Professional Documents
Culture Documents
The Ministry of Science and Higher Education of The Russian Federation
The Ministry of Science and Higher Education of The Russian Federation
TRAINING REPORT
2
Content
Introduction...................................................................................................................4
1 Measurement of radioactive waste.............................................................................5
1.1 Methods for measuring radioactive waste...............................................................5
1.2 Elemental composition of spent nuclear fuel..........................................................7
1.3 Interaction of gamma radiation with matter............................................................8
2 Regulatory and legal support for the management of radioactive waste and radiation
safety rules...................................................................................................................13
2.1 Classification of radioactive waste........................................................................13
2.2 Legal support in the management of radioactive waste........................................14
2.3 Ensuring radiation safety.......................................................................................16
3 Radiation survey of liquid radioactive waste storage...............................................19
3.1 Theoretical justification of the project..................................................................19
3.2 Calculation of the power of the radiation source...................................................20
Conclusion...................................................................................................................24
References...................................................................................................................25
3
APPROVED BY
Director of Programme
“Nuclear Science and Technology”
______ Dr. Vera Verkhoturova
«___»_________2021
4
Introduction
5
1 Measurement of radioactive waste
1.1 Methods for measuring radioactive waste
6
measurement geometry templates used in waste characterization are cylindrical
vessels (tanks, barrels) and rectangular objects (boxes, crates, containers) made of
various materials.
The accuracy control when measuring small-volume objects is as follows.
Create certified objects in the form of a small package (cylindrical vessel, box,
canister), filled with a material close in density to the object under study. The
material inside the vessel is impregnated with a solution prepared on the basis of a
sample radionuclide solution. To control the accuracy over a wide range of energies,
it is recommended to use the following set: Am 241 (59 кэВ), Cs137 (662 кэВ), Co60
(1173 и 1332 кэВ).
The accuracy control is considered successful if for each radionuclide in the
certified object, the modulus of the difference between the measured and passport
activity values does not exceed the square root of the sum of the squares of the
statistical uncertainty of the measurement and the statistical error of the activity.
When measuring large-volume packages, computational methods are used to
calibrate the spectrometer based on the efficiency of recording gamma rays of
different energies. The methods used in the software are based on the integration of
the response functions (specific activity) from a "point" source (part of the object
under study) over the volume of the object under study. In this case, the algorithm for
calculating the registration efficiency takes into account the absorption of gamma
rays by the source material and the packaging wall material, as well as the source-
detector distance and the location of the detector relative to the source [2].
Non-destructive gamma-ray spectrometry is used to quickly determine the
radiation characteristics of waste. The limitation of this method is the inability to
measure the complex detectable radionuclides present in the waste (for example, C 14,
Cl36, Ni63, Sr90, U238, Pu241). Gamma radiation emitted during the decay of complex-
detectable radionuclides is either absent or does not have sufficient intensity or
energy to be detected by gamma-ray spectrometry. To solve the problem of rapid
determination of the content of complex detectable radionuclides in waste (for
example, isotopes of uranium and plutonium), a method of liquid-scintillation
7
spectrometry is proposed, which allows rapid analysis of complex detectable
radionuclides by the "screening" method without complete radiochemical isolation of
radionuclides in the preparation of a counting sample.
Spent nuclear fuel is uranium that has worked in a nuclear reactor and
contains radioactive fission products. In most countries, nuclear fuel that has spent its
due time in a nuclear power plant reactor is considered radioactive waste and is sent
to burial grounds or exported abroad. Russia and several other nuclear powers
(including France, England, and India) are developing technologies for processing
irradiated fuel and are striving to completely close the fuel cycle in the future [3].
The composition of spent nuclear fuel is shown in table 1.
Table 1 – Radionuclides determining the activity of SNF
Time interval, year Defining radionuclides
Up to100 Fe55, Co58, Ni59, Sr90, Ru106, Sb125, Cs137, Ce144, Pm147
100-1000 Sm151, Co60, Cs137, Ni59
1000-10000 Pu239, Am241
104-105 Np237, Pu239, Am243, Ni59, Zr93
Above 105 I129, Tc99, Pu239
8
Gamma radiation, which is of interest for nondestructive analysis, is in the
energy range from 10 to 2000 keV and interacts with detectors and absorbers through
three main processes: photoelectric absorption, Compton scattering, and pair
formation.
A gamma-ray quantum can interact with the bound electron of an atom in
such a way that it loses all its energy and ceases to exist as a gamma-ray quantum, as
shown in Figure 1. Some of the energy of the gamma-ray quantum is used to
overcome the binding energy of the electron, and most of the remaining energy is
transferred to the released electron as kinetic energy. A very small part of the recoil
energy remains in the atom to preserve momentum. This process is called
photoelectric absorption. Photoelectric absorption is an important process for
detecting gamma radiation, because the gamma-ray quantum gives up all its energy,
and the resulting pulse falls into the peak of total absorption [4].
The probability of photoelectric absorption depends on the gamma-ray
energy, the binding energy of the electron, and the atomic number of the atom. This
probability is greater the greater the bond between the electron and the atom.
Therefore, K-electrons are most susceptible to the photoelectric effect, provided that
the energy of the gamma quantum exceeds the binding energy of the K-electron.
Photoelectric absorption is the predominant interaction process for low-energy
gamma quanta, X-ray quanta, and Bremsstrahlung. The energy of the photoelectron
released during the interaction is the difference between the energy of the gamma-ray
quantum and the binding energy of the electron.
9
Figure 1 – Photoelectric absorption
In most detectors, the photoelectron quickly stops in the active volume of the
detector, which produces a small output pulse with an amplitude proportional to the
energy lost by the photoelectron. The binding energy of the electron is not lost, but
manifests itself in the form of characteristic X-ray radiation emitted simultaneously
with the photoelectron. In most cases, these X-ray quanta are absorbed in the detector
simultaneously with the photoelectron, and the resulting output pulse is proportional
to the total energy of the incident gamma-ray quantum. When low-energy gamma
rays are detected by small detectors, a significant number of K-series X-ray quanta
can leave the detector, which leads to the presence of leakage peaks in the observed
spectrum. The energy of the leakage peaks is less than the energy of the total
absorption peak by an amount equal to the energy of the X-ray quantum.
Compton scattering is an elastic collision process in which a gamma-ray
quantum interacts with a free or weakly bound electron and transfers some of its
energy to the electron. According to the laws of conservation of energy and
momentum, an electron weakly bound to an atom can receive only a fraction of the
energy of the gamma quantum, and the gamma quantum does not disappear in the
Compton interaction, which involves the outer, least bound electrons of the scattering
atom. The electron becomes a free electron with a kinetic energy equal to the
difference between the energy lost by the gamma quantum and the binding energy of
the electron. Since the binding energy of the electron is very small compared to the
10
energy of the gamma quanta, the kinetic energy of the electron is very close to the
energy lost by the gamma quantum. The process is shown in Figure 2.
11
minimum energy required for the formation of an electron and a positron. If the
energy of the gamma-ray quantum exceeds 1.022 MeV, the excess energy is divided
between the electron and the positron in the form of their kinetic energy. This
interaction process is not essential for the analysis of nuclear materials, since the
values of the most important characteristic energies of gamma radiation are below
1.022 MeV. The process is shown in Figure 3.
12
2186 keV of the fission product Pr144. The gamma-ray spectrum of Pr144 contains
peaks of single and double leaks, which occur as a result of the formation of pairs in a
germanium detector by a gamma quantum with an energy of 2186 keV.
The probability of pair formation varies approximately as the square of the
atomic number Z and becomes significant for elements with a high Z, such as lead or
uranium [4].
13
2 Regulatory and legal support for the management of radioactive waste
and radiation safety rules
2.1 Classification of radioactive waste
According to the Russian "Law on the Use of Atomic Energy", radioactive waste
is nuclear materials and radioactive substances, the further use of which is not
provided for.
Federal Law No. 190 classifies RW as removable and special. Disposed
radioactive waste – radioactive waste for which the risks associated with radiation
exposure, other risks, as well as the costs associated with the extraction of such
radioactive waste from the storage point of radioactive waste, their subsequent
handling, including disposal, do not exceed the risks and costs associated with the
disposal of such radioactive waste at their location. Special radioactive waste –
radioactive waste for which the risks associated with radiation exposure, other risks,
as well as the costs associated with the extraction of such radioactive waste from the
storage point of radioactive waste, their subsequent handling, including disposal [1].
The disposal of radioactive waste for disposal purposes is classified according to
the following criteria, as shown in Figure 4.
Figure 4 – Classification of RW
14
2.2 Legal support in the management of radioactive waste
15
permissible to bury the disposed RW belonging to classes 3, 4 and 6, and in the deep
burial sites, the disposal of RW classes 1 and 2 is carried out.
The safety of disposal sites should be ensured through the consistent
implementation of the concept of deep-layered protection, based on the use of a
system of physical barriers to the spread of ionizing radiation and radioactive
substances into the environment. Engineering safety barriers include RW packaging,
its individual elements, engineering structures of the disposal site, construction
structures of structures, buffer materials, covering screens. Natural barriers include
elements of a natural geological formation, bearing and enclosing rocks.
The system of state accounting and control of radioactive substances and RW
is designed to determine the available quantity, a differentiated approach to
determining the procedures for accounting and control of disposed RW, taking into
account their classification.
The accounting units are: the total amount of RW, mass, volume, physical
properties and radionuclide composition of which are determined on the basis of a
single set of data and measurement results, located in a sealed container; a preserved
RW storage facility; a section of radiation-contaminated territory.
The main principles of accounting and control of RAO are:
– continuity of accounting and control;
– frequency of inventory surveys;
– determination of the cash quantity and verification of its compliance with
the accounting data;
– timely documentation of the results of operations;
– a differentiated approach to the definition of accounting and control
procedures for disposed RW, taking into account their classification.
Accounting and control of RW should be supported by the implementation of
organizational and technical measures, such as limiting the number of persons
allowed to work with RW, restricting access to RW storage sites and using access
control tools. Seals should be installed on containers, safes, where RW is located, as
well as in places of access to this equipment.
16
When transferring RW, registration is carried out after the input control.
Entrance control when receiving RW should include an external inspection of RW
accounting units and verification of attribute attributes: the presence of accounting
units; compliance of the number and type of accounting units and their identifiers
with accounting data; integrity of accounting units; compliance of numbers and types
of seals with accounting data. The entrance control includes checking the actual
presence of RW.
18
The system for handling liquid and solid radioactive waste includes its
collection, sorting, packaging, temporary storage, conditioning (concentration,
curing, pressing, incineration), transportation, long-term storage and (or) disposal.
Transportation of radioactive waste should be carried out in mechanically
strong sealed packages on specially equipped vehicles [8].
The choice of disposal sites for radioactive waste should be made taking into
account hydrogeological, geomorphological, tectonic and seismic conditions. At the
same time, radiation safety of the population and the environment should be ensured
during the entire period of waste isolation, taking into account the long-term forecast.
The main dose limits are set out in Table 2.
Table 2 – Main dose limits
Normalized values Dose limits
personnel (Group A) population
Effective dose 20 mSv per year on average 1 mSv per year on
for any consecutive 5 years, average for any
but no more than 50 mSv consecutive 5 years, but
per year no more than 5 mSv per
year
Equivalent dose per
year in:
the lens of the eye; 150 mSv 15 mSv
skin; 500 mSv 50 mSv
hands and feet. 500 mSv 50 mSv
The annual effective dose of personnel exposure due to the normal operation
of man-made sources of ionizing radiation should not exceed the dose limits set out
in Table 2.
The annual effective dose is the sum of the effective dose of external radiation
received in a calendar year and the expected effective dose of internal radiation due
to the ingestion of radionuclides in the same year.
19
3 Radiation survey of liquid radioactive waste storage
3.1 Theoretical justification of the project
20
or autonomous unmanned mobile vehicle, an automated workplace for the operator of
the hardware complex, and specialized software [9].
Advantages of the project:
– safety: no impact of radiation fields on personnel due to their significant
distance from the object of inspection;
– speed: a significant reduction in the time spent on the survey of a single
LRW storage pool, compared to existing technologies;
– cost-effectiveness: a significant reduction in the amount of costs for the
survey of a single LW storage pool;
– all-weather: the ability to operate the complex in all weather conditions
during the open water period;
– simplicity: the software and hardware design makes it easy to operate the
complex by one person;
– multi-functionality: the ability to simultaneously use different types of
payload on an unmanned mobile vehicle;
– autonomy: the ability to operate the complex both in fully automatic mode
and automatically under the control of the operator;
– variability: the possibility for the operator to determine the program for
conducting a radiation survey of the pool-storage of radioactive waste.
W W 0 e x , (1)
where W 0 , W – radiation power before and after passing through the substance
layer, respectively,
21
µ – linear attenuation coefficient, depending on the nature of the absorbing
substance and the photon energy of the incident radiation,
x – thickness of the substance layer.
m i mi i
, (2)
W W 0 e m x (3)
Formula 3 is used if the radiation source is a point source. If the distance from
the radiation source to the detector is much greater than the size of the source, then
the source will be a point.
In another case, you can use the following formulas. Since the power is
measured in J/s and the absorbed dose in J/kg, the ratio 4 can be derived.
W D m
t , (4)
22
D (1 g ) K , (5)
where D – absorbed dose;
K – kerma.
In this paper, we can measure the energy of gamma rays from Cs 137 (661keV),
then g is less than 0.01 and the equality 6 is valid.
DK (6)
It is assumed that the radiation source is in the form of a disk, then formula 7
is used.
d a
2 2
D AS Г Ln 2
d , (7)
23
10 2
2 2
D 10.4 10 21.33 10 Ln 27.33 10 8
10 18
2
10
W 27.33 10 8
W0 m x
0.090810
67.76 10 8W
e e
As can be seen from the formulas, the power of the source at the bottom
exceeds the measured power, therefore, when passing through the water layer, the
power decreases. Also, when the water density increases due to impurities, the power
of the source decreases even more.
24
Conclusion
In the course of the work done, the main laws and regulations in the field of
safe management of radioactive waste, the main standards of radiation safety for
personnel and the public were considered. The main methods of measuring
radioactive waste are also studied, and the types of interaction of gamma radiation
with matter are considered. Based on the legal documentation, radioactive waste is
classified by activity, half-life, and aggregate state.
Rosatom is developing a project to measure radioactive waste in wet storage
facilities using unmanned means. This project will help to minimize the interaction of
personnel with radioactive waste. In the course of this work, formulas were derived
for determining the power of a point radiation source at the bottom of the storage, as
well as for a source with a disk geometry.
25
References
1. On the management of radioactive waste: Federal Law No. 190 of July
29, 2011 [Electronic resource]: Access from the legal system "ConsultantPlus".
2. Processing, conditioning and transportation of raw
materialsГоскорпорация [Electronic resource] – Access mode: http://www.radwaste-
journal.ru/docs/journals/24/07imethods_for_measuring_the_radiation_characteristics
_of_waste.pdf – Title from the screen. – (Accessed 02.06.2021).
3. ELEMENTAL AND ISOTOPIC COMPOSITION OF SNF [Electronic
resource] – Access mode: https:// doc134078372_603325189 – Title from the screen.
– (Accessed 10.06.2021).
4. Nature of gamma radiation [Electronic resource] – Access mode: https://
glava1-14.pdf – Title from the screen. – (Accessed 12.06.2021).
5. Methods and instruments for measuring nuclear and other radioactive
material / Boyko, Silaev – Moscow, 2011. – 356p.
6. Basic rules for accounting and control of radioactive substances and
radioactive waste in an organization [Electronic resource]: Access from the legal
system "ConsultantPlus".
7. Basic Sanitary Rules for Ensuring Radiation Safety (OSPORB 99/2010)
[Electronic resource]: Access from the legal system "ConsultantPlus".
8. Radiation safety standard (NRB 99/2009) [Electronic resource]: Access
from the legal system "ConsultantPlus".
9. State Corporation «Rosatom» [Electronic resource] – Mode of access:
https://www.rosatom.ru/about/ – Screen title. – (Date of access: 16.06.2021).
26