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    Handbook of Preparative Inorganic Chemistry Brauer 2nd Ed Both Vols

    Uploaded by

    Laís Medeiros

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    of 1906
    HANDBOOK OF PREPARATIVE INORGANIC CHEMISTRY VOLUME 1 - SECOND EDITION Edited by GEORG BRAUER PROFESSOR OF INORGANIC CHEMISTRY UNIVERSITY OF FREIBURG TRANSLATED BY SCRIPTA TECHNICA, INC. TRANSLATION EDITOR REED F. RILEY ASSOCIATE PROFESSOR OF CHEMISTRY POLYTECHNIC INSTITUTE OF BROOKLYN 1963 @ ACADEMIC PRESS - New York + London CopyRIGHT © 1963 By ACADEMIC PRESS INC. ALL RIGHTS RESERVED NO PART OF THIS BOOK MAY BE REPRODUCED IN ANY FORM. BY PHOTOSTAT, MICROFILM, OR ANY OTHER MEANS, WITHOUT WRITTEN PERMISSION FROM THE PUBLISHERS. ACADEMIC PRESS INC. 111 FIFTH AVENUE New York 3, N. Y. United Kingdom Edition Published by ACADEMIC PRESS INC. (Lonpon) Lr. BERKELEY Square House, Lonpon W. 1 Library of Congress Catalog Card Number: 63-14307 Translated from the German HANDBUCH DER PRAPARATIVEN ANORGANISCHEN CHEMIE BD. 1, 884 pp., 1960 Published by FERDINAND ENKE VERLAG, STUTTGART PRINTED IN THE UNITED STATES OF AMERICA From the Preface to the First Edition For many years, the inorganic section of the “Handbook of Preparative Chemistry” by L. Vanino was a laboratory standard. By 1940, however, the third (and last) edition of the handbook was no longer in print. Rather than simply reissue the Vanino manual, the Ferdinand Enke Press projected a completely new book: in contrast to the old, the new work would be written by a number of inorganic chemists, each a specialist in the given field. As editor, the publishers were able to obtain the services of Prof. Robert Schwartz. It was Prof. Schwartz who laid down what was to be the fundamental guideline for all subsequent work: that only those procedures were to be included which had been tested and confirmed in laboratory practice. Concerning the choice of sub- stances, while not pretending to be exhaustive, the book would cover most of the compounds of inherent scientific interest or of importance for purposes of instruction. At the same time, it was clearly apparent that the common commercial chemicals, as well as those whose preparations require only the simplest chemical operations, need not be included, The organization of the work took account of the broad scope and varied nature of contemporary preparative inorganic chemistry. The increasingly rigorous purity requirements, the use of unstable substances and those sensitive to air and moisture, the employ- ment of ultralow and ultrahigh temperatures and pressures, etc., have increasingly complicated the experimental apparatus and techniques. Thus, in the introductory part (Preparative Methods) the authors have endeavored to assemble a number of experimental techniques and special apparatus that can be extended to applications much more general than the original purposes for which they were designed. This is complemented by an Index of Techniques at the end of the work, This index links the contents of Part I with the various experimental procedures distributed throughout the work, Space considerations have forced abridgments in several places. Thus, a literature reference must often take the place of a more detailed description, Occasionally, different researchers have solved a given problem by different experimental techniques, Here again a reference to the literature is in order. Naturally, the choice of preferred method is always a subjective decision of the individual experimenter, Thus, our own selection may not always seem correct or adequate to every inorganic chemist. As is customary, please forward any pertinent criticism to either the editor or publisher. It will be gratefully received, v vi PREFACE TO THE SECOND EDITION What has been said above also holds true for Part II (Elements and Compounds) and even more so for Part III (Special Groups of Substances). In every case the decision as to inclusion or omission was dictated by considerations of available space. Here, again, the editor would be grateful for any suggestions or criticisms. Preface to the Second Edition The first edition of the Handbook of Preparative Inorganic Chemistry was intended to fill a gap in the existing literature. Because it accomplished its mission so well, it has won wide respect and readership, Thus, the authors have been persuaded to issue a second, revised and enlarged edition, eventhough a relatively brief period has elapsed since the appearance of the first. The present edition is much more thana revision of the previous work, Several sections had to be completely rewritten; in a number of cases, the choice of compounds to be included has been changed; above all, recently developed processes, methods and apparatus could not be neglected, The reader will note also that several new authors have cooperated in this venture. Thus, we are presenting what is in many respects a com- pletely new work. Most of the preparative methods presented here have either been verified by repetition inthe author’s own laboratory or checked and rechecked in those of our collaborators. We trust that the reader will benefit from the improved reliability and reproducibility that this affords, The editorial work could not have been completed without the invaluable help of Dr. H, Barninghausen, Miss G. Boos, and my wife, Doris Brauer. Credit for the careful layout of the more than eighty new or revised drawings found in the book goes to Mrs, U. Sporkert. To all of my co-workers, advisers, colleagues and friends who have given their assistance, I wish to extend my heartfelt thanks, Freiburg, April 1960 G, Brauer Translation Editor's Preface The Handbook of Preparative Inorganic Chemistry byG. Brauer has been a valuable addition to the detailed preparative literature for some years largely because of the number and diversity of me- thods which are contained in its pages. The translation of this work, therefore, will simplify the task of synthesis for chemists whose German is less than proficient. Because laboratory practice, as outlined in Part I of the Hand- book, is in some ways different from laboratory practice in the United States a number of additions and omissions have been made in the translated text. These include: (1) the removal of the names of German suppliers and trade names and the substitution of Amer- ican trade names and suppliers, the latter only occasionally, (2) conversion of German glass and ground-glass joint sizes to their American equivalents, (3) substitution throughout the text of "liquid nitrogen" for "liquid air", (4) improvement in the nomenclature where it was judged unclear. In addition, certain brief sections have been omitted or rewritten when the practice or equipment de- scribed was outmoded or so different as to be inapplicable in the United States. It is hoped that these changes have been consistent and wise de- spite the diffusion of responsibility for the production of a book of this size. Reed F, Riley Brooklyn, New York August, 1963 Conversion of Concentration Units Det = density of solvent Den = density of solution Dse = density of solute Mgt = molecular weight of solvent Mse = molecular weight of solute Unit a b © d | eee g-/100 ml, 7 100 +c + Det [100 +d « Det = solvent [ bePst | TOs Dagjee | 100 pb] 8/400 g oot i 100+ 100-4 solvent Det (100+ Dyn | “100-4 g-/100 ml, 100+a*Dgy | 100+b-+D., i. solutic ae ad d+ Den oo“ (100 + Dy) ta | 100+» g-/100 g. solution 100+a 100+ b a a (wt, 96) (100+ Dy) tal T0OFb Dan a d e £ |g | 8+/100 g. solution 7 e+ Dee a (wt, 9%) ( ) 1+ Dee 100 + Dgp/Dee Iml. /100 ml, solution d=Dsn Peet e (vol. $6) > e i RK aoe f Ise sles/ 100 mol 200 | 100 moles/100 moles. = |——--; — 7 f | solution (mole %) ‘4 Mse (00-Dsn Me f 14 1+ > a Ms © Pre Mot mole fraction = moles of solute/ total moles =75 molality = moles of solute/1000 g. of solvent =10eb se molarity = moles of solute/1000 ml, of solution =10*¢ se Example: The concentration of a solution of sulfur in carbon disulfide (15°C, given Dg, = 1.35, Dgt=1.26, Dge = 2.07) is 24.0 g. $/100 ml. CSg or 19.05 g. S/100 g. CS, or 21.6 g. 8/100 ml. solution or 16.0 g. $/100 g. solution or 16.0 wt. % or 10.4 vol. % or 31.2 mole % viii Contents FROM THE PREFACE TO THE FIRST EDITION . v PREFACE TO THE SECOND EDITION... « . vi TRANSLATION EDITOR'S PREFACE sees ee eee ecco veces . vii CONVERSION OF CONCENTRATION UNITS, ee ee eee ere ee eeee Vili Part I Preparative Methods PREPARATIVE METHODS » eee ee ee Assembly of Apparatus... ee 4 Glas8... 26. eee eee eee oe 5 Ceramic Materials...... oe 12 Metals. . oe see o- 17 Plastics . eee eee ee seeee 25 Pure Solvents ........ . 25 Mercury, ...eeeeeeee . 27 Sealing Materials and Lubricants . . 28 High Temperatures .......... . 32 Low Temperatures,..... o . 42 Constant Temperature ........ 7 45 Temperature Measurement ..... . 49 High Vacuum and Exclusion of Air : 53 Special Vacuum Systems ....... . 66 Gases 2... eee eee eee eee eee . 7 Liquefied Gases as Solvent Media . 7 86 Electrical Discharges.... oe . 90 Purification of Substances . Par . 91 Analysis of Purity oe a 7 100 Powder Reactions ..... oe . 103 Part Il Elements and Compounds SECTION I. HYDROGEN, DEUTERIUM, WATER «++ e+e seoeee AM Hydrogen Hz... wee oe oe » 1 Pure Water..... soe eee o. . 117 Deuterium and Deuterium Compounds wee oe .- 119 Deuterium Dz... oe oe ee . 121 SECTION 2. HYDROGEN PEROXIDE .. SECTION 4. FLUORINE COMPOUNDS ...~ CONTENTS, Hydrogen Deuteride HD... Deuterium Fluoride DF... Deuterium Chloride DCl .. Deuterium Bromide DBr . Deuterium Iodide DI... Deuterium Sulfide D,S .. Deuterosulfuric Acid D3S0,. Deuteroammonia ND,........- Deuterophosphoric Acid D,PO,. Hydrogen Peroxide H,0,... SECTION 3. FLUORINE, HYDROGEN FLUORIDE Fluorine Fg ........--22+0-+- Hydrogen Fluoride HF ... General Remarks....... Chlorine Monofluoride CIF Chlorine Trifluoride CIF, .. Bromine Trifluoride BrF,. Bromine Pentafluoride BrF Iodine Pentafluoride IF, ..... Iodine Heptafluoride IF7 .. Dioxygen Difluoride OF, . Oxygen Difluoride OF, ... . Chlorine Dioxide Fluoride ClO,F Chlorine Trioxide Fluoride ClO,F Chlorine Tetroxide Fluoride ClO, F Sulfur Tetrafluoride SF,... Sulfur Hexafluoride SFg ..... Thionyl Fluoride SOF, ... Thionyl Tetrafluoride SOF, Sulfuryl Fluoride SO3F, .. Trisulfuryl Fluoride S,0,F, Thionyl Chloride Fluoride SOCIF Sulfuryl Chloride Fluoride SO,CIF Sulfuryl Bromide Fluoride SO,BrF Fluorosulfonic Acid HSO,F .... Potassium Fluorosulfinate KSO,F Selenium Hexafluoride SeF,... Selenium Tetrafluoride SeF, .. Tellurium Hexafluoride TeF, Nitrogen Trifluoride NF, .... Ammonium Fluoride NH4F .... Ammonium Hydrogen Fluoride NH: HF 126 127 129 131 134 135 137 138 140 140 143 143 145 150 150 153 155 156 158 159 160 162 163 165 166 167 168 169 170 171 173 174 174 175 176 177 178 179 180 180 181 183 183 CONTENTS, Nitrosyl Fluoride NOF ........ Nitrososulfuryl Fluoride FSO,NO . Nitryl Fluoride NO,F......... Fluorine Nitrate NO,F ........ Phosphorus (II) Fluoride PF, ... Phosphorus (V) Fluoride PF,.... Phosphorus Dichloride Fluoride PCl Phosphorus Dichloride Trifluoride PCIE Beeee Phosphorus Oxide Trifluoride POF, ....... Tetrachlorophosphonium Hexafluorophosphate (Vv) PClae PFa. eee eee ee ee eee eee ee eee Phosphonitrilic Fluorides (PNFa)g, (PNF 2) 4 Ammonium Hexafluorophosphate (V) NH4PF, . Ammonium Difluorophosphate (V) NH,PO2F, . Potassium Hexafluorophosphate (V) KPF, . Arsenic (III) Fluoride AsF,....... Arsenic (V) Fluoride AsF , Antimony (II) Fluoride SbF, . Antimony (V) Fluoride SbF , Antimony Dichloride Trifluoride SCF: . Bismuth (III) Fluoride BiF,... Bismuth (V) Fluoride BiF , . Carbon Tetrafluoride CF, . Trifluoromethane CHF, . . Trifluoroiodomethane CIF, .... Carbonyl Fluoride COF,..... Carbonyl Chlorofluoride COCIF Carbonyl Bromofluoride COBrF Carbonyl Iodofluoride COIF... Silicon Tetrafluoride SiF,. Trifluorosilane SiHF,.........4 Hexafluorosilicic Acid H,SiF, ..... Germanium Tetrafluoride GeF, .. Potassium Hexafluorogermanate Kg\ Tin (II) Fluoride SnF3... Tin (IV) Fluoride SnF,.. Lead (II) Fluoride PbF, .... Lead (IV) Fluoride PbF,. Boron Trifluoride BF, .. Fluoroboric Acid HBF 4. . Sodium Fluoroborate NaBF, . Potassium Fluoroborate KBF,. Potassium Hydroxyfluoroborate KBF , Nitrosyl Fluoroborate NOBF, ..... Aluminum Fluoride .......+.66 Ammonium Hexafluoroaluminate (NH) gAlFe . Ammonium Tetrafluoroaluminate NH ,AIF 4. . xi 184 186 186 187 189 190 191 192 193 193 194 195 196 196 197 198 199 200 200 201 202 203 204 205 206 208 210 211 212 214 214 215 216 217 217 218 219 219 221 222 223 223 224 225 226 227 xii CONTENTS Gallium (III) Fluoride GaFg.......02.e2ee0% Ammonium Hexafluorogallate eae eriee ee Indium (II) Fluoride NF, .......2006 Ammonium Hexafluoroindate (NH 4) (INF). . Thallium (1) Fluoride TIF ....... Thallium (III) Fluoride TIF, .... Beryllium Fluoride BeF, . Ammonium Tetrafluoroberyllate (NH) BeF - Magnesium Fluoride MgFgz ......-eee6 Calcium Fluoride CaF,... Strontium Fluoride SrF, . Barium Fluoride BaF, .. Lithium Fluoride LiF... Sodium Fluoride NaF .... Potassium Fluoride KF.. Potassium Hydrogen Fluori Potassium Tetrafluorobromate (III) KBrF ,. Potassium Hexafluoroiodate (V) KIF, ... Copper (II) Fluoride CuF, . Silver Subfluoride AgaF . Silver Fluoride AgF.... Silver (Il) Fluoride AgF,.. Zine Fluoride ZnFz .... Cadmium Fluoride CdF, . Mercury (I) Fluoride Hg,F3 Mercury (II) Fluoride HgF, Scandium Fluoride SeF, . Yttrium Fluoride YF,... Lanthanum Fluoride LaF, . Cerium (III) Fluoride CeF, Cerium (IV) Fluoride CeF Europium (1) Fluoride EuF, Titanium (III) Fluoride TiF, . Titanium (IV) Fluoride TiF, .. Zirconium (IV) Fluoride ZrF, . Vanadium (III) Fluoride VF, .. Vanadium (IV) Fluoride VF, . Vanadium (V) Fluoride VF 5 eee Niobium (V) Fluoride NbF, ..........- Potassium Heptafluoroniobate (V) K,NbF 7 Tantalum (V) Fluoride TaF, ......... Potassium Heptafluorotantalate (V) KzTaF. Chromium (II) Fluoride CrF,... Chromium (III) Fluoride CrF, .. Chromium (IV) Fluoride CrF, .. Chromyl Fluoride CrO;F3;..... Molybdenum (VI) Fluoride MoF,. 227 228 228 229 230 230 231 232 232 233 234 234 235 235 236 237 237 238 238 239 240 241 242 243 243 244 245 246 246 247 247 248 248 250 251 252 252 253 254 255 255 256 256 257 258 258 259 CONTENTS Tungsten (VI) Fluoride WF, pewter Uranium (IV) Fluoride UF 4 Uranium (VI) Fluoride UF, ry Manganese (II) Fluoride MnF, ... Manganese (III) Fluoride MnF,... Potassium Hexafluoromanganate (IV) KgMnF, Rhenium (VI) Fluoride ReF, ... Iron (Il) Fluoride FeF,.. Tron (III) Fluoride FeF, . Cobalt (Il) Fluoride CoF; Cobalt (III) Fluoride CoF, Nickel (II) Fluoride NiFg....... Potassium Hexafluoronickelate (IV) KNIFe Iridium (VI) Fluoride IrFg........0206 SECTION 5. CHLORINE, BROMINE, IODINE Chlorine Clg............. Chlorine Hydrate Cl, - 6 H30.. Bromine Brg.....-e+6- Bromine Hydrate Brg -8 H,O . HodinedIg--oetetsre-c eiorocets Hydrogen Chloride HCl. . Hydrogen Bromide HBr. . Hydrogen Iodide HI..... Ammonium Iodide NH4I. . Potassium Iodide KI... Iodine Monochloride IC] Iodine Monobromide IBr Iodine Trichloride IC1, .. Polyhalides Potassium Triiodide KI, + H,0.- oe Cesium Dichlorobromide CsBrCl, Potassium Dichloroiodide KICl,.. Cesium Dichloroiodide CsICl, ... Potassium Dibromoiodide KIBr,. . Cesium Dibromoiodide CsIBr,... Potassium Tetrachloroiodide KIC1, Tetrachloroiodic Acid HIC1, - 4 H, Dichlorine Oxide Cl,O ... oe Chlorine Dioxide ClO, .........- Dichlorine Hexoxide C130, Dichlorine Heptoxide C1,0, Bromine Oxides... Diiodine Pentoxide I,0, Hypochlorous Acid HC1O wae Sodium Hypochlorite NaClO - 5 HzO Sodium Hypobromite NaBrO - 5 H;O xiii 260 261 262 262 263 264 264 266 266 267 268 269 269 270 272 272 274 275 276 277 280 282 286 289 290 290 291 292 293 294 294 295 296 296 297 298 299 299 301 303 304 306 307 308 309 310 xiv CONTENTS: Potassium Hypobromite KBrO - 3 H,O Sodium Chlorite NaClO, * 3 Hg! Chloric Acid HClO, .........4. Ammonium Chlorate NH,Cl0, Barium Chlorate Ba(ClO,)3 - H,0. Bromic Acid HBrO,.......... Barium Bromate Ba(BrO,), + H,0 Todic Acid HIOg......-eeeee08 Perchloric Acid HC1O,........- Alkaline Earth Perchlorates .... Nitrosyl Perchlorate NOC1O, Nitryl Perchlorate NO,C10,4 Periodic Acid HgIOg....... Sodium Periodates Na,H,I0,, NalO,. eee Potassium Periodate KIO,... Barium Periodate Ba,H(IO¢)— Chlorine Nitrate CINO,..... Dipyridineiodine (I) Perchlorate (1(C tH.N).JCIO, a Bromine (III) Nitrate Br(NO,), ...... Iodine (Ill) Nitrate I(NO4)5 . + Iodine (III) Sulfate 1p(SO4)g 2... Iodine (III) Perchlorate I(C104),... Iodine (III) Iodate 1(10g), or 1405 .. Oxoiodine (III) Sulfate (I0),S0, - H3;0 Diiodine Tetroxide IO + IO, or Ig04.. SECTION 6. OXYGEN, OZONE Oxygen Og ...... Ozone Og ....-2. SECTION 7. SULFUR, SELENIUM, TELLURIUM , SulfurS ......... Hydrogen Sulfide H,S Crude Sulfane H,S, Pure Sulfanes .... see Ammonium Hydrogen Sulfide NH,HS Sodium Hydrogen Sulfide NaHS.... Sodium Sulfide NaS ...... Potassium Sulfide KS .... Sodium Disulfide NagSg.... Potassium Disulfide KS; .. Potassium Trisulfide K3S, Sodium Tetrasulfide NaS, ... Potassium Tetrasulfide KS, Sodium Pentasulfide NaS. Potassium Pentasulfide KS, Potassium Hexasulfide K,S, CONTENTS, Ammonium Pentasulfide (NH4)25,. Dichloromonosulfane SClz...... Dichlorodisulfane S,Cl, . wee Dichlorotri-, -tetra-, -penta- shexa-, ~hepta- and cocta~ sulfane SgClg, S4Clg, SgClg, SgClg, S7Clg, SaClg ...- Dichlorotrisulfane S,Cl, . Dichlorotetrasulfane S,Cl, Sulfur Tetrachloride SCl4 Dibromodisulfane S,Br, . Dibromotri-,-tetra-, -penta-, ~hexa-, “hepta~ and ~octa- sulfane S,Br,, S,Bra, S,Brg, SgBrg, SyBrg, SgBrg... Lower Sulfur Oxides S,0, SO. Disulfur Trioxide $,0,... Polysulfur Peroxide (SOg_ 4x. - Thionyl Chloride SOC1,.. Sulfuryl Chloride SO,Cl,.. Chlorosulfonic Acid HSO,Cl. . . Pyrosulfuryl Chloride $30,Clz... Thionyl Bromide SOBr,........ Peroxymonosulfuric Acid HgSO,. . Peroxydisulfuric Acid H,S,0, .. Ammonium Peroxydisulfate (NH 4)35,0, Potassium Peroxydisulfate K,S,0, .. Cobalt Sulfoxylate CoSO,+3H,O... Sodium Dithionite Na,S,0,+ 2 H,O Zinc Dithionite ZnS30,......... Sodium Dithionate Na,$,0, - 2 H,0. Barium Dithionate BaS,O, - 2H3;0. Potassium Trithionate KgS,0,.... Potassium Tetrathionate KzS 40,4... Potassium Pentathionate K,S,0, - 1.! Potassium Hexathionate K,S,0, . . Wackenroder Liquid.......... Polythionic Acids HS,03, HaS,0, ..... Nitrosyl Hydrogen Sulfate (NO)HSO,.... Tetrasulfur Tetranitride S4N,........ Tetrasulfur Dinitride S.Ng ..... Disulfur Dinitride S,Ng........ Sulfur Nitride Tetrahydride S,{NH) 4 . Heptasulfur Imide SyNH........6 q-Sulfanuric Chloride [OS(N)CI], ...... Trisulfur Dinitrogen Dioxide $,N,0,.... Trisulfur Dinitrogen Pentoxide S,NgO. . Selenium Se........... Hydrogen Selenide H,Se. . . Sodium Hydrogen Selenide NaHSe ....... Sodium Selenide, Potassium Selenide Na,Se, K,Se 5 Hy 369 370 371 372 373 375 376 377 379 379 380 382 382 383 385 386 387 388 389 390 392 393 393 394 395 397 398 399 401 403 405 405 406 406 408 409 411 411 412 413 414 415 418 419 421 xvi SECTION 8. NITROGEN... CONTENTS Sodium Diselenide Na2Sez..... Diselenium Dichloride Se,Clz Selenium Tetrachloride SeCly . Hexachloroselenium Salts .... Diselenium Dibromide SezBr2 . Selenium Tetrabromide SeBr 4 . Selenium Dioxide SeOz .... Selenium Oxychloride SeOCl2. Selenous Acid (anhydrous) H2SeQs. . Sodium Selenite Na2SeO,-5 H20.. Selenic Acid HaSeO 4. Sodium Selenate NazSeO4 Sodium Selenopentathionate Na 2SeS Os . “3 H,0 Selenium Sulfur Trioxide SeSO,.... Selenium Nitride Se .N4.... : Tellurium Te, Colloidal Tellurium Solution. Hydrogen Telluride HzTe ... Sodium Telluride, PotassiumTelluride NagTe, K. Sodium Ditelluride NagTea. Tellurium Tetrachloride TeCly, Hexachlorotellurium Salts... Tellurium Tetrabromide TeBr 4 . Tellurium Tetraiodide Tel,.... Tellurium Dioxide TeOz ... Tellurous Acid HzTeO,... Sodium Tellurite NazTeO3. Tellurium Trioxide TeO, . Telluric Acid HgTeOg Sodium Tetrahydrogentellurate (vp ‘NaH {Tedg, Sodium Orthotellurate NagTeOg ..-.. sees Sodium Telluropentathionate NazgTeS ,O,-2H20.. Tellurium Sulfur Trioxide TeSO, .........-.-- Nitrogen Nz ..... . Ammonia NH3.... . Lithium Amide LiNH,.... Lithium Imide Li,NH .. Sodium Amide NaNH2... Hydrazinium Sulfate NgHgSO,4..- Hydrazine Hydrate N2H «> H, Hydrazine NgH4..... Hydrazoic Acid HNg Azides........6 oe Chlorine Azide CIN,...... 421 422 423 425 426 427 428 429 430 431 432 433 434 435 435 437 438 438 441 442 442 444 445 447 447 449 449 450 451 453 453 454 455 457 457 460 463 464 465 468 469 469 472 474 416 CONTENTS Monochloramine CINHg... Nitrogen Trichloride NCl,. Nitrogen Triiodide and Tribromide, Monobromamine Thionyl Imide SONH .... 2... eee eee reece ene Sulfamide SO(NHa)2 -.- +2 see e eee eee eee Trisulfimide and Its Silver Salt (SOgNH) (SOgN) 3483 * 3H20 Nitrous Oxide N20. . Nitric Oxide NO.... . Nitrogen Trioxide NOs. . . Nitrogen Dioxide NOz, N2O4... Nitrogen Pentoxide N2Og. . Nitric Acid HNO3...... Hyponitrous Acid HzN202 Silver Hyponitrite Ag2N202 Sodium Hyponitrite NagN2O2 - 9H20 Nitramide NHzNO2g......2.-008 Hydroxylammonium Chloride (NH gOH)C1 Hydroxylammonium Salts.......... Hydroxylamine NH20H .......2.65 Potassium Hydroxylamine Disulfonate HON(SO3K)2.--- 2-2-2 eeeeeeeeee Potassium Dinitrososulfite K2S0, * (NO)2. Potassium Nitrosodisulfonate ON(SO 3K) 3. Potassium Nitrilosulfonate N(SO 3K) g - 2 H20. Potassium Imidosulfonate HN(SO3K)2..... Potassium Amidosulfonate HzgNSOsK..... Potassium Chloroimidosulfonate C1N(SO 5K) a. Amidosulfonic acid H2NSO,H.........- Potassium Hydrazinedisulfonate H2Ng(SO3K) 2. Potassium Azodisulfonate Ng(SO3K)2.......- Hydroxylamineisomonosulfonic Acid NH;SO4 . Nitrosyl Chloride NOC]... Nitrosyl Bromide NOBr. . Nitryl Chloride NO,Cl. . . Sodium Nitrosyl NaNO... Sodium Nitroxylate NagNO2 Sodium Hyponitrate NazN2O,.. SECTION 9. PHOSPHORUS ..... White Phosphorus P,... Red Phosphorus.......+ Black Phosphorus.......... Colloidal Phosphorus .... eeee Phogphine and Diphosphine PHs P2H, Sodium Dihydrogenphosphide NaPH, .. Phosphonium Iodide PH ......-.. xvii 4TT 479 480 480 482 + 483 484 485 487 488 489 491 492 493 495 496 498 500 501 503 504 504 506 506 507 508 508 509 510 510 511 513 513 514 515 517 518 518 519 522 524 525 530 531 CONTENTS Thiophosphoryl Chloride PSClg...... Phosphoryl (V) Bromide POBr; .... Thiophosphoryl (V) Bromide PSBr,. Diphosphoric Acid Tetrachloride P,0,Cl, . Diphosphorus Tetraiodide Pal ,. Phosphorus (II) Iodide PI... Phosphorus (V) Oxide P305 (P

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