S L=C L ln ( T )

du L =−S L dT

SG =CpLn ( T )−Rln ( P )

du G=−SG dT +ϑG dP

du L =duG

−S L dT =−SG dT +ϑG dP

−S L T + SG T =ϑ G P

dT ( sG −s L )=ϑG P

P S G −S L
T
= (
ϑG )
g(T,P)= SG −S L

SG −S L =Cpln ( T )−Rln ( P )−S L ln ⁡( T )

dT dP dT
( SG −S L ) =Cp T −R P −C G T

dT dP
dg ( T , P ) =( Cp−C L ) −R
T P
De PV=RT

dP dT
=
P RT
dP P
=
dT RT
dT dP
dg ( T , P ) =( Cp−C L ) −R
T P
tal que : ( Cp−C L ) T =d ( T , G ) y g ( T , P )=SG −S L entonces

α
dg= −( Cp−C L )
T
Despejo en Ec.22 y reemplazo Ec.22

−S L T + SG T =ϑ G P

−S L T =ϑG P−SG T
 dT dP
dg ( T , P ) =( Cp−C L ) −R
T P
Entonces

dP P ∝
=
dT RT T [
−( Cp−C L ) ]
dP dT ∝
=
P RT T [
−( Cp−C L )]

dP dT ∝ 1
P
=
T RT R[
− ( Cp−C L ) ]
dP dT ∝ ( Cp−C L )
P
=
T RT
−[R ]
P0 T ( Cp−C L )
ln
P
=ln 0
∝
T T0R[−
R ]
( Cp−C L )
P T T0
ln 0 =
P [ ( )] ( )
∝
T0 R
1− 0
T T
R

(Cp−C L)
T T0
P=P 0 exp
[ ( )] ( )
∝
T0R
1− 0
T T
R