Aiits 2016 HCT Vi Jeem Jeea/advanced/paper-1/solutions/solutions

1
AIITS-HCT-VI(Paper-1)-PCM(S)-JEE(Advanced)/16
FIITJEE
FIITJEE Students From All Programs have bagged 33 in Top 100, 77 in Top 200 and 205 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2015:
JEE(Advanced)-2016
ALL INDIA INTEGRATED TEST SERIES
ANSWERS, HINTS & SOLUTIONS
HALF COURCE TEST –VI
(Paper - 1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. B D A
4551 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
2. C C A
3. C A A
4. B C A
5. A, B, C, D A, B, D B, C
6. A, B, D B, C, D A, C
7. A, C B, C, D A, B, C
8. A, B A, B A, B
9. A A B
10. A B A
11. B C C
(A)  (r) (A)  (p) (A)  (s)
(B)  (p) (B)  (s) (B)  (p)
1.
(C)  (s) (C)  (q, t) (C)  (r)
(D)  (q) (D)  (r) (D)  (q)
(A)  (p, q, r) (A)  (r); (A)  (p)
(B)  (s, t) (B)  (p, q, t) (B)  (q)
2.
(C)  (s, t) (C)  (p, q, s) (C)  (r)
(D)  (p, q, r) (D)  (p, t) (D)  (s)
1. 4 2 8
2. 2 2 5
3. 3 6 1
4. 1 3 8
5. 4 4 7
6. 4 9 7
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website: www.fiitjee.com
2
Physics PART – I
SECTION – A
1. V1 = 4.5 m/s, V2 = 3 m/s
d
2. F  g  L  x   gL   xu 
dt
3. vp x  5 , v p y  5
5 2 = 7.1 m/s approx.
4. Solve the problem using  as the coefficient of kinetic friction. Linear velocity radius to zero
before angular velocity becomes zero.
5. y = A sin (kx - t + )
at t = 0, x = 0, y = 5 mm
1
at t  , x = 0, y = 0
24
also  = 2m, A = 10 mm
Solve to get answer.
6. Given PT = Constant and PV = nRT

 P2V = constant
 PV1/2 = K.
From first law of thermodynamics
Q = U + O
 
 Pf Vf  PV
i i

CT  CV T   
 1  1 
 2 
C = CV + 2R
R
33.24   2R
Y 1
2
 Y = 1.5 and Y  1 
f
 f = 4.
7. Impulse = change in momentum

 
 2(v 2  v1 )
2
 2(3iˆ  ˆj)

As impulse is in the normal direction of colliding surface
6
1
tan  
3 
 1
  tan1  
3
 1
  90  tan1   .
3
3
KAd d
8. H  K(2rL)
dr dr
r2 
dr 2KL 2
  r  H  d
r
1  1
dQ 2KL(2  1 )
H  80
dt r 
ln  2 
 r1 
dm
 L  80
dt
dm 80 80 
    kg/second.
dt L 80  4200 4200
Fcos  Fcos2 
9. Tensile stress  
A / cos  A
10. Tensile stress is maximum when cos2 is maximum i.e. at  = 0º
F sin  F sin  cos  F sin 2

11. Shearing stress   
A / cos  A 2A
SECTION – C
 2 
1.   a sin t  (x cos   y cos )
  
represents a wave travelling along a line in x-y plane through origin making an angle  with x-axis
and  with the y-axis.
2
  (x2  x1 )cos   (y 2  y1)cos 

comparing with the given equation, we get
 = 30º,  = 60º,  = 1m,  = 30/s
Also,  = 4.
2. P =  A e (30004 – 3004) = 2 kW.
50 1 2GM
3. v= V =
100 e 2 R
Applying energy conservation
GMm 1 GMm
  m v 2   
R 2 (R  h)
2GM 2GM
  v2 = 
R Rh
1 2GM 1 1 
 . = 2GM   
4 R R Rh
1 h
 =
4R R(R  h)
  R + h = 4h
  h = R/3
4
4 N = mg N
 N = m r 2
 mg = m. 2 sin  
2
mr2
N
g

2sin  mg
0.1 10

2  sin30
 = 1 rad / s.
5. x = A cos t
dx
v   A sin t
dt
d2 x
a   A2 cos t
dt 2
amax  A2
amax 1 A2 1
max = I max  I  MR2  MR A2
R 2 R 2
max  4N.m
6. A1v1  A 2 v 2
v2 =16 m/s
Applying Bernoulli’s equation
1 1 3 3
P1  v12  P2  v 22 ( = 0.9  10 kg/m )
2 2
5
Chemistry PART – II
SECTION – A
1. H2 O
Mg2 C3   CH3  C  C  H   i Na
 ii CH3 CH2  Cl  H3 C  C  C  CH2  CH3
 X  Y
P 2 - catalyst
Me Et
C C
H H
( 2Z ) - pent - 2 - ene
Hence (D) is correct.
0
140 C NaBH4 H2 O
2. BCl3  3NH4 Cl  B3N 3H3 Cl3 
 reduction 
 BNH3 3 6   NH3  H3BO3  H2
(A )
 trichloroborazine   Borazine or
Inorganic benzene  B
Hence (C) is correct.
3. CH3 H 2C Cl CH3 CH3 CH3 CH3

Cl2
H Cl  H

hv
Cl Cl Cl H Cl H Cl H Cl
H 2C CH 2 CH3 H 2C CH2 CH3 H 2C CH2 CH3 CH Cl CH 2 CH2
(S)-2-chloropentane (optically active (1) (optically inactive) H 2C CH3 CH Cl CH2
(optically CH3 H2 C Cl
active (2)
(one optically (optically
active and one active (1)
optically
inactive)
Hence (A) is correct.
4. The limiting reagent here is HCl. So calculating with the limiting reagent, the total number of
products is 7.5.
5. Symmetrical alkenes give same products.
6.
&
,
have (4n + 2) electrons.
7. CCl4 does not undergo hydrolysis.
8. KEmax of photoelectrons ejected depends only on frequency and not on its intensity.
Also, photoelectric effect is a direct evidence for the particle nature of light not of dual nature.
Hence (A), (B) is correct.
9. CH3 O
i  O
H2C C CH CH2 
 ii  Zn / H O  HCHO
3
2
H3C C CHO HCHO
6
10.
O
 i O

ii Zn / H O 
3
2
11. Oxidative ozonolysis
SECTION – B
1. F
F
S O
Xe
F
O O F
O (D)
(B)
Trigonal bipyramidal
2. (A) CH3
i O3
H C
ii Zn/H O  2 2

2
CH3
(B) CHO
 i O
H2C CH CH CH CH3 
ii Zn / H O 2HCHO 3
2
H3C CHO
CHO
(C) H3C
i  O3
CHO
(H3C)2C CH CH CH2 
 ii Zn / H O  2
C O HCHO
CHO
H3C
(D) H3C CH CH2 
 ii Zn / H O H3C  i  O3
CHO HCHO
2
SECTION – C
1. 

AgSCN  
 Ag  SCN

a a


AgBr 
 Ag  Br
 
b b
K  sp AgSCN  a  b  a  1.0  1012
 2
K sp AgBr  a  b  b 5.0  1013
2. N2  3H2  2NH3

Initial 2 5 0
(after N2 reacted50%) 1 2 2
Total moles of N2, H2 and NH3 = 5 mol (after reaction)
Initial mol = 7
7
Pressure at start = 7 atm.

Hence pressure at equilibrium = 5 atm.
2
Partial pressure of NH3 =  5 = 2 atm.
5
4.   4.9 B.M, 4.9  n n  2 

Number of unpaired electorn in Mnx+ = 4, x = 3
5. Volume withdrawn = (20 2)  20 = 20 L

20
Numer of balloons = 4
5
6. Maximum number of electron in 3rd orbit = 18

 electrons with spin quantum number m s = 1/2 = 9
8
Mathematics PART – III
SECTION – A
1. Put x = 1 and x = – 1 and adding
25
325  1 1  2   1
a0 + a2 + … + a50 = 
2 2
25
C0  C1  2  C2  2  ...  C25  225  1
25 25 2 25

2
2 1  25 C1  25 C2 2  ...  25C25 224 

2
 2 13  25 C2  ...  25C25 225   even.
2. Circle touching y = x at (0, 0) can be taken as x 2 + y2 + (x – y) = 0 … (i)
This bisects the circumference of the circle x 2 + y2 + 2y – 3 = 0 … (ii)
Hence radical axis between (i) and (ii) must pass through the centre of (ii) which is (0, – 1)
Radical axis is (x – y) – 2y + 3 = 0, hence x = – 5 put x = – 5 in (i) to get the result.
3. Number of positive integral solution of x + y + z + w = 50 is 50C3
Number of positive integral solution of x + y + z + w = 19 is 19C3
4. For equilateral triangle
z2  z1  z3  z2  z1  z3  a
z2  z3 z  z3 a 3
Also  z1 will be the length of median as well as altitude i.e. 2  z1 
2 2 2
2 2
z 2  z1  z 3  z1 1 
Hence, sin   2 2
   .
z 2  z 3  2z1  z 3  z 2 2 4
x2 y2
5. Any conic having its foci same as the given ellipse will have equation   1 , x is
9 4
variable now if the curve passes through (3, 2), we get
 = 6
Putting value of , we get the required answer.
6. For real roots 4a2 – 4b (a – 1)  0
 a2 – ba + b  0
Now for above inequality to hold for all values of a,
b2 – 4b  0 or 0  b  4.
7. We have AE = EP = AP = 1  AP = PT = 1 A
 APT is isosceles
This makes AET a 30º – 60º – 90º triangle, 1 30º 13
So AT = 3 and ATX = 150º 1 3
since TX = 2 60º 30º 150º
 By applying cosine rule in ATX, we get E
2 1 P 1 T 2 X
(AX) = 3 + 4 – 4 3 cos 150º
= 7 + 6 = 13
 AX  13
13  1  16 2 1
 cos XAE    .
 
 2  13 1 2 13 13
9
8. Let A be (h, k), then altitude = k

2 2
Also AB : AC = 2 : 1, hence AB = 4AC
2 2 2 2 2 2
Now, AB = h + k and AC = (6 – h) + k
2
 AC2  12 
2
 4AC     10
 4 
 20  96  AC  20  96
5 7
9-11. Slope of AB  , hence slope of PQ 
7 5
C   C
Let equation of PQ be 7x + 5y = C, then coordinates of P & Q will be  ,0  &  0,  . Now
7   5
x 5y 7x y
equation of AQ and BP will be  0&  1
7 c C 5
2 2
Eliminating C from these two equations gives the locus of R as the circle x + y – 7x + 5y = 0.
Now, T will be the point on the diameter through origin of this circle at a distance 74 i.e.
distance of centre from origin + radius. Hence coordinate of T is (7, –5). Equation of the requires
parabola (y + 5)2 = 2(x – 7). The line y = - 3 meets the parabola at (9, - 3). As the line is parallel to
 15 
the axis so any ray incident along it will pass through focus  ,  5  of the parabola after getting
 2 
 15 
reflected. Hence the reflected ray will be travelling along the line joining (9, –3) &  ,  5  .
 2 
Hence equation of reflected ray will be 4x – 3y = 45.
SECTION – B
1. (A) Required numbers of ways = 2C1  2C1  7!  2!

(B) Required numbers of ways = 8!
(C) Required numbers of ways = 6!  2!  2C1  2C1
(D) Required numbers of ways = 9!  8C2  6C2  4C2 2C2
2. (A) 2 sinx, sin 2x & 2cosx are in A.P., hence sin 2x = sin x + cos x
Now, let sin x + cos x = t, then sin 2x = t2 – 1, then the above equation gives t2 – t – 1 = 0 or
1 5
t  sin x  cos x 
2
(B) Let C be the sides angles, then angles will be
 c   c
 , , 
3 3 3 3 3
 c    
   c  c  , hence angles are , , .
3 3 2 6 3 2
a b c a b c
Now     
   1 3 2
sin sin sin
6 2 2
  
Hence angles are , , .
6 3 2
a b c
Now  
  
sin sin sin
6 3 2
10
a b c
   .
1 3 2
(C) Let AB = a, BC = 3 a, CA = 3a & AD = 3 3 a
a2  27a2  BD2 3a2  9a2  BD2
Now cos A + cos C = 0   0
3 3a2 3 3a2
BD
BD2 = 20a2   20  2 5
AB
2a2c 2 8a2c 2
(D) a + c = 2b & b2 = 2 2
 (a + c)2 = 2
a c a  c2
4 2 2 2
 (a + c) – 2ac(a + c) – 8a c = 0
 a  c 2
 2,4
ac
But 4 gives a = c, hence taking – 2
a
a2 + 4ac + c2 = 0   3  2 .
c
SECTION – C
R 3
1.   2  ABC must be equilateral
r 1.5

so a = b = c = 2R sin =R 3
3
2 3 4
 1  2  1  3  1 
Now a cot2 A + b2 cot3 B + c3 cot4 C  R 3 
 3
  R 3   
 3

  R 3  
 3

R R 2 R3 3  32  33 39
      13 3
3 3 3 3 3
m  n 16
m = 13, n = 3    8.
2 2
 5   5   5   5   5   5 
210 sin  11  cos  11  cos  10  cos  9  ...cos  3  cos  2 
2. 2  2  2  2  2  2 
210
5
sin
1
 102   4 5
2 1024
hx ky
3. Let P be (h, k), then chord of contact will be
 1
2 3
Homogenising equation of hyperbola by equation of chord of contact gives
2
x2 y2  hx ky  1 h2 1 k 2
    1 . If these are perpendicular lines, then    0
2 3  2 3  2 4 3 a
x2 y2 1
hence required locus is  
4 9 6
R
4. For equilateral triangle r  , hence R = 8
2
11
r R
Now in radius r of ABC is the circum radius for second triangle. Hence x1  
2 4
x1 R R
Similarly x 2   , x3  …
2 8 16
R R R
x1 + x2 + x3 + …  =    ...
4 8 16
R
R
Hence sum of all these radii is 4   R  8 .
R 2
1
2
2 2 2
z3  z  z3 z 3  z  z 3
5. R.M.S.  A.M.  
3 3
2 2 2 2
Also |z – 3| + |z| + |z + 3| = 2(|z| + 9), hence z  10  a = 3
where as z  3  z  z  3  z  3  2  2  3  |z|  4
 b = 4.
a + b = 7.
6. Let us form that equation having roots y = g(x i)

i.e. y = x2 – 2  x  y  2
2 2
 y2   y2  1 0
y + 20y + 40y + 79y2 + 74y + 23 = 0
5 4 3

 g(x1) g(x2) … g(x5) = product of roots
= – 23
x1x2x3x4x5 = – 1  g(x1x2x3x4x5) = – 1
 g(x1)g(x2) … g(x5) – 30g(x1x2 … x5) = 7.

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1

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. V1 = 4.5 m/s, V2 = 3 m/s

6. Given PT = Constant and PV = nRT

7. Impulse = change in momentum

10. Tensile stress is maximum when cos2 is maximum i.e. at  = 0º

F sin  F sin  cos  F sin 2

2. P =  A e (30004 – 3004) = 2 kW.

Hence (C) is correct.

3. CH3 H 2C Cl CH3 CH3 CH3 CH3

Hence (A) is correct.

5. Symmetrical alkenes give same products.

7. CCl4 does not undergo hydrolysis.

11. Oxidative ozonolysis

2. N2  3H2  2NH3

Pressure at start = 7 atm.

4.   4.9 B.M, 4.9  n n  2 

5. Volume withdrawn = (20 2)  20 = 20 L

6. Maximum number of electron in 3rd orbit = 18

Mathematics PART – III

8. Let A be (h, k), then altitude = k

1. (A) Required numbers of ways = 2C1  2C1  7!  2!

6. Let us form that equation having roots y = g(x i)

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