S-furnace ΔH rx = 487005700 kJ

2 CuFeS2 + 13/4 O2 = Cu2S + 1/2 FeS + 3/2 FeO

m 523 849.875 0 0 0
r 523 849.875 261.5 130.75 392.25
s 0 0 261.5 130.75 392.25

CaCO3 = CaO + CO2

m 17.5 0 0
r 17.5 17.5 17.5
s 0 17.5 17.5

2 FeS + 3 O2 + SiO2 = Fe2SiO4 + 2 SO2

m 130.75 196.125 65.375 0 0
r 130.75 196.125 65.375 65.375 130.75
s 0 0 0 65.375 130.75

2 FeO + SiO2 = Fe2SiO4

m 392.25 196.125 0
r 392.25 196.125 196.125
s 0 0 196.125

CaO + SiO2 = CaO.SiO2

m 17.5 17.5 0
r 17.5 17.5 17.5
s 0 0 17.5

Masuk Keluar
Komponen Ar
Mol Massa (kg) Mol
CuFeS2 183.5 523 95970.5 0
CaCO3 100 17.5 1750 0
SiO2 60 279 16740 0
O2 32 1046 33472 0
N2 28 3934.95238095238 110178.666666667 3934.95238095238
Cu2S 159 0 0 261.5
Fe2SiO4 204 0 0 261.5
CaO.SiO2 116 0 0 17.5
SO2 64 0 0 784.5
CO2 44 0 0 17.5
pengotor 235.4 3.1 729.74 3.1
TOTAL 258840.906666667
 CL - furnace

Masuk Keluar
Komponen Ar
Mol Massa (ton) Mol
Cu2S 159 261.5 41578.5 261.5
pengotor 235.4 3.1 729.74 3.1
Fe2SiO4 204 261.5 53346 261.5
CaO.SiO2 116 17.5 2030 17.5
TOTAL 97684.24

C - furnace

CaCO3 = CaO + CO2

m 20.83 0 0
r 20.83 20.83 20.83
s 0 20.83 20.83

ΔH rx = -128.97 kcal/mol
-18.97 0 -38.5 -70.94
Cu2S + 2 O2 = 2 CuO + SO2
m 3 6 0 0
r 3 6 6 3
s 0 0 6 3

Cu2S + O2 = 2 Cu + SO2
m 258.5 240.405 0 0
r 240.405 240.405 480.81 240.405
s 18.095 0 480.81 240.405

Masuk Keluar
Komponen Ar
Mol Massa (kg) Mol
Cu 63.5 3.75 238.125 484.56
CaCO3 100 20.83 2083 0
O2 32 246.405 7884.96 0
N2 28 926.952142857143 25954.66 926.952142857143
Cu2S 159 261.5 41578.5 18.095
CuO 79.5 0 0 6
FeO 72 0 0 0
CaO 56 0 0 20.83
SO2 64 0 0 243.405
CO2 44 0 0 20.83
pengotor 235.4 3.1 729.74 3.1
TOTAL 78468.985
 Anode furnace

Cu2S + O2 = 2 Cu + SO2
m 0.25 0.25 0 0
r 0.25 0.25 0.5 0.25
s 0 0 0.5 0.25

ΔH rx = -13.47 kcal/mol
-38.5 -18.97 0 -70.94
2 CuO + Cu2S = 4 Cu + SO2
m 6 3 0 0
r 6 3 12 3
s 0 0 12 3

Masuk Keluar
Komponen Ar
Mol Massa (kg) Mol
Cu 63.5 484.56 30769.56 497.06
O2 32 0.25 8 0
N2 28 0.94047619047619 26.3333333333333 0.94047619047619
Cu2S 159 3.25 516.75 0
CuO 79.5 6 477 0
SO2 64 0 0 3.25
pengotor 235.4 3.1 729.74 3.1
TOTAL 32527.3833333333
 + 5/2 SO2
0
653.75
653.75

persentaseCp
PbSO4 72.2 26.4 19.0608
SeO2 12.11 0 0
Se 3.81 8.35 0.318135
88.12 19.37894

Keluar persentaseBM
Massa (kg) PbSO4 72.2 303.26 218.9537
0 SeO2 12.11 110.96 13.43726
0 Se 3.81 78.96 3.008376
0 88.12 235.3994
0
110178.666666667
41578.5 persentaseΔH fusion
53346 PbSO4 72.2 9600 6931.2
2030 SeO2 12.11 0 0
50208 Se 3.81 0 0
770 88.12 6931.2
729.74
258840.906666667
Keluar
Massa (ton)
41578.5
729.74
53346
2030
97684.24

Perry's Tabel 178 hal. 186 - 194

mol fraksi %
Cu 480.81 0.974957 97.49574
CuO 6 0.012166 1.216644
Cu2S 3.25 0.00659 0.659015
lainya 3.1 0.006286 0.628599
TOTAL 493.16

Keluar
Massa (kg)
30769.56
0
0 14.845 2360.355
25954.66 5.25 834.75
2877.105
477
0
1166.48
15577.92
916.52
729.74
78468.985
Keluar
Massa (kg)
31563.31
0
26.3333333333333
0
0
208
729.74
32527.3833333333
 S-furnace ΔH rx = 487005700 kJ

2 CuFeS2 + 13/4 O2 = Cu2S + 1/2 FeS + 3/2 FeO

m 835 1356.875 0 0 0
r 835 1356.875 417.5 208.75 626.25
s 0 0 417.5 208.75 626.25

CaCO3 = CaO + CO2

m 26.5 0 0
r 26.5 26.5 26.5
s 0 26.5 26.5

2 FeS + 3 O2 + SiO2 = Fe2SiO4 + 2 SO2

m 208.75 313.125 104.375 0 0
r 208.75 313.125 104.375 104.375 208.75
s 0 0 0 104.375 208.75

2 FeO + SiO2 = Fe2SiO4

m 626.25 313.125 0
r 626.25 313.125 313.125
s 0 0 313.125

CaO + SiO2 = CaO.SiO2

m 26.5 26.5 0
r 26.5 26.5 26.5
s 0 0 26.5

Masuk Keluar
Komponen Ar
Mol Massa (ton) Mol
CuFeS2 183.5 835 153222.5 0
CaCO3 100 26.5 2650 0
SiO2 60 444 26640 0
O2 32 1670 53440 0
N2 28 6282.38095238095 175906.666666667 6282.38095238095
Cu2S 159 0 0 417.5
Fe2SiO4 204 0 0 417.5
CaO.SiO2 116 0 0 26.5
SO2 64 0 0 1252.5
CO2 44 0 0 26.5
pengotor 235.4 5 1177 5
TOTAL 413036.166666667
 CL - furnace

Masuk Keluar
Komponen Ar
Mol Massa (ton) Mol
Cu2S 159 417.5 66382.5 417.5
pengotor 235.4 5 1177 5
Fe2SiO4 204 417.5 85170 417.5
CaO.SiO2 116 26.5 3074 26.5
TOTAL 155803.5

C - furnace

CaCO3 = CaO + CO2

m 31.5 0 0
r 31.5 31.5 31.5
s 0 31.5 31.5

ΔH rx = -128.97 kcal/mol
-18.97 0 -38.5 -70.94
Cu2S + 2 O2 = 2 CuO + SO2
m 4.75 9.5 0 0
r 4.75 9.5 9.5 4.75
s 0 0 9.5 4.75

Cu2S + O2 = 2 Cu + SO2
m 412.75 383.8575 0 0
r 383.8575 383.8575 767.715 383.8575
s 28.8925 0 767.715 383.8575

Masuk Keluar
Komponen Ar
Mol Massa (kg) Mol
Cu 63.5 7.6472 485.5972 775.3622
CaCO3 100 31.5 3150 0
O2 32 393.3575 12587.44 0
N2 28 1479.77345238095 41433.6566666667 1479.77345238095
Cu2S 159 417.5 66382.5 28.8925
CuO 79.5 0 0 9.5
FeO 72 0 0 0
CaO 56 0 0 31.5
SO2 64 0 0 388.6075
CO2 44 0 0 31.5
pengotor 235.4 5 1177 5
TOTAL 125216.193866667
 Anode furnace

Cu2S + O2 = 2 Cu + SO2
m 0.5 0.5 0 0
r 0.5 0.5 1 0.5
s 0 0 1 0.5

ΔH rx = -13.47 kcal/mol
-38.5 -18.97 0 -70.94
2 CuO + Cu2S = 4 Cu + SO2
m 9.5 4.75 0 0
r 9.5 4.75 19 4.75
s 0 0 19 4.75

Masuk Keluar
Komponen Ar
Mol Massa (kg) Mol
Cu 63.5 775.3622 49235.4997 795.3622
O2 32 0.5 16 0
N2 28 1.88095238095238 52.6666666666667 1.88095238095238
Cu2S 159 5.25 834.75 0
CuO 79.5 9.5 755.25 0
SO2 64 0 0 5.25
pengotor 235.4 5 1177 5
TOTAL 52071.1663666667
 + 5/2 SO2
0
1043.75
1043.75

persentaseCp
PbSO4 72.2 26.4 19.0608
SeO2 12.11 0 0
Se 3.81 8.35 0.318135
88.12 19.37894

Keluar persentaseBM
Massa (ton) PbSO4 72.2 303.26 218.9537
0 SeO2 12.11 110.96 13.43726
0 Se 3.81 78.96 3.008376
0 88.12 235.3994
0
175906.666666667
66382.5 persentaseΔH fusion
85170 PbSO4 72.2 9600 6931.2
3074 SeO2 12.11 0 0
80160 Se 3.81 0 0
1166 88.12 6931.2
1177
413036.166666667
Keluar
Massa (ton)
66382.5
1177
85170
3074
155803.5

Perry's Tabel 178 hal. 186 - 194

mol fraksi %
Cu 767.715 0.97492 97.49195
CuO 9.5 0.012064 1.206403
Cu2S 5.25 0.006667 0.666696
lainya 5 0.006349 0.634949
TOTAL 787.465

Keluar
Massa (kg)
49235.4997
0
0 23.6425 3759.158
41433.6566666667 5.25 834.75
4593.9075
755.25
0
1764
24870.88
1386
1177
125216.193866667
Keluar
Massa (kg)
50505.4997
0
52.6666666666667
0
0
336
1177
52071.1663666667