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VCI SHRINK FILM FPE691

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: VCI SHRINK FILM FPE691 – ANTI UV – FLAME RETARDANT

VOLATILE CORROSION INHIBITOR

Application: This product is recommended for:

Pre-packaging of metal materials.
Corrosion protection for ferrous and nonferrous metal materials that are in
storage and transportation processes.

Manufacturer: VCI Brasil Indústria e Comércio de Embalagens Ltda.

Address: Rodovia Marechal Rondon, Km 334,3 - Chácaras Bauruenses - Bauru, SP
Telephone: (14) 2106-66600 / Fax: (14) 2106-6608
Site: www.vcibrasil.com.br

Emergency telephone number: 55-14-2106-6600

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture: The product (mixture) not classified as hazardous,
according to the Globally Harmonized System (GHS) and ABNT NBR 14725/2012.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC: Void
Information concerning particular hazards for human and environment: No hazards to be
particularly mentioned. Please note the information of this Material Safety Data Sheet.

Label elements:
Pictogram: not classified as hazardous
Signal word: not classified as hazardous
GHS label elements: Void
Hazard statements: Void

* We recommend that all chemicals be handled with care

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or a doctor if you feel unwell
P501 - Dispose of contents/container in accordance with local regulation
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VCI SHRINK FILM FPE691

3. COMPOSITION AND INFORMATION ON INGREDIENTS

Chemical or Generic Name: Mixture

Synonym: Mixture
CAS #: Not applicable for the mixture

Ingredients / impurities: do not contain hazardous chemicals

Chemical name CAS # Weight percentage

VCI SALT 1 - anticorrosive additive Not determined Industrial Property
VCI SALT 2 - anticorrosive additive Not determined Industrial Property
VCI SALT 3 – anti-UV – Flame Retardant Not determined Industrial Property
Polyethylene Resin MI 30 9002-88-4 97 – 98%

Note 1: Salts derived from non-aromatic amines, and its composition is obtained through chemical synthesis reactions, to
prepare the active volatile corrosion inhibitor:
Note 2: Its formulation does not contain any heavy metals nor any nitrite, nitrate, sulfate, chromate salts, nor any amines
included on the negative list of chemical products.
Note 3: The chemical products used by the VCI Brasil Company are not dangerous to human health and they are not
suspects of causing cancer. They do not promote chemical interactions, nor do they decompose into toxic substances.

4. FIRST AID MEASURES

General advice:
If inhaled:
In case of skin contact:
In case of eye contact:
If swallowed:
Notes for the physician:
Consult a physician. Show this safety data sheet to the doctor in
attendance.
If breathed in, move person into fresh air. If not breathing, give
artificial respiration. Consult a physician.
Take off contaminated clothing and shoes immediately. Wash off
with soap and plenty of water. Consult a physician.
Rinse thoroughly with plenty of water for at least 15 minutes and
consult a physician.
Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Rinse mouth with water. Consult a physician.
Symptomatic treatment.

5. FIREFIGHTING MEASURES
Appropriate means of Not applicable; non-combustible product.
extinguishing:
Inappropriate means of Not applicable; non-combustible product.
extinguishing:
Specific hazards: Not applicable.
Advice for firefighters: Not required.
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6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions for non- If necessary to act, wear protective clothing as described in
emergency personal: Section 8 of this safety data sheet.

Personal precautions for Wear protective clothing as described in Section 8 of this

emergency responders: safety data sheet.
Removal of sources of ignition: Not applicable.
Control of dust: Not applicable.
Avoid inhalation, contact with
eyes and mucosa: Not applicable.
Environmental Stop the leak if this is possible at no risk. Do not send the leaked material
precautions: to public drainage systems. Avoid the chance of contamination of surface
or spring waters. Restrict flow to the smallest area possible.
Cleaning methods
Recovery: Gather the product in an appropriate container, identifying it for
subsequent recovery, treatment or disposal.
Neutralization: Absorb with dirt or other non-combustible absorbent material. Any use of
water must be consider the subsequent treatment of the contaminated
water.
Disposal: Contact the local environmental authorities in the event of leaks or
contamination of the soil, surface or spring waters.

7. HANDLING AND STORAGE

Precautions for safe handling
Safe handling precautions: Wear protective clothing as described in Section 8 of this safety
data sheet. Do not handle open container. Provide local exhaust /
ventilation in closed environments. Respect the general safety
and industrial hygiene rules.
Safe handling instructions: Respect the general safety and industrial hygiene rules.
Conditions for safe storage
Appropriate conditions: The containers must be stored in identified and ventilated areas.
Conditions to be avoided: Do not expose the drums to the sun, rain and high temperatures.

Incompatibility: Keep away from acids and strong oxidizing agents.

Recommended materials Plastic bag.
for packaging:
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VCI SHRINK FILM FPE691

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Control parameters
Occupational exposure Not established.
limits:
Exposure controls
Appropriate engineering Handle in accordance with good industrial hygiene safety
controls: practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection: Safety glasses.
Hand protection: For casual contact PVC gloves are suitable. Gloves must be
inspected prior to use.

Breathing protection: Not applicable.

Skin and body protection: Rubber or PVC apron and boots.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Solid - Pellets

Colour: White OR Blue (Phtalocianine pigment)
Odor: Characteristc
pH: 7.5 – 8.5 (extract in water)
Boiling point: No data available
Distillation range: No data available
Freezing point: No data available
Melting point: ~ 180 ºC
Decomposition above 340 ºC
temperature:
Flash point: No data available
Auto-ignition No data available
temperature:
Explosive Limits: LEL (lower explosive limit): No data available
UEL (Upper explosive limit): No data available
Vapour pressure: No data available
Vapour density: No data available
Density: 0.92 g/cm3
Water solubility:: Chemicals Soluble
VCI chemical product applied to Polyethylene Resin is soluble in
Water, Ethanol and Methanol
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10. STABILITY AND REACTIVITY

Chemical stability:
Reactivity:
Possibility of hazardous
reactions:
Incompatible materials:
Hazardous decomposition
materials:
Stable under recommended storage conditions. Does not
polymerize.
Under recommended storage conditions, the product is not
susceptible to dangerous reactions.
No data available
Keep away from strong chemical oxidizing agents (peroxides,
chlorates, chromic acid and others).
In case of fire in nearby areas, smoke may form.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity DL50 Oral > 5000 mg/kg
DL50 Dermal > 5000 mg/kg
CL50 Inhalation > 16.146 mg/L (4 H)

Skin corrosion/irritation Not classified as irritant.

Serious eye damage/eye
irritation Not classified as irritant.
Sensitization: No data available
Germ cell mutagenicity No data available
Carcinogenicity: No data available
Reproductive toxicity: No data available
Specific target organ toxicity - single
exposure: No data available
Specific target organ toxicity -
repeated exposure: No data available
Aspiration hazard: No data available
Additional data: Respect the general safety and industrial hygiene
rules.

12. ECOLOGICAL INFORMATION

Persistence and Classified as biodegradable, by the method OECD TG 301B.
degradability:
Mobility: All action/measures must be in accordance with environmental
regulations and requirements of local environmental
authorities.
Environmental impact: Product is not aggressive to the environment.
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13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product:
They can be treated at an ETS so long as disposal meets the
limits set down by local environmental entities. If you opt to
dispose of the product without treatment, environmental
legislation must also be obeyed so the residue does not harm
the fauna, flora and air (if incinerated).

Contaminated packaging: Do not reuse contaminated packaging. It should be disposed of

in a landfill or incinerated, or, sent to companies with
appropriate treatment according to local legislation and
permission from the environmental entity.

14. TRANSPORT INFORMATION

ONU Number:
IMDG Class: PRODUCT (MIXTURE) NOT CLASSIFIED AS HAZARDOUS FOR TRANSPORT
ICAO/IATA Class:

Commercial Name: VCI SHRINK FILM FPE691

Proper Shiping Name: VCI POLYETHYLENE FILM,
VCI COMPOUND – NON TOXICANT (ocular, dermal and inhalation)

Road Transport in Brazil

Resolution No. 420 of 12 February 2004 of the National Land Transport Agency (ANTT),
Approves the Supplementary Instructions to the Regulation of the Transport of Dangerous
Goods and its modifications

Domestic and International Air Transport

ANAC - National Civil Aviation Agency - Resolution No. 129 of December 8, 2009. RBAC N175 -
(BRAZILIAN CIVIL AVIATION REGULATION) - TRANSPORT OF DANGEROUS ARTICLES IN CIVIL
AIRCRAFT. IS N 175-001 - SUPPLEMENTARY INSTRUCTION - IS ICAO - "International Civil
Aviation Organization" - Doc 9284-NA / 905 IATA - "International Air Transport Association"
Dangerous Goods Regulation (DGR)

International Maritime Transport

DPC - Ports and Coasts Directory (Transportation in Brazilian waters) Maritime Authority Norms
(NORMAM) NORMAM 01 / DPC: Ships in Open Sea Navigation NORMAM
02 / DPC: Inland Navigation Ships IMO - "International Maritime Organization" International
Maritime Dangerous Goods Code (IMDG Code)
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15. REGULATORY INFORMATION

This data sheet (MSDS) was prepared according to the ABNT (Associação Brasileira de Normas
Técnicas) NBR 14725-4: 2012 and NR-26 according to the GHS (Globally Harmonized System -
Globally Harmonized System of Classification and Labeling of Chemicals).

Regulation of Land Transport of Dangerous Goods of the Ministry of Transportation of Brazil

(Ordinance No. 420 of February 12, 2004). (Section 14)

16. OTHER INFORMATION

Controle do documento:
Revision Date Description
00 20.01.2009 Initial document preparation
01 31.08.2010 Alteration in the Section 16
02 26.10.2010 Manufacturer's information
03 02.10.2012 Classification for transport
04 24.06.2015 Update the model NBR 14725 – GHS
05 30.11.2017 Compliance with standards NBR 14725 – GHS

The information in this MSDS represents current data and precisely reflects our best knowledge
for the appropriate handling of this product under normal conditions and according to the
specific application on the package and/or in literature. Any other use of the product that
involves its combined use with other products or other processes is the user's responsibility.
The chemical products used by VCI Brasil are not dangerous to human health and are not
suspected of causing cancer. They do not cause chemical interactions and they do not
decompose into toxic substances.

RESPOSIBLE FOR THE MANUFACTURER`S INFORMATION (V-ACTIVE VCI):

MÁRIO CELSO GENOVEZ

RESPONSIBLE CHEMIST
Químico, M.Sc. - CRQ IV 04234930