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100 Ammonia

T=150

T=200
Ammonia, NH3
Pressure-Enthalpy Diagram
S=Specific Entropy, kJ/kg*K
T=Temperature, ºC

S=8
S=9

S=7
S=5

S=6
10 T=120
T=110 S=10
T=100
T=90
T=80
T=70
T=60
T=50
Pressure [MPa]

T=40
T=30
1 T=20 S=11

T=10

T=0

T=-10

T=-20

S=12
T=-30
0.1
T=-40

T=-50

T=-60
S=13

T=-70
0.01
-1200 -1000 -800 -600 -400 -200 0 200 400 600 800 1000
Produced by I. Aartun, NTNU 2002. Based on the program Allprops,
Enthalpy [kJ/kg] Center for Applied Thermodynamic Studies, University of Idaho.
Carbon Dioxide: Pressure - Enthalpy Diagram
10,000

180

400
350 F
300
160

200

250
140

450

500
F

o
20
o

100

120
60

80
-40 F

-20
t=0

40
o
3
/ft
30 lb

75
45 sity =

70
50 40 35 D en 25

55
60

65
20
15

5
22
75

-0.
50
10

0
-.2
5

-.30

20
-.2
- .3 2

-0.
0
Melting Line

-.375

-0.35
75

-.400
-.1 3
/ft
1,000 5.0 lb

-.425

50
-.450
4.0
F

-.1
Entropy = -0.500 Btu/lb,o

25 3.0
0.9 -.1
-.475
Pressure, Psi

0.7 0.8
00 2.0
0.6 -.1
-.525

0.4 0.5
1.5

75
-.0
.3
-.550

1.0

50
o F

-.0
b,
u/l
0.2 0 Bt
5
02 y=
-0 . op
100 0.1 E3 ntr
0.5 lb/ft
Density =
Triple Point (75.122 psia, -69.804

100
120
140

250
60
o

-20
-40

20
40

80

160

200
F)

180

300

400
350
0
ne
Sublimation Li

Drawn with CO 2TabTM Copyright © 1999


A Spreadsheet Add-in for the Thermodynamic and ChemicaLogic Corporation
Transport Properties of Carbon Dioxide www.chemicalogic.com
Enthalpy, Btu/lb
10
-200 -180 -160 -140 -120 -100 -80 -60 -40 -20 0 20 40 60 80
Carbon Dioxide: Pressure - Enthalpy Diagram

1,000

240 C
180

280
200

220

260
120

160
t=0 C

100

140
80
40

o
60
-20

o
-40

20
0 00
3
90

00
r= r=8 kg/m 0
0 r = 60

12
0
00 = 70 0
1 sity

r=

50
r= Den r= 50

11
50

00
10

r=
0
r = 40

11
r=

r=
0
r = 30
3
0 kg/m
r = 20

0
-2.00

-1.70

--1.6

0
-1.90

0
-1.80
.30 kJ/kg, oC

-.9
0
s = -2.20

0
- 1 .5

.30

0
.0
r = 150

10
-1.4

-.8
-2.10

-1
-1.
-1

20
-1.
100

0
r = 100

-.7
Entropy = -2

r = 75

0
-.6
Pressure, Bar

r = 50
-.50
r = 35
0
-. 4 r = 25
3
= 20 kg/m
Melting Line

0 Density
-. 3
r =15

0 r = 10
10 -.2
0
-. 1 r=8

240
=
r=6

s
Triple Point (5.18 bar, -56.558 oC)

220
160

200
180
120
100

140
-40 C

40
60
20

80
-20
o

0
Sublimation Line

Copyright © 1999
Drawn with CO 2TabTM ChemicaLogic Corporation
A Spreadsheet Add-in for the Thermodynamic and www.chemicalogic.com
Transport Properties of Carbon Dioxide Enthalpy, kJ/kg
1
-500 -400 -300 -200 -100 0 100 200
100 Ethane
Ethane
Pressure-Enthalpy Diagram S=5.0 S=5.5
S=Specific Entropy, kJ/kg*K S=6.0 S=6.5
S=4.0 T=Temperature, ºC

S=4.5
S=7.0

10
Pressure [MPa]

S=7.5
T=20

T=200
T=10
T=0
T=-10
T=-20

T=150
T=-30
1
T=-40 S=8.0

T=-50

T=100
T=-60

T=-70

T=50
T=0
T=-80
T=-50

S=8.5
0.1
-300 -200 -100 0 100 200 300 400 500 600 700 800
Produced by I. Aartun, NTNU 2002. Based on the program Allprops,
Enthalpy [kJ/kg] Center for Applied Thermodynamic Studies, University of Idaho.
Pressure-Enthalpy Diagram for Water and Steam
Based on the IAPWS-95 Formulation for General and Scientific Use
10000

Joule-Thomson Inversion

1000

100
Pressure, bar

10

10% 20% 30% 40% 50% 60% 70% 80% 90%

0.1

0.01
0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000
Drawn with SteamTab Duo V3.0. Enthalpy, kJ/kg Copyright © 1998 ChemicaLogic Corporation.
WATER: PRESSURE-ENTHALPY DIAGRAM
(Based on IAPWS-95 Formulation for General and Scientific Use)
s=1.0 s=1.4 s=1.5 s=1.6
v=0.0165 v=0.02 700 F s=1.1 s=1.2 s=1.3
v=0.018 v=0.075 v=0.1
10,000.0 v=0.017 v=0.025 v=0.05
v=0.03 v=0.15 v=0.2
900 F
s=1.7
600F
800 F v=0.3

500F v=0.5 s=1.8

v=1.0 s=1.9
1,000.0
400F
v=2.5
s=2.0

300F v=5

s=2.1
v=10
200F
100.0
v=20 s=2.2
Pressure, psi

100F v=40 s=2.3


v=60
v=80
1500F
v=100 s=2.4
10.0 1400F
v=200
50F
v=300 s=2.5
1300F
v=400
v=600 s=2.6

1200F v=800
10% 20% 30% 40% 50% 60% 70% 80% 90% v=1000
1.0 1100F
s=2.7
1000F
900F
s=2.8
800F

0.1
0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000
Drawn with SteamTab Duo V3.0. Enthalpy, Btu/lb Copyright © 1998 ChemicaLogic Corporation.

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