t i LeGTURE 4.1 PROBLEMS LO) Weity the cel wactiny and detrdY hale mae ctiony nad calotlaty: thy odacd pytuabal op cache Af tie pallewing wily (A) Dao LEnspe Cag) HAGA DY (647 Layla nee at te oO tee ANE WR oe oY Sw EMT et tly [1 GCG) | acy Cag) HA Go) Leg) 1H) varias nt tw + hy ANODE ct be ad Ut rit» UM tte Ce) PED Ly Lev Comal ap, Kt CF CoAT cap B Cree Cg) ft) came: Or tay pot oh ANOS [re COATT by” rtte CENT UN) py WY yf rv (onde) tere abr con tbr edLECTURE 2-l PROBLEM 2 2) The starcond potanhal of o Dorie Cel, with wll yeaution Znl¢) * Ge oq) Ze" (aq) +Cal) Xe LDV at 25°C. Calloke eonccgendi dawdord wicion Gb Energy. 4.000! * @aew Case): Efe (8) + sO at ae 2 geting ce wathon® Za lt) 4+ CUM (aq) > 20 aq) + Gus) ‘Reguchion haf reaction 24 acted —> mee - Chdaton nak veation: 2 als) —> Ze (aq) + 2" © aces VEE! «2 (au485 S/mot) (+ u10v) 22 se (+1105)SCTURE oy The ston i ae Randard potential of the ct Agta] AFCA] ABT Ca) | AgG) ie t0.9504V ot 83%, eacatate Auilibrium conttant for ane dieeotution of AgTIs) Mop te ayer A9T6s) 47 wet T 89 ag) 12°" Gag) = WTO) Peat 40 x amy reas AL nk wr bot = VEE ed a 2 © (9 (ute )(roaman)( 2) (8.50 Soa) Catt ae) k= st.oIs keris" Kepee. (uit io") "4 42x10 (tert Sad nyt Caazsto"")Lectwee 2.2 ~ 4). The rove of bie _reataion A+ 20 —* 3 reported ot 2-1 mol din’? o'. dtate ene of ——{wiabion_ano_confumptionof tne parricopanct. At 2B—*GUtD j Roe oP tenction : 2.1 mol din *e" A+ Z2B-* Gt + D | Rose of Renctton * 1-14 RI®: Rates of z gonmuaupicon oP sarod FOUN OW afay Bote, of padi prio M Re > = A014 mpl amo") = aatimolaw =e 7 ated ae = 2B = 262Amo dino") = SA nol di t ; tte 7 Rate op contwimptvon |Foydtian C = = $0 = 8(1A moldm ss) = Synod ec) 2 = eg STE depyZ = Beaton Fate = WA moi dno!) <_ enya sac! Fake of contumpiion B= -LECTURE 22 PROBLEM 2 At 400 K, the rate of decomposition of a gaseous compound was 9.71 Pa s-1 when 10% had reacted and 7.67 Pa s-1 when 20% had reacted. Identify the order of the reaction. a Ve K CAI 107% ceacled: am = [90]? gor reacted: 7-61 « [g0]° gl), 3B) ( T4 (3 266 = Qe? wv ap 2 1-266 71-2669) Thar data blend erty thee sence bhi tort = butyl bromide Md ty pew tut betel md bgdn borne weld iv a Sul prere. Ldeatipy thy ender fy aie aed aleelate the rity ata and the malar uneaintiny tp burt bull br mide wemaining Aptir th tly 6 yy oth ants tC Cr eet dnt) Tal = wat GPU ee nett nai bert ty We COATED) peppy tenn pani -Lttet Lait [esr AEE ort pat + quid pit a 7 In OA) = fale - ket Te Ch] = 0055 = ryere At Hf tly pars Lie 9 erty peteLECTURE 2.2 PROBLEM 4 The rate constant of a chemical reaction is found to triple when the temperature is raised from 240C to 490C. Evaluate the activation energy. Ke T=20nisk 232215 K ARRHENIUS EQUATION Inke = INA - Eq we, RMT, Te I \ ina =e (aan - 35 Eq 34974 S/mol or 34°97 }[mo! auce , Ea (1-2)