INTERNATIONAL STANDARD Soil quality — Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography 70 dos hycrocarburos de Crea Cxo par sso sera Z00K6)180 16703:2004(€) Contents Page Foreword — w 1 scope. : 1 2 Normative reforences 1 3 Terms and definitions nee . 2 4 ntorforance ons 2 5 Princip. 2 6 Reagents nn 2 87 ydrocarton standard solution for calibration oa 3 88 Controlsolution amas 83 Systempertormance siandard solution a mm} 7 Apparatus oo se 3 8 Sampling, sample conservation and prot os ‘ 2 Procedure. =—— z : 6 84 Preparation of the clean-up column 5 82 Blank Seater = 5 93 Extaciion and cleanup - 2 2 ms 84 Determination by gas chromatography a) 85 Quality controle nnn — : 7 7 40 Precision 11 Testreport sn a 8 ‘Annox A (informative) Examples of gas chromatograms of mineral il hydrocarbon slandard ‘oil samples, » ‘Annex B (informative) Detormination ofthe boiling range of mineral el hydrocarbons from the ia chromatograms. 16eee INTERNATIONAL STANDARD 180 16703:2003(6) Soil quality — Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography 4 Scope “Tis International Standard specifies a moths fr the quantiatie determination ef he mineral ol inyarocarbon content a fai-molst eol samples by gos chvomslosranry “The methods applicable to mineral ol contents (mass fection) Batwosn 109 mg and 10 000 arg sol fxgraseeg ae oy matter and can be azaptod tolowe” mis cf desecton “This International Stonéard i apeabe tote coterminaton of at nysiacarbors wth a olirgrarge o! 75-6 0.525, of mahanas from Cites to Gusti, of scakanes, cycoslianes,akybenzares. hyinapnthalonss and polyyete aromatic compounds, provided Tha trey ve rol absorbed on the specified ‘olor during the clean-up procedure, “This International Standard ls nat apaeabe to the quantiaive determination of hydrocarbons < Cio siginatng Fem gasclines. (nthe bass of he peak pattern ofthe gas chromatogram obtanee, ard fhe boling ports oft ini PakanesIstod n Auras 8 the appronmate bolng range o tre mineral land some avast information ‘ihe cornacaion the contamination can Bo oba%03 2. Normative references “The folowing reterenced documents ave naspensabe for he application ofthis daciment. For dated Tetecences. ey the edtion cted ppp. For undated roaroncse, te ates ection ef he veforences {Soeoment inckiing any amernsments) apres 2 180 £406-1:1990, Water quality — Cateration anes evaluation of anaitical mtods and estimation of povormonce choratersies—~ Par 1: Statistical evouaton of te near caoration fancion $0 102811, Soil qually — Samalng — Par 1 Guidance on tre desian of sampling programmes 150 11488-1908, So quality — Determination of ry mattor ana water cantont av a mass basis — Gravineinie 150 14807, Sol quatiy — Proreutmentof samples for determinotion of ergane contominants (2150204 Attra 1180 16703:2004(€) 3 Terms and definitions For the purposes ofthis document. the falloning terms and detintions py a4 inydrocarbon content Iu gas ehvematopraphy) sum of compounds extractate with acetoneineptane(2+1) that do not adscrb on 2 Frsiiycoloris and ean be chromstegrephed ona non-polar copary column wit etenion mes betweon those of mdocane (cists) and totacentane [CwHe2) noTESutetancos tat comply wth ths dein ae may lng-han or brand alight, ays. lover Povey or mayest aroma yaocatons 4 Interferences ‘Non-polar and weakly polar compounds e.g, halogenated hyeroearbons) and righ contents of pole ‘Compounds may interfere wih te determination 5 Principle ‘Aknown amourt ofthe homogenize so! sample is extractod by mocharical shaking cr sonication wth Sostonolenoptane. The ergariclayr fs separated and washed trea wth water Poof compouncs are Femoved by adsorption on Flor An aqui of he purified extrac analysed by eaplary 905 ‘Gromatograpny wih lame onzaton detecton The ictal peak araa the range dei iedby ihe standards (Robrane and matracantane s measured. end the amour of hycrecarbor' inthe sargles varies ‘gains an external Standars consisting ef eaval amounts of two ctferent types of mncal ol Inetead of heptane, another non-polar slvent e 9. petoieum ether, eyconexane, hexane) may be used, rower ts sufabity foc the extraction of hydrocarbons fam so shall be proven. [gevolume nacton or concent tne tna tact 6 Reagents In general el eagents shall be reagent grade and sulle fr thir sponte purposes, G4 Acetone, (CHs}00, 62 mHeptane, Crs 63 Florisi for proparation of clean-up column, particle Sze 150 yn to 250 um (60-mesh to 109 mesh). heatea for atleast 16h at 140“C and stores n'a desicator over a molecular save Jae carsidges contin 2g of Flas and 2g of sadum sultan also agpcadia. {64 Anhydrous sodium sulfate (NazSO2), nested frat east 2 at $60 °C 6.5 Test solution of teary stearate (C2sH7202), 1) Fors ia vate name fora proper distemaceous substance mat cnsiing of anys magnesium sist Bhanu taste rat na cory nan eno cowie ws180 16703:2004(€) Dissolve about 100 mg of moctadecanoic acd actadecyl este in 100 ml octane (62), 66 Retention-time window (RTW) standard solution, containing mfetiacantane an w.cecane Rotomton-ime window (ATW) standard auton is the range-dfining standard solution, sigh (20+ 1) eng of Imtetracentano inte a 1 volumate ack, siazowo complstelyn an appropriate vslume of meptane (62), oa S50 pet nlocane about 21 mg). mix wl fil upto voluma win nhoptano ar romogentsa, This colton shal be Useafor all elution stops af he hydrocarbon standava (6), Store atroom tomparaur, NoTEn,Taracntae i nly madoratlyeoule in heptane. Sight warming anor smcation aces the Sesion proces 187 Hydrocarbon standard solution for eaibration, ‘Moc approximately equal masses of wo aiferent types of mineral ci Waigh accurately hs mitre and {ssoWe in the FTW standard solution (66) to gve a hycrocarban mass concontravon of about 8 gh The fistil type should show discroto poaks (29. a diesa uo) inthe gas elvemstogeam, 23 can be soenin Figure At (it pant of to chromatogram). The sacond ype should Mave a boing range higher thane Ws on, and should show a hump inthe gas exromatogiam, ae ean be eoon n igure A # (ght part ofthe Ghromategram). Asuitabie ol tt type i for pxampia a ubneating ol wht ay addines, ‘The carat solutions ean be prepated by eluting an siquet of hs standerd gluten (68) wih difaront Volumes ofthe RW standard scluion (5 6) Control solution Prepsre an independent conto solution in accerdarce wih (6.7) using 2 hydrocarbon concentration abot in {he midde ofthe working range of the system-performance standard soluian (6) 63. System-pertormance standard solution Praparoa mature of equal smounts, on a mass bass. ofthe alkanes having even carbon numbers rom Cro to Gan, dsoived in r-Poptano (6.2), te give mass concentrations of about 80 msl exch maha, Street ‘om temperature NOTE 1 soni roto vey te stabi fe pe ciomsoyapc tn ta esate of nahanes 2h son ad oman onthe steno i rect tre 7 Apparatus, 174 Standard laboratory glessws (6h) ond deed betoe use which shat be weated at high temperatures or ensea wih acetone 2a puree ryote adn alse wail cna Cairn an pesto Flcara.WsutrSesoe 110-1209 Bern Gormany ve craton gv a owennce oust s Intemational Stndard and dosent sonst sv ondetanant ty 160 ots praaet (21502008 Ate sare 3180 16703:2004(E) 7.2 Mixing device. /Amecharical shaker wit atleast 120 horizontal shaking movements ger mine, o aematvely an utrasonic ath cane used 7.3 Laboratory centrtuge, eapanie of producing an accaertion of at least 1 500 1.4 Gas enromatograph, equipped witha non-cgerminaing ingcton sytem [ereleraly oncelemn or Breronabilonpeatuevapreatenhjecion PT} capa conn onde famelonaston ster NOTE the seo lame-oume inecten system cansnyrove he ln a tac ender 75. Capillary column, of used sie, with he following properties: | nompalar stationary phase: 2g mobiized 100 % simathy!posioxane, 96 %i-smetylS % ‘phenyl pelyelovane, or moshed sloxane palmer | lenge som to25m 04 mm 10.032 mm | im ickness 04 pm 1.0 ym ‘Tne column shal give a baseline separation for he malkanes in the system-per‘ormance standard soution 6 ‘Thermal tsboow-beed columns are profored ‘The uso ofa pre-column, 2g. wide‘bore (0.53 mm interna ameter) deactivated fed sca ofa least 2m of length hat sus he analyicalcelumn ands connected tot using 9 zero-flyme connector. e recommenced, 17. Data system, capable ofintegratng the tot! area of te chvomatogra, compensating for cok Bleed and emieyraing after detning amnew taselno TET Glass exteaction vessel, of volume at east 100 ml, wth stow cape provided wth an inlay of PTFE: 1.8 Glass tubo, of volume 25-ml wth a round-lase stopper or wih stew caps proved! wth a nay of Pre. 7.9. Separatory funnel, of capaciy a least 500 ml wit a ground-gass Seppe 1.40 Chromatography column for clean-up. Gass columns of about 10 mm internal alameter shall be used. The ugper part ofthe column shows be ‘iden to use ss a savent reservoir aoa the lower pat narowed to fm 3p ‘8 Sampling, sample conservation and pretreatment ‘Sampling shal be carried out according to 180 10981-1 and in coordination with the analytical laboratory. ‘The samples shouldbe kept sealed in darkness ata tomparature of abou 4°, ond extracted witha & period off week this isnot possible, samples shall be stored at [18 °C or ower. Belore analysis tho samples shall bo homegenzea, ‘ 12 50200- rata rsene180 16703:2004(€), 9 Procedure 9.4. Preparation of the clean-up column Push e plug of pre washes glass wool or # PTFE ft gown into the col (70), Thon, uecesshvaly a 2g (of Flor (63) and 2 g of sodium sulfate (6.4) Prepare tne column immediately before use 92 Blank ‘Win exch seras of samples, carry out a bank determination according to 9.3 using al reagents in iomtca! ‘amounts but without a sample. I Blank valves are unvsualy high (more than 10 ol he lowest velue intrest), ever step inthe procedure shall be checked to determin th cause ofthese hgh banks 9.3 Extraction and clean-up ‘Weigh an exact amount (about 209) ofthe homogenized Fel-meist or pretreated sol sample according to SO 14507 into a lass extraction vessel (77) anc ad (40+ 1) mi ef acetona(6 1). After bay shaking Dy hand, a (20 0,1) ml ofthe RTW. standard solution (66), Close the vessel and exact me sampie for" Using mechanical shaking or sonication (72) Aer setting of the sold material anstora¢ much as poste bf tne supernatant into a eaparatory funn (7.9) To remote the aeetene, wash the argare pasa twice by Shaking thoroughly (5 min) wih 100 ml of water. Calec he organic layer n a gass ube 7 8). Add suffcient odin aus eo tatno lamp 19 formed. Transtor 10 mol he exact 3 clean ealumn led with Flor (9-1), Do nat pre-wash the column with organic solvent. Galt th erie eluate Transfer an aliquot of the purieg extractte 8 GC-wal and analyee by gas chromstosranhy lf approprate, test porions of 5 gta 30g can be used (eg. smaller test poricrs should be used if samples ‘orb the major porton ol the exracion solvent added tampa naka shoud ba increased f ngh sons ty 'Srequres) [Aternatve extraction procodures, eg, accelerated sent extraction (ASE), may be used provided hay give ‘omparaie exvacton perormances ‘tis vary important thatthe clean-up column be feshy prepared snd active, snd thatthe extract be fee of ‘ottora [ess than 0.1% (volume raion] especaly when ihe sample coriais polyeyci aromatic Dydrocarbone [PAH) in adation to mineral ol hysrocatbone Make suo that PAs are astarbod onthe clean. ‘Gp column If the cstnel peaks of PAHS ae observed in Ure GC-FID ctvemarogram (see Annex A), tis ‘shovld be mentonad nthe fst report NOTE roves acca pana prance cn be ppd Hovde aha ncesay ty 944 Dotormination by gas chromatography 98.41 Test of the performance ofthe gas chromatographic system Use a capilary column vth ona ofthe specified statonary phates (75) for gas ebromsategraphie analysis. ‘Adjust the gas chrometograph (7 4) to provide an optimal separation The r-kanes = he )star pertormance standard saluton (68) shal be bascline-separated. The lative response ct ho mttracortane {ey shatlbe at east 0.8, wit respect to r-acosane (Cz). For an example of gas chromatographic candtons, soe Annex A 942 Repeatability test Record a gas chromatogram ofthe eclumn bleed by njecion ofan oppxcnriate volume of montane. Than inject the same volumo ofa sutable oneentraian athe conta saluton 6) thes tmes, and record tna ‘Ghomatogram foreach inaction. Integrate the chromatagroms according fo 9.45, ord caleuate the mean ol180 16703:2004(€) the measured peak areas and the cortesponding standard deviation, The relaive standard deviation shall net be gresterthan 8%, 943 Calibration ‘whan tna method ie used forthe fst te andor whan the apparatus or eperatoris cnangad, carry outa base calibration according to 80 4466-1 ncucing the determination a he lst of duction anant of Perfo an externa calibration by analysing aminimum ofS etions of nysrecarbon standars soluten (6.7) ‘which shall over the working range. Coleuate a cabvaton function by iar regression analyss of te corrected peak areas, Use a chromatogram of -hoptane to correct the peak ao ol he ehomtagrame ef he hysrecarbon Flandard solitons forte colurm bleed From tn caluiied rogreswion line, dtermine ine acival eons uty of the metnos 44 val ity check of the calibration funetion Check he valli ofthe eaten function within each batch of samples by snalsis of ene ndependon! ‘onto solution (66) The vai chock sont protiers of ealraton balare real carrpes aren Chock ‘hather he result wihin © 19% of tne reference value ofthe conel olution. his ia ho cate, No actual Calbraton fncions ssauined Io be valid Ife, perform a row ealraton according 03.43 NoTEis good anya pracic to perfom bth a esbaton check a (Sneentelt coatonanceoy paced dung to anaes ora tich samples. Ths ndcpenset souton can pron einer 945 Measurement ‘Analyse the blank (9.2) and the sample exracs (23), caliraton standards (6.7) and cori! solutions (6.8) Under denieal gos chromstogranhieconations -Hoptane shal be analysed in each sample batch. Tho resuling ervematogram 6 uses 0 coract Chromatograms of lanes (62) sample serie (93) caloraton standards (6 7) ans coool solutions (68) forcolumn bleed port tegiation 46 Integration tegrata he total area betwen the ndocane Cre and netraconiane Cxo peaks ofthe chromatogram, Stat the imegraion atthe retention time ust after he end ofthe n-decane pootat he ogra ave i ant of he oven! peak, End the integration ofthe (ata ofe a the retonsan ime jst bere the beaaing ofthe ‘nbracoriare peck at he same sgna level (see Annex A) Inlogiatemftracontane (Cis) 38 a eoparate ek forthe emovery check “The presence of peaks on the tall of he slvent peak with retention times less then that of mdecane indicates that tne eampla conta low-boing vlatie hydrocarbons. Ths shouldbe mentioned n te fest report ‘Asonhorzonal baseline at the and ofthe chromatogram (elanion te greater than that of mfetracontano), ‘hia signal level groator han tv Bleed, cdicates that ha sample contane nigh boing hytocarbora sith ‘hore tan 40 carbon some. This thould be mestaes in he tat report should be ovsures that hese ‘Compounds elite completely Hom the column tharwsa they can cause niererences wih the subsequent Sample anayss. ‘Alchromatograms should be checkes visual for coroe intag’aton. The stat aa sion tina of he Integration enous bo visible on the chromatogram. {comatogram othe samp exoct wih that ofthe sysiom-prfermance siandard solzion 80), Tha eaospandog, ling ong en be garued om noe 3180 16702:2004(€) NOTE 27e peak shape and sina tensity of metracontne re ses o changin ha sutace props le Injctr anor na pre-coumn de to conamaton oy ean rstanie,“Thwetos, ay canbe woes ae gsc Ineaton ofthe nee foreplay palin ard finer 947 Calculation Calcuste the mineral i content ofthe sol sample using Equation (1): 100 wey 800, 0 » ae @ andwhere vwnis the hydrocarbon mass traction of he sil sample in miliarams per hlogram dry mater ) Ss me nydrocarbor mass concentration of he extract calculated rom the calbraton tune rligeams per ie; ‘isthe volume ofthe msheptone extract, lili F's the dutonfacter (it appieabl ms the mass ofthe sample token fr analys, in grams: sis te ary matter content ofthe sol sample, expressed as a percentage (mass tacton), determines ‘secording 19150 11485, “tsi the integated peak area of he sample exract, expressed in instrenent dependent unis. ‘> iste intercept of ne Y-axs. expressed in instrment-cependent ints 44 isthe slope of the catration function. exeresseain tres per mia mg) Round the i oto signifcare figures. 9.5 Quality control 85:1 Suitability check ofthe clean-up procedure “The clean-up efciancy of ech batch of Floris column packing shal be checked lt Fons eatidges are sed, ther sutabilty forthe leen-up procedure shat be eneckod inthe samme way) by the olan rocodore ‘dd 101 ofthe n-ectadecancic acid octadecy ester solution (6.5)t0 the clean-up column 9 1) filed wth Bog ot ions! ana? g af sosum ulate, and esi! the ontre eluate Analyso a portion of ha reaslong Soudion by gas ehvomaiagranhy. Analyse a 119 ction ofthe untested m-acadsean ae detadecy ester fest solution (6.5) 2 reference, Determine ne recovery othe nociadacano's aoe octadecyl ester ater tlesrup on the bare ofthe po area in respec foie untested moctadocnnoc aed octoseey estar [see Equation (3) (01802008 Att manne 7180 16703:2004(6) Ros 282 ei [Roo isthe recovery of moctadacanaie acd actadecylester(1+19), a8 a percent (6) {foo isthe peak area of n-octadecancic acid ectadecyl ester ater Cear-up onthe Flori column, in ‘ratament dependent unis 4's the peak area of th (1419) luton of untreated n-octadecancic aie octadecyl ester, in instrument-dependent uns, “The recovery shal not exceed 5 %, the recovery of moctadecanaic acid octadecy ester acid is above 5 %, fate the Flori according to (6.3) and repeat the test. 95.2 Recovery ofthe hydrocarbon standard solution “The recovery of the hydrocarbon standard soltion shall be crecked with each bate of rer Flori ‘Gariidgee aroused, recovery sal be chacked n ne some way) bythe flowing prosecure ‘Ad 10 mi of he hydrocarbon standard solutn (6.7) tothe cleanup column (91) les with 2.0 of Flr ‘dnd 2g of socum suloe, and cals he enira eluate, Analyes a norton ofthe puro slvion by 935 ‘hromstograpny fnalyee the unteatea hyarocarbon stancars solution as feferonce. Octarmine the ecovery tine nyeroesbone on the base ofthe peak area ofthe pushed ana untested stars slutons [see Equation 2 ares 00 where eis the recovery of the hydrocarbon standard tne the peak area ofthe hydrocarbon standard ater clean-up onthe Fria column in instvumnt epondent nts Avice tho peak aoa of untrostod hydrocarbon standard in instrument dependont units ‘Tne recovery shale more than 80% 10 Precision “Ine performance characteristics ofthe method as determined by nterlaboratory tudes are gwen in Annex 41 Test report “The tet reper shel contain at asthe following information 2) arelerence to this nternatona! Standard (150 16703-2004 ')aveterence tothe method used for extraction (shaking or soricaton o other) and clean-up ©) a complete entiteaton of the samale180 16703:2004(6) 9) the resuts ofthe eotermintion 12) a reference tothe occurence of ow: (< Cre) ancorhighsbeling (> Cao) compounds in he ehvomstoram, 1) any detis not spacfod inthis International Standard or which are eptonal, 3¢ wel a8 any thar actor that might nave afected ie results,180 16703:2008(€) Annex A (informative) Examples of gas chromatograms of mineral and soil samples hydrocarbon standard Figure 1 shows the gas evomatagram ofthe caltration mir of mineral ol cansising of equal pars of =| ‘ese Kel and oluicaing ol Figure A2 shows the gos chromalosrom of fe “ean bleed” afer nection ‘of heptane, and Figure A shows tho tegrotd gus chiomatogram of ne calbraton misurs of mineral Ot {ores for he ‘column oigea The tla peak area between r-docane (C10) ane niovacaniane (C4) Used forquantfeaton i ncicatod as hatched area ‘The Figures A and AS show integrated gas chromatograms corrected for the “column blaed” of ew and Ighly contacted sal Figue AS shows a cvemategram ofa system-performance standard soliton. Examples of cremstograms of sl samples wit epreseriatve characteristics ae cian in Figures A At. ‘The gas ehematograms were recerded uncer the allowing conditions Injectontennique on-column Inyecton volume Ape sy ‘Colum yp: WOOT fusedtica Cour ona am Interna iometer 932mm quid phase ex.s Fm hceness: 10um Pre-coume: activated fused sca capary, 2m x0.63 mm Corer ga ion Pressure oop Detector fame ienzation detector Detector tomporature 380°C Temperature programme: 80°C for t ma: 20°Cimin fo 360°C; 380°C for 18min 0 (21802008 Aree sesened180 16703:2004(€) Figure A — Gas chromatogram ofthe calibration mixure consisting of equal pets of diesol fuel fd lubricating oi, 600 200 200 1 Z 0 5 oy 5 ‘ Figure A.2— Gas chromatogram of the “column blood 2 {1502004 anreseee "180 16703:2004(€) 900 600 Figure A —Intagrated gas chroma . "er ram ofthe caloration mixture of minora oi corrected 1 2 sso 300 ‘0 0 ° 5 © 6 1 Koy Figure A4— Integrated gas chromatogram ofa low-contaminated soil sample corrected ‘orthe "column bioed”™ 2 °180 16703:2004(€) 2280 sto 2 nisrasentene Figure A.8 — Integrated gas chromatogram of a highly contami Corrected forthe “column bleed & 0 000 35000 30 000 25 000 2000 15000 10 000 000 co oz ow HCH Co euces CH ° 2 Ss % 9 mS & MS 2 mn Figure A6 —Gas chromatogram ofa system-performance standard solution ee) 2%180 16703:2008(€) 4 1200 1 000 200 18.945 on 00 11.400 s7308 200 ° wg fo © 2 te 16 6 » nin t Figure A.7 — Gas chromatogram — Sample 3 GC Soll (sulficient clean-up for PANS) 4 1200 1000 eat tno ao 114st 19520 480 0 ° wtp Pe w @ 1% 6 * 2 ‘min 1 : Figure A8— Gas chromatogram — Semple 3 GC Soi insuiciont clean-up for PAHS) 4“a 143 000 ogi ‘0 c09 F- 100 000 a0 000 0-000 40 000 20 000 0 . 2 8 45 0 05 8 0S Figure A.8 — Sampie GC S« ‘with neue (acetone content about 2.5% weloansup of PAHS). 4 te 000 120 000 100 000 0 0c0 0 000 co 0 Figure A.10-— Sample 3.GC Soil (acetone content loss than 0,1 % In oxtract) ‘ith sufficient clean-up of PAHS 180 16703:2004(€) 6180 16703:2004(€) Annex B (informative) Determination of the boiling range of mineral oil hydrocarbons. from the gas chromatogram Using the data fom Tabo 8.1, he approxi bong range ofthe nysrocarbors in he sample canbe tsttbates by 2anpuison ofthe peak pate af te same chromatogram and hat of fh ralkane mire ‘Table Bt — Boling points ofthe naikanes with from 6 to 44 carbon atoms Toner eaeAnnex C (informative) Procis data ‘An ietacaboratory comparison was cried out in 2003. The pracision data from this intraborstory ‘Comparison ave guen in TasleC Table 1 — Provision data for 15016703 180 16703:2004(€) woeat or @ a =e ae ‘Gowan? Rae © Ten ma oo Ho saen | Foon 2 oy oo aa sansorssolton | Grsumetie 284291180 15703:2004) 0 e a @ @ 8 Bibliography ISOITR 11046, Soi qual — Determination of miner ol cantant — Moto ty iarod speceamaty fang gos chromatographic motion ISO 11464-1994, Sol qualiy — Proveatmont of samples forpysico-chemicat analysos 0 15009, Sc quatty — Gas vomatographic determination ofthe contort of yao aromatic hhrdocerbors,naphalene and volatile halogenated hycrocarbons —~ Purge-ond-tap meted with ‘ermal desorption 'S0 9317-2, Water quaity — Determinetion of nycrocarbon ol index — Part 2 Atethod using solvent lentacton and ges chromatography ‘EN 14099 2000, Charactartzaton of waste — Detonation of hycrocorbo content inthe range of toto Cxeby gas chromatography