb-Sr ages of biotite-feldspar minerals in pegmatite
intrusions record cooling to Ca 400 ~ 500°C by 490 - 470 Ma. The general
peak granulite facies metamorphism and widespread migmatization of the
area happened at 530 and 525 Ma from SHRIMP U-Pb zircon age (Shabeer et
al, 2005). Miller et al, (1996) estimated the crystallization age of gemstone
Pegmatites in Southern Kerala by U-Pb and Pb ~ Pb dating of gem quality
pale brown and translucent green gem zircons from the Melankode pegmatite
and obtained an average age of 51342 Ma. Later Santosh et al, (2002) have
reported pink sapphire and chrysoberyl from the same Melankode pegmatite.
GEOLOGY OF GEMSTONES DEPOSITS
Southern Tamil Nadu and adjacent southern Kerala define a major gem
field in South India, covering an area of more than 150 x 75 Km, stretching
intermittently from the Achankovil Shear Zone area upto the Southern margin
of the KKB. From southern Kerala gemstones bearing deposits are reported
from Rose Mala, Melankoda, Venganoor, Bonaccord, Mudakkal, Nedumtheri,
Aruvikkara, Kulathupuzha, Xizharur, Vamanapuram and Tenmala. while
Chrysobery! is reported from these locations, pink Sapphire is located from.
Rose Mala and Melankoda (Soman and Nair, 1985; Menon et al., 1994; Menon
and Santosh, 1995; Santosh et al,, 2002). In southern Tamil Nadu, gem minerals
occur in three principal settings:
(1)as primary deposits associated with pegmatites emplaced within pelitic
gneisses of granulite facies (Khondalites) (2) as secondary deposits within
paleoplacers in alluvial gravels of Pleistocene to recent age and associated
with river and stream systems of the area and (3) as residual gem deposits
near to their source rock within the weathered zone of source rock and
adjoining weathered calc-silicate rocks. Gemstones obtained from placer
deposits are generally of higher quality since during their transport in streams,
the gems with fractures, inclusions or other flaws tend to break along these
lines of weakness and also attain smooth surfaces. Indicator heavy minerals
such as tourmaline, gamet, zircon, beryl and opaque minerals are regarded
as pathfinders by local prospectors for the occurrence of gems. Gravel deposits
in potholes and in the upstream side of the rock exposures, crossing, the courseChrysobery| from Southern Tamil Nadu of South India 67
of rivers are intensely panned for the recovery of gemstones by local
prospectors,
CHRYSOBERYL FROM SOUTHERN TAMIL NADU
There are three main varieties of chrysoberyl mined as gemstones in
Southern Tamil Nadu namely chrysobery!, alexandrite and cymophane (cat's
eye). Allare identical compositionally being aluminate of beryllium (BeAl,O),
but have different appearances and gem properties. The chrysoberyl has'a
hardness of 8.5 and is doubly refractive (1.745 - 1.754) with a birefringence
varying between 0,008 and 0.010. Specific gravity is between 3.71 and 3.73
slightly less than that of the pink sapphire of the area (3.9 - 4.0). It generally
occurs as interpenetrated complex twin crystals with single simple forms being
rare, Italways in crystals usually embedded in books of biotite, or in plates of
feldspar or in the host of quartz of pegmatites.
Simple chrysoberyl varies from transparent through translucent and
opaque varieties and yellow, green, bluish green and colourless chrysoberyl
are common. Like Sri Lankan stones an unattractive brown chrysoberyl is
also common. The colour results from the presence of Fe™ ions in the structure
and fully transparent coloured types are the most favoured for gemstones.
A well known variety of chrysoberyl is cat's eye or cymophane. It has
acicular mineral inclusions oriented at an angle to the vertical C-axis of the
crystal which produces a chatoyancy effect when cut in “en cabochon” form
perpendicular to the C-axis, Best effect is observed in cloudy or translucent
yellowish chatoyant chrysoberyl.
The most valued alexandrite chrysobery1 is bluish emerald green colour
which results from small scale replacement aluminium by chromium in
structure. This mineral has a characteristic property of changing colour with
a change between natural and artificial tight, from green to a deep red colour,
often with a tint of violet. Because of their rarity and colour change capability,
alexandrite gems are some of the most expensive gems in the world.
The primary chrysoberyl mineralization occurrences are associated with
a variety of complex pegmatites that are emplaced within the aluminous
supracrustal kondalites (Fig,2). Examples of gem hosted pegmatite are reported
from Ermalpuram, Papankulam, Kalakkad, Perumalkulam, Ervadi and
Mudavankulam. Most of these pegmatites are partly weathered at the top
due to lateritisation. On considering the above locations it appears that the
chrysoberyl bearing gem pegmatities are lithologically and structurally
controlled. Lithologically the gem pegmatites are grey pegmatites enriched in
grey smoky quartz (35-40%) and grey potash feldspars (20-30%), unlike the
168 Mineral Exploration
late pink pegmatites of the area which usually have pink garnets (10%), pink
potash feldspar (30-40%), pink perthite (5-7%) and plagioclase less than 3%
or absent. The grey pegmatites are rich in ALO, K,O, Th, Sr, U, Nb, Rb and
Zr and poor in total FeO and Cr as compaared to the pink pegmatites and
both pegmatites have equal abundance of P,O,, CaO, MnO, TiO,, MgO, NaO,
Ga, Y, Pb and Zn (Manimaran 1995). To locate the gem bearing grey pegmatite,
the lithoguides used are 1) Islands of schorl rock (network of black tourmaline
and smoky quartz) (2) patches of cuneiform graphic granites (intergrown
quartz and feldspars) (3) glistening spots of moonstones of greyish and
yellowish varieties and (4) translucent, red garnets even upto cricket ball size.
Tourmaline, emerald and aquamarine are the usual associates of the
chrysoberyl. Invariably all the gem-bearing pegmatites strike between N60°E
S60°W and N80°E S80°W with steep dips to vertical and all are intruded in
ENE - WSW dextral shear zone observed in adjoining khondalites. Pegmatite
intrusion and dextral shearing of khondalites are of syngenetic origin (Fig.3,
4 and 5).
The Ermalpuram gem pegmatite is 100m thick band running more than
a Kilometre and strikes N 60°E - S60°W with vertical dip. The pegmatite
intruded both khondalite and calc-silicate rock (Fig.3). Pink Sapphire
occurrence in pegmatite as reported by authors especially near the contract
zone of calc-siliciate rock. Schorl rock, graphic growth of quartz and feldspars,
books of biotite, yellow, brown and green coloured chrysoberyl, emerald, pink
sapphire, gem garnets, black tourmaline, bluish spinel, green and yellow
zircons are reported from Ermalpuram, Gems are ubiquitous in this
pegmatites. The Fig.4 shows a weathered gem pegmatite of Ermalpuram, a
source rock for liberated gems so as to form residual deposits in the nearby
Karst cavern formed due to the removal of calc-silicate rock due to water
leaching. Fig.6 shows a exploited residual gem deposit located at the contact
zone of gem pegmatites of Ermalpuram.
In Papankulam, Perumalkulam and Ervadi, yellow and brown
chrysoberyl are seen. At Mudavankulam exploited gem pegmatite quarry,
the adjoining Khondalite strikes E-W with low angle dips towards $ and the
vertical pegmatite strikes ENE - WSW direction and the foliation planes of
adjoining khondalites show dextral shearing. Smoky grey moonstone, grey
moonstone, schorl rock, tourmaline, large crystals of brown biotite and green
beryl are seen in the outer zone. In Kalakkad mountainous terrain, all kinds
of chrysoberyl are reported from primary, alluvial and residual deposits.
Diamond like colourless but heavy chrysoberyl, alexandrite, cat’s eyes occur
in Kalakkad regions.(Chrysoberyl from Southern Tamil Nadu of South India
re aurfewno}
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kh70 Mineral Exploration
Fig.6. A site of totally exploited and removed residual gem
deposit, near gem bearing pegmatite at Ermalpuram.
In southern Tamil Nadu chrysobery| is also found as water worn pebbles
and fragments in alluvial deposits and has a wide distribution in the river
courses of Thamiraparani, Manimuthar and Patchaiaru of Tirunelveli District.
‘At Papanasam, the gem bearing gravel is of variable thickness, attaining a
maximum of 3m and lying above the bedrock comprising Khondalites.
Important gem minerals recovered from placers include alexandrite, cat’s eye,
beryl, pink sapphire, garnet, topaz and zircon.
INDIA, SRILANKA AND MADAGASCAR CONNECTION
Various models have been proposed for the juxtaposition of India and
Madagascar within East Gondwana. Madgascar-India fits are based mostly
on matching of the Palghat ~ Cauvery Shear Zone (PCSZ) (Janardhan, 1999;
Janardhan and Srikarni, 2001) or Achankovil Shear Zone (ASZ) of South
India (e.g. Windley et al. 1994; Yoshida et al. 1999; Santosh et al. 2002; Braun
and Kriegsman, 2003; Cenki et al. 2004) with the Ranotsara shear of
ar. Recently following Martelat (1998), de Wit et al, (2001), Collins
and Windley (2002) and Shabeer et al, (2005) on the basis of geologic and
tectonic features the N ~ S trending Tranomaro Shear Zone in southern
Madagascar is correlated with NW - SE trending Achankovil - Shear Zone in
southern India. Santosh etal, (2002) inferred the extension of Ranotsara shear
zone into the Achankovil shear zone on the basis of pink sapphire occurrence.
Many of the ductile shear zones like PCSZ and the ASZ should terminate in
the west before reaching Madagascar, as no significant major dextral shear
zone has been documented in Madagascar (Jain et al, 2003).
‘A predominance of dextral movement along the Moyar ~ Bhavani shear
zone (MBSZ) and steep and gentle plunging mineral lineations at places areChrysoberyl from Southern Tamil Nadu of South India nm
consistent with the model of regional Neoproterozoic transpressional tectonics
superposed on the Palaeoproterozoic thrust system (Chetty etal, 2003). Hence,
dextral MBSZ is not to be correlated with sinistral RSZ of Madgascar. The E-
W striking Palghat-Cauvery shear zone is a dextral, strike-slip dominant,
ductile shear zone evolved in a N-S compressive regime (Cruz et al, 2000),
unlike sinistral ASZ of South India and Sinistral RSZ of Madagascar formed
in a ENE - WSW compression regime (Manimaran, 1995) and in a E-W
compression regime (Martelat ef al, 1999) respectively. Hence PCSZ can not
be eastern extension of Ranotsara Shear Zone in Gondawana Assembly.
Correlation with Madgascar is weakened as the ASZ is no longer considered
a major crustal shear zone, whereas correlation with Srilanka is strengthened
by the presence of a similar syntactical bend possibly produced by an indentor
(Cenki and Kriegsman, 2005).
An attempt is made here to fit the ASZ of South India with Ranotsara
shear zone of Madagascar and position of Sri Lanka on the basis of comparable
chrysoberyl bearing gem pegmatites of Similar age (Fig.7). Chrysoberyl bearing
pegmatites have been widely reported from a number of localities in southern
Madagascar including Betroka, Illakka from Ranotsara Shear Zone and
Antranondambo south of RSZ. These occurrences also carry garnet, spinel,
aquamarine, tourmaline and other gems. De Wit et al, (2001) dated a cordierite
~ bearing pegmatities within the RSZ at 548 and at 523 - 527 Ma from U-Pb
dating of monazites. The age of chrysobery! bearing pegmatites mineralization
reported from southern India South of ASZ is also similar 51342 Ma (Miller et
al, 1996), Moreover, north of ASZ no chrysoberyl occurrence is reported.
Yellow-blue-green chrysoberyl varieties, cat’s eye and alexandrite in
pegmatites occur at Pattara near to Morawaka, and in sediments of
Matugama, Rakwana and Ratnapura. The other gem stones are spinel, garnet,
tourmaline, topaz, zircon, beryl, moonstone, citrine, amethyst and kornerupine,
(Munasinghe and Dissanaya, Ke 1981; Harder, 1992; Gunaratne and
Dissanayake, 1995).
The zircon U-Pb lower fraction intercepts between 510 and 460 Ma (Holzi
et al, 1994) from Vijayan complex of Sri Lanka probably reflect the age of
peak metamorphism and intrusive events of pegmatites like southern India
and southern Madagascar. The identical gem field in these three continental
fragments, the clear proximity to the intercontinental shear belt and the
available ages for chrysoberyl mineralization in all these East Gondwana
Crustal fragments allow a close correlation during the late Pan - African
time, Further studies are needed to extend the intercontinental shear belt into
Africa, since the celebrated chrysoberyl occurrences are reported from
Zimbabwe and Tanzania.
Wa7 Mineral Exploration
Lotzow-Holm Complex
Yamato-Belgica
Complex.
Fig. 7. India-Sri Lanka-Madagascar assembly within East Gondwana (modified after Braun and
Kriagsman, 2003). The locations of chrysoberyl bearing gem pegmatites are shown. The
sinistral Achankovil Shear Zone extending into Sinistral Ranotsara Shear Zone of
Madagascar and also crossing the Southern tip of Sri Lanka (exactly where?) are possible
Con the basis of chrysobery! mineralization at 1. Betroka 2. Iiakaka 3. Antranondambo 4.
Rose Mala 5. Kalakkad 6. Ratnapura 7. MatugChrysoberyl from Southern Tamil Nadu of South India 73
ACKNOWLEDGEMENTS
The first author expresses his sincere thanks to Mr. A.P.C.V.
Chockalingam, Secretary and Prof. A. Francis, Principal, V.O.C, College,
Tuticorin. The help extended by Dr. N.S. Gururajan, Wadia Institute of
Himalayan Geology, Detradun and faculty members, Department of Gelogy,
University of Kerala, are highly acknowledged.
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