Here is the order of when the MCU movies were released:

1. Iron Man
2. The Incredible Hulk
3. Iron Man 2
4. Thor
5. Captain America: The First Avenger
6. The Avengers / Avengers Assemble
7. Iron Man 3
8. Thor: The Dark World
9. Captain America: The Winter Soldier
10. Guardians of the Galaxy
11. Avengers: Age of Ultron
12. Ant-Man
13. Captain America: Civil War
14. Doctor Strange
15. Guardians of the Galaxy Vol. 2
16. Spider-Man: Homecoming
17. Thor: Ragnarok
18. Black Panther
19. Avengers: Infinity War
20. Ant-Man and the Wasp
21. Captain Marvel
22. Avengers: Endgame
23. Spider-Man: Far From Home