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  • Chem and Ionic Eq Synopsis

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    CHEM AND IONIC EQ SYNOPSIS (4)

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    10 views7 pages

    Chem and Ionic Eq Synopsis

    Uploaded by

    Fcd Cjll

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 7
    Chemical Equilibrium ——— ee OVERVIEW 5) aw of mass action: It was given by Guldbergand Waage. It j.atheoretical concept which states that the rate of reaction isretly proportional to the product of molar concentration sfreactants with each concentration term raised to the power qual othe stoichiometric coefficient of the species in the balanced equation. Equilibrium constant (K) It is the ratio of the velocity constants of forward reaction to that of backward reaction. Foran equilibrium: aA + BB === eC + dD chpy rer Stoichiometric representation of equilib: constant im constant | Chemical reaction A+sB==C+D .| CHD A+B |e fon a = C+D 2A+2B—> D i oe Equation (iii) is obtained by subtracting equation (ii) from equation () xX K L asp—oc aK i, 2A+23 4D a ii, 3A+3B—> C+D Ka? Equation (ii) is obtained by addition of equations (and Kak xk, 2 ace of jes are used in pl 4% In equilibrium constant, ifactivitis : igimensionless (i.e i molar concentrations, k becomes tp, tse unit) | Relationship between Kj» K,. and Ky {equilibrium constant in term of pressure) K,= KART)" and K, = Kp)" then K,=K.=K, ve; K,> Ka K,>K, An=-ve; — K, K,, the reaction will proceed in the direction reactants, + If

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