Autopista al Aeropuerto Km.

8 Minerals Services
Tel: 3769500 Barranquilla
FAX: 3769503 - 3762071 A.A. 3505 F490101
Barranquilla-Colombia Job No. OL54043|3
Página 1 de 5

Report N°: 1707102019I

MATERIAL SAFETY DATA SHEET

Section 1 – Chemical Product and Company Identification

MSDS Name CARBON MINERAL

Catalog Numbers N/A
Synonyms CARBON MINERAL
Company Identification C.I. FRONTIER COAL S.A.S
Address BARRANQUILLA - ATLANTICO
CRA 77B NO.57-141-OFIC.812 LAS AMERICAS UNO

Telephone

Section 2 – Composition/Information on Ingredients

Laboratory ID: CO1700874.001 Analysis Date: 30/06/2017

ID Muestra: MUESTRA 1 CARBON TIPO 1
*-COMPLETE PROXIMATE ANALYSIS As Received Dry Basis Method
Total Moisture, pct.wt. 18.15 ASTM D3302/D3302M-15*
Ash, pct.wt. 7.34 8.97 ASTM D7582-15(*)
Volatile Matter, pct.wt. 37.12 45.35 ASTM D3175-11 (*)
Fixed Carbon (by diff), pct.wt. 37.39 45.68 ASTM D3172-07a(by diff)
Sulfur, pct.wt. 0.98 1.20 ASTM D4239-14e2 Method A(*)
Gross Calorific Value (BTU/Lb) 9535 11649 ASTM D5865-13(*)
Gross Calorific Value (Kcal/Kg) 5297 6472 ASTM D5865-13
Gross Calorific Value (GJ/TM) 22.18 27.10 ASTM D5865-13
Gross Calorific Value (J/g) 22178 27096 ASTM D5865-13

*-ULTIMATE ANALYSIS IN COAL As Received Dry Basis Method

Total Moisture, pct.wt. 18.15 ASTM D3302/D3302M-15*
Ash, pct.wt. 7.34 8.97 ASTM D7582-15(*)
Sulfur, pct.wt. 0.98 1.20 ASTM D4239-14e2 Method A(*)
Carbon, pct.wt. 53.7 65.6 ASTM D5373-14 Metodo A (*)
Hydrogen, pct.wt. 4.04 4.93 ASTM D5373-14 Metodo A (*)
Nitrogen, pct.wt. 1.36 1.66 ASTM D5373-14 Metodo A (*)
Oxygen (by diff) 14.41 17.61 ASTM D3176-09 (by diff)

*-FUSION TEMP OF ASH OXIDIZING ATMOSPHERE °C °F Method

Initial Deformation Temperature, IT 1239 2262 ASTM 1857/D1857M-04(2010)*
Softening Temperature, ST 1251 2284 ASTM 1857/D1857M-04(2010)*
Hemispherical Temperature, HT 1273 2323 ASTM 1857/D1857M-04(2010)*
Fluid Temperature, FT 1294 2361 ASTM 1857/D1857M-04(2010)*

*-FUSION TEMP OF ASH REDUCING ATMOSPHERE °C °F Method

Initial Deformation Temperature, IT 1169 2136 ASTM 1857/D1857M-04(2010)*
Softening Temperature, ST 1201 2194 ASTM 1857/D1857M-04(2010)*
Hemispherical Temperature, HT 1232 2250 ASTM 1857/D1857M-04(2010)*
Fluid Temperature, FT 1271 2320 ASTM 1857/D1857M-04(2010)*

*-HARDGROVE GRINDABILITY INDEX Result Method

Hardgrove Grindability Index 49 ASTM D409M-12(*)
Hardgrove Grindability Moisture 12.80 % ASTM D409M-12(*)
The information contained herein is for the purpose of facilitating pre-shipment inspection and does not relieve exporters or importers from their obligations in respect of compliance
with the import regulations of the country of import. The services provided under the PSI Programme are not intended to affect the contractual rights and obligations of the parties to a
transaction for which SGS is not acting. Should a party desire that SGS perform quality or quantity inspections for letter of credit purposes, said party should take contact with the
nearest SGS affiliate and such inspection shall be subject to the SGS General Conditions of Service. Although every effort has been made to ensure the correctness of the
information, as at the date of issuance of this data sheet, SGS does not accept any responsibility for errors or omissions and, furthermore, the information may subsequently be
subject to change as may be announced by the Authorities in the country of import. Consequently, exporters and importers are advised to check with SGS, prior to shipment of the
goods, if there is any doubt concerning the issuance of a Clean Report of Findings. For further information, or clarification, pl ease contact the SGS Office in the country of export of
the goods.
WARNING: The sample(s) to which the findings recorded herein (the “Findings”) relate was (were) drawn and / or provided by the Client or by a third party acting at the Client’s
direction. The Findings constitute no warranty of the sample’s representativeness of any goods and strictly relate to the sample(s). The Company accepts no liability with regard to
the origin or source from which the sample(s) is/are said to be extracted. This document is issued by the Company under its General Conditions of Service accessible at
http://www.sgs.com/terms_and_conditions.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is
advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole
responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Autopista al Aeropuerto Km.8 Minerals Services
Tel: 3769500 Barranquilla
FAX: 3769503 - 3762071 A.A. 3505 F490101
Barranquilla-Colombia Job No. OL54043|3
Página 2 de 5

Report N°: 1707102019I

MATERIAL SAFETY DATA SHEET

*-MAJOR AND MINOR ELEMENTS Result Method

Sulphur trioxide, SO3 11.73 % ASTM D5016-08e1 (*)
Aluminum Oxide, Al2 O3 18.77 % ASTM D6349-13(*)
Barium Oxide, BaO 0.47 % ASTM D6349-13(*)
Calcium Oxide, CaO 8.63 % ASTM D6349-13(*)
Strontium Oxide, SrO 0.17 % ASTM D6349-13(*)
Phosphorus Pentoxide, P2 O5 0.18 % ASTM D6349-13(*)
Iron Oxide, Fe2 O3 11.49 % ASTM D6349-13(*)
Magnesium Oxide, MgO 4.23 % ASTM D6349-13(*)
Manganese Oxide, Mn3O4 0.10 % ASTM D6349-13(*)
Manganese Oxide, MnO2 0.11 % ASTM D6349-13(*)
Potassium Oxide, K2O 0.84 % ASTM D6349-13(*)
Silicon Dioxide, SiO2 40.82 % ASTM D6349-13(*)
Sodium Oxide, Na2O 0.79 % ASTM D6349-13(*)
Titanium Dioxide, TiO2 0.85 % ASTM D6349-13(*)
Non-Normalized Results

Hazardous Ingredients (specific) Not applicable

% Not applicable
CAS Number Not applicable
LD50 of Ingredient Not applicable
LC50 of Ingredient Not applicable

Section 3 - Hazards Identification

Material Appearance Black, solids to fine dust

Caution May cause mechanical eye and skin irritation
Effect on health Eye: dust may cause mechanical irritation
Skin: dust may cause mechanical irritation
Ingestion: large amount may cause irritation
Inhalation: dust irritates respiratory tract, chronic inhalation may lead to a
decreased pulmonary function. Continued exposure to dust may lead to lung
disease, coal worker’s pneomonconiosis, which is characterized by continued
coughing and shortness of breath.

Section 4 - First Aid Measures

Eyes Flush repeatedly with water, seek medical attention if no relief

Skin Wash with soap and water see medical attention if no relief
Ingestion Seek Medical advice
Inhalation Place patient in a fresh air environment as soon as possible
Seek medical attention if breathing problem persists.

The information contained herein is for the purpose of facilitating pre-shipment inspection and does not relieve exporters or importers from their obligations in respect of compliance
with the import regulations of the country of import. The services provided under the PSI Programme are not intended to affect the contractual rights and obligations of the parties to a
transaction for which SGS is not acting. Should a party desire that SGS perform quality or quantity inspections for letter of credit purposes, said party should take contact with the
nearest SGS affiliate and such inspection shall be subject to the SGS General Conditions of Service. Although every effort has been made to ensure the correctness of the
information, as at the date of issuance of this data sheet, SGS does not accept any responsibility for errors or omissions and, furthermore, the information may subsequently be
subject to change as may be announced by the Authorities in the country of import. Consequently, exporters and importers are advised to check with SGS, prior to shipment of the
goods, if there is any doubt concerning the issuance of a Clean Report of Findings. For further information, or clarification, pl ease contact the SGS Office in the country of export of
the goods.
WARNING: The sample(s) to which the findings recorded herein (the “Findings”) relate was (were) drawn and / or provided by the Client or by a third party acting at the Client’s
direction. The Findings constitute no warranty of the sample’s representativeness of any goods and strictly relate to the sample(s). The Company accepts no liability with regard to
the origin or source from which the sample(s) is/are said to be extracted. This document is issued by the Company under its General Conditions of Service accessible at
http://www.sgs.com/terms_and_conditions.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is
advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole
responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Autopista al Aeropuerto Km.8 Minerals Services
Tel: 3769500 Barranquilla
FAX: 3769503 - 3762071 A.A. 3505 F490101
Barranquilla-Colombia Job No. OL54043|3
Página 3 de 5

Report N°: 1707102019I

MATERIAL SAFETY DATA SHEET

Section 5 - Fire Fighting Measures

General Information Wear a self contained breathing apparatus with fullprotective gear, coal dust
may be a potentially explosive material – avoid catalytic sparks or flames in a
dusty environment.
Extinguishing Media Water spray (fog) is best extinguishing medium for small fires; carbon dioxide
dry chemical media and foam may also be used.
Piles of coal not properly compacted/stacked may ignite – use of water to
control fire in a stock pile may result in hydrogen explosion.

Auto ignition Temperature Not applicable

Flash Point Not applicable
NFPA Rating Not available
Explosion Limits Lower: not available
Upper: not available

Section 6 - Accidental Release Measures

General Information Utile suitable personal protective equipment

Spills Vacuum or sweep up material into suitable area/container for storage/disposal.
Avoid generating dusty conditions.

Section 7 - Handling and Storage

Handling Work with correct equipment.

Wash self thoroughly after handling
Work always with adequate ventilation
Avoid contacting with eyes, skin and clothing
Avoid ingestion and inhalation
Storage Avoid stacking in loose piles for extended time, storing near heat sources or
oxidizing agents and compatible substances or in improperly ventilated areas.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls Use adequate ventilation to keep airborne concentration of finex particles to a
minimum
Exposure Limits Not applicable
Personal Protective Eyes Always wear appropriate protective eyeglasses or safety goggles
equipment
Skin Wear appropriate gloves to protect skin exposure
Clothing Wear appropriate protective clothing to minimize skin exposure

Respirator Use dust respirators where excessive airborne dust is present in

the workplace.
The information contained herein is for the purpose of facilitating pre-shipment inspection and does not relieve exporters or importers from their obligations in respect of compliance
with the import regulations of the country of import. The services provided under the PSI Programme are not intended to affect the contractual rights and obligations of the parties to a
transaction for which SGS is not acting. Should a party desire that SGS perform quality or quantity inspections for letter of credit purposes, said party should take contact with the
nearest SGS affiliate and such inspection shall be subject to the SGS General Conditions of Service. Although every effort has been made to ensure the correctness of the
information, as at the date of issuance of this data sheet, SGS does not accept any responsibility for errors or omissions and, furthermore, the information may subsequently be
subject to change as may be announced by the Authorities in the country of import. Consequently, exporters and importers are advised to check with SGS, prior to shipment of the
goods, if there is any doubt concerning the issuance of a Clean Report of Findings. For further information, or clarification, pl ease contact the SGS Office in the country of export of
the goods.
WARNING: The sample(s) to which the findings recorded herein (the “Findings”) relate was (were) drawn and / or provided by the Client or by a third party acting at the Client’s
direction. The Findings constitute no warranty of the sample’s representativeness of any goods and strictly relate to the sample(s). The Company accepts no liability with regard to
the origin or source from which the sample(s) is/are said to be extracted. This document is issued by the Company under its General Conditions of Service accessible at
http://www.sgs.com/terms_and_conditions.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is
advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole
responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Autopista al Aeropuerto Km.8 Minerals Services
Tel: 3769500 Barranquilla
FAX: 3769503 - 3762071 A.A. 3505 F490101
Barranquilla-Colombia Job No. OL54043|3
Página 4 de 5

Report N°: 1707102019I

MATERIAL SAFETY DATA SHEET

Section 9 – Physical & Chemical Properties

Physical State Solid

Appearance Black – dull to shirty
Odor Little or no odor
PH Not available
Vapour Pressure Negligible
Vapour Density Not available
Evaporation Rate Negligible
Viscosity Not available
Boiling Point Not available
Freezing/Melting Point Not applicable
Decomposition Temperature Not applicable
Solubility Insoluble in water
Specific gravity/density 0.9 – 1.0
Molecular Formula Not applicable
Molecular Weight Not applicable

Section 10 - Stability & Reactivity

Chemical Stability Stable under standard temperatures and pressures

Hazardous decomposition CO2
products
Hazardous Polymerization Not reported

Section 11 – Toxicological Information

Carcinogenicity Not available Neurotoxicity No data available

Epidemiology No data available Mutagenicity No data available
Teratogenicity No data available Other studies No data available
Reproductive effects No data available
Section 12 – Ecological Information

Ecotoxicity No data available

Environmental No data available
Physical No data available
Chemical No data available
Other Studies No data available

Section 13 - Disposal Consideration

General Not relevant

The information contained herein is for the purpose of facilitating pre-shipment inspection and does not relieve exporters or importers from their obligations in respect of compliance
with the import regulations of the country of import. The services provided under the PSI Programme are not intended to affect the contractual rights and obligations of the parties to a
transaction for which SGS is not acting. Should a party desire that SGS perform quality or quantity inspections for letter of credit purposes, said party should take contact with the
nearest SGS affiliate and such inspection shall be subject to the SGS General Conditions of Service. Although every effort has been made to ensure the correctness of the
information, as at the date of issuance of this data sheet, SGS does not accept any responsibility for errors or omissions and, furthermore, the information may subsequently be
subject to change as may be announced by the Authorities in the country of import. Consequently, exporters and importers are advised to check with SGS, prior to shipment of the
goods, if there is any doubt concerning the issuance of a Clean Report of Findings. For further information, or clarification, pl ease contact the SGS Office in the country of export of
the goods.
WARNING: The sample(s) to which the findings recorded herein (the “Findings”) relate was (were) drawn and / or provided by the Client or by a third party acting at the Client’s
direction. The Findings constitute no warranty of the sample’s representativeness of any goods and strictly relate to the sample(s). The Company accepts no liability with regard to
the origin or source from which the sample(s) is/are said to be extracted. This document is issued by the Company under its General Conditions of Service accessible at
http://www.sgs.com/terms_and_conditions.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is
advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole
responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Autopista al Aeropuerto Km.8 Minerals Services
Tel: 3769500 Barranquilla
FAX: 3769503 - 3762071 A.A. 3505 F490101
Barranquilla-Colombia Job No. OL54043|3
Página 5 de 5

Report N°: 1707102019I

MATERIAL SAFETY DATA SHEET

Section 14 - Transport Information

General Land, air and marine

Section 15 - Regulatory Information

General Not relevant

Section 16 - Additional Information

General Not relevant

Barranquilla,Colombia SGS COLOMBIA S.A.S.

July 10th, 2017

The information contained herein is for the purpose of facilitating pre-shipment inspection and does not relieve exporters or importers from their obligations in respect of compliance
with the import regulations of the country of import. The services provided under the PSI Programme are not intended to affect the contractual rights and obligations of the parties to a
transaction for which SGS is not acting. Should a party desire that SGS perform quality or quantity inspections for letter of credit purposes, said party should take contact with the
nearest SGS affiliate and such inspection shall be subject to the SGS General Conditions of Service. Although every effort has been made to ensure the correctness of the
information, as at the date of issuance of this data sheet, SGS does not accept any responsibility for errors or omissions and, furthermore, the information may subsequently be
subject to change as may be announced by the Authorities in the country of import. Consequently, exporters and importers are advised to check with SGS, prior to shipment of the
goods, if there is any doubt concerning the issuance of a Clean Report of Findings. For further information, or clarification, pl ease contact the SGS Office in the country of export of
the goods.
WARNING: The sample(s) to which the findings recorded herein (the “Findings”) relate was (were) drawn and / or provided by the Client or by a third party acting at the Client’s
direction. The Findings constitute no warranty of the sample’s representativeness of any goods and strictly relate to the sample(s). The Company accepts no liability with regard to
the origin or source from which the sample(s) is/are said to be extracted. This document is issued by the Company under its General Conditions of Service accessible at
http://www.sgs.com/terms_and_conditions.htm. Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein. Any holder of this document is
advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole
responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.