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REGULATION (EC) No 1272 2008 On Classification, Labelling and Packaging of Substances and Mixtures
REGULATION (EC) No 1272 2008 On Classification, Labelling and Packaging of Substances and Mixtures
REGULATIONS
THE EUROPEAN PARLIAMENT AND THE COUNCIL OF THE (4) Trade in substances and mixtures is an issue relating not
EUROPEAN UNION, only to the internal market, but also to the global market.
Enterprises should therefore benefit from the global
harmonisation of rules for classification and labelling and
Having regard to the Treaty establishing the European Commu- from consistency between, on the one hand, the rules for
nity, and in particular Article 95 thereof, classification and labelling for supply and use and, on the
other hand, those for transport.
Having regard to the proposal from the Commission,
Whereas:
(6) This Regulation follows various declarations whereby the
Community confirmed its intention to contribute to the
(1) This Regulation should ensure a high level of protection of global harmonisation of criteria for classification and
human health and the environment as well as the free labelling, not only at UN level, but also through the
movement of chemical substances, mixtures and certain incorporation of the internationally agreed GHS criteria
specific articles, while enhancing competitiveness and into Community law.
innovation.
the level of protection achieved through the system of requirements of food law, establishing the European Food
harmonisation of classification and labelling, through Safety Authority and laying down procedures in matters of
Community hazard classes not yet part of the GHS as well food safety (11) and Regulation (EC) No 1831/2003 of the
as through current labelling and packaging rules. European Parliament and of the Council of 22 September
2003 on additives for use in animal nutrition (12) or except
where substances and mixtures are transported by air, sea,
road, rail or inland waterways.
(9) This Regulation should be without prejudice to the full and
complete application of Community competition rules.
(12) The terms and definitions used in this Regulation should be
consistent with those set out in Regulation (EC) No 1907/
2006 of the European Parliament and of the Council of
(10) The objective of this Regulation should be to determine 18 December 2006 concerning the Registration, Evalua-
which properties of substances and mixtures should lead to tion, Authorisation and Restriction of Chemicals
a classification as hazardous, in order for the hazards of (REACH) (13), with those set out in the rules governing
substances and mixtures to be properly identified and transport and with the definitions specified at UN level in
communicated. Such properties should include physical the GHS, in order to ensure maximum consistency in the
hazards as well as hazards to human health and to the application of chemicals legislation within the Community
environment, including hazards to the ozone layer. in the context of global trade. The hazard classes specified
in the GHS should be set out in this Regulation for the same
reason.
of Regulation (EC) No 1907/2006. In fulfilling their and differentiations in order for that manufacturer,
responsibilities for classification, downstream users should importer or downstream user to arrive at a conclusion as
be allowed to use the classification of a substance or to whether or not the substance or mixture should be
mixture derived in accordance with this Regulation by an classified as hazardous.
actor in the supply chain, provided that they do not change
the composition of the substance or mixture. Responsibility
for classification of substances not placed on the market
that are subject to registration or notification under (21) While the classification of any substance or mixture may be
Regulation (EC) No 1907/2006 should mainly lie with carried out on the basis of available information, the
the manufacturers, producers of articles and importers. available information to be used for the purposes of this
However, there should be a possibility to provide for Regulation should preferably have been generated in
harmonised classifications of substances for hazard classes accordance with the test methods referred to in Regula-
of highest concern and of other substances on a case-by- tion (EC) No 1907/2006, transport provisions or inter-
case basis which should be applied by all manufacturers, national principles or procedures for the validation of
importers and downstream users of such substances and of information, so as to ensure quality and comparability of
mixtures containing such substances. the results and consistency with other requirements at
international or Community level. The same test methods,
provisions, principles and procedures should be followed
where the manufacturer, importer or downstream user
chooses to generate new information.
(17) Where a decision has been taken to harmonise the
classification of a substance for a specific hazard class or
differentiation within a hazard class by including or revising
an entry for that purpose in Part 3 of Annex VI to this
(22) To facilitate hazard identification for mixtures, manufac-
Regulation, the manufacturer, importer and downstream
turers, importers and downstream users should base this
user should apply this harmonised classification, and only
identification on the data for the mixture itself, where
self-classify for the remaining, non-harmonised hazard
available, except for mixtures with carcinogenic, germ cell
classes or differentiations within the hazard class.
mutagenic or reproductive toxic substances, or where the
biodegradation or bioaccumulation properties in the
hazard class hazardous to the aquatic environment are
evaluated. In those cases, as the hazards of the mixture
cannot be sufficiently assessed in a manner that is based on
(18) To ensure that customers receive information on hazards,
the mixture itself, the data for the individual substances of
suppliers of substances and mixtures should ensure that
the mixture should normally be used as a basis for the
they are labelled and packaged in accordance with this
hazard identification of the mixture.
Regulation before placing them on the market, according to
the classification derived. In fulfilling their responsibilities
downstream users should be allowed to use the classifica-
tion of a substance or mixture derived in accordance with
this Regulation by an actor in the supply chain, provided (23) If sufficient information is available on similar tested
that they do not change the composition of the substance mixtures, including relevant ingredients of the mixtures, it
or mixture, and distributors should be allowed to use the is possible to determine the hazardous properties of an
classification of a substance or mixture derived in untested mixture by applying certain rules known as
accordance with this Regulation by an actor in the supply ‘bridging principles’. Those rules allow characterisation of
chain. the hazards of the mixture without performing tests on it,
but rather by building on the available information on
similar tested mixtures. Where no or inadequate test data
are available for the mixture itself, manufacturers, importers
and downstream users should therefore follow the bridging
(19) To ensure information on hazardous substances is available principles to ensure adequate comparability of results of the
when they are included in mixtures containing at least one classification of such mixtures.
substance that is classified as hazardous, supplemental
labelling information should be provided, where applicable.
(25) The protection of animals falling within the scope of substance or mixture is placed on the market and in which
Council Directive 86/609/EEC of 24 November 1986 on it can reasonably be expected to be used. It should,
the approximation of laws, regulations and administrative however, be possible to use, for the purpose of this
provisions of the Member States regarding the protection of Regulation, the results of tests that are carried out to
animals used for experimental and other scientific comply with other regulatory requirements, including those
purposes (1) is of high priority. Accordingly, where the laid down by third countries, even if the tests were not
manufacturer, importer or downstream user chooses to carried out on the substance or mixture in the form(s) or
generate information for the purposes of this Regulation, physical state(s) in which it is placed on the market and in
they should first consider means other than testing on which it can reasonably be expected to be used.
animals within the scope of Directive 86/609/EEC. Tests on
non-human primates should be prohibited for the purposes
of this Regulation. (31) If tests are performed, they should comply where
appropriate with the relevant requirements for the protec-
tion of laboratory animals, set out in Directive 86/609/EEC,
(26) The test methods in Commission Regulation (EC) No 440/ and, in the case of ecotoxicological and toxicological tests,
2008 of 30 May 2008 laying down test methods pursuant good laboratory practice, set out in Directive 2004/10/EC
to Regulation (EC) No 1907/2006 of the European of the European Parliament and of the Council of
Parliament and of the Council on the Registration, 11 February 2004 on the harmonisation of laws,
Evaluation, Authorisation and Restriction of Chemicals regulations and administrative provisions relating to the
(REACH) (2) are regularly reviewed and improved with a application of the principles of good laboratory practice
view to reducing testing on vertebrate animals and the and the verification of their application for tests on
number of animals involved. The European Centre for the chemical substances (3).
Validation of Alternative Methods (ECVAM) of the
Commission's Joint Research Centre plays an important
role in the scientific assessment and validation of alternative (32) The criteria for classification in different hazard classes and
test methods. differentiations should be set out in an annex, which should
also contain additional provisions as to how the criteria
may be met.
(27) The classification and labelling criteria set out in this
Regulation should take the utmost account of promoting
alternative methods for the assessment of hazards of
substances and mixtures and of the obligation to generate (33) Recognising that the application of the criteria for the
information on intrinsic properties by means other than different hazard classes to information is not always
tests on animals within the meaning of Directive 86/609/ straightforward and simple, manufacturers, importers and
EEC as laid down in Regulation (EC) No 1907/2006. Future downstream users should apply weight of evidence
criteria should not become a barrier to this aim and the determinations involving expert judgement to arrive at
corresponding obligations under that Regulation, and adequate results.
should under no circumstances lead to the use of animal
tests where alternative tests are adequate for the purposes of
classification and labelling. (34) Specific concentration limits for substances should be
assigned to a substance by a manufacturer, importer or
downstream user in accordance with the criteria referred to
(28) For the purposes of classification, data should not be in this Regulation, provided the manufacturer, importer or
generated by means of testing on humans. Available, downstream user is able to justify the limits and informs the
reliable epidemiological data and experience with regard to European Chemicals Agency (hereinafter referred to as
the effects of substances and mixtures on humans (e.g. ‘the Agency’) accordingly. However, specific concentration
occupational data and data from accident databases) should limits should not be set for harmonised hazard classes or
be taken into account and may be given priority over data differentiations for substances included in the harmonised
derived from animal studies when they demonstrate classification and labelling tables annexed to this Regula-
hazards not identified from those studies. The results of tion. Guidance should be provided by the Agency for the
animal studies should be weighed against the results of data purpose of setting the specific concentration limits. In order
from humans and expert judgement should be used to to ensure uniformity, specific concentration limits should
ensure the best protection of human health when also be included, where appropriate, in cases of harmonised
evaluating both the animal and human data. classifications. Specific concentration limits should take
precedence over any other concentration limit for the
purpose of classification.
(29) New information as regards physical hazards should always
be necessary, except if the data are already available or if a
derogation is provided for in this Regulation. (35) Multiplying factors (M-factors) for substances classified as
hazardous to the aquatic environment, acute category 1 or
chronic category 1, should be assigned to a substance by a
(30) Testing that is carried out for the sole purpose of this manufacturer, importer or downstream user in accordance
Regulation should be carried out on the substance or with the criteria referred to in this Regulation. Guidance
mixture in the form(s) or physical state(s) in which the should be provided by the Agency for the purpose of
setting the M-factors.
(1) OJ L 358, 18.12.1986, p. 1.
(2) OJ L 142, 31.5.2008, p. 1. (3) OJ L 50, 20.2.2004, p. 44.
31.12.2008 EN Official Journal of the European Union L 353/5
(36) For reasons of proportionality and workability, generic cut- (43) It is essential that the substances and mixtures placed on the
off values should be defined, both for identified impurities, market are well identified. However, the Agency should
additives and individual constituents of substances and for allow enterprises, upon their request and where necessary,
substances in mixtures, specifying when information on to describe the chemical identity of certain substances in a
these should be taken into account in determining the way that does not put the confidential nature of their
hazard classification of substances and mixtures. businesses at risk. Where the Agency refuses such a request,
an appeal should be allowed in accordance with this
Regulation. The appeal should have a suspensive effect, so
that the confidential information with regard to which the
(37) To ensure adequate classification of mixtures, available request has been made, should not appear on the label
information on synergistic and antagonistic effects should while the appeal is pending.
be taken into account for the classification of mixtures.
(40) The two instruments foreseen by this Regulation to be used (46) To limit the information on the label to the most essential
to communicate the hazards of substances and mixtures are information, principles of precedence should determine the
labels and the safety data sheets provided for in Regula- most appropriate label elements for cases in which
tion (EC) No 1907/2006. Of these two, the label is the only substances or mixtures possess several hazardous proper-
tool for communication to consumers, but it may also serve ties.
to draw the attention of workers to the more comprehen-
sive information on substances or mixtures provided in
safety data sheets. Since the provisions on safety data sheets (47) Council Directive 91/414/EEC of 15 July 1991 concerning
are included in Regulation (EC) No 1907/2006 which uses the placing of plant protection products on the market (1)
the safety data sheet as the main communication tool and Directive 98/8/EC of the European Parliament and of
within the supply chain of substances, it is appropriate not the Council of 16 February 1998 concerning the placing of
to duplicate the same provisions in this Regulation. biocidal products on the market (2) should remain fully
applicable to any product within their scope.
mixtures, is ensured by Regulation (EC) No 1907/2006. (56) Different manufacturers and importers of the same
However, in exceptional circumstances, substances and substance should make every effort to agree on a single
mixtures may also be supplied to the general public classification for that substance except for hazard classes
unpackaged. Where appropriate, relevant labelling infor- and differentiations subject to a harmonised classification
mation should be supplied to the general public by other for that substance.
means, such as an invoice or bill.
(50) Rules for the application of labels and the location of (57) To ensure a harmonised level of protection for the general
information on labels are necessary to ensure that the public, and, in particular, for persons who come into
information on labels can be easily understood. contact with certain substances, and the proper functioning
of other Community legislation relying on classification
and labelling, an inventory should record the classification
(51) This Regulation should set general packaging standards, in in accordance with this Regulation agreed, if possible, by
order to ensure the safe supply of hazardous substances and manufacturers and importers of the same substance, as well
mixtures. as decisions taken at Community level to harmonise the
classification and labelling of some substances.
(55) The Agency should study the possibilities for further (63) The responsible bodies, where requested by a Member State,
simplification of the notification procedure in particular may undertake statistical analysis to identify where
taking into account the needs of SMEs. improved risk management measures might be needed.
31.12.2008 EN Official Journal of the European Union L 353/7
(64) Regular reports by the Member States and the Agency on (71) To avoid unnecessary burdens on enterprises, substances
the operation of this Regulation should be an indispensable and mixtures which are already in the supply chain when
means of monitoring the implementation of chemicals the labelling provisions of this Regulation become applic-
legislation as well as trends in this field. Conclusions drawn able to them may continue to be placed on the market
from findings in the reports should be useful and practical without relabelling for a certain period of time.
tools for reviewing the Regulation and, where necessary, for
formulating proposals for amendments.
(78) When, on imperative grounds of urgency, the normal time 2. This Regulation shall not apply to the following:
limits for the regulatory procedure with scrutiny cannot be
complied with, the Commission should be able to apply the
urgency procedure provided for in Article 5a(6) of (a) radioactive substances and mixtures within the scope of
Decision 1999/468/EC for the adoption of adaptations to Council Directive 96/29/Euratom of 13 May 1996 laying
technical progress. down basic safety standards for the protection of the health
of workers and the general public against the danger arising
from ionising radiation (1);
(79) The Commission should also for the purposes of this
Regulation be assisted by the Committee established by
Regulation (EC) No 1907/2006, with a view to ensuring a (b) substances and mixtures which are subject to customs
consistent approach to the updating of chemicals legisla- supervision, provided that they do not undergo any
tion, treatment or processing, and which are in temporary
storage, or in a free zone or free warehouse with a view to
re-exportation, or in transit;
HAVE ADOPTED THIS REGULATION:
GENERAL ISSUES (d) substances and mixtures for scientific research and
development, which are not placed on the market, provided
Article 1 they are used under controlled conditions in accordance
with Community workplace and environmental legislation.
Purpose and scope
3. Waste as defined in Directive 2006/12/EC of the European
1. The purpose of this Regulation is to ensure a high level of Parliament and of the Council of 5 April 2006 on waste (2) is not
protection of human health and the environment as well as the a substance, mixture or article within the meaning of Article 2 of
free movement of substances, mixtures and articles as referred to this Regulation.
in Article 4(8) by:
(ii) suppliers to label and package substances and (b) veterinary medicinal products as defined in Directive 2001/
mixtures placed on the market; 82/EC;
(d) establishing a list of substances with their harmonised (i) as a food additive in foodstuffs within the scope of
classifications and labelling elements at Community level in Directive 89/107/EEC;
Part 3 of Annex VI;
(ii) as a flavouring in foodstuffs within the scope of
(e) establishing a classification and labelling inventory of Directive 88/388/EEC and Decision 1999/217/EC;
substances, which is made up of all notifications, submis-
sions and harmonised classifications and labelling elements (1) OJ L 159, 29.6.1996, p. 1.
referred to in points (c) and (d). (2) OJ L 114, 27.4.2006, p. 9.
31.12.2008 EN Official Journal of the European Union L 353/9
(iii) as an additive in feeding stuffs within the scope of 9. ‘article’ means an object which during production is given a
Regulation (EC) No 1831/2003; special shape, surface or design which determines its
function to a greater degree than does its chemical
composition;
(iv) in animal nutrition within the scope of Directive 82/
471/EEC.
10. ‘producer of an article’ means any natural or legal person
6. Save where Article 33 applies this Regulation shall not apply who makes or assembles an article within the Community;
to the transport of dangerous goods by air, sea, road, rail or
inland waterways.
11. ‘polymer’ means a substance consisting of molecules
characterised by the sequence of one or more types of
Article 2 monomer units. Such molecules must be distributed over a
range of molecular weights wherein differences in the
Definitions molecular weight are primarily attributable to differences in
the number of monomer units. A polymer comprises the
following:
For the purpose of this Regulation, the following definitions shall
apply:
(a) a simple weight majority of molecules containing at
1. ‘hazard class’ means the nature of the physical, health or least three monomer units which are covalently
environmental hazard; bound to at least one other monomer unit or other
reactant;
4. ‘signal word’ means a word that indicates the relative level 12. ‘monomer’ means a substance which is capable of forming
of severity of hazards to alert the reader to a potential covalent bonds with a sequence of additional like or unlike
hazard; the following two levels are distinguished: molecules under the conditions of the relevant polymer-
forming reaction used for the particular process;
5. ‘hazard statement’ means a phrase assigned to a hazard 14. ‘manufacturing’ means production or extraction of sub-
class and category that describes the nature of the hazards stances in the natural state;
of a hazardous substance or mixture, including, where
appropriate, the degree of hazard;
15. ‘manufacturer’ means any natural or legal person estab-
lished within the Community who manufactures a
6. ‘precautionary statement’ means a phrase that describes substance within the Community;
recommended measure(s) to minimise or prevent adverse
effects resulting from exposure to a hazardous substance or
mixture due to its use or disposal; 16. ‘import’ means the physical introduction into the customs
territory of the Community;
7. ‘substance’ means a chemical element and its compounds in
the natural state or obtained by any manufacturing process,
including any additive necessary to preserve its stability and 17. ‘importer’ means any natural or legal person established
any impurity deriving from the process used, but excluding within the Community who is responsible for import;
any solvent which may be separated without affecting the
stability of the substance or changing its composition;
18. ‘placing on the market’ means supplying or making
available, whether in return for payment or free of charge,
8. ‘mixture’ means a mixture or solution composed of two or to a third party. Import shall be deemed to be placing on
more substances; the market;
L 353/10 EN Official Journal of the European Union 31.12.2008
19. ‘downstream user’ means any natural or legal person 30. ‘scientific research and development’ means any scientific
established within the Community, other than the experimentation, analysis or chemical research carried out
manufacturer or the importer, who uses a substance, either under controlled conditions;
on its own or in a mixture, in the course of his industrial or
professional activities. A distributor or a consumer is not a
downstream user. A re-importer exempted pursuant to 31. ‘cut-off value’ means a threshold of any classified impurity,
Article 2(7)(c) of Regulation (EC) No 1907/2006 shall be additive or individual constituent in a substance or in a
regarded as a downstream user; mixture, above which threshold these shall be taken into
account for determining if the substance or the mixture,
respectively, shall be classified;
20. ‘distributor’ means any natural or legal person established
within the Community, including a retailer, who only stores
and places on the market a substance, on its own or in a 32. ‘concentration limit’ means a threshold of any classified
mixture, for third parties; impurity, additive or individual constituent in a substance
or in a mixture that may trigger classification of the
substance or the mixture, respectively;
21. ‘intermediate’ means a substance that is manufactured for
and consumed in or used for chemical processing in order 33. ‘differentiation’ means distinction within hazard classes
to be transformed into another substance (hereinafter depending on the route of exposure or the nature of the
referred to as ‘synthesis’); effects;
22. ‘non-isolated intermediate’ means an intermediate that 34. ‘M-factor’ means a multiplying factor. It is applied to the
during synthesis is not intentionally removed (except for concentration of a substance classified as hazardous to the
sampling) from the equipment in which the synthesis takes aquatic environment acute category 1 or chronic category 1,
place. Such equipment includes the reaction vessel, its and is used to derive by the summation method the
ancillary equipment, and any equipment through which the classification of a mixture in which the substance is present;
substance(s) pass(es) during a continuous flow or batch
process as well as the pipework for transfer from one vessel
to another for the purpose of the next reaction step, but it 35. ‘package’ means the complete product of the packing
excludes tanks or other vessels in which the substance(s) are operation, consisting of the packaging and its contents;
stored after the manufacture;
24. ‘competent authority’ means the authority or authorities or 37. ‘intermediate packaging’ means packaging placed between
bodies established by the Member States to carry out the inner packaging, or articles, and outer packaging.
obligations arising from this Regulation;
Article 3
25. ‘use’ means any processing, formulation, consumption,
storage, keeping, treatment, filling into containers, transfer Hazardous substances and mixtures and specification of
from one container to another, mixing, production of an hazard classes
article or any other utilisation;
A substance or a mixture fulfilling the criteria relating to physical
hazards, health hazards or environmental hazards, laid down in
26. ‘supplier’ means any manufacturer, importer, downstream Parts 2 to 5 of Annex I is hazardous and shall be classified in
user or distributor placing on the market a substance, on its relation to the respective hazard classes provided for in that
own or in a mixture, or a mixture; Annex.
27. ‘alloy’ means a metallic material, homogeneous on a Where, in Annex I, hazard classes are differentiated on the basis
macroscopic scale, consisting of two or more elements so of the route of exposure or the nature of the effects, the
combined that they cannot be readily separated by substance or mixture shall be classified in accordance with such
mechanical means; alloys are considered to be mixtures differentiation.
for the purposes of this Regulation;
Article 4
28. ‘UN RTDG’ means the United Nations Recommendations
on the Transport of Dangerous Goods; General obligations to classify, label and package
CHAPTER 1
(a) Articles 6, 7(1) or (5), 17 or 18 of Regulation (EC) No 1907/
2006 provide for registration of a substance; Identification and examination of information
Article 5
(b) Articles 7(2) or 9 of Regulation (EC) No 1907/2006
provide for notification. Identification and examination of available information on
substances
3. If a substance is subject to harmonised classification and 1. Manufacturers, importers and downstream users of a
labelling in accordance with Title V through an entry in Part 3 of substance shall identify the relevant available information for
Annex VI, that substance shall be classified in accordance with the purposes of determining whether the substance entails a
that entry, and a classification of that substance in accordance physical, health or environmental hazard as set out in Annex I,
with Title II shall not be performed for the hazard classes or and, in particular, the following:
differentiations covered by that entry.
Further, in cases where the available test data on the mixture 3. The tests referred to in paragraph 1 shall be conducted in
itself demonstrate germ cell mutagenic, carcinogenic or toxic to accordance with one of the following methods:
reproduction effects which have not been identified from the
information on the individual substances, those data shall also be
(a) the test methods referred to in Article 13(3) of Regula-
taken into account.
tion (EC) No 1907/2006;
6. Tests that are carried out for the purposes of this Regulation substance or mixture is placed on the market and in which it can
shall be carried out on the substance or on the mixture in the reasonably be expected to be used.
form(s) or physical state(s) in which the substance or mixture is
placed on the market and in which it can reasonably be expected
to be used.
Article 10
CHAPTER 1
1. Manufacturers, importers and downstream users shall take
all reasonable steps available to them to make themselves aware
of new scientific or technical information that may affect the Content of the label
classification of the substances or mixtures they place on the
market. When a manufacturer, importer or downstream user Article 17
becomes aware of such information which he considers to be
adequate and reliable, that manufacturer, importer or down- General rules
stream user shall without undue delay carry out a new evaluation
in accordance with this Chapter. 1. A substance or mixture classified as hazardous and
contained in packaging shall bear a label including the following
elements:
2. Where the manufacturer, importer or downstream user
introduces a change to a mixture that has been classified as (a) the name, address and telephone number of the supplier(s);
hazardous, that manufacturer, importer or downstream user shall
carry out a new evaluation in accordance with this Chapter
where the change is either of the following: (b) the nominal quantity of the substance or mixture in the
package made available to the general public, unless this
quantity is specified elsewhere on the package;
(a) a change in the composition of the initial concentration of
one or more of the hazardous constituents in concentra- (c) product identifiers as specified in Article 18;
tions at or above the limits in Table 1.2 of Part 1 of Annex I;
(d) where applicable, hazard pictograms in accordance with
Article 19;
(b) a change in the composition involving the substitution or
addition of one or more constituents in concentrations at
or above the cut-off value referred to in Article 11(3). (e) where applicable, signal words in accordance with
Article 20;
3. A new evaluation in accordance with paragraphs 1 and 2 (f) where applicable, hazard statements in accordance with
shall not be required if there is valid scientific justification that Article 21;
this will not result in a change of classification.
2. The product identifier for a substance shall consist of at least 2. Subject to Article 33, hazard pictograms shall fulfil the
the following: requirements laid down in section 1.2.1 of Annex I and in
Annex V.
(a) if the substance is included in Part 3 of Annex VI, a name
and an identification number as given therein; 3. The hazard pictogram relevant for each specific classification
is set out in the tables indicating the label elements required for
each hazard class in Annex I.
(b) if the substance is not included in Part 3 of Annex VI, but
appears in the classification and labelling inventory, a name Article 20
and an identification number as given therein;
Signal words
(c) if the substance is not included in Part 3 of Annex VI nor in
the classification and labelling inventory, the number 1. The label shall include the relevant signal word in
provided by the CAS (hereinafter referred to as ‘the CAS accordance with the classification of the hazardous substance
number’), together with the name set out in the or mixture.
nomenclature provided by the IUPAC (hereinafter referred
to as ‘the IUPAC Nomenclature’), or the CAS number 2. The signal word relevant for each specific classification is set
together with another international chemical name(s); or out in the tables indicating the label elements required for each
hazard class in Parts 2 to 5 of Annex I.
(d) if the CAS number is not available, the name set out in the
IUPAC Nomenclature or another international chemical 3. Where the signal word ‘Danger’ is used on the label, the
name(s). signal word ‘Warning’ shall not appear on the label.
Where the name in the IUPAC nomenclature exceeds 100 char- Article 21
acters, one of the other names (usual name, trade name,
abbreviation) referred to in section 2.1.2 of Annex VI to Hazard statements
Regulation (EC) No 1907/2006 may be used provided that the
notification in accordance with Article 40 includes both the 1. The label shall include the relevant hazard statements in
name set out in the IUPAC Nomenclature and the other name accordance with the classification of the hazardous substance or
used. mixture.
(a) the trade name or the designation of the mixture; 3. Where a substance is included in Part 3 of Annex VI, the
hazard statement relevant for each specific classification covered
by the entry in that Part shall be used on the label, together with
(b) the identity of all substances in the mixture that contribute the hazard statements referred to in paragraph 2 for any other
to the classification of the mixture as regards acute toxicity, classification not covered by that entry.
skin corrosion or serious eye damage, germ cell mutageni-
city, carcinogenicity, reproductive toxicity, respiratory or
skin sensitisation, specific target organ toxicity (STOT) or 4. The hazard statements shall be worded in accordance with
aspiration hazard. Annex III.
Article 22
Where, in the case referred to in (b), that requirement leads to the
provision of multiple chemical names, a maximum of four
chemical names shall suffice, unless more than four names are Precautionary statements
needed to reflect the nature and the severity of the hazards.
1. The label shall include the relevant precautionary state-
ments.
The chemical names selected shall identify the substances
primarily responsible for the major health hazards which have 2. The precautionary statements shall be selected from those
given rise to the classification and the choice of the correspond- set out in the tables in Parts 2 to 5 of Annex I indicating the label
ing hazard statements. elements for each hazard class.
A reduced fee shall be set for SMEs. 1. Statements shall be included in the section for supplemental
information on the label where a substance or mixture classified
as hazardous has the physical properties or health properties
3. The Agency may require further information from the referred to in sections 1.1 and 1.2 of Annex II.
manufacturer, importer or downstream user making the request
if such information is necessary to take a decision. If the Agency
raises no objection within six weeks of the request or the receipt
of further required information, the use of the requested name The statements shall be worded in accordance with sections 1.1
shall be deemed to be allowed. and 1.2 of Annex II and Part 2 of Annex III.
4. If the Agency does not accept the request, the practical Where a substance is included in Part 3 of Annex VI, any
arrangements referred to in Article 118(3) of Regulation (EC) supplemental hazard statements given therein for the substance
No 1907/2006 shall apply. shall be included in the supplemental information on the label.
L 353/18 EN Official Journal of the European Union 31.12.2008
2. A statement shall be included in the section for supple- (c) if the hazard pictogram ‘GHS05’ applies, the hazard
mental information on the label where a substance or mixture pictogram ‘GHS07’ shall not appear for skin or eye
classified as hazardous falls within the scope of Directive 91/ irritation;
414/EEC.
(a) if the hazard pictogram ‘GHS01’ applies, the use of the Article 29
hazard pictograms ‘GHS02’ and ‘GHS03’ shall be optional,
except in cases where more than one of these hazard Exemptions from labelling and packaging requirements
pictograms are compulsory;
1. Where the packaging of a substance or a mixture is either in
(b) if the hazard pictogram ‘GHS06’ applies, the hazard such a shape or form or is so small that it is impossible to meet
pictogram ‘GHS07’ shall not appear; the requirements of Article 31 for a label in the languages of the
31.12.2008 EN Official Journal of the European Union L 353/19
Member State in which the substance or mixture is placed on the 2. The colour and presentation of any label shall be such that
market, the label elements in accordance with the first the hazard pictogram stands out clearly.
subparagraph of Article 17(2) shall be provided in accordance
with section 1.5.1 of Annex I.
3. The label elements referred to in Article 17(1) shall be
clearly and indelibly marked. They shall stand out clearly from
2. If the full label information cannot be provided in the way the background and be of such size and spacing as to be easily
specified in paragraph 1 the label information may be reduced in read.
accordance with section 1.5.2 of Annex I.
4. The shape, colour and the size of a hazard pictogram as well
3. When a hazardous substance or mixture referred to in Part 5 as the dimensions of the label shall be as set out in section 1.2.1
of Annex II is supplied to the general public without packaging it of Annex I.
shall be accompanied by a copy of the label elements in
accordance with Article 17. 5. A label shall not be required when the label elements
referred to in Article 17(1) are shown clearly on the packaging
itself. In such cases, the requirements of this Chapter applicable
4. For certain mixtures classified as hazardous to the to a label shall be applied to the information shown on the
environment, exemptions to certain provisions on environmen- packaging.
tal labelling or specific provisions in relation to environmental
labelling may be determined in accordance with the procedure
referred to in Article 53, where it can be demonstrated that there Article 32
would be a reduction in the environmental impact. Such
exemptions or specific provisions are defined in Part 2 of Location of information on the label
Annex II.
1. The hazard pictograms, signal word, hazard statements and
precautionary statements shall be located together on the label.
5. The Commission may request the Agency to prepare and
submit to it further draft exemptions from labelling and
packaging requirements. 2. The supplier may decide the order of the hazard statements
on the label. However, subject to paragraph 4, all hazard
statements shall be grouped on the label by language.
Article 30
The supplier may decide the order of the precautionary
Updating information on labels
statements on the label. However, subject to paragraph 4, all
precautionary statements shall be grouped on the label by
1. The supplier shall ensure that the label is updated, without language.
undue delay, following any change to the classification and
labelling of that substance or mixture, where the new hazard is
more severe or where new supplemental labelling elements are 3. Groups of hazard statements and groups of precautionary
required under Article 25, taking into account the nature of the statements referred to in paragraph 2 shall be located together on
change as regards the protection of human health and the the label by language.
environment. Suppliers shall cooperate in accordance with
Article 4(9) to complete the changes to the labelling without 4. The supplemental information shall be placed in the
undue delay. supplemental information section referred to in Article 25, and
shall be located with the other label elements specified in
2. Where labelling changes are required other than those Article 17(1)(a) to (g).
referred to in paragraph 1, the supplier shall ensure that the label
is updated within 18 months. 5. In addition to its use in hazard pictograms, colour may be
used on other areas of the label to implement special labelling
requirements.
3. The supplier of a substance or a mixture within the scope of
Directives 91/414/EEC or 98/8/EC shall update the label in
accordance with those Directives. 6. Label elements resulting from the requirements provided for
in other Community acts shall be placed in the section for
supplemental information on the label referred to in Article 25.
CHAPTER 2
Article 33
Application of labels
Specific rules for labelling of outer packaging, inner
Article 31 packaging and single packaging
General rules for the application of labels 1. Where a package consists of an outer and an inner
packaging, together with any intermediate packaging, and the
1. Labels shall be firmly affixed to one or more surfaces of the outer packaging meets labelling provisions in accordance with
packaging immediately containing the substance or mixture and the rules on the transport of dangerous goods, the inner and any
shall be readable horizontally when the package is set down intermediate packaging shall be labelled in accordance with this
normally. Regulation. The outer packaging may also be labelled in
L 353/20 EN Official Journal of the European Union 31.12.2008
accordance with this Regulation. Where the hazard pictogram(s) (c) the packaging and fastenings shall be strong and solid
required by this Regulation relate to the same hazard as in the throughout to ensure that they will not loosen and will
rules for the transport of dangerous goods, the hazard picto- safely meet the normal stresses and strains of handling;
gram(s) required by this Regulation need not appear on the outer
packaging.
(d) packaging fitted with replaceable fastening devices shall be
designed so that it can be refastened repeatedly without the
2. Where the outer packaging of a package is not required to contents escaping.
meet labelling provisions in accordance with rules on the
transport of dangerous goods, both the outer and any inner
2. Packaging containing a hazardous substance or a mixture
packaging, including any intermediate packaging, shall be
supplied to the general public shall not have either a shape or
labelled in accordance with this Regulation. However, if the
design likely to attract or arouse the active curiosity of children
outer packaging permits the inner or intermediate packaging
or to mislead consumers, or have a similar presentation or a
labelling to be clearly seen, the outer packaging need not be
design used for foodstuff or animal feeding stuff or medicinal or
labelled.
cosmetic products, which would mislead consumers.
3. Single packages that meet the labelling provisions in Where the packaging contains a substance or mixture which
accordance with the rules on the transport of dangerous goods meets the requirements in section 3.1.1 of Annex II it shall have
shall be labelled both in accordance with this Regulation and the a child-resistant fastening in accordance with sections 3.1.2,
rules on the transport of dangerous goods. Where the hazard 3.1.3 and 3.1.4.2 of Annex II.
pictogram(s) required by this Regulation relate to the same
hazard as in rules on the transport of dangerous goods, the
hazard pictogram(s) required by this Regulation need not appear. Where the packaging contains a substance or mixture which
meets the requirements in section 3.2.1 of Annex II it shall bear a
tactile warning of danger in accordance with section 3.2.2 of
Article 34 Annex II.
Report on communication on safe use of chemicals 3. The packaging of substances and mixtures shall be deemed
to satisfy the requirements of paragraph 1(a), (b) and (c) if it
1. By 20 January 2012, the Agency shall carry out a study on complies with the requirements of the rules on the transport of
the communication of information to the general public on the dangerous goods by air, sea, road, rail or inland waterways.
safe use of substances and mixtures and the potential need for
additional information on labels. This study shall be carried out
in consultation with competent authorities and stakeholders and TITLE V
drawing as appropriate on relevant best practice.
HARMONISATION OF CLASSIFICATION AND LABELLING OF
SUBSTANCES AND THE CLASSIFICATION AND LABELLING
2. Without prejudice to the labelling rules provided for in this INVENTORY
Title, the Commission shall, on the basis of the study referred to
in paragraph 1, submit a report to the European Parliament and
the Council and, if justified, present a legislative proposal to CHAPTER 1
amend this Regulation.
Establishing harmonised classification and labelling of
substances
TITLE IV
Article 36
PACKAGING
Harmonisation of classification and labelling of substances
Article 35
1. A substance that fulfils the criteria set out in Annex I for the
following shall normally be subject to harmonised classification
Packaging and labelling in accordance with Article 37:
2. A substance that is an active substance in the meaning of 5. Where the Commission finds that the harmonisation of the
Directive 91/414/EEC or Directive 98/8/EC shall normally be classification and labelling of the substance concerned is
subject to harmonised classification and labelling. For such appropriate, it shall, without undue delay, submit a draft decision
substances, the procedures set out in Article 37, paragraphs 1, 4, concerning the inclusion of that substance together with the
5 and 6 shall apply. relevant classification and labelling elements in Table 3.1 of
Part 3 of Annex VI and, where appropriate, the specific
concentration limits or M-factors.
3. Where a substance fulfils the criteria for other hazard classes
or differentiations than those referred to in paragraph 1 and does
A corresponding entry shall be included in Table 3.2 of Part 3 of
not fall under paragraph 2, a harmonised classification and
Annex VI subject to the same conditions, until 31 May 2015.
labelling in accordance with Article 37 may also be added to
Annex VI on a case-by-case basis, if justification is provided
demonstrating the need for such action at Community level. That measure, designed to amend non-essential elements of this
Regulation, shall be adopted in accordance with the regulatory
procedure with scrutiny referred to in Article 54(3). On
Article 37 imperative grounds of urgency, the Commission may have
recourse to the urgency procedure referred to in Article 54(4).
Procedure for harmonisation of classification and labelling
of substances 6. Manufacturers, importers and downstream users who have
new information which may lead to a change of the harmonised
classification and labelling elements of a substance in Part 3 of
1. A competent authority may submit to the Agency a Annex VI shall submit a proposal in accordance with the second
proposal for harmonised classification and labelling of sub- subparagraph of paragraph 2 to the competent authority in one
stances and, where appropriate, specific concentration limits or of the Member States in which the substance is placed on the
M-factors, or a proposal for a revision thereof. market.
The proposal shall follow the format set out in Part 2 of Article 38
Annex VI and contain the relevant information provided for in
Part 1 of Annex VI. Content of opinions and decisions for harmonised
classification and labelling in Part 3 of Annex VI;
accessibility of information
2. A manufacturer, importer or downstream user of a
substance may submit to the Agency a proposal for harmonised 1. Any opinion referred to in Article 37(4) and any decision
classification and labelling of that substance and, where according to Article 37(5) shall at least specify for each
appropriate, specific concentration limits or M-factors, provided substance:
that there is no entry in Part 3 of Annex VI for such a substance
in relation to the hazard class or differentiation covered by that
proposal. (a) the identity of the substance as specified in sections 2.1 to
2.3.4 of Annex VI to Regulation (EC) No 1907/2006;
The proposal shall be drawn up in accordance with the relevant (b) the classification of the substance referred to in Article 36,
Parts of sections 1, 2 and 3 of Annex I to Regulation (EC) including a statement of reasons;
No 1907/2006 and it shall follow the format set out in Part B of
the Chemical Safety Report of section 7 of that Annex. It shall
contain the relevant information provided for in Part 1 of (c) the specific concentration limits or M-factors, where
Annex VI to this Regulation. Article 111 of Regulation (EC) applicable;
No 1907/2006 shall apply.
(d) the label elements specified in points (d), (e) and (f) of
3. Where the proposal of the manufacturer, importer or Article 17(1) for the substance, together with any
downstream user concerns the harmonised classification and supplemental hazard statements for the substance, deter-
labelling of a substance in accordance with Article 36(3), it shall mined in accordance with Article 25(1);
be accompanied by the fee determined by the Commission in
accordance with the regulatory procedure referred to in
(e) any other parameter enabling an assessment to be made of
Article 54(2).
the health or environmental hazard of mixtures containing
the hazardous substance in question or of substances
containing such hazardous substances as identified impu-
4. The Committee for Risk Assessment of the Agency set up rities, additives and constituents, if relevant.
pursuant to Article 76(1)(c) of Regulation (EC) No 1907/2006
shall adopt an opinion on any proposal submitted pursuant to
paragraphs 1 or 2 within 18 months of receipt of the proposal, 2. When making publicly available an opinion or a decision as
giving the parties concerned the opportunity to comment. The referred to in Article 37(4) and (5) of this Regulation, Arti-
Agency shall forward this opinion and any comments to the cle 118(2) and Article 119 of Regulation (EC) No 1907/2006
Commission. shall apply.
L 353/22 EN Official Journal of the European Union 31.12.2008
CHAPTER 2 The notifier shall submit this information in the format specified
pursuant to Article 111 of Regulation (EC) No 1907/2006.
Classification and labelling inventory
(b) whether, in respect of the entry, it is a joint entry between 2. The appointed bodies shall provide all requisite guarantees
registrants of the same substance as referred to in Arti- for maintaining the confidentiality of the information received.
cle 11(1) of Regulation (EC) No 1907/2006; Such information may only be used:
(c) whether it is an agreed entry of two or more notifiers or (a) to meet medical demand by formulating preventative and
registrants in accordance with Article 41; curative measures, in particular in the event of an
emergency;
The information referred to in (a) shall be updated where a (b) where requested by the Member State, to undertake
decision is taken in accordance with Article 37(5). statistical analysis to identify where improved risk manage-
ment measures may be needed.
TITLE VI
The information shall not be used for other purposes.
COMPETENT AUTHORITIES AND ENFORCEMENT
3. The appointed bodies shall have at their disposal all the
Article 43 information required from the importers and downstream users
responsible for marketing to carry out the tasks for which they
are responsible.
Appointment of competent authorities and enforcement
authorities and cooperation between authorities
4. By 20 January 2012 the Commission shall carry out a
Member States shall appoint the competent authority or review to assess the possibility of harmonising the information
competent authorities responsible for proposals for harmonised referred to in paragraph 1, including establishing a format for the
classification and labelling and the authorities responsible for the submission of information by importers and downstream users
enforcement of the obligations set out in this Regulation. to appointed bodies. On the basis of this review, and following
consultation with relevant stakeholders such as the European
Association of Poison Centres and Clinical Toxicologists
The competent authorities and the authorities responsible for (EAPCCT), the Commission may adopt a Regulation adding an
enforcement shall cooperate with each other in the performance Annex to this Regulation.
of their tasks under this Regulation and shall give the
corresponding authorities of other Member States all necessary
and useful support to this end. Those measures, designed to amend non-essential elements of
this Regulation, by supplementing it, shall be adopted in
accordance with the regulatory procedure with scrutiny referred
Article 44 to in Article 54(3).
Helpdesk
Article 46
Obligation to maintain information and requests for On grounds relating to the classification, labelling or packaging
information of substances and mixtures within the meaning of this
Regulation, Member States shall not prohibit, restrict or impede
1. The supplier shall assemble and keep available all the the placing on the market of substances or mixtures which
information used by that supplier for the purposes of comply with this Regulation and, where appropriate, with
classification and labelling under this Regulation for a period Community acts adopted in implementation of this Regulation.
of at least 10 years after the substance or the mixture was last
supplied by that supplier.
Article 52
The supplier shall keep this information together with the
information required in Article 36 of Regulation (EC) No 1907/ Safeguard clause
2006.
1. Where a Member State has justifiable grounds for believing
2. In the event of a supplier ceasing activity, or transferring that a substance or a mixture, although satisfying the
part or all of his operations to a third party, the party responsible requirements of this Regulation, constitutes a serious risk to
for liquidating the supplier's undertaking or assuming respon- human health or the environment due to reasons of classifica-
sibility for the placing on the market of the substance or mixture tion, labelling or packaging, it may take appropriate provisional
concerned shall be bound by the obligation in paragraph 1 in measures. The Member State shall immediately inform the
place of the supplier. Commission, the Agency and the other Member States thereof,
giving the reasons for its decision.
Committee procedure
4. Article 6 shall be replaced by the following:
1. The Commission shall be assisted by the Committee
instituted by Article 133 of Regulation (EC) No 1907/2006. ‘Article 6
4. Where reference is made to this paragraph, Article 5a(1), 5. Article 22(3) and (4) shall be deleted;
(2), (4) and (6) and Article 7 of Decision 1999/468/EC shall
apply, having regard to the provisions of Article 8 thereof.
6. Article 23(2) shall be amended as follows:
(c) in point (d), the words ‘Annex I’ shall be replaced by — point 2.1.1 (a) and (b),
‘Part 3 of Annex VI to Regulation (EC) No 1272/
2008’; — point 2.2 (a) and (b),
(d) in point (e), the words ‘Annex I’ shall be replaced by — point 2.3 (a) and (b),
‘Part 3 of Annex VI to Regulation (EC) No 1272/
2008’;
— point 3.1.1 (a) and (b),
(e) in point (f), the words ‘Annex I’ shall be replaced by — point 3.3 (a) and (b),
‘Part 3 of Annex VI of Regulation (EC) No 1272/
2008’;
— point 3.4 (a) and (b),
7. Article 24(4) second subparagraph shall be deleted;
— point 4.1.1 (a) and (b),
9. Article 31(2) and (3) shall be deleted; — point 5.1.1 (a) and (b),
10. the following Article shall be inserted after Article 32: — point 5.2.1 (a) and (b),
Transitional provision regarding labelling and — point 5.4.1 (a) and (b),
packaging of substances
Articles 22 to 25 shall not apply to substances from — point 6.1 (a) and (b),
1 December 2010.’;
— point 6.2 (a) and (b),
11. Annex I shall be deleted.
— point 7.1 (a) and (b),
Article 56
— point 7.2 (a) and (b),
Amendments to Directive 1999/45/EC
— point 8.1 (a) and (b),
Directive 1999/45/EC shall be amended as follows:
— point 8.2 (a) and (b),
1. in Article 3(2), first indent, the words ‘Annex I to Directive
67/548/EEC’ shall be replaced by ‘Part 3 of Annex VI to — point 9.1 (a) and (b),
Regulation (EC) No 1272/2008 of the European Parliament
and of the Council of 16 December 2008 on classification,
— point 9.2 (a) and (b),
labelling and packaging of substances and mixtures (*).
(c) Annex II, points (a) and (b) and the last paragraph of — point 2.1 (a) and (b),
the Introduction;
— point 3.1 (a) and (b),
(d) Annex II, Part A,
— point 4.1 (a) and (b),
— point 1.1.1 (a) and (b), — point 5.1 (a) and (b),
— point 1.2 (a) and (b), — point 6.1 (a) and (b),
31.12.2008 EN Official Journal of the European Union L 353/27
(h) Annex III, Part A, section (b) Non-aquatic environ- (ea) for substances classified as hazardous to the
ment point 1.1 (a) and (b); aquatic environment, if an M-factor has been
set in an agreed entry in the classification and
(i) Annex V, section A points 3 and 4; labelling inventory referred to in Article 42 of
Regulation (EC) No 1272/2008, the cut-off
value in Table 1.1 of Annex I to that Regulation
(j) Annex V, section B point 9; adjusted using the calculation set out in
section 4.1 of Annex I to that Regulation;’;
(k) Annex VI, Part A, the third column of the table under
point 2; 2. Article 31 shall be amended as follows:
(m) Annex VIII, Appendix 1, second column of the table; ‘8. A safety data sheet shall be provided free of
charge on paper or electronically no later than the
date on which the substance or mixture is first
(n) Annex VIII, Appendix 2, second column of the table; supplied.’;
3. in Annex VI, Part B, point 1, paragraph 3 first indent and (b) the following paragraph shall be added:
paragraph 5, the words ‘Annex I’ shall be replaced by ‘Part 3
of Annex VI to Regulation (EC) No 1272/2008’;
‘10. Where substances are classified in accordance
4. in Annex VI, Part B, point 4.2, final paragraph, the words with Regulation (EC) No 1272/2008 during the
‘Annex I to Directive 67/548/EEC (19th adaptation)’ shall period from its entry into force until 1 December
be replaced by ‘Part 3 of Annex VI to Regulation (EC) 2010, that classification may be added in the safety
No 1272/2008’. data sheet together with the classification in accor-
dance with Directive 67/548/EEC.
Article 57
From 1 December 2010 until 1 June 2015, the safety
Amendments to Regulation (EC) No 1907/2006 from the data sheets for substances shall contain the classifica-
entry into force of this Regulation tion according to both Directive 67/548/EEC and
Regulation (EC) No 1272/2008.
Regulation (EC) No 1907/2006 shall be amended as from the
entry into force of this Regulation as follows: Where mixtures are classified in accordance with
Regulation (EC) No 1272/2008 during the period
1. Article 14(2) shall be amended as follows: from its entry into force until 1 June 2015, that
classification may be added in the safety data sheet,
together with the classification in accordance with
(a) point (b) shall be replaced by the following:
Directive 1999/45/EC. However, until 1 June 2015,
where substances or mixtures are both classified and
‘(b) the specific concentration limits that have been labelled in accordance with Regulation (EC) No 1272/
set in Part 3 of Annex VI to Regula- 2008 that classification shall be provided in the safety
tion (EC) No 1272/2008 of the European data sheet, together with the classification in accor-
Parliament and of the Council of 16 December dance with Directives 67/548/EEC and 1999/45/EC
2008 on classification, labelling and packaging respectively, for the substance, the mixture and its
of substances and mixtures (*); constituents.’;
(ba) for substances classified as hazardous to the 3. Article 56(6)(b) shall be replaced by the following:
aquatic environment, if a multiplying factor
(hereinafter referred to as “M-factor”) has been
set in Part 3 of Annex VI to Regula- ‘(b) for all other substances, below the lowest of the
tion (EC) No 1272/2008, the cut-off value in concentration limits specified in Directive 1999/45/
Table 1.1 of Annex I to that Regulation EC or in Part 3 of Annex VI to Regula-
adjusted using the calculation set out in tion (EC) No 1272/2008 which result in the
section 4.1 of Annex I to that Regulation; classification of the mixture as dangerous.’;
(*) OJ L 353, 31.12.2008, p. 1’; 4. Article 59(2) and 3 shall be amended as follows:
(b) point (e) shall be replaced by the following: (a) in paragraph 2, the second sentence shall be replaced
by the following:
‘(e) the specific concentration limits given in an
agreed entry in the classification and labelling ‘The dossier may be limited, if appropriate, to a
inventory referred to in Article 42 of Regula- reference to an entry in Part 3 of Annex VI to
tion (EC) No 1272/2008; Regulation (EC) No 1272/2008.’;
L 353/28 EN Official Journal of the European Union 31.12.2008
(b) in paragraph 3, the second sentence shall be replaced 2008 classified as germ cell mutagen
by the following: category 1A or 1B (Table 3.1) or mutagen
category 1 or 2 (Table 3.2) and listed as
‘The dossier may be limited, if appropriate, to a follows:
reference to an entry in Part 3 of Annex VI to
Regulation (EC) No 1272/2008.’; — Mutagen category 1A (Table 3.1)/
mutagen category 1 (Table 3.2) listed
5. in Article 76(1)(c), the words ‘Title XI’ shall be replaced by in Appendix 3
‘Title V of Regulation (EC) No 1272/2008’;
— Mutagen category 1B (Table 3.1)/
6. Article 77 shall be amended as follows: mutagen category 2 (Table 3.2) listed
in Appendix 4
(a) in paragraph 2, the first sentence of point (e) shall be
replaced by the following:
30. Substances which appear in Part 3 of
Annex VI to Regulation (EC) No 1272/
‘(e) establishing and maintaining database(s) with
2008 classified as toxic to reproduction
information on all registered substances, the
category 1A or 1B (Table 3.1) or toxic to
classification and labelling inventory and the
reproduction category 1 or 2 (Table 3.2)
harmonised classification and labelling list
and listed as follows:
established in accordance with Regula-
tion (EC) No 1272/2008;’;
— Reproductive toxicant category 1A
(b) in paragraph 3, point (a), the words ‘Titles VI to XI’ adverse effects on sexual function
shall be replaced by ‘Titles VI to X’; and fertility or on development (Table
3.1) or reproductive toxicant cate-
7. Title XI shall be deleted; gory 1 with R60 (May impair fertility)
or R61 (May cause harm to the
8. Annex XV, sections I and II shall be amended as follows: unborn child) (Table 3.2) listed in
Appendix 5
(a) section I shall be amended as follows:
— Reproductive toxicant category 1B
(i) the first indent shall be deleted; adverse effects on sexual function
and fertility or on development (Table
(ii) the second indent shall be replaced by the 3.1) or reproductive toxicant cate-
following: gory 2 with R60 (May impair fertility)
or R61 (May cause harm to the
‘— the identification of CMRs, PBTs, vPvBs, or unborn child) (Table 3.2) listed in
a substance of equivalent concern in Appendix 6’;
accordance with Article 59,’;
(b) in the column ‘Conditions of restriction’, in entry 28,
(b) in section II, point 1 shall be deleted; the first indent of point 1 shall be replaced by the
following:
9. the table in Annex XVII shall be amended as follows:
‘— either the relevant specific concentration limit
(a) the column ‘Designation of the substance, of the specified in Part 3 of Annex VI to Regula-
groups of substances or of the preparation’, shall be tion (EC) No 1272/2008, or’;
amended as follows:
10. Appendices 1 to 6 to Annex XVII shall be amended as
(i) entries 28, 29 and 30 shall be replaced by the follows:
following:
(a) the Foreword shall be amended as follows:
‘28. Substances which appear in Part 3 of
Annex VI to Regulation (EC) No 1272/
2008 classified as carcinogen category 1A (i) in the section entitled ‘Substances’, the words
or 1B (Table 3.1) or carcinogen category 1 ‘Annex I to Directive 67/548/EEC’ shall be
or 2 (Table 3.2) and listed as follows: replaced by ‘Part 3 of Annex VI to Regula-
tion (EC) No 1272/2008’;
— Carcinogen category 1A (Table 3.1)/
carcinogen category 1 (Table 3.2) (ii) in the section entitled ‘Index number’, the words
listed in Appendix 1 ‘Annex I to Directive 67/548/EEC’ shall be
replaced by ‘Part 3 of Annex VI to Regula-
— Carcinogen category 1B (Table 3.1)/ tion (EC) No 1272/2008’;
carcinogen category 2 (Table 3.2)
listed in Appendix 2 (iii) in the section entitled ‘Notes’, the words ‘the
foreword of Annex I to Directive 67/548/EEC’
29. Substances which appear in Part 3 of shall be replaced by ‘Part 1 of Annex VI to
Annex VI to Regulation (EC) No 1272/ Regulation (EC) No 1272/2008’;
31.12.2008 EN Official Journal of the European Union L 353/29
(iv) Note A shall be replaced by the following: Part 3 of Annex VI to Regulation (EC) No 1272/
2008.
‘Note A:
However, such substances are sometimes placed
Without prejudice to Article 17(2) of Regulation on the market in a non-stabilised form. In this
(EC) No 1272/2008, the name of the substance case, the supplier who places such a substance
must appear on the label in the form of one of on the market must state on the label the name
the designations given in Part 3 of Annex VI to of the substance followed by the words “non-
that Regulation. stabilised”.’;
(v) Note D shall be replaced by the following: ‘Point 28 — Carcinogens: category 1A (Table 3.1)/
category 1 (Table 3.2)’;
‘Note D:
(c) Appendix 2 shall be amended as follows:
Certain substances which are susceptible to
spontaneous polymerisation or decomposition (i) the title shall be replaced by ‘Point 28 —
are generally placed on the market in a stabilised Carcinogens: category 1B (Table 3.1)/ category 2
form. It is in this form that they are listed in (Table 3.2)’;
L 353/30 EN Official Journal of the European Union 31.12.2008
(ii) in the entries index Nos 024-017-00-8, 611- or is assessed to be a PBT or vPvB, the chemical safety
024-001, 611-029-00-9, 611-030-00-4 and assessment shall include the following additional steps:’;
650-017-00-8, the words ‘Annex I to Direc-
tive 67/548/EEC’ shall be replaced by ‘Annex VI 2. Article 31 shall be amended as follows
to Regulation (EC) No 1272/2008.’;
‘Point 30 — Reproductive toxicants: category 1B ‘1. The Agency shall examine any testing proposal set out
(Table 3.1)/category 2 (Table 3.2)’; in a registration or a downstream user report for provision
of the information specified in Annexes IX and X for a
11. the word ‘preparation’ or ‘preparations’ within the meaning substance. Priority shall be given to registrations of
of Article 3 (2) of Regulation (EC) 1907/2006 shall be substances which have or may have PBT, vPvB, sensitising
replaced by ‘mixture’ or ‘mixtures’ respectively throughout and/or carcinogenic, mutagenic or toxic for reproduction
the text. (CMR) properties, or substances above 100 tonnes per year
with uses resulting in widespread and diffuse exposure,
Article 58 provided they fulfil the criteria for any of the following
hazard classes or categories set out in Annex I of
Amendments to Regulation (EC) No 1907/2006 from Regulation (EC) No 1272/2008:
1 December 2010
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and
Regulation (EC) No 1907/2006 shall be amended from B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14
1 December 2010 as follows: categories 1 and 2, 2.15 types A to F;
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and 4. Article 57(a), (b) and (c) shall be replaced by the following:
B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14
categories 1 and 2, 2.15 types A to F;
‘(a) substances meeting the criteria for classification in the
hazard class carcinogenicity category 1A or 1B in
(b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual accordance with section 3.6 of Annex I to Regula-
function and fertility or on development, 3.8 effects tion (EC) No 1272/2008;
other than narcotic effects, 3.9 and 3.10;
(b) substances meeting the criteria for classification in the
(c) hazard class 4.1; hazard class germ cell mutagenicity category 1A or 1B
in accordance with section 3.5 of Annex I to
(d) hazard class 5.1, Regulation (EC) No 1272/2008;
31.12.2008 EN Official Journal of the European Union L 353/31
(c) substances meeting the criteria for classification in the (ii) in point (g), the introductory phrase shall be
hazard class reproductive toxicity category 1A or 1B, replaced by the following:
adverse effects on sexual function and fertility or on
development in accordance with section 3.7 of
Annex I to Regulation(EC) No 1272/2008;’; ‘(g) subject to Article 24 of Regulation (EC)
No 1272/2008, the name in the IUPAC
nomenclature for substances referred to in
5. in Article 65 the words ‘Directive 67/548/EEC’ shall be paragraph 1(a) of this Article that are only
replaced by ‘Directive 67/548/EEC and Regulation (EC) used as one or more of the following:’;
No 1272/2008’;
8. in Article 138(1), the second sentence of the introductory
6. Article 68(2) shall be replaced by the following: phrase shall be replaced by the following:
4.3 Specific concentration limits, where applicable, result- 14. Annex X shall be amended as follows:
ing from the application of Article 10 of Regulation
(EC) No 1272/2008 and Articles 4 to 7 of
Directive 1999/45/EC.’;
(a) in column 2, point 8.7, the second and third
paragraphs shall be replaced by the following:
‘If a substance is known to have an adverse effect on 15. in Annex XIII, the second and third indents of point 1.3
fertility, meeting the criteria for classification as toxic for shall be replaced by the following:
reproduction category 1A or 1B: May damage fertility
(H360F), and the available data are adequate to support a
robust risk assessment, then no further testing for fertility ‘— the substance is classified as carcinogenic (category 1A
will be necessary. However, testing for developmental or 1B), germ cell mutagenic (category 1A or 1B), or
toxicity must be considered. toxic for reproduction (category 1A, 1B or 2), or
If a substance is known to cause developmental toxicity, — there is other evidence of chronic toxicity, as identified
meeting the criteria for classification as toxic for reproduc- by the classifications STOT (repeated exposure),
tion category 1A or 1B: May damage the unborn child category 1 (oral, dermal, inhalation of gases/vapours,
(H360D), and the available data are adequate to support a inhalation of dust/mist/fume) or category 2 (oral,
robust risk assessment, then no further testing for dermal, inhalation of gases/vapours, inhalation of
developmental toxicity will be necessary. However, testing dust/mist/fume) according to Regulation (EC) No 1272/
for effects on fertility must be considered.’; 2008’;
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16. in the table in Annex XVII, the column ‘Designation of the 2. Article 31 shall be amended as follows:
substance, of the groups of substances or of the mixture’
shall be amended as follows:
(a) in paragraph 1, point (a) shall be replaced by the
following:
(a) entry 3 shall be replaced by the following:
Regulation (EC) No 1907/2006 shall be amended from 1 June (c) paragraph 4 shall be replaced by the following:
2015 as follows:
‘4. The safety data sheet need not be supplied where
1. Article 14(2) shall be replaced by the following: hazardous substances or mixtures offered or sold to
the general public are provided with sufficient
information to enable users to take the necessary
‘2. A chemical safety assessment in accordance with measures as regards the protection of human health,
paragraph 1 need not be performed for a substance which safety and the environment, unless requested by a
is present in a mixture if the concentration of the substance downstream user or distributor.’;
in the mixture is less than
4. in Article 65 the words ‘and Directive 1999/45/EC’ shall be (ii) point 2 (d) shall be replaced by the following:
deleted;
(b) footnote 1 to point 3.3(a), first indent, shall be deleted; 1. Until 1 December 2010, substances shall be classified,
labelled and packaged in accordance with Directive 67/548/EEC.
(c) point 3.6 shall be replaced by:
(i) the second indent of point 1 shall be replaced by 5. Where a substance or mixture has been classified in
the following: accordance with Directive 67/548/EEC or 1999/45/EC before
1 December 2010 or 1 June 2015 respectively, manufacturers,
‘— the relevant generic concentration limit importers and downstream users may amend the classification of
specified in Part 3 of Annex I of Regula- the substance or mixture using the conversion table in Annex VII
tion (EC) No 1272/2008.’; to this Regulation.
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6. Until 1 December 2011 a Member State may maintain any If the proposed harmonised classification and labelling submitted
existing and more stringent classification and labelling of under the first subparagraph is not included or is included in an
substances entered into Part 3 of Annex VI to this Regulation, amended form in Part 3 of Annex VI in accordance with
provided that these classifications and labelling elements have Article 37(5), the exemption in the first subparagraph of this
been notified to the Commission in accordance with the paragraph is no longer valid.
safeguard clause in Directive 67/548/EEC before 20 January
2009 and that the Member State submits a proposal for Article 62
harmonised classification and labelling containing these classi-
fications and labelling elements to the Agency in accordance Entry into force
with Article 37(1) of this Regulation by 1 June 2009.
This Regulation shall enter into force on the 20th day following
It is a precondition that a decision on the proposed classification its publication in the Official Journal of the European Union.
and labelling by the Commission in accordance with the
safeguard clause of Directive 67/548/EEC has not yet been Titles II, III and IV shall apply in respect of substances from
taken before 20 January 2009. 1 December 2010 and in respect of mixtures from 1 June 2015.
This Regulation shall be binding in its entirety and directly applicable in all Member States.
ANNEX I
This annex sets out the criteria for classification in hazard classes and in their differentiations and sets out additional
provisions on how the criteria may be met.
1.0. Definitions
(i) at 50 oC has a vapour pressure of not more than 300 kPa (3 bar);
(ii) is not completely gaseous at 20 oC and at a standard pressure of 101,3 kPa; and
(iii) which has a melting point or initial melting point of 20 oC or less at a standard pressure of 101,3 kPa;
Solid means a substance or mixture which does not meet the definitions of liquid or gas.
Suppliers in a supply chain shall cooperate to meet the requirements for classification, labelling and packaging
set out in this Regulation.
Suppliers in an industry sector may cooperate to manage the transitional arrangements in Article 61 for
substances and mixtures placed on the market.
Suppliers in an industry sector may cooperate through formation of a network or by other means to share
data and expertise when classifying substances and mixtures in accordance with Title II of this Regulation. In
these circumstances suppliers in an industry sector shall document fully the basis on which classification
decisions are made and shall make available to the competent authorities and, on request, to the relevant
enforcement authorities the documentation, together with the data and information on which classifications
are based. However, where suppliers in an industry sector cooperate in this way, each supplier shall remain
fully responsible for the classification, labelling and packaging of substances and mixtures he places on the
market, and for meeting any other requirements of this Regulation.
The network may also be used to exchange information and best practices with a view to simplifying
fulfilment of the notification obligations.
1.1.1. The role and application of expert judgement and weight of evidence determination
1.1.1.1. Where the criteria cannot be applied directly to available identified information, or where only the
information referred to in Article 6(5) is available, the weight of evidence determination using expert
judgment shall be applied in accordance with Article 9(3) or 9(4) respectively.
1.1.1.2. The approach to classifying mixtures may include the application of expert judgement in a number of areas in
order to ensure existing information can be used for as many mixtures as possible in order to provide
protection for human health and the environment. Expert judgement may also be required in interpreting
data for hazard classification of substances, especially where weight of evidence determinations are needed.
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1.1.1.3. A weight of evidence determination means that all available information bearing on the determination of
hazard is considered together, such as the results of suitable in vitro tests, relevant animal data, information
from the application of the category approach (grouping, read-across), (Q)SAR results, human experience
such as occupational data and data from accident databases, epidemiological and clinical studies and well-
documented case reports and observations. The quality and consistency of the data shall be given appropriate
weight. Information on substances or mixtures related to the substance or mixture being classified shall be
considered as appropriate, as well as site of action and mechanism or mode of action study results. Both
positive and negative results shall be assembled together in a single weight of evidence determination.
1.1.1.4. For the purpose of classification for health hazards (Part 3) established hazardous effects seen in appropriate
animal studies or from human experience that are consistent with the criteria for classification shall normally
justify classification. Where evidence is available from both humans and animals and there is a conflict
between the findings, the quality and reliability of the evidence from both sources shall be evaluated in order
to resolve the question of classification. Generally, adequate, reliable and representative data on humans
(including epidemiological studies, scientifically valid case studies as specified in this Annex or statistically
backed experience) shall have precedence over other data. However, even well-designed and conducted
epidemiological studies may lack a sufficient number of subjects to detect relatively rare but still significant
effects, to assess potentially confounding factors. Therefore, positive results from well-conducted animal
studies are not necessarily negated by the lack of positive human experience but require an assessment of the
robustness, quality and statistical power of both the human and animal data.
1.1.1.5. For the purpose of classification for health hazards (Part 3) route of exposure, mechanistic information and
metabolism studies are pertinent to determining the relevance of an effect in humans. When such
information, as far as there is reassurance about the robustness and quality of the data, raises doubt about
relevance in humans, a lower classification may be warranted. When there is scientific evidence that the
mechanism or mode of action is not relevant to humans, the substance or mixture should not be classified.
1.1.2.1. Specific concentration limits or M-factors shall be applied in accordance with Article 10.
1.1.2.2.1. Cut-off values indicate when the presence of a substance needs to be taken into account for the purposes of
classification of a substance or a mixture containing that hazardous substance, whether as an identified
impurity, additive, or individual constituent (see Article 11).
(a) For health and environmental hazards in Parts 3, 4 and 5 of this Annex:
(i) for substances where a specific concentration limit is set for the relevant hazard class or
differentiation either in Part 3 of Annex VI or in the classification and labelling inventory referred
to in Article 42, and where the hazard class or differentiation is mentioned in Table 1.1, the lower
of the specific concentration limit and the relevant generic cut-off value in Table 1.1; or
(ii) for substances where a specific concentration limit is set for the relevant hazard class or
differentiation either in Part 3 of Annex VI or in the classification and labelling inventory referred
to in Article 42, and where the hazard class or differentiation is not mentioned in Table 1.1, the
specific concentration limit set either in Part 3 of Annex VI or in the classification and labelling
inventory; or
(iii) for substances where no specific concentration limit is set for the relevant hazard class or
differentiation either in Part 3 of Annex VI or in the classification and labelling inventory referred
to in Article 42, and where the hazard class or differentiation is mentioned in Table 1.1, the
relevant generic cut-off value set out in that table; or
(iv) for substances where no specific concentration limit is set for the relevant hazard class or
differentiation either in Part 3 of Annex VI or in the classification and labelling inventory referred
to in Article 42, and where the hazard class or differentiation is not mentioned in Table 1.1, the
generic concentration limit for classification in the relevant sections of Parts 3, 4 and 5 of this
Annex.
L 353/38 EN Official Journal of the European Union 31.12.2008
(i) for substances where an M-factor has been set for the relevant hazard category either in Part 3 of
Annex VI, or in the classification and labelling inventory referred to in Article 42, the generic cut-
off value in Table 1.1 adjusted using the calculation set out in section 4.1 of this Annex; or
(ii) for substances where no M-factor is set for the relevant hazard category either in Part 3 of
Annex VI or in the classification and labelling inventory referred to in Article 42, the relevant
generic cut-off value set out in Table 1.1.
Table 1.1
Note
Generic cut-off values are in weight percentages except for gaseous mixtures where they are in
volume percentage.
1.1.3. Bridging principles for the classification of mixtures where test data are not available for the complete
mixture
Where the mixture itself has not been tested to determine its hazardous properties, but there are sufficient
data on similar tested mixtures and individual hazardous ingredient substances to adequately characterise the
hazards of the mixture, these data shall be used in accordance with the following bridging rules referred to in
Article 9(4) for each individual hazard class in Part 3 and Part 4 of this Annex, subject to any specific
provisions for mixtures in each hazard class.
1.1.3.1. Dilution
If a mixture is diluted with a substance (diluent) which has an equivalent or lower hazard category
classification than the least hazardous original ingredient substance and which is not expected to affect the
hazard classification of other ingredient substances, then one of the following shall be applied:
— the method explained in each section of Part 3 and in Part 4 for classification of mixtures when data are
available for all components or only some components of the mixture;
— in the case of acute toxicity, the method for classification of mixtures based on ingredients of the
mixture (additivity formula).
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1.1.3.2. Batching
The hazard category of one production batch of a mixture can be assumed to be substantially equivalent to
that of another production batch of the same commercial product, and produced by or under the control of
the same supplier, unless there is reason to believe there is significant variation such that the hazard
classification of the batch has changed. If the latter occurs, a new evaluation is necessary.
In the case of the classification of mixtures covered by sections 3.1, 3.2, 3.3, 3.8, 3.9, 3.10 and 4.1, if a
mixture is classified in the highest hazard category or sub-category, and the concentration of the ingredients
of the mixture that are in that category or sub-category is increased, the new mixture shall be classified in that
category or sub-category without additional testing.
In the case of the classification of mixtures covered by sections 3.1, 3.2, 3.3, 3.8, 3.9, 3.10 and 4.1, for three
mixtures with identical hazardous ingredients, where mixtures A and B are in the same hazard category and
mixture C has the same active hazardous ingredients with concentrations intermediate to the concentrations
of those hazardous ingredients in mixtures A and B, then mixture C is assumed to be in the same hazard
category as A and B.
(i) A+B
(ii) C + B;
(c) the concentration of ingredient A in mixture (i) equals that of ingredient C in mixture (ii);
(d) hazard data for A and C are available and substantially equivalent, i.e. they are in the same hazard
category and are not expected to affect the hazard classification of B.
If mixture (i) is already classified in a particular hazard class based on test data, mixture (ii) shall be assigned
the same hazard category.
The following variations in initial concentration are defined for the application of Article 15(2)(a):
Table 1.2
1.1.3.7. Aerosols
In the case of the classification of mixtures covered by sections 3.1, 3.2, 3.3, 3.4, 3.8 and 3.9, an aerosol form
of a mixture shall be classified in the same hazard category as the non-aerosolised form of the mixture,
provided that the added propellant does not affect the hazardous properties of the mixture upon spraying and
scientific evidence is available demonstrating that the aerosolised form is not more hazardous than the
nonaerosolised form.
1.2. Labelling
1.2.1.1. Hazard pictograms as laid down in Annex V shall have a black symbol on a white background with a red
frame sufficiently wide to be clearly visible.
1.2.1.2. Hazard pictograms shall be in the shape of a square set at a point. Each hazard pictogram shall cover at least
one fifteenth of the surface area of the harmonised label but the minimum area shall not be less than 1 cm 2.
Table 1.3
Dimension of labels
For transportable gas cylinders, one of the following shall be permitted to be used for gas cylinders with a
water capacity of less than or equal to 150 litres:
(a) A format and dimensions following the prescriptions of the current edition of Standard ISO 7225
relating to ‘Gas cylinders — Precautionary labels’. In this case, the label can bear the generic name or
industrial or commercial name of the substance or mixture provided that the hazardous substances in a
mixture are shown on the body of the gas cylinder in a clear and indelible way.
(b) The information specified in Article 17 provided on a durable information disc or label held captive on
the cylinder.
1.3.2. Gas containers intended for propane, butane or liquefied petroleum gas (LPG)
1.3.2.1. If propane, butane and liquefied petroleum gas or a mixture containing these substances classified in
accordance with the criteria of this Annex, is placed on the market in closed refillable cylinders or in non-
refillable cartridges within the scope of EN 417 as fuel gases which are only released for combustion (current
edition of EN 417, relating to ‘Non-refillable metallic gas cartridges for liquefied petroleum gases, with or
without a valve, for use with portable appliances; construction, inspection, testing and marking’), these
cylinders or cartridges shall only be labelled with the appropriate pictogram and the hazard and
precautionary statements concerning flammability.
1.3.2.2. No information concerning the effects on human health and the environment is required on the label. Instead
the supplier shall provide the information concerning effects on human health and the environment to
downstream users or distributors by means of the safety data sheet (SDS).
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1.3.2.3. For consumers, sufficient information shall be transmitted to enable them to take all necessary measures for
health and safety.
1.3.3. Aerosols and containers fitted with a sealed spray attachment and containing substances or mixtures
classified as presenting an aspiration hazard
With regard to the application of section 3.10.4, substances or mixtures classified in accordance with the
criteria of sections 3.10.2 and 3.10.3 need not be labelled for this hazard when placed on the market in
aerosol containers or in containers fitted with a sealed spray attachment.
1.3.4. Metals in massive form, alloys, mixtures containing polymers, mixtures containing elastomers
1.3.4.1. Metals in massive form, alloys, mixtures containing polymers and mixtures containing elastomers do not
require a label according to this Annex, if they do not present a hazard to human health by inhalation,
ingestion or contact with skin or to the aquatic environment in the form in which they are placed on the
market, although classified as hazardous in accordance with the criteria of this Annex.
1.3.4.2. Instead, the supplier shall provide the information to downstream users or distributors by means of the SDS.
1.3.5. Explosives placed on the market with a view to obtaining an explosive or pyrotechnic effect
Explosives, as referred to in section 2.1, placed on the market with a view to obtaining an explosive or
pyrotechnic effect shall be labelled and packaged in accordance with the requirements for explosives only.
1.4.1. Requests for use of an alternative chemical name under Article 24 may be granted only where
(I) the substance has not been assigned a Community workplace exposure limit; and
(II) the manufacturer, importer or downstream user can demonstrate that the use of the alternative
chemical name meets the need to provide enough information for necessary health and safety
precautions to be taken in the workplace and the need to ensure that risks from handling the mixture
can be controlled; and
(III) the substance is classified exclusively as one or more of the following hazard categories:
1.4.2. The choice of the chemical name(s) for mixtures intended for the fragrance or perfume industry
In the case of substances occurring in nature, a chemical name or chemical names of the type ‘essential oil of
…’ or ‘extract of …’ may be used instead of the chemical names of the components of that essential oil or
extract as referred to in Article 18(3)(b).
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1.5.1.1. Where Article 29(1) applies, the label elements mentioned in Article 17 may be provided in one of the
following ways:
1.5.1.2. The label on any inner packaging shall contain at least hazard pictograms, the product identifier referred to in
Article 18 and name and telephone number of the supplier of the substance or mixture.
1.5.2.1.1. The hazard statements and the precautionary statements linked to the hazard categories listed below may be
omitted from the label elements required by Article 17 where:
(a) the contents of the package do not exceed 125 ml; and
(b) the substance or mixture is classified in one or more of the following hazard categories:
7) Substances and mixtures which, in contact with water, emit flammable gases of categories 1, 2
or 3;
11) Acute toxicity of category 4, if the substances or mixtures are not supplied to the general public;
14) Specific target organ toxicity — single exposure of category 2 or 3, if the substance or mixture is
not supplied to the general public;
15) Specific target organ toxicity — repeated exposure of category 2, if the substance or mixture is
not supplied to the general public;
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The exemptions for labelling of small packages of aerosols as flammable laid down in Directive 75/324/
EEC shall apply to aerosol dispensers.
1.5.2.1.2. The precautionary statements linked to the hazard categories listed below may be omitted from the label
elements required by Article 17 where:
(a) the contents of the package do not exceed 125 ml; and
(b) the substance or mixture is classified in one or more of the following hazard categories:
1.5.2.1.3. The pictogram, the hazard statement and the precautionary statement linked to the hazard categories listed
below may be omitted from the label elements required by Article 17 where:
(a) the contents of the package do not exceed 125 ml; and
(b) the substance or mixture is classified in one or more of the following hazard categories:
1) Corrosive to metals.
The label elements required by Article 17 may be omitted from soluble packaging intended for single use
where:
(a) The content of each soluble packaging does not exceed a volume of 25 ml;
(b) The classification of the contents of the soluble packaging is exclusively one or more of the hazard
categories in 1.5.2.1.1 (b); and
(c) The soluble packaging is contained within outer packaging that fully meets the requirements of
Article 17.
1.5.2.3. Section 1.5.2.2 shall not apply to substances or mixtures within the scope of Directives 91/414/EEC or
98/8/EC.
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2.1. Explosives
2.1.1. Definitions
(b) explosive articles, except devices containing explosive substances or mixtures in such quantity or of
such a character that their inadvertent or accidental ignition or initiation shall not cause any effect
external to the device either by projection, fire, smoke, heat or loud noise; and
(c) substances, mixtures and articles not mentioned in points (a) and (b) which are manufactured with a
view to producing a practical, explosive or pyrotechnic effect.
2.1.1.2. For the purposes of this Regulation the following definitions shall apply:
An explosive substance or mixture is a solid or liquid substance or mixture of substances which is in itself
capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to
cause damage to the surroundings. Pyrotechnic substances are included even when they do not evolve gases.
An unstable explosive is an explosive substance or mixture which is thermally unstable and/or too sensitive
for normal handling, transport and use.
An intentional explosive is a substance, mixture or article which is manufactured with a view to producing a
practical, explosive or pyrotechnic effect.
2.1.2.1. Substances, mixtures and articles of this class are classified as an unstable explosive on the basis of the
flowchart in Figure 2.1.2. The test methods are described in Part I of the UN Recommendations on the
Transport of Dangerous Goods, Manual of Tests and Criteria.
2.1.2.2. Substances, mixtures and articles of this class, which are not classified as an unstable explosive, shall be
assigned to one of the following six divisions depending on the type of hazard they present:
(a) Division 1.1 Substances, mixtures and articles which have a mass explosion hazard (a mass explosion is
one which affects almost the entire quantity present virtually instantaneously);
(b) Division 1.2 Substances, mixtures and articles which have a projection hazard but not a mass explosion
hazard;
(c) Division 1.3 Substances, mixtures and articles which have a fire hazard and either a minor blast hazard
or a minor projection hazard or both, but not a mass explosion hazard:
(ii) which burn one after another, producing minor blast or projection effects or both;
31.12.2008 EN Official Journal of the European Union L 353/45
(d) Division 1.4 Substances, mixtures and articles which present no significant hazard:
— substances, mixtures and articles which present only a small hazard in the event of ignition or
initiation. The effects are largely confined to the package and no projection of fragments of
appreciable size or range is to be expected. An external fire shall not cause virtually instantaneous
explosion of almost the entire contents of the package;
(e) Division 1.5 Very insensitive substances or mixtures which have a mass explosion hazard:
— substances and mixtures which have a mass explosion hazard but are so insensitive that there is
very little probability of initiation or of transition from burning to detonation under normal
conditions;
(f) Division 1.6 Extremely insensitive articles which do not have a mass explosion hazard:
— articles which contain only extremely insensitive detonating substances or mixtures and which
demonstrate a negligible probability of accidental initiation or propagation.
2.1.2.3. Explosives, which are not classified as an unstable explosive, shall be classified in one of the six divisions
referred to in paragraph 2.1.2.2 of this Annex based on Test Series 2 to 8 in Part I of the UN
Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria according to the
results of the tests laid down in Table 2.1.1:
Table 2.1.1
Category Criteria
For explosives of Divisions 1.1 to 1.6, the following are the core set of
tests that need to be performed:
Explosibility: according to UN Test Series 2 (section 12 of the UN
Recommendations on the Transport of Dangerous Goods, Manual of
Tests and Criteria). Intentional explosives (1) shall not be subject to UN
Test Series 2.
Unstable explosives or explosives Sensitiveness: according to UN Test Series 3 (section 13 of the UN
of Divisions 1.1 to 1.6 Recommendations on the Transport of Dangerous Goods, Manual of
Tests and Criteria).
Thermal stability: according to UN Test 3(c) (sub-section 13.6.1 of the
UN Recommendations on the Transport of Dangerous Goods, Manual
of Tests and Criteria).
Further tests are necessary to allocate the correct Division.
(1) This comprises substances, mixtures and articles which are manufactured with a view to producing a practical, explosive
or pyrotechnic effect.
2.1.2.4. If explosives are unpackaged or repacked in packaging other than the original or similar packaging, they shall
be retested.
NOTE to Table 2.1.2: Unpackaged explosives or explosives repacked in packaging other than the original or
similar packaging shall include all of the following label elements:
unless the hazard is shown to correspond to one of the hazard categories in Table 2.1.2, in which case the
corresponding symbol, the signal word and/or the hazard statement shall be assigned.
Table 2.1.2
L 353/46
Label elements for explosives
Classification Unstable Explosive Division 1.1 Division 1.2 Division 1.3 Division 1.4 Division 1.5 Division 1.6
GHS Pictograms
EN
Signal Word Danger Danger Danger Danger Warning Danger No signal word
Hazard Statement H200: Unstable Explo- H201: Explosive; mass H202: Explosive; severe H203: Explosive; fire, H204: Fire or projec- H205: May mass No hazard statement
sive explosion hazard projection hazard blast or projection tion hazard explode in fire
hazard
Precautionary Statement P201 P210 P210 P210 P210 P210 No precautionary state-
Prevention P202 P230 P230 P230 P240 P230 ment
Precautionary Statement P372 P370+P380 P370+P380 P370+P380 P370+P380 P370+P380 No precautionary state-
Response P373 P372 P372 P372 P372 P372 ment
P380 P373 P373 P373 P373 P373
Precautionary Statement P401 P401 P401 P401 P401 P401 No precautionary state-
Storage ment
Precautionary Statement P501 P501 P501 P501 P501 P501 No precautionary state-
Disposal ment
31.12.2008
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2.1.4.1. The classification of substances, mixtures and articles in the explosives hazard class and further allocation to a
division is a very complex, three step procedure. Reference to Part I of the UN Recommendations on the
Transport of Dangerous Goods, Manual of Tests and Criteria is necessary.
The first step is to ascertain whether the substance or mixture has explosive effects (Test Series 1). The second
step is the acceptance procedure (Test Series 2 to 4) and the third step is the assignment to a hazard division
(Test Series 5 to 7). The assessment whether a candidate for ‘ammonium nitrate emulsion or suspension or
gel, intermediate for blasting explosives (ANE)’ is insensitive enough for inclusion as an oxidising liquid
(section 2.13) or an oxidising solid (section 2.14) is answered by Test Series 8 tests.
Explosive substances and mixtures wetted with water or alcohols, or diluted with other substances to suppress
their explosive properties, may be treated differently in terms of classification and other hazard classes may
apply, according to their physical properties (see also Annex II section 1.1.).
Certain physical hazards (due to explosive properties) are altered by dilution, as is the case for desensitised
explosives, by inclusion in a mixture or article, packaging or other factors.
The classification procedure is set out in the following decision logic (see Figures 2.1.1 to 2.1.4).
L 353/48 EN Official Journal of the European Union 31.12.2008
Figure 2.1.1
Overall scheme of the procedure for classifying a substance, mixture or article in the class of explosives (Class 1
for transport)
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Figure 2.1.2
Procedure for provisional acceptance of a substance, mixture or article in the class of explosives (Class 1 for
transport)
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Figure 2.1.3
Procedure for assignment to a division in the class of explosives (Class 1 for transport)
31.12.2008 EN Official Journal of the European Union L 353/51
Figure 2.1.4
Explosive properties are associated with the presence of certain chemical groups in a molecule which can
react to produce very rapid increases in temperature or pressure. The screening procedure is aimed at
identifying the presence of such reactive groups and the potential for rapid energy release. If the screening
procedure identifies the substance or mixture to be a potential explosive, the acceptance procedure (see
section 10.3 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria) has to be performed.
Note
Neither a Series 1 type (a) propagation of detonation test nor a Series 2 type (a) test of sensitivity to detonative
shock is required if the exothermic decomposition energy of organic materials is less than 800 J/g.
(a) There are no chemical groups associated with explosive properties present in the molecule. Examples of
groups which may indicate explosive properties are given in Table A6.1 in Appendix 6 of the UN
Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria; or
(b) The substance contains chemical groups associated with explosive properties which include oxygen and
the calculated oxygen balance is less than - 200;
(c) When the organic substance or a homogenous mixture of organic substances contains chemical groups
associated with explosive properties but the exothermic decomposition energy is less than 500 J/g and
the onset of exothermic decomposition is below 500 oC. The exothermic decomposition energy can be
determined using a suitable calorimetric technique; or
(d) For mixtures of inorganic oxidising substances with organic material(s), the concentration of the
inorganic oxidising substance is:
2.1.4.4. In the case of mixtures containing any known explosives, the acceptance procedure has to be performed.
2.2.1. Definition
Flammable gas means a gas or gas mixture having a flammable range with air at 20 oC and a standard
pressure of 101,3 kPa.
2.2.2.1. A flammable gas shall be classified in this class in accordance with Table 2.2.1:
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Table 2.2.1
Category Criteria
o
Gases, which at 20 C and a standard pressure of 101,3 kPa:
1 (a) are ignitable when in a mixture of 13 % or less by volume in air; or
(b) have a flammable range with air of at least 12 percentage points regardless of the lower
flammable limit.
Note
Label elements shall be used for substances and mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.2.2.
Table 2.2.2
2.2.4.1. Flammability shall be determined by tests or, for mixtures where there are sufficient data available, by
calculation in accordance with the methods adopted by ISO (see ISO 10156 as amended, Gases and gas
mixtures — Determination of fire potential and oxidising ability for the selection of cylinder valve outlet).
Where insufficient data are available to use these methods, test method EN 1839 as amended (Determination
of explosion limits of gases and vapours) can be used.
2.3.1. Definitions
Aerosols, this means aerosol dispensers, are any non-refillable receptacles made of metal, glass or plastics and
containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder,
and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in
a gas, as a foam, paste or powder or in a liquid state or in a gaseous state.
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2.3.2.1. Aerosols shall be considered for classification as flammable in accordance with 2.3.2.2 if they contain any
component which is classified as flammable according to the criteria contained in this Part, i.e.:
— Liquids with a flash point ≤ 93 oC, which includes Flammable Liquids according to section 2.6;
Note
Flammable components do not cover pyrophoric, self-heating or water-reactive substances and mixtures
because such components are never used as aerosol contents.
2.3.2.2. A flammable aerosol shall be classified in one of the two categories for this Class on the basis of its
components, of its chemical heat of combustion and, if applicable, of the results of the foam test (for foam
aerosols) and of the ignition distance test and enclosed space test (for spray aerosols) in accordance with
Figure 2.3.1 and the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria, Part III, sub-sections 31.4, 31.5 and 31.6.
Figure 2.3.1
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.3.2.
Table 2.3.2
2.3.4.1. The chemical heat of combustion (ΔHc), in kilojoules per gram (kJ/g), is the product of the theoretical heat of
combustion (ΔHcomb), and a combustion efficiency, usually less than 1,0 (a typical combustion efficiency is
0,95 or 95 %).
For a composite aerosol formulation, the chemical heat of combustion is the summation of the weighted
heats of combustion for the individual components, as follows:
n
ΔHc ðproductÞ = Σ wi % ΔHcðiÞ
i
where:
The chemical heats of combustion can be found in the literature, calculated or determined by tests (see ASTM
D 240 as amended — Standard Test Methods for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb
Calorimeter, EN/ISO 13943 as amended, 86.l to 86.3 — Fire safety — Vocabulary, and NFPA 30B as
amended — Code for the Manufacture and Storage of Aerosol Products).
2.4.1. Definitions
Oxidising gas means any gas or gas mixture which may, generally by providing oxygen, cause or contribute to
the combustion of other material more than air does.
2.4.2.1. An oxidising gas shall be classified in a single category for this class in accordance with Table 2.4.1.:
Table 2.4.1
Category Criteria
1 Any gas which may, generally by providing oxygen, cause or contribute to the combustion
of other material more than air does.
Note
‘Gases which cause or contribute to the combustion of other material more than air’ means pure gases or gas
mixtures with an oxidising power greater than 23,5 % as determined by a method specified in ISO 10156 as
amended or 10156-2 as amended.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.4.2.
Table 2.4.2
Classification Category 1
GHS Pictogram
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Classification Category 1
Signal Word Danger
Hazard Statement H270: May cause or intensify fire; oxidiser
Precautionary Statement P220
Prevention P244
Precautionary Statement P370 + P376
Response
Precautionary Statement P403
Storage
Precautionary Statement
Disposal
To classify an oxidising gas, tests or calculation methods as described in ISO 10156 as amended, gases and
gas mixtures — Determination of fire potential and oxidising ability for the selection of cylinder valve outlet
and ISO 10156-2 as amended, gas cylinders — gases and gas mixtures — Determination of oxidising ability
of toxic and corrosive gases and gas mixtures — shall be performed.
2.5.1. Definition
2.5.1.1. Gases under pressure are gases which are contained in a receptacle at a pressure of 200 kPa (gauge) or more,
or which are liquefied or liquefied and refrigerated.
They comprise compressed gases, liquefied gases, dissolved gases and refrigerated liquefied gases.
2.5.1.2. The critical temperature is the temperature above which a pure gas cannot be liquefied, regardless of the
degree of compression.
Gases shall be classified, according to their physical state when packaged, in one of four groups in accordance
with Table 2.5.1:
Table 2.5.1
Group Criteria
Compressed gas A gas which when packaged under pressure is entirely gaseous at - 50 oC;
including all gases with a critical temperature ≤ - 50 oC.
Liquefied gas A gas which, when packaged under pressure, is partially liquid at
temperatures above - 50 oC. A distinction is made between:
(i) high pressure liquefied gas: a gas with a critical temperature between
- 50 oC and + 65 oC; and
(ii) low pressure liquefied gas: a gas with a critical temperature above
+ 65 oC.
Refrigerated liquefied gas A gas which when packaged is made partially liquid because of its low
temperature.
Dissolved gas A gas which when packaged under pressure is dissolved in a liquid phase
solvent.
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Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.5.2.
Table 2.5.2
Refrigerated lique-
Classification Compressed gas Liquefied gas Dissolved gas
fied gas
GHS Pictograms
Data can be found in the literature, calculated or determined by testing. Most pure gases are already classified
in the UN Recommendations on the Transport of Dangerous Goods, Model Regulations.
2.6.1. Definition
Flammable liquid means a liquid having a flash point of not more than 60 oC.
2.6.2.1. A flammable liquid shall be classified in one of the three categories for this class in accordance with
Table 2.6.1:
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Table 2.6.1
Category Criteria
1 Flash point < 23 C and initial boiling point ≤ 35 oC
o
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.6.2.
Table 2.6.2
2.6.4.1. For the classification of flammable liquids data on flash point and initial boiling point are needed. Data can
be determined by testing, found in literature or calculated. If data are not available, the flash point and the
initial boiling point shall be determined through testing. For flash point determination a closed-cup method
shall be used.
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2.6.4.2. In the case of mixtures (1) containing known flammable liquids in defined concentrations, although they may
contain non-volatile components e.g. polymers, additives, the flash point need not be determined
experimentally if the calculated flash point of the mixture, using the method given in 2.6.4.3, is at least
5 oC (2) greater than the relevant classification criterion and provided that:
(a) the composition of the mixture is accurately known (if the material has a specified range of
composition, the composition with the lowest calculated flash point shall be selected for assessment);
(b) the lower explosion limit of each component is known (an appropriate correlation has to be applied
when these data are extrapolated to other temperatures than test conditions) as well as a method for
calculating the lower explosion limit;
(c) the temperature dependence of the saturated vapour pressure and of the activity coefficient is known
for each component as present in the mixture;
2.6.4.3. One suitable method is described in Gmehling and Rasmussen (Ind. Eng. Fundament, 21, 186, (1982)). For a
mixture containing non-volatile components the flash point is calculated from the volatile components. It is
considered that a non-volatile component only slightly decreases the partial pressure of the solvents and the
calculated flash point is only slightly below the measured value.
2.6.4.4. Possible test methods for determining the flash point of flammable liquids are listed in Table 2.6.3.
Table 2.6.3
(1) To date, the calculation method has been validated for mixtures containing up to 6 volatile components. These components may be
flammable liquids like hydrocarbons, ethers, alcohols, esters (except acrylates), and water. It is however not yet validated for mixtures
containing halogenated sulphurous, and/or phosphoric compounds as well as reactive acrylates.
(2) If the calculated flash point is less than 5 oC greater than the relevant classification criterion, the calculation method may not be used and
the flash point should be determined experimentally.
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2.6.4.5. Liquids with a flash point of more than 35 oC need not be classified in Category 3 if negative results have
been obtained in the sustained combustibility test L.2, Part III, section 32 of the UN Recommendations on the
Transport of Dangerous Goods, Manual of Tests and Criteria.
2.7.1. Definition
2.7.1.1. A flammable solid means a solid which is readily combustible, or may cause or contribute to fire through
friction.
Readily combustible solids are powdered, granular, or pasty substances or mixtures which are dangerous if
they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame
spreads rapidly.
2.7.2.1. Powdered, granular or pasty substances or mixtures (except powders of metals or metal alloys — see 2.7.2.2)
shall be classified as readily combustible solids when the time of burning of one or more of the test runs,
performed in accordance with the test method described in Part III, sub-section 33.2.1, of the UN
Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, is less than 45
seconds or the rate of burning is more than 2,2 mm/s.
2.7.2.2. Powders of metals or metal alloys shall be classified as flammable solids when they can be ignited and the
reaction spreads over the whole length of the sample in 10 minutes or less.
2.7.2.3. A flammable solid shall be classified in one of the two categories for this class using Method N.1 as described
in 33.2.1 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria in
accordance with Table 2.7.1:
Table 2.7.1
Category Criteria
Note
The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for
the purposes of supply or transport, the same chemical is to be presented in a physical form different from
that which was tested and which is considered likely to materially alter its performance in a classification test,
the substance shall also be tested in the new form.
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Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.7.2.
Table 2.7.2
2.8.1. Definition
2.8.1.1. Self-reactive substances or mixtures are thermally unstable liquid or solid substances or mixtures liable to
undergo a strongly exothermic decomposition even without participation of oxygen (air). This definition
excludes substances and mixtures classified according to this Part as explosives, organic peroxides or as
oxidising.
2.8.1.2. A self-reactive substance or mixture is regarded as possessing explosive properties when in laboratory testing
the formulation is liable to detonate, to deflagrate rapidly or to show a violent effect when heated under
confinement.
2.8.2.1. Any self-reactive substance or mixture shall be considered for classification in this class as a self-reactive
substance or mixture unless:
(b) they are oxidising liquids or solids, according to the criteria given in 2.13 or 2.14, except that mixtures
of oxidising substances, which contain 5 % or more of combustible organic substances shall be
classified as self-reactive substances according to the procedure defined in 2.8.2.2;
(c) they are organic peroxides, according to the criteria given in 2.15;
(e) their self-accelerating decomposition temperature (SADT) is greater than 75 oC for a 50 kg package (1).
(1) See UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, sub-sections 28.1, 28.2, 28.3 and
Table 28.3.
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2.8.2.2. Mixtures of oxidising substances, meeting the criteria for classification as oxidising substances, which contain
5 % or more of combustible organic substances and which do not meet the criteria mentioned in (a), (c), (d)
or (e) in 2.8.2.1, shall be subjected to the self-reactive substances classification procedure;
Such a mixture showing the properties of a self-reactive substance type B to F (see 2.8.2.3) shall be classified
as a self-reactive substance.
Where the test is conducted in the package form and the packaging is changed, a further test shall be
conducted where it is considered that the change in packaging will affect the outcome of the test.
2.8.2.3. Self-reactive substances and mixtures shall be classified in one of the seven categories of ‘types A to G’ for this
class, according to the following principles:
(a) any self-reactive substance or mixture which can detonate or deflagrate rapidly, as packaged, shall be
defined as self-reactive substance TYPE A;
(b) any self-reactive substance or mixture possessing explosive properties and which, as packaged, neither
detonates nor deflagrates rapidly, but is liable to undergo a thermal explosion in that package shall be
defined as self-reactive substance TYPE B;
(c) any self-reactive substance or mixture possessing explosive properties when the substance or mixture as
packaged cannot detonate or deflagrate rapidly or undergo a thermal explosion shall be defined as self-
reactive substance TYPE C;
(i) detonates partially, does not deflagrate rapidly and shows no violent effect when heated under
confinement; or
(ii) does not detonate at all, deflagrates slowly and shows no violent effect when heated under
confinement; or
(iii) does not detonate or deflagrate at all and shows a medium effect when heated under
confinement;
(e) any self-reactive substance or mixture which, in laboratory testing, neither detonates nor deflagrates at
all and shows low or no effect when heated under confinement shall be defined as self-reactive
substance TYPE E;
(f) any self-reactive substance or mixture which, in laboratory testing, neither detonates in the cavitated
state nor deflagrates at all and shows only a low or no effect when heated under confinement as well as
low or no explosive power shall be defined as self-reactive substance TYPE F;
(g) any self-reactive substance or mixture which, in laboratory testing, neither detonates in the cavitated
state nor deflagrates at all and shows no effect when heated under confinement nor any explosive
power, provided that it is thermally stable (SADT is 60 oC to 75 oC for a 50 kg package), and, for liquid
mixtures, a diluent having a boiling point not less than 150 oC is used for desensitisation shall be
defined as self-reactive substance TYPE G. If the mixture is not thermally stable or a diluent having a
boiling point less than 150 oC is used for desensitisation, the mixture shall be defined as self-reactive
substance TYPE F.
Where the test is conducted in the package form and the packaging is changed, a further test shall be
conducted where it is considered that the change in packaging will affect the outcome of the test.
Self-reactive substances need to be subjected to temperature control if their SADT is less than or equal to
55 oC. Test methods for determining the SADT as well as the derivation of control and emergency
temperatures are given in, Part II, section 28 of the UN Recommendations on the Transport of Dangerous
Goods, Manual of Tests and Criteria. The test selected shall be conducted in a manner which is representative,
both in size and material, of the package.
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Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.8.1.
Table 2.8.1
There are no
Signal Word Danger Danger Danger Warning label elements
allocated to this
Hazard State- H240: Heat- H241: Heat- H242: Heat- H242: Heat- hazard category
ment ing may cause ing may cause ing may cause ing may cause
an explosion a fire or a fire a fire
explosion
Precautionary P210 P210 P210 P210
Statement P220 P220 P220 P220
Prevention P234 P234 P234 P234
P280 P280 P280 P280
Precautionary P370 + P378 P370 + P378 P370 + P378 P370 + P378
Statement P370 + P380 P370 + P380
Response + P375 + P375
Precautionary P403 + P235 P403 + P235 P403 + P235 P403 + P235
Statement P411 P411 P411 P411
Storage P420 P420 P420 P420
Precautionary P501 P501 P501 P501
Statement
Disposal
Type G has no hazard communication elements assigned but shall be considered for properties belonging to
other hazard classes.
2.8.4.1. The properties of self-reactive substances or mixtures which are decisive for their classification shall be
determined experimentally. The classification of a self reactive substance or mixture shall be performed in
accordance with test series A to H as described in Part II of the UN Recommendations on the Transport of
Dangerous Goods, Manual of Tests and Criteria. The procedure for classification is described in Figure 2.8.1.
2.8.4.2. The classification procedures for self-reactive substances and mixtures need not be applied if:
(a) There are no chemical groups present in the molecule associated with explosive or self reactive
properties. Examples of such groups are given in Tables A6.1 and A6.2 in Appendix 6 of the UN
Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria; or
(b) For a single organic substance or a homogeneous mixture of organic substances, the estimated SADT
for a 50 kg package is greater than 75 oC or the exothermic decomposition energy is less than 300J/g.
The onset temperature and decomposition energy can be estimated using a suitable calorimetric
technique (see Part II, sub-section 20.3.3.3 of the UN Recommendations on the Transport of
Dangerous Goods, Manual of Tests and Criteria).
L 353/66 EN Official Journal of the European Union 31.12.2008
Figure 2.8.1
2.9.1. Definition
Pyrophoric liquid means a liquid substance or mixture which, even in small quantities, is liable to ignite
within five minutes after coming into contact with air.
2.9.2.1. A pyrophoric liquid shall be classified in a single category for this class using test N.3 in Part III, sub-
section 33.3.1.5 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria according to Table 2.9.1:
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Table 2.9.1
Category Criteria
1 The liquid ignites within 5 min when added to an inert carrier and exposed to air, or it
ignites or chars a filter paper on contact with air within 5 min.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.9.2.
Table 2.9.2
Classification Category 1
GHS Pictogram
2.9.4.1. The classification procedure for pyrophoric liquids need not be applied when experience in manufacture or
handling shows that the substance or mixture does not ignite spontaneously on coming into contact with air
at normal temperatures (i.e. the substance is known to be stable at room temperature for prolonged periods
of time (days)).
2.10.1. Definition
Pyrophoric solid means a solid substance or mixture which, even in small quantities, is liable to ignite within
five minutes after coming into contact with air.
2.10.2.1. A pyrophoric solid shall be classified in a single category for this class using test N.2 in Part III, sub-
section 33.3.1.4 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria in accordance with Table 2.10.1:
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Table 2.10.1
Category Criteria
1 The solid ignites within 5 minutes of coming into contact with air.
Note
The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for
the purposes of supply or transport, the same chemical is to be presented in a physical form different from
that which was tested and which is considered likely to materially alter its performance in a classification test,
the substance shall also be tested in the new form.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.10.2.
Table 2.10.2
Classification Category 1
GHS Pictogram
2.10.4.1. The classification procedure for pyrophoric solids need not be applied when experience in manufacture or
handling shows that the substance or mixture does not ignite spontaneously on coming into contact with air
at normal temperatures (i.e. the substance is known to be stable at room temperature for prolonged periods
of time (days)).
2.11.1. Definition
2.11.1.1. A self-heating substance or mixture is a liquid or solid substance or mixture, other than a pyrophoric liquid
or solid, which, by reaction with air and without energy supply, is liable to self-heat; this substance or mixture
differs from a pyrophoric liquid or solid in that it will ignite only when in large amounts (kilograms) and after
long periods of time (hours or days).
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2.11.1.2. Self-heating of substances or mixtures, leading to spontaneous combustion, is caused by reaction of the
substance or mixture with oxygen (in the air) and the heat developed not being conducted away rapidly
enough to the surroundings. Spontaneous combustion occurs when the rate of heat production exceeds the
rate of heat loss and the auto-ignition temperature is reached.
2.11.2.1. A substance or mixture shall be classified as a self-heating substance or mixture of this class, if in the tests
performed in accordance with the test method given in the UN Recommendations on the Transport of
Dangerous Goods, Manual of Tests and Criteria, Part III, sub-section 33.3.1.6:
(b) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a negative result is
obtained in a test using a 100 mm cube sample at 120 oC and the substance or mixture is to be packed
in packages with a volume of more than 3 m3;
(c) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a negative result is
obtained in a test using a 100 mm cube sample at 100 oC and the substance or mixture is to be packed
in packages with a volume of more than 450 litres;
(d) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a positive result is
obtained in a test using a 100 mm cube sample at 100 oC.
2.11.2.2. A self-heating substance or mixture shall be classified in one of the two categories for this class if, in a test
performed in accordance with test method N.4 in Part III, sub-section 33.3.1.6 of the UN Recommendations
on the Transport of Dangerous Goods, Manual of Tests and Criteria, the result meets the criteria according to
Table 2.11.1:
Table 2.11.1
Category Criteria
1 A positive result is obtained in a test using a 25 mm sample cube at 140 oC
(a) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a
negative result is obtained in a test using a 25 mm cube sample at 140 oC and the
substance or mixture is to be packed in packages with a volume of more than 3 m 3; or
(b) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a
negative result is obtained in a test using a 25 mm cube sample at 140 oC, a positive
2 result is obtained in a test using a 100 mm cube sample at 120 oC and the substance or
mixture is to be packed in packages with a volume of more than 450 litres; or
(c) a positive result is obtained in a test using a 100 mm sample cube at 140 oC and a
negative result is obtained in a test using a 25 mm cube sample at 140 oC and a positive
result is obtained in a test using a 100 mm cube sample at 100 oC.
Note
The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for
the purposes of supply or transport, the same chemical is to be presented in a physical form different from
that which was tested and which is considered likely to materially alter its performance in a classification test,
the substance shall also be tested in the new form.
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2.11.2.3. Substances and mixtures with a temperature of spontaneous combustion higher than 50 oC for a volume of
27 m3 shall not be classified as a self-heating substance or mixture.
2.11.2.4. Substances and mixtures with a spontaneous ignition temperature higher than 50 oC for a volume of
450 litres shall not be assigned to Category 1 of this class.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.11.2.
Table 2.11.2
2.11.4.1. For detailed schemes for the decision logic for classification and the tests to be carried out for ascertaining the
different categories, see Figure 2.11.1.
2.11.4.2. The classification procedure for self-heating substances or mixtures need not be applied if the results of a
screening test can be adequately correlated with the classification test and an appropriate safety margin is
applied. Examples of screening tests are:
(a) The Grewer Oven test (VDI guideline 2263, Part 1, 1990, Test methods for the Determination of the
Safety Characteristics of Dusts) with an onset temperature 80 K above the reference temperature for a
volume of 1 l;
(b) The Bulk Powder Screening Test (Gibson, N. Harper, D.J. Rogers, R.Evaluation of the fire and explosion
risks in drying powders, Plant Operations Progress, 4 (3), 181-189, 1985) with an onset temperature
60 K above the reference temperature for a volume of 1 l.
31.12.2008 EN Official Journal of the European Union L 353/71
Figure 2.11.1.
2.12. Substances and mixtures which in contact with water emit flammable gases
2.12.1. Definition
Substances or mixtures which, in contact with water, emit flammable gases means solid or liquid substances
or mixtures which, by interaction with water, are liable to become spontaneously flammable or to give off
flammable gases in dangerous quantities.
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2.12.2.1. A substance or mixture which, in contact with water, emits flammable gases shall be classified in one of the
three categories for this class, using test N.5 in Part III, sub-section 33.4.1.4 of the UN Recommendations on
the Transport of Dangerous Goods, Manual of Tests and Criteria, in accordance with Table 2.12.1:
Table 2.12.1
Criteria for substances or mixtures which in contact with water emit flammable gases
Category Criteria
Any substance or mixture which reacts vigorously with water at ambient temperatures and
demonstrates generally a tendency for the gas produced to ignite spontaneously, or which
1 reacts readily with water at ambient temperatures such that the rate of evolution of
flammable gas is equal to or greater than 10 litres per kilogram of substance over any one
minute.
Any substance or mixture which reacts readily with water at ambient temperatures such that
2 the maximum rate of evolution of flammable gas is equal to or greater than 20 litres per
kilogram of substance per hour, and which does not meet the criteria for Category 1.
Any substance or mixture which reacts slowly with water at ambient temperatures such that
3 the maximum rate of evolution of flammable gas is equal to or greater than 1 litre per
kilogram of substance per hour, and which does not meet the criteria for Categories 1 and 2.
Note:
The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for
the purposes of supply or transport, the same chemical is to be presented in a physical form different from
that which was tested and which is considered likely to materially alter its performance in a classification test,
the substance must also be tested in the new form.
2.12.2.2. A substance or mixture shall be classified as a substance or mixture which in contact with water emits
flammable gases if spontaneous ignition takes place in any step of the test procedure.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.12.2.
Table 2.12.2
Label elements for substances or mixtures which in contact with water emit flammable gases
2.12.4.1. The classification procedure for this class need not be applied if:
(a) the chemical structure of the substance or mixture does not contain metals or metalloids; or
(b) experience in production or handling shows that the substance or mixture does not react with water,
e.g. the substance is manufactured with water or washed with water; or
(c) the substance or mixture is known to be soluble in water to form a stable mixture.
2.13.1. Definition
Oxidising liquid means a liquid substance or mixture which, while in itself not necessarily combustible, may,
generally by yielding oxygen, cause, or contribute to, the combustion of other material.
2.13.2.1. An oxidising liquid shall be classified in one of the three categories for this class using test O.2 in Part III, sub-
section 34.4.2 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria in accordance with Table 2.13.1:
Table 2.13.1
Category Criteria
Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and
1 cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by
mass, of substance (or mixture) and cellulose is less than that of a 1:1 mixture, by mass, of
50 % perchloric acid and cellulose.
Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and
2 cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure
rise time of a 1:1 mixture, by mass, of 40 % aqueous sodium chlorate solution and cellulose;
and the criteria for Category 1 are not met.
Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and
3 cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure
rise time of a 1:1 mixture, by mass, of 65 % aqueous nitric acid and cellulose; and the
criteria for Category 1 and 2 are not met.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.13.2.
Table 2.13.2
2.13.4.1. For organic substances or mixtures the classification procedure for this class shall not apply if:
(a) the substance or mixture does not contain oxygen, fluorine or chlorine; or
(b) the substance or mixture contains oxygen, fluorine or chlorine and these elements are chemically
bonded only to carbon or hydrogen.
2.13.4.2. For inorganic substances or mixtures the classification procedure for this class shall not apply if they do not
contain oxygen or halogen atoms.
2.13.4.3. In the event of divergence between test results and known experience in the handling and use of substances
or mixtures which shows them to be oxidising, judgments based on known experience shall take precedence
over test results.
2.13.4.4. In cases where substances or mixtures generate a pressure rise (too high or too low), caused by chemical
reactions not characterising the oxidising properties of the substance or mixture, the test described in Part III,
sub-section 34.4.2 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria shall be repeated with an inert substance, e.g. diatomite (kieselguhr), in place of the cellulose in order
to clarify the nature of the reaction and to check for a false positive result.
2.14.1. Definition
Oxidising solid means a solid substance or mixture which, while in itself is not necessarily combustible, may,
generally by yielding oxygen, cause, or contribute to, the combustion of other material.
2.14.2.1. An oxidising solid shall be classified in one of the three categories for this class using test O.1 in Part III, sub-
section 34.4.1 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria in accordance with Table 2.14.1:
31.12.2008 EN Official Journal of the European Union L 353/75
Table 2.14.1
Category Criteria
Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested,
1 exhibits a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of
potassium bromate and cellulose.
Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested,
2 exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture
(by mass) of potassium bromate and cellulose and the criteria for Category 1 are not met.
Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested,
3 exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture
(by mass) of potassium bromate and cellulose and the criteria for Categories 1 and 2 are not
met.
Note 1
Some oxidising solids also present explosion hazards under certain conditions (when stored in large
quantities). Some types of ammonium nitrate may give rise to an explosion hazard under extreme conditions
and the ‘Resistance to detonation test’ (BC Code, Annex 3, Test 5) can be used to assess this hazard.
Appropriate information shall be made in the SDS.
Note 2
The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for
the purposes of supply or transport, the same chemical is to be presented in a physical form different from
that which was tested and which is considered likely to materially alter its performance in a classification test,
the substance shall also be tested in the new form.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.14.2.
Table 2.14.2
2.14.4.1. For organic substances or mixtures the classification procedure for this class shall not apply if:
(a) the substance or mixture does not contain oxygen, fluorine or chlorine; or
(b) the substance or mixture contains oxygen, fluorine or chlorine and these elements are chemically
bonded only to carbon or hydrogen.
2.14.4.2. For inorganic substances or mixtures the classification procedure for this class shall not apply if they do not
contain oxygen or halogen atoms.
2.14.4.3. In the event of divergence between test results and known experience in the handling and use of substances
or mixtures which shows them to be oxidising, judgments based on known experience shall take precedence
over test results.
2.15.1. Definition
2.15.1.1. Organic peroxides means liquid or solid organic substances which contain the bivalent -O-O- structure and
may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been
replaced by organic radicals. The term organic peroxide includes organic peroxide mixtures (formulations)
containing at least one organic peroxide. Organic peroxides are thermally unstable substances or mixtures,
which can undergo exothermic self-accelerating decomposition. In addition, they can have one or more of the
following properties:
2.15.1.2. An organic peroxide is regarded as possessing explosive properties when in laboratory testing the mixture
(formulation) is liable to detonate, to deflagrate rapidly or to show a violent effect when heated under
confinement.
2.15.2.1. Any organic peroxide shall be considered for classification in this class, unless it contains:
(a) not more than 1,0 % available oxygen from the organic peroxides when containing not more than
1,0 % hydrogen peroxide; or
(b) not more than 0,5 % available oxygen from the organic peroxides when containing more than 1,0 %
but not more than 7,0 % hydrogen peroxide.
Note
The available oxygen content ( %) of an organic peroxide mixture is given by the formula:
n
ni ci
16 Σ
i mi
where:
2.15.2.2. Organic peroxides shall be classified in one of the seven categories of ‘Types A to G’ for this class, according
to the following principles:
(a) any organic peroxide which, as packaged, can detonate or deflagrate rapidly shall be defined as organic
peroxide TYPE A;
(b) any organic peroxide possessing explosive properties and which, as packaged, neither detonates nor
deflagrates rapidly, but is liable to undergo a thermal explosion in that package shall be defined as
organic peroxide TYPE B;
(c) any organic peroxide possessing explosive properties when the substance or mixture as packaged
cannot detonate or deflagrate rapidly or undergo a thermal explosion shall be defined as organic
peroxide TYPE C;
(i) detonates partially, does not deflagrate rapidly and shows no violent effect when heated under
confinement; or
(ii) does not detonate at all, deflagrates slowly and shows no violent effect when heated under
confinement; or
(iii) does not detonate or deflagrate at all and shows a medium effect when heated under
confinement;
(e) any organic peroxide which, in laboratory testing, neither detonates nor deflagrates at all and shows low
or no effect when heated under confinement shall be defined as organic peroxide TYPE E;
(f) any organic peroxide which, in laboratory testing, neither detonates in the cavitated state nor
deflagrates at all and shows only a low or no effect when heated under confinement as well as low or
no explosive power shall be defined as organic peroxide TYPE F;
(g) any organic peroxide which, in laboratory testing, neither detonates in the cavitated state nor
deflagrates at all and shows no effect when heated under confinement nor any explosive power,
provided that it is thermally stable, i.e. the SADT is 60 oC or higher for a 50 kg package (1), and, for
liquid mixtures, a diluent having a boiling point of not less than 150 oC is used for desensitisation, shall
be defined as organic peroxide TYPE G. If the organic peroxide is not thermally stable or a diluent
having a boiling point less than 150 oC is used for desensitisation, the organic peroxide shall be defined
as organic peroxide TYPE F.
Where the test is conducted in the package form and the packaging is changed, a further test shall be
conducted where it is considered that the change in packaging will affect the outcome of the test.
(b) Organic peroxide type D showing a medium effect when heated under confinement ( 2) with an SADT
≤ 50 oC or showing a low or no effect when heated under confinement with an SADT ≤ 45 oC; and
(1) See UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, sub-sections 28.1, 28.2, 28.3 and
Table 28.3.
(2) As determined by test series E as prescribed in UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and
Criteria, Part II.
L 353/78 EN Official Journal of the European Union 31.12.2008
Test methods for determining the SADT as well as the derivation of control and emergency temperatures are
given in the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria,
Part II, section 28. The test selected shall be conducted in a manner which is representative, both in size and
material, of the package.
Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.15.1.
Table 2.15.1
There are no
Signal Word Danger Danger Danger Warning label elements
allocated to this
Hazard State- H240: Heat- H241: Heat- H242: Heat- H242: Heat- hazard category
ment ing may cause ing may cause ing may cause ing may cause
an explosion a fire or a fire a fire
explosion
Precautionary P210 P210 P210 P210
Statement P220 P220 P220 P220
Prevention P234 P234 P234 P234
P280 P280 P280 P280
Precautionary
Statement
Response
Precautionary P411 + P235 P411 + P235 P411 + P235 P411 + P235
Statement P410 P410 P410 P410
Storage P420 P420 P420 P420
Precautionary P501 P501 P501 P501
Statement
Disposal
Type G has no hazard communication elements assigned but shall be considered for properties belonging to
other hazard classes.
2.15.4.1. Organic peroxides are classified by definition based on their chemical structure and on the available oxygen
and hydrogen peroxide contents of the mixture (see 2.15.2.1). The properties of organic peroxides which are
necessary for their classification shall be determined experimentally. The classification of organic peroxides
shall be performed in accordance with test series A to H as described in Part II of the UN Recommendations
on the Transport of Dangerous Goods, Manual of Tests and Criteria. The procedure for classification is
described in Figure 2.15.1.
2.15.4.2. Mixtures of already classified organic peroxides may be classified as the same type of organic peroxide as that
of the most dangerous component. However, as two stable components can form a thermally less stable
mixture, the SADT of the mixture shall be determined.
Note: The sum of the individual parts can be more hazardous than the individual components.
31.12.2008 EN Official Journal of the European Union L 353/79
Figure 2.15.1
Organic Peroxides
2.16.1. Definition
A substance or a mixture that is corrosive to metals means a substance or a mixture which by chemical action
will materially damage, or even destroy, metals.
2.16.2.1. A substance or a mixture which is corrosive to metals is classified in a single category for this class, using the
test in Part III, sub-section 37.4 of the UN Recommendations on the Transport of Dangerous Goods, Manual
of Tests and Criteria, in accordance with Table 2.16.1:
L 353/80 EN Official Journal of the European Union 31.12.2008
Table 2.16.1
Category Criteria
1 Corrosion rate on either steel or aluminium surfaces exceeding 6,25 mm per year at a test
temperature of 55 oC when tested on both materials.
Note
Where an initial test on either steel or aluminium indicates the substance or mixture being tested is corrosive
the follow up test on the other metal is not required.
Label elements shall be used for substances and mixtures meeting the criteria for classification in this hazard
class in accordance with Table 2.16.2.
Table 2.16.2
Classification Category 1
GHS Pictogram
Precautionary Statement
Disposal
2.16.4.1. The corrosion rate can be measured according to the test method of Part III sub-section 37.4 of the UN
Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. The specimen to be
used for the test shall be made of the following materials:
— S275J2G3+CR (1.0144 resp.St 44-3), ISO 3574 as amended, Unified Numbering System (UNS)
G 10200, or SAE 1020;
(b) for the purposes of testing aluminium: non-clad types 7075-T6 or AZ5GU-T6.
31.12.2008 EN Official Journal of the European Union L 353/81
3.1.1. Definitions
3.1.1.1. Acute toxicity means those adverse effects occurring following oral or dermal administration of a single dose
of a substance or a mixture, or multiple doses given within 24 hours, or an inhalation exposure of 4 hours.
3.1.2.1. Substances can be allocated to one of four toxicity categories based on acute toxicity by the oral, dermal or
inhalation route according to the numeric criteria shown in Table 3.1.1. Acute toxicity values are expressed as
(approximate) LD50 (oral, dermal) or LC50 (inhalation) values or as acute toxicity estimates (ATE). Explanatory
notes are shown following Table 3.1.1.
Table 3.1.1
Acute toxicity hazard categories and acute toxicity estimates (ATE) defining the respective categories
(a) The acute toxicity estimate (ATE) for the classification of a substance or ingredient in a mixture is derived using:
— the appropriate conversion value from Table 3.1.2 that relates to the results of a range test, or
— the appropriate conversion value from Table 3.1.2 that relates to a classification category.
(b) Generic concentration limits for inhalation toxicity in the table are based on 4 hour testing exposures.
Conversion of existing inhalation toxicity data which have been generated using a 1 hour exposure can be
carried out by dividing by a factor of 2 for gases and vapours and 4 for dusts and mists.
(c) For some substances or mixtures the test atmosphere will not just be a vapour but will consist of a mixture of
liquid and vapour phases. For other substances or mixtures the test atmosphere may consist of a vapour which
is near the gaseous phase. In these latter cases, classification shall be based on ppmV as follows: Category 1
(100 ppmV), Category 2 (500 ppmV), Category 3 (2 500 ppmV), Category 4 (20 000 ppmV).
— Vapour: the gaseous form of a substance or mixture released from its liquid or solid state.
Dust is generally formed by mechanical processes. Mist is generally formed by condensation of supersaturated
vapours or by physical shearing of liquids. Dusts and mists generally have sizes ranging from less than 1 to
about 100 μm.
3.1.2.2.1. The preferred test species for evaluation of acute toxicity by the oral and inhalation routes is the rat, while the
rat or rabbit are preferred for evaluation of acute dermal toxicity. When experimental data for acute toxicity
are available in several animal species, scientific judgement shall be used in selecting the most appropriate
LD50 value from among valid, well-performed tests.
3.1.2.3. Specific considerations for classification of substances as acutely toxic by the inhalation route
3.1.2.3.1. Units for inhalation toxicity are a function of the form of the inhaled material. Values for dusts and mists are
expressed in mg/l. Values for gases are expressed in ppmV. Acknowledging the difficulties in testing vapours,
some of which consist of mixtures of liquid and vapour phases, the table provides values in units of mg/l.
However, for those vapours which are near the gaseous phase, classification shall be based on ppmV.
3.1.2.3.2. Of particular importance in classifying for inhalation toxicity is the use of well articulated values in the high
toxicity categories for dusts and mists. Inhaled particles between 1 and 4 microns mean mass aerodynamic
diameter (MMAD) will deposit in all regions of the rat respiratory tract. This particle size range corresponds
to a maximum dose of about 2 mg/l. In order to achieve applicability of animal experiments to human
exposure, dusts and mists would ideally be tested in this range in rats.
3.1.2.3.3. In addition to classification for inhalation toxicity, if data are available that indicates that the mechanism of
toxicity was corrosivity, the substance or mixture shall also be labelled as ‘corrosive to the respiratory tract’
(see note 1 in 3.1.4.1). Corrosion of the respiratory tract is defined by destruction of the respiratory tract
tissue after a single, limited period of exposure analogous to skin corrosion; this includes destruction of the
mucosa. The corrosivity evaluation can be based on expert judgment using such evidence as: human and
animal experience, existing (in vitro) data, pH values, information from similar substances or any other
pertinent data.
3.1.3.1. The criteria for classification of substances for acute toxicity as outlined in section 3.1.2 are based on lethal
dose data (tested or derived). For mixtures, it is necessary to obtain or derive information that allows the
criteria to be applied to the mixture for the purpose of classification. The approach to classification for acute
toxicity is tiered, and is dependent upon the amount of information available for the mixture itself and for its
ingredients. The flow chart of Figure 3.1.1 outlines the process to be followed.
31.12.2008 EN Official Journal of the European Union L 353/83
3.1.3.2. For acute toxicity each route of exposure shall be considered for the classification of mixtures, but only one
route of exposure is needed as long as this route is followed (estimated or tested) for all ingredients. If the
acute toxicity is determined for more than one route of exposure, the more severe hazard category will be
used for classification. All available information shall be considered and all relevant routes of exposure shall
be identified for hazard communication.
3.1.3.3. In order to make use of all available data for purposes of classifying the hazards of the mixtures, certain
assumptions have been made and are applied where appropriate in the tiered approach:
(a) the ‘relevant ingredients’ of a mixture are those which are present in concentrations of 1 % (w/w for
solids, liquids, dusts, mists and vapours and v/v for gases) or greater, unless there is a reason to suspect
that an ingredient present at a concentration of less than 1 % is still relevant for classifying the mixture
for acute toxicity (see Table 1.1).
(b) where a classified mixture is used as an ingredient of another mixture, the actual or derived acute
toxicity estimate (ATE) for that mixture may be used, when calculating the classification of the new
mixture using the formulas in section 3.1.3.6.1 and paragraph 3.1.3.6.2.3.
Figure 3.1.1
3.1.3.4. Classification of mixtures where acute toxicity data are available for the complete mixture
3.1.3.4.1. Where the mixture itself has been tested to determine its acute toxicity, it shall be classified according to the
same criteria as those used for substances, presented in Table 3.1.1. If test data for the mixture are not
available, the procedures presented under sections 3.1.3.5 and 3.1.3.6 shall be followed.
3.1.3.5. Classification of mixtures where acute toxicity data are available for the complete mixture: bridging principles
3.1.3.5.1. Where the mixture itself has not been tested to determine its acute toxicity, but there are sufficient data on the
individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these
data shall be used in accordance with the bridging rules set out in section 1.1.3.
L 353/84 EN Official Journal of the European Union 31.12.2008
3.1.3.5.2. If a mixture is diluted with water or other totally non-toxic material, the toxicity of the mixture can be
calculated from test data on the undiluted mixture.
In order to ensure that classification of the mixture is accurate, and that the calculation need only be
performed once for all systems, sectors, and categories, the acute toxicity estimate (ATE) of ingredients shall
be considered as follows:
(a) include ingredients with a known acute toxicity, which fall into any of the acute toxicity categories
shown in Table 3.1.1;
(b) ignore ingredients that are presumed not acutely toxic (e.g., water, sugar);
(c) ignore ingredients if the oral limit test does not show acute toxicity at 2 000 mg/kg bodyweight.
Ingredients that fall within the scope of this paragraph are considered to be ingredients with a known acute
toxicity estimate (ATE).
The ATE of the mixture is determined by calculation from the ATE values for all relevant ingredients
according to the following formula for Oral, Dermal or Inhalation Toxicity:
100 Ci
=Σ
ATEmix n ATEi
where:
3.1.3.6.2. Classification of mixtures when data are not available for all components
3.1.3.6.2.1. Where an ATE is not available for an individual ingredient of the mixture, but available information, such as
that listed below, can provide a derived conversion value such as those laid out in Table 3.1.2, the formula in
section 3.1.3.6.1 shall be applied.
(a) extrapolation between oral, dermal and inhalation acute toxicity estimates ( 1). Such an evaluation could
require appropriate pharmacodynamic and pharmacokinetic data;
(b) evidence from human exposure that indicates toxic effects but does not provide lethal dose data;
(c) evidence from any other toxicity tests/assays available on the substance that indicates toxic acute effects
but does not necessarily provide lethal dose data; or
(1) For ingredients with acute toxicity estimates available for other than the most appropriate exposure route, values may be extrapolated
from the available exposure route(s) to the most appropriate route. Dermal and inhalation route data are not always required for
ingredients. However, in case data requirements for specific ingredients include acute toxicity estimates for the dermal and inhalation
route, the values to be used in the formula need to be from the required exposure route.
31.12.2008 EN Official Journal of the European Union L 353/85
This approach generally requires substantial supplemental technical information, and a highly trained and
experienced expert (expert judgement, see section 1.1.1), to reliably estimate acute toxicity. If such
information is not available, proceed to paragraph 3.1.3.6.2.3.
3.1.3.6.2.2. In the event that an ingredient without any useable information at all is used in a mixture at a concentration
of 1 % or greater, it is concluded that the mixture cannot be attributed a definitive acute toxicity estimate. In
this situation the mixture shall be classified based on the known ingredients only, with the additional
statement that x percent of the mixture consists of ingredient(s) of unknown toxicity.
3.1.3.6.2.3. If the total concentration of the ingredient(s) with unknown acute toxicity is ≤ 10 % then the formula
presented in section 3.1.3.6.1 shall be used. If the total concentration of the ingredient(s) with unknown
toxicity is > 10 %, the formula presented in section 3.1.3.6.1 shall be corrected to adjust for the total
percentage of the unknown ingredient(s) as follows:
100 − ΣC unknown if > 10 %
=Σ
Ci
ATEmix n ATEi
Table 3.1.2
Conversion from experimentally obtained acute toxicity range values (or acute toxicity hazard
categories) to acute toxicity point estimates for classification for the respective routes of exposure
Note 1
These values are designed to be used in the calculation of the ATE for classification of a mixture based on its
components and do not represent test results.
3.1.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.1.3.
L 353/86 EN Official Journal of the European Union 31.12.2008
Table 3.1.3
GHS Pictograms
Precautionary Statement P301 + P310 P301 + P310 P301 + P310 P301 + P312
Response (oral) P321 P321 P321 P330
P330 P330 P330
Precautionary Statement P302 + P350 P302 + P350 P302 + P352 P302 + P352
Response (dermal) P310 P310 P312 P312
P322 P322 P322 P322
P361 P361 P361 P363
P363 P363 P363
Precautionary Statement P304 + P340 P304 + P340 P304 + P340 P304 + P340
Response (inhalation) P310 P310 P311 P312
P320 P320 P321
Note 1
In addition to classification for inhalation toxicity, if data are available that indicates that the mechanism of
toxicity is corrosivity, the substance or mixture shall also be labelled as EUH071: ‘corrosive to the respiratory
tract’ — see advice at 3.1.2.3.3. In addition to an appropriate acute toxicity pictogram, a corrosivity
pictogram (used for skin and eye corrosivity) may be added together with the statement ‘corrosive to the
respiratory tract’.
Note 2
In the event that an ingredient without any useable information at all is used in a mixture at a concentration
of 1 % or greater, the mixture shall be labelled with the additional statement that ‘x percent of the mixture
consists of ingredient(s) of unknown toxicity’ — see advice at 3.1.3.6.2.2.
3.2.1. Definitions
3.2.1.1. Skin Corrosion means the production of irreversible damage to the skin; namely, visible necrosis through the
epidermis and into the dermis, following the application of a test substance for up to 4 hours. Corrosive
reactions are typified by ulcers, bleeding, bloody scabs, and, by the end of observation at 14 days, by
discolouration due to blanching of the skin, complete areas of alopecia, and scars. Histopathology shall be
considered to evaluate questionable lesions.
Skin Irritation means the production of reversible damage to the skin following the application of a test
substance for up to 4 hours.
3.2.2.1. Several factors need to be considered in determining the corrosion and irritation potential of substances
before testing is undertaken. Solid substances (powders) may become corrosive or irritant when moistened or
in contact with moist skin or mucous membranes. Existing human experience and animal data from single or
repeated exposure shall be the first line of analysis, as they give information directly relevant to effects on the
skin. In vitro alternatives that have been validated and accepted may also be used to help make classification
decisions (see Article 5). In some cases enough information may be available from structurally related
compounds to make classification decisions.
3.2.2.2. Likewise, pH extremes like ≤ 2 and ≥ 11,5 may indicate the potential to cause skin effects, especially when
buffering capacity is known, although the correlation is not perfect. Generally, such substances are expected
to produce significant effects on the skin. If consideration of alkali/acid reserve suggests the substance may
not be corrosive despite the low or high pH value, then further testing shall be carried out to confirm this,
preferably by use of an appropriate validated in vitro test.
3.2.2.3. If a substance is highly toxic by the dermal route, a skin irritation/corrosion study is not practicable since the
amount of test substance to be applied considerably exceeds the toxic dose and, consequently, results in the
death of the animals. When observations are made of skin irritation/corrosion in acute toxicity studies and
are observed up through the limit dose, additional testing is not needed, provided that the dilutions used and
species tested are equivalent.
3.2.2.4. All the above information that is available on a substance shall be used in determining the need for in vivo
skin irritation testing.
Although information might be gained from the evaluation of single parameters within a tier (see
paragraph 3.2.2.5), e.g. caustic alkalis with extreme pH shall be considered as skin corrosives, there is merit in
considering the totality of existing information and making an overall weight of evidence determination. This
is especially true when there is information available on some but not all parameters. Generally, primary
emphasis shall be placed upon existing human experience and data, followed by animal experience and
testing data, followed by other sources of information, but case-by-case determinations are necessary.
3.2.2.5. A tiered approach to the evaluation of initial information shall be considered, where applicable, recognising
that all elements may not be relevant in certain cases.
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3.2.2.6. Corrosion
3.2.2.6.1. On the basis of the results of animal testing a substance is classified as corrosive, as shown in Table 3.2.1. A
corrosive substance is a substance that produces destruction of skin tissue, namely, visible necrosis through
the epidermis and into the dermis, in at least 1 tested animal after exposure up to a 4 hour duration.
Corrosive reactions are typified by ulcers, bleeding, bloody scabs and, by the end of observation at 14 days,
by discoloration due to blanching of the skin, complete areas of alopecia and scars. Histopathology shall be
considered to discern questionable lesions.
3.2.2.6.2. Three subcategories are provided within the corrosive category: subcategory 1A — where responses are noted
following up to 3 minutes exposure and up to 1 hour observation; subcategory 1B — where responses are
described following exposure between 3 minutes and 1 hour and observations up to 14 days; and
subcategory 1C — where responses occur after exposures between 1 hour and 4 hours and observations up
to 14 days.
3.2.2.6.3. The use of human data is discussed in paragraphs 3.2.2.1 and 3.2.2.4 and also in paragraphs 1.1.1.3, 1.1.1.4
and.1.1.1.5.
Table 3.2.1
3.2.2.7. Irritation
3.2.2.7.1. Using the results of animal testing a single irritant category (Category 2) is presented in Table 3.2.2. The use of
human data is discussed in paragraphs 3.2.2.1 and 3.2.2.4 and also in paragraphs 1.1.1.3, 1.1.1.4
and.1.1.1.5. The major criterion for the irritant category is that at least 2 of 3 tested animals have a mean
score of ≥ 2,3 - ≤ 4,0.
Table 3.2.2
Category Criteria
(1) Mean value of ≥ 2,3 - ≤ 4,0 for erythema/eschar or for oedema in at least 2 of 3 tested
animals from gradings at 24, 48 and 72 hours after patch removal or, if reactions are
delayed, from grades on 3 consecutive days after the onset of skin reactions; or
Category 2: (2) Inflammation that persists to the end of the observation period normally 14 days in
at least 2 animals, particularly taking into account alopecia (limited area),
Irritant hyperkeratosis, hyperplasia, and scaling; or
(3) In some cases where there is pronounced variability of response among animals, with
very definite positive effects related to chemical exposure in a single animal but less
than the criteria above.
3.2.2.8.1. Animal irritant responses within a test can be quite variable, as they are with corrosion. The major criterion
for classification of a substance as irritant to skin, as shown in paragraph 3.2.2.7.1, is the mean value of the
scores for either erythema/eschar or oedema calculated in at least 2 of 3 tested animals. A separate irritant
criterion accommodates cases when there is a significant irritant response but less than the mean score
criterion for a positive test. For example, a test material might be designated as an irritant if at least 1 of 3
tested animals shows a very elevated mean score throughout the study, including lesions persisting at the end
of an observation period of normally 14 days. Other responses could also fulfil this criterion. However, it
should be ascertained that the responses are the result of chemical exposure.
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3.2.2.8.2. Reversibility of skin lesions is another consideration in evaluating irritant responses. When inflammation
persists to the end of the observation period in 2 or more test animals, taking into consideration alopecia
(limited area), hyperkeratosis, hyperplasia and scaling, then a material shall be considered to be an irritant.
3.2.3.1. Classification of mixtures when data are available for the complete mixture
3.2.3.1.1. The mixture will be classified using the criteria for substances, and taking into account the testing and
evaluation strategies to develop data for these hazard classes.
3.2.3.1.2. Unlike other hazard classes, there are alternative tests available for skin corrosivity of certain types of
substances and mixtures that can give an accurate result for classification purposes, as well as being simple
and relatively inexpensive to perform. When considering testing of the mixture, classifiers are encouraged to
use a tiered weight of evidence strategy as included in the criteria for classification of substances for skin
corrosion and irritation (paragraph 3.2.2.5), to help ensure an accurate classification as well as avoid
unnecessary animal testing. A mixture is considered corrosive to skin (Skin Corrosive Category 1) if it has a
pH of 2 or less or a pH of 11,5 or greater. If consideration of alkali/acid reserve suggests the substance or
mixture may not be corrosive despite the low or high pH value, then further testing shall be carried out to
confirm this, preferably by use of an appropriate validated in vitro test.
3.2.3.2. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.2.3.2.1. Where the mixture itself has not been tested to determine its skin irritation/corrosion hazards, but there are
sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards
of the mixture, these data shall be used in accordance with the bridging rules set out in section 1.1.3.
3.2.3.3. Classification of mixtures when data are available for all components or only for some components of the mixture
3.2.3.3.1. In order to make use of all available data for purposes of classifying the skin irritation/corrosion hazards of
mixtures, the following assumption has been made and is applied where appropriate in the tiered approach:
Assumption: the ‘relevant ingredients’ of a mixture are those which are present in concentrations of 1 % (w/w
for solids, liquids, dusts, mists and vapours and v/v for gases) or greater, unless there is a presumption (e.g., in
the case of corrosive ingredients) that an ingredient present at a concentration of less than 1 % can still be
relevant for classifying the mixture for skin irritation/corrosion.
3.2.3.3.2. In general, the approach to classification of mixtures as irritant or corrosive to skin when data are available on
the components, but not on the mixture as a whole, is based on the theory of additivity, such that each
corrosive or irritant component contributes to the overall irritant or corrosive properties of the mixture in
proportion to its potency and concentration. A weighting factor of 10 is used for corrosive components
when they are present at a concentration below the generic concentration limit for classification with
Category 1, but are at a concentration that will contribute to the classification of the mixture as an irritant.
The mixture is classified as corrosive or irritant when the sum of the concentrations of such components
exceeds a concentration limit.
3.2.3.3.3. Table 3.2.3 provides the generic concentration limits to be used to determine if the mixture is considered to
be an irritant or a corrosive to the skin.
3.2.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids
and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in para-
graphs 3.2.3.3.1 and 3.2.3.3.2 may not be applicable given that many of such substances are corrosive or
irritant at concentrations < 1 %.
3.2.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as a classification criterion (see
paragraph 3.2.3.1.2) since pH is a better indicator of corrosion than the concentration limits of Table 3.2.3.
3.2.3.3.4.3. A mixture containing ingredients that are corrosive or irritant to the skin and that cannot be classified on the
basis of the additivity approach (Table 3.2.3), due to chemical characteristics that make this approach
unworkable, shall be classified as Skin Corrosive Category 1A, 1B or 1C if it contains ≥ 1 % of an ingredient
classified in Category 1A, 1B or 1C respectively or as Category 2 when it contains ≥ 3 % of an irritant
ingredient. Classification of mixtures with ingredients for which the approach in Table 3.2.3 does not apply is
summarised in Table 3.2.4.
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3.2.3.3.5. On occasion, reliable data may show that the skin corrosion/irritation hazard of an ingredient will not be
evident when present at a level above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4. In
these cases the mixture shall be classified according to that data (see also Articles 10 and 11). On other
occasions, when it is expected that the skin corrosion/irritation hazard of an ingredient is not evident when
present at a level above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4, testing of the
mixture shall be considered. In those cases the tiered weight of evidence strategy shall be applied, as described
in paragraph 3.2.2.5.
3.2.3.3.6. If there are data showing that (an) ingredient(s) is/are corrosive or irritant at a concentration of < 1 %
(corrosive) or < 3 % (irritant), the mixture shall be classified accordingly.
Table 3.2.3
Generic concentration limits of ingredients classified for skin corrosive/irritant hazard (Category 1
or 2) that trigger classification of the mixture as corrosive/irritant to skin
Note
The sum of all ingredients of a mixture classified as Skin Corrosive Category 1A, 1B or 1C respectively, shall
each be ≥ 5 % respectively in order to classify the mixture as either Skin Corrosive Category 1A, 1B or 1C. If
the sum of the Skin Corrosive Category 1A ingredients is < 5 % but the sum of Category 1A+1B ingredients
is ≥ 5 %, the mixture shall be classified as Skin Corrosive Category 1B. Similarly, if the sum of Skin Corrosive
Category 1A+1B ingredients is < 5 % but the sum of Category 1A+1B+1C ingredients is ≥ 5 % the mixture
shall be classified as Skin Corrosive Category 1C.
Table 3.2.4
Generic concentration limits of ingredients of a mixture for which the additivity approach does not
apply, that trigger classification of the mixture as corrosive/irritant to skin
3.2.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.2.5.
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Table 3.2.5
3.3.1. Definitions
3.3.1.1. Serious eye damage means the production of tissue damage in the eye, or serious physical decay of vision,
following application of a test substance to the anterior surface of the eye, which is not fully reversible within
21 days of application.
Eye irritation means the production of changes in the eye following the application of test substance to the
anterior surface of the eye, which are fully reversible within 21 days of application.
3.3.2.1. The classification system for substances involves a tiered testing and evaluation scheme, combining pre-
existing information on serious ocular tissue damage and on eye irritation (including data relating to
historical human or animal experience) as well as considerations on (Q)SAR and the output of validated in
vitro tests in order to avoid unnecessary animal testing.
3.3.2.2. Before any in vivo testing for serious eye damage/eye irritation is carried out, all existing information on a
substance shall be reviewed. Preliminary decisions can often be made from existing data as to whether a
substance causes serious (i.e. irreversible) damage to the eyes. If a substance can be classified on the basis of
these data, no testing is required.
3.3.2.3. Several factors need to be considered in determining the serious eye damage or irritation potential of a
substance before testing is undertaken. Accumulated human and animal experience shall be the first line of
analysis, as it gives information directly relevant to effects on the eye. In some cases enough information may
be available from structurally related compounds to make hazard decisions. Likewise, pH extremes like ≤ 2
and ≥ 11,5 may produce serious eye damage, especially when associated with significant buffering capacity.
Such substances are expected to produce significant effects on the eyes. Possible skin corrosion has to be
L 353/92 EN Official Journal of the European Union 31.12.2008
evaluated prior to consideration of serious eye damage/eye irritation in order to avoid testing for local effects
on eyes with skin corrosive substances. Skin corrosive substances shall be considered as leading to serious
damage to the eyes as well (Category 1), while skin irritant substances may be considered as leading to eye
irritation (Category 2). In vitro alternatives that have been validated and accepted can be used to make
classification decisions (see Article 5).
3.3.2.4. All the above information that is available on a substance shall be used in determining the need for in vivo
eye irritation testing. Although information may be gained from the evaluation of single parameters within a
tier (e.g. caustic alkalis with extreme pH shall be considered as local corrosives), the totality of existing
information shall be considered in making an overall weight of evidence determination, particularly when
there is information available on some but not all parameters. Generally, primary emphasis shall be placed
upon expert judgement, considering human experience with the substance, followed by the outcome of skin
irritation testing and of well-validated alternative methods. Animal testing with corrosive substances or
mixtures shall be avoided whenever possible.
3.3.2.5. A tiered approach to the evaluation of initial information shall be considered where applicable, while
recognising that all elements may not be relevant in certain cases.
3.3.2.6.1. Substances that have the potential to seriously damage the eyes are classified in Category 1 (irreversible effects
on the eye). Substances are classified in this hazard category on the basis of the results of animal testing, in
accordance with the criteria listed in Table 3.3.1. These observations include animals with grade 4 cornea
lesions and other severe reactions (e.g., destruction of cornea) observed at any time during the test, as well as
persistent corneal opacity, discoloration of the cornea by a dye substance, adhesion, pannus, and interference
with the function of the iris or other effects that impair sight. In this context, persistent lesions are considered
those which are not fully reversible within an observation period of normally 21 days. Substances are also
classified in Category 1 if they fulfil the criteria of corneal opacity ≥ 3 or iritis > 1,5 detected in a Draize eye
test with rabbits, recognising that such severe lesions usually do not reverse within a 21-day observation
period.
Table 3.3.1
Category Criteria
If, when applied to the eye of an animal, a substance produces:
— at least in one animal effects on the cornea, iris or conjunctiva that are not expected to
reverse or have not fully reversed within an observation period of normally 21 days;
Irreversible and/or
effects on the — at least in 2 of 3 tested animals, a positive response of:
eye
(Category 1) — corneal opacity ≥ 3 and/or
— iritis > 1,5
calculated as the mean scores following grading at 24, 48 and 72 hours after installation of
the test material.
3.3.2.6.2. The use of human data is discussed in paragraphs 3.3.2.1, 3.3.2.4, and also in paragraphs 1.1.1.3, 1.1.1.4
and 1.1.1.5.
3.3.2.7.1. Substances that have the potential to induce reversible eye irritation are classified in Category 2 (irritating to
eyes).
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Table 3.3.2
Category Criteria
if, when applied to the eye of an animal, a substance
produces:
— at least in 2 of 3 tested animals, a positive
response of:
— corneal opacity ≥ 1 and/or
Irritating to eyes — iritis ≥ 1, and/or
(Category 2) — conjunctival redness ≥ 2 and/or
— conjunctival oedema (chemosis) ≥ 2
— calculated as the mean scores following
grading at 24, 48 and 72 hours after
installation of the test material, and which
fully reverses within an observation period of
21 days
3.3.2.7.2. For those substances where there is pronounced variability among animal responses, this information shall be
taken into account in determining the classification.
3.3.3.1. Classification of mixtures when data are available for the complete mixture
3.3.3.1.1. The mixture will be classified using the criteria for substances, and taking into account the testing and
evaluation strategies used to develop data for these hazard classes.
3.3.3.1.2. Unlike other hazard classes, there are alternative tests available for skin corrosivity of certain types of
mixtures that give an accurate result for classification purposes, as well as being simple and relatively
inexpensive to perform. When considering testing of the mixture classifiers are encouraged to use a tiered
weight of evidence strategy as included in the criteria for classification of substances for skin corrosion and
serious eye damage and eye irritation to help ensure an accurate classification, as well as avoid unnecessary
animal testing. A mixture is considered to cause serious eye damage (Category 1) if it has a pH ≤ 2,0 or ≥
11,5. If consideration of alkali/acid reserve suggests the mixture may not have the potential to cause serious
eye damage despite the low or high pH value, then further testing needs to be carried out to confirm this,
preferably by use of an appropriate validated in vitro test.
3.3.3.2. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.3.3.2.1. Where the mixture itself has not been tested to determine its skin corrosivity or potential to cause serious eye
damage or irritation, but there are sufficient data on the individual ingredients and similar tested mixtures to
adequately characterise the hazards of the mixture, these data shall be used in accordance with the bridging
rules set out in section 1.1.3.
3.3.3.3. Classification of mixtures when data are available for all components or only for some components of the mixture
3.3.3.3.1. In order to make use of all available data for purposes of classifying the eye irritation/serious eye damaging
properties of the mixtures, the following assumption has been made and is applied where appropriate in the
tiered approach:
Assumption: The ‘relevant ingredients’ of a mixture are those which are present in concentrations of 1 % (w/w
for solids, liquids, dusts, mists and vapours and v/v for gases) or greater, unless there is a presumption (e.g. in
the case of corrosive ingredients) that an ingredient present at a concentration of less than 1 % is still relevant
for classifying the mixture for eye irritation/serious eye damage.
3.3.3.3.2. In general, the approach to classification of mixtures as eye irritant or seriously damaging to the eye when
data are available on the components, but not on the mixture as a whole, is based on the theory of additivity,
such that each corrosive or irritant component contributes to the overall irritant or corrosive properties of
the mixture in proportion to its potency and concentration. A weighting factor of 10 is used for corrosive
components when they are present at a concentration below the generic concentration limit for classification
in Category 1, but are at a concentration that will contribute to the classification of the mixture as an irritant.
The mixture is classified as seriously damaging to the eye or eye irritant when the sum of the concentrations
of such components exceeds a concentration limit.
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3.3.3.3.3. Table 3.3.3 provides the generic concentration limits to be used to determine if the mixture shall be classified
as irritant or as seriously damaging to the eye.
3.3.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids
and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in para-
graphs 3.3.3.3.1 and 3.3.3.3.2 might not work given that many of such substances are corrosive or irritant
at concentrations < 1 %.
3.3.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as classification criteria (see
paragraph 3.3.2.3) since pH will be a better indicator of serious eye damage than the generic concentration
limits of Table 3.3.3.
3.3.3.3.4.3. A mixture containing corrosive or irritant ingredients that cannot be classified based on the additivity
approach (Table 3.3.3), due to chemical characteristics that make this approach unworkable, shall be classified
as Category 1 for effects on the eye if it contains ≥ 1 % of a corrosive ingredient and as Category 2 when it
contains ≥ 3 % of an irritant ingredient. Classification of mixtures with ingredients for which the approach in
Table 3.3.3 does not apply is summarised in Table 3.3.4.
3.3.3.3.5. On occasion, reliable data may show that the reversible/irreversible eye effects of an ingredient will not be
evident when present at a level above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4. In
these cases the mixture shall be classified according to those data. On other occasions, when it is expected
that the skin corrosion/irritation hazards or the reversible/irreversible eye effects of an ingredient will not be
evident when present at a level above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4,
testing of the mixture shall be considered. In those cases, the tiered weight of evidence strategy shall be
applied.
3.3.3.3.6. If there are data showing that (an) ingredient(s) may be corrosive or irritant at a concentration of < 1 %
(corrosive) or < 3 % (irritant), the mixture shall be classified accordingly.
Table 3.3.3
Generic concentration limits of ingredients of a mixture classified as Skin corrosive Category 1 and/
or eye Category 1 or 2 for effects on the eye that trigger classification of the mixture for effects on
the eye (Category 1 or 2)
Table 3.3.4
Generic concentration limits of ingredients of a mixture for which the additivity approach does not
apply, that trigger classification of the mixture as hazardous to the eye
3.3.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.3.5.
Table 3.3.5
3.4.1.1. Respiratory sensitiser means a substance that will lead to hypersensitivity of the airways following inhalation
of the substance.
3.4.1.2. Skin sensitiser means a substance that will lead to an allergic response following skin contact.
3.4.1.3. For the purpose of section 3.4, sensitisation includes two phases: the first phase is induction of specialised
immunological memory in an individual by exposure to an allergen. The second phase is elicitation, i.e.
production of a cell-mediated or antibody-mediated allergic response by exposure of a sensitised individual to
an allergen.
3.4.1.4. For respiratory sensitisation, the pattern of induction followed by elicitation phases is shared in common with
skin sensitisation. For skin sensitisation, an induction phase is required in which the immune system learns to
react; clinical symptoms can then arise when subsequent exposure is sufficient to elicit a visible skin reaction
(elicitation phase). As a consequence, predictive tests usually follow this pattern in which there is an induction
phase, the response to which is measured by a standardised elicitation phase, typically involving a patch test.
The local lymph node assay is the exception, directly measuring the induction response. Evidence of skin
sensitisation in humans normally is assessed by a diagnostic patch test.
3.4.1.5. Usually, for both skin and respiratory sensitisation, lower levels are necessary for elicitation than are required
for induction. Provisions for alerting sensitised individuals to the presence of a particular sensitiser in a
mixture can be found at section 3.4.4.
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— Respiratory Sensitisation;
— Skin Sensitisation.
Substances shall be classified as respiratory sensitisers (Category 1) in accordance with the criteria in
Table 3.4.1:
Table 3.4.1
Category Criteria
Substances shall be classified as respiratory sensitisers (Category 1) in accordance with the
following criteria:
Category 1 (a) if there is evidence in humans that the substance can lead to specific respiratory
hypersensitivity and/or
(b) if there are positive results from an appropriate animal test.
3.4.2.1.1.1. Evidence that a substance can induce specific respiratory hypersensitivity will normally be based on human
experience. In this context, hypersensitivity is normally seen as asthma, but other hypersensitivity reactions
such as rhinitis/conjunctivitis and alveolitis are also considered. The condition will have the clinical character
of an allergic reaction. However, immunological mechanisms do not have to be demonstrated.
3.4.2.1.1.2. When considering the human evidence, it is necessary for a decision on classification to take into account, in
addition to the evidence from the cases:
The use of human data is discussed in paragraphs 1.1.1.3, 1.1.1.4 and 1.1.1.5.
(a) clinical history and data from appropriate lung function tests related to exposure to the substance,
confirmed by other supportive evidence which may include:
(iii) studies that indicate other specific hypersensitivity reactions where immunological mechanisms
of action have not been proven, e.g. repeated low-level irritation, pharmacologically mediated
effects;
(b) data from one or more positive bronchial challenge tests with the substance conducted according to
accepted guidelines for the determination of a specific hypersensitivity reaction.
3.4.2.1.1.4. Clinical history shall include both medical and occupational history to determine a relationship between
exposure to a specific substance and development of respiratory hypersensitivity. Relevant information
includes aggravating factors both in the home and workplace, the onset and progress of the disease, family
history and medical history of the patient in question. The medical history shall also include a note of other
allergic or airway disorders from childhood, and smoking history.
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3.4.2.1.1.5. The results of positive bronchial challenge tests are considered to provide sufficient evidence for classification
on their own. It is however recognised that in practice many of the examinations listed above will already
have been carried out.
3.4.2.1.2.1. Data from appropriate animal studies (1) which may be indicative of the potential of a substance to cause
sensitisation by inhalation in humans (2) may include:
(i) measurements of Immunoglobulin E (IgE) and other specific immunological parameters in mice;
3.4.2.2.1. Substances shall be classified as skin sensitisers (Category 1) in accordance with the criteria in Table 3.4.2:
Table 3.4.2
Category Criteria
Substances shall be classified as skin sensitisers (Category 1) in accordance with the
following criteria:
Category 1 (i) if there is evidence in humans that the substance can lead to sensitisation by skin
contact in a substantial number of persons, or
(ii) if there are positive results from an appropriate animal test (see specific criteria in
paragraph 3.4.2.2.4.1).
3.4.2.2.2.1. For classification of a substance as a skin sensitiser, evidence shall include any or all of the following:
(a) positive data from patch testing, normally obtained in more than one dermatology clinic;
(b) epidemiological studies showing allergic contact dermatitis caused by the substance; Situations in which
a high proportion of those exposed exhibit characteristic symptoms are to be looked at with special
concern, even if the number of cases is small;
(d) positive data from experimental studies on humans (see Article 7(3));
(e) well documented episodes of allergic contact dermatitis, normally obtained in more than one
dermatology clinic.
The use of human data is discussed in paragraphs 1.1.1.3, 1.1.1.4 and 1.1.1.5.
3.4.2.2.2.2. Positive effects seen in either humans or animals will normally justify classification. Evidence from animal
studies (see section 3.4.2.2.4) is usually much more reliable than evidence from human exposure. However, in
cases where evidence is available from both sources, and there is conflict between the results, the quality and
reliability of the evidence from both sources must be assessed in order to resolve the question of classification
on a case-by-case basis. Normally, human data are not generated in controlled experiments with volunteers
for the purpose of hazard classification but rather as part of risk assessment to confirm lack of effects seen in
animal tests. Consequently, positive human data on skin sensitisation are usually derived from case-control or
other, less defined studies. Evaluation of human data must therefore be carried out with caution, as the
frequency of cases reflect, in addition to the intrinsic properties of the substances, factors such as the
exposure situation, bioavailability, individual predisposition and preventive measures taken. Negative human
data can not normally be used to negate positive results from animal studies.
(1) At present recognised animal models for the testing of respiratory hypersensitivity are not available.
(2) The mechanisms by which substances induce symptoms of asthma are not yet fully known. For preventative measures, these substances
are considered respiratory sensitisers. However, if on the basis of the evidence, it can be demonstrated that these substances induce
symptoms of asthma by irritation only in people with bronchial hyper reactivity, they should not be considered as respiratory sensitisers.
L 353/98 EN Official Journal of the European Union 31.12.2008
3.4.2.2.2.3. If none of the above mentioned conditions are met the substance need not be classified as a skin sensitiser.
However, a combination of two or more indicators of skin sensitisation as listed below may alter the decision,
which shall be considered on a case-by-case basis:
(b) epidemiological studies of limited power, e.g. where chance, bias or confounders have not been ruled
out fully with reasonable confidence;
(c) data from animal tests, performed according to existing guidelines, which do not meet the criteria for a
positive result described in paragraph 3.4.2.2.4.1, but which are sufficiently close to the limit to be
considered significant;
3.4.2.2.3.1. Some substances meeting the criteria for classification as respiratory sensitisers may in addition cause
immunological contact urticaria. Consideration shall be given to classifying these substances also as skin
sensitisers and including information concerning contact urticaria on the label or in the SDS using
appropriate warning information.
3.4.2.2.3.2. For substances which produce signs of immunological contact urticaria but which do not fulfil the criteria as
a respiratory sensitiser, consideration shall be given to classification as a skin sensitiser. There is no recognised
animal model available to identify substances which cause immunological contact urticaria. Therefore,
classification will normally be based on human evidence, which will be similar to that for skin sensitisation.
3.4.2.2.4.1. When an adjuvant type guinea pig test method for skin sensitisation is used, a response of at least 30 % of the
animals is considered as positive. For a non-adjuvant guinea pig test method a response of at least 15 % of the
animals is considered positive. Test methods for skin sensitisation described in Regulation (EC) No 440/2008
adopted in accordance with Article 13(3) of Regulation (EC) No 1907/2006 (‘Test Method Regulation’) shall
be used, or other methods provided that they are well-validated and scientific justification is given.
3.4.3.1. Classification of mixtures when data are available for the complete mixture
3.4.3.1.1. When reliable and good quality evidence from human experience or appropriate studies in experimental
animals, as described in the criteria for substances, is available for the mixture, then the mixture can be
classified by weight of evidence evaluation of these data. Care shall be exercised in evaluating data on
mixtures, that the dose used does not render the results inconclusive.
3.4.3.2. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.4.3.2.1. Where the mixture itself has not been tested to determine its sensitising properties, but there are sufficient
data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the
mixture, these data shall be used in accordance with the bridging rules set out in section 1.1.3.
3.4.3.3. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture
3.4.3.3.1. The mixture shall be classified as a respiratory or skin sensitiser when at least one ingredient has been
classified as a respiratory or skin sensitiser and is present at or above the appropriate generic concentration
limit as shown in Table 3.4.3 for solid/liquid and gas respectively.
3.4.3.3.2. Some substances that are classified as sensitisers may elicit a response, when present in a mixture in quantities
below the concentrations established in Table 3.4.1, in individuals who are already sensitised to the substance
or mixture (see Note 1 to Table 3.4.3).
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Table 3.4.3
Note 1
This concentration limit is generally used for the application of the special labelling requirements of
Annex II section 2.8 to protect already sensitised individuals. A SDS is required for the mixture containing an
ingredient above this concentration.
Note 2
Note 3
3.4.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.4.4.
Table 3.4.4
3.5.1.1. A mutation means a permanent change in the amount or structure of the genetic material in a cell. The term
‘mutation’ applies both to heritable genetic changes that may be manifested at the phenotypic level and to the
underlying DNA modifications when known (including specific base pair changes and chromosomal
translocations). The term ‘mutagenic’ and ‘mutagen’ will be used for agents giving rise to an increased
occurrence of mutations in populations of cells and/or organisms.
3.5.1.2. The more general terms ‘genotoxic’ and ‘genotoxicity’ apply to agents or processes which alter the structure,
information content, or segregation of DNA, including those which cause DNA damage by interfering with
normal replication processes, or which in a non-physiological manner (temporarily) alter its replication.
Genotoxicity test results are usually taken as indicators for mutagenic effects.
3.5.2.1. This hazard class is primarily concerned with substances that may cause mutations in the germ cells of
humans that can be transmitted to the progeny. However, the results from mutagenicity or genotoxicity tests
in vitro and in mammalian somatic and germ cells in vivo are also considered in classifying substances and
mixtures within this hazard class.
3.5.2.2. For the purpose of classification for germ cell mutagenicity, substances are allocated to one of two categories
as shown in Table 3.5.1.
Table 3.5.1
Categories Criteria
Category 1A: The classification in Category 1A is based on positive evidence from human
epidemiological studies.
Substances to be regarded as if they induce heritable mutations in the germ cells of
humans.
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Categories Criteria
CATEGORY 2: Substances which cause concern for humans owing to the possibility that they may
induce heritable mutations in the germ cells of humans
The classification in Category 2 is based on:
— positive evidence obtained from experiments in mammals and/or in some cases
from in vitro experiments, obtained from:
— somatic cell mutagenicity tests in vivo, in mammals; or
— other in vivo somatic cell genotoxicity tests which are supported by
positive results from in vitro mutagenicity assays.
Note: Substances which are positive in in vitro mammalian mutagenicity assays, and
which also show chemical structure activity relationship to known germ cell
mutagens, shall be considered for classification as Category 2 mutagens.
3.5.2.3.1. To arrive at a classification, test results are considered from experiments determining mutagenic and/or
genotoxic effects in germ and/or somatic cells of exposed animals. Mutagenic and/or genotoxic effects
determined in in vitro tests shall also be considered.
3.5.2.3.2. The system is hazard based, classifying substances on the basis of their intrinsic ability to induce mutations in
germ cells. The scheme is, therefore, not meant for the (quantitative) risk assessment of substances.
3.5.2.3.3. Classification for heritable effects in human germ cells is made on the basis of well conducted, sufficiently
validated tests, preferably as described in Regulation (EC) No 440/2008 adopted in accordance with
Article 13(3) of Regulation (EC) No 1907/2006 (‘Test Method Regulation’) such as those listed in the
following paragraphs. Evaluation of the test results shall be done using expert judgement and all the available
evidence shall be weighed in arriving at a classification.
3.5.2.3.9. The classification of individual substances shall be based on the total weight of evidence available, using
expert judgement (See 1.1.1). In those instances where a single well-conducted test is used for classification, it
shall provide clear and unambiguously positive results. If new, well validated, tests arise these may also be
used in the total weight of evidence to be considered. The relevance of the route of exposure used in the study
of the substance compared to the route of human exposure shall also be taken into account.
3.5.3.1. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture
3.5.3.1.1. The mixture shall be classified as a mutagen when at least one ingredient has been classified as a Category 1A,
Category 1B or Category 2 mutagen and is present at or above the appropriate generic concentration limit as
shown in Table 3.5.2 for Category 1A, Category 1B and Category 2 respectively.
Table 3.5.2
Generic concentration limits of ingredients of a mixture classified as germ cell mutagens that trigger
classification of the mixture.
Note
The concentration limits in the table above apply to solids and liquids (w/w units) as well as gases (v/v units).
3.5.3.2. Classification of mixtures when data are available for the complete mixture
3.5.3.2.1. Classification of mixtures will be based on the available test data for the individual ingredients of the mixture
using concentration limits for the ingredients classified as germ cell mutagens. On a case-by-case basis, test
data on mixtures may be used for classification when demonstrating effects that have not been established
from the evaluation based on the individual ingredients. In such cases, the test results for the mixture as a
whole must be shown to be conclusive taking into account dose and other factors such as duration,
observations, sensitivity and statistical analysis of germ cell mutagenicity test systems. Adequate
documentation supporting the classification shall be retained and made available for review upon request.
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3.5.3.3. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.5.3.3.1. Where the mixture itself has not been tested to determine its germ cell mutagenicity hazard, but there are
sufficient data on the individual ingredients and similar tested mixtures (subject to paragraph 3.5.3.2.1), to
adequately characterise the hazards of the mixture, these data shall be used in accordance with the applicable
bridging rules set out in section 1.1.3.
3.5.4.1. Label elements shall be used in accordance with Table 3.5.3, for substances or mixtures meeting the criteria
for classification in this hazard class.
Table 3.5.3
It is increasingly accepted that the process of chemical-induced tumorigenesis in humans and animals
involves genetic changes for example in proto-oncogenes and/or tumour suppresser genes of somatic cells.
Therefore, the demonstration of mutagenic properties of substances in somatic and/or germ cells of
mammals in vivo may have implications for the potential classification of these substances as carcinogens (see
also Carcinogenicity, section 3.6, paragraph 3.6.2.2.6).
3.6. Carcinogenicity
3.6.1. Definition
3.6.1.1. Carcinogen means a substance or a mixture of substances which induce cancer or increase its incidence.
Substances which have induced benign and malignant tumours in well performed experimental studies on
animals are considered also to be presumed or suspected human carcinogens unless there is strong evidence
that the mechanism of tumour formation is not relevant for humans.
3.6.2.1. For the purpose of classification for carcinogenicity, substances are allocated to one of two categories based
on strength of evidence and additional considerations (weight of evidence). In certain instances, route-specific
classification may be warranted, if it can be conclusively proved that no other route of exposure exhibits the
hazard.
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Table 3.6.1
Categories Criteria
CATEGORY 1: Known or presumed human carcinogens
A substance is classified in Category 1 for carcinogenicity on the basis of
epidemiological and/or animal data. A substance may be further distinguished
as:
Category 1A: Category 1A, known to have carcinogenic potential for humans, classification is
largely based on human evidence, or
Category 1B: Category 1B, presumed to have carcinogenic potential for humans, classification
is largely based on animal evidence.
The classification in Category 1A and 1B is based on strength of evidence
together with additional considerations (see section 3.6.2.2). Such evidence may
be derived from:
— human studies that establish a causal relationship between human
exposure to a substance and the development of cancer (known human
carcinogen); or
— animal experiments for which there is sufficient (1) evidence to
demonstrate animal carcinogenicity (presumed human carcinogen).
In addition, on a case-by-case basis, scientific judgement may warrant a decision
of presumed human carcinogenicity derived from studies showing limited
evidence of carcinogenicity in humans together with limited evidence of
carcinogenicity in experimental animals.
CATEGORY 2: Suspected human carcinogens
The placing of a substance in Category 2 is done on the basis of evidence
obtained from human and/or animal studies, but which is not sufficiently
convincing to place the substance in Category 1A or 1B, based on strength of
evidence together with additional considerations (see section 3.6.2.2). Such
evidence may be derived either from limited (1) evidence of carcinogenicity in
human studies or from limited evidence of carcinogenicity in animal studies.
(1) Note: See 3.6.2.2.4.
3.6.2.2.1. Classification as a carcinogen is made on the basis of evidence from reliable and acceptable studies and is
intended to be used for substances which have an intrinsic property to cause cancer. The evaluations shall be
based on all existing data, peer-reviewed published studies and additional acceptable data.
3.6.2.2.2. Classification of a substance as a carcinogen is a process that involves two interrelated determinations:
evaluations of strength of evidence and consideration of all other relevant information to place substances
with human cancer potential into hazard categories.
3.6.2.2.3. Strength of evidence involves the enumeration of tumours in human and animal studies and determination of
their level of statistical significance. Sufficient human evidence demonstrates causality between human
exposure and the development of cancer, whereas sufficient evidence in animals shows a causal relationship
between the substance and an increased incidence of tumours. Limited evidence in humans is demonstrated
by a positive association between exposure and cancer, but a causal relationship cannot be stated. Limited
evidence in animals is provided when data suggest a carcinogenic effect, but are less than sufficient. The terms
‘sufficient’ and ‘limited’ have been used here as they have been defined by the International Agency for
Research on Cancer (IARC) and read as follows:
The evidence relevant to carcinogenicity from studies in humans is classified into one of the following
categories:
— limited evidence of carcinogenicity: a positive association has been observed between exposure to
the agent and cancer for which a causal interpretation is considered to be credible, but chance,
bias or confounding could not be ruled out with reasonable confidence.
Carcinogenicity in experimental animals can be evaluated using conventional bioassays, bioassays that
employ genetically modified animals, and other in-vivo bioassays that focus on one or more of the
critical stages of carcinogenesis. In the absence of data from conventional long-term bioassays or from
assays with neoplasia as the end-point, consistently positive results in several models that address
several stages in the multistage process of carcinogenesis should be considered in evaluating the degree
of evidence of carcinogenicity in experimental animals. The evidence relevant to carcinogenicity in
experimental animals is classified into one of the following categories:
— sufficient evidence of carcinogenicity: a causal relationship has been established between the
agent and an increased incidence of malignant neoplasms or of an appropriate combination of
benign and malignant neoplasms in (a) two or more species of animals or (b) two or more
independent studies in one species carried out at different times or in different laboratories or
under different protocols. An increased incidence of tumours in both sexes of a single species in a
well-conducted study, ideally conducted under Good Laboratory Practices, can also provide
sufficient evidence. A single study in one species and sex might be considered to provide
sufficient evidence of carcinogenicity when malignant neoplasms occur to an unusual degree
with regard to incidence, site, type of tumour or age at onset, or when there are strong findings of
tumours at multiple sites;
— limited evidence of carcinogenicity: the data suggest a carcinogenic effect but are limited for
making a definitive evaluation because, e.g. (a) the evidence of carcinogenicity is restricted to a
single experiment; (b) there are unresolved questions regarding the adequacy of the design,
conduct or interpretation of the studies; (c) the agent increases the incidence only of benign
neoplasms or lesions of uncertain neoplastic potential; or (d) the evidence of carcinogenicity is
restricted to studies that demonstrate only promoting activity in a narrow range of tissues or
organs.
3.6.2.2.4. Additional considerations (as part of the weight of evidence approach (see 1.1.1)). Beyond the determination
of the strength of evidence for carcinogenicity, a number of other factors need to be considered that influence
the overall likelihood that a substance poses a carcinogenic hazard in humans. The full list of factors that
influence this determination would be very lengthy, but some of the more important ones are considered
here.
3.6.2.2.5. The factors can be viewed as either increasing or decreasing the level of concern for human carcinogenicity.
The relative emphasis accorded to each factor depends upon the amount and coherence of evidence bearing
on each. Generally there is a requirement for more complete information to decrease than to increase the
level of concern. Additional considerations should be used in evaluating the tumour findings and the other
factors in a case-by-case manner.
3.6.2.2.6. Some important factors which may be taken into consideration, when assessing the overall level of concern
are:
(g) structural similarity to a substance(s) for which there is good evidence of carcinogenicity;
(i) comparison of absorption, distribution, metabolism and excretion between test animals and humans;
(k) mode of action and its relevance for humans, such as cytotoxicity with growth stimulation, mitogenesis,
immunosuppression, mutagenicity.
Mutagenicity: it is recognised that genetic events are central in the overall process of cancer
development. Therefore evidence of mutagenic activity in vivo may indicate that a substance has a
potential for carcinogenic effects.
3.6.2.2.7. A substance that has not been tested for carcinogenicity may in certain instances be classified in Category 1A,
Category 1B or Category 2 based on tumour data from a structural analogue together with substantial
support from consideration of other important factors such as formation of common significant metabolites,
e.g. for benzidine congener dyes.
3.6.2.2.8. The classification shall take into consideration whether or not the substance is absorbed by a given route(s);
or whether there are only local tumours at the site of administration for the tested route(s), and adequate
testing by other major route(s) show lack of carcinogenicity.
3.6.2.2.9. It is important that whatever is known of the physico-chemical, toxicokinetic and toxicodynamic properties
of the substances, as well as any available relevant information on chemical analogues, i.e. structure activity
relationship, is taken into consideration when undertaking classification.
3.6.3.1. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture
3.6.3.1.1. The mixture will be classified as a carcinogen when at least one ingredient has been classified as a
Category 1A, Category 1B or Category 2 carcinogen and is present at or above the appropriate generic
concentration limit as shown in Table 3.6.2 for Category 1A, Category 1B and Category 2 respectively.
Table 3.6.2
Note
The concentration limits in the table above apply to solids and liquids (w/w units) as well as gases (v/v units).
Note 1
If a Category 2 carcinogen is present in the mixture as an ingredient at a concentration ≥ 0,1 % a SDS shall be
available for the mixture upon request.
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3.6.3.2. Classification of mixtures when data are available for the complete mixture
3.6.3.2.1. Classification of mixtures will be based on the available test data for the individual ingredients of the mixture
using concentration limits for the ingredients classified as carcinogens. On a case-by-case basis, test data on
mixtures may be used for classification when demonstrating effects that have not been established from the
evaluation based on the individual ingredients. In such cases, the test results for the mixture as a whole must
be shown to be conclusive taking into account dose and other factors such as duration, observations,
sensitivity and statistical analysis of carcinogenicity test systems. Adequate documentation supporting the
classification shall be retained and made available for review upon request.
3.6.3.3. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.6.3.3.1. Where the mixture itself has not been tested to determine its carcinogenic hazard, but there are sufficient data
on the individual ingredients and similar tested mixtures (subject to paragraph 3.6.3.2.1) to adequately
characterise the hazards of the mixture, these data shall be used in accordance with the applicable bridging
rules set out in section 1.1.3.
3.6.4.1. Label elements shall be used in accordance with Table 3.6.3, for substances or mixtures meeting the criteria
for classification in this hazard class.
Table 3.6.3
3.7.1.1. Reproductive toxicity includes adverse effects on sexual function and fertility in adult males and females, as
well as developmental toxicity in the offspring. The definitions presented below are adapted from those
agreed as working definitions in IPCS/EHC Document No 225, Principles for Evaluating Health Risks to
Reproduction Associated with Exposure to Chemicals. For classification purposes, the known induction of
genetically based heritable effects in the offspring is addressed in Germ Cell Mutagenicity (section 3.5), since
in the present classification system it is considered more appropriate to address such effects under the
separate hazard class of germ cell mutagenicity.
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In this classification system, reproductive toxicity is subdivided under two main headings:
Some reproductive toxic effects cannot be clearly assigned to either impairment of sexual function and
fertility or to developmental toxicity. Nonetheless, substances with these effects, or mixtures containing them,
shall be classified as reproductive toxicants.
3.7.1.2. For the purpose of classification the hazard class Reproductive Toxicity is differentiated into:
— adverse effects
— on development;
Any effect of substances that has the potential to interfere with sexual function and fertility. This includes, but
is not limited to, alterations to the female and male reproductive system, adverse effects on onset of puberty,
gamete production and transport, reproductive cycle normality, sexual behaviour, fertility, parturition,
pregnancy outcomes, premature reproductive senescence, or modifications in other functions that are
dependent on the integrity of the reproductive systems.
Developmental toxicity includes, in its widest sense, any effect which interferes with normal development of
the conceptus, either before or after birth, and resulting from exposure of either parent prior to conception,
or exposure of the developing offspring during prenatal development, or postnatally, to the time of sexual
maturation. However, it is considered that classification under the heading of developmental toxicity is
primarily intended to provide a hazard warning for pregnant women, and for men and women of
reproductive capacity. Therefore, for pragmatic purposes of classification, developmental toxicity essentially
means adverse effects induced during pregnancy, or as a result of parental exposure. These effects can be
manifested at any point in the life span of the organism. The major manifestations of developmental toxicity
include (1) death of the developing organism, (2) structural abnormality, (3) altered growth, and (4) functional
deficiency.
3.7.1.5. Adverse effects on or via lactation are also included in reproductive toxicity, but for classification purposes,
such effects are treated separately (see Table 3.7.1 (b)). This is because it is desirable to be able to classify
substances specifically for an adverse effect on lactation so that a specific hazard warning about this effect can
be provided for lactating mothers.
3.7.2.1.1. For the purpose of classification for reproductive toxicity, substances are allocated to one of two categories.
Within each category, effects on sexual function and fertility, and on development, are considered separately.
In addition, effects on lactation are allocated to a separate hazard category.
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Table 3.7.1(a)
Categories Criteria
Table 3.7.1(b)
3.7.2.2.1. Classification is made on the basis of the appropriate criteria, outlined above, and an assessment of the total
weight of evidence (see 1.1.1). Classification as a reproductive toxicant is intended to be used for substances
which have an intrinsic, specific property to produce an adverse effect on reproduction and substances shall
not be so classified if such an effect is produced solely as a non-specific secondary consequence of other toxic
effects.
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The classification of a substance is derived from the hazard categories in the following order of precedence:
Category 1A, Category 1B, Category 2 and the additional Category for effects on or via lactation. If a
substance meets the criteria for classification into both of the main categories (for example Category 1B for
effects on sexual function and fertility and also Category 2 for development) then both hazard differentiations
shall be communicated by the respective hazard statements. Classification in the additional category for
effects on or via lactation will be considered irrespective of a classification into Category 1A, Category 1B or
Category 2.
3.7.2.2.2. In the evaluation of toxic effects on the developing offspring, it is important to consider the possible
influence of maternal toxicity (see section 3.7.2.4).
3.7.2.2.3. For human evidence to provide the primary basis for a Category 1A classification there must be reliable
evidence of an adverse effect on reproduction in humans. Evidence used for classification shall ideally be from
well conducted epidemiological studies which include the use of appropriate controls, balanced assessment,
and due consideration of bias or confounding factors. Less rigorous data from studies in humans shall be
supplemented with adequate data from studies in experimental animals and classification in Category 1B shall
be considered.
3.7.2.3.1. Classification as a reproductive toxicant is made on the basis of an assessment of the total weight of evidence,
see section 1.1.1. This means that all available information that bears on the determination of reproductive
toxicity is considered together, such as epidemiological studies and case reports in humans and specific
reproduction studies along with sub-chronic, chronic and special study results in animals that provide
relevant information regarding toxicity to reproductive and related endocrine organs. Evaluation of
substances chemically related to the substance under study may also be included, particularly when
information on the substance is scarce. The weight given to the available evidence will be influenced by
factors such as the quality of the studies, consistency of results, nature and severity of effects, the presence of
maternal toxicity in experimental animal studies, level of statistical significance for inter-group differences,
number of endpoints affected, relevance of route of administration to humans and freedom from bias. Both
positive and negative results are assembled together into a weight of evidence determination. A single,
positive study performed according to good scientific principles and with statistically or biologically
significant positive results may justify classification (see also 3.7.2.2.3).
3.7.2.3.2. Toxicokinetic studies in animals and humans, site of action and mechanism or mode of action study results
may provide relevant information which reduces or increases concerns about the hazard to human health. If
it is conclusively demonstrated that the clearly identified mechanism or mode of action has no relevance for
humans or when the toxicokinetic differences are so marked that it is certain that the hazardous property will
not be expressed in humans then a substance which produces an adverse effect on reproduction in
experimental animals should not be classified.
3.7.2.3.3. If, in some reproductive toxicity studies in experimental animals the only effects recorded are considered to be
of low or minimal toxicological significance, classification may not necessarily be the outcome. These effects
include small changes in semen parameters or in the incidence of spontaneous defects in the foetus, small
changes in the proportions of common foetal variants such as are observed in skeletal examinations, or in
foetal weights, or small differences in postnatal developmental assessments.
3.7.2.3.4. Data from animal studies ideally shall provide clear evidence of specific reproductive toxicity in the absence of
other systemic toxic effects. However, if developmental toxicity occurs together with other toxic effects in the
dam, the potential influence of the generalised adverse effects shall be assessed to the extent possible. The
preferred approach is to consider adverse effects in the embryo/foetus first, and then evaluate maternal
toxicity, along with any other factors which are likely to have influenced these effects, as part of the weight of
evidence. In general, developmental effects that are observed at maternally toxic doses shall not be
automatically discounted. Discounting developmental effects that are observed at maternally toxic doses can
only be done on a case-by-case basis when a causal relationship is established or refuted.
3.7.2.3.5. If appropriate information is available it is important to try to determine whether developmental toxicity is
due to a specific maternally mediated mechanism or to a non-specific secondary mechanism, like maternal
stress and the disruption of homeostasis. Generally, the presence of maternal toxicity shall not be used to
negate findings of embryo/foetal effects, unless it can be clearly demonstrated that the effects are secondary
non-specific effects. This is especially the case when the effects in the offspring are significant, e.g. irreversible
effects such as structural malformations. In some situations it can be assumed that reproductive toxicity is due
to a secondary consequence of maternal toxicity and discount the effects, if the substance is so toxic that
dams fail to thrive and there is severe inanition, they are incapable of nursing pups; or they are prostrate or
dying.
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3.7.2.4.1. Development of the offspring throughout gestation and during the early postnatal stages can be influenced
by toxic effects in the mother either through non-specific mechanisms related to stress and the disruption of
maternal homeostasis, or by specific maternally-mediated mechanisms. In the interpretation of the
developmental outcome to decide classification for developmental effects it is important to consider the
possible influence of maternal toxicity. This is a complex issue because of uncertainties surrounding the
relationship between maternal toxicity and developmental outcome. Expert judgement and a weight of
evidence approach, using all available studies, shall be used to determine the degree of influence that shall be
attributed to maternal toxicity when interpreting the criteria for classification for developmental effects. The
adverse effects in the embryo/foetus shall be first considered, and then maternal toxicity, along with any other
factors which are likely to have influenced these effects, as weight of evidence, to help reach a conclusion
about classification.
3.7.2.4.2. Based on pragmatic observation, maternal toxicity may, depending on severity, influence development via
non-specific secondary mechanisms, producing effects such as depressed foetal weight, retarded ossification,
and possibly resorptions and certain malformations in some strains of certain species. However, the limited
number of studies which have investigated the relationship between developmental effects and general
maternal toxicity have failed to demonstrate a consistent, reproducible relationship across species.
Developmental effects which occur even in the presence of maternal toxicity are considered to be evidence of
developmental toxicity, unless it can be unequivocally demonstrated on a case-by-case basis that the
developmental effects are secondary to maternal toxicity. Moreover, classification shall be considered where
there is a significant toxic effect in the offspring, e.g. irreversible effects such as structural malformations,
embryo/foetal lethality, significant post-natal functional deficiencies.
3.7.2.4.3. Classification shall not automatically be discounted for substances that produce developmental toxicity only
in association with maternal toxicity, even if a specific maternally-mediated mechanism has been
demonstrated. In such a case, classification in Category 2 may be considered more appropriate than
Category 1. However, when a substance is so toxic that maternal death or severe inanition results, or the dams
are prostrate and incapable of nursing the pups, it is reasonable to assume that developmental toxicity is
produced solely as a secondary consequence of maternal toxicity and discount the developmental effects.
Classification is not necessarily the outcome in the case of minor developmental changes, when there is only
a small reduction in foetal/pup body weight or retardation of ossification when seen in association with
maternal toxicity.
3.7.2.4.4. Some of the end points used to assess maternal effects are provided below. Data on these end points, if
available, need to be evaluated in light of their statistical or biological significance and dose response
relationship.
Maternal mortality:
an increased incidence of mortality among the treated dams over the controls shall be considered evidence of
maternal toxicity if the increase occurs in a dose-related manner and can be attributed to the systemic toxicity
of the test material. Maternal mortality greater than 10 % is considered excessive and the data for that dose
level shall not normally be considered for further evaluation.
Mating index
Fertility index
Gestation length
Consideration of the maternal body weight change and/or adjusted (corrected) maternal body weight shall be
included in the evaluation of maternal toxicity whenever such data are available. The calculation of an
adjusted (corrected) mean maternal body weight change, which is the difference between the initial and
(1) It is recognised that the Mating index and the Fertility index can also be affected by the male.
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terminal body weight minus the gravid uterine weight (or alternatively, the sum of the weights of the
foetuses), may indicate whether the effect is maternal or intrauterine. In rabbits, the body weight gain may not
be useful indicators of maternal toxicity because of normal fluctuations in body weight during pregnancy.
The observation of a significant decrease in the average food or water consumption in treated dams compared
to the control group is useful in evaluating maternal toxicity, particularly when the test material is
administered in the diet or drinking water. Changes in food or water consumption need to be evaluated in
conjunction with maternal body weights when determining if the effects noted are reflective of maternal
toxicity or more simply, unpalatability of the test material in feed or water.
Clinical evaluations (including clinical signs, markers, haematology and clinical chemistry studies):
The observation of increased incidence of significant clinical signs of toxicity in treated dams relative to the
control group is useful in evaluating maternal toxicity. If this is to be used as the basis for the assessment of
maternal toxicity, the types, incidence, degree and duration of clinical signs shall be reported in the study.
Clinical signs of maternal intoxication include: coma, prostration, hyperactivity, loss of righting reflex, ataxia,
or laboured breathing.
Post-mortem data:
Increased incidence and/or severity of post-mortem findings may be indicative of maternal toxicity. This can
include gross or microscopic pathological findings or organ weight data, including absolute organ weight,
organ-to-body weight ratio, or organ-to-brain weight ratio. When supported by findings of adverse
histopathological effects in the affected organ(s), the observation of a significant change in the average weight
of suspected target organ(s) of treated dams, compared to those in the control group, may be considered
evidence of maternal toxicity.
3.7.2.5.1. A number of internationally accepted test methods are available; these include methods for developmental
toxicity testing (e.g. OECD Test Guideline 414), and methods for one or two-generation toxicity testing (e.g.
OECD Test Guidelines 415, 416).
3.7.2.5.2. Results obtained from Screening Tests (e.g. OECD Guidelines 421 — Reproduction/Developmental Toxicity
Screening Test, and 422 — Combined Repeated Dose Toxicity Study with Reproduction/Development
Toxicity Screening Test) can also be used to justify classification, although it is recognised that the quality of
this evidence is less reliable than that obtained through full studies.
3.7.2.5.3. Adverse effects or changes, seen in short- or long-term repeated dose toxicity studies, which are judged likely
to impair reproductive function and which occur in the absence of significant generalised toxicity, may be
used as a basis for classification, e.g. histopathological changes in the gonads.
3.7.2.5.4. Evidence from in vitro assays, or non-mammalian tests, and from analogous substances using structure-
activity relationship (SAR), can contribute to the procedure for classification. In all cases of this nature, expert
judgement must be used to assess the adequacy of the data. Inadequate data shall not be used as a primary
support for classification.
3.7.2.5.5. It is preferable that animal studies are conducted using appropriate routes of administration which relate to
the potential route of human exposure. However, in practice, reproductive toxicity studies are commonly
conducted using the oral route, and such studies will normally be suitable for evaluating the hazardous
properties of the substance with respect to reproductive toxicity. However, if it can be conclusively
demonstrated that the clearly identified mechanism or mode of action has no relevance for humans or when
the toxicokinetic differences are so marked that it is certain that the hazardous property will not be expressed
in humans then a substance which produces an adverse effect on reproduction in experimental animals shall
not be classified.
3.7.2.5.6. Studies involving routes of administration such as intravenous or intraperitoneal injection, which result in
exposure of the reproductive organs to unrealistically high levels of the test substance, or elicit local damage
to the reproductive organs, including irritation, must be interpreted with extreme caution and on their own
are not normally the basis for classification.
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3.7.2.5.7. There is general agreement about the concept of a limit dose, above which the production of an adverse effect
is considered to be outside the criteria which lead to classification, but not regarding the inclusion within the
criteria of a specific dose as a limit dose. However, some guidelines for test methods, specify a limit dose,
others qualify the limit dose with a statement that higher doses may be necessary if anticipated human
exposure is sufficiently high that an adequate margin of exposure is not achieved. Also, due to species
differences in toxicokinetics, establishing a specific limit dose may not be adequate for situations where
humans are more sensitive than the animal model.
3.7.2.5.8. In principle, adverse effects on reproduction seen only at very high dose levels in animal studies (for example
doses that induce prostration, severe inappetence, excessive mortality) would not normally lead to
classification, unless other information is available, e.g. toxicokinetics information indicating that humans
may be more susceptible than animals, to suggest that classification is appropriate. Please also refer to the
section on maternal toxicity (3.7.2.4) for further guidance in this area.
3.7.2.5.9. However, specification of the actual ‘limit dose’ will depend upon the test method that has been employed to
provide the test results, e.g. in the OECD Test Guideline for repeated dose toxicity studies by the oral route, an
upper dose of 1 000 mg/kg has been recommended as a limit dose, unless expected human response
indicates the need for a higher dose level.
3.7.3.1. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture
3.7.3.1.1. The mixture shall be classified as a reproductive toxicant when at least one ingredient has been classified as a
Category 1A, Category 1B or Category 2 reproductive toxicant and is present at or above the appropriate
generic concentration limit as shown in Table 3.7.2 for Category 1A, Category 1B and Category 2
respectively.
3.7.3.1.2. The mixture shall be classified for effects on or via lactation when at least one ingredient has been classified
for effects on or via lactation and is present at or above the appropriate generic concentration limit as shown
in Table 3.7.2 for the additional category for effects on or via lactation.
Table 3.7.2
Note
The concentration limits in the table above apply to solids and liquids (w/w units) as well as gases (v/v units).
Note 1
If a Category 1 or Category 2 reproductive toxicant or a substance classified for effects on or via lactation is
present in the mixture as an ingredient at a concentration above 0,1 %, a SDS shall be available for the
mixture upon request.
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3.7.3.2. Classification of mixtures when data are available for the complete mixture
3.7.3.2.1. Classification of mixtures will be based on the available test data for the individual ingredients of the mixture
using concentration limits for the ingredients of the mixture. On a case-by-case basis, test data on mixtures
may be used for classification when demonstrating effects that have not been established from the evaluation
based on the individual components. In such cases, the test results for the mixture as a whole must be shown
to be conclusive taking into account dose and other factors such as duration, observations, sensitivity and
statistical analysis of reproduction test systems. Adequate documentation supporting the classification shall
be retained and made available for review upon request.
3.7.3.3. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.7.3.3.1. Subject to paragraph 3.7.3.2.1, where the mixture itself has not been tested to determine its reproductive
toxicity, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately
characterise the hazards of the mixture, these data shall be used in accordance with the applicable bridging
rules set out in section 1.1.3.
3.7.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.7.3
Table 3.7.3
3.8.1.1. Specific target organ toxicity (single exposure) is defined as specific, non lethal target organ toxicity arising
from a single exposure to a substance or mixture. All significant health effects that can impair function, both
reversible and irreversible, immediate and/or delayed and not specifically addressed in sections 3.1 to 3.7 and
3.10 are included (see also 3.8.1.6).
3.8.1.2. Classification identifies the substance or mixture as being a specific target organ toxicant and, as such, it may
present a potential for adverse health effects in people who are exposed to it.
3.8.1.3. These adverse health effects produced by a single exposure include consistent and identifiable toxic effects in
humans, or, in experimental animals, toxicologically significant changes which have affected the function or
morphology of a tissue/organ, or have produced serious changes to the biochemistry or haematology of the
organism, and these changes are relevant for human health.
3.8.1.4. Assessment shall take into consideration not only significant changes in a single organ or biological system
but also generalised changes of a less severe nature involving several organs.
3.8.1.5. Specific target organ toxicity can occur by any route that is relevant for humans, i.e. principally oral, dermal
or inhalation.
3.8.1.6. Specific target organ toxicity following a repeated exposure is classified as described in Specific target organ
toxicity — Repeated exposure (section 3.9) and is therefore excluded from section 3.8. Other specific toxic
effects, listed below, are assessed separately and consequently are not included here:
3.8.1.7. The hazard class Specific Target Organ Toxicity — Single Exposure is differentiated into:
Table 3.8.1
Categories Criteria
Substances that have produced significant toxicity in humans or that, on the basis of
evidence from studies in experimental animals, can be presumed to have the potential to
produce significant toxicity in humans following single exposure
Substances are classified in Category 1 for specific target organ toxicity (single exposure)
on the basis of:
Category 1
(a) reliable and good quality evidence from human cases or epidemiological studies; or
(b) observations from appropriate studies in experimental animals in which significant
and/or severe toxic effects of relevance to human health were produced at generally
low exposure concentrations. Guidance dose/concentration values are provided
below (see 3.8.2.1.9) to be used as part of weight-of-evidence evaluation.
Substances that, on the basis of evidence from studies in experimental animals can be
presumed to have the potential to be harmful to human health following single exposure
Substances are classified in Category 2 for specific target organ toxicity (single exposure)
on the basis of observations from appropriate studies in experimental animals in which
Category 2 significant toxic effects, of relevance to human health, were produced at generally
moderate exposure concentrations. Guidance dose/concentration values are provided
below (see 3.8.2.1.9) in order to help in classification.
In exceptional cases, human evidence can also be used to place a substance in Category 2
(see 3.8.2.1.6).
Transient target organ effects
This category only includes narcotic effects and respiratory tract irritation. These are
target organ effects for which a substance does not meet the criteria to be classified in
Category 3 Categories 1 or 2 indicated above. These are effects which adversely alter human function
for a short duration after exposure and from which humans may recover in a reasonable
period without leaving significant alteration of structure or function. Substances are
classified specifically for these effects as laid down in 3.8.2.2.
Note: Attempts shall be made to determine the primary target organ of toxicity and to classify for that purpose, such as
hepatotoxicants, neurotoxicants. The data shall be carefully evaluated and, where possible, secondary effects should not be
included (e.g. a hepatotoxicant can produce secondary effects in the nervous or gastro-intestinal systems).
3.8.2.1.1. Substances are classified for immediate or delayed effects separately, by the use of expert judgement (see
1.1.1) on the basis of the weight of all evidence available, including the use of recommended guidance values
(see 3.8.2.1.9). Substances are then placed in Category 1 or 2, depending upon the nature and severity of the
effect(s) observed (Table 3.8.1).
3.8.2.1.2. The relevant route or routes of exposure by which the classified substance produces damage shall be
identified (see 3.8.1.5).
3.8.2.1.3. Classification is determined by expert judgement (see section 1.1.1), on the basis of the weight of all evidence
available including the guidance presented below.
3.8.2.1.4. Weight of evidence of all data (see section 1.1.1), including human incidents, epidemiology, and studies
conducted in experimental animals, is used to substantiate specific target organ toxic effects that merit
classification.
3.8.2.1.5. The information required to evaluate specific target organ toxicity comes either from single exposure in
humans, such as: exposure at home, in the workplace or environmentally, or from studies conducted in
experimental animals. The standard animal studies in rats or mice that provide this information are acute
toxicity studies which can include clinical observations and detailed macroscopic and microscopic
examination to enable the toxic effects on target tissues/organs to be identified. Results of acute toxicity
studies conducted in other species may also provide relevant information.
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3.8.2.1.6. In exceptional cases, based on expert judgement, it is appropriate to place certain substances with human
evidence of target organ toxicity in Category 2:
(a) when the weight of human evidence is not sufficiently convincing to warrant Category 1 classification,
and/or
Dose/concentration levels in humans shall not be considered in the classification and any available evidence
from animal studies shall be consistent with the Category 2 classification. In other words, if there are also
animal data available on the substance that warrant Category 1 classification, the substance shall be classified
as Category 1.
3.8.2.1.7.1. Classification is supported by evidence associating single exposure to the substance with a consistent and
identifiable toxic effect.
3.8.2.1.7.2. Evidence from human experience/incidents is usually restricted to reports of adverse health consequence,
often with uncertainty about exposure conditions, and may not provide the scientific detail that can be
obtained from well-conducted studies in experimental animals.
3.8.2.1.7.3. Evidence from appropriate studies in experimental animals can furnish much more detail, in the form of
clinical observations, and macroscopic and microscopic pathological examination, and this can often reveal
hazards that may not be life-threatening but could indicate functional impairment. Consequently all available
evidence, and relevance to human health, must be taken into consideration in the classification process,
including but not limited to the following effects in humans and/or animals:
(b) significant functional changes, more than transient in nature, in the respiratory system, central or
peripheral nervous systems, other organs or other organ systems, including signs of central nervous
system depression and effects on special senses (such as sight, hearing and sense of smell);
(c) any consistent and significant adverse change in clinical biochemistry, haematology, or urinalysis
parameters;
(d) significant organ damage noted at necropsy and/or subsequently seen or confirmed at microscopic
examination;
(e) multi-focal or diffuse necrosis, fibrosis or granuloma formation in vital organs with regenerative
capacity;
(f) morphological changes that are potentially reversible but provide clear evidence of marked organ
dysfunction;
(g) evidence of appreciable cell death (including cell degeneration and reduced cell number) in vital organs
incapable of regeneration.
It is recognised that effects may be seen that does not justify classification. Such effects in humans and/or
animals include, but are not limited to:
(a) clinical observations or small changes in bodyweight gain, food consumption or water intake that may
have some toxicological importance but that do not, by themselves, indicate ‘significant’ toxicity;
(b) small changes in clinical biochemistry, haematology or urinalysis parameters and/or transient effects,
when such changes or effects are of doubtful or minimal toxicological importance;
(e) substance-induced species-specific mechanisms of toxicity, i.e. demonstrated with reasonable certainty
to be not relevant for human health, shall not justify classification.
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3.8.2.1.9. Guidance values to assist with classification based on the results obtained from
studies conducted in exper imental animals for Category 1 and 2
3.8.2.1.9.1. In order to help reach a decision about whether a substance shall be classified or not, and to what degree it
shall be classified (Category 1 or Category 2), dose/concentration ‘guidance values’ are provided for
consideration of the dose/concentration which has been shown to produce significant health effects. The
principal argument for proposing such guidance values is that all substances are potentially toxic and there
has to be a reasonable dose/concentration above which a degree of toxic effect is acknowledged.
3.8.2.1.9.2. Thus, in animal studies, when significant toxic effects are observed that indicate classification, consideration
of the dose/concentration at which these effects were seen, in relation to the suggested guidance values,
provides useful information to help assess the need to classify (since the toxic effects are a consequence of the
hazardous property(ies) and also the dose/concentration).
3.8.2.1.9.3. The guidance value (C) ranges for single-dose exposure which has produced a significant non-lethal toxic
effect are those applicable to acute toxicity testing, as indicated in Table 3.8.2.
Table 3.8.2
Note
(a) The guidance values and ranges mentioned in Table 3.8.2 are intended only for guidance purposes, i.e.
to be used as part of the weight of evidence approach, and to assist with decision about classification.
They are not intended as strict demarcation values.
(b) Guidance values are not provided for Category 3 substances since this classification is primarily based
on human data. Animal data, if available, shall be included in the weight of evidence evaluation.
3.8.2.1.10.1. When a substance is characterised only by use of animal data (typical of new substances, but also true for
many existing substances), the classification process includes reference to dose/concentration guidance values
as one of the elements that contribute to the weight of evidence approach.
3.8.2.1.10.2. When well-substantiated human data are available showing a specific target organ toxic effect that can be
reliably attributed to single exposure to a substance, the substance shall normally be classified. Positive human
data, regardless of probable dose, predominates over animal data. Thus, if a substance is unclassified because
specific target organ toxicity observed was considered not relevant or significant to humans, if subsequent
human incident data become available showing a specific target organ toxic effect, the substance shall be
classified.
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3.8.2.1.10.3. A substance that has not been tested for specific target organ toxicity may, where appropriate, be classified on
the basis of data from a validated structure activity relationship and expert judgement-based extrapolation
from a structural analogue that has previously been classified together with substantial support from
consideration of other important factors such as formation of common significant metabolites.
3.8.2.1.10.4. Saturated vapour concentration shall be considered, where appropriate, as an additional element to provide
for specific health and safety protection
The criteria for classifying substances as Category 3 for respiratory tract irritation are:
(a) respiratory irritant effects (characterised by localised redness, oedema, pruritis and/or pain) that impair
function with symptoms such as cough, pain, choking, and breathing difficulties are included. This
evaluation will be based primarily on human data;
(b) subjective human observations could be supported by objective measurements of clear respiratory tract
irritation (RTI) (such as electrophysiological responses, biomarkers of inflammation in nasal or
bronchoalveolar lavage fluids);
(c) the symptoms observed in humans shall also be typical of those that would be produced in the exposed
population rather than being an isolated idiosyncratic reaction or response triggered only in individuals
with hypersensitive airways. Ambiguous reports simply of ‘irritation’ shall be excluded as this term is
commonly used to describe a wide range of sensations including those such as smell, unpleasant taste, a
tickling sensation, and dryness, which are outside the scope of classification for respiratory irritation;
(d) there are currently no validated animal tests that deal specifically with RTI, however, useful information
may be obtained from the single and repeated inhalation toxicity tests. For example, animal studies may
provide useful information in terms of clinical signs of toxicity (dyspnoea, rhinitis etc) and
histopathology (e.g. hyperemia, edema, minimal inflammation, thickened mucous layer) which are
reversible and may be reflective of the characteristic clinical symptoms described above. Such animal
studies can be used as part of weight of evidence evaluation;
(e) this special classification would occur only when more severe organ effects including in the respiratory
system are not observed.
The criteria for classifying substances as Category 3 for narcotic effects are:
(a) central nervous system depression including narcotic effects in humans such as drowsiness, narcosis,
reduced alertness, loss of reflexes, lack of coordination, and vertigo are included. These effects can also
be manifested as severe headache or nausea, and can lead to reduced judgment, dizziness, irritability,
fatigue, impaired memory function, deficits in perception and coordination, reaction time, or
sleepiness;
(b) narcotic effects observed in animal studies may include lethargy, lack of coordination, loss of righting
reflex, and ataxia. If these effects are not transient in nature, then they shall be considered to support
classification for Category 1 or 2 specific target organ toxicity single exposure.
3.8.3.1. Mixtures are classified using the same criteria as for substances, or alternatively as described below. As with
substances, mixtures shall be classified for specific target organ toxicity following single exposure.
3.8.3.2. Classification of mixtures when data are available for the complete mixture
3.8.3.2.1. When reliable and good quality evidence from human experience or appropriate studies in experimental
animals, as described in the criteria for substances, is available for the mixture, then the mixture shall be
classified by weight of evidence evaluation of these data (see 1.1.1.4). Care shall be exercised in evaluating
data on mixtures, that the dose, duration, observation or analysis, do not render the results inconclusive.
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3.8.3.3. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.8.3.3.1. Where the mixture itself has not been tested to determine its specific target organ toxicity, but there are
sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards
of the mixture, these data shall be used in accordance with the bridging principles set out in section 1.1.3.
3.8.3.4. Classification of mixtures when data are available for all components or only for some components of the mixture
3.8.3.4.1. Where there is no reliable evidence or test data for the specific mixture itself, and the bridging principles
cannot be used to enable classification, then classification of the mixture is based on the classification of the
ingredient substances. In this case, the mixture shall be classified as a specific target organ toxicant (specific
organ specified), following single exposure, when at least one ingredient has been classified as a Category 1 or
Category 2 specific target organ toxicant and is present at or above the appropriate generic concentration
limit as mentioned in Table 3.8.3 for Category 1 and 2 respectively.
3.8.3.4.2. These generic concentration limits and consequent classifications shall be applied appropriately to single-dose
specific target organ toxicants.
3.8.3.4.3. Mixtures shall be classified for either or both single- and repeated-dose toxicity independently.
Table 3.8.3
Generic concentration limits of ingredients of a mixture classified as a specific target organ toxicant
that trigger classification of the mixture as Category 1 or 2
Note 1
If a Category 2 specific target organ toxicant is present in the mixture as an ingredient at a concentration
≥ 1,0 % a SDS shall be available for the mixture upon request.
3.8.3.4.4. Care shall be exercised when toxicants affecting more than one organ system are combined that the
potentiation or synergistic interactions are considered, because certain substances can cause target organ
toxicity at < 1 % concentration when other ingredients in the mixture are known to potentiate its toxic effect.
3.8.3.4.5. Care shall be exercised when extrapolating toxicity of a mixture that contains Category 3 ingredient(s). A
generic concentration limit of 20 % is appropriate; however, it shall be recognised that this concentration
limit may be higher or lower depending on the Category 3 ingredient(s) and that some effects such as
respiratory tract irritation may not occur below a certain concentration while other effects such as narcotic
effects may occur below this 20 % value. Expert judgement shall be exercised.
3.8.4.1 Label elements shall be used in accordance with Table 3.8.4., for substances or mixtures meeting the criteria
for classification in this hazard class.
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Table 3.8.4
Label elements for specific target organ toxicity after single exposure
3.9.1.1. Target organ toxicity (repeated exposure) means specific, target organ toxicity arising from a repeated
exposure to a substance or mixture. All significant health effects that can impair function, both reversible and
irreversible, immediate and/or delayed are included. However, other specific toxic effects that are specifically
addressed in sections 3.1 to 3.8 and 3.10 are not included here.
3.9.1.2. Classification for target organ toxicity (repeated exposure) identifies the substance as being a specific target
organ toxicant and, as such, it may present a potential for adverse health effects in people who are exposed to
it.
3.9.1.3. These adverse health effects include consistent and identifiable toxic effects in humans, or, in experimental
animals, toxicologically significant changes which have affected the function or morphology of a tissue/organ,
or have produced serious changes to the biochemistry or haematology of the organism and these changes are
relevant for human health.
3.9.1.4. Assessment shall take into consideration not only significant changes in a single organ or biological system
but also generalised changes of a less severe nature involving several organs.
3.9.1.5. Specific target organ toxicity can occur by any route that is relevant for humans, i.e. principally oral, dermal
or inhalation.
3.9.1.6. Non-lethal toxic effects observed after a single-event exposure are classified as described in Specific target
organ toxicity — Single exposure (section 3.8) and are therefore excluded from section 3.9.
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3.9.2.1. Substances are classified as specific target organ toxicants following repeated exposure by the use of expert
judgement (see 1.1.1), on the basis of the weight of all evidence available, including the use of recommended
guidance values which take into account the duration of exposure and the dose/concentration which
produced the effect(s), (see 3.9.2.9), and are placed in one of two categories, depending upon the nature and
severity of the effect(s) observed (Table 3.9.1).
Table 3.9.1
Categories Criteria
Substances that have produced significant toxicity in humans or that, on the basis of
evidence from studies in experimental animals, can be presumed to have the potential to
produce significant toxicity in humans following repeated exposure.
Substances are classified in Category 1 for target organ toxicity (repeat exposure) on the
basis of:
Category 1
— reliable and good quality evidence from human cases or epidemiological studies; or
— observations from appropriate studies in experimental animals in which significant
and/or severe toxic effects, of relevance to human health, were produced at generally
low exposure concentrations. Guidance dose/concentration values are provided below
(see 3.9.2.9), to be used as part of a weight-of- evidence evaluation.
Substances that, on the basis of evidence from studies in experimental animals can be
presumed to have the potential to be harmful to human health following repeated exposure.
Substances are classified in category 2 for target organ toxicity (repeat exposure) on the basis
of observations from appropriate studies in experimental animals in which significant toxic
Category 2 effects, of relevance to human health, were produced at generally moderate exposure
concentrations. Guidance dose/concentration values are provided below (see 3.9.2.9) in
order to help in classification.
In exceptional cases human evidence can also be used to place a substance in Category 2
(see 3.9.2.6).
Note
Attempts shall be made to determine the primary target organ of toxicity and classify for that purpose, such
as hepatotoxicants, neurotoxicants. One shall carefully evaluate the data and, where possible, not include
secondary effects (a hepatotoxicant can produce secondary effects in the nervous or gastro-intestinal systems).
3.9.2.2. The relevant route or routes of exposure by which the classified substance produces damage shall be
identified.
3.9.2.3. Classification is determined by expert judgement (see section 1.1.1), on the basis of the weight of all evidence
available including the guidance presented below.
3.9.2.4. Weight of evidence of all data (see section 1.1.1), including human incidents, epidemiology, and studies
conducted in experimental animals, is used to substantiate specific target organ toxic effects that merit
classification. This taps the considerable body of industrial toxicology data collected over the years. Evaluation
shall be based on all existing data, including peer-reviewed published studies and additional acceptable data.
3.9.2.5. The information required to evaluate specific target organ toxicity comes either from repeated exposure in
humans, such as exposure at home, in the workplace or environmentally, or from studies conducted in
experimental animals. The standard animal studies in rats or mice that provide this information are 28 day,
90 day or lifetime studies (up to 2 years) that include haematological, clinicochemical and detailed
macroscopic and microscopic examination to enable the toxic effects on target tissues/organs to be identified.
Data from repeat dose studies performed in other species shall also be used, if available. Other long-term
exposure studies, such as on carcinogenicity, neurotoxicity or reproductive toxicity, may also provide evidence
of specific target organ toxicity that could be used in the assessment of classification.
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3.9.2.6. In exceptional cases, based on expert judgement, it is appropriate to place certain substances with human
evidence of specific target organ toxicity in Category 2:
(a) when the weight of human evidence is not sufficiently convincing to warrant Category 1 classification;
and/or
Dose/concentration levels in humans shall not be considered in the classification and any available evidence
from animal studies shall be consistent with the Category 2 classification. In other words, if there are also
animal data available on the substance that warrant Category 1 classification, the substance shall be classified
as Category 1.
3.9.2.7. Effects considered to support classification for specific target organ toxicity following repeated exposure
3.9.2.7.1. Reliable evidence associating repeated exposure to the substance with a consistent and identifiable toxic effect
demonstrates support for the classification.
3.9.2.7.2. Evidence from human experience/incidents is usually restricted to reports of adverse health consequence,
often with uncertainty about exposure conditions, and may not provide the scientific detail that can be
obtained from well-conducted studies in experimental animals.
3.9.2.7.3. Evidence from appropriate studies in experimental animals can furnish much more detail, in the form of
clinical observations, haematology, clinical chemistry, and macroscopic and microscopic pathological
examination, and this can often reveal hazards that may not be life-threatening but could indicate functional
impairment. Consequently all available evidence, and relevance to human health, shall be taken into
consideration in the classification process, including but not limited to the following toxic effects in humans
and/or animals:
(a) morbidity or death resulting from repeated or long-term exposure. Morbidity or death may result from
repeated exposure, even to relatively low doses/concentrations, due to bioaccumulation of the
substance or its metabolites, and/or due to the overwhelming of the de-toxification process by repeated
exposure to the substance or its metabolites;
(b) significant functional changes in the central or peripheral nervous systems or other organ systems,
including signs of central nervous system depression and effects on special senses (e.g. sight, hearing
and sense of smell);
(c) any consistent and significant adverse change in clinical biochemistry, haematology, or urinalysis
parameters;
(d) significant organ damage noted at necropsy and/or subsequently seen or confirmed at microscopic
examination;
(e) multi-focal or diffuse necrosis, fibrosis or granuloma formation in vital organs with regenerative
capacity;
(f) morphological changes that are potentially reversible but provide clear evidence of marked organ
dysfunction (e.g., severe fatty change in the liver);
(g) evidence of appreciable cell death (including cell degeneration and reduced cell number) in vital organs
incapable of regeneration.
3.9.2.8. Effects considered not to support classification for specific target organ toxicity following repeated exposure
3.9.2.8.1. It is recognised that effects may be seen in humans and/or animals that do not justify classification. Such
effects include, but are not limited to:
(a) clinical observations or small changes in bodyweight gain, food consumption or water intake that have
toxicological importance but that do not, by themselves, indicate ‘significant’ toxicity;
(b) small changes in clinical biochemistry, haematology or urinalysis parameters and/or transient effects,
when such changes or effects are of doubtful or minimal toxicological importance;
(e) substance-induced species-specific mechanisms of toxicity, i.e. demonstrated with reasonable certainty
to be not relevant for human health, shall not justify classification.
3.9.2.9. Guidance values to assist with classification based on the results obtained from studies conducted in experimental animals
3.9.2.9.1. In studies conducted in experimental animals, reliance on observation of effects alone, without reference to
the duration of experimental exposure and dose/concentration, omits a fundamental concept of toxicology,
i.e. all substances are potentially toxic, and what determines the toxicity is a function of the dose/
concentration and the duration of exposure. In most studies conducted in experimental animals the test
guidelines use an upper limit dose value.
3.9.2.9.2. In order to help reach a decision about whether a substance shall be classified or not, and to what degree it
shall be classified (Category 1 or Category 2), dose/concentration ‘guidance values’ are provided for
consideration of the dose/concentration which has been shown to produce significant health effects. The
principal argument for proposing such guidance values is that all substances are potentially toxic and there
has to be a reasonable dose/concentration above which a degree of toxic effect is acknowledged. Also,
repeated-dose studies conducted in experimental animals are designed to produce toxicity at the highest dose
used in order to optimise the test objective and so most studies will reveal some toxic effect at least at this
highest dose. What is therefore to be decided is not only what effects have been produced, but also at what
dose/concentration they were produced and how relevant is that for humans.
3.9.2.9.3. Thus, in animal studies, when significant toxic effects are observed that indicate classification, consideration
of the duration of experimental exposure and the dose/concentration at which these effects were seen, in
relation to the suggested guidance values, can provide useful information to help assess the need to classify
(since the toxic effects are a consequence of the hazardous property(ies) and also the duration of exposure and
the dose/concentration).
3.9.2.9.4. The decision to classify at all can be influenced by reference to the dose/concentration guidance values at or
below which a significant toxic effect has been observed.
3.9.2.9.5. The guidance values refer to effects seen in a standard 90-day toxicity study conducted in rats. They can be
used as a basis to extrapolate equivalent guidance values for toxicity studies of greater or lesser duration, using
dose/exposure time extrapolation similar to Haber's rule for inhalation, which states essentially that the
effective dose is directly proportional to the exposure concentration and the duration of exposure. The
assessment shall be done on a case-by-case basis; for a 28-day study the guidance values below is increased by
a factor of three.
3.9.2.9.6. Thus classification in Category 1 is applicable, when significant toxic effects observed in a 90-day repeated-
dose study conducted in experimental animals are seen to occur at or below the guidance values (C) as
indicated in Table 3.9.2:
Table 3.9.2
3.9.2.9.7. Classification in Category 2 is applicable, when significant toxic effects observed in a 90-day repeated-dose
study conducted in experimental animals are seen to occur within the guidance value ranges as indicated in
Table 3.9.3:
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Table 3.9.3
3.9.2.9.8. The guidance values and ranges mentioned in paragraphs 3.9.2.9.6 and 3.9.2.9.7 are intended only for
guidance purposes, i.e. to be used as part of the weight of evidence approach, and to assist with decisions
about classification. They are not intended as strict demarcation values.
3.9.2.9.9. Thus it is feasible that a specific profile of toxicity occurs in repeat-dose animal studies at a dose/
concentration below the guidance value, such as < 100 mg/kg bw/day by the oral route, however the nature
of the effect, such as nephrotoxicity seen only in male rats of a particular strain known to be susceptible to
this effect may result in the decision not to classify. Conversely, a specific profile of toxicity may be seen in
animal studies occurring at above a guidance value, such as ≥ 100 mg/kg bw/day by the oral route, and in
addition there is supplementary information from other sources, such as other long-term administration
studies, or human case experience, which supports a conclusion that, in view of the weight of evidence,
classification is the prudent action to take.
3.9.2.10.1. When a substance is characterised only by use of animal data (typical of new substances, but also true for
many existing substances), the classification process includes reference to dose/concentration guidance values
as one of the elements that contribute to the weight of evidence approach.
3.9.2.10.2. When well-substantiated human data are available showing a specific target organ toxic effect that can be
reliably attributed to repeated or prolonged exposure to a substance, the substance shall normally be
classified. Positive human data, regardless of probable dose, predominates over animal data. Thus, if a
substance is unclassified because no specific target organ toxicity was seen at or below the dose/concentration
guidance value for animal testing, if subsequent human incident data become available showing a specific
target organ toxic effect, the substance shall be classified.
3.9.2.10.3. A substance that has not been tested for specific target organ toxicity may, where appropriate, be classified on
the basis of data from a validated structure activity relationship and expert judgement-based extrapolation
from a structural analogue that has previously been classified together with substantial support from
consideration of other important factors such as formation of common significant metabolites.
3.9.2.10.4. Saturated vapour concentration shall be considered, where appropriate, as an additional element to provide
for specific health and safety protection
3.9.3.1. Mixtures are classified using the same criteria as for substances, or alternatively as described below. As with
substances, mixtures shall be classified for specific target organ toxicity following repeated exposure.
3.9.3.2. Classification of mixtures when data are available for the complete mixture
3.9.3.2.1. When reliable and good quality evidence from human experience or appropriate studies in experimental
animals, as described in the criteria for substances, is available for the mixture (see 1.1.1.4), then the mixture
shall be classified by weight of evidence evaluation of these data. Care shall be exercised in evaluating data on
mixtures, that the dose, duration, observation or analysis, do not render the results inconclusive.
L 353/126 EN Official Journal of the European Union 31.12.2008
3.9.3.3. Classification of mixtures when data are not available for the complete mixture: bridging principles
3.9.3.3.1. Where the mixture itself has not been tested to determine its specific target organ toxicity, but there are
sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards
of the mixture, these data shall be used in accordance with the bridging principles set out in section 1.1.3.
3.9.3.4. Classification of mixtures when data are available for all components or only for some components of the mixture
3.9.3.4.1. Where there is no reliable evidence or test data for the specific mixture itself, and the bridging principles
cannot be used to enable classification, then classification of the mixture is based on the classification of the
ingredient substances. In this case, the mixture shall be classified as a specific target organ toxicant (specific
organ specified), following single exposure, repeat exposure, or both when at least one ingredient has been
classified as a Category 1 or Category 2 specific target organ toxicant and is present at or above the
appropriate generic concentration limit as laid out in Table 3.9.4 for Category 1 and 2 respectively.
Table 3.9.4
Generic concentration limits of ingredients of a mixture classified as a specific target organ toxicant
that trigger classification of the mixture
Note 1
If a Category 2 specific target organ toxicant is present in the mixture as an ingredient at a concentration
≥ 1,0 % a SDS shall be available for the mixture upon request.
3.9.3.4.2. These generic concentration limits and consequent classifications apply to repeated-dose target organ
toxicants.
3.9.3.4.3. Mixtures shall be classified for either or both single- and repeated-dose toxicity independently.
3.9.3.4.4. Care shall be exercised when toxicants affecting more than one organ system are combined that the
potentiation or synergistic interactions are considered, because certain substances can cause target organ
toxicity at < 1 % concentration when other ingredients in the mixture are known to potentiate its toxic effect.
3.9.4.1. Label elements shall be used in accordance with Table 3.9.5 for substances or mixtures meeting the criteria
for classification in this hazard class.
Table 3.9.5
Label elements for specific target organ toxicity after repeated exposure
3.10.1.1. These criteria provide a means of classifying substances or mixtures that may pose an aspiration toxicity
hazard to humans.
3.10.1.2 ‘Aspiration’ means the entry of a liquid or solid substance or mixture directly through the oral or nasal cavity,
or indirectly from vomiting, into the trachea and lower respiratory system.
3.10.1.3. Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary
injury or death following aspiration.
3.10.1.4. Aspiration is initiated at the moment of inspiration, in the time required to take one breath, as the causative
material lodges at the crossroad of the upper respiratory and digestive tracts in the laryngopharyngeal region.
3.10.1.5. Aspiration of a substance or mixture can occur as it is vomited following ingestion. This has consequences for
labelling, particularly where, due to acute toxicity, a recommendation may be considered to induce vomiting
after ingestion. However, if the substance/mixture also presents an aspiration toxicity hazard, the
recommendation to induce vomiting shall be modified.
3.10.1.6.1. A review of the medical literature on chemical aspiration revealed that some hydrocarbons (petroleum
distillates) and certain chlorinated hydrocarbons have been shown to pose an aspiration hazard in humans.
3.10.1.6.2. The classification criteria refer to kinematic viscosity. The following provides the conversion between
dynamic and kinematic viscosity:
Aerosol and mist forms of a substance or a mixture (product) are usually dispensed in containers such as self-
pressurised containers, trigger and pump sprayers. The key to classifying these products is whether a pool of
product is formed in the mouth, which then may be aspirated. If the mist or aerosol from a pressurised
container is fine, a pool may not be formed. On the other hand, if a pressurised container dispenses product
in a stream, a pool may be formed that may then be aspirated. Usually, the mist produced by trigger and
pump sprayers is coarse and therefore, a pool may be formed that then may be aspirated. When the pump
mechanism may be removed, and the contents are available to be swallowed then the classification of the
substance or mixture shall be considered.
L 353/128 EN Official Journal of the European Union 31.12.2008
Table 3.10.1
Category Criteria
Substances known to cause human aspiration toxicity hazards or to be regarded as if they
cause human aspiration toxicity hazard
A substance is classified in Category 1:
Category 1 (a) based on reliable and good quality human evidence
or
(b) if it is a hydrocarbon and has a kinematic viscosity of 20,5 mm 2/s or less, measured at
40 oC.
Note:
Substances in Category 1 include but are not limited to certain hydrocarbons, turpentine and pine oil.
3.10.3.1. Classification when data are available for the complete mixture
A mixture is classified in Category 1 based on reliable and good quality human evidence.
3.10.3.2. Classification when data are not available for the complete mixture: bridging principles
3.10.3.2.1. Where the mixture itself has not been tested to determine its aspiration toxicity, but there are sufficient data
on the individual ingredients and similar tested mixtures to adequately characterise the hazard of the mixture,
these data shall be used in accordance with the bridging principles set out in section 1.1.3. However, in the
case of application of the dilution bridging principle, the concentration of aspiration toxicant(s) shall be 10 %
or more.
3.10.3.3. Classification when data are available for all components or only some components of the mixture
3.10.3.3.1. Category 1
3.10.3.3.1.1. A mixture which contains a total of 10 % or more of a substance or substances classified in Category 1, and
has a kinematic viscosity of 20,5 mm2 /s or less, measured at 40 oC, shall be classified in Category 1.
3.10.3.3.1.2. In the case of a mixture which separates into two or more distinct layers, one of which contains 10 % or more
of a substance or substances classified in Category 1 and has a kinematic viscosity of 20,5 mm o /s or less,
measured at 40 oC, then the entire mixture is classified in Category 1.
3.10.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 3.10.2.
Table 3.10.2
Classification Category 1
GHS Pictogram
Classification Category 1
Precautionary Statement
Prevention
4.1.1.1. Definitions
Acute aquatic toxicity means the intrinsic property of a substance to be injurious to an organism in a short-
term exposure to that substance.
Availability of a substance means the extent to which this substance becomes a soluble or disaggregate
species. For metal availability, the extent to which the metal ion portion of a metal (M o) compound can
disaggregate from the rest of the compound (molecule).
Bioavailability (or biological availability) means the extent to which a substance is taken up by an organism,
and distributed to an area within the organism. It is dependent upon physico-chemical properties of the
substance, anatomy and physiology of the organism, pharmacokinetics, and route of exposure. Availability is
not a prerequisite for bioavailability.
Bioaccumulation means the net result of uptake, transformation and elimination of a substance in an
organism due to all routes of exposure (i.e. air, water, sediment/soil and food).
Bioconcentration means the net result of uptake, transformation and elimination of a substance in an
organism due to waterborne exposure.
Chronic aquatic toxicity means the intrinsic property of a substance to cause adverse effects to aquatic
organisms during exposures which are determined in relation to the life-cycle of the organism.
Degradation means the decomposition of organic molecules to smaller molecules and eventually to carbon
dioxide, water and salts.
4.1.1.2.1. The basic elements used for classification for aquatic environmental hazards are:
4.1.1.2.2. Preferably data shall be derived using the standardised test methods referred to in Article 8(3). In practice data
from other standardised test methods such as national methods shall also be used where they are considered
as equivalent. Where valid data are available from non-standard testing and from non-testing methods, these
shall be considered in classification provided they fulfil the requirements specified in section 1 of Annex XI to
Regulation (EC) No 1907/2006. In general, both freshwater and marine species toxicity data are considered
suitable for use in classification provided the test method used are equivalent. Where such data are not
available classification shall be based on the best available data. See also Part 1.
4.1.1.3.1. Classification of substances and mixtures for environmental hazards requires the identification of the hazards
they present to the aquatic environment. The aquatic environment is considered in terms of the aquatic
organisms that live in the water, and the aquatic ecosystem of which they are part. The basis, therefore, of the
identification of hazard is the aquatic toxicity of the substance or mixture, although this shall be modified by
taking account of further information on the degradation and bioaccumulation behaviour, if appropriate.
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4.1.1.3.2. While the classification system applies to all substances and mixtures, it is recognised that for special cases the
Agency will issue guidance.
4.1.2.1. The core classification system for substances consists of one acute classification category and three chronic
classification categories. The acute and the chronic classification categories are applied independently. The
criteria for classification of a substance in acute Category 1 are defined on the basis of acute aquatic toxicity
data only (EC50 or LC50). The criteria for classification of a substance into the chronic categories combine two
types of information, i.e. acute aquatic toxicity data and environmental fate data (degradability and
bioaccumulation data).
4.1.2.2. The system also introduces a ‘safety net’ classification (referred to as Chronic Category 4) for use when the
data available do not allow classification under the formal criteria but there are nevertheless some grounds for
concern (see example in table 4.1.0).
4.1.2.3. The system for classification recognises that the core intrinsic hazard to aquatic organisms is represented by
both the acute and chronic toxicity of a substance. Separate hazard categories are defined for both properties
representing a gradation in the level of hazard identified. The lowest of the available toxicity values shall
normally be used to define the appropriate hazard category(ies). There are circumstances, however, when a
weight of evidence approach is appropriate.
4.1.2.4. The principal hazard of a ‘hazardous to the aquatic environment’ substance is defined by chronic toxicity,
although acute toxicity at L(E)C50 levels ≤ 1 mg/l are also considered hazardous. The intrinsic properties of a
lack of rapid degradability and/or a potential to bioconcentrate in combination with acute toxicity are used to
assign a substance to a chronic (long term) hazard category.
4.1.2.5. Substances with acute toxicities well below 1 mg/l contribute as components of a mixture to the toxicity of
the mixture even at a low concentration and shall normally be given increased weight in applying the
summation of classification approach (see note 1 of Table 4.1.0 and 4.1.3.5.5).
4.1.2.6. The criteria for classifying and categorising substances as ‘hazardous to the aquatic environment’ are
summarised in Table 4.1.0.
Table 4.1.0
Chronic Category 3
96 hr LC50 (for fish) > 10 to ≤ 100 mg/l and/or
48 hr EC50 (for crustacea) > 10 to ≤ 100 mg/l and/or
72 or 96 hr ErC50 (for algae or other aquatic plants) > 10 to ≤ 100 mg/l (Note 2)
and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if
absent, the log Kow ≥ 4) unless the chronic toxicity NOECs are > 1 mg/l.
‘Safety net’ classification
Chronic Category 4
Cases when data do not allow classification under the above criteria but there are nevertheless some
grounds for concern. This includes, for example, poorly soluble substances for which no acute toxicity is
recorded at levels up to the water solubility (note 3), and which are not rapidly degradable and have an
experimentally determined BCF ≥ 500 (or, if absent, a log Kow ≥ 4), indicating a potential to
bioaccumulate, will be classified in this category unless other scientific evidence exists showing
classification to be unnecessary. Such evidence includes chronic toxicity NOECs > water solubility or
> 1 mg/l, or evidence of rapid degradation in the environment.
Note 1
When classifying substances as Acute Category 1 and/or Chronic Category 1 it is necessary at the same time
to indicate an appropriate M-factor (see table 4.1.3).
Note 2
Classification shall be based on the ErC50 [= EC50 (growth rate)]. In circumstances where the basis of the EC50
is not specified or no ErC50 is recorded, classification shall be based on the lowest EC50 available.
Note 3
‘No acute toxicity’ is taken to mean that the L(E)C50(s) is/are above the water solubility. Also for poorly soluble
substances, (water solubility < 1 mg/l), where there is evidence that the acute test does not provide a true
measure of the intrinsic toxicity.
4.1.2.7.1. Acute aquatic toxicity is normally determined using a fish 96 hour LC50, a crustacea species 48 hour EC50
and/or an algal species 72 or 96 hour EC50. These species cover a range of trophic levels and taxa and are
considered as surrogate for all aquatic organisms. Data on other species (e.g. Lemna spp.) shall also be
considered if the test methodology is suitable. The aquatic plant growth inhibition tests are normally
considered as chronic tests but the EC50s are treated as acute values for classification purposes (see note 2).
4.1.2.7.2. For determining chronic aquatic toxicity for classification purposes data generated according to the
standardised test methods referred to in Article 8(3) shall be accepted, as well as results obtained from other
validated and internationally accepted test methods. The NOECS or other equivalent L(E)C x (e.g. EC10) shall be
used.
4.1.2.8. Bioaccumulation
4.1.2.8.1. Bioaccumulation of substances within aquatic organisms can give rise to toxic effects over longer time scales
even when actual water concentrations are low. For organic substances the potential for bioaccumulation
shall normally be determined by using the octanol/water partition coefficient, usually reported as a log K ow.
The relationship between the log Kow of an organic substance and its bioconcentration as measured by the
bioconcentration factor (BCF) in fish has considerable scientific literature support. Using a cut-off value of log
Kow ≥ 4 is intended to identify only those substances with a real potential to bioconcentrate. While this
represents a potential to bioaccumulate, an experimentally determined BCF provides a better measure and
shall be used in preference if available. A BCF in fish of ≥ 500 is indicative of the potential to bioconcentrate
for classification purposes.
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4.1.2.9.1. Substances that rapidly degrade can be quickly removed from the environment. While effects of such
substances can occur, particularly in the event of a spillage or accident, they are localised and of short
duration. In the absence of rapid degradation in the environment a substance in the water has the potential to
exert toxicity over a wide temporal and spatial scale.
4.1.2.9.2. One way of demonstrating rapid degradation utilises the biodegradation screening tests designed to
determine whether an organic substance is ‘readily biodegradable’. Where such data are not available, a BOD
(5 days)/COD ratio ≥ 0,5 is considered as indicative of rapid degradation. Thus, a substance which passes this
screening test is considered likely to biodegrade ‘rapidly’ in the aquatic environment, and is thus unlikely to be
persistent. However, a fail in the screening test does not necessarily mean that the substance will not degrade
rapidly in the environment. Other evidence of rapid degradation in the environment may therefore also be
considered and are of particular importance where the substances are inhibitory to microbial activity at the
concentration levels used in standard testing. Thus, a further classification criterion is included which allows
the use of data to show that the substance did actually degrade biotically or abiotically in the aquatic
environment by > 70 % in 28 days. Thus, if degradation is demonstrated under environmentally realistic
conditions, then the criterion of ‘rapid degradability’ is met.
4.1.2.9.3. Many degradation data are available in the form of degradation half-lives and these can be used in defining
rapid degradation provided that ultimate biodegradation of the substance, i.e. full mineralisation, is achieved.
Primary biodegradation does not normally suffice in the assessment of rapid degradability unless it can be
demonstrated that the degradation products do not fulfil the criteria for classification as hazardous to the
aquatic environment.
4.1.2.9.4. The criteria used reflect the fact that environmental degradation may be biotic or abiotic. Hydrolysis can be
considered if the hydrolysis products do not fulfil the criteria for classification as hazardous to the aquatic
environment.
4.1.2.9.5. Substances are considered rapidly degradable in the environment if one of the following criteria holds true:
(a) if, in 28-day ready biodegradation studies, at least the following levels of degradation are achieved;
(ii) tests based on oxygen depletion or carbon dioxide generation: 60 % of theoretical maximum.
These levels of biodegradation must be achieved within 10 days of the start of degradation which point
is taken as the time when 10 % of the substance has been degraded; or
(b) if, in those cases where only BOD and COD data are available, when the ratio of BOD5/COD is ≥ 0,5;
or
(c) if other convincing scientific evidence is available to demonstrate that the substance can be degraded
(biotically and/or abiotically) in the aquatic environment to a level > 70 % within a 28-day period.
4.1.2.10.1. For inorganic compounds and metals, the concept of degradability as applied to organic compounds has
limited or no meaning. Rather, such substances may be transformed by normal environmental processes to
either increase or decrease the bioavailability of the toxic species. Equally the use of bioaccumulation data
shall be treated with care (1).
4.1.2.10.2. Poorly soluble inorganic compounds and metals may be acutely or chronically toxic in the aquatic
environment depending on the intrinsic toxicity of the bioavailable inorganic species and the rate and amount
of this species which enter solution.
(1) Specific guidance will be provided by the Agency on how these data for such substances may be used in meeting the requirements of the
classification criteria.
L 353/134 EN Official Journal of the European Union 31.12.2008
4.1.3.1. The classification system for mixtures covers all classification categories which are used for substances, i.e.
Acute Category 1 and Chronic Categories 1 to 4. In order to make use of all available data for purposes of
classifying the aquatic environmental hazards of the mixture, the following is applied where appropriate:
The ‘relevant components’ of a mixture are those which are classified ‘Acute Category 1’ or ‘Chronic Category
1’ and present in a concentration of 0,1 % (w/w) or greater, and those which are classified ‘Chronic Category
2’, ‘Chronic Category 3’ or ‘Chronic Category 4’ and present in a concentration of 1 % (w/w) or greater, unless
there is a presumption (such as in the case of highly toxic components (see 4.1.3.5.5.5)) that a component
present in a lower concentration can still be relevant for classifying the mixture for aquatic environmental
hazards. Generally, for substances classified as ‘Acute Category 1’ or ‘Chronic Category 1’ the concentration to
be taken into account is (0,1/M) %. (For explanation M-factor see 4.1.3.5.5.5).
4.1.3.2. The approach for classification of aquatic environmental hazards is tiered, and is dependent upon the type of
information available for the mixture itself and for its components. Figure 4.1.2 outlines the process to be
followed.
Figure 4.1.2
Tiered approach to classification of mixtures for acute and chronic (long term) aquatic
environmental hazards
4.1.3.3. Classification of mixtures when data are available for the complete mixture
4.1.3.3.1. When the mixture as a whole has been tested to determine its aquatic toxicity, it is classified according to the
criteria that have been agreed for substances, but only for acute hazard. The classification is normally based
on the data for fish, crustacea and algae/plants. Classification of mixtures by using LC 50 or EC50 data for the
mixture as a whole is not possible for chronic categories since both toxicity data and environmental fate data
31.12.2008 EN Official Journal of the European Union L 353/135
are needed, and there are no degradability and bioaccumulation data for mixtures as a whole. It is not possible
to apply the criteria for chronic classification because the data from degradability and bioaccumulation tests
of mixtures cannot be interpreted; they are meaningful only for single substances.
4.1.3.3.2. When there is acute toxicity test data (LC50 or EC50) available for the mixture as a whole, these data as well as
information with respect to the classification of components for chronic (long-term) hazard shall be used to
complete the classification for tested mixtures as follows. When chronic toxicity data (NOEC) is also available,
this shall be used too.
(a) L(E)C50 (LC50 or EC50) of the tested mixture ≤ 100 mg/l and NOEC of the tested mixture ≤ 1 mg/l or
unknown:
— Classify mixture as Acute Category 1 (LC50 or EC50 of the tested mixture ≤ 1 mg/l) or no need for
acute classification (LC50 and EC50 of the tested mixture > 1 mg/l).
— Apply summation method (see 4.1.3.5.5) for chronic classification (Chronic Category 1, 2, 3, 4
or no need for chronic classification).
(b) L(E)C50 of the tested mixture ≤ 100 mg/l and NOEC(s) of the tested mixture > 1 mg/l:
— Apply summation method (see 4.1.3.5.5) for classification as Chronic Category 1. If the mixture
is not classified as Chronic Category 1, then there is no need for chronic classification.
(c) L(E)C50(s) of the tested mixture > 100 mg/l, or above the water solubility, and NOEC of the tested
mixture ≤ 1 mg/l or unknown:
— Apply summation method (see 4.1.3.5.5) for Chronic classification (Chronic Category 4 or no
need for chronic classification).
(d) L(E)C50(s) of the tested mixture > 100 mg/l, or above the water solubility, and NOEC(s) of the tested
mixture > 1 mg/l:
4.1.3.4. Classification of mixtures when data are not available for the complete mixture: Bridging principles
4.1.3.4.1. Where the mixture itself has not been tested to determine its aquatic environmental hazard, but there are
sufficient data on the individual components and similar tested mixtures to adequately characterise the
hazards of the mixture, this data shall be used in accordance with the bridging rules set out in section 1.1.3.
However, in relation to application of the bridging rule for dilution, paragraphs 4.1.3.4.2 and 4.1.3.4.3 shall
be used.
4.1.3.4.2. Dilution: if a mixture is formed by diluting another mixture or a substance classified for its aquatic
environmental hazard with a diluent which has an equivalent or lower aquatic hazard classification than the
least toxic original component and which is not expected to affect the aquatic hazards of other components,
then the mixture may be classified as equivalent to the original mixture or substance.
4.1.3.4.3. If a mixture is formed by diluting another classified mixture or substance with water or other totally non-
toxic material, the toxicity of the mixture can be calculated from the original mixture or substance
4.1.3.5. Classification of mixtures when data are available for all components or only for some components of the mixture
4.1.3.5.1. The classification of a mixture is based on summation of the classification of its components. The percentage
of components classified as ‘Acute’ or ‘Chronic’ is fed straight in to the summation method. Details of the
summation method are described in 4.1.3.5.5.
L 353/136 EN Official Journal of the European Union 31.12.2008
4.1.3.5.2. When a mixture consists of components that are not (yet) classified (as Acute Category 1 and/or Chronic
Category 1, 2, 3 or 4) adequate data for these components shall be taken into account when available. When
adequate toxicity data are available for more than one component in the mixture, the combined toxicity of
those components is calculated using the following additivity formula, and the calculated toxicity is used to
assign that portion of the mixture an acute category which is then subsequently used in applying the
summation method.
ΣCi = Σ Ci
CðEÞL50m η CðEÞL50i
where:
4.1.3.5.3. When applying the additivity formula for part of the mixture, it is preferable to calculate the toxicity of this
part of the mixture using for each substance toxicity values that relate to the same taxonomic group (i.e. fish,
daphnia, algae or equivalent) and then to use the highest toxicity (lowest value) obtained (i.e. use the most
sensitive of the three taxonomic groups). However, when toxicity data for each component are not available
in the same taxonomic group, the toxicity value of each component is selected in the same manner that
toxicity values are selected for the classification of substances, i.e. the higher toxicity (from the most sensitive
test organism) is used. The calculated acute toxicity is then used to assess whether this part of the mixture
shall be classified as Acute Category 1 using the same criteria described for substances.
4.1.3.5.4. If a mixture is classified in more than one way, the method yielding the more conservative result shall be used.
4.1.3.5.5.1. Rationale
4.1.3.5.5.1.1. In case of the substance classification categories Acute Category 1 or Chronic Category 1 to Chronic
Category 3, the underlying toxicity criteria differ by a factor of 10 in moving from one category to another.
Substances with a classification in a high toxicity band therefore contribute to the classification of a mixture
in a lower band. The calculation of these classification categories therefore needs to consider the contribution
of all substances classified as Acute Category 1/Chronic Category 1, Chronic Category 2 and Chronic
Category 3 together.
4.1.3.5.5.1.2. When a mixture contains components classified as Acute Category 1 or Chronic Category 1, attention must
be paid to the fact that such components, when their acute toxicity is below 1 mg/l contribute to the toxicity
of the mixture even at a low concentration. Active ingredients in pesticides often possess such high aquatic
toxicity but also some other substances like organometallic compounds. Under these circumstances the
application of the normal generic concentration limits leads to an ‘under-classification’ of the mixture.
Therefore, multiplying factors shall be applied to account for highly toxic components, as described in
paragraph 4.1.3.5.5.5.
4.1.3.5.5.2.1. In general a more severe classification for mixtures overrides a less severe classification, e.g. a classification for
chronic toxicity with Chronic Category 1 overrides a classification with Chronic Category 2. As a
consequence, in this example, the classification procedure is already completed if the result of the
classification is Chronic Category 1. A more severe classification than Chronic Category 1 is not possible.
Therefore it is not necessary to undergo the further classification procedure.
4.1.3.5.5.3.1. First all components classified as Acute Category 1 are considered. If the sum of these components is greater
than 25 % the whole mixture is classified as Acute Category 1.
31.12.2008 EN Official Journal of the European Union L 353/137
4.1.3.5.5.3.2. The classification of mixtures for acute hazards based on this summation of classified components, is
summarised in Table 4.1.1.
Table 4.1.1
4.1.3.5.5.4.1. First all components classified as Chronic Category 1 are considered. If the sum of these components
multiplied by their corresponding M-factors is equal to or greater than 25 % the mixture is classified as
Chronic Category 1. If the result of the calculation is a classification of the mixture as Chronic Category 1 the
classification procedure is completed.
4.1.3.5.5.4.2. In cases where the mixture is not classified as Chronic Category 1, classification of the mixture as Chronic
Category 2 is considered. A mixture is classified as Chronic Category 2 if 10 times the sum of all components
classified as Chronic Category 1 multiplied by their corresponding M-factors plus the sum of all components
classified as Chronic Category 2 is equal to or greater than 25 %. If the result of the calculation is
classification of the mixture as Chronic Category 2, the classification process is completed.
4.1.3.5.5.4.3. In cases where the mixture is not classified either as Chronic Category 1 or Chronic Category 2, classification
of the mixture as Chronic Category 3 is considered. A mixture is classified as Chronic Category 3 if 100 times
the sum of all components classified as Chronic Category 1 multiplied by their corresponding M-factors plus
10 times the sum of all components classified with Chronic Category 2 plus the sum of all components
classified as Chronic Category 3 is ≥ 25 %.
4.1.3.5.5.4.4. If the mixture is still not classified in Chronic Category 1, 2 or 3, classification of the mixture as Chronic
Category 4 shall be considered. A mixture is classified as Chronic Category 4 if the sum of the percentages of
components classified as Chronic Category 1, 2, 3 and 4 is equal to or greater than 25 %.
4.1.3.5.5.4.5. The classification of mixtures for chronic (long term) hazards, based on this summation of classified
components, is summarised in Table 4.1.2.
Table 4.1.2
Classification of a mixture for chronic (long term) hazards, based on summation of classified
components
4.1.3.5.5.5. M i x t u r e s w i t h h i g h l y t ox i c c o m p o n e n t s
4.1.3.5.5.5.1. Acute Category 1 and Chronic Category 1 components with toxicities below 1 mg/l contribute to the toxicity
of the mixture even at a low concentration and shall normally be given increased weight in applying the
summation of classification approach. When a mixture contains components classified as Acute or Chronic
Category 1, one of the following shall be applied:
— The tiered approach described in 4.1.3.5.5.3 and 4.1.3.5.5.4 using a weighted sum by multiplying the
concentrations of Acute Category 1 and Chronic Category 1 components by a factor, instead of merely
adding up the percentages. This means that the concentration of ‘Acute Category 1’ in the left column
of Table 4.1.1 and the concentration of ‘Chronic Category 1’ in the left column of Table 4.1.2 are
multiplied by the appropriate multiplying factor. The multiplying factors to be applied to these
components are defined using the toxicity value, as summarised in Table 4.1.3. Therefore, in order to
classify a mixture containing Acute/Chronic Category 1 components, the classifier needs to be
informed of the value of the M-factor in order to apply the summation method;
— The additivity formula (see 4.1.3.5.2) provided that toxicity data are available for all highly toxic
components in the mixture and there is convincing evidence that all other components, including those
for which specific acute toxicity data are not available, are of low or no toxicity and do not significantly
contribute to the environmental hazard of the mixture.
Table 4.1.3
4.1.3.6.1. In the event that no useable information on acute and/or chronic (long term) aquatic hazard is available for
one or more relevant components, it is concluded that the mixture cannot be attributed to one or more
definitive hazard category(ies). In this situation the mixture shall be classified based on the known
components only, with the additional statement in the SDS that: ‘Contains x % of components with unknown
hazards to the aquatic environment’.
4.1.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 4.1.4.
Table 4.1.4
ACUTE
Category 1
GHS Pictogram
ACUTE
Category 1
CHRONIC
Hazard Statement H410: Very toxic H411: Toxic to H412: Harmful to H413: May cause
to aquatic life aquatic life with aquatic life with long lasting harm-
with long lasting long lasting long lasting ful effects to aquatic
effects effects effects life
Precautionary
Statement Storage
5.1.1.1. Substance Hazardous to the Ozone Layer means a substance which, on the basis of the available evidence
concerning its properties and its predicted or observed environmental fate and behaviour may present a
danger to the structure and/or the functioning of the stratospheric ozone layer. This includes substances
which are listed in Annex I to Regulation (EC) No 2037/2000 of the European Parliament and of the Council
of 29 June 2000 on substances that deplete the ozone layer (1) and its subsequent amendments.
5.1.2.1. A substance shall be classified as Hazardous to the Ozone Layer if the available evidence concerning its
properties and its predicted or observed environmental fate and behaviour indicate that it may present a
danger to the structure and/or the functioning of the stratospheric ozone layer.
5.1.3.1. Mixtures shall be classified as Hazardous to the Ozone Layer on the basis of the individual concentration of
the substance(s) contained therein that are also classified as Hazardous to the Ozone Layer, in accordance
with Table 5.1.
Table 5.1
Generic concentration limits for substances (in a mixture), classified as Hazardous to the Ozone
Layer, that trigger classification of the mixture as Hazardous to the Ozone Layer
5.1.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard
class in accordance with Table 5.2
Table 5.2
Symbol/pictogram
ANNEX II
SPECIAL RULES FOR LABELLING AND PACKAGING OF CERTAIN SUBSTANCES AND MIXTURES
— Part 1 contains special rules for the labelling of certain classified substances and mixtures.
— Part 2 sets out rules for additional hazard statements to be included on the label of certain mixtures.
— Part 4 sets out a special rule for the labelling of plant protection products.
— Part 5 sets up a list of hazardous substances and mixtures to which Article 29(3) applies.
The statements set out in sections 1.1 and 1.2 shall be assigned in accordance with Article 25(1) to substances
and mixtures classified for physical, health or environmental hazards.
For explosive substances and mixtures as referred to in section 2.1 of Annex I, placed on the market wetted with
water or alcohols or diluted with other substances to suppress their explosive properties.
For substances and mixtures which are unstable at ambient temperatures, such as acetylene.
For substances and mixtures which react violently with water, such as acetyl chloride, alkali metals, titanium
tetrachloride.
For substances and mixtures not classified as flammable themselves, which may form flammable/explosive
vapour-air mixtures. For substances this might be the case for halogenated hydrocarbons and for mixtures this
might be the case due to a volatile flammable component or due to the loss of a volatile non-flammable
component.
For substances and mixtures which may form explosive peroxides during storage, such as diethyl ether,
1,4-dioxane.
For substances and mixtures not in themselves classified as explosive in accordance with section 2.1 of Annex I,
but which may nevertheless display explosive properties in practice if heated under sufficient confinement. In
particular, substances which decompose explosively if heated in a steel drum do not show this effect if heated in
less-strong containers.
L 353/142 EN Official Journal of the European Union 31.12.2008
For substances and mixtures which in contact with water or damp air, evolve gases classified for acute toxicity in
category 1, 2 or 3 in potentially dangerous amounts, such as aluminium phosphide, phosphorus pentasulphide.
For substances and mixtures which react with acids to evolve gases classified for acute toxicity in category 3 in
dangerous amounts, such as sodium hypochlorite, barium polysulphide.
For substances and mixtures which react with acids to evolve gases classified for acute toxicity in category 1 or 2
in dangerous amounts, such as salts of hydrogen cyanide, sodium azide.
For substances and mixtures which may cause concern as a result of skin dryness, flaking or cracking but which
do not meet the criteria for skin irritancy in section 3.2 of Annex I, based on either:
— practical observations; or
For substances or mixtures where an eye irritation test has resulted in overt signs of systemic toxicity or mortality
among the animals tested, which is likely to be attributed to absorption of the substance or mixture through the
mucous membranes of the eye. The statement shall also be applied if there is evidence in humans for systemic
toxicity after eye contact.
The statement shall also be applied where a substance or a mixture contains another substance labelled for this
effect, if the concentration of this substance is equal to, or greater than 0,1 %, unless otherwise specified in part 3
of Annex VI.
For substances and mixtures in addition to classification for inhalation toxicity, if data are available that indicate
that the mechanism of toxicity is corrosivity, in accordance with section 3.1.2.3.3 and Note 1 of Table 3.1.3 in
Annex I.
For substances and mixtures in addition to classification for skin corrosivity, if no acute inhalation test data are
available and which may be inhaled.
2. PART 2: SPECIAL RULES FOR SUPPLEMENTAL LABEL ELEMENTS FOR CERTAIN MIXTURES
The statements set out in sections 2.1 to 2.10 shall be assigned to mixtures in accordance with Article 25(6).
The label on the packaging of paints and varnishes containing lead in quantities exceeding 0,15 % (expressed as
weight of metal) of the total weight of the mixture, as determined in accordance with ISO standard 6503, shall
bear the following statement:
EUH201 — ‘Contains lead. Should not be used on surfaces liable to be chewed or sucked by children’
In the case of packages the contents of which are less than 125 ml, the statement may be as follows:
The label on the immediate packaging of adhesives based on cyanoacrylate shall bear the following statement:
EUH202 — ‘Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children’
Unless cements or cement mixtures are already classified and labelled as a sensitiser with the hazard statement
H317, ‘May cause an allergic skin reaction’, the label on the packaging of cements and cement mixtures that
contain, when they are hydrated, more than 0,0002 % soluble chromium (VI) of the total dry weight of the
cement shall bear the statement:
If reducing agents are used, then the packaging of cement or cement-containing mixtures shall include
information on the packing date, the storage conditions and the storage period appropriate to maintaining the
activity of the reducing agent and to keeping the content of soluble chromium VI below 0,0002 %.
Unless already identified on the label of the packaging, mixtures containing isocyanates (as monomers,
oligomers, prepolymers, etc., or as mixtures thereof) shall bear the following statement:
2.5. Mixtures containing epoxy constituents with an average molecular weight ≤ 700
Unless already identified on the label of the packaging, mixtures containing epoxy constituents with an average
molecular weight ≤ 700 shall bear the following statement:
2.6. Mixtures sold to the general public which contain active chlorine
The label on the packaging of mixtures containing more than 1 % of active chlorine shall bear the following
statement:
EUH206 — ‘Warning! Do not use together with other products. May release dangerous gases (chlorine)’
2.7. Mixtures containing cadmium (alloys) and intended to be used for brazing or soldering
The label on the packaging of the above mentioned mixtures shall bear the following statement:
EUH207 — ‘Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by
the manufacturer. Comply with the safety instructions’
2.8. Mixtures not classified as sensitising but containing at least one sensitising substance
The label on the packaging of mixtures containing at least one substance classified as sensitising and present in a
concentration equal to or greater than 0,1 % or in a concentration equal to or greater than that specified under a
specific note for the substance in part 3 of Annex VI shall bear the statement:
For liquid mixtures which show no flashpoint or a flashpoint higher than 60 oC but not more than 93 oC and
contain a halogenated hydrocarbon and more than 5 % highly flammable or flammable substances, the label on
the packaging shall bear one of the following statements, depending on whether the substances referred to above
are highly flammable or flammable:
— ≥ 0,1 % of a substance classified as toxic to reproduction categories 1A, 1B or 2, or with effects on or via
lactation; or
— at least one substance in an individual concentration of ≥ 1 % by weight for non-gaseous mixtures and
≥ 0,2 % by volume for gaseous mixtures either:
2.11 Aerosols
Note that aerosols are also subject to the labelling provisions in accordance with points 2.2 and 2.3 in the Annex
to Directive 75/324/EEC.
3.1.1.1. Packaging of whatever capacity containing a substance or mixture supplied to the general public and classified for
acute toxicity, categories 1 to 3, STOT — single exposure category 1, STOT — repeated exposure category 1, or
skin corrosion category 1 shall be fitted with child-resistant fastenings.
3.1.1.2. Packaging of whatever capacity containing a substance or mixture supplied to the general public presenting an
aspiration hazard and classified according to sections 3.10.2 and 3.10.3 of Annex I and labelled according to
section 3.10.4.1 of Annex I, with the exception of substances and mixtures placed on the market in the form of
aerosols or in a container fitted with a sealed spray attachment, shall be fitted with child-resistant fastenings.
3.1.1.3 Where a substances or mixture has at least one of the substances mentioned below present in a concentration
equal to or greater than the maximum individual concentrations specified, which are supplied to the general
public, the packaging of whatever capacity shall be fitted with child-resistant fastenings.
3.1.4 Notes
3.1.4.1. Evidence of conformity with the above standards may be certified only by laboratories which conform with
Standard EN ISO/IEC 17025 as amended.
— the type of closure is such that it is not necessary to perform the test referred to in section 3.1.2. or 3.1.3;
or
— the closure has been tested and has been found to conform with the standards referred to above.
EUH401 — ‘To avoid risks to human health and the environment, comply with the instructions for use’
5. PART 5: LIST OF HAZARDOUS SUBSTANCES AND MIXTURES TO WHICH ARTICLE 29(3) APPLIES
— Ready mixed cement and concrete in the wet state.
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ANNEX III
The hazard statements shall be applied in accordance with Parts 2, 3 and 4 of Annex I.
Table 1.1
BG Нестабилен експлозив.
ES Explosivo inestable.
CS Nestabilní výbušnina.
DA Ustabilt eksplosiv.
DE Instabil, explosiv.
ET Ebapüsiv lõhkeaine.
EL Ασταθή εκρηκτικά.
EN Unstable explosives.
FR Explosif instable.
GA Pléascáin éagobhsaí.
IT Esplosivo instabile.
HU Instabil robbanóanyagok.
MT Splussivi instabbli.
PT Explosivo instável.
RO Exploziv instabil.
SK Nestabilné výbušniny.
SL Nestabilni eksplozivi.
FI Epästabiili räjähde.
SV Instabilt explosivt.
(1) The codification system for GHS hazard statements is still under discussion in the UN Committee of Experts and therefore amendments
might be needed.
DA Eksplosiv, masseeksplosionsfare.
ET Plahvatusohtlik; massiplahvatusoht.
FI Räjähde; massaräjähdysvaara.
DE Explosiv; Gefahr durch Feuer, Luftdruck oder Splitter, Spreng- und Wurfstücke.
GA Gás fíor-inadhainte.
BG Запалим газ.
ES Gas inflamable.
CS Hořlavý plyn.
DA Brandfarlig gas.
DE Entzündbares Gas.
31.12.2008 EN Official Journal of the European Union L 353/151
ET Tuleohtlik gaas.
EL Εύφλεκτο αέριο.
EN Flammable gas.
FR Gaz inflammable.
GA Gás inadhainte.
IT Gas infiammabile.
LV Uzliesmojoša gāze.
LT Degios dujos.
HU Tűzveszélyes gáz.
MT Gass li jaqbad.
NL Ontvlambaar gas.
PL Gaz łatwopalny.
PT Gás inflamável.
RO Gaz inflamabil.
SK Horľavý plyn.
SL Vnetljiv plin.
FI Syttyvä kaasu.
SV Brandfarlig gas.
GA Aerasól fíor-inadhainte.
BG Запалим аерозол.
ES Aerosol inflamable.
CS Hořlavý aerosol.
DA Brandfarlig aerosol.
DE Entzündbares Aerosol.
ET Tuleohtlik aerosool.
EL Εύφλεκτο αερόλυμα.
EN Flammable aerosol.
FR Aérosol inflammable.
GA Aerasól inadhainte.
IT Aerosol infiammabile.
LV Uzliesmojošs aerosols.
LT Degus aerozolis.
HU Tűzveszélyes aeroszol.
MT Aerosol li jaqbad.
NL Ontvlambare aerosol.
PL Aerozol łatwopalny.
PT Aerossol inflamável.
RO Aerosol inflamabil.
SK Horľavý aerosól.
SL Vnetljiv aerosol.
FI Syttyvä aerosoli.
SV Brandfarlig aerosol.
ES Sólido inflamable.
DE Entzündbarer Feststoff.
EL Εύφλεκτο στερεό.
31.12.2008 EN Official Journal of the European Union L 353/155
EN Flammable solid.
GA Solad inadhainte.
IT Solido infiammabile.
MT Solidu li jaqbad.
PT Sólido inflamável.
RO Solid inflamabil.
HU Hő hatására robbanhat.
FI Räjähdysvaarallinen kuumennettaessa.
HU Hő hatására meggyulladhat.
FI Palovaarallinen kuumennettaessa.
HU Önmelegedő: meggyulladhat.
H260 Language 2.12 — Substances and Mixtures which, in contact with water, emit flammable gases, Hazard
Category 1
CS Při styku s vodou uvolňuje hořlavé plyny, které se mohou samovolně vznítit.
DA Ved kontakt med vand udvikles brandfarlige gasser, som kan selvantænde.
DE In Berührung mit Wasser entstehen entzündbare Gase, die sich spontan entzünden können.
EN In contact with water releases flammable gases which may ignite spontaneously.
FR Dégage au contact de l'eau des gaz inflammables qui peuvent s'enflammer spontanément.
IT A contatto con l'acqua libera gas infiammabili che possono infiammarsi spontaneamente.
LV Nonākot saskarē ar ūdeni, izdala uzliesmojošas gāzes, kas var spontāni aizdegties.
MT Meta jmiss ma' l-ilma jerħi gassijiet li jaqbdu li jistgħu jieħdu n-nar spontanjament.
NL In contact met water komen ontvlambare gassen vrij die spontaan kunnen ontbranden.
H260 Language 2.12 — Substances and Mixtures which, in contact with water, emit flammable gases, Hazard
Category 1
SK Pri kontakte s vodou uvoľňuje horľavé plyny, ktoré sa môžu spontánne zapáliť.
SV Vid kontakt med vatten utvecklas brandfarliga gaser som kan självantända.
H261 Language 2.12 — Substances and Mixtures which, in contact with water, emit flammable gases, Hazard
Category 2
GA Gás cuisnithe istigh ann; d'fhéadfadh sé a bheith ina chúis le dónna crióigineacha nó le
díobháil chrióigineach.
MT Fih gass imkessaħ; jista' jikkawża ħruq jew dannu minn temperaturi baxxi.
Table 1.2
ET Allaneelamisel surmav.
EN Fatal if swallowed.
GA Marfach má shlogtar.
IT Letale se ingerito.
LT Mirtina prarijus.
HU Lenyelve halálos.
SK Smrteľný po požití.
FI Tappavaa nieltynä.
ET Allaneelamisel mürgine.
EN Toxic if swallowed.
GA Tocsaineach má shlogtar.
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IT Tossico se ingerito.
LV Toksisks, ja norij.
LT Toksiška prarijus.
HU Lenyelve mérgező.
SK Toxický po požití.
FI Myrkyllistä nieltynä.
ET Allaneelamisel kahjulik.
EN Harmful if swallowed.
GA Díobhálach má shlogtar.
IT Nocivo se ingerito.
LV Kaitīgs, ja norij.
LT Kenksminga prarijus.
HU Lenyelve ártalmas.
SK Škodlivý po požití.
FI Haitallista nieltynä.
FR Peut être mortel en cas d'ingestion et de pénétration dans les voies respiratoires.
CS Dráždí kůži.
DA Forårsager hudirritation.
DE Verursacht Hautreizungen.
ET Põhjustab nahaärritust.
LV Kairina ādu.
LT Dirgina odą.
HU Bőrirritáló hatású.
NL Veroorzaakt huidirritatie.
SK Dráždi kožu.
FI Ärsyttää ihoa.
SV Irriterar huden.
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ET Sissehingamisel surmav.
EN Fatal if inhaled.
GA Marfach má ionanálaítear.
IT Letale se inalato.
LT Mirtina įkvėpus.
HU Belélegezve halálos.
FI Tappavaa hengitettynä.
ET Sissehingamisel mürgine.
EN Toxic if inhaled.
GA Tocsaineach má ionanálaítear.
IT Tossico se inalato.
LV Toksisks ieelpojot.
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LT Toksiška įkvėpus.
HU Belélegezve mérgező.
FI Myrkyllistä hengitettynä.
ET Sissehingamisel kahjulik.
EN Harmful if inhaled.
GA Díobhálach má ionanálaítear.
IT Nocivo se inalato.
LV Kaitīgs ieelpojot.
LT Kenksminga įkvėpus.
HU Belélegezve ártalmas.
FI Haitallista hengitettynä.
BG Може да причини алергични или астматични симптоми или затруднения в дишането при
вдишване.
CS Při vdechování může vyvolat příznaky alergie nebo astmatu nebo dýchací potíže.
FR Peut provoquer des symptômes allergiques ou d'asthme ou des difficultés respiratoires par
inhalation.
LV Ja ieelpo, var izraisīt alerģiju vai astmas simptomus, vai apgrūtināt elpošanu.
LT Įkvėpus gali sukelti alerginę reakciją, astmos simptomus arba apsunkinti kvėpavimą.
MT Jista’ jikkawża sintomi ta' allerġija jew ta’ ażma jew diffikultajiet biex jittieħed in-nifs jekk
jinxtamm.
PL Może powodować objawy alergii lub astmy lub trudności w oddychaniu w następstwie
wdychania.
RO Poate provoca simptome de alergie sau astm sau dificultăţi de respiraţie în caz de inhalare.
SK Pri vdýchnutí môže vyvolať alergiu alebo príznaky astmy, alebo dýchacie ťažkosti.
SL Lahko povzroči simptome alergije ali astme ali težave z dihanjem pri vdihavanju.
H335 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 3, Respiratory tract irritation
H335 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 3, Respiratory tract irritation
H336 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 3, Narcosis
H336 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 3, Narcosis
BG Може да причини генетични дефекти < да се посочи пътят на експозицията, ако е доказано
убедително, че няма друг път на експозиция, който води до същата опасност >.
CS Může vyvolat genetické poškození <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní
cesty expozice nejsou nebezpečné>.
DA Kan forårsage genetiske defekter <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke
kan frembringes ad nogen anden eksponeringsvej>.
DE Kann genetische Defekte verursachen <Expositionsweg angeben, sofern schlüssig belegt ist, dass
diese Gefahr bei keinem anderen Expositionsweg besteht>.
ET Võib põhjustada geneetilisi defekte <märkida kokkupuuteviis, kui on veenvalt tõestatud, et muud
kokkupuuteviisid ei ole ohtlikud>.
EL Μπορεί να προκαλέσει γενετικά ελαττώματα < αναφέρεται η οδός έκθεσης αν έχει αποδειχθεί
αδιαμφισβήτητα ότι δεν υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης >.
EN May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
FR Peut induire des anomalies génétiques <indiquer la voie d'exposition s'il est formellement prouvé
qu'aucune autre voie d'exposition ne conduit au même danger>.
IT Può provocare alterazioni genetiche <indicare la via di esposizione se è accertato che nessun'altra
via di esposizione comporta il medesimo pericolo>.
LV Var izraisīt ģenētiskus bojājumus <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi
iedarbības ceļi nerada bīstamību>.
LT Gali sukelti genetinius defektus <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti
veikimo būdai nepavojingi>.
HU Genetikai károsodást okozhat < meg kell adni az expozíciós útvonalat, ha meggyőzően
bizonyított, hogy más expozíciós útvonal nem okozza a veszélyt >.
MT Jista’ jikkawża difetti ġenetiċi <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod
konklużiv li l-ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu>.
PL Może powodować wady genetyczne <podać drogę narażenia, jeżeli definitywnie udowodniono, że
inna droga narażenia nie powoduje zagrożenia>.
PT Pode provocar anomalias genéticas <indicar a via de exposição se existirem provas concludentes de
que o perigo não decorre de nenhuma outra via de exposição>.
RO Poate provoca anomalii genetice <indicaţi calea de expunere, dacă există probe concludente că
nicio altă cale de expunere nu provoacă acest pericol>.
FI Saattaa aiheuttaa perimävaurioita <mainitaan altistumisreitti, jos on kiistatta osoitettu, että vaara
ei voi aiheutua muiden altistumisreittien kautta>.
SV Kan orsaka genetiska defekter <ange exponeringsväg om det är definitivt bevisat att faran inte kan
orsakas av några andra exponeringsvägar>.
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BG Предполага се, че причинява генетични дефекти < да се посочи пътят на експозицията, ако
е доказано убедително, че няма друг път на експозиция, който води до същата опасност >.
CS Podezření na genetické poškození <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní
cesty expozice nejsou nebezpečné>.
DA Mistænkt for at forårsage genetiske defekter <angiv eksponeringsvej, hvis det er endeligt påvist, at
faren ikke kan frembringes ad nogen anden eksponeringsvej>.
EL Ύποπτο για πρόκληση γενετικών ελαττωμάτων <αναφέρεται η οδός έκθεσης αν έχει αποδειχθεί
αδιαμφισβήτητα ότι δεν υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης>.
EN Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.
FR Susceptible d'induire des anomalies génétiques <indiquer la voie d'exposition s'il est
formellement prouvé qu'aucune autre voie d'exposition ne conduit au même danger>.
LT Įtariama, kad gali sukelti genetinius defektus <nurodyti veikimo būdą, jeigu įtikinamai nustatyta,
kad kiti veikimo būdai nepavojingi>.
HU Feltehetően genetikai károsodást okoz < meg kell adni az expozíciós útvonalat, ha meggyőzően
bizonyított, hogy más expozíciós útvonal nem okozza a veszélyt >.
MT Suspettat li jikkawża difetti ġenetiċi <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod
konklużiv li l-ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu>.
NL Verdacht van het veroorzaken van genetische schade <blootstellingsroute vermelden indien
afdoende bewezen is dat het gevaar bij andere blootstellingsroutes niet aanwezig is>.
PL Podejrzewa się, że powoduje wady genetyczne <podać drogę narażenia, jeżeli definitywnie
udowodniono, że inna droga narażenia nie powoduje zagrożenia>.
RO Susceptibil de a provoca anomalii genetice < indicaţi calea de expunere, dacă există probe
concludente că nicio altă cale de expunere nu provoacă acest pericol>.
SV Misstänks kunna orsaka genetiska defekter <ange exponeringsväg om det är definitivt bevisat att
faran inte kan orsakas av några andra exponeringsvägar>.
BG Може да причини рак < да се посочи пътят на експозицията, ако е доказано убедително, че
няма друг път на експозиция, който води до същата опасност >.
CS Může vyvolat rakovinu <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní cesty expozice
nejsou nebezpečné>.
DA Kan fremkalde kræft <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan
frembringes ad nogen anden eksponeringsvej>.
DE Kann Krebs erzeugen <Expositionsweg angeben, sofern schlüssig belegt ist, dass diese Gefahr bei
keinem anderen Expositionsweg besteht>.
EN May cause cancer <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
FR Peut provoquer le cancer <indiquer la voie d'exposition s'il est formellement prouvé qu'aucune autre
voie d'exposition ne conduit au même danger>.
LV Var izraisīt vēzi <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi iedarbības ceļi nerada
bīstamību>.
LT Gali sukelti vėžį <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo būdai
nepavojingi>.
HU Rákot okozhat < meg kell adni az expozíciós útvonalat, ha meggyőzően bizonyított, hogy más
expozíciós útvonal nem okozza a veszélyt >.
MT Jista’ jikkawża l-kanċer <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li
l-ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu>.
NL Kan kanker veroorzaken <blootstellingsroute vermelden indien afdoende bewezen is dat het gevaar
bij andere blootstellingsroutes niet aanwezig is>
PL Może powodować raka <podać drogę narażenia, jeżeli definitywnie udowodniono, że inna droga
narażenia nie powoduje zagrożenia>.
PT Pode provocar cancro <indicar a via de exposição se existirem provas concludentes de que o perigo
não decorre de nenhuma outra via de exposição>.
RO Poate provoca cancer <indicaţi calea de expunere, dacă există probe concludente că nicio altă cale
de expunere nu provoacă acest pericol>.
SK Môže spôsobiť rakovinu <uveďte spôsob expozície, ak sa presvedčivo preukáže, že iné spôsoby
expozície nevyvolávajú nebezpečenstvo>.
SL Lahko povzroči raka <navesti način izpostavljenosti, če je prepričljivo dokazano, da noben drug
način izpostavljenosti ne povzroča takšne nevarnosti>.
FI Saattaa aiheuttaa syöpää <mainitaan altistumisreitti, jos on kiistatta osoitettu, että vaara ei voi
aiheutua muiden altistumisreittien kautta>.
SV Kan orsaka cancer <ange exponeringsväg om det är definitivt bevisat att faran inte kan orsakas av
några andra exponeringsvägar>.
BG Предполага се, че причинява рак < да се посочи пътят на експозицията, ако е доказано
убедително, че няма друг път на експозиция, който води до същата опасност >.
CS Podezření na vyvolání rakoviny <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní
cesty expozice nejsou nebezpečné>.
L 353/180 EN Official Journal of the European Union 31.12.2008
DA Mistænkt for at fremkalde kræft <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke
kan frembringes ad nogen anden eksponeringsvej>.
DE Kann vermutlich Krebs erzeugen <Expositionsweg angeben, sofern schlüssig belegt ist, dass diese
Gefahr bei keinem anderen Expositionsweg besteht>.
EN Suspected of causing cancer <state route of exposure if it is conclusively proven that no other routs
of exposure cause the hazard>.
FR Susceptible de provoquer le cancer <indiquer la voie d'exposition s'il est formellement prouvé
qu'aucune autre voie d'exposition ne conduit au même danger>.
IT Sospettato di provocare il cancro <indicare la via di esposizione se è accertato che nessun'altra via
di esposizione comporta il medesimo pericolo>.
LV Ir aizdomas, ka var izraisīt vēzi <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi
iedarbības ceļi nerada bīstamību>.
LT Įtariama, kad sukelia vėžį <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo
būdai nepavojingi>.
HU Feltehetően rákot okoz < meg kell adni az expozíciós útvonalat, ha meggyőzően bizonyított, hogy
más expozíciós útvonal nem okozza a veszélyt >.
MT Suspettat li jikkawża l-kanċer <ara l-mod ta’ espożizzjoni jekk ikun pruvat b'mod konklużiv
li l-ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu >.
NL Verdacht van het veroorzaken van kanker <blootstellingsroute vermelden indien afdoende
bewezen is dat het gevaar bij andere blootstellingsroutes niet aanwezig is>.
PL Podejrzewa się, że powoduje raka <podać drogę narażenia, jeżeli definitywnie udowodniono, że
inna droga narażenia nie powoduje zagrożenia>.
PT Suspeito de provocar cancro <indicar a via de exposição se existirem provas concludentes de que o
perigo não decorre de nenhuma outra via de exposição>.
RO Susceptibil de a provoca cancer <indicaţi calea de expunere, dacă există probe concludente că nicio
altă cale de expunere nu provoacă acest pericol>.
SL Sum povzročitve raka <navesti način izpostavljenosti, če je prepričljivo dokazano, da noben drug
način izpostavljenosti ne povzroča takšne nevarnosti>.
FI Epäillään aiheuttavan syöpää <mainitaan altistumisreitti, jos on kiistatta osoitettu, että vaara ei
voi aiheutua muiden altistumisreittien kautta>.
SV Misstänks kunna orsaka cancer <ange exponeringsväg om det är definitivt bevisat att faran inte
kan orsakas av några andra exponeringsvägar>.
CS Může poškodit reprodukční schopnost nebo plod v těle matky <uveďte specifický účinek, je-li
znám> <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní cesty expozice nejsou
nebezpečné>.
31.12.2008 EN Official Journal of the European Union L 353/181
DA Kan skade forplantningsevnen eller det ufødte barn <angiv specifik effekt, hvis kendt> <angiv
eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan frembringes ad nogen anden
eksponeringsvej>.
DE Kann die Fruchtbarkeit beeinträchtigen oder das Kind im Mutterleib schädigen <konkrete
Wirkung angeben, sofern bekannt> <Expositionsweg angeben, sofern schlüssig belegt ist, dass die
Gefahr bei keinem anderen Expositionsweg besteht>.
ET Võib kahjustada viljakust või loodet <märkida spetsiifiline toime, kui see on teada> <märkida
kokkupuuteviis, kui on veenvalt tõestatud, et muud kokkupuuteviisid ei ole ohtlikud>.
EN May damage fertility or the unborn child <state specific effect if known > <state route of exposure
if it is conclusively proven that no other routes of exposure cause the hazard>.
FR Peut nuire à la fertilité ou au fœtus <indiquer l'effet spécifique s'il est connu> <indiquer la voie
d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même
danger>.
IT Può nuocere alla fertilità o al feto <indicare l'effetto specifico, se noto><indicare la via di
esposizione se è accertato che nessun'altra via di esposizione comporta il medesimo pericolo>.
LV Var kaitēt auglībai vai nedzimušajam bērnam <norādīt īpašo ietekmi, ja tā ir zināma> <norādīt
iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi iedarbības ceļi nerada bīstamību>.
LT Gali pakenkti vaisingumui arba negimusiam vaikui <nurodyti konkretų poveikį, jeigu žinomas>
<nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo būdai nepavojingi>.
HU Károsíthatja a termékenységet vagy a születendő gyermeket < ha ismert, meg kell adni a
konkrét hatást > < meg kell adni az expozíciós útvonalat, ha meggyőzően bizonyított, hogy más
expozíciós útvonal nem okozza a veszélyt >.
MT Jista' jagħmel ħsara lill-fertilità jew lit-tarbija li għadha fil-ġuf <semmi l-effett speċifiku jekk
ikun magħruf> <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li l-ebda mod ta'
espożizzjoni ieħor ma jikkawża l-periklu>.
NL Kan de vruchtbaarheid of het ongeboren kind schaden <specifiek effect vermelden indien
bekend> <blootstellingsroute vermelden indien afdoende bewezen is dat het gevaar bij andere
blootstellingsroutes niet aanwezig is>.
PL Może działać szkodliwie na płodność lub na dziecko w łonie matki <podać szczególny skutek,
jeżeli jest znany> <podać drogę narażenia, jeżeli definitywnie udowodniono, że inne drogi narażenia
nie stwarzają zagrożenia>.
PT Pode afectar a fertilidade ou o nascituro <indicar o efeito específico se este for conhecido> <indicar
a via de exposição se existirem provas concludentes de que o perigo não decorre de nenhuma outra via
de exposição>.
RO Poate dăuna fertilităţii sau fătului <indicaţi efectul specific, dacă este cunoscut><indicaţi calea de
expunere, dacă există probe concludente că nicio altă cale de expunere nu provoacă acest pericol>.
SK Môže spôsobiť poškodenie plodnosti alebo nenarodeného dieťaťa <uveďte konkrétny účinok,
ak je známy > <uveďte spôsob expozície, ak sa presvedčivo preukáže, že iné spôsoby expozície
nevyvolávajú nebezpečenstvo>.
SL Lahko škoduje plodnosti ali nerojenemu otroku <navesti posebni učinek, če je znan> <navesti
način izpostavljenosti, če je prepričljivo dokazano, da noben drug način izpostavljenosti ne povzroča
takšne nevarnosti>.
SV Kan skada fertiliteten eller det ofödda barnet <ange specifik effekt om denna är känd> <ange
exponeringsväg om det är definitivt bevisat att faran inte kan orsakas av några andra
exponeringsvägar>.
L 353/182 EN Official Journal of the European Union 31.12.2008
BG Предполага се, че уврежда оплодителната способност или плода < да се посочи конкретното
въздействие, ако е известно > < да се посочи пътят на експозицията, ако е доказано
убедително, че няма друг път на експозиция, който води до същата опасност >.
ES Se sospecha que perjudica la fertilidad o daña al feto <indíquese el efecto específico si se conoce>
<indíquese la vía de exposición si se ha demostrado concluyentemente que el peligro no se produce por
ninguna otra vía>.
CS Podezření na poškození reprodukční schopnosti nebo plodu v těle matky <uveďte specifický
účinek, je-li znám> <uveďte cestu expozice, je-li přesvědčivě prokázáno, že ostatní cesty expozice
nejsou nebezpečné>.
DA Mistænkt for at skade forplantningsevnen eller det ufødte barn <angiv specifik effekt, hvis
kendt> <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan frembringes ad nogen
anden eksponeringsvej>.
DE Kann vermutlich die Fruchtbarkeit beeinträchtigen oder das Kind im Mutterleib schädigen
< konkrete Wirkung angebe, n sofern bekannt > <Expositionsweg angeben, sofern schlüssig belegt
ist, dass die Gefahr bei keinem anderen Expositionsweg besteht>
ET Arvatavasti kahjustab viljakust või loodet <märkida spetsiifiline toime, kui see on teada>
<märkida kokkupuuteviis, kui on veenvalt tõestatud, et muud kokkupuuteviisid ei ole ohtlikud>.
EL Ύποπτο για πρόκληση βλάβης στη γονιμότητα ή στο έμβρυο <αναφέρεται η ειδική επίπτωση
εάν είναι γνωστή> <αναφέρεται η οδός έκθεσης αν έχει αποδειχθεί αδιαμφισβήτητα ότι δεν
υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης>.
EN Suspected of damaging fertility or the unborn child <state specific effect if known> <state route
of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
FR Susceptible de nuire à la fertilité ou au fœtus <indiquer l'effet s'il est connu> <indiquer la voie
d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même
danger>.
IT Sospettato di nuocere alla fertilità o al feto <indicare l'effetto specifico, se noto> <indicare la via
di esposizione se è accertato che nessun'altra via di esposizione comporta il medesimo pericolo>.
LV Ir aizdomas, ka var kaitēt auglībai vai nedzimušajam bērnam <norādīt īpašo ietekmi, ja tā ir
zināma> <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi iedarbības ceļi nerada
bīstamību>.
LT Įtariama, kad kenkia vaisingumui arba negimusiam vaikui <nurodyti konkretų poveikį, jeigu
žinomas> <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo būdai nepavojingi>.
HU Feltehetően károsítja a termékenységet vagy a születendő gyermeket < ha ismert, meg kell
adni a konkrét hatást > < meg kell adni az expozíciós útvonalat, ha meggyőzően bizonyított, hogy
más expozíciós útvonal nem okozza a veszélyt >.
MT Suspettat li jagħmel ħsara lill-fertilità jew lit-tarbija li għadha fil-ġuf <semmi l-effett speċifiku
jekk ikun magħruf> <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li l-ebda mod
ta' espożizzjoni ieħor ma jikkawża l-periklu >.
NL Kan mogelijks de vruchtbaarheid of het ongeboren kind schaden <specifiek effect vermelden
indien bekend> <blootstellingsroute vermelden indien afdoende bewezen is dat het gevaar bij andere
blootstellingsroutes niet aanwezig is>.
PL Podejrzewa się, że działa szkodliwie na płodność lub na dziecko w łonie matki <podać
szczególny skutek, jeżeli jest znany> <podać drogę narażenia, jeżeli definitywnie udowodniono, że
inne drogi narażenia nie stwarzają zagrożenia>.
PT Suspeito de afectar a fertilidade ou o nascituro <indicar o efeito específico se este for conhecido>
<indicar a via de exposição se existirem provas concludentes de que o perigo não decorre de nenhuma
outra via de exposição>.
RO Susceptibil de a dăuna fertilităţii sau fătului <indicaţi efectul specific, dacă este
cunoscut><indicaţi calea de expunere, dacă există probe concludente că nicio altă cale de expunere nu
provoacă acest pericol>.
SL Sum škodljivosti za plodnost ali nerojenega otroka <navesti posebni učinek, če je znan>
<navesti način izpostavljenosti, če je prepričljivo dokazano, da noben drug način izpostavljenosti ne
povzroča takšne nevarnosti>.
SV Misstänks kunna skada fertiliteten eller det ofödda barnet <ange specifik effekt om denna är
känd> <ange exponeringsväg om det är definitivt bevisat att faran inte kan orsakas av några andra
exponeringsvägar>.
H362 Language 3.7 — Reproductive toxicity, Additional category, Effects on or via lactation
H370 Language 3.8 — Specific target organ toxicity — single exposure, Hazard Category 1
BG Причинява увреждане на органите < или да се посочат всички засегнати органи, ако са
известни> < да се посочи пътят на експозицията, ако е доказано убедително, че няма друг
път на експозиция, който води до същата опасност >.
ES Provoca daños en los órganos <o indíquense todos los órganos afectados, si se conocen>
<indíquese la vía de exposición si se ha demostrado concluyentemente que el peligro no se produce por
ninguna otra vía>.
CS Způsobuje poškození orgánů <nebo uvést všechny postižené orgány, jsou-li známy> <uveďte cestu
expozice, je-li přesvědčivě prokázáno, že ostatní cesty expozice nejsou nebezpečné>.
L 353/184 EN Official Journal of the European Union 31.12.2008
H370 Language 3.8 — Specific target organ toxicity — single exposure, Hazard Category 1
DA Forårsager organskader <eller angiv alle berørte organer, hvis de kendes> <angiv eksponeringsvej,
hvis det er endeligt påvist, at faren ikke kan frembringes ad nogen anden eksponeringsvej>.
DE Schädigt die Organe <oder alle betroffenen Organe nennen, sofern bekannt> <Expositionsweg
angeben, sofern schlüssig belegt ist, dass diese Gefahr bei keinem anderen Expositionsweg besteht>.
ET Kahjustab elundeid <või märkida kõik mõjutatud elundid, kui need on teada> <märkida
kokkupuuteviis, kui on veenvalt tõestatud, et muud kokkupuuteviisid ei ole ohtlikud>.
EL Προκαλεί βλάβες στα όργανα <ή αναφέρονται όλα τα όργανα που βλάπτονται, εάν είναι
γνωστά> < αναφέρεται η οδός έκθεσης αν έχει αποδειχθεί αδιαμφισβήτητα ότι δεν υπάρχει
κίνδυνος από τις άλλες οδούς έκθεσης >.
EN Causes damage to organs <or state all organs affected, if known> <state route of exposure if it is
conclusively proven that no other routes of exposure cause the hazard>.
FR Risque avéré d'effets graves pour les organes <ou indiquer tous les organes affectés, s'ils sont
connus> <indiquer la voie d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition
ne conduit au même danger>.
GA Déanann sé damáiste d'orgáin <nó tabhair na horgáin go léir a bhuailtear, más eol> <tabhair an
bealach nochta má tá sé cruthaithe go cinntitheach nach bealach nochta ar bith eile is cúis leis an
nguais>.
IT Provoca danni agli organi <o indicare tutti gli organi interessati, se noti> <indicare la via di
esposizione se è accertato che nessun'altra via di esposizione comporta il medesimo pericolo>.
LV Rada orgānu bojājumus <vai norādīt visus skartos orgānus, ja tie ir zināmi> <norādīt iedarbības
ceļu, ja ir nepārprotami pierādīts, ka citi iedarbības ceļi nerada bīstamību>.
LT Kenkia organams <arba nurodyti visus veikiamus organus, jeigu žinomi> <nurodyti veikimo būdą,
jeigu įtikinamai nustatyta, kad kiti veikimo būdai nepavojingi>.
HU Károsítja a szerveket < vagy meg kell adni az összes érintett szervet, ha ismertek > < meg kell adni
az expozíciós útvonalat, ha meggyőzően bizonyított, hogy más expozíciós útvonal nem okozza a
veszélyt >.
MT Jagħmel ħsara lill-organi <jew semmi l-organi kollha affettwati, jekk ikunu magħrufa> <semmi
l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li l-ebda mod ta' espożizzjoni ieħor ma
jikkawża l-periklu>.
NL Veroorzaakt schade aan organen <of alle betrokken organen vermelden indien bekend>
<blootstellingsroute vermelden indien afdoende bewezen is dat het gevaar bij andere
blootstellingsroutes niet aanwezig is>.
PL Powoduje uszkodzenie narządów <podać szczególny skutek, jeśli jest znany> <podać drogę
narażenia, jeżeli udowodniono, że inne drogi narażenia nie stwarzają zagrożenia>.
PT Afecta os órgãos <ou indicar todos os órgãos afectados, se forem conhecidos> <indicar a via de
exposição se existirem provas concludentes de que o perigo não decorre de nenhuma outra via de
exposição>.
RO Provoacă leziuni ale organelor <sau indicaţi toate organele afectate, dacă sunt cunoscute>
<indicaţi calea de expunere, dacă există probe concludente că nicio altă cale de expunere nu provoacă
acest pericol>.
SK Spôsobuje poškodenie orgánov <alebo uveďte všetky zasiahnuté orgány, ak sú známe> <uveďte
spôsob expozície, ak sa presvedčivo preukáže, že iné spôsoby expozície nevyvolávajú nebezpečenstvo>.
SL Škoduje organom <ali navesti vse organe, na katere vpliva, če je znano> <navesti način
izpostavljenosti, če je prepričljivo dokazano, da noben drug način izpostavljenosti ne povzroča takšne
nevarnosti>.
FI Vahingoittaa elimiä <tai mainitaan kaikki tiedetyt kohde-elimet> <mainitaan altistumisreitti, jos
on kiistatta osoitettu, että vaara ei voi aiheutua muiden altistumisreittien kautta>.
SV Orsakar organskador <eller ange vilka organ som påverkas om detta är känt> <ange
exponeringsväg om det är definitivt bevisat att faran inte kan orsakas av några andra
exponeringsvägar>.
H371 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 2
BG Може да причини увреждане на органите < или да се посочат всички засегнати органи, ако
са известни> < да се посочи пътят на експозицията, ако е доказано убедително, че няма
друг път на експозиция, който води до същата опасност >.
31.12.2008 EN Official Journal of the European Union L 353/185
H371 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 2
ES Puede provocar daños en los órganos <o indíquense todos los órganos afectados, si se conocen>
<indíquese la vía de exposición si se ha demostrado concluyentemente que el peligro no se produce por
ninguna otra vía>.
CS Může způsobit poškození orgánů <nebo uvést všechny postižené orgány, jsou-li známy> <uveďte
cestu expozice, je-li přesvědčivě prokázáno, že ostatní cesty expozice nejsou nebezpečné>.
DA Kan forårsage organskader <eller angiv alle berørte organer, hvis de kendes> <angiv
eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan frembringes ad nogen anden
eksponeringsvej>.
DE Kann die Organe schädigen <oder alle betroffenen Organe nennen, sofern bekann>
<Expositionsweg angeben, sofern schlüssig belegt ist, dass diese Gefahr bei keinem anderen
Expositionsweg besteht>.
ET Võib kahjustada elundeid <või märkida kõik mõjutatud elundid, kui need on teada> <märkida
kokkupuuteviis, kui on veenvalt tõestatud, et muud kokkupuuteviisid ei ole ohtlikud>.
EL Μπορεί να προκαλέσει βλάβες στα όργανα <ή αναφέρονται όλα τα όργανα που βλάπτονται, εάν
είναι γνωστά> <αναφέρεται η οδός έκθεσης αν έχει αποδειχθεί αδιαμφισβήτητα ότι δεν
υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης>.
EN May cause damage to organs <or state all organs affected, if known> <state route of exposure if it
is conclusively proven that no other routes of exposure cause the hazard>.
FR Risque présumé d'effets graves pour les organes <ou indiquer tous les organes affectés, s'ils sont
connus> <indiquer la voie d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition
ne conduit au même danger>.
GA D'fhéadfadh damáiste a dhéanamh d'orgáin <nó tabhair na horgáin go léir a bhuailtear, más
eol> <tabhair an bealach nochta má tá sé cruthaithe go cinntitheach nach bealach nochta ar bith eile
is cúis leis an nguais>.
IT Può provocare danni agli organi <o indicare tutti gli organi interessati, se noti> <indicare la via di
esposizione se è accertato che nessun'altra via di esposizione comporta il medesimo pericolo>.
LV Var izraisīt orgānu bojājumus <vai norādīt visus skartos orgānus, ja tie ir zināmi> <norādīt
iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi iedarbības ceļi nerada bīstamību>.
LT Gali pakenkti organams <arba nurodyti visus veikiamus organus, jeigu žinomi> <nurodyti veikimo
būdą, jeigu įtikinamai nustatyta, kad kiti veikimo būdai nepavojingi>.
HU Károsíthatja a szerveket < vagy meg kell adni az összes érintett szervet, ha ismertek > < meg kell
adni az expozíciós útvonalat, ha meggyőzően bizonyított, hogy más expozíciós útvonal nem okozza a
veszélyt >.
MT Jista’ jikkawża ħsara lill-organi <jew semmi l-organi kollha affettwati, jekk ikunu magħrufa>
<semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li l-ebda mod ta'’ espożizzjoni ieħor
ma jikkawża l-periklu>.
NL Kan schade aan organen <of alle betrokken organen vermelden indien bekend> veroorzaken
<blootstellingsroute vermelden indien afdoende bewezen is dat het gevaar bij andere
blootstellingsroutes niet aanwezig is>.
PL Może powodować uszkodzenie narządów <podać wszystkie znane narządy, których to dotyczy>
<podać drogę narażenia, jeżeli udowodniono, że inne drogi narażenia nie stwarzają zagrożenia>.
PT Pode afectar os órgãos <ou indicar todos os órgãos afectados, se forem conhecidos> <indicar a via
de exposição se existirem provas concludentes de que o perigo não decorre de nenhuma outra via de
exposição>.
RO Poate provoca leziuni ale organelor <sau indicaţi toate organele afectate, dacă sunt cunoscute>
<indicaţi calea de expunere, dacă există probe concludente că nicio altă cale de expunere nu provoacă
acest pericol>.
SK Môže spôsobiť poškodenie orgánov <alebo uveďte všetky zasiahnuté orgány, ak sú známe>
<uveďte spôsob expozície, ak sa presvedčivo preukáže, že iné spôsoby expozície nevyvolávajú
nebezpečenstvo>.
SL Lahko škoduje organom <ali navesti vse organe, na katere vpliva, če je znano> <navesti način
izpostavljenosti, če je prepričljivo dokazano, da noben drug način izpostavljenosti ne povzroča takšne
nevarnosti>.
H371 Language 3.8 — Specific target organ toxicity — Single exposure, Hazard Category 2
SV Kan orsaka organskador <eller ange vilka organ som påverkas om detta är känt> <ange
exponeringsväg om det är definitivt bevisat att faran inte kan orsakas av några andra
exponeringsvägar>.
H372 Language 3.9 — Specific target organ toxicity — Repeated exposure, Hazard Category 1
BG Причинява увреждане на органите < или да се посочат всички засегнати органи, ако са
известни > посредством продължителна или повтаряща се експозиция < да се посочи
пътят на експозицията, ако е доказано убедително, че няма друг път на експозиция, който
води до същата опасност >.
ES Provoca daños en los órganos <indíquense todos los órganos afectados, si se conocen> tras
exposiciones prolongadas o repetidas <indíquese la vía de exposición si se ha demostrado
concluyentemente que el peligro no se produce por ninguna otra vía>.
CS Způsobuje poškození orgánů <nebo uvést všechny postižené orgány, jsou-li známy> při
prodloužené nebo opakované expozici <uveďte cestu expozice, je-li přesvědčivě prokázáno, že
ostatní cesty expozice nejsou nebezpečné>.
DA Forårsager organskader <eller angiv alle berørte organer, hvis de kendes> ved længerevarende
eller gentagen eksponering <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan
frembringes ad nogen anden eksponeringsvej>.
DE Schädigt die Organe <alle betroffenen Organe nennen> bei längerer oder wiederholter
Exposition <Expositionsweg angeben, wenn schlüssig belegt ist, dass diese Gefahr bei keinem
anderen Expositionsweg besteht>.
ET Kahjustab elundeid <või märkida kõik mõjutatud elundid, kui need on teada> pikaajalisel või
korduval kokkupuutel <märkida kokkupuuteviis, kui on veenvalt tõestatud, et muud
kokkupuuteviisid ei ole ohtlikud>.
EL Προκαλεί βλάβες στα όργανα <ή αναφέρονται όλα τα όργανα που βλάπτονται, εάν είναι
γνωστά> ύστερα από παρατεταμένη ή επανειλημμένη έκθεση < αναφέρεται η οδός έκθεσης αν
έχει αποδειχθεί αδιαμφισβήτητα ότι δεν υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης >.
EN Causes damage to organs <or state all organs affected, if known> through prolonged or
repeated exposure <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
FR Risque avéré d'effets graves pour les organes <indiquer tous les organes affectés, s'ils sont
connus> à la suite d'expositions répétées ou d'une exposition prolongée <indiquer la voie
d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même
danger>.
GA Déanann damáiste d'orgáin <nó tabhair na horgáin go léir a bhuailtear, más eol> trí nochtadh
fada nó ilnochtadh <tabhair an bealach nochta má tá sé cruthaithe go cinntitheach nach bealach
nochta ar bith eile is cúis leis an nguais>.
IT Provoca danni agli organi <o indicare tutti gli organi interessati, se noti> in caso di esposizione
prolungata o ripetuta <indicare la via di esposizione se è accertato che nessun'altra via di
esposizione comporta il medesimo pericolo>.
LV Izraisa orgānu bojājumus <vai norādīt visus skartos orgānus, ja tie ir zināmi> ilgstošas vai
atkārtotas iedarbības rezultātā <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi
iedarbības ceļi nerada bīstamību>.
LT Kenkia organams <arba nurodyti visus veikiamus organus, jeigu žinoma>, jeigu medžiaga veikia
ilgai arba kartotinai <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo būdai
nepavojingi>.
HU Ismétlődő vagy hosszabb expozíció esetén < meg kell adni az expozíciós útvonalat, ha
meggyőzően bizonyított, hogy más expozíciós útvonal nem okozza a veszélyt > károsítja a szerveket
< vagy meg kell adni az összes érintett szervet, ha ismertek >.
MT Jikkawża ħsara lill-organi <jew semmi l-organi kollha affettwati, jekk ikunu magħrufa> minħabba
espożizzjoni fit-tul jew ripetuta <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod konklużiv li l-
ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu>.
NL Veroorzaakt schade aan organen <of alle betrokken organen vermelden indien bekend> bij
langdurige of herhaalde blootstelling <blootstellingsroute vermelden indien afdoende bewezen is
dat het gevaar bij andere blootstellingsroutes niet aanwezig is>.
PL Powoduje uszkodzenie narządów <podać wszystkie znane narządy, których to dotyczy > poprzez
długotrwałe lub powtarzane narażenie <podać drogę narażenia, jeżeli udowodniono, że inne
drogi narażenia nie stwarzają zagrożenia>.
31.12.2008 EN Official Journal of the European Union L 353/187
H372 Language 3.9 — Specific target organ toxicity — Repeated exposure, Hazard Category 1
PT Afecta os órgãos <ou indicar todos os órgãos afectados, se forem conhecidos> após exposição
prolongada ou repetida <indicar a via de exposição se existirem provas concludentes de que o
perigo não decorre de nenhuma outra via de exposição>.
RO Provoacă leziuni ale organelor <sau indicaţi toate organele afectate, dacă sunt cunoscute> în caz
de expunere prelungită sau repetată <indicaţi calea de expunere, dacă există probe concludente că
nicio altă cale de expunere nu provoacă acest pericol>.
SK Spôsobuje poškodenie orgánov <alebo uveďte všetky zasiahnuté orgány, ak sú známe>pri dlhšej
alebo opakovanej expozícii <uveďte spôsob expozície, ak sa presvedčivo preukáže, že iné spôsoby
expozície nevyvolávajú nebezpečenstvo>.
SL Škoduje organom <ali navesti vse organe, na katere vpliva, če je znano> pri dolgotrajni ali
ponavljajoči se izpostavljenosti <navesti način izpostavljenosti, če je prepričljivo dokazano, da
noben drug način izpostavljenosti ne povzroča takšne nevarnosti>.
FI Vahingoittaa elimiä <tai mainitaan kaikki tiedetyt kohde-elimet> pitkäaikaisessa tai toistuvassa
altistumisessa <mainitaan altistumisreitti, jos on kiistatta osoitettu, että vaara ei voi aiheutua
muiden altistumisreittien kautta>.
SV Orsakar organskador <eller ange vilka organ som påverkas om detta är känt> genom lång eller
upprepad exponering <ange exponeringsväg om det är definitivt bevisat att faran inte kan orsakas
av några andra exponeringsvägar>.
H373 Language 3.9 — Specific target organ toxicity — Repeated exposure, Hazard Category 2
BG Може да причини увреждане на органите < или да се посочат всички засегнати органи, ако
са известни > при продължителна или повтаряща се експозиция < да се посочи пътят на
експозицията, ако е доказано убедително, че няма друг път на експозиция, който води до
същата опасност >.
ES Puede provocar daños en los órganos <indíquense todos los órganos afectados, si se conocen>
tras exposiciones prolongadas o repetidas <indíquese la vía de exposición si se ha demostrado
concluyentemente que el peligro no se produce por ninguna otra vía>.
CS Může způsobit poškození orgánů <nebo uvést všechny postižené orgány, jsou-li známy> při
prodloužené nebo opakované expozici <uveďte cestu expozice, je-li přesvědčivě prokázáno, že
ostatní cesty expozice nejsou nebezpečné>.
DA Kan forårsage organskader <eller angiv alle berørte organer, hvis de kendes> ved længerevarende
eller gentagen eksponering <angiv eksponeringsvej, hvis det er endeligt påvist, at faren ikke kan
frembringes ad nogen anden eksponeringsvej>.
DE Kann die Organe schädigen <alle betroffenen Organe nennen, sofern bekannt> bei längerer oder
wiederholter Exposition <Expositionsweg angeben, wenn schlüssig belegt ist, dass diese Gefahr bei
keinem anderen Expositionsweg besteht>.
ET Võib kahjustada elundeid <või märkida kõik mõjutatud elundid, kui need on teada> pikaajalisel
või korduval kokkupuutel <märkida kokkupuuteviis, kui on veenvalt tõestatud, et muud
kokkupuuteviisid ei ole ohtlikud>.
EL Μπορεί να προκαλέσει βλάβες στα όργανα <ή αναφέρονται όλα τα όργανα που βλάπτονται, εάν
είναι γνωστά> ύστερα από παρατεταμένη ή επανειλημμένη έκθεση <αναφέρεται η οδός έκθεσης
αν έχει αποδειχθεί αδιαμφισβήτητα ότι δεν υπάρχει κίνδυνος από τις άλλες οδούς έκθεσης>.
EN May cause damage to organs <or state all organs affected, if known> through prolonged or
repeated exposure <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
FR Risque présumé d'effets graves pour les organes <ou indiquer tous les organes affectés, s'ils sont
connus> à la suite d'expositions répétées ou d'une exposition prolongée <indiquer la voie
d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même
danger>.
GA D'fhéadfadh sé damáiste a dhéanamh d'orgáin <nó tabhair na horgáin go léir a bhuailtear, más
eol> trí nochtadh fada nó ilnochtadh <tabhair an bealach nochta má tá sé cruthaithe go
cinntitheach nach bealach nochta ar bith eile is cúis leis an nguais>.
IT Può provocare danni agli organi <o indicare tutti gli organi interessati, se noti> in caso di
esposizione prolungata o ripetuta <indicare la via di esposizione se è accertato che nessun'altra via
di esposizione comporta il medesimo pericolo>.
LV Var izraisīt orgānu bojājumus <vai norādīt visus skartos orgānus, ja tie ir zināmi> ilgstošas vai
atkārtotas iedarbības rezultātā <norādīt iedarbības ceļu, ja ir nepārprotami pierādīts, ka citi
iedarbības ceļi nerada bīstamību>.
L 353/188 EN Official Journal of the European Union 31.12.2008
H373 Language 3.9 — Specific target organ toxicity — Repeated exposure, Hazard Category 2
LT Gali pakenkti organams <arba nurodyti visus veikiamus organus, jeigu žinomi>, jeigu medžiaga
veikia ilgai arba kartotinai <nurodyti veikimo būdą, jeigu įtikinamai nustatyta, kad kiti veikimo
būdai nepavojingi>.
HU Ismétlődő vagy hosszabb expozíció esetén < meg kell adni az expozíciós útvonalat, ha
meggyőzően bizonyított, hogy más expozíciós útvonal nem okozza a veszélyt > károsíthatja a
szerveket > vagy meg kell adni az összes érintett szervet, ha ismertek >.
MT Jista’ jikkawża ħsara lill-organi <jew semmi l-organi kollha affettwati, jekk ikunu magħrufa>
minħabba espożizzjoni fit-tul jew ripetuta <semmi l-mod ta' espożizzjoni jekk ikun pruvat b'mod
konklużiv li l-ebda mod ta' espożizzjoni ieħor ma jikkawża l-periklu>.
NL Kan schade aan organen <of alle betrokken organen vermelden indien bekend> veroorzaken bij
langdurige of herhaalde blootstelling <blootstellingsroute vermelden indien afdoende bewezen is
dat het gevaar bij andere blootstellingsroutes niet aanwezig is>.
PL Może powodować uszkodzenie narządów <podać wszystkie znane narządy, których to dotyczy >
poprzez długotrwałe lub narażenie powtarzane <podać drogę narażenia, jeśli udowodniono, że
inne drogi narażenia nie stwarzają zagrożenia>.
PT Pode afectar os órgãos <ou indicar todos os órgãos afectados, se forem conhecidos> após
exposição prolongada ou repetida <indicar a via de exposição se existirem provas concludentes de
que o perigo não decorre de nenhuma outra via de exposição>.
RO Poate provoca leziuni ale organelor <sau indicaţi toate organele afectate, dacă sunt cunoscute> în
caz de expunere prelungită sau repetată <indicaţi calea de expunere, dacă există probe
concludente că nicio altă cale de expunere nu provoacă acest pericol>.
SK Môže spôsobiť poškodenie orgánov <alebo uveďte všetky zasiahnuté orgány, ak sú známe>pri
dlhšej alebo opakovanej expozícii <uveďte spôsob expozície, ak sa presvedčivo preukáže, že iné
spôsoby expozície nevyvolávajú nebezpečenstvo>.
SL Lahko škoduje organom <ali navesti vse organe, na katere vpliva, če je znano> pri dolgotrajni ali
ponavljajoči se izpostavljenosti <navesti način izpostavljenosti, če je prepričljivo dokazano, da
noben drug način izpostavljenosti ne povzroča takšne nevarnosti>.
FI Saattaa vahingoittaa elimiä <tai mainitaan kaikki tiedetyt kohde-elimet> pitkäaikaisessa tai
toistuvassa altistumisessa <mainitaan altistumisreitti, jos on kiistatta osoitettu, että vaara ei voi
aiheutua muiden altistumisreittien kautta>
SV Kan orsaka organskador <eller ange vilka organ som påverkas om detta är känt> genom lång
eller upprepad exponering <ange exponeringsväg om det är definitivt bevisat att faran inte kan
orsakas av några andra exponeringsvägar>.
Table 1.3
H410 Language 4.1 — Hazardous to the aquatic environment — Chronic Hazard, Category 1
ES Muy tóxico para los organismos acuáticos, con efectos nocivos duraderos.
FR Très toxique pour les organismes aquatiques, entraîne des effets néfastes à long terme.
IT Molto tossico per gli organismi acquatici con effetti di lunga durata.
NL Zeer giftig voor in het water levende organismen, met langdurige gevolgen.
H411 Language 4.1 — Hazardous to the aquatic environment — Chronic Hazard, Category 2
FR Toxique pour les organismes aquatiques, entraîne des effets néfastes à long terme.
H412 Language 4.1 — Hazardous to the aquatic environment — Chronic Hazard, Category 3
FR Nocif pour les organismes aquatiques, entraîne des effets néfastes à long terme.
H412 Language 4.1 — Hazardous to the aquatic environment — Chronic Hazard, Category 3
H413 Language 4.1 — Hazardous to the aquatic environment — Chronic Hazard, Category 4
ES Puede ser nocivo para los organismos acuáticos, con efectos nocivos duraderos.
IT Può essere nocivo per gli organismi acquatici con effetti di lunga durata.
NL Kan langdurige schadelijke gevolgen voor in het water levende organismen hebben.
Table 2.1
Physical properties
ET Plahvatusohtlik kuivana.
FI Räjähtävää kuivana.
CS Při používání může vytvářet hořlavé nebo výbušné směsi par se vzduchem.
MT Meta jintuża jista' jifforma taħlitiet esplussivi jew li jaqbdu jekk jitħallat ma' l-arja.
Table 2.2
Health properties
LV Atkārtota iedarbība var radīt sausu ādu vai izraisīt tās sprēgāšanu.
ET Söövitav hingamisteedele.
LV Kodīgs elpceļiem.
FI Hengityselimiä syövyttävää.
SV Frätande på luftvägarna.
Table 2.3
Environmental properties
ET Ohtlik osoonikihile.
HU Veszélyes az ózonrétegre.
FI Vaarallista otsonikerrokselle.
EUH 201/
Language
201A
201 BG Съдържа олово. Да не се използва върху повърхност, която евентуално може да се дъвче или
201A смуче от деца.
Внимание! Съдържа олово.
31.12.2008 EN Official Journal of the European Union L 353/201
EUH 201/
Language
201A
201 ES Contiene plomo. No utilizar en objetos que los niños puedan masticar o chupar.
201A ¡Atención! Contiene plomo.
201 CS Obsahuje olovo. Nemá se používat na povrchy, které mohou okusovat nebo olizovat děti.
201A Pozor! Obsahuje olovo.
201 DA Indeholder bly. Må ikke anvendes på genstande, som børn vil kunne tygge eller sutte på.
201A Advarsel! Indeholder bly.
201 DE Enthält Blei. Nicht für den Anstrich von Gegenständen verwenden, die von Kindern gekaut
201A oder gelutscht werden könnten.
Achtung! Enthält Blei.
201 ET Sisaldab pliid. Mitte kasutada pindadel, mida lapsed võivad närida või imeda.
201A Ettevaatust! Sisaldab pliid.
201 EN Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
201A Warning! Contains lead.
201 FR Contient du plomb. Ne pas utiliser sur les objets susceptibles d'être mâchés ou sucés par des
201A enfants.
Attention! Contient du plomb.
201 GA Luaidhe ann. Níor chóir a úsáid ar dhromchlaí a d'fhéadfadh a bheith á gcogaint nó á sú ag
201A leanaí.
Rabhadh! Luaidhe ann.
201 IT Contiene piombo. Non utilizzare su oggetti che possono essere masticati o succhiati dai
201A bambini.
Attenzione! Contiene piombo.
201 LV Satur svinu. Nedrīkst lietot uz virsmām, kuras var nonākt bērnam mutē.
201A Brīdinājums! Satur svinu.
201 LT Sudėtyje yra švino. Nenaudoti paviršiams, kurie gali būti vaikų kramtomi arba čiulpiami.
201A Atsargiai! Sudėtyje yra švino.
201 HU Ólmot tartalmaz. Tilos olyan felületeken használni, amelyeket gyermekek szájukba
201A vehetnek.
Figyelem! Ólmot tartalmaz.
201 MT Fih iċ-ċomb. M'għandux jintuża' fuq uċuh li x'aktarx jomogħduhom jew jerdgħuhom it-tfal.
201A Twissija! Fih iċ-ċomb.
201 NL Bevat lood. Mag niet worden gebruikt voor voorwerpen waarin kinderen kunnen bijten of
201A waaraan kinderen kunnen zuigen.
Let op! Bevat lood.
201 PL Zawiera ołów. Nie należy stosować na powierzchniach, które mogą być gryzione lub ssane
201A przez dzieci.
Uwaga! Zawiera ołów.
201 PT Contém chumbo. Não utilizar em superfícies que possam ser mordidas ou chupadas por
201A crianças.
Atenção! Contém chumbo.
201 RO Conţine plumb. A nu se utiliza pe obiecte care pot fi mestecate sau supte de copii.
201A Atenţie! Conţine plumb.
201 SK Obsahuje olovo. Nepoužívajte na povrchy, ktoré by mohli žuť alebo oblizovať deti.
201A Pozor! Obsahuje olovo.
201 SL Vsebuje svinec. Ne sme se nanašati na površine, ki bi jih lahko žvečili ali sesali otroci.
201A Pozor! Vsebuje svinec.
L 353/202 EN Official Journal of the European Union 31.12.2008
EUH 201/
Language
201A
201 FI Sisältää lyijyä. Ei saa käyttää pintoihin, joita lapset voivat pureskella tai imeä.
201A Varoitus! Sisältää lyijyä.
201 SV Innehåller bly. Bör inte användas på ytor där barn kan komma åt att tugga eller suga.
201A Varning! Innehåller bly.
ES Cianoacrilato. Peligro. Se adhiere a la piel y a los ojos en pocos segundos. Mantener fuera
del alcance de los niños.
CS Kyanoakrylát. Nebezpečí. Okamžitě slepuje kůži a oči. Uchovávejte mimo dosah dětí.
DE Cyanacrylat. Gefahr. Klebt innerhalb von Sekunden Haut und Augenlider zusammen. Darf
nicht in die Hände von Kindern gelangen.
ET Tsüanoakrülaat. Ohtlik. Liimib naha ja silmad hetkega. Hoida lastele kättesaamatus kohas.
EL Κυανοακρυλική ένωση. Κίνδυνος. Κολλάει στην επιδερμίδα και στα μάτια μέσα σε λίγα
δευτερόλεπτα. Να φυλάσσεται μακριά από παιδιά.
EN Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
FR Cyanoacrylate. Danger. Colle à la peau et aux yeux en quelques secondes. À conserver hors
de portée des enfants.
IT Cianoacrilato. Pericolo. Incolla la pelle e gli occhi in pochi secondi. Tenere fuori dalla
portata dei bambini.
MT Cyanoacrylate. Periklu. Iwaħħal il-ġilda u l-għajnejn fi ftit sekondi. Żomm ‘il bogħod minn
fejn jistgħu jilħquh it-tfal.
NL Cyanoacrylaat. Gevaarlijk. Kleeft binnen enkele seconden aan huid en oogleden. Buiten het
bereik van kinderen houden.
PT Cianoacrilato. Perigo. Cola à pele e aos olhos em poucos segundos. Manter fora do alcance
das crianças.
SL Cianoakrilat. Nevarno. Kožo in oči zlepi v nekaj sekundah. Hraniti zunaj dosega otrok.
SV Cyanoakrylat. Fara. Fäster snabbt på hud och ögon. Förvaras oåtkomligt för barn.
31.12.2008 EN Official Journal of the European Union L 353/203
BG Внимание! Да не се използва заедно с други продукти. Може да отдели опасни газове (хлор).
31.12.2008 EN Official Journal of the European Union L 353/205
ES ¡Atención! No utilizar junto con otros productos. Puede desprender gases peligrosos (cloro).
CS Pozor! Nepoužívejte společně s jinými výrobky. Může uvolňovat nebezpečné plyny (chlor).
DA Advarsel! Må ikke anvendes i forbindelse med andre produkter. Farlige luftarter (chlor) kan
frigøres.
DE Achtung! Nicht zusammen mit anderen Produkten verwenden, da gefährliche Gase (Chlor)
freigesetzt werden können.
ET Ettevaatust! Mitte kasutada koos teiste toodetega. Segust võib eralduda ohtlikke gaase
(kloori).
EN Warning! Do not use together with other products. May release dangerous gases (chlorine).
FR Attention! Ne pas utiliser en combinaison avec d'autres produits. Peut libérer des gaz
dangereux (chlore).
IT Attenzione! Non utilizzare in combinazione con altri prodotti. Possono liberarsi gas
pericolosi (cloro).
LV Brīdinājums! Nelietot kopā ar citiem produktiem. Var izdalīt bīstamas gāzes (hloru).
LT Atsargiai! Nenaudoti kartu su kitais produktais. Gali išskirti pavojingas dujas (chlorą).
HU Figyelem! Tilos más termékekkel együtt használni. Veszélyes gázok (klór) szabadulhatnak
fel.
MT Twissija! Tużahx flimkien ma’ prodotti oħra. Jista’ jerħi gassijiet perikolużi (kloru).
NL Let op! Niet in combinatie met andere producten gebruiken. Er kunnen gevaarlijke gassen
(chloor) vrijkomen.
PL Uwaga! Nie stosować razem z innymi produktami. Może wydzielać niebezpieczne gazy
(chlor).
PT Atenção! Não utilizar juntamente com outros produtos. Podem libertar-se gases perigosos
(cloro).
RO Atenţie! A nu se folosi împreună cu alte produse. Poate elibera gaze periculoase (clor).
SK Pozor! Nepoužívajte spolu s inými výrobkami. Môžu uvoľňovať nebezpečné plyny (chlór).
SL Pozor! Ne uporabljajte skupaj z drugimi izdelki. Lahko se sproščajo nevarni plini (klor).
FI Varoitus! Älä käytä yhdessä muiden tuotteiden kanssa. Tuotteesta voi vapautua vaarallista
kaasua (klooria).
SV Varning! Får ej användas tillsammans med andra produkter. Kan avge farliga gaser (klor).
BG Внимание! Съдържа кадмий. При употреба се образуват опасни пари. Вижте информацията,
предоставена от производителя. Спазвайте инструкциите за безопасност.
CS Pozor! Obsahuje kadmium. Při používání vznikají nebezpečné výpary. Viz informace
dodané výrobcem. Dodržujte bezpečnostní pokyny.
DE Achtung! Enthält Cadmium. Bei der Verwendung entstehen gefährliche Dämpfe. Hinweise
des Herstellers beachten. Sicherheitsanweisungen einhalten.
L 353/206 EN Official Journal of the European Union 31.12.2008
EN Warning! Contains cadmium. Dangerous fumes are formed during use. See information
supplied by the manufacturer. Comply with the safety instructions.
LV Brīdinājums! Satur kadmiju. Lietojot veidojas bīstami izgarojumi. Sk. ražotāja sniegto
informāciju. Ievērot drošības instrukcijas.
LT Atsargiai! Sudėtyje yra kadmio. Naudojant susidaro pavojingi garai. Žiūrėti gamintojo
pateiktą informaciją. Vykdyti saugos instrukcijas.
MT Twissija! Fih il-kadmju. Waqt li jintuża jiffurmaw dħaħen perikolużi. Ara l-informazzjoni
mogħtija mill-fabbrikant. Ħares l-istruzzjonijiet dwar is-sigurtà.
NL Let op! Bevat cadmium. Bij het gebruik ontwikkelen zich gevaarlijke dampen. Zie de
aanwijzingen van de fabrikant. Neem de veiligheidsvoorschriften in acht.
PL Uwaga! Zawiera kadm. Podczas stosowania wydziela niebezpieczne pary. Zapoznaj się z
informacją dostarczoną przez producenta. Przestrzegaj instrukcji bezpiecznego stosowania.
SK Pozor! Obsahuje kadmium. Pri používaní sa tvorí nebezpečný dym. Pozri informácie od
výrobcu. Dodržiavajte bezpečnostné pokyny.
SL Pozor! Vsebuje kadmij. Med uporabo nastajajo nevarni dimi. Preberite informacije
proizvajalca. Upoštevajte navodila za varno uporabo.
SV Varning! Innehåller kadmium. Farliga ångor bildas vid användning. Se information från
tillverkaren. Följ skyddsanvisningarna.
NL Bevat <naam van de sensibiliserende stof>. Kan een allergische reactie veroorzaken.
EUH 209/
Language
209A
ANNEX IV
In selecting the precautionary statements in accordance with Articles 22 and 28(3), suppliers may combine the
Precautionary Statements in the table below, having regard to clarity and comprehensibility of the precautionary advice.
Table 6.1
General precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Table 6.2
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P210 Keep away from heat/ Explosives (section 2.1) Divisions 1.1, Manufacturer/supplier
sparks/open flames/hot 1.2, 1.3, 1.4, to specify applicable
surfaces. — No smoking. 1.5 ignition source(s).
2, 3 … Manufacturer/sup-
plier to specify incom-
patible materials.
L 353/212 EN Official Journal of the European Union 31.12.2008
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
2, 3 … Manufacturer/sup-
plier to specify incom-
patible materials.
Organic peroxides (section 2.15) Types A, B, C,
D, E, F
P223 Keep away from any possi- Substances and mixtures which, in 1, 2
ble contact with water, contact with water, emit flam-
because of violent reaction mable gases (section 2.12)
and possible flash fire.
P230 Keep wetted with … Explosives (section 2.1) Divisions 1.1, … Manufacturer/sup-
1.2, 1.3, 1.5 plier to specify appro-
priate material.
— if drying out
increases explosion
hazard, except as
needed for manu-
facturing or oper-
ating processes
(e.g. nitrocellulose).
P234 Keep only in original con- Self-reactive substances and mix- Types A, B, C,
tainer. tures (section 2.8) D, E, F
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P240 Ground/bond container and Explosives (section 2.1) Divisions 1.1, — if the explosive is
receiving equipment. 1.2, 1.3, 1.4, electrostatically
1.5 sensitive.
P250 Do not subject to grinding/ Explosives (section 2.1) Divisions 1.1, … Manufacturer/sup-
shock/…/friction. 1.2, 1.3, 1.4, plier to specify applic-
1.5 able rough handling.
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P264 Wash … thoroughly after Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Manufacturer/supplier
handling. to specify parts of the
body to be washed
Acute toxicity — dermal (sec- 1, 2 after handling.
tion 3.1)
P270 Do not eat, drink or smoke Acute toxicity — oral (section 3.1) 1, 2, 3, 4
when using this product.
Acute toxicity — dermal (sec- 1, 2
tion 3.1)
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P273 Avoid release to the envir- Hazardous to the aquatic envi- 1 — if this is not the
onment. ronment — acute aquatic hazard intended use.
(section 4.1)
P280 Wear protective gloves/pro- Explosives (section 2.1) Divisions 1.1, Manufacturer/supplier
tective clothing/eye protec- 1.2, 1.3, 1.4, to specify type of
tion/face protection. 1.5 equipment.
— Specify face pro-
tection.
Prevention precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P282 Wear cold insulating gloves/ Gases under pressure (section 2.5) Refrigerated
face shield/eye protection. liquefied gas
Table 6.3
Code Response precautionary Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P315 Get immediate medical Gases under pressure (section 2.5) Refrigerated
advice/attention. liquefied gas
P320 Specific treatment is urgent Acute toxicity — inhalation (sec- 1, 2 … Reference to sup-
(see … on this label). tion 3.1) plemental first aid
instruction.
— if immediate
administration of
antidote is
required.
P321 Specific treatment (see … Acute toxicity — oral (section 3.1) 1, 2, 3 … Reference to sup-
on this label). plemental first aid
instruction.
— if immediate
administration of
antidote is
required.
31.12.2008 EN Official Journal of the European Union L 353/219
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P322 Specific measures (see … on Acute toxicity — dermal (sec- 1, 2 … Reference to sup-
this label). tion 3.1) plemental first aid
instruction.
— if immediate mea-
sures such as spe-
cific cleansing
agent is advised.
P331 Do NOT induce vomiting. Skin corrosion (section 3.2) 1A, 1B, 1C
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P336 Thaw frosted parts with Gases under pressure (section 2.5) Refrigerated
lukewarm water. Do not liquefied gas
rub affected area.
P338 Remove contact lenses, if Skin corrosion (section 3.2) 1A, 1B, 1C
present and easy to do.
Continue rinsing.
Serious eye damage/eye irritation 1
(section 3.3)
P351 Rinse cautiously with water Skin corrosion (section 3.2) 1A, 1B, 1C
for several minutes.
Serious eye damage/eye irritation 1
(section 3.3)
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P372 Explosion risk in case of Explosives (section 2.1) Unstable — except if explosives
fire. explosives and are 1.4S AMMU-
Divisions 1.1, NITION AND
1.2, 1.3, 1.4, COMPONENTS
1.5 THEREOF.
P374 Fight fire with normal pre- Explosives (section 2.1) Division 1.4 — if explosives are
cautions from a reasonable 1.4S AMMUNI-
distance. TION AND COM-
PONENTS
THEREOF.
L 353/222 EN Official Journal of the European Union 31.12.2008
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P375 Fight fire remotely due to Self-reactive substances and mix- Types A, B
the risk of explosion. tures (section 2.8)
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P305 + IF IN EYES: Rinse cautiously Skin corrosion (section 3.2) 1A, 1B, 1C
P351 + with water for several min-
P338 utes. Remove contact Serious eye damage/eye irritation 1
lenses, if present and easy to (section 3.3)
do. Continue rinsing.
Eye irritation (section 3.3) 2
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P370 + In case of fire: Use … for Flammable liquids (section 2.6) 1, 2, 3 … Manufacturer/sup-
P378 extinction. plier to specify appro-
priate media.
Flammable solids (section 2.7) 1, 2
— if water increases
risk.
Self-reactive substances and mix- Types A, B, C,
tures (section 2.8) D, E, F
Response precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Table 6.4
Storage precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Liquefied gas
Refrigerated
Liquefied gas
Dissolved gas
Storage precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Liquefied gas
Dissolved gas
P411 Store at temperatures not Self-reactive substances and mix- Types A, B, C, … Manufacturer/sup-
exceeding … oC/…oF. tures (section 2.8) D, E, F plier to specify tem-
perature
Organic peroxides (section 2.15) Types A, B, C,
D, E, F
P413 Store bulk masses greater Self-heating substances and mix- 1, 2 … Manufacturer/sup-
than … kg/…lbs at tem- tures (section 2.11) plier to specify mass
peratures not exceeding and temperature.
… oC/…oF.
P420 Store away from other ma- Self-reactive substances and mix- Types A, B, C,
terials. tures (section 2.8) D, E, F
Storage precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
P410 + Protect from sunlight. Store Gases under pressure (section 2.5) Compressed
P403 in a well-ventilated place. gas
Liquefied gas
Dissolved gas
P411 + Store at temperatures not Organic peroxides (section 2.15) Types A, B, C, … Manufacturer/sup-
P235 exceeding … oC/…oF. Keep D, E, F plier to specify tem-
cool. perature.
Table 6.5
Code Disposal precautionary Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
Disposal precautionary
Code Hazard class Hazard category Conditions for use
statements
(1) (2) (3) (4) (5)
The precautionary statements shall be taken from this part of Annex IV and selected in accordance with Part 1.
Table 1.1
P101 Language
CS Je-li nutná lékařská pomoc, mějte po ruce obal nebo štítek výrobku.
P101 Language
EL Εάν ζητήσετε ιατρική συμβουλή, να έχετε μαζί σας τον περιέκτη του προϊόντος ή την ετικέτα.
GA Más gá comhairle liachta, bíodh coimeádán nó lipéad an táirge ina aice láimhe.
MT Jekk ikun meħtieġ parir mediku, ara li jkollok il-kontenitur jew it-tikketta tal-prodott fil-
qrib.
NL Bij het inwinnen van medisch advies, de verpakking of het etiket ter beschikking houden.
PL W razie konieczności zasięgnięcia porady lekarza należy pokazać pojemnik lub etykietę.
RO Dacă este necesară consultarea medicului, țineți la îndemână recipientul sau eticheta
produsului.
SL Če je potreben zdravniški nasvet, mora biti na voljo posoda ali etiketa proizvoda.
P102 Language
LV Sargāt no bērniem.
P102 Language
P103 Language
Table 1.2
P201 Language
P201 Language
P202 Language
EN Do not handle until all safety precautions have been read and understood.
HU Ne használja addig, amíg az összes biztonsági óvintézkedést el nem olvasta és meg nem
értette.
L 353/232 EN Official Journal of the European Union 31.12.2008
P202 Language
PT Não manuseie o produto antes de ter lido e percebido todas as precauções de segurança.
P210 Language
P211 Language
FR Ne pas vaporiser sur une flamme nue ou sur toute autre source d’ignition.
RO Nu pulverizaţi deasupra unei flăcări deschise sau unei alte surse de aprindere.
P220 Language
P220 Language
P221 Language
ES Tomar todas las precauciones necesarias para no mezclar con materias combustibles…
FR Prendre toutes précautions pour éviter de mélanger avec des matières combustibles…
P222 Language
P223 Language
BG Да се избягва всякакъв възможен контакт с вода поради бурна реакция и възможно внезапно
запалване.
ES Mantener alejado de cualquier posible contacto con el agua, pues reacciona violentamente y
puede provocar una llamarada.
CS Chraňte před možným stykem s vodou kvůli prudké reakci a možnému náhlému vzplanutí.
DA Undgå enhver kontakt med vand, da dette kan fremkalde voldsom reaktion og risiko for
eksplosionsagtig brand.
DE Kontakt mit Wasser wegen heftiger Reaktion und möglichem Aufflammen unbedingt
verhindern.
ET Hoida igasuguse kokkupuute eest veega, vastasel juhul reageerib ägedalt ja võib põhjustada
hetkpõlemise.
EL Αποφύγετε κάθε πιθανή επαφή με το νερό, διότι αντιδρά βίαια και μπορεί να προκληθεί
ανάφλεξη.
EN Keep away from any possible contact with water, because of violent reaction and possible
flash fire.
FR Éviter tout contact avec l’eau, à cause du risque de réaction violente et d’inflammation
spontanée.
L 353/236 EN Official Journal of the European Union 31.12.2008
P223 Language
GA Ná ceadaigh teagmháil de shaghas ar bith le huisce, mar gheall ar imoibriú foirtil agus
splancthine a d’fhéadfadh a bheith ann.
LT Saugoti nuo bet kokio galimo kontakto su vandeniu, nes smarkiai reaguoja ir gali susidaryti
ugnies pliūpsnis.
MT Żomm ‘il bogħod minn kull kuntatt possibbli ma' l-ilma, minħabba li jirreaġġixxi bil-
qawwa u jista’ jkun hemm fjamma nar.
NL Contact met water vermijden in verband met een heftige reactie en een mogelijke
wolkbrand.
PT Não deixar entrar em contacto com a água: risco de reacção violenta e possibilidade de
formação de chama súbita.
RO A se evita orice contact cu apa, din cauza reacţiei violente şi a riscului de aprindere
spontană.
SL Hraniti ločeno od možnega stika z vodo zaradi burne reakcije in možnega bliskovitega
požara.
SV Undvik all kontakt med vatten eftersom det kan framkalla en våldsam reaktion och
explosionsartad brand.
P230 Language
BG Да се държи навлажнен с…
ET Niisutada …-ga.
EL Να διατηρείται υγρό με …
LV Vienmēr samitrināt ar …
MT Żommu mxarrab bi …
P230 Language
SK Uchovávajte zvlhčené …
SL Hraniti prepojeno z …
FI Säilytä kostutettuna …
P231 Language
ET Käidelda inertgaasis.
P232 Language
BG Да се пази от влага.
ES Proteger de la humedad.
P232 Language
FR Protéger de l’humidité.
GA Cosain ar thaise.
IT Proteggere dall’umidità.
LV Aizsargāt no mitruma.
HU Nedvességtől védendő.
MT Ipproteġi mill-umdità.
RO A se proteja de umiditate.
FI Suojaa kosteudelta.
P233 Language
P233 Language
P234 Language
FI Säilytä alkuperäispakkauksessa.
P235 Language
BG Да се държи на хладно.
CS Uchovávejte v chladu.
DA Opbevares køligt.
DE Kühl halten.
L 353/240 EN Official Journal of the European Union 31.12.2008
P235 Language
ET Hoida jahedas.
EL Να διατηρείται δροσερό.
EN Keep cool.
FR Tenir au frais.
GA Coimeád fionnuar é
LV Turēt vēsumā.
MT Żomm frisk.
NL Koel bewaren.
RO A se păstra la rece.
SK Uchovávajte v chlade.
SL Hraniti na hladnem.
FI Säilytä viileässä.
SV Förvaras svalt.
P240 Language
P240 Language
P241 Language
P242 Language
P242 Language
P243 Language
P243 Language
P244 Language
P250 Language
BG Да не се подлага на стържене/удар/…/триене
CS Nevystavujte obrušování/nárazům/…/tření.
DE Nicht schleifen/stoßen/…/reiben.
P250 Language
EL Να αποφεύγεται άλεση/κρούση/…/τριβή.
LV Nepakļaut drupināšanai/triecienam/…/berzei
LT Nešlifuoti/netrankyti/…/netrinti.
NL Malen/schokken/…/wrijving vermijden.
RO A nu supune la abraziuni/şocuri/…/frecare.
SK Nevystavujte brúseniu/nárazu/…/treniu.
SL Ne izpostavljati drgnjenju/udarcem/…/trenju.
FI Suojele rasitukselta/iskuilta/…/hankaukselta.
P251 Language
DA Beholder under tryk: Må ikke punkteres eller brændes, heller ikke efter brug.
DE Behälter steht unter Druck: Nicht durchstechen oder verbrennen, auch nicht nach der
Verwendung.
ET Mahuti on rõhu all: mitte purustada ega põletada isegi pärast kasutamist.
EL Περιέκτης υπό πίεση. Να μην τρυπηθεί ή καεί ακόμη και μετά τη χρήση.
HU Nyomás alatti edény: ne lyukassza ki vagy égesse el, még használat után sem.
PL Pojemnik pod ciśnieniem. Nie przekłuwać ani nie spalać, nawet po zużyciu.
PT Recipiente sob pressão. Não furar nem queimar, mesmo após utilização.
31.12.2008 EN Official Journal of the European Union L 353/245
P251 Language
SK Nádoba je pod tlakom: neprepichujte alebo nespaľujte ju, a to ani po spotrebovaní obsahu.
SV Tryckbehållare: Får inte punkteras eller brännas, gäller även tömd behållare.
P260 Language
BG Не вдишвайте прах/пушек/газ/дим/изпарения/аерозоли
CS Nevdechujte prach/dým/plyn/mlhu/páry/aerosoly.
GA Ná hanálaigh deannach/múch/gás/ceo/gala/sprae.
LV Neieelpot putekļus/tvaikus/gāzi/dūmus/izgarojumus/smidzinājumu.
LT Neįkvėpti dulkių/dūmų/dujų/rūko/garų/aerozolio.
RO Nu inspiraţi praful/fumul/gazul/ceața/vaporii/spray-ul.
SK Nevdychujte prach/dym/plyn/hmlu/pary/aerosóly.
SL Ne vdihavati prahu/dima/plina/meglice/hlapov/razpršila.
P261 Language
P261 Language
SL Ne vdihavati prahu/dima/plina/meglice/hlapov/razpršila.
P262 Language
DE Nicht in die Augen, auf die Haut oder auf die Kleidung gelangen lassen.
P262 Language
P263 Language
P264 Language
P264 Language
P270 Language
DA Der må ikke spises, drikkes eller ryges under brugen af dette produkt.
NL Niet eten, drinken of roken tijdens het gebruik van dit product.
P270 Language
P271 Language
P272 Language
P272 Language
IT Gli indumenti da lavoro contaminati non devono essere portati fuori dal luogo di lavoro.
P273 Language
P273 Language
P280 Language
DA Bær beskyttelseshandsker/beskyttelsestøj/øjenbeskyttelse/ansigtsbeskyttelse
DE Schutzhandschuhe/Schutzkleidung/Augenschutz/Gesichtsschutz tragen.
ET Kanda kaitsekindaid/kaitserõivastust/kaitseprille/kaitsemaski.
FI Käytä suojakäsineitä/suojavaatetusta/silmiensuojainta/kasvonsuojainta.
SV Använd skyddshandskar/skyddskläder/ögonskydd/ansiktsskydd.
P281 Language
P281 Language
P282 Language
ET Kanda külmakaitsekindaid/kaitsemaski/kaitseprille.
FR Porter des gants isolants contre le froid/un équipement de protection du visage/des yeux.
P282 Language
P283 Language
P284 Language
DA Anvend åndedrætsværn.
DE Atemschutz tragen.
P284 Language
LV Izmantot gāzmasku.
NL Adembescherming dragen.
FI Käytä hengityksensuojainta.
SV Använd andningsskydd.
P285 Language
P285 Language
P231 +
Language
P232
P235 +
Language
P410
P235 +
Language
P410
Table 1.3
P301 Language
BG ПРИ ПОГЛЪЩАНЕ:
ES EN CASO DE INGESTIÓN:
CS PŘI POŽITÍ:
DA I TILFÆLDE AF INDTAGELSE:
DE BEI VERSCHLUCKEN:
ET ALLANEELAMISE KORRAL:
EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΚΑΤΑΠΟΣΗΣ:
EN IF SWALLOWED:
FR EN CAS D’INGESTION:
GA MÁ SHLOGTAR:
IT IN CASO DI INGESTIONE:
LV NORĪŠANAS GADĪJUMĀ:
LT PRARIJUS:
HU LENYELÉS ESETÉN:
MT JEKK JINBELA’:
31.12.2008 EN Official Journal of the European Union L 353/257
P301 Language
NL NA INSLIKKEN:
PL W PRZYPADKU POŁKNIĘCIA:
PT EM CASO DE INGESTÃO:
RO ÎN CAZ DE ÎNGHIŢIRE:
SK PO POŽITÍ:
SL PRI ZAUŽITJU:
SV VID FÖRTÄRING:
P302 Language
EN IF ON SKIN:
LV SASKARĒ AR ĀDU:
HU HA BŐRRE KERÜL:
SV VID HUDKONTAKT:
P303 Language
P303 Language
P304 Language
BG ПРИ ВДИШВАНЕ:
ES EN CASO DE INHALACIÓN:
CS PŘI VDECHNUTÍ:
DA VED INDÅNDING:
DE BEI EINATMEN:
ET SISSEHINGAMISE KORRAL:
EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΙΣΠΝΟΗΣ:
EN IF INHALED:
FR EN CAS D’INHALATION:
GA MÁ IONANÁLAÍTEAR:
IT IN CASO DI INALAZIONE:
LV IEELPOJOT:
LT ĮKVĖPUS:
HU BELÉLEGZÉS ESETÉN:
NL NA INADEMING:
31.12.2008 EN Official Journal of the European Union L 353/259
P304 Language
PT EM CASO DE INALAÇÃO:
RO ÎN CAZ DE INHALARE:
SK PO VDÝCHNUTÍ:
SL PRI VDIHAVANJU:
SV VID INANDNING:
P305 Language
EN IF IN EYES:
LV IEKĻŪSTOT ACĪS:
LT PATEKUS Į AKIS:
SK PO ZASIAHNUTÍ OČÍ:
P306 Language
P306 Language
EN IF ON CLOTHING:
LV SASKARĒ AR APĢĒRBU:
HU HA RUHÁRA KERÜL:
NL NA MORSEN OP KLEDING:
P307 Language
BG ПРИ експозиция:
ES EN CASO DE exposición:
CS PŘI expozici:
DA VED eksponering:
DE BEI Exposition:
ET Kokkupuute korral:
EL ΣΕ ΠΕΡΙΠΤΩΣΗ έκθεσης:
EN IF exposed:
FR EN CAS d’exposition:
GA I gCÁS nochta:
IT IN CASO di esposizione:
LV JA saskaras:
LT Esant sąlyčiui:
HU Expozíció esetén:
MT JEKK espost:
NL NA blootstelling:
PL W PRZYPADKU narażenia:
31.12.2008 EN Official Journal of the European Union L 353/261
P307 Language
PT EM CASO DE exposição:
RO ÎN CAZ DE expunere:
SK PO expozícii:
SL PRI izpostavljenosti:
FI Altistumisen tapahduttua:
SV Om du exponerats:
P308 Language
EN IF exposed or concerned:
NL NA (mogelijke) blootstelling:
P309 Language
P309 Language
P310 Language
P310 Language
P311 Language
P312 Language
P312 Language
P313 Language
ES Consultar a un médico.
DA Søg lægehjælp.
EL Συμβουλευθείτε/Επισκεφθείτε γιατρό.
FR Consulter un médecin.
IT Consultare un medico.
LT Kreiptis į gydytoją.
MT Ikkonsulta tabib.
31.12.2008 EN Official Journal of the European Union L 353/265
P313 Language
PT Consulte um médico.
RO Consultaţi medicul.
FI Hakeudu lääkäriin.
SV Sök läkarhjälp.
P314 Language
P315 Language
P315 Language
P320 Language
P320 Language
P321 Language
P322 Language
P322 Language
P330 Language
BG Изплакнете устата.
ES Enjuagarse la boca.
CS Vypláchněte ústa.
DA Skyl munden.
DE Mund ausspülen.
ET Loputada suud.
EL Ξεπλύνετε το στόμα.
EN Rinse mouth.
FR Rincer la bouche.
GA Sruthlaítear an béal.
IT Sciacquare la bocca.
LV Izskalot muti.
LT Išskalauti burną.
MT Laħlaħ ħalqek.
NL De mond spoelen.
PL Wypłukać usta.
31.12.2008 EN Official Journal of the European Union L 353/269
P330 Language
PT Enxaguar a boca.
RO Clătiţi gura.
SK Vypláchnite ústa.
SL Izprati usta.
FI Huuhdo suu.
SV Skölj munnen.
P331 Language
BG НЕ предизвиквайте повръщане.
ES NO provocar el vómito.
CS NEVYVOLÁVEJTE zvracení.
GA NÁ spreagtar urlacan.
LV NEIZRAISĪT vemšanu.
LT NESKATINTI vėmimo.
HU TILOS hánytatni.
MT TIPPROVOKAX ir-remettar.
RO NU provocaţi voma.
SK Nevyvolávajte zvracanie.
SL NE izzvati bruhanja.
FI EI saa oksennuttaa.
P332 Language
DA Ved hudirritation:
DE Bei Hautreizung:
L 353/270 EN Official Journal of the European Union 31.12.2008
P332 Language
ET Nahaärrituse korral:
HU Bőrirritáció esetén:
NL Bij huidirritatie:
SV Vid hudirritation:
P333 Language
P333 Language
P334 Language
P335 Language
P335 Language
P336 Language
ES Descongelar las partes heladas con agua tibia. No frotar la zona afectada.
DA Forsigtig opvarmning af frostskadede legemsdele i lunkent vand. Gnid ikke det angrebne
område.
DE Vereiste Bereiche mit lauwarmem Wasser auftauen. Betroffenen Bereich nicht reiben.
ET Sulatada külmunud piirkonnad leige veega. Kannatada saanud piirkonda mitte hõõruda.
EL Ξεπαγώστε τα παγωμένα μέρη με χλιαρό νερό. Μην τρίβετε την περιοχή που πάγωσε.
FR Dégeler les parties gelées avec de l’eau tiède. Ne pas frotter les zones touchées.
IT Sgelare le parti congelate usando acqua tiepida. Non sfregare la parte interessata.
HU A fagyott részeket langyos vízzel fel kell melegíteni. Tilos az érintett terület dörzsölése.
NL Bevroren lichaamsdelen met lauw water ontdooien. Niet wrijven op de betrokken plaatsen.
PT Derreter as zonas congeladas com água morna. Não friccionar a zona afectada.
31.12.2008 EN Official Journal of the European Union L 353/273
P336 Language
SV Värm det köldskadade området med ljummet vatten. Gnid inte det skadade området.
P337 Language
P338 Language
BG Свалете контактните лещи, ако има такива и доколкото това е възможно. Продължете с
изплакването.
CS Vyjměte kontaktní čočky, jsou-li nasazeny a pokud je lze vyjmout snadno. Pokračujte ve
vyplachování.
DA Fjern eventuelle kontaktlinser, hvis dette kan gøres let. Fortsæt skylning.
P338 Language
ET Eemaldada kontaktläätsed, kui neid kasutatakse ja kui neid on kerge eemaldada. Loputada
veel kord.
EL Εάν υπάρχουν φακοί επαφής, αφαιρέστε τους, εφόσον είναι εύκολο. Συνεχίστε να ξεπλένετε.
FR Enlever les lentilles de contact si la victime en porte et si elles peuvent être facilement
enlevées. Continuer à rincer.
GA Tóg amach na tadhall-lionsaí, más ann dóibh agus más furasta é sin a dhéanamh. Lean den
sruthlú.
LT Išimti kontaktinius lęšius, jeigu jie yra ir jeigu lengvai galima tai padaryti. Toliau plauti akis.
MT Neħħi l-lentijiet tal-kuntatt, jekk ikun hemm u jkunu faċli biex tneħħihom. Kompli laħlaħ.
PT Se usar lentes de contacto, retire-as, se tal lhe for possível. Continue a enxaguar.
RO Scoateţi lentilele de contact, dacă este cazul şi dacă acest lucru se poate face cu uşurinţă.
Continuaţi să clătiţi.
SL Odstranite kontaktne leče, če jih imate in če to lahko storite brez težav. Nadaljujte z
izpiranjem.
P340 Language
DA Flyt personen til et sted med frisk luft og sørg for, at vedkommende hviler i en stilling, som
letter vejrtrækningen.
DE Die betroffene Person an die frische Luft bringen und in einer Position ruhigstellen, die das
Atmen erleichtert.
EL Μεταφέρετε τον παθόντα στον καθαρό αέρα και αφήστε τον να ξεκουραστεί σε στάση που
διευκολύνει την αναπνοή.
EN Remove victim to fresh air and keep at rest in a position comfortable for breathing.
FR Transporter la victime à l'extérieur et la maintenir au repos dans une position où elle peut
confortablement respirer.
GA Tabhair amach faoin aer an duine agus coimeád socair é, i riocht ina bhféadfaidh sé anáil a
tharraingt go réidh.
P340 Language
LV Izvest cietušo svaigā gaisā un turēt miera stāvoklī, lai būtu ērti elpot.
LT Išnešti nukentėjusįjį į gryną orą; jam būtina ramybė ir padėtis, leidžianti laisvai kvėpuoti.
HU Az érintett személyt friss levegőre kell vinni és olyan nyugalmi testhelyzetbe kell helyezni,
hogy könnyen tudjon lélegezni.
MT Esponi lill-vittma għall-arja friska u żommha mistrieħa f’pożizzjoni komda biex tkun tista’
tieħu n-nifs.
NL Het slachtoffer in de frisse lucht brengen en laten rusten in een houding die het ademen
vergemakkelijkt.
PT Retirar a vítima para uma zona ao ar livre e mantê-la em repouso numa posição que não
dificulte a respiração.
RO Transportaţi victima la aer liber şi menţineţi-o în stare de repaus într-o poziţie confortabilă
pentru respiraţie.
SV Flytta personen till frisk luft och se till att han eller hon vilar i en ställning som underlättar
andningen
P341 Language
CS Při obtížném dýchání přeneste postiženého na čerstvý vzduch a ponechte jej v klidu
v poloze usnadňující dýchání.
DA Ved vejrtrækningsbesvær: Flyt personen til et sted med frisk luft og sørg for, at
vedkommende hviler i en stilling, som letter vejrtrækningen.
DE Bei Atembeschwerden an die frische Luft bringen und in einer Position ruhigstellen, die das
Atmen erleichtert.
EL Εάν ο παθών έχει δύσπνοια, μεταφέρετέ τον στον καθαρό αέρα και αφήστε τον να ξεκουραστεί σε
στάση που διευκολύνει την αναπνοή.
EN If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
GA Más deacair don duine análú, tabhair amach faoin aer é agus coimeád socair é, i riocht ina
bhféadfaidh sé anáil a tharraingt go réidh.
LV Ja elpošana ir apgrūtināta, izvest cietušo svaigā gaisā un turēt miera stāvoklī, lai būtu ērti
elpot.
LT Jeigu nukentėjusiajam sunku kvėpuoti, išnešti jį į gryną orą; jam būtina ramybė ir padėtis,
leidžianti laisvai kvėpuoti.
HU Légzési nehézségek esetén az érintett személyt friss levegőre kell vinni és olyan nyugalmi
testhelyzetbe kell helyezni, hogy könnyen tudjon lélegezni.
L 353/276 EN Official Journal of the European Union 31.12.2008
P341 Language
MT Jekk in-nifs ikun diffiċli, esponi lill-vittma għall-arja friska u żommha mistrieħa f’pożizzjoni
komda biex tkun tista' tieħu n-nifs.
PT Em caso de dificuldade respiratória, retirar a vítima para uma zona ao ar livre e mantê-la em
repouso numa posição que não dificulte a respiração.
RO Dacă respiraţia este dificilă, transportaţi victima la aer liber şi menţineţi-o în stare de repaus
într-o poziţie confortabilă pentru respiraţie.
SL Pri oteženem dihanju prenesti žrtev na svež zrak in jo pustiti počivati v položaju, ki olajša
dihanje.
SV Vid andningsbesvär, flytta personen till frisk luft och se till att han eller hon vilar i en
ställning som underlättar andningen.
P342 Language
DA Ved luftvejssymptomer:
NL Bij ademhalingssymptomen:
P342 Language
P350 Language
P351 Language
P351 Language
P352 Language
P352 Language
P353 Language
P360 Language
BG Незабавно облейте замърсеното облекло и кожата обилно с вода, преди да свалите дрехите.
ES Aclarar inmediatamente con agua abundante las prendas y la piel contaminadas antes de
quitarse la ropa.
CS Kontaminovaný oděv a kůži okamžitě omyjte velkým množstvím vody a potom oděv
odložte.
DA Skyl omgående tilsmudset tøj og hud med rigeligt vand, før tøjet fjernes.
DE Kontaminierte Kleidung und Haut sofort mit viel Wasser abwaschen und danach Kleidung
ausziehen.
ET Saastunud rõivad ja nahk loputada viivitamata rohke veega ning alles seejärel rõivad
eemaldada.
EL Ξεπλύνετε αμέσως τα μολυσμένα ρούχα και την επιδερμίδα με άφθονο νερό πριν αφαιρέσετε τα
ρούχα.
L 353/280 EN Official Journal of the European Union 31.12.2008
P360 Language
EN Rinse immediately contaminated clothing and skin with plenty of water before removing
clothes.
GA Sruthlaítear éadaí éillithe agus an craiceann láithreach le neart uisce sula mbaineann an
duine na héadaí de.
LV Nekavējoties noskalot piesārņoto apģērbu un skarto ādu ar lielu daudzumu ūdens pirms
apģērba novilkšanas.
LT Prieš nuvelkant užterštus drabužius, nedelsiant juos ir odą nuplauti dideliu kiekiu vandens.
HU A ruhák levetése előtt a szennyezett ruházatot és a bőrt bő vízzel azonnal le kell öblíteni.
MT Laħlaħ mall-ewwel l-ilbies ikkontaminat u l-ġilda b’ħafna ilma qabel ma tneħħi l-ilbies.
NL Verontreinigde kleding en huid onmiddellijk met veel water afspoelen en pas daarna
kleding uittrekken.
PL Natychmiast spłukać zanieczyszczoną odzież i skórę dużą ilością wody przed zdjęciem
odzieży.
PT Enxaguar imediatamente com muita água a roupa e a pele contaminadas antes de se despir.
SK Kontaminovaný odev a pokožku ihneď opláchnite veľkým množstvom vody a potom odev
odstráňte.
SL Takoj izprati kontaminirana oblačila in kožo z veliko vode pred odstranitvijo oblačil.
SV Skölj genast nedstänkta kläder och hud med mycket vatten innan du tar av dig kläderna.
P361 Language
P361 Language
P362 Language
GA Bain díot láithreach na héadaí éillithe go léir agus nigh iad sula ndéanfar iad a athúsáid.
P363 Language
P363 Language
P370 Language
BG При пожар:
ES En caso de incendio:
CS V případě požáru:
DA Ved brand:
DE Bei Brand:
ET Tulekahju korral:
EL Σε περίπτωση πυρκαγιάς:
EN In case of fire:
FR En cas d’incendie:
GA I gcás dóiteáin:
IT In caso di incendio:
LV Ugunsgrēka gadījumā:
LT Gaisro atveju:
HU Tűz esetén:
P370 Language
PL W przypadku pożaru:
PT Em caso de incêndio:
RO În caz de incendiu:
SK V prípade požiaru:
SL Ob požaru:
FI Tulipalon sattuessa:
SV Vid brand:
P371 Language
P372 Language
P372 Language
P373 Language
P373 Language
P374 Language
ES Luchar contra el incendio desde una distancia razonable, tomando las precauciones
habituales.
EL Προσπαθήστε να σβήσετε την πυρκαγιά λαμβάνοντας τις κατάλληλες προφυλάξεις και από
εύλογη απόσταση.
P375 Language
P375 Language
EL Προσπαθήστε να σβήσετε την πυρκαγιά από απόσταση, επειδή υπάρχει κίνδυνος έκρηξης.
P376 Language
P376 Language
P377 Language
ET Lekkiva gaasi põlemise korral mitte kustutada, välja arvatud juhul, kui leket on võimalik
ohutult peatada.
IT In caso d’incendio dovuto a perdita di gas, non estinguere a meno che non sia possibile
bloccare la perdita senza pericolo.
PT Incêndio por fuga de gás: não apagar, a menos que se possa deter a fuga em segurança.
RO Incendiu cauzat de o scurgere de gaz: nu încercaţi să stingeţi, decât dacă scurgerea poate fi
oprită în siguranţă.
P377 Language
P378 Language
BG Използвайте … за гасене.
CS K hašení použijte …
ET Kustutamiseks kasutada …
IT Estinguere con…
LV Nodzēšanai izmantot…
LT Gesinimui naudoti …
HU Az oltáshoz … használandó.
NL Blussen met …
PL Użyć … do gaszenia.
SK Na hasenie použite …
SL Za gašenje uporabiti …
P380 Language
BG Евакуирайте зоната.
ES Evacuar la zona.
CS Vykliďte _roctor.
DA Evakuer området.
DE Umgebung räumen.
ET Ala evakueerida.
31.12.2008 EN Official Journal of the European Union L 353/289
P380 Language
EN Evacuate area.
FR Évacuer la zone.
IT Evacuare la zona.
LV Evakuēt zonu.
LT Evakuoti zoną.
MT Evakwa ż-żona.
NL Evacueren.
PL Ewakuować teren.
PT Evacuar a zona.
RO Evacuaţi zona.
SK Priestory evakuujte.
SL Izprazniti območje.
FI Evakuoi alue.
SV Utrym området.
P381 Language
EL Απομακρύνετε τις πηγές ανάφλεξης, εάν αυτό μπορεί να γίνει χωρίς κίνδυνο.
FR Éliminer toutes les sources d’ignition si cela est faisable sans danger.
RO Eliminaţi toate sursele de aprindere, dacă acest lucru se poate face în siguranţă.
L 353/290 EN Official Journal of the European Union 31.12.2008
P381 Language
P390 Language
FR Absorber toute substance répandue pour éviter qu’elle attaque les matériaux environnants.
P391 Language
BG Съберете разлятото.
ES Recoger el vertido.
DA Udslip opsamles.
P391 Language
EN Collect spillage.
GA Bailigh doirteadh.
MT Iġbor it-tixrid.
PL Zebrać wyciek.
FI Valumat on kerättävä.
P301 + Language
P310
P301 +
Language
P310
P301 + Language
P312
MT JEKK JINBELA’: Ikkuntattja ĊENTRU TA' L-AVVELENAMENT jew tabib jekk tħossok ma
tiflaħx.
P301 +
Language
P312
P301 +
P330 + Language
P331
P302 +
Language
P334
DA VED KONTAKT MED HUDEN: Skyl under koldt vand/anvend våde omslag.
L 353/294 EN Official Journal of the European Union 31.12.2008
P302 +
Language
P334
DE BEI KONTAKT MIT DER HAUT: In kaltes Wasser tauchen/nassen Verband anlegen.
FR EN CAS DE CONTACT AVEC LA PEAU: rincer à l’eau fraîche/poser une compresse humide.
GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN: Tum in uisce fionnuar/cuir bréid fliuch air.
P302 +
Language
P350
ES EN CASO DE CONTACTO CON LA PIEL: Lavar suavemente con agua y jabón abundantes.
DA VED KONTAKT MED HUDEN: Vask forsigtigt med rigeligt sæbe og vand.
DE BEI KONTAKT MIT DER HAUT: Behutsam mit viel Wasser und Seife waschen.
GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN: Nigh go bog le neart gallúnaí agus uisce.
P302 +
Language
P350
NL BIJ CONTACT MET DE HUID: voorzichtig wassen met veel water en zeep.
PL W PRZYPADKU DOSTANIA SIĘ NA SKÓRĘ: Delikatnie umyć dużą iloścą wody z mydłem.
P302 +
Language
P352
DE BEI KONTAKT MIT DER HAUT: Mit viel Wasser und Seife waschen.
P303 +
P361 + Language
P353
BG ПРИ КОНТАКТ С КОЖАТА (или косата): Незабавно свалете цялото замърсено облекло.
Облейте кожата с вода/вземете душ
CS PŘI STYKU S KŮŽÍ (nebo s vlasy): Veškeré kontaminované části oděvu okamžitě svlékněte.
Opláchněte kůži vodou/osprchujte.
DA VED KONTAKT MED HUDEN (eller håret): Tilsmudset tøj tages straks af/fjernes. Skyl/brus
huden med vand.
DE BEI KONTAKT MIT DER HAUT (oder dem Haar): Alle beschmutzten, getränkten
Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen/duschen.
ET NAHALE (või juustele) SATTUMISE KORRAL: võtta viivitamata kõik saastunud rõivad
seljast. Loputada nahka veega/loputada duši all.
EN IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
FR EN CAS DE CONTACT AVEC LA PEAU (ou les cheveux): enlever immédiatement les
vêtements contaminés. Rincer la peau à l’eau/se doucher.
LV SASKARĒ AR ĀDU (vai matiem): noģērbt visu piesārņoto apģērbu. Noskalot ādu ar ūdeni/
dušā.
LT PATEKUS ANT ODOS (arba plaukų): Nedelsiant nuvilkti/pašalinti visus užterštus drabužius.
Odą nuplauti vandeniu/čiurkšle.
MT JEKK FUQ IL-ĠILDA (jew xagħar): Neħħi/inża’ minnufih l-ilbies kontaminat. Laħlaħ il-ġilda
bl-ilma/bix-xawer.
NL BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken
— huid met water afspoelen/afdouchen.
SL PRI STIKU S KOŽO (ali lasmi): takoj odstraniti/sleči vsa kontaminirana oblačila. Izprati
kožo z vodo/prho.
FI JOS KEMIKAALIA JOUTUU IHOLLE (tai hiuksiin): Riisu saastunut vaatetus välittömästi.
Huuhdo/suihkuta iho vedellä.
SV VID HUDKONTAKT (även håret): Ta omedelbart av alla nedstänkta kläder. Skölj huden
med vatten/duscha.
31.12.2008 EN Official Journal of the European Union L 353/297
P304 +
Language
P340
CS PŘI VDECHNUTÍ: Přeneste postiženého na čerstvý vzduch a ponechte jej v klidu v poloze
usnadňující dýchání.
DA VED INDÅNDING: Flyt personen til et sted med frisk luft og sørg for, at vedkommende
hviler i en stilling, som letter vejrtrækningen.
DE BEI EINATMEN: An die frische Luft bringen und in einer Position ruhigstellen, die das
Atmen erleichtert.
EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΙΣΠΝΟΗΣ: Μεταφέρετε τον παθόντα στον καθαρό αέρα και αφήστε τον να
ξεκουραστεί σε στάση που διευκολύνει την αναπνοή.
EN IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
GA MÁ IONÁLAÍTEAR, tabhair amach faoin aer an duine agus coimeád socair é, i riocht ina
bhféadfaidh sé anáil a tharraingt go réidh.
LV IEELPOŠANAS GADĪJUMĀ: izvest cietušo svaigā gaisā un turēt miera stāvoklī, lai būtu ērti
elpot.
LT ĮKVĖPUS: Išnešti nukentėjusįjį į gryną orą; jam būtina ramybė ir padėtis, leidžianti laisvai
kvėpuoti.
HU BELÉLEGZÉS ESETÉN: Az érintett személyt friss levegőre kell vinni és olyan nyugalmi
testhelyzetbe kell helyezni, hogy könnyen tudjon lélegezni.
NL NA INADEMING: het slachtoffer in de frisse lucht brengen en laten rusten in een houding
die het ademen vergemakkelijkt.
SL PRI VDIHAVANJU: prenesti žrtev na svež zrak in jo pustiti počivati v položaju, ki olajša
dihanje.
SV VID INANDNING: Flytta personen till frisk luft och se till att han eller hon vilar i en
ställning som underlättar andningen.
L 353/298 EN Official Journal of the European Union 31.12.2008
P304 +
Language
P341
DA VED INDÅNDING: Ved vejrtrækningsbesvær: Flyt personen til et sted med frisk luft og sørg
for, at vedkommende hviler i en stilling, som letter vejrtrækningen.
DE BEI EINATMEN: Bei Atembeschwerden an die frische Luft bringen und in einer Position
ruhigstellen, die das Atmen erleichtert.
EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΙΣΠΝΟΗΣ: Εάν ο παθών έχει δύσπνοια, μεταφέρετέ τον στον καθαρό αέρα και
αφήστε τον να ξεκουραστεί σε στάση που διευκολύνει την αναπνοή.
EN IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing.
GA MÁ THÉANN AN TÁIRGE SEO LE hANÁIL DUINE, tabhair amach faoin aer an duine agus
coimeád socair é, i riocht ina bhféadfaidh sé anáil a tharraingt go réidh.
LT ĮKVĖPUS: Jeigu nukentėjusiajam sunku kvėpuoti, išnešti jį į gryną orą; jam būtina ramybė ir
padėtis, leidžianti laisvai kvėpuoti.
HU BELÉLEGZÉS ESETÉN: Légzési nehézségek esetén az érintett személyt friss levegőre kell
vinni és olyan nyugalmi testhelyzetbe kell helyezni, hogy könnyen tudjon lélegezni.
MT JEKK JITTIEĦED FIN-NIFS: Jekk in-nifs ikun diffiċli, esponi lill-vittma għall-arja friska u
żommha mistrieħa f’pożizzjoni komda biex tkun tista’ tieħu n-nifs.
RO ÎN CAZ DE INHALARE: dacă respiraţia este dificilă, transportaţi victima la aer liber şi
menţineţi-o în stare de repaus, într-o poziţie confortabilă pentru respiraţie.
SL PRI VDIHAVANJU: prenesti žrtev pri oteženem dihanju na svež zrak in jo pustiti počivati v
položaju, ki olajša dihanje.
SV VID INANDNING: Vid andningsbesvär, flytta personen till frisk luft och se till att han eller
hon vilar i en ställning som underlättar andningen.
31.12.2008 EN Official Journal of the European Union L 353/299
P305 +
P351 + Language
P338
ES EN CASO DE CONTACTO CON LOS OJOS: Aclarar cuidadosamente con agua durante
varios minutos. Quitar las lentes de contacto, si lleva y resulta fácil. Seguir aclarando.
CS PŘI ZASAŽENÍ OČÍ: Několik minut opatrně vyplachujte vodou. Vyjměte kontaktní čočky,
jsou-li nasazeny a pokud je lze vyjmout snadno. Pokračujte ve vyplachování.
DA VED KONTAKT MED ØJNENE: Skyl forsigtigt med vand i flere minutter. Fjern eventuelle
kontaktlinser, hvis dette kan gøres let. Fortsæt skylning.
DE BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen.
Vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΑ ΜΑΤΙΑ: Ξεπλύνετε προσεκτικά με νερό για αρκετά λεπτά. Εάν
υπάρχουν φακοί επαφής, αφαιρέστε τους, εφόσον είναι εύκολο. Συνεχίστε να ξεπλένετε.
EN IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
FR EN CAS DE CONTACT AVEC LES YEUX: rincer avec précaution à l’eau pendant plusieurs
minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être
facilement enlevées. Continuer à rincer.
IT IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti.
Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
LT PATEKUS Į AKIS: Kelias minutes atsargiai plauti vandeniu. Išimti kontaktinius lęšius, jeigu
jie yra ir jeigu lengvai galima tai padaryti. Toliau plauti akis.
HU SZEMBE KERÜLÉS esetén: Több percig tartó óvatos öblítés vízzel. Adott esetben a
kontaktlencsék eltávolítása, ha könnyen megoldható. Az öblítés folytatása.
MT JEKK JIDĦOL FL-GĦAJNEJN: Laħlaħ b'attenzjoni bl-ilma għal diversi minuti. Neħħi l-
lentijiet tal-kuntatt, jekk ikun hemm u jkunu faċli biex tneħħihom. Kompli laħlaħ.
NL BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal
minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
PL W PRZYPADKU DOSTANIA SIĘ DO OCZU: Ostrożnie płukać wodą przez kilka minut.
Wyjąć soczewki kontaktowe, jeżeli są i można je łatwo usunąć. Nadal płukać.
RO ÎN CAZ DE CONTACT CU OCHII: clătiţi cu atenţie cu apă timp de mai multe minute.
Scoateţi lentilele de contact, dacă este cazul şi dacă acest lucru se poate face cu uşurinţă.
Continuaţi să clătiţi.
SL PRI STIKU Z OČMI: previdno izpirajte z vodo nekaj minut. Odstranite kontaktne leče, če jih
imate in če to lahko storite brez težav. Nadaljujte z izpiranjem.
FI JOS KEMIKAALIA JOUTUU SILMIIN: Huuhdo huolellisesti vedellä usean minuutin ajan.
Poista piilolinssit, _edical voi tehdä helposti. Jatka huuhtomista.
SV VID KONTAKT MED ÖGONEN: Skölj försiktigt med vatten i flera minuter. Ta ur eventuella
kontaktlinser om det går lätt. Fortsätt att skölja.
L 353/300 EN Official Journal of the European Union 31.12.2008
P306 +
Language
P360
CS PŘI STYKU S ODĚVEM: Kontaminovaný oděv a kůži oklamžitě omyjte velkým množstvím
vody a potom oděv odložte.
DA VED KONTAKT MED TØJET: Skyl omgående tilsmudset tøj og hud med rigeligt vand, før
tøjet fjernes.
DE BEI KONTAKT MIT DER KLEIDUNG: Kontaminierte Kleidung und Haut sofort mit viel
Wasser abwaschen und danach Kleidung ausziehen.
EN IF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water
before removing clothes.
LT PATEKUS ANT DRABUŽIŲ: Prieš nuvelkant užterštus drabužius, nedelsiant juos ir odą
nuplauti dideliu kiekiu vandens.
MT JEKK FUQ L-ILBIES: laħlaħ mall-ewwel l-ilbies ikkontaminat u l-ġilda b’ħafna ilma qabel ma
tneħħi l-ilbies.
SL PRI STIKU Z OBLAČILI: takoj izprati kontaminirana oblačila in kožo z veliko vode pred
odstranitvijo oblačil.
SV VID KONTAKT MED KLÄDERNA: Skölj omedelbart nedstänkta kläder och hud med
mycket vatten innan du tar av dig kläderna.
31.12.2008 EN Official Journal of the European Union L 353/301
P307 +
Language
P311
P308 +
Language
P313
DE BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P308 +
Language
P313
PL W przypadku narażenia lub styczności: Zasięgnąć porady/zgłosić się pod opiekę lekarza.
P309 + Language
P311
LV Ja nokļūst saskarē vai jums ir slikta pašsajūta: sazinieties ar SAINDĒŠANĀS CENTRU vai
ārstu.
MT JEKK espost jew tħossok ma tiflaħx: Ikkuntattja ĊENTRU TA' L-AVVELENAMENT jew
tabib.
P309 +
Language
P311
SL PRI izpostavljenosti ali slabem počutju: pokličite CENTER ZA ZASTRUPITVE ali zdravnika.
P332 + Language
P313
P333 +
Language
P313
BG При поява на кожно дразнене или обрив на кожата: Потърсете медицински съвет/помощ.
P333 +
Language
P313
P335 +
Language
P334
ES Sacudir las partículas que se hayan depositado en la piel. Sumergir en agua fresca/aplicar
compresas húmedas.
DA Børst løse partikler bort fra huden. Skyl under koldt vand/anvend våde omslag.
DE Lose Partikel von der Haut abbürsten. In kaltes Wasser tauchen/nassen Verband anlegen.
ET Pühkida lahtised osakesed nahalt maha. Hoida jahedas vees / panna peale niiske kompress.
EL Αφαιρέστε προσεκτικά τα σωματίδια που έχουν μείνει στο δέρμα. Πλύντε με άφθονο δροσερό
νερό/τυλίξτε με βρεγμένους επιδέσμους.
EN Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
FR Enlever avec précaution les particules déposées sur la peau. Rincer à l’eau fraîche/poser une
compresse humide.
GA Scuab cáithníní scaoilte den chraiceann. Tum in uisce fionnuar/cuir bréid fliuch air.
P335 +
Language
P334
LT Neprilipusias daleles nuvalyti nuo odos. Įmerkti į vėsų vandenį/apvynioti šlapiais tvarsčiais.
HU A bőrre tapadó szemcséket óvatosan le kell kefélni. Hideg vízzel/nedves kötéssel kell hűteni.
MT Farfar il-frak mhux imwaħħal minn mal-ġilda. Daħħal fl-ilma frisk/kebbeb f’faxex
imxarrbin.
NL Losse deeltjes van de huid afvegen. In koud water onderdompelen/nat verband aanbrengen.
SL S krtačo odstraniti razsute delce s kože. Potopiti v hladno vodo/zaviti v mokre povoje.
SV Borsta bort lösa partiklar från huden. Skölj under kallt vatten/använd våta omslag.
P337 +
Language
P313
P337 +
Language
P313
P342 +
Language
P311
MT Jekk ikollok sintomi respiratorji: Ikkuntattja ĊENTRU TA' L-AVVELENAMENT jew tabib.
P370 +
Language
P376
P370 +
Language
P376
NL In geval van brand: het lek dichten als dat veilig gedaan kan worden.
RO În caz de incendiu: opriţi scurgerea, dacă acest lucru se poate face în siguranţă.
SV Vid brand: Stoppa läckan om det kan göras på ett säkert sätt.
P370 +
Language
P378
P370 +
Language
P378
P370 + Language
P380
P370 +
P380 + Language
P375
BG При пожар: Евакуирайте зоната. Гасете пожара от разстояние поради опасност от експлозия.
ES En caso de incendio: Evacuar la zona. Luchar contra el incendio a distancia, dado el riesgo
de explosión.
31.12.2008 EN Official Journal of the European Union L 353/309
P370 +
P380 + Language
P375
DE Bei Brand: Umgebung räumen. Wegen Explosionsgefahr Brand aus der Entfernung
bekämpfen.
EL Σε περίπτωση πυρκαγιάς: Εκκενώστε την περιοχή. Προσπαθήστε να σβήσετε την πυρκαγιά από
απόσταση, επειδή υπάρχει κίνδυνος έκρηξης.
EN In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
GA I gcás dóiteáin: Aslonnaigh gach duine as an limistéar. Téigh i gcianghleic leis an dóiteán
mar gheall ar an mbaol pléasctha.
LV Ugunsgrēka gadījumā: evakuēt zonu. Dzēst uguni no attāluma eksplozijas riska dēļ.
LT Gaisro atveju: evakuoti zoną. Gaisrą gesinti iš toli dėl sprogimo pavojaus.
HU Tűz esetén: Ki kell üríteni a területet. A tűz oltását robbanásveszély miatt távolból kell
végezni.
MT F’każ ta' nar: Evakwa ż-żona. Itfi n-nar mill-bogħod minħabba r-riskju ta' splużjoni.
RO În caz de incendiu: evacuaţi zona. Stingeţi incendiul de la distanţă din cauza pericolului de
explozie.
P371 +
P380 + Language
P375
BG При голям пожар и значителни количества: Евакуирайте зоната. Гасете пожара от разстояние
поради опасност от експлозия.
CS V případě velkého požáru a velkého množství: Vykliďte prostor. Kvůli nebezpečí výbuchu
haste z dostatečné vzdálenosti.
DA Ved større brand og store mængder: Evakuer området. Bekæmp branden på afstand på
grund af eksplosionsfare.
DE Bei Großbrand und großen Mengen: Umgebung räumen. Wegen Explosionsgefahr Brand
aus der Entfernung bekämpfen.
ET Suure tulekahju korral ning kui on tegemist suurte kogustega: ala evakueerida.
Plahvatusohu tõttu teha kustutustöid eemalt.
L 353/310 EN Official Journal of the European Union 31.12.2008
P371 +
P380 + Language
P375
EL Σε περίπτωση σοβαρής πυρκαγιάς και εάν πρόκειται για μεγάλες ποσότητες: Εκκενώστε την
περιοχή. Προσπαθήστε να σβήσετε την πυρκαγιά από απόσταση, επειδή υπάρχει κίνδυνος
έκρηξης.
EN In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk
of explosion.
FR En cas d’incendie important et s’il s’agit de grandes quantités: évacuer la zone. Combattre
l’incendie à distance à cause du risque d’explosion.
LV Ugunsgrēka vai liela apjoma gadījumā: evakuēt zonu. Dzēst uguni no attāluma eksplozijas
riska dēļ.
LT Didelio gaisro ir didelių kiekių atveju: evakuoti zoną. Gaisrą gesinti iš toli dėl sprogimo
pavojaus.
HU Nagyobb tűz és nagy mennyiség esetén: Ki kell üríteni a területet. A tűz oltását
robbanásveszély miatt távolból kell végezni.
MT F’każ ta' nar kbir u kwantitajiet kbar: Evakwa ż-żona. Itfi n-nar mill-bogħod minħabba r-
riskju ta' splużjoni.
NL In geval van grote brand en grote hoeveelheden: evacueren. Op afstand blussen omwille van
ontploffingsgevaar.
SL Ob velikem požaru in velikih količinah: izprazniti območje. Gasiti z večje razdalje zaradi
nevarnosti eksplozije.
FI Jos tulipalo ja ainemäärät ovat suuret: Evakuoi alue. Sammuta palo etäältä räjähdysvaaran
takia.
SV Vid större brand och stora mängder: Utrym området. Bekämpa branden på avstånd på
grund av explosionsrisken.
Table 1.4
P401 Language
BG Да се съхранява…
ES Almacenar …
CS Skladujte …
DA Opbevares …
DE … aufbewahren.
ET Hoida …
EL Αποθηκεύεται …
31.12.2008 EN Official Journal of the European Union L 353/311
P401 Language
EN Store …
FR Stocker …
GA Stóráil …
IT Conservare…
LV Glabāt…
LT Laikyti…
HU Tárolás: … .
MT Aħżen …
NL … bewaren.
PL Przechowywać …
PT Armazenar …
RO A se depozita…
SK Uchovávajte …
SL Hraniti …
FI Varastoi …
SV Förvaras …
P402 Language
ET Hoida kuivas.
P402 Language
SL Hraniti na suhem.
SV Förvaras torrt.
P403 Language
P404 Language
P404 Language
FI Varastoi suljettuna.
P405 Language
CS Skladujte uzamčené.
ET Hoida lukustatult.
EL Φυλάσσεται κλειδωμένο.
LT Laikyti užrakintą.
HU Elzárva tárolandó.
SK Uchovávajte uzamknuté.
SL Hraniti zaklenjeno.
L 353/314 EN Official Journal of the European Union 31.12.2008
P405 Language
SV Förvaras inlåst.
P406 Language
LV Glabāt tvertnē, kas aizsargā pret koroziju/… tvertnes ar iekšējo pretkorozijas izolāciju.
P407 Language
P407 Language
P410 Language
HU Napfénytől védendő.
P410 Language
FI Suojaa auringonvalolta.
P411 Language
P412 Language
P412 Language
P413 Language
CS Množství větší než … kg/… liber skladujte při teplotě nepřesahující … oC/…oF.
DA Bulkmængder på over … kg/…lbs opbevares ved en temperatur, som ikke overstiger … oC/
…oF.
DE Schüttgut in Mengen von mehr als … kg bei Temperaturen von nicht mehr als … oC
aufbewahren
ET Kogust, mis on suurem kui … kg/… naela, hoida temperatuuril mitte üle … oC/… oF.
EL Οι σωροί χύδην με βάρος άνω των … kg/… lbs αποθηκεύονται σε θερμοκρασίες που δεν
υπερβαίνουν τους … oC/…oF.
EN Store bulk masses greater than … kg/… lbs at temperatures not exceeding … oC/…oF.
FR Stocker les quantités en vrac de plus de … kg/… lb à une température ne dépassant pas
… oC/… oF.
LV Lielus apjomus, kas pārsniedz … kg/… lbs, uzglabāt temperatūrā, kas nepārsniedz … oC/
…oF.
LT Didesnius kaip … kg/… lbs medžiagos kiekius laikyti ne aukštesnėje kaip … oC/…oF
temperatūroje.
MT Aħżen il-kwantitajiet f’massa ta' akbar minn … kg/… lbs f’temperaturi ta' mhux aktar minn
… oC/…oF.
L 353/318 EN Official Journal of the European Union 31.12.2008
P413 Language
NL Bulkmateriaal, indien meer dan … kg/… lbs, bij temperaturen van maximaal … oC
bewaren.
PT Armazenar quantidades a granel superiores a … kg/… lbs a uma temperatura não superior
a … oC/…oF.
RO Depozitaţi cantităţile în vrac mai mari de … kg/… lbs la temperaturi care să nu depăşească
… oC/…oF.
SK Veľké množstvo s hmotnosťou nad … kg/… lbs uchovávajte pri teplote do … oC/…oF.
SL Razsute količine, večje od … kg/… lbs, hraniti pri temperaturi do … oC/… oF.
SV Bulkprodukter som väger mer än … kg/… lbs förvaras vid högst … oC/…oF.
P420 Language
P422 Language
ES Almacenar el contenido en …
CS Skladujte pod …
ET Hoida sisu …
EL Το περιεχόμενο αποθηκεύεται σε …
IT Conservare sotto…
LT Turinį laikyti …
NL Onder … bewaren.
PL Zawartość przechowywać w …
PT Armazenar o conteúdo em …
SK Obsah uchovávajte v …
SL Vsebino hraniti v …
FI Varastoi sisältö …
SV Förvara innehållet i…
P402 +
P404 Language
P402 +
Language
P404
P403 +
P233 Language
FR Stocker dans un endroit bien ventilé. Maintenir le récipient fermé de manière étanche.
P403 +
Language
P235
P410 + Language
P403
P410 +
Language
P403
P410 +
P412 Language
DA Beskyttes mod sollys. Må ikke udsættes for en temperatur, som overstiger 50 oC/122oF.
DE Vor Sonnenbestrahlung schützen und nicht Temperaturen von mehr als 50 oC aussetzen.
EL Να προστατεύεται από τις ηλιακές ακτίνες. Να μην εκτίθεται σε θερμοκρασίες που υπερβαίνουν
τους 50 oC/122oF.
P410 +
Language
P412
SV Skyddas från solljus. Får inte utsättas för temperaturer över 50 oC/122 oF.
P411 + Language
P235
Table 1.5
P501 Language
BG Съдържанието/съдът да се изхвърли в …
CS Odstraňte obsah/obal …
DA Indholdet/beholderen bortskaffes i …
DE Inhalt/Behälter … zuführen.
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P501 Language
ET Sisu/mahuti kõrvaldada …
EN Dispose of contents/container to …
IT Smaltire il prodotto/recipiente in …
LV Atbrīvoties no satura/tvertnes…
MT Armi l-kontenut/il-kontenitur fi …
PL Zawartość/pojemnik usuwać do …
PT Eliminar o conteúdo/recipiente em …
RO Aruncaţi conţinutul/recipientul la …
SK Zneškodnite obsah/nádobu …
SL Odstraniti vsebino/posodo …
FI Hävitä sisältö/pakkaus …
ANNEX V
HAZARD PICTOGRAMS
INTRODUCTION
The hazard pictograms for each hazard class, differentiation of a hazard class and hazard category shall satisfy the provisions
of this Annex and Annex I, section 1.2 and conform, in terms of colour, symbols and general format, to the specimens
shown.
1.6. A pictogram is not required for the following physical hazard classes and hazard categories:
2.5. A pictogram is not required for the following health hazard categories:
Section 3.7: Reproductive toxicity, Effects on or via lactation, additional hazard category
L 353/328 EN Official Journal of the European Union 31.12.2008
A pictogram is not required for the following environmental hazard classes and hazard categories:
ANNEX VI
Part 1 of this Annex provides an introduction to the list of harmonised classification and labelling, including information
listed for each entry and related classifications and hazard statements in Table 3.1, subject to certain considerations arising
from translating the classifications listed in Annex I to Directive 67/548/EEC.
Part 2 of this Annex lays down general principles for preparing dossiers to propose and justify harmonised classification and
labelling of substances at Community level.
Part 3 of this Annex lists hazardous substances for which harmonised classification and labelling have been established at
Community level. In Table 3.1 the classification and labelling are based on the criteria in Annex I to this Regulation. In
Table 3.2 classification and labelling are based on the criteria in Annex VI to Directive 67/548/EEC.
Entries in Part 3 are listed according to the atomic number of the element most characteristic of the properties
of the substance. Organic substances, because of their variety, have been placed in classes. The Index number for
each substance is in the form of a digit sequence of the type ABC-RST-VW-Y. ABC corresponds to the atomic
number of the most characteristic element or the most characteristic organic group in the molecule. RST is the
consecutive number of the substance in the series ABC. VW denotes the form in which the substance is
produced or placed on the market. Y is the check-digit calculated in accordance with the 10-digit ISBN method.
This number is indicated in the column entitled ‘Index No’.
1.1.1.2. EC numbers
The EC number, i.e. EINECS, ELINCS or NLP, is the official number of the substance within the European Union.
The EINECS number can be obtained from the European Inventory of Existing Commercial Chemical Substance
(EINECS) (1). The ELINCS number can be obtained from the European List of Notified Substances (as amended)
(EUR 22543 EN, Office for Official Publications of the European Communities, 2006, ISSN 1018-5593). The
NLP number can be obtained from the list of ‘No-longer-polymers’ (as amended) (Document, Office for Official
Publications of the European Communities, 1997, ISBN 92-827-8995-0). The EC number is a seven-digit
system of the type XXX-XXX-X which starts at 200-001-8 (EINECS), at 400-010-9 (ELINCS) and at 500-001-0
(NLP). This number is indicated in the column entitled ‘EC No’.
The Chemical Abstracts Service (CAS) number is also included to assist identification of the entry. It should be
noted that the EINECS number includes both anhydrous and hydrated forms of a substance, and there are
frequently different CAS numbers for anhydrous and hydrated forms. The CAS number included is for the
anhydrous form only, and therefore the CAS number shown does not always describe the entry as accurately as
the EINECS number. This number is indicated in the column entitled ‘CAS No’.
Wherever possible, hazardous substances are designated by their IUPAC names. Substances listed in EINECS,
ELINCS or the list of ‘No-longer-polymers’ are designated using the names in these lists. Other names, such as
usual or common names, are included in some cases. Whenever possible, plant protection products and
biocides are designated by their ISO names.
Impurities, additives and minor components are normally not mentioned unless they contribute significantly to
the classification of the substance.
Some substances are described with a specific percentage of purity. Substances containing a higher content of
active material (e.g. organic peroxide) than this percentage are not included in the entry in Part 3 and may have
other hazardous properties (e.g. explosive) and should be classified and labelled accordingly.
Where specific concentration limits are shown, these apply to the substance or substances shown in the entry. In
particular, in the case of entries which are mixtures of substances or substances described with a specific
percentage of purity, the limits apply to the substance as described in Part 3 and not the pure substance.
Without prejudice to Article 17(2), for substances appearing in Part 3, the name of the substance to be used on
the label shall be one of the designations given there. For certain substances, additional information has been
added in square brackets in order to help identify the substance. This additional information need not be
included on the label.
Certain entries contain a reference to impurities; in these cases the name of the substance is followed by the text:
‘(containing ≥ xx % impurity)’. The reference in brackets is then to be considered as a part of the name, and must
be included on the label.
A number of group entries are included in Part 3. In these cases, the classification and labelling requirements
will apply to all substances covered by the description.
In some cases, there are classification and labelling requirements for specific substances that would be covered
by the group entry. In such cases a specific entry is included in Part 3 for the substance and the group entry will
be annotated with the phrase ‘except those specified elsewhere in this Annex’.
In some cases, individual substances may be covered by more than one group entry. In these cases, the
classification of the substance reflects the classification for each of the two group entries. In cases where
different classifications for the same hazard are given, the most severe classification shall be applied.
Entries in Part 3 for salts (under any denomination) cover both anhydrous and hydrous forms, unless specified
otherwise.
EC or CAS numbers are not usually included for entries which comprise more than four individual substances.
1.1.2. Information related to the classification and labelling of each entry in Table 3.1
1.1.2.1.1. H a z a r d c l a s s a n d c a t e g o r y c o d e s
The classification for each entry is based on the criteria set out in Annex I, in accordance with Article 13(a) and
is presented in the form of a code representing the hazard class and the category or categories/divisions/types
within this hazard class.
The Hazard class and category codes used for each of the hazard categories/divisions/types included in a class
are shown in Table 1.1.
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Table 1.1
Carcinogenicity Carc. 1A
Carc. 1B
Carc. 2
1.1.2.1.2. H a z a r d s t a t e m e n t c o d e s
The hazard statements assigned in accordance with Article 13(b), are indicated in accordance with Annex III. In
addition, for certain hazard statements letters are added to the 3-digit code. The following additional codes are
used:
(i) the hazard pictogram codes as specified in Annex V, in accordance with the precedence rules in Article 26;
(ii) the signal word code ‘Dgr’ for ‘Danger’or ‘Wng’ for ‘Warning’, in accordance with the precedence rule in
Article 20(3);
(iii) the hazard statement codes as specified in Annex III, in accordance with the classification;
(iv) the codes for the supplemental statements assigned in accordance with Article 25(1) and the rules
specified in Annex II, part 1.
Specific concentration limits, where different from the generic concentration limits given in Annex I for a
certain category, are given in a separate column together with the classification concerned using the same codes
as under 1.1.2.1.1. Where no specific concentration limits are given in this Annex for a certain category, the
generic concentration limits given in Annex I must be applied for the classification of substances containing
impurities, additives or individual constituents or for mixtures. An asterisk ( *) in this column indicates that the
entry has specific concentration limits for acute toxicity under Directive 67/548/EEC (Table 3.2): see also
section 1.2.1.
Unless otherwise shown, the concentration limits are a percentage by weight of the substance calculated with
reference to the total weight of the mixture.
In case an M-factor has been harmonised for substances classified as hazardous to the aquatic environment in
the categories Aquatic Acute 1 or Aquatic Chronic 1, this M-factor is given in the same column as the specific
concentration limits. Where an M-factor is not given in Table 3.1, an M-factor based on available data for the
substance shall be set by the manufacturer, importer or downstream user. When a mixture including the
substance is classified by the manufacturer, importer or downstream user using the summation method, this M-
factor shall be used. For the setting of M-factors, see paragraph 4.1.3.5.5.5 of Annex I.
The note(s) assigned to an entry are listed in the column entitled ‘Notes’. The meaning of the notes is as follows:
Note A:
Without prejudice to Article 17(2), the name of the substance must appear on the label in the form of one of
the designations given in Part 3.
In Part 3, use is sometimes made of a general description such as ‘... compounds’ or ‘... salts’. In this case, the
supplier is required to state on the label the correct name, due account being taken of section 1.1.1.4.
Note B:
Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and,
therefore, these solutions require different classification and labelling since the hazards vary at different
concentrations.
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In Part 3 entries with Note B have a general designation of the following type: ‘nitric acid … %’.
In this case the supplier must state the percentage concentration of the solution on the label. Unless otherwise
stated, it is assumed that the percentage concentration is calculated on a weight/weight basis.
Note C:
Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers.
In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of
isomers.
Note D:
Certain substances which are susceptible to spontaneous polymerisation or decomposition are generally placed
on the market in a stabilised form. It is in this form that they are listed in Part 3.
However, such substances are sometimes placed on the market in a non-stabilised form. In this case, the supplier
must state on the label the name of the substance followed by the words ‘non-stabilised’.
N o t e E ( Ta b l e 3 . 2 ) :
Substances with specific effects on human health (see Chapter 4 of Annex VI to Directive 67/548/EEC) that are
classified as carcinogenic, mutagenic and/or toxic for reproduction in categories 1 or 2 are ascribed Note E if
they are also classified as very toxic (T+), toxic (T) or harmful (Xn). For these substances, the risk phrases R20,
R21, R22, R23, R24, R25, R26, R27, R28, R39, R68 (harmful), R48 and R65 and all combinations of these risk
phrases shall be preceded by the word ‘Also’.
Note F:
This substance may contain a stabiliser. If the stabiliser changes the hazardous properties of the substance, as
indicated by the classification in Part 3, classification and labelling should be provided in accordance with the
rules for classification and labelling of hazardous mixtures.
Note G:
This substance may be marketed in an explosive form in which case it must be evaluated using the appropriate
test methods. The classification and labelling provided shall reflect the explosive properties.
N o t e H ( Ta b l e 3 . 1 ) :
The classification and labelling shown for this substance applies to the hazardous property(ies) indicated by the
hazard statement(s) in combination with the hazard class(es) and category(ies) shown. The requirements of
Article 4 for manufacturers, importers or downstream users of this substance apply to all other hazard classes
and categories. For hazard classes where the route of exposure or the nature of the effects leads to a
differentiation of the classification of the hazard class, the manufacturer, importer or downstream user is
required to consider the routes of exposure or the nature of the effects not already considered.
The final label shall follow the requirements of Article 17 and of section 1.2 of Annex I.
N o t e H ( Ta b l e 3 . 2 ) :
The classification and label shown for this substance applies to the dangerous property(ies) indicated by the risk
phrase(s) in combination with the category(ies) of danger shown. Manufacturers, importers and downstream
users of this substance shall be obliged to carry out an investigation to make themselves aware of the relevant
and accessible data which exists for all other properties to classify and label the substance. The final label shall
follow the requirements of section 7 of Annex VI to Directive 67/548/EEC.
Note J:
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less
than 0,1 % w/w benzene (EINECS No 200-753-7). This note applies only to certain complex coal- and oil-
derived substances in Part 3.
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Note K:
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less
than 0,1 % w/w 1,3-butadiene (EINECS No 203-450-8). If the substance is not classified as a carcinogen or
mutagen, at least the precautionary statements (P102-)P210-P403 (Table 3.1) or the S-phrases (2-)9-16
(Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3.
Note L:
The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 %
DMSO extract as measured by IP 346 ‘Determination of polycyclic aromatics in unused lubricating base oils and
asphaltene free petroleum fractions — Dimethyl sulphoxide extraction refractive index method’, Institute of
Petroleum, London. This note applies only to certain complex oil-derived substances in Part 3.
Note M:
The classification as a carcinogen need not apply if it can be shown that the substance contains less than
0,005 % w/w benzo[a]-pyrene (EINECS No 200-028-5). This note applies only to certain complex coal-derived
substances in Part 3.
Note N:
The classification as a carcinogen need not apply if the full refining history is known and it can be shown that
the substance from which it is produced is not a carcinogen. This note applies only to certain complex oil-
derived substances in Part 3.
Note P:
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less
than 0,1 % w/w benzene (EINECS No 200-753-7).
When the substance is not classified as a carcinogen at least the precautionary statements (P102-)P260-P262-
P301 + P310-P331 (Table 3.1) or the S-phrases (2-)23-24-62 (Table 3.2) shall apply.
Note Q:
The classification as a carcinogen need not apply if it can be shown that the substance fulfils one of the
following conditions:
— a short term biopersistence test by inhalation has shown that the fibres longer than 20 μm have a
weighted half-life less than 10 days; or
— a short term biopersistence test by intratracheal instillation has shown that the fibres longer than 20 μm
have a weighted half-life less than 40 days; or
— absence of relevant pathogenicity or neoplastic changes in a suitable long term inhalation test.
Note R:
The classification as a carcinogen need not apply to fibres with a length weighted geometric mean diameter less
two standard geometric errors greater than 6 μm.
Note S:
This substance may not require a label according to Article 17 (see section 1.3 of Annex I) (Table 3.1).
L 353/336 EN Official Journal of the European Union 31.12.2008
This substance may not require a label according to Article 23 of Directive 67/548/EEC (see section 8 of
Annex VI to that Directive) (Table 3.2).
Note T:
This substance may be marketed in a form which does not have the physical hazards as indicated by the
classification in the entry in Part 3. If the results of the relevant method or methods in accordance with Part 2 of
Annex I of this Regulation show that the specific form of substance marketed does not exhibit this physical
property or these physical hazards, the substance shall be classified in accordance with the result or results of
this test or these tests. Relevant information, including reference to the relevant test method(s) shall be included
in the safety data sheet.
N o t e U ( Ta b l e 3 . 1 ) :
When put on the market gases have to be classified as ‘Gases under pressure’, in one of the groups compressed
gas, liquefied gas, refrigerated liquefied gas or dissolved gas. The group depends on the physical state in which
the gas is packaged and therefore has to be assigned case by case.
Note 1:
The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation
(Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of
the metallic element calculated with reference to the total weight of the mixture.
Note 2:
The concentration of isocyanate stated is the percentage by weight of the free monomer calculated with
reference to the total weight of the mixture.
Note 3:
The concentration stated is the percentage by weight of chromate ions dissolved in water calculated with
reference to the total weight of the mixture.
Note 5:
The concentration limits for gaseous mixtures are expressed as volume per volume percentage.
Note 7:
Alloys containing nickel are classified for skin sensitisation when the release rate of 0,5 μg Ni/cm2/week, as
measured by the European Standard reference test method EN 1811, is exceeded.
1.1.4. Information related to the classification and labelling of each entry in Table 3.2
The classification for each category of danger (as defined in Article 2(2) of Directive 67/548/EEC) is normally
presented in the form of an abbreviation representing the category of danger together with the appropriate risk
phrase or phrases. However, in some cases (i.e. substances classified as flammable, sensitising and some
substances classified as dangerous for the environment) the risk phrase alone is used;
— explosive: E
— oxidising: O
— extremely flammable: F+
— highly flammable: F
31.12.2008 EN Official Journal of the European Union L 353/337
— flammable: R10
— very toxic: T+
— Toxic: T
— harmful: Xn
— corrosive: C
— irritant: Xi
(i) the letter assigned to the substance in accordance with Annex II to Directive 67/548/EEC (see Arti-
cle 23(2)(c) Directive 67/548/EEC). This acts as an abbreviation for the symbol and for the indication of
danger (if these are assigned);
(ii) the risk phrases, denoted as a series of numbers preceded by the letter R indicating the nature of the
special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/
EEC). The numbers are separated by either a dash (-) to denote separate statements concerning special risks
(R), or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks as set
out in Annex III to Directive 67/548/EEC;
(iii) the safety phrases denoted as a series of numbers preceded by the letter S indicating the recommended
safety precautions, in accordance with Annex IV to Directive 67/548/EEC (see Article 23(2)(e)
Directive 67/548/EEC). Again the numbers are separated by either a dash or an oblique stroke; the
significance of recommended safety precautions is set out in Annex IV to Directive 67/548/EEC. The
safety phrases shown apply only to substances; for mixtures, phrases are selected according to the usual
rules.
Note that for certain dangerous substances and mixtures sold to the general public certain S-phrases are
mandatory.
S1, S2 and S45 are obligatory for all very toxic, toxic and corrosive substances and mixtures sold to the
general public.
S2 and S46 are obligatory for all other dangerous substances and mixtures sold to the general public other
than those that have only been classified as dangerous for the environment.
Safety phrases S1 and S2 are shown in brackets in Annex I and can only be omitted from the label when
the substance or mixture is sold for industrial use only.
The concentration limits and associated classifications are necessary to classify dangerous mixtures containing
the substance in accordance with Directive 1999/45/EC.
Unless otherwise shown, the concentration limits are a percentage by weight of the substance calculated with
reference to the total weight of the mixture.
L 353/338 EN Official Journal of the European Union 31.12.2008
Where no concentration limits are given, the concentration limits to be used when applying the conventional
method of assessing health hazards are those in Annex II, and when applying the conventional method of
assessing environmental hazards are those in Annex III to Directive 1999/45/EC.
It is recommended to update the physical hazards of some entries in Table 3.2 in a forthcoming adaptation to
technical progress.
Until these entries are updated, the physical hazards of the corresponding entries in both tables will not be in
conformity. These entries are indicated with reference ⊗ in Table 3.2.
1.2. Classifications and hazard statements in table 3.1 arising from translation of classifications listed in
Annex i to directive 67/548/EEC
For certain hazard classes, including acute toxicity and STOT repeated exposure, the classification according to
the criteria in Directive 67/548/EEC does not correspond directly to the classification in a hazard class and
category under this Regulation. In these cases the classification in this Annex shall be considered as a minimum
classification. This classification shall be applied if none of the following conditions are fulfilled:
— the manufacturer or importer has access to data or other information as specified in Part 1 of Annex I that
lead to classification in a more severe category compared to the minimum classification. Classification in
the more severe category must then be applied;
— the minimum classification can be further refined based on the translation table in Annex VII when the
physical state of the substance used in the acute inhalation toxicity test is known to the manufacturer or
importer. The classification as obtained from Annex VII shall then substitute the minimum classification
indicated in this Annex if it differs from it.
Minimum classification for a category is indicated by the reference * in the column ‘Classification’ in Table 3.1.
The reference * can also be found in the column ‘Specific concentration Limits and M-factors’ where it indicates
that the entry concerned has specific concentration limits under Directive 67/548/EEC (Table 3.2) for acute
toxicity. These concentration limits cannot be ‘translated’ into concentration limits under this Regulation,
especially when a minimum classification is given. However, when the reference * is shown, the classification for
acute toxicity for this entry may be of special concern.
For certain hazard classes, e.g. STOT, the route of exposure should be indicated in the hazard statement only if it
is conclusively proven that no other route of exposure can cause the hazard in accordance to the criteria in
Annex I. Under Directive 67/548/EEC the route of exposure is indicated for classifications with R48 when there
was data justifying the classification for this route of exposure. The classification under 67/548/EEC indicating
the route of exposure has been translated into the corresponding class and category according to this
Regulation, but with a general hazard statement not specifying the route of exposure as the necessary
information is not available.
**
These hazard statements are indicated by the reference in Table 3.1.
Hazard statements H360 and H361 indicate a general concern for effects on both fertility and development:
‘May damage/Suspected of damaging fertility or the unborn child’. According to the criteria, the general hazard
statement can be replaced by the hazard statement indicating only the property of concern, where either fertility
or developmental effects are proven to be not relevant.
31.12.2008 EN Official Journal of the European Union L 353/339
In order not to lose information from the harmonised classifications for fertility and developmental effects
under Directive 67/548/EEC, the classifications have been translated only for those effects classified under that
Directive.
These hazard statements are indicated by the reference *** in Table 3.1.
For some entries the correct classification for physical hazards could not be established because sufficient data
are not available for the application of the classification criteria in this Regulation. The entry might be assigned
to a different (also higher) category or even another hazard class than indicated. The correct classification shall
be confirmed by testing.
The entries with physical hazards that need to be confirmed by testing are indicated by the reference **** in
Table 3.1.
This Part lays down general principles for preparing dossiers to propose and justify harmonised classification
and labelling.
The relevant parts of sections 1, 2 and 3 of Annex I to Regulation (EC) No 1907/2006 shall be used for the
methodology and format of any dossier.
For all dossiers any relevant information from registration dossiers shall be considered and other available
information may be used. For hazard information which has not been previously submitted to the Agency, a
robust study summary shall be included in the dossier.
A dossier for harmonised classification and labelling shall contain the following:
— Proposal
The proposal shall include the identity of the substance or substances concerned and the harmonised
classification and labelling proposed.
A comparison of the available information with the criteria contained in Parts 2 to 5, taking into account
the general principles in Part 1, of Annex I to this Regulation shall be completed and documented in the
format set out in Part B of the Chemical Safety Report in Annex I to Regulation (EC) No 1907/2006.
For other effects than carcinogenity, mutagenicity, reprotoxicity and respiratory sensitisation a justification
shall be provided that there is a need for action demonstrated at Community level. This does not apply for
an active substance in the meaning of Directive 91/414/EEC or Directive 98/8/EC.
Table 3.1: List of harmonised classification and labelling of hazardous substances is listed in the separate Volume IIIa.
Table 3.2: The list of harmonised classification and labelling of hazardous substances from Annex I to Directive 67/548/EEC
is listed in the separate Volume IIIb.
Table 3.1
L 353/340
List of harmonised classification and labelling of hazardous substances
EN
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
001-002-00-4 aluminium lithium hydride 240-877-9 16853-85-3 Water-react. 1 H260 GHS02 H260
31.12.2008
Skin Irrit. 2 H335 H315
Skin Sens. 1 H315 H317
H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
004-002-00-2 beryllium compounds with the exception of — — Carc. 1B H350i GHS06 H350i A
EN
aluminium beryllium silicates, and with Acute Tox. 2 * H330 GHS08 H330
those specified elsewhere in this Annex Acute Tox. 3 * H301 GHS09 H301
STOT RE 1 H372 Dgr H372 **
Eye Irrit. 2 ** H319
STOT SE 3 H319 H335
Skin Irrit. 2 H335 H315
Skin Sens. 1 H315 H317
Aquatic H317 H411
Chronic 2 H411
005-001-00-X boron trifluoride 231-569-5 7637-07-2 Press. Gas H330 GHS04 H330 EUH014 U
Acute Tox. 2 * H314 GHS06 H314
Skin Corr. 1A GHS05
Dgr
005-002-00-5 boron trichloride 233-658-4 10294-34-5 Press. Gas H330 GHS04 H330 EUH014 U
Acute Tox. 2 * H300 GHS06 H300
Acute Tox. 2 * H314 GHS05 H314
Skin Corr. 1B Dgr
005-003-00-0 boron tribromide 233-657-9 10294-33-4 Acute Tox. 2 * H330 GHS06 H330 EUH014
L 353/341
Acute Tox. 2 * H300 GHS05 H300
Skin Corr. 1A H314 Dgr H314
L 353/342
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Corr. 1B H314 GHS05 H314
Dgr
005-005-00-1 trimethyl borate 204-468-9 121-43-7 Flam. Liq. 3 H226 GHS02 H226
005-006-00-7 dibutyltin hydrogen borate 401-040-5 75113-37-0 STOT RE 1 H372 GHS08 H372 **
Acute Tox. 4 * ** GHS05 H312
Acute Tox. 4 * H312 GHS07 H302
Eye Dam. 1 H302 GHS09 H318
Skin Sens. 1 H318 Dgr H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
005-009-00-3 tetrabutylammonium butyltriphenylborate 418-080-4 120307-06-4 Skin Sens. 1 H317 GHS07 H317
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
penta-2,4-dienylidene]cyclohexa-2,5-dienyli- Aquatic Acute 1 H400 GHS09 H410
dene}ammonium butyltriphenylborate Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-001-00-2 carbon monoxide 211-128-3 630-08-0 Flam. Gas 1 H220 GHS02 H220 U
EN
Press. Gas H360- GHS04 H360D ***
Repr. 1A D *** GHS06 H331
Acute Tox. 3 * H331 GHS08 H372 **
STOT RE 1 H372 Dgr
**
006-005-00-4 thiram (ISO); 205-286-2 137-26-8 Acute Tox. 4 * H332 GHS08 H332 M = 10
tetramethylthiuram disulphide Acute Tox. 4 * H302 GHS07 H302
STOT RE 2 * H373 GHS09 H373 **
Eye Irrit. 2 ** Wng H319
Skin Irrit. 2 H319 H315
Skin Sens. 1 H315 H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
006-006-00-X hydrogen cyanide; 200-821-6 74-90-8 Flam. Liq. 1 H224 GHS02 H224
hydrocyanic acid Acute Tox. 2 * H330 GHS06 H330
L 353/343
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
L 353/344
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-006-01-7 hydrogen cyanide … %; 200-821-6 74-90-8 Acute Tox. 2 * H330 GHS06 H330 B
EN
hydrocyanic acid … % Acute Tox. 1 H310 GHS09 H310
Acute Tox. 2 * H300 Dgr H300
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
006-007-00-5 salts of hydrogen cyanide with the exception — — Acute Tox. 2 * H330 GHS06 H330 EUH032 A
of complex cyanides such as ferrocyanides, Acute Tox. 1 H310 GHS09 H310
006-008-00-0 antu (ISO); 201-706-3 86-88-4 Acute Tox. 2 * H300 GHS06 H300
1-(1-naphthyl)-2-thiourea Carc. 2 H351 GHS08 H351
Dgr
006-009-00-6 1-isopropyl-3-methylpyrazol-5-yl dimethyl- 204-318-2 119-38-0 Acute Tox. 1 H310 GHS06 H310
carbamate; Acute Tox. 2 * H300 Dgr H300
isolan
31.12.2008
Aquatic Acute 1 H400 GHS09 H400
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-012-00-2 ziram (ISO); 205-288-3 137-30-4 Acute Tox. 2 * H330 GHS06 H330 M = 100
EN
zinc bis dimethyldithiocarbamate Acute Tox. 4 * H302 GHS08 H302
STOT RE 2 * H373 GHS05 H373 **
STOT SE 3 ** GHS09 H335
Eye Dam. 1 H335 Dgr H318
Skin Sens. 1 H318 H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
006-014-00-3 nabam (ISO); 205-547-0 142-59-6 Acute Tox. 4 * H302 GHS07 H302
disodium ethylenebis(N,N'-dithiocarbamate) STOT SE 3 H335 GHS09 H335
Skin Sens. 1 H317 Wng H317
Aquatic Acute 1 H410 H410
Aquatic
Chronic 1
006-016-00-4 propoxur (ISO); 204-043-8 114-26-1 Acute Tox. 3 * H301 GHS06 H301
2-isopropyloxyphenyl N-methylcarbamate; Aquatic Acute 1 H400 GHS09 H410
L 353/345
2-isopropoxyphenyl methylcarbamate Aquatic H410 Dgr
Chronic 1
L 353/346
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-017-00-X aldicarb (ISO); 204-123-2 116-06-3 Acute Tox. 2 * H330 GHS06 H330
EN
2-methyl-2-(methylthio)propanal-O-(N-me- Acute Tox. 2 * H300 GHS09 H300
thylcarbamoyl)oxime Acute Tox. 3 * H311 Dgr H311
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
006-018-00-5 aminocarb (ISO); 217-990-7 2032-59-9 Acute Tox. 3 * H311 GHS06 H311
4-dimethylamino-3-tolyl methylcarbamate Acute Tox. 3 * H301 GHS09 H301
Aquatic Acute 1 H400 Dgr H410
006-020-00-6 barban (ISO); 202-930-4 101-27-9 Acute Tox. 4 * H302 GHS07 H302
4-chlorbut-2-ynyl N-(3-chlorophenyl)carba- Skin Sens. 1 H317 GHS09 H317
mate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
31.12.2008
006-022-00-7 decarbofuran (ISO); — 1563-67-3 Acute Tox. 3 * H331 GHS06 H331
2,3-dihydro-2-methylbenzofuran-7-yl Acute Tox. 3 * H311 Dgr H311
methylcarbamate Acute Tox. 3 * H301 H301
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-023-00-2 mercaptodimethur (ISO); 217-991-2 2032-65-7 Acute Tox. 3 * H301 GHS06 H301
EN
methiocarb (ISO); Aquatic Acute 1 H400 GHS09 H410
3,5-dimethyl-4-methylthiophenyl N-methyl- Aquatic H410 Dgr
carbamate Chronic 1
006-024-00-8 proxan-sodium (ISO); 205-443-5 140-93-2 Acute Tox. 4 * H302 GHS07 H302
sodium O-isopropyldithiocarbonate Skin Irrit. 2 H315 GHS09 H315
Aquatic H411 Wng H411
Chronic 2
006-026-00-9 carbofuran (ISO); 216-353-0 1563-66-2 Acute Tox. 2 * H330 GHS06 H330
2,3-dihydro-2,2-dimethylbenzofuran-7-yl Acute Tox. 2 * H300 GHS09 H300
N-methylcarbamate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
006-028-00-X dinobuton (ISO); 213-546-1 973-21-7 Acute Tox. 3 * H301 GHS06 H301
L 353/347
2-(1-methylpropyl)-4,6-dinitrophenyl iso- Aquatic Acute 1 H400 GHS09 H410
propyl carbonate Aquatic H410 Dgr
Chronic 1
L 353/348
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-029-00-5 dioxacarb (ISO); 230-253-4 6988-21-2 Acute Tox. 3 * H301 GHS06 H301
EN
2-(1,3-dioxolan-2-yl)phenyl N-methylcarba- Aquatic H411 GHS09 H411
mate Chronic 2 Dgr
006-030-00-0 EPTC (ISO); 212-073-8 759-94-4 Acute Tox. 4 * H302 GHS07 H302
S-ethyl dipropylthiocarbamate Wng
006-031-00-6 formetanate (ISO); 244-879-0 22259-30-9 Acute Tox. 2 * H330 GHS06 H330
3-[(EZ)-dimethylaminomethyleneamino] Acute Tox. 2 * H300 GHS09 H300
006-032-00-1 monolinuron (ISO); 217-129-5 1746-81-2 Acute Tox. 4 * H302 GHS08 H302
3-(4-chlorophenyl)-1-methoxy-1-methyl- STOT RE 2 * H373 GHS07 H373 **
urea Aquatic Acute 1 ** GHS09 H410
Aquatic H400 Wng
Chronic 1 H410
006-033-00-7 metoxuron (ISO); 243-433-2 19937-59-8 Aquatic Acute 1 H400 GHS09 H410
3-(3-chloro-4-methoxyphenyl)-1,1-dimethy- Aquatic H410 Wng
lurea Chronic 1
006-034-00-2 pebulate (ISO); 214-215-4 1114-71-2 Acute Tox. 4 * H302 GHS07 H302
N-butyl-N-ethyl-S-propylthiocarbamate Aquatic H411 GHS09 H411
Chronic 2 Wng
006-035-00-8 pirimicarb (ISO); 245-430-1 23103-98-2 Acute Tox. 3 * H301 GHS06 H301
5,6-dimethyl-2-dimethylamino-pyrimidin-4- Aquatic Acute 1 H400 GHS09 H410
yl N,N-dimethylcarbamate Aquatic H410 Dgr
Chronic 1
31.12.2008
006-036-00-3 benzthiazuron (ISO); 217-685-9 1929-88-0 Acute Tox. 4 * H302 GHS07 H302
1-benzothiazol-2-yl-3-methylurea Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-037-00-9 promecarb (ISO); 220-113-0 2631-37-0 Acute Tox. 3 * H301 GHS06 H301
EN
3-isopropyl-5-methylphenyl N-methylcar- Aquatic Acute 1 H400 GHS09 H410
bamate Aquatic H410 Dgr
Chronic 1
006-041-00-0 dimethylcarbamoyl chloride 201-208-6 79-44-7 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
Acute Tox. 3 * H331 GHS08 H331 ≥ 0,001 %
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
L 353/349
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
L 353/350
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
trichloroacetate; Eye Irrit. 2 H319 GHS07 H319
monuron-TCA Skin Irrit. 2 H315 GHS09 H315
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
006-046-00-8 bendiocarb (ISO); 245-216-8 22781-23-3 Acute Tox. 3 * H331 GHS06 H331
2,2-dimethyl-1,3-benzodioxol-4-yl Acute Tox. 3 * H301 GHS09 H301
N-methylcarbamate Acute Tox. 4 * H312 Dgr H312
Aquatic Acute 1 H410 H410
Aquatic
Chronic 1
006-048-00-9 ethiofencarb (ISO); 249-981-9 29973-13-5 Acute Tox. 4 * H302 GHS07 H302
2-(ethylthiomethyl)phenyl N-methylcarba- Aquatic Acute 1 H400 GHS09 H410
mate Aquatic H410 Wng
Chronic 1
31.12.2008
006-049-00-4 dixanthogen; 207-944-4 502-55-6 Acute Tox. 4 * H302 GHS07 H302
O,O-diethyl dithiobis(thioformate) Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic Acute 1 H400 GHS09 H410
fenuron-TCA Aquatic H410 Wng
Chronic 1
006-051-00-5 ferbam (ISO); 238-484-2 14484-64-1 Eye Irrit. 2 H319 GHS07 H319
iron tris(dimethyldithiocarbamate) STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
006-053-00-6 isoprocarb (ISO); 220-114-6 2631-40-5 Acute Tox. 4 * H302 GHS07 H302
2-isopropylphenyl N-methylcarbamate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
006-054-00-1 mexacarbate (ISO); 206-249-3 315-18-4 Acute Tox. 2 * H300 GHS06 H300
3,5-dimethyl-4-dimethylaminophenyl Acute Tox. 4 * H312 GHS09 H312
N-methylcarbamate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
006-055-00-7 xylylcarb (ISO); 219-364-9 2425-10-7 Acute Tox. 4 * H302 GHS07 H302
3,4-dimethylphenyl N-methylcarbamate; Aquatic Acute 1 H400 GHS09 H410
3,4-xylyl methylcarbamate; Aquatic H410 Wng
MPMC Chronic 1
L 353/351
006-056-00-2 metolcarb (ISO); 214-446-0 1129-41-5 Acute Tox. 4 * H302 GHS07 H302
m-tolyl methylcarbamate; Aquatic H411 GHS09 H411
MTMC Chronic 2 Wng
L 353/352
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-057-00-8 nitrapyrin (ISO); 217-682-2 1929-82-4 Acute Tox. 4 * H302 GHS07 H302
EN
2-chloro-6-trichloromethylpyridine Aquatic H411 GHS09 H411
Chronic 2 Wng
006-059-00-9 oxamyl (ISO); 245-445-3 23135-22-0 Acute Tox. 2 * H330 GHS06 H330
006-060-00-4 oxycarboxin (ISO); 226-066-2 5259-88-1 Acute Tox. 4 * H302 GHS07 H302
2,3-dihydro-6-methyl-5-(N-phenylcarba- Aquatic H412 Wng H412
moyl)-1,4-oxothiine 4,4-dioxide Chronic 3
006-061-00-X S-ethyl N-(dimethylaminopropyl)thiocarba- 243-193-9 19622-19-6 Acute Tox. 4 * H302 GHS07 H302
matehydrochloride; Aquatic H411 GHS09 H411
prothiocarb hydrochloride Chronic 2 Wng
006-063-00-0 thiobencarb (ISO); 248-924-5 28249-77-6 Acute Tox. 4 * H302 GHS07 H302
S-4-chlorobenzyl diethylthiocarbamate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
006-064-00-6 thiofanox (ISO); 254-346-4 39196-18-4 Acute Tox. 1 H310 GHS06 H310
3,3-dimethyl-1-(methylthio)butanone-O-(N- Acute Tox. 2 * H300 GHS09 H300
31.12.2008
methylcarbamoyl)oxime Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H311 GHS09 H311
triamid Aquatic H411 Dgr H411
Chronic 2
006-066-00-7 vernolate (ISO); 217-681-7 1929-77-7 Acute Tox. 4 * H302 GHS07 H302
S-propyl dipropylthiocarbamate Aquatic H411 GHS09 H411
Chronic 2 Wng
006-071-00-4 cyclooct-4-en-1-yl methyl carbonate 401-620-8 87731-18-8 Skin Sens. 1 H317 GHS07 H317
Wng
006-072-00-X prosulfocarb (ISO); 401-730-6 52888-80-9 Acute Tox. 4 * H302 GHS07 H302
S-benzyl N,N-dipropylthiocarbamate Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
L 353/353
006-073-00-5 3-(dimethylamino)propylurea 401-950-2 31506-43-1 Eye Dam. 1 H318 GHS05 H318
Dgr
L 353/354
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-074-00-0 2-(3-(prop-1-en-2-yl)phenyl)prop-2-yl iso- 402-440-2 2094-99-7 Acute Tox. 2 * H330 GHS06 H330
cyanate
EN
Skin Corr. 1B H314 GHS08 H314
STOT RE 2 * H373 GHS05 H373 **
Resp. Sens. 1 ** GHS09 H334
Skin Sens. 1 H334 Dgr H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
006-080-00-3 tetramethylthiuram monosulphide 202-605-7 97-74-5 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
006-081-00-9 zinc bis(dibutyldithiocarbamate) 205-232-8 136-23-2 Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-082-00-4 zinc bis(diethyldithiocarbamate) 238-270-9 14324-55-1 Acute Tox. 4 * H302 GHS07 H302
EN
Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
006-084-00-5 carbosulfan (ISO); 259-565-9 55285-14-8 Acute Tox. 3 * H331 GHS06 H331
2,3-dihydro-2,2-dimethyl-7-benzofuryl Acute Tox. 3 * H301 GHS09 H301
[(dibutylamino)thio]methylcarbamate Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
006-085-00-0 fenobucarb (ISO); 223-188-8 3766-81-2 Acute Tox. 4 * H302 GHS07 H302
2-butylphenyl methylcarbamate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
006-086-00-6 ethyl [2-(4-phenoxyphenoxy)ethyl]carba- 276-696-7 72490-01-8 Aquatic Acute 1 H400 GHS09 H410
L 353/355
mate; Aquatic H410 Wng
fenoxycarb Chronic 1
L 353/356
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
006-087-00-1 2,3-dihydro-2,2-dimethyl-7-benzofuryl 2,4- 265-974-3 65907-30-4 Acute Tox. 2 * H330 GHS06 H330
EN
dimethyl-6-oxa-5-oxo-3-thia-2,4-diazade- Acute Tox. 3 * H301 GHS08 H301
canoate; STOT RE 2 * H373 GHS09 H373 **
furathiocarb Eye Irrit. 2 ** Dgr H319
Skin Irrit. 2 H319 H315
Skin Sens. 1 H315 H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
006-089-00-2 chlorine dioxide 233-162-8 10049-04-4 Ox. Gas 1 H270 GHS03 H270 EUH006 M = 1000 U
Press. Gas H330 GHS04 H330
Acute Tox. 2 * H314 GHS06 H314
Skin Corr. 1B H400 GHS05 H400
Aquatic Acute 1 GHS09
Dgr
006-089-01-X chlorine dioxide . . . % 233-162-8 10049-04-4 Acute Tox. 3 * H301 GHS06 H301 Skin Corr. 1B; B
Skin Corr. 1B H314 GHS05 H314 H314: C ≥ 10 %
Aquatic Acute 1 H400 GHS09 H400 Skin Irrit. 2;
Dgr H315: 3 % ≤ C
< 10 %
Eye Irrit. 2; H319:
0,3 % ≤ C < 10 %
STOT SE 3;
H335: C ≥ 3 %
M = 10
006-090-00-8 2-(3-iodoprop-2-yn-1-yloxy)ethyl phenyl- 408-010-0 88558-41-2 Acute Tox. 4 * H332 GHS05 H332
31.12.2008
carbamate Eye Dam. 1 H318 GHS07 H318
Aquatic H412 Dgr H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
007-001-00-5 ammonia, anhydrous 231-635-3 7664-41-7 Flam. Gas 2 H221 GHS04 H221 U
EN
Press. Gas H331 GHS06 H331
Acute Tox. 3 * H314 GHS05 H314
Skin Corr. 1B H400 GHS09 H400
Aquatic Acute 1 Dgr
007-001-01-2 ammonia ….% 215-647-6 1336-21-6 Skin Corr. 1B H314 GHS05 H314 STOT SE 3; B
Aquatic Acute 1 H400 GHS09 H400 H335: C ≥ 5 %
Dgr
007-003-00-6 chlormequat chloride (ISO); 213-666-4 999-81-5 Acute Tox. 4 * H312 GHS07 H312
2-chloroethyltrimethylammonium chloride Acute Tox. 4 * H302 Wng H302
007-004-00-1 nitric acid … % 231-714-2 7697-37-2 Ox. Liq. 3 H272 GHS03 H272 Skin Corr. 1A; B
Skin Corr. 1A H314 GHS05 H314 H314: C ≥ 20 %
Dgr Skin Corr. 1B;
H314: 5 % ≤ C
< 20 %
Ox. Liq. 3; H272:
C ≥ 65 %
007-006-00-2 ethyl nitrite 203-722-6 109-95-5 Flam. Gas 1 H220 GHS02 H220 U
Press. Gas H332 GHS04 H332
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Acute Tox. 4 *
L 353/357
007-007-00-8 ethyl nitrate 210-903-3 625-58-1 Unst. Expl. H200 GHS01 H200
Dgr
L 353/358
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
007-008-00-3 hydrazine 206-114-9 302-01-2 Flam. Liq. 3 H226 GHS02 H226 Skin Corr. 1B;
EN
Carc. 1B H350 GHS06 H350 H314: C ≥ 10 %
Acute Tox. 3 * H331 GHS08 H331 Skin Irrit. 2;
Acute Tox. 3 * H311 GHS05 H311 H315: 3 % ≤ C
< 10 %
Acute Tox. 3 * H301 GHS09 H301
Eye Irrit. 2; H319:
Skin Corr. 1B H314 Dgr H314 3 % ≤ C < 10 %
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
007-010-00-4 sodium nitrite 231-555-9 7632-00-0 Ox. Sol. 3 H272 GHS03 H272 *
Acute Tox. 3 * H301 GHS06 H301
Aquatic Acute 1 H400 GHS09 H400
Dgr
007-011-00-X potassium nitrite 231-832-4 7758-09-0 Ox. Sol. 2 H272 GHS03 H272 *
Acute Tox. 3 * H301 GHS06 H301
Aquatic Acute 1 H400 GHS09 H400
Dgr
31.12.2008
Aquatic H411 Dgr H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
007-013-00-0 1,2-dimethylhydrazine — 540-73-8 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
EN
Acute Tox. 3 * H331 GHS08 H331 ≥ 0,01 %
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic H411 H411
Chronic 2
007-016-00-7 butyl nitrite 208-862-1 544-16-1 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H301 Dgr H301
007-017-00-2 isobutyl nitrite 208-819-7 542-56-3 Flam. Liq. 2 H225 GHS02 H225
Carc. 1B H350 GHS08 H350
Muta. 2 H341 GHS07 H341
L 353/359
Acute Tox. 4 * H332 Dgr H332
Acute Tox. 4 * H302 H302
L 353/360
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
007-018-00-8 sec-butyl nitrite 213-104-8 924-43-6 Flam. Liq. 2 H225 GHS02 H225
EN
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
007-019-00-3 tert-butyl nitrite 208-757-0 540-80-7 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
007-020-00-9 pentyl nitrite; [1] 207-332-7 463-04-7 [1] Flam. Liq. 2 H225 GHS02 H225
31.12.2008
Aquatic Acute 1 H318 Dgr H410
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
007-025-00-6 (4-hydrazinophenyl)-N-methylmethanesul- 406-090-1 81880-96-8 Muta. 2 H341 GHS06 H341
fonamide hydrochloride Acute Tox. 3 * H301 GHS08 H301
STOT RE 1 H372 GHS09 H372 **
Skin Sens. 1 ** Dgr H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
L 353/361
Dgr
L 353/362
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
008-003-00-9 hydrogen peroxide solution … % 231-765-0 7722-84-1 Ox. Liq. 1 H271 GHS03 H271 Ox. Liq. 1; H271: B
EN
Acute Tox. 4 * H332 GHS05 H332 C ≥ 70 %****
Acute Tox. 4 * H302 GHS07 H302 Ox. Liq. 2; H272:
Skin Corr. 1A H314 Dgr H314 50 % ≤ C
< 70 % ****
*
Skin Corr. 1A;
H314: C ≥ 70 %
Skin Corr. 1B;
H314: 50 % ≤ C
< 70 %
Skin Irrit. 2;
009-002-00-6 hydrogen fluoride 231-634-8 7664-39-3 Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 GHS05 H310
Acute Tox. 2 * H300 Dgr H300
Skin Corr. 1A H314 H314
009-003-00-1 hydrofluoric acid … % 231-634-8 7664-39-3 Acute Tox. 2 * H330 GHS06 H330 Skin Corr. 1A; B
Acute Tox. 1 H310 GHS05 H310 H314: C ≥ 7 %
Acute Tox. 2 * H300 Dgr H300 Skin Corr. 1B;
H314: 1 % ≤ C
31.12.2008
Skin Corr. 1A H314 H314
< 7%
Eye Irrit. 2; H319:
0,1 % ≤ C < 1 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
009-004-00-7 sodium fluoride 231-667-8 7681-49-4 Acute Tox. 3 * H301 GHS06 H301 EUH032
EN
Eye Irrit. 2 H319 Dgr H319
Skin Irrit. 2 H315 H315
009-005-00-2 potassium fluoride 232-151-5 7789-23-3 Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 Dgr H311
Acute Tox. 3 * H301 H301
009-006-00-8 ammonium fluoride 235-185-9 12125-01-8 Acute Tox. 3 * H331 GHS06 H331
009-007-00-3 sodium bifluoride; 215-608-3 1333-83-1 Acute Tox. 3 * H301 GHS06 H301 *
sodium hydrogen difluoride Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B;
Dgr H314: C ≥ 1 %
Skin Irrit. 2;
H315: 0,1 % ≤ C
< 1%
Eye Irrit. 2; H319:
0,1 % ≤ C < 1 %
009-008-00-9 potassium bifluoride; 232-156-2 7789-29-9 Acute Tox. 3 * H301 GHS06 H301 *
potassium hydrogen difluoride Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B;
Dgr H314: C ≥ 1 %
Skin Irrit. 2;
H315: 0,1 % ≤ C
< 1%
Eye Irrit. 2; H319:
0,1 % ≤ C < 1 %
009-009-00-4 ammonium bifluoride; 215-676-4 1341-49-7 Acute Tox. 3 * H301 GHS06 H301 *
ammonium hydrogen difluoride Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B;
Dgr H314: C ≥ 1 %
Skin Irrit. 2;
H315: 0,1 % ≤ C
L 353/363
< 1%
Eye Irrit. 2; H319:
0,1 % ≤ C < 1 %
L 353/364
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
009-010-00-X fluoroboric acid ... % 240-898-3 16872-11-0 Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B; B
EN
Dgr H314: C ≥ 25 %
Skin Irrit. 2;
H315: 10 % ≤ C
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
009-011-00-5 fluorosilicic acid ... % 241-034-8 16961-83-4 Skin Corr. 1B H314 GHS05 H314 B
Dgr
009-013-00-6 fluorosilicates, with the exception of those — — Acute Tox. 4 * H302 GHS07 H302 * A
specified elsewhere in this Annex Wng
009-015-00-7 sulphuryl difluoride 220-281-5 2699-79-8 Press. Gas H331 GHS04 H331 U
Acute Tox. 3 * H373 GHS06 H373 **
31.12.2008
STOT RE 2 * ** GHS08 H400
Aquatic Acute 1 H400 GHS09
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
cryolite 239-148-8 15096-52-3 Acute Tox. 4 * ** GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
Aquatic H302 Dgr H411
Chronic 2 H411
009-017-00-8 potassium mu-fluoro-bis(triethylaluminium) 400-040-2 12091-08-6 Flam. Sol. 1 H228 GHS02 H228 EUH014 T
Water-react. 1 H270 GHS05 H270
Skin Corr. 1A H314 GHS07 H314
Acute Tox. 4 * H332 Dgr H332
011-002-00-6 sodium hydroxide; 215-185-5 1310-73-2 Skin Corr. 1A H314 GHS05 H314 Skin Corr. 1A;
caustic soda Dgr H314: C ≥ 5 %
Skin Corr. 1B;
H314: 2 % ≤ C
< 5%
Skin Irrit. 2;
H315: 0,5 % ≤ C
< 2%
Eye Irrit. 2; H319:
0,5 % ≤ C < 2 %
011-003-00-1 sodium peroxide 215-209-4 1313-60-6 Ox. Sol. 1 H271 GHS03 H271
Skin Corr. 1A H314 GHS05 H314
Dgr
011-004-00-7 sodium azide 247-852-1 26628-22-8 Acute Tox. 2 * H300 GHS06 H300 EUH032
L 353/365
Aquatic Acute 1 H400 GHS09 H400
Aquatic H410 Dgr H410
Chronic 1
L 353/366
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
011-005-00-2 sodium carbonate 207-838-8 497-19-8 Eye Irrit. 2 H319 GHS07 H319
Wng
EN
011-006-00-8 sodium cyanate 213-030-6 917-61-3 Acute Tox. 4 * H302 GHS07 H302
Aquatic H412 Wng H412
Chronic 3
012-002-00-9 magnesium, powder or turnings 231-104-6 — Flam. Sol. 1 H228 GHS02 H228 T
Water-react. 2 H261 Dgr H261
Self-heat. 1 H252 H252
013-001-00-6 aluminium powder (pyrophoric) 231-072-3 7429-90-5 Water-react. 2 H261 GHS02 H261 T
Pyr. Sol. 1 H250 Dgr H250
013-003-00-7 aluminium chloride, anhydrous 231-208-1 7446-70-0 Skin Corr. 1B H314 GHS05 H314
Dgr
31.12.2008
013-005-00-8 diethyl(ethyldimethylsilanolato)aluminium 401-160-8 55426-95-4 Water-react. 1 H260 GHS02 H260 EUH014
Pyr. Liq. 1 H250 GHS05 H250
Skin Corr. 1A H314 Dgr H314
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
aminoethanolato)(1-methoxypropan-2- Eye Dam. 1 H318 GHS05 H318
olato)aluminium(III), dimerised Dgr
013-008-00-4 di-n-octylaluminium iodide 408-190-0 7585-14-0 Pyr. Liq. 1 H250 GHS02 H250 EUH014
013-009-00-X sodium (n-butyl)x(ethyl)y-1,5-dihydro)alu- 418-720-2 — Flam. Sol. 1 H228 GHS02 H228 EUH014 T
minate x = 0,5 y = 1,5 Water-react. 1 H260 GHS05 H260
Pyr. Sol. 1 H250 GHS07 H250
Acute Tox. 4 * H332 Dgr H332
Skin Corr. 1A H314 H314
014-001-00-9 trichlorosilane 233-042-5 10025-78-2 Flam. Liq. 1 H224 GHS02 H224 EUH014 * T
Pyr. Liq. 1 H250 GHS05 H250 EUH029 STOT SE 3;
Acute Tox. 4 * H332 GHS07 H332 H335: C ≥ 1 %
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1A H314 H314
014-002-00-4 silicon tetrachloride 233-054-0 10026-04-7 Eye Irrit. 2 H319 GHS07 H319 EUH014
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
L 353/367
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
L 353/368
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
014-004-00-5 trichloro(methyl)silane; 200-902-6 75-79-6 Flam. Liq. 2 H225 GHS02 H225 EUH014 Skin Irrit. 2;
H315: C ≥ 1 %
EN
methyltrichlorosilane Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335 Eye Irrit. 2; H319:
Skin Irrit. 2 H315 H315 C ≥ 1%
STOT SE 3;
H335: C ≥ 1 %
014-005-00-0 tetraethyl silicate; 201-083-8 78-10-4 Flam. Liq. 3 H226 GHS02 H226
ethyl silicate Acute Tox. 4 * H332 GHS07 H332
Eye Irrit. 2 H319 Wng H319
STOT SE 3 H335 H335
014-010-00-8 disodium metasilicate 229-912-9 6834-92-0 Skin Corr. 1B H314 GHS05 H314
STOT SE 3 H335 GHS07 H335
Dgr
31.12.2008
014-012-00-9 bis(3-(trimethoxysilyl)propyl)amine 403-480-3 — Eye Dam. 1 H318 GHS05 H318
Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1B H314 GHS09 H314
Aquatic H411 Dgr H411
Chronic 2
014-014-00-X etacelasil (ISO); 253-704-7 37894-46-5 Repr. 1B H360- GHS08 H360D ***
6-(2-chloroethyl)-6-(2-methoxyethoxy)- Acute Tox. 4 * D *** GHS07 H302
2,5,7,10-tetraoxa-6-silaundecane STOT RE 2 * H302 Dgr H373 **
H373
**
014-016-00-0 reaction mass of: 1,3-dihex-5-en-1-yl- 406-490-6 — Aquatic H411 GHS09 H411
1,1,3,3-tetramethyldisiloxane; Chronic 2
1,3-dihex-n-en-1-yl-1,1,3,3-tetramethyldisi-
loxane
014-019-00-7 reaction mass of: 4-[[bis-(4-fluorophenyl) 403-250-2 — Carc. 2 H351 GHS08 H351
methylsilyl]methyl]-4H-1,2,4-triazole; Repr. 1B H360- GHS07 H360D ***
1-[[bis-(4-fluorophenyl)methylsilyl]methyl]- Acute Tox. 4 * D *** GHS09 H302
1H-1,2,4-triazole Aquatic H302 Dgr H411
Chronic 2 H411
L 353/369
014-020-00-2 bis(1,1-dimethyl-2-propynyloxy)dimethylsi- 414-960-7 53863-99-3 Acute Tox. 4 * H332 GHS07 H332
lane Wng
L 353/370
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
014-021-00-8 tris(isopropenyloxy)phenyl silane 411-340-8 52301-18-5 Aquatic Acute 1 H400 GHS09 H400
EN
Aquatic H410 Wng H410
Chronic 1
014-022-00-3 reaction product of: (2-hydroxy-4-(3-prope- 401-530-9 — Flam. Sol. 1 H228 GHS02 H228 T
noxy)benzophenone and triethoxysilane) STOT SE 1 H370 GHS08 H370 **
with (hydrolysis product of silica and Acute Tox. 4 * ** GHS07 H332
methyltrimethoxysilane) H332
Acute Tox. 4 * Dgr H312
Acute Tox. 4 * H312 H302
H302
31.12.2008
dimethoxysilyloxy-ω-[3(1-oxoprop-2-enyl)- Wng
1-oxypropyl]dimethoxysilyl poly(dimethyl-
siloxane)
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
pentan-2-one)oxime] Acute Tox. 4 * *** GHS07 H302
STOT RE 2 * H302 Wng H373 **
H373
**
015-001-00-1 white phosphorus 231-768-7 12185-10-3 Pyr. Sol. 1 H250 GHS02 H250
Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 2 * H300 GHS05 H300
Skin Corr. 1A H314 GHS09 H314
Aquatic Acute 1 H400 Dgr H400
015-002-00-7 red phosphorus 231-768-7 7723-14-0 Flam. Sol. 1 H228 GHS02 H228
Aquatic H412 Dgr H412
Chronic 3
015-003-00-2 calcium phosphide; 215-142-0 1305-99-3 Water-react. 1 H260 GHS02 H260 EUH029 T
L 353/371
tricalcium diphosphide Acute Tox. 2 * H300 GHS06 H300
Aquatic Acute 1 H400 GHS09 H400
Dgr
L 353/372
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-004-00-8 aluminium phosphide 244-088-0 20859-73-8 Water-react. 1 H260 GHS02 H260 EUH029 T
EN
Acute Tox. 2 * H300 GHS06 H300 EUH032
Aquatic Acute 1 H400 GHS09 H400
Dgr
015-005-00-3 magnesium phosphide; 235-023-7 12057-74-8 Water-react. 1 H260 GHS02 H260 EUH029 T
trimagnesium diphosphide Acute Tox. 2 * H300 GHS06 H300
Aquatic Acute 1 H400 GHS09 H400
Dgr
015-007-00-4 phosphorus trichloride 231-749-3 7719-12-2 Acute Tox. 2 * H330 GHS06 H330 EUH014
Acute Tox. 2 * H300 GHS08 H300 EUH029
STOT RE 2 * H373 GHS05 H373 **
Skin Corr. 1A ** Dgr H314
H314
015-008-00-X phosphorus pentachloride 233-060-3 10026-13-8 Acute Tox. 2 * H330 GHS06 H330 EUH014
Acute Tox. 4 * H302 GHS08 H302 EUH029
STOT RE 2 * H373 GHS05 H373 **
Skin Corr. 1B ** Dgr H314
H314
015-009-00-5 phosphoryl trichloride 233-046-7 10025-87-3 Acute Tox. 2 * H330 GHS06 H330 EUH014
STOT RE 1 H372 GHS08 H372 ** EUH029
Acute Tox. 4 * ** GHS05 H302
Skin Corr. 1A H302 Dgr H314
H314
31.12.2008
015-010-00-0 phosphorus pentoxide 215-236-1 1314-56-3 Skin Corr. 1A H314 GHS05 H314
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-011-00-6 phosphoric acid ... %, orthophosphoric acid 231-633-2 7664-38-2 Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B; B
EN
... % Dgr H314: C ≥ 25 %
Skin Irrit. 2;
H315: 10 % ≤ C
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
015-012-00-1 tetraphosphorus trisulphide; 215-245-0 1314-85-8 Flam. Sol. 2 H228 GHS02 H228 T
phosphorus sesquisulphid Water-react. 1 H260 GHS07 H260
Acute Tox. 4 * H302 GHS09 H302
015-013-00-7 triethyl phosphate 201-114-5 78-40-0 Acute Tox. 4 * H302 GHS07 H302
Wng
015-015-00-8 tricresyl phosphate (o-o-o-, o-o-m-, o-o-p-, 201-103-5 78-30-8 STOT SE 1 H370 GHS08 H370 ** STOT SE 1; C
o-m-m-, o-m-p-, o-p-p-); Aquatic ** GHS09 H411 H370: C ≥ 1 %
tritolyl phosphate (o-o-o-, o-o-m-, o-o-p-, Chronic 2 H411 Dgr STOT SE 2;
o-m-m-, o-m-p-, o-p-p-); H371: 0,2 % ≤ C
< 1%
015-016-00-3 tricresyl phosphate (m-m-m-, m-m-p-, m-p-p-, 201-105-6 78-32-0 Acute Tox. 4 * H312 GHS07 H312 * C
p-p-p-); Acute Tox. 4 * H302 GHS09 H302
tritolyl phosphate (m-m-m-, m-m-p-, m-p-p-, Aquatic H411 Wng H411
p-p-p-); Chronic 2
015-019-00-X dichlorvos (ISO); 200-547-7 62-73-7 Acute Tox. 2 * H330 GHS06 H330
2,2-dichlorovinyl dimethyl phosphate Acute Tox. 3 * H311 GHS09 H311
L 353/373
Acute Tox. 3 * H301 Dgr H301
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H400
L 353/374
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-020-00-5 mevinphos (ISO); 232-095-1 7786-34-7 Acute Tox. 1 H310 GHS06 H310 M = 10000
EN
2-methoxycarbonyl-1-methylvinyl dimethyl Acute Tox. 2 * H300 GHS09 H300
phosphate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-021-00-0 trichlorfon (ISO); 200-149-3 52-68-6 Acute Tox. 4 * H302 GHS07 H302 M = 1000
dimethyl 2,2,2-trichloro-1-hydroxyethyl- Skin Sens. 1 H317 GHS09 H317
phosphonate Aquatic Acute 1 H400 Wng H400
Aquatic H410 H410
015-025-00-2 TEPP (ISO); 203-495-3 107-49-3 Acute Tox. 1 H310 GHS06 H310
tetraethyl pyrophosphate Acute Tox. 2 * H300 GHS09 H300
Aquatic Acute 1 H400 Dgr H400
31.12.2008
015-026-00-8 schradan (ISO); 205-801-0 152-16-9 Acute Tox. 1 H310 GHS06 H310
octamethylpyrophosphoramide Acute Tox. 2 * H300 Dgr H300
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-027-00-3 sulfotep (ISO); 222-995-2 3689-24-5 Acute Tox. 1 H310 GHS06 H310 M = 1000
EN
O,O,O,O-tetraethyl dithiopyrophosphate Acute Tox. 2 * H300 GHS09 H300
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-028-00-9 demeton-O (ISO); 206-053-8 298-03-3 Acute Tox. 1 H310 GHS06 H310
O,O-diethyl-O-2-ethylthioethyl phosphor- Acute Tox. 2 * H300 GHS09 H300
othioate Aquatic Acute 1 H400 Dgr H400
015-030-00-X demeton-O-methyl (ISO); 212-758-1 867-27-6 Acute Tox. 3 * H301 GHS06 H301
O-2-ethylthioethyl O,O-dimethyl phosphor- Dgr
othioate
015-031-00-5 demeton-S-methyl (ISO); 213-052-6 919-86-8 Acute Tox. 3 * H311 GHS06 H311
S-2-ethylthioethyl dimethyl phosphorothio- Acute Tox. 3 * H301 GHS09 H301
ate Aquatic H411 Dgr H411
Chronic 2
015-032-00-0 prothoate (ISO); 218-893-2 2275-18-5 Acute Tox. 1 H310 GHS06 H310
O,O-diethyl isopropylcarbamoylmethyl Acute Tox. 2 * H300 Dgr H300
phosphorodithioate Aquatic H412 H412
Chronic 3
015-033-00-6 phorate (ISO); 206-052-2 298-02-2 Acute Tox. 1 H310 GHS06 H310 M = 1000
O,O-diethyl ethylthiomethyl phosphoro- Acute Tox. 2 * H300 GHS09 H300
dithioate
L 353/375
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/376
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-034-00-1 parathion (ISO); 200-271-7 56-38-2 Acute Tox. 2 * H330 GHS06 H330 M = 100
EN
O,O-diethyl O-4-nitrophenyl phospho- Acute Tox. 2 * H300 GHS08 H300
rothioate Acute Tox. 3 * H311 GHS09 H311
STOT RE 1 H372 Dgr H372 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
015-035-00-7 parathion — methyl (ISO); 206-050-1 298-00-0 Flam. Liq. 3 H226 GHS02 H226 M = 100
015-036-00-2 O-ethyl O-4-nitrophenyl phenylphospho- 218-276-8 2104-64-5 Acute Tox. 1 H310 GHS06 H310
nothioate; Acute Tox. 2 * H300 GHS09 H300
EPN Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-037-00-8 phenkapton (ISO); 218-892-7 2275-14-1 Acute Tox. 3 * H331 GHS06 H331
S-(2,5-dichlorophenylthiomethyl) O,O- Acute Tox. 3 * H311 GHS09 H311
diethyl phosphorodithioate Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-038-00-3 coumaphos (ISO); 200-285-3 56-72-4 Acute Tox. 2 * H300 GHS06 H300
O-3-chloro-4-methylcoumarin-7-yl O,O- Acute Tox. 4 * H312 GHS09 H312
31.12.2008
diethyl phosphorothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-039-00-9 azinphos-methyl (ISO); 201-676-1 86-50-0 Acute Tox. 2 * H330 GHS06 H330
EN
O,O-dimethyl-4-oxobenzotriazin-3- Acute Tox. 2 * H300 GHS09 H300
ylmethyl phosphorodithioate Acute Tox. 3 * H311 Dgr H311
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-040-00-4 diazinon (ISO); 206-373-8 333-41-5 Acute Tox. 4 * H302 GHS07 H302
015-041-00-X malathion (ISO); 204-497-7 121-75-5 Acute Tox. 4 * H302 GHS07 H302 M = 100
1,2-bis (ethoxycarbonyl) ethyl O,O-dimethyl Aquatic Acute 1 H400 GHS09 H400
phosphorodithioate Aquatic H410 Wng H410
Chronic 1
015-042-00-5 chlorthion 207-902-5 500-28-7 Acute Tox. 4 * H332 GHS07 H332 M = 100
O-(3-chloro-4-nitrophenyl) O,O-dimethyl Acute Tox. 4 * H312 GHS09 H312
phosphorothioate Acute Tox. 4 * H302 Wng H302
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-044-00-6 carbophenothion (ISO); 212-324-1 786-19-6 Acute Tox. 3 * H311 GHS06 H311
4-chlorophenylthiomethyl O,O-diethyl Acute Tox. 3 * H301 GHS09 H301
phosphorodithioate
L 353/377
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/378
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-045-00-1 mecarbam (ISO); 219-993-9 2595-54-2 Acute Tox. 3 * H311 GHS06 H311
EN
N-ethoxycarbonyl-N-methylcarbamoyl- Acute Tox. 3 * H301 GHS09 H301
methyl O,O-diethyl phosphorodithioate Aquatic Acute 1 H400 Dgr H400
Aquatic H410 H410
Chronic 1
015-049-00-3 endothion (ISO); 220-472-3 2778-04-3 Acute Tox. 3 * H311 GHS06 H311
S-5-methoxy-4-oxopyran-2-ylmethyl Acute Tox. 3 * H301 Dgr H301
dimethyl phosphorothioate
015-050-00-9 thiometon (ISO); 211-362-6 640-15-3 Acute Tox. 3 * H301 GHS06 H301
S-2-ethylthioethyl O,O-dimethyl phospho- Acute Tox. 4 * H312 Dgr H312
rodithioate
31.12.2008
015-051-00-4 dimethoate (ISO); 200-480-3 60-51-5 Acute Tox. 4 * H312 GHS07 H312
O,O-dimethyl methylcarbamoylmethyl Acute Tox. 4 * H302 Wng H302
phosphorodithioate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-052-00-X fenchlorphos (ISO); 206-082-6 299-84-3 Acute Tox. 4 * H312 GHS07 H312
EN
O,O-dimethyl O-2,4,5-trichlorophenyl Acute Tox. 4 * H302 GHS09 H302
phosphorothioate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
015-053-00-5 menazon (ISO); 201-123-4 78-57-9 Acute Tox. 4 * H302 GHS07 H302
S-[(4,6-diamino-1,3,5-triazin-2-yl)methyl] Aquatic H412 Wng H412
O,O-dimethyl phosphorodithioate Chronic 3
015-055-00-6 naled (ISO); 206-098-3 300-76-5 Acute Tox. 4 * H312 GHS07 H312 M = 1000
1,2-dibromo-2,2-dichloroethyl dimethyl Acute Tox. 4 * H302 GHS09 H302
phosphate Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H400
015-056-00-1 azinphos-ethyl (ISO); 220-147-6 2642-71-9 Acute Tox. 2 * H300 GHS06 H300
O,O-diethyl 4-oxobenzotriazin-3-ylmethyl Acute Tox. 3 * H311 GHS09 H311
phosphorodithioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-057-00-7 formothion (ISO); 219-818-6 2540-82-1 Acute Tox. 4 * H312 GHS07 H312
N-formyl-N-methylcarbamoylmethyl O,O- Acute Tox. 4 * H302 Wng H302
dimethyl phosphorodithioate
015-058-00-2 morphothion (ISO); 205-628-0 144-41-2 Acute Tox. 3 * H331 GHS06 H331
O,O-dimethyl-S-(morpholinocarbonyl- Acute Tox. 3 * H311 GHS09 H311
methyl) phosphorodithioate Acute Tox. 3 * H301 Dgr H301
L 353/379
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/380
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-059-00-8 vamidothion (ISO); 218-894-8 2275-23-2 Acute Tox. 3 * H301 GHS06 H301
EN
O,O-dimethyl S-2-(1-methylcarbamoy- Acute Tox. 4 * H312 GHS09 H312
lethylthio) ethyl phosphorothioate Aquatic Acute 1 H400 Dgr H400
015-060-00-3 disulfoton (ISO); 206-054-3 298-04-4 Acute Tox. 1 H310 GHS06 H310
O,O-diethyl 2-ethylthioethyl phosphoro- Acute Tox. 2 * H300 GHS09 H300
dithioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-063-00-X dioxathion (ISO); 201-107-7 78-34-2 Acute Tox. 2 * H330 GHS06 H330 M = 1000
1,4-dioxan-2,3-diyl-O,O,O',O'-tetraethyl di Acute Tox. 2 * H300 GHS09 H300
(phosphorodithioate) Acute Tox. 3 * H311 Dgr H311
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-064-00-5 bromophos-ethyl (ISO); 225-399-0 4824-78-6 Acute Tox. 3 * H301 GHS06 H301
O-4-bromo-2,5-dichlorophenyl O,O-diethyl Acute Tox. 4 * H312 GHS09 H312
phosphorothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
31.12.2008
Acute Tox. 2 * H300 Dgr H300
Aquatic H411 H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-066-00-6 omethoate (ISO); 214-197-8 1113-02-6 Acute Tox. 3 * H301 GHS06 H301
EN
O,O-dimethyl S-methylcarbamoylmethyl Acute Tox. 4 * H312 GHS09 H312
phosphorothioate Aquatic Acute 1 H400 Dgr H400
015-067-00-1 phosalone (ISO); 218-996-2 2310-17-0 Acute Tox. 3 * H301 GHS06 H301
S-(6-chloro-2-oxobenzoxazolin-3-ylmethyl) Acute Tox. 4 * H312 GHS09 H312
O,O-diethyl phosphorodithioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-069-00-2 methidathion (ISO); 213-449-4 950-37-8 Acute Tox. 2 * H300 GHS06 H300
2,3-dihydro-5-methoxy-2-oxo-1,3,4-thiadia- Acute Tox. 4 * H312 GHS09 H312
zol-3-ylmethyl-O,O-dimethylphosphoro- Aquatic Acute 1 H400 Dgr H410
dithioate Aquatic H410
Chronic 1
015-070-00-8 cyanthoate (ISO); 223-099-4 3734-95-0 Acute Tox. 2 * H300 GHS06 H300
S-(N-(1-cyano-1-methylethyl)carbamoyl- Acute Tox. 3 * H311 Dgr H311
methyl) O,O-diethyl phosphorothioate
015-071-00-3 chlorfenvinphos (ISO); 207-432-0 470-90-6 Acute Tox. 2 * H300 GHS06 H300
2-chloro-1-(2,4 dichlorophenyl) vinyl Acute Tox. 3 * H311 GHS09 H311
diethyl phosphate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/381
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/382
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-073-00-4 dicrotophos (ISO); 205-494-3 141-66-2 Acute Tox. 2 * H300 GHS06 H300
EN
(Z)-2-dimethylcarbamoyl-1-methylvinyl Acute Tox. 3 * H311 GHS09 H311
dimethyl phosphate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-074-00-X crufomate (ISO); 206-083-1 299-86-5 Acute Tox. 4 * H312 GHS07 H312
4-tert-butyl-2-chlorophenyl methyl methyl- Acute Tox. 4 * H302 GHS09 H302
phosphoramidate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
015-078-00-1 demeton-S-methylsulphon (ISO); 241-109-5 17040-19-6 Acute Tox. 3 * H301 GHS06 H301
S-2-ethylsulphonylethyl dimethyl phos- Acute Tox. 4 * H312 GHS09 H312
phorothioate Aquatic H411 Dgr H411
Chronic 2
015-079-00-7 acephate (ISO); 250-241-2 30560-19-1 Acute Tox. 4 * H302 GHS07 H302
O,S-dimethyl acetylphosphoramidothioate Wng
31.12.2008
015-080-00-2 amidithion (ISO); — 919-76-6 Acute Tox. 4 * H302 GHS07 H302
2-methoxyethylcarbamoylmethyl O,O- Wng
dimethyl phosphorodithioate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-081-00-8 O,O,O',O'-tetrapropyl dithiopyrophosphate 221-817-0 3244-90-4 Acute Tox. 4 * H312 GHS07 H312
EN
Acute Tox. 4 * H302 GHS09 H302
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
015-082-00-3 azothoate (ISO); 227-419-3 5834-96-8 Acute Tox. 4 * H332 GHS07 H332
O-4-(4-chlorophenylazo)phenyl O,O- Acute Tox. 4 * H302 Wng H302
dimethyl phosphorothioate
015-084-00-4 chlorpyrifos (ISO); 220-864-4 2921-88-2 Acute Tox. 3 * H301 GHS06 H301 M = 10000
O,O-diethyl O-3,5,6-trichloro-2-pyridyl Aquatic Acute 1 H400 GHS09 H400
phosphorothioate Aquatic H410 Dgr H410
Chronic 1
015-085-00-X chlorphonium chloride (ISO); 204-105-4 115-78-6 Acute Tox. 3 * H301 GHS06 H301
tributyl (2,4-dichlorobenzyl) phosphonium Acute Tox. 4 * H312 Dgr H312
chloride Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
015-087-00-0 cyanophos (ISO); 220-130-3 2636-26-2 Acute Tox. 4 * H312 GHS07 H312
O-4-cyanophenyl O,O-dimethyl phosphor- Acute Tox. 4 * H302 GHS09 H302
othioate
L 353/383
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
L 353/384
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-088-00-6 dialifos (ISO); 233-689-3 10311-84-9 Acute Tox. 2 * H300 GHS06 H300
EN
2-chloro-1-phthalimidoethyl O,O-diethyl Acute Tox. 3 * H311 GHS09 H311
phosphorodithioate Aquatic Acute 1 H400 Dgr H400
Aquatic H410 H410
Chronic 1
015-089-00-1 ethoate-methyl (ISO); 204-121-1 116-01-8 Acute Tox. 4 * H312 GHS07 H312
ethylcarbamoylmethyl O,O-dimethyl phos- Acute Tox. 4 * H302 Wng H302
phorodithioate
015-091-00-2 fonofos (ISO); 213-408-0 944-22-9 Acute Tox. 1 H310 GHS06 H310
O-ethyl phenyl ethylphosphonodithioate Acute Tox. 2 * H300 GHS09 H300
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-092-00-8 phosacetim (ISO); 223-874-7 4104-14-7 Acute Tox. 1 H310 GHS06 H310
O,O-bis(4-chlorophenyl) N-acetimidoylpho- Acute Tox. 2 * H300 GHS09 H300
sphoramidothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-093-00-3 leptophos (ISO); 244-472-8 21609-90-5 Acute Tox. 3 * H301 GHS06 H301
O-4-bromo-2,5-dichlorophenyl O-methyl STOT SE 1 H370 GHS08 H370 **
phenylphosphorothioate Acute Tox. 4 * ** GHS09 H312
Aquatic Acute 1 H312 Dgr H410
Aquatic H400
Chronic 1 H410
015-094-00-9 mephosfolan (ISO); 213-447-3 950-10-7 Acute Tox. 1 H310 GHS06 H310
31.12.2008
diethyl 4-methyl-1,3-dithiolan-2-ylidene- Acute Tox. 2 * H300 GHS09 H300
phosphoramidate Aquatic H411 Dgr H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-095-00-4 methamidophos (ISO); 233-606-0 10265-92-6 Acute Tox. 2 * H330 GHS06 H330
EN
O,S-dimethyl phosphoramidothioate Acute Tox. 2 * H300 GHS09 H300
Acute Tox. 3 * H311 Dgr H311
Aquatic Acute 1 H400 H400
015-096-00-X oxydisulfoton (ISO); 219-679-1 2497-07-6 Acute Tox. 2 * H300 GHS06 H300 M = 10
O,O-diethyl S-2-ethylsulphinylethyl phos- Acute Tox. 3 * H311 GHS09 H311
phorodithioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
015-097-00-5 phenthoate (ISO); 219-997-0 2597-03-7 Acute Tox. 4 * H312 GHS07 H312 M = 100
ethyl 2-(dimethoxyphosphinothioylthio)-2- Acute Tox. 4 * H302 GHS09 H302
phenylacetate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
015-098-00-0 trichloronate (ISO); 206-326-1 327-98-0 Acute Tox. 2 * H300 GHS06 H300
O-ethyl O-2,4,5-trichlorophenyl ethylphos- Acute Tox. 3 * H311 GHS09 H311
phonothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-099-00-6 pirimiphos-ethyl (ISO); 245-704-0 23505-41-1 Acute Tox. 3 * H301 GHS06 H301
O,O-diethyl O-2-diethylamino-6-methylpyr- Acute Tox. 4 * H312 GHS09 H312
imidin-4-yl phosphorothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-100-00-X phoxim (ISO); 238-887-3 14816-18-3 Acute Tox. 4 * H302 GHS07 H302 M = 1000
α-(diethoxyphosphinothioylimino) phenyla- Aquatic Acute 1 H400 GHS09 H410
L 353/385
cetonitrile Aquatic H410 Wng
Chronic 1
L 353/386
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-101-00-5 phosmet (ISO); 211-987-4 732-11-6 Acute Tox. 4 * H312 GHS07 H312 M = 100
EN
O,O-dimethyl phthalimidomethyl S-phos- Acute Tox. 4 * H302 GHS09 H302
phorodithioate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
015-104-00-1 diphosphorus pentasulphide; 215-242-4 1314-80-3 Flam. Sol. 1 H228 GHS02 H228 EUH029 T
phosphorus pentasulphide Water-react. 1 H260 GHS07 H260
Acute Tox. 4 * H332 GHS09 H332
Acute Tox. 4 * H302 Dgr H302
Aquatic Acute 1 H400 H400
015-105-00-7 triphenyl phosphite 202-908-4 101-02-0 Eye Irrit. 2 H319 GHS07 H319 Skin Irrit. 2;
Skin Irrit. 2 H315 GHS09 H315 H315: C ≥ 5 %
Aquatic Acute 1 H400 Wng H410 Eye Irrit. 2; H319:
Aquatic H410 C ≥ 5%
Chronic 1
015-106-00-2 hexamethylphosphoric triamide; 211-653-8 680-31-9 Carc. 1B H350 GHS08 H350 Carc. 1B; H350: C
hexamethylphosphoramide Muta. 1B H340 Dgr H340 ≥ 0,01 %
015-107-00-8 ethoprophos (ISO); 236-152-1 13194-48-4 Acute Tox. 2 * H330 GHS06 H330
ethyl-S,S-dipropyl phosphorodithioate Acute Tox. 1 H310 GHS09 H310
Acute Tox. 3 * H301 Dgr H301
Skin Sens. 1 H317 H317
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-108-00-3 bromophos (ISO); 218-277-3 2104-96-3 Acute Tox. 4 * H302 GHS07 H302 M = 100
EN
O-4-bromo-2,5-dichlorophenyl O,O- Aquatic Acute 1 H400 GHS09 H410
dimethyl phosphorothioate Aquatic H410 Wng
Chronic 1
015-109-00-9 crotoxyphos (ISO); 231-720-5 7700-17-6 Acute Tox. 3 * H311 GHS06 H311 M = 10
1-phenylethyl 3-(dimethoxyphosphinyloxy) Acute Tox. 3 * H301 GHS09 H301
isocrotonate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-111-00-X phosfolan (ISO); 213-423-2 947-02-4 Acute Tox. 1 H310 GHS06 H310
diethyl 1,3-dithiolan-2-ylidenephosphora- Acute Tox. 2 * H300 Dgr H300
midate
015-112-00-5 thionazin (ISO); 206-049-6 297-97-2 Acute Tox. 1 H310 GHS06 H310
O,O-diethyl O-pyrazin-2-yl phosphorothio- Acute Tox. 2 * H300 Dgr H300
ate;
015-114-00-6 chlormephos (ISO); 246-538-1 24934-91-6 Acute Tox. 1 H310 GHS06 H310
S-chloromethyl O,O-diethyl phosphoro- Acute Tox. 2 * H300 GHS09 H300
dithioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-115-00-1 chlorthiophos (ISO) 244-663-6 21923-23-9 Acute Tox. 2 * H300 GHS06 H300
Acute Tox. 3 * H311 GHS09 H311
L 353/387
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/388
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-116-00-7 demephion-O (ISO); 211-666-9 682-80-4 Acute Tox. 2 * H300 GHS06 H300
EN
O,O-dimethyl O-2-methylthioethyl phos- Acute Tox. 3 * H311 Dgr H311
phorothioate
015-117-00-2 demephion-S (ISO); 219-971-9 2587-90-8 Acute Tox. 2 * H300 GHS06 H300
O,O-dimethyl S-2-methylthioethyl phos- Acute Tox. 3 * H311 Dgr H311
phorothioate
015-119-00-3 dimethyl 4-(methylthio)phenyl phosphate — 3254-63-5 Acute Tox. 1 H310 GHS06 H310
Acute Tox. 2 * H300 Dgr H300
015-120-00-9 ditalimfos (ISO); 225-875-8 5131-24-8 Skin Irrit. 2 H315 GHS07 H315
O,O-diethyl phthalimidophosphonothioate Skin Sens. 1 H317 Wng H317
015-121-00-4 edifenphos (ISO); 241-178-1 17109-49-8 Acute Tox. 3 * H331 GHS06 H331
O-ethyl S,S-diphenyl phosphorodithioate Acute Tox. 3 * H301 GHS09 H301
Acute Tox. 4 * H312 Dgr H312
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-122-00-X etrimfos (ISO); 253-855-9 38260-54-7 Acute Tox. 4 * H302 GHS07 H302 M = 10
O-6-ethoxy-2-ethylpyrimidin-4-yl O,O- Aquatic Acute 1 H400 GHS09 H410
dimethylphosphorothioate Aquatic H410 Wng
Chronic 1
015-123-00-5 fenamiphos (ISO); 244-848-1 22224-92-6 Acute Tox. 2 * H300 GHS06 H300 M = 100
ethyl-4-methylthio-m-tolyl isopropyl phos- Acute Tox. 3 * H311 GHS09 H311
31.12.2008
phoramidate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-124-00-0 fosthietan (ISO); 244-437-7 21548-32-3 Acute Tox. 1 H310 GHS06 H310
EN
diethyl 1,3-dithietan-2-ylidenephosphora- Acute Tox. 2 * H300 Dgr H300
midate
015-125-00-6 glyphosine (ISO); 219-468-4 2439-99-8 Eye Dam. 1 H318 GHS05 H318
N,N-bis(phosphonomethyl)glycine Dgr
015-126-00-1 heptenophos (ISO); 245-737-0 23560-59-0 Acute Tox. 3 * H301 GHS06 H301 M = 100
7-chlorobicyclo(3.2.0)hepta-2,6-dien-6-yl Aquatic Acute 1 H400 GHS09 H410
dimethyl phosphate Aquatic H410 Dgr
015-129-00-8 isofenphos (ISO); 246-814-1 25311-71-1 Acute Tox. 3 * H311 GHS06 H311 M = 100
O-ethyl O-2-isopropoxycarbonylphenyl-iso- Acute Tox. 3 * H301 GHS09 H301
propylphosphoramidothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-131-00-9 isoxathion (ISO); 242-624-8 18854-01-8 Acute Tox. 3 * H311 GHS06 H311
O,O-diethyl O-5-phenylisoxazol-3-ylphos- Acute Tox. 3 * H301 GHS09 H301
L 353/389
phorothioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/390
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-132-00-4 S-(chlorophenylthiomethyl) O,O-dimethyl- — 953-17-3 Acute Tox. 3 * H311 GHS06 H311 M = 1000
EN
phosphorodithioate; Acute Tox. 3 * H301 GHS09 H301
methylcarbophenothione Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-135-00-0 profenofos (ISO) 255-255-2 41198-08-7 Acute Tox. 4 * H332 GHS07 H332 M = 1000
O-(4-bromo-2-chlorophenyl) O-ethyl Acute Tox. 4 * H312 GHS09 H312
S-propyl phosphorothioate; Acute Tox. 4 * H302 Wng H302
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-136-00-6 trans-isopropyl-3-[[(ethylamino)methoxyfos- 250-517-2 31218-83-4 Acute Tox. 3 * H301 GHS06 H301 M = 100
finothioyl]oxy]crotonate; Aquatic Acute 1 H400 GHS09 H410
isopropyl 3-[[(ethylamino)methoxyphosphi- Aquatic H410 Dgr
nothioyl]oxy]isocrotonate; Chronic 1
propetamphos (ISO)
015-137-00-1 pyrazophos (ISO); 236-656-1 13457-18-6 Acute Tox. 4 * H332 GHS07 H332
O,O-diethyl O-(6-ethoxycarbonyl-5-methyl- Acute Tox. 4 * H302 GHS09 H302
31.12.2008
pyrazolo[2,3-a]pyrimidin-2-yl) phosphoro- Aquatic Acute 1 H400 Wng H410
thioate Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-138-00-7 quinalphos (ISO); 237-031-6 13593-03-8 Acute Tox. 3 * H301 GHS06 H301 M = 1000
EN
O,O-diethyl-O-quinoxalin-2-yl phosphoro- Acute Tox. 4 * H312 GHS09 H312
thioate Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-139-00-2 terbufos (ISO); 235-963-8 13071-79-9 Acute Tox. 1 H310 GHS06 H310 M = 1000
S-tert-butylthiomethyl O,O-diethylphos- Acute Tox. 2 * H300 GHS09 H300
phorodithioate; Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
015-141-00-3 ethylenediammonium O,O-bis(octyl) phos- 400-520-1 — Skin Corr. 1B H314 GHS05 H314
phorodithioate, mixed isomers Acute Tox. 4 * H302 GHS07 H302
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
015-143-00-4 reaction mass of 2-chloroethyl chloropropyl 401-740-0 — Acute Tox. 4 * H302 GHS07 H302
2-chloroethylphosphonate, reaction mass of Wng
isomers and 2-chloroethyl chloropropyl
2-chloropropylphosphonate,
reaction mass of isomers
L 353/391
015-144-00-X reaction mass of pentyl methylphosphinate 402-090-0 87025-52-3 Skin Corr. 1B H314 GHS05 H314
and 2-methylbutyl methylphosphinate Dgr
L 353/392
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-145-00-5 reaction mass of copper(I) O,O-diisopropyl 401-520-4 — Aquatic Acute 1 H400 GHS09 H410
phosphorodithioate and copper(I) O-iso-
EN
Aquatic H410 Wng
propyl O-(4-methylpent-2-yl) phosphoro- Chronic 1
dithioate and copper(I) O,O-bis(4-
methylpent-2-yl) phosphorodithioate
015-148-00-1 2-(diphosphonomethyl)succinic acid 403-070-4 51395-42-7 Skin Corr. 1B H314 GHS05 H314
Skin Sens. 1 H317 GHS07 H317
Dgr
015-149-00-7 reaction mass of: hexyldioctylphosphine- 403-470-9 — Skin Corr. 1B H314 GHS05 H314
oxide; Aquatic Acute 1 H400 GHS09 H410
dihexyloctylphosphineoxide; Aquatic H410 Dgr
trioctylphosphineoxide Chronic 1
015-152-00-3 dioxabenzofos (ISO); 223-292-3 3811-49-2 Acute Tox. 3 * H311 GHS06 H311
2-methoxy-4H-1,3,2-benzodioxaphos- Acute Tox. 3 * H301 GHS08 H301
31.12.2008
phorin 2-sulphide STOT SE 1 H370 GHS09 H370 **
Aquatic ** Dgr H411
Chronic 2 H411
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-153-00-9 isazofos (ISO); 255-863-8 42509-80-8 Acute Tox. 2 * H330 GHS06 H330
EN
O-(5-chloro-1-isopropyl-1,2,4-triazol-3-yl) Acute Tox. 3 * H311 GHS08 H311
O,O-diethyl phosphorothioate Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
Skin Sens. 1 ** H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
015-154-00-4 2-chloroethylphosphonic acid; 240-718-3 16672-87-0 Acute Tox. 4 * H332 GHS05 H332 STOT SE 3;
ethephon Acute Tox. 4 * H312 GHS07 H312 H335: C ≥ 5 %
015-155-00-X ammonium 2-amino-4-(hydroxymethylpho- 278-636-5 77182-82-2 Acute Tox. 4 * H302 GHS07 H302
sphinyl)butyrate; Wng
glufosinate ammonium
015-156-00-5 methyl 3-[(dimethoxyphosphinothioyl)oxy] 250-366-9 30864-28-9 [1] Acute Tox. 4 * H302 GHS07 H302
methacrylate; [1] [1]-[2] 62610-77-9 [2] Skin Sens. 1 H317 GHS09 H317
methacrifos (ISO); Aquatic Acute 1 H400 Wng H410
methyl (E)-3-[(dimethoxyphosphinothioyl) Aquatic H410
oxy]methacrylate [2] Chronic 1
015-157-00-0 phosphonic acid; [1] 237-066-7 13598-36-2 [1] Acute Tox. 4 * H302 GHS05 H302
phosphorous acid [2] [1] 10294-56-1 [2] Skin Corr. 1A H314 GHS07 H314
233-663-1 Dgr
[2]
015-159-00-1 hydroxyphosphonoacetic acid 405-710-8 23783-26-8 Acute Tox. 4 * H302 GHS08 H302
STOT RE 2 * H373 GHS05 H373 **
L 353/393
Skin Corr. 1B ** GHS07 H314
Skin Sens. 1 H314 Dgr H317
H317
L 353/394
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-160-00-7 vanadyl pyrophosphate 406-260-5 58834-75-6 Eye Irrit. 2 H319 GHS07 H319
EN
Skin Sens. 1 H317 Wng H317
Aquatic H412 H412
Chronic 3
015-161-00-2 divanadyl pyrophosphate 407-130-0 65232-89-5 Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
015-165-00-4 reaction mass of: thiobis(4,1-phenylene)-S,S, 404-986-7 — Eye Dam. 1 H318 GHS05 H318
S',S'-tetraphenyldisulfonium bishexafluoro- Aquatic Acute 1 H400 GHS09 H410
phosphate; Aquatic H410 Dgr
diphenyl(4-phenylthiophenyl)sulfonium Chronic 1
hexafluorophosphate
31.12.2008
015-167-00-5 3-(hydroxyphenylphosphinyl)propanoic acid 411-200-6 14657-64-8 Eye Dam. 1 H318 GHS05 H318
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
015-168-00-0 fosthiazate (ISO); — 98886-44-3 Acute Tox. 3 * H331 GHS06 H331 EUH070
EN
(RS)-S-sec-butyl-O-ethyl-2-oxo-1,3-thiazoli- Acute Tox. 3 * H301 GHS09 H301
din-3-ylphosphonothioate Acute Tox. 4 * H312 Dgr H312
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
015-170-00-1 reaction mass of: di-(1-octane-N,N,N-tri- 407-490-9 — Acute Tox. 4 * H312 GHS05 H312
methylammonium) octylphosphate; Acute Tox. 4 * H302 GHS07 H302
1-octane-N,N,N-trimethylammonium di- Skin Corr. 1B H314 Dgr H314
octylphosphate;
1-octane-N,N,N-trimethylammonium octyl-
phosphate
015-172-00-2 reaction mass of: bis(isotridecylammonium) 406-240-6 — Flam. Liq. 3 H226 GHS02 H226
mono(di-(4-methylpent-2-yloxy)thiophos- Skin Corr. 1B H314 GHS05 H314
phorothionylisopropyl)phosphate; Aquatic H411 GHS09 H411
isotridecylammonium bis(di-(4-methylpent- Chronic 2 Dgr
2-yloxy)thiophosphorothionylisopropyl)
phosphate
015-173-00-8 methyl [2-(1,1-dimethylethyl)-6-methoxy- 414-080-3 117291-73-3 Acute Tox. 4 * H302 GHS07 H302
L 353/395
pyrimidin-4-yl]ethylphosphonothioate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
L 353/396
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Eye Dam. 1 H318 GHS05 H318
Aquatic H411 GHS09 H411
Chronic 2 Dgr
015-175-00-9 tert-butyl (triphenylphosphoranylidene) 412-880-7 35000-38-5 Acute Tox. 3 * H301 GHS06 H301
acetate STOT RE 2 * H373 GHS08 H373 **
Eye Irrit. 2 ** GHS09 H319
Skin Sens. 1 H319 Dgr H317
Aquatic H317 H411
Chronic 2 H411
015-178-00-5 (R)-α-phenylethylammonium (-)-(1R, 2S)- 418-570-8 25383-07-7 Repr. 2 H361f GHS08 H361f ***
(1,2-epoxypropyl)phosphonate monohy- Aquatic *** GHS09 H411
drate Chronic 2 H411 Wng
015-179-00-0 UVCB condensation product of: tetrakis- 422-720-8 166242-53-1 Carc. 2 H351 GHS08 H351
hydroxymethylphosphonium chloride, urea Acute Tox. 4 * H302 GHS05 H302
and distilled hydrogenated C16-18 tallow STOT RE 2 * H373 GHS07 H373 **
alkylamine **
Skin Corr. 1B GHS09 H314
Skin Sens. 1 H314 Dgr H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
31.12.2008
poxy]-(4-phenylbutyl)phosphinyl] acetic Skin Sens. 1 H317 GHS07 H317
acid, (-)-cinchonidine (1:1) salt Aquatic H412 Dgr H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Press. Gas H330 GHS04 H330
Acute Tox. 2 * H314 GHS06 H314
Skin Corr. 1B H400 GHS05 H400
Aquatic Acute 1 GHS09
Dgr
015-184-00-8 Salts of glyphosate, with the exception of — — Aquatic H411 GHS09 H411 A
those specified elsewhere in this Annex Chronic 2
015-187-00-4 reaction mass of: tetrasodium(((2-hydro- 417-540-1 — Eye Dam. 1 H318 GHS05 H318
xyethyl)imino)bis(methylene))bisphospho- Aquatic H411 GHS09 H411
nate, N-oxide; Chronic 2 Dgr
trisodium ((tetrahydro-2-hydroxy-4H-1,4,2-
oxazaphosphorin-4-yl)-methyl)phospho-
nate, N-oxide, P-oxide
015-189-00-5 phenyl bis(2,4,6-trimethylbenzoyl)-phos- 423-340-5 162881-26-7 Skin Sens. 1 H317 GHS07 H317
phine oxide Aquatic H413 Wng H413
Chronic 4
016-001-00-4 hydrogen sulphide 231-977-3 7783-06-4 Flam. Gas 1 H220 GHS02 H220 U
Press. Gas H330 GHS04 H330
Acute Tox. 2 * H400 GHS06 H400
Aquatic Acute 1 GHS09
Dgr
L 353/397
016-002-00-X barium sulphide 244-214-4 21109-95-5 Acute Tox. 4 * H332 GHS07 H332 EUH031
Acute Tox. 4 * H302 GHS09 H302
Aquatic Acute 1 H400 Wng H400
L 353/398
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-003-00-5 barium polysulphides 256-814-3 50864-67-0 Eye Irrit. 2 H319 GHS07 H319 EUH031
EN
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H400
016-004-00-0 calcium sulphide 243-873-5 20548-54-3 Eye Irrit. 2 H319 GHS07 H319 EUH031
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H400
016-006-00-1 dipotassium sulphide; 215-197-0 1312-73-8 Skin Corr. 1B H314 GHS05 H314 EUH031
potassium sulphide Aquatic Acute 1 H400 GHS09 H400
Dgr
016-007-00-7 potassium polysulphides 253-390-1 37199-66-9 Skin Corr. 1B H314 GHS05 H314 EUH031
Aquatic Acute 1 H400 GHS09 H400
Dgr
016-008-00-2 ammonium polysulphides 232-989-1 9080-17-5 Skin Corr. 1B H314 GHS05 H314 EUH031 EUH031: C ≥ 1 %
Aquatic Acute 1 H400 GHS09 H400
Dgr
016-009-00-8 disodium sulphide; 215-211-5 1313-82-2 Skin Corr. 1B H314 GHS05 H314 EUH031
sodium sulphide Aquatic Acute 1 H400 GHS09 H400
Dgr
016-010-00-3 sodium polysulphides 215-686-9 1344-08-7 Acute Tox. 3 * H301 GHS06 H301 EUH031
31.12.2008
Skin Corr. 1B H314 GHS05 H314
Aquatic Acute 1 H400 GHS09 H400
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-011-00-9 sulphur dioxide 231-195-2 7446-09-5 Press. Gas H331 GHS04 H331 * U
EN
Acute Tox. 3 * H314 GHS06 H314 5
Skin Corr. 1B GHS05
Dgr
016-012-00-4 disulphur dichloride; 233-036-2 10025-67-9 Acute Tox. 3 * H301 GHS06 H301 EUH014 STOT SE 3;
sulfur monochloride Acute Tox. 4 * H332 GHS05 H332 EUH029 H335: C ≥ 1 %
Skin Corr. 1A H314 GHS09 H314
Aquatic Acute 1 H400 Dgr H400
016-014-00-5 sulphur tetrachloride — 13451-08-6 Skin Corr. 1B H314 GHS05 H314 EUH014 STOT SE 3;
Aquatic Acute 1 H400 GHS09 H400 H335: C ≥ 5 %
Dgr
016-015-00-0 thionyl dichloride; 231-748-8 7719-09-7 Acute Tox. 4 * H332 GHS05 H332 EUH014 STOT SE 3;
thionyl chloride Acute Tox. 4 * H302 GHS07 H302 EUH029 H335: C ≥ 1 %
Skin Corr. 1A H314 Dgr H314
016-016-00-6 sulphuryl chloride 232-245-6 7791-25-5 Skin Corr. 1B H314 GHS05 H314 EUH014
STOT SE 3 H335 GHS07 H335
Dgr
016-017-00-1 chlorosulphonic acid 232-234-6 7790-94-5 Skin Corr. 1A H314 GHS05 H314 EUH014
STOT SE 3 H335 GHS07 H335
Dgr
L 353/399
016-018-00-7 fluorosulphonic acid 232-149-4 7789-21-1 Acute Tox. 4 * H332 GHS05 H332
Skin Corr. 1A H314 GHS07 H314
Dgr
L 353/400
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-019-00-2 oleum ... % SO3 — — Skin Corr. 1A H314 GHS05 H314 EUH014 B
EN
STOT SE 3 H335 GHS07 H335
Dgr
016-020-00-8 sulphuric acid ... % 231-639-5 7664-93-9 Skin Corr. 1A H314 GHS05 H314 Skin Corr. 1A; B
Dgr H314: C ≥ 15 %
Skin Irrit. 2;
H315: 5 % ≤ C
< 15 %
Eye Irrit. 2; H319:
016-023-00-4 dimethyl sulphate 201-058-1 77-78-1 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
Muta. 2 H341 GHS08 H341 ≥ 0,01 %
Acute Tox. 2 * H330 GHS05 H330 Muta. 2; H341: C
Acute Tox. 3 * H301 Dgr H301 ≥ 0,01 %
Skin Corr. 1B H314 H314 STOT SE 3;
H335: C ≥ 5 %
Skin Sens. 1 H317 H317
31.12.2008
bis(methoxythiocarbonyl) disulphide Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-025-00-5 disul (ISO); 205-259-5 149-26-8 Acute Tox. 4 * H302 GHS05 H302
EN
2-(2,4-dichlorophenoxy)ethyl hydrogensul- Skin Irrit. 2 H315 GHS07 H315
phate; Eye Dam. 1 H318 Dgr H318
2,4-DES
016-026-00-0 sulphamidic acid; 226-218-8 5329-14-6 Eye Irrit. 2 H319 GHS07 H319
sulphamic acid; Skin Irrit. 2 H315 Wng H315
sulfamic acid Aquatic H412 H412
Chronic 3
016-028-00-1 sodium dithionite; 231-890-0 7775-14-6 Self-heat. 1 H251 GHS02 H251 EUH031
sodium hydrosulphite Acute Tox. 4 * H302 GHS07 H302
Dgr
016-029-00-7 p-toluenesulphonic acid, containing more — — Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B;
than 5 % H2SO4 Dgr H314: C ≥ 25 %
Skin Irrit. 2;
H315: 10 % ≤ C
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
016-030-00-2 p-toluenesulphonic acid (containing a ma- 203-180-0 104-15-4 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
ximum of 5 % H2SO4) STOT SE 3 H335 Wng H335 H335: C ≥ 20 %
Skin Irrit. 2 H315 H315
L 353/401
016-032-00-3 1,3-propanesultone; 214-317-9 1120-71-4 Carc. 1B H350 GHS08 H350 Carc. 1B; H350: C
1,2-oxathiolane 2,2-dioxide Acute Tox. 4 * H312 GHS07 H312 ≥ 0,01 %
Acute Tox. 4 * H302 Dgr H302
L 353/402
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 2 * H330 GHS05 H330
Acute Tox. 4 * H312 GHS08 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
016-034-00-4 tetrasodium 3,3'-(piperazine-1,4-diylbis((6- 400-010-9 81898-60-4 Skin Sens. 1 H317 GHS07 H317
chloro-1,3,5-triazine-2,4-diyl)imino(2-aceta- Wng
mido)-4,1-phenyleneazo))bis(naphthalene-
1,5-disulphonate)
016-037-00-0 disodium 1-amino-4-(4-benzenesulphona- 400-350-8 85153-93-1 Eye Dam. 1 H318 GHS05 H318
mido-3-sulphonatoanilino)anthraquinone- Aquatic H412 Dgr H412
2-sulphonate Chronic 3
016-038-00-6 disodium 6-((4-chloro-6-(N-methyl)-2-tolui- 400-380-1 86393-35-3 Skin Sens. 1 H317 GHS07 H317
dino)-1,3,5-triazin-2-ylamino)-1-hydroxy-2- Wng
(4-methoxy-2-sulphonatophenylazo)
naphthalene-3-sulphonate
31.12.2008
4-(2,5-disulphonatophenylazo)phenylazo)- Wng
3-ureidoanilino)-1,3,5-triazin-2-ylamino)
benzene-1,4-disulphonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-040-00-7 reaction mass of disodium 6-(2,4-dihydro- 400-570-4 — Eye Irrit. 2 H319 GHS07 H319
xyphenylazo)-3-(4-(4-(2,4-dihydroxypheny- Wng
EN
lazo)anilino)-3-sulphonatophenylazo)-4-
hydroxynaphthalene-2-sulphonate and diso-
dium 6-(2,4-diaminophenylazo)-3-(4-(4-
(2,4-diaminophenylazo)anilino)-3-sulphona-
tophenylazo)-4-hydroxynaphthalene-2-sul-
phonate and trisodium 6-(2,4-
dihydroxyphenylazo)-3-(4-(4-(7-(2,4-dihy-
droxyphenylazo)-1-hydroxy-3-sulphonato-
2-naphthylazo)anilino)-3-sulphonatopheny-
lazo)-4-hydroxynaphthalene-2-sulphonate
016-042-00-8 tetrasodium 5-benzamido-3-(5-(4-fluoro-6- 400-790-0 85665-97-0 Eye Irrit. 2 H319 GHS07 H319
(1-sulphonato-2-naphthylamino)-1,3,5-tria- Skin Irrit. 2 H315 Wng H315
zin-2-ylamino)-2-sulphonatophenylazo)-4- Skin Sens. 1 H317 H317
hydroxynaphthalene-2,7- disulphonate
016-045-00-4 lithium sodium hydrogen 4-amino-6-(5-(5- 401-560-2 108624-00-6 Skin Sens. 1 H317 GHS07 H317
chloro-2,6-difluoropyrimidin-4-ylamino)-2- Wng
sulphonatophenylazo)-5-hydroxy-3-(4-(2-
(sulphonatooxy)ethylsulphonyl)phenylazo)
naphthalene-2,7-disulphonate
016-046-00-X sodium hydrogensulphate 231-665-7 7681-38-1 Eye Dam. 1 H318 GHS05 H318
Dgr
016-047-00-5 hexasodium 7-(4-(4-(4-(2,5-disulphonatoa- 401-650-1 85665-96-9 Skin Sens. 1 H317 GHS07 H317
L 353/403
nilino)-6-fluoro-1,3,5-triazin-2-ylamino)-2- Wng
methylphenylazo)-7-sulphonatonaphthy-
lazo)naphthalene-1,3,5- trisulphonate
L 353/404
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
hydroxypropylamino)-4-methylpyridin-3- Aquatic H412 Dgr H412
ylazo)benzenesulphonate Chronic 3
016-050-00-1 potassium sodium 5-(4-chloro-6-(N-(4-(4- 402-150-6 — Eye Irrit. 2 H319 GHS07 H319
016-051-00-7 trisodium 7-(4-(6-fluoro-4-(2-(2-vinylsul- 402-170-5 106359-91-5 Skin Sens. 1 H317 GHS07 H317
phonylethoxy)ethylamino)-1,3,5-triazin-2- Wng
ylamino)-2-ureidophenylazo)naphthalene-
1,3,6- trisulphonate
016-052-00-2 benzyltributylammonium 4-hydroxy- 402-240-5 102561-46-6 Acute Tox. 4 * H332 GHS07 H332
naphthalene-1-sulphonate Aquatic H411 GHS09 H411
Chronic 2 Wng
016-053-00-8 (C16 or C18-n-alkyl)(C16 or C18-n-alkyl) 402-460-1 — Skin Irrit. 2 H315 GHS07 H315
ammonium 2-((C16 or C18-n-alkyl)(C16 or Skin Sens. 1 H317 Wng H317
C18-n-alkyl)carbamoyl)benzenesulphonate Aquatic H413 H413
Chronic 4
31.12.2008
STOT SE 3 H319 H335
Skin Sens. 1 H335 H317
H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
(2-hydroxyethylamino)-1,3,5-triazin-2-yla- Skin Sens. 1 H317 GHS07 H317
mino)-2-sulfonatophenylazo)-5-hydroxy- Dgr
naphthalene-2,7-sulfonate (containing >
35 % sodium chloride and sodium acetate)
016-056-00-4 potassium hydrogensulphate 231-594-1 7646-93-7 Skin Corr. 1B H314 GHS05 H314
STOT SE 3 H335 GHS07 H335
Dgr
016-058-00-5 thionyl chloride, reaction products with 404-820-3 — Skin Irrit. 2 H315 GHS07 H315
1,3,4-thiadiazol-2,5-dithiol, tert-nonanethiol Skin Sens. 1 H317 Wng H317
and C12-14-tert-alkylamine Aquatic H412 H412
Chronic 3
016-060-00-6 diammonium peroxodisulphate; 231-786-5 7727-54-0 Ox. Sol. 3 H272 GHS03 H272
ammonium persulphate Acute Tox. 4 * H302 GHS08 H302
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
L 353/405
Resp. Sens. 1 H334 H334
Skin Sens. 1 H317 H317
L 353/406
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-061-00-1 dipotassium peroxodisulphate; 231-781-8 7727-21-1 Ox. Sol. 3 H272 GHS03 H272
EN
potassium persulphate Acute Tox. 4 * H302 GHS08 H302
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Resp. Sens. 1 H334 H334
Skin Sens. 1 H317 H317
016-063-00-2 sodium metabisulphite 231-673-0 7681-57-4 Acute Tox. 4 * H302 GHS05 H302 EUH031
Eye Dam. 1 H318 GHS07 H318
Dgr
016-064-00-8 sodium hydrogensulphite . . . %; 231-548-0 7631-90-5 Acute Tox. 4 * H302 GHS07 H302 EUH031 B
sodium bisulphite . . . % Wng
016-068-00-X sodium 3,5-bis(tetradecyloxycarbonyl)ben- 407-720-8 155160-86-4 Skin Sens. 1 H317 GHS07 H317
zenesulfinate Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
016-069-00-5 3,5-bis-(tetradecyloxycarbonyl)benzenesulfi- 407-990-7 141915-64-2 Skin Sens. 1 H317 GHS07 H317
nic acid Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
016-071-00-6 trisodium 3-amino-6,13-dichloro-10-((3- 410-130-3 136248-03-8 Skin Sens. 1 H317 GHS07 H317
((4-chloro-6-(2-sulfophenylamino)-1,3,5- Wng
triazin-2-yl)amino)propyl) amino)-4,11-tri-
phenoxydioxazinedisulfonate
L 353/407
016-078-00-4 4-methyl-N,N-bis(2-(((4-methylphenyl)sulfo- 413-300-5 56187-04-3 Aquatic H413 —
nyl)amino)ethyl)benzenesulfonamide Chronic 4
L 353/408
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H413 Wng H413
Chronic 4
016-080-00-5 sodium 2-anilino-5-(2-nitro-4-(N-phenylsul- 412-320-1 31361-99-6 Eye Dam. 1 H318 GHS05 H318
famoyl))anilinobenzenesulfonate Aquatic H412 Dgr H412
Chronic 3
31.12.2008
016-086-00-8 tetrasodium 10-amino-6,13-dichloro-3-(3- 402-590-9 109125-56-6 Eye Dam. 1 H318 GHS05 H318
(4-(2,5-disulfonatoanilino)-6-fluoro-1,3,5- Dgr
triazin-2-ylamino)prop-3-ylamino)-5,12-
dioxa-7,14-diazapentacene-4,11-disulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
016-087-00-3 reaction mass of: thiobis(4,1-phenylene)-S,S, 403-490-8 104558-95-4 Eye Irrit. 2 H319 GHS07 H319
S',S'-tetraphenyldisulfonium bishexafluoro-
EN
Skin Sens. 1 H317 GHS09 H317
phosphate; Aquatic Acute 1 H400 Wng H410
diphenyl(4-phenylthiophenyl)sulfonium Aquatic H410
hexafluorophosphate; Chronic 1
propylene carbonate
016-091-00-5 C12-14-tert-alkyl ammonium 1-amino-9,10- 414-110-5 — Eye Dam. 1 H318 GHS05 H318
dihydro-9,10-dioxo-4-(2,4,6-trimethylani- Aquatic Acute 1 H400 GHS09 H410
lino)-anthracen-2-sulfonate Aquatic H410 Dgr
Chronic 1
016-093-00-6 reaction mass of: 4-(7-hydroxy-2,4,4-tri- 414-770-4 140698-96-0 Self-react. C H242 GHS02 H242
methyl-2-chromanyl)resorcinol-4-yl-tris(6- **** H351 GHS08 H351
diazo-5,6-dihydro-5-oxonaphthalen-1-sulfo- Carc. 2 Dgr
nate);
4-(7-hydroxy-2,4,4-trimethyl-2-chromanyl)
resorcinolbis(6-diazo-5,6-dihydro-5-oxo-
naphthalen-1-sulfonate) (2:1)
016-095-00-7 reaction mass of: reaction product of 4,4'- 417-980-4 — Self-react. C H242 GHS02 H242
methylenebis[2-(4-hydroxybenzyl)-3,6- **** H351 GHS08 H351
dimethylphenol] and 6-diazo-5,6-dihydro- Carc. 2 Dgr
5-oxo-naphthalenesulfonate (1:2);
Reaction product of 4,4'-methylenebis[2-(4-
L 353/409
hydroxybenzyl)-3,6-dimethylphenol] and 6-
diazo-5,6-dihydro-5-oxo-naphthalenesulfo-
nate (1:3)
L 353/410
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methyl 3-(4-methoxy-6-methyl-1,3,5-tria- Aquatic H410 Wng
zin-2-ylcarbamoylsulfamoyl)thiophene-2- Chronic 1
carboxylate
017-002-00-2 hydrogen chloride 231-595-7 7647-01-0 Press. Gas H331 GHS04 H331 U
Acute Tox. 3 * H314 GHS06 H314 5
Skin Corr. 1A GHS05
Dgr
017-002-01-X hydrochloric acid ... % 231-595-7 — Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B; B
STOT SE 3 H335 GHS07 H335 H314: C ≥ 25 %
Dgr Skin Irrit. 2;
H315: 10 % ≤ C
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
STOT SE 3;
H335: C ≥ 10 %
017-003-00-8 barium chlorate 236-760-7 13477-00-4 Ox. Sol. 1 H271 GHS03 H271
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 GHS09 H302
Aquatic H411 Dgr H411
Chronic 2
017-004-00-3 potassium chlorate 223-289-7 3811-04-9 Ox. Sol. 1 H271 GHS03 H271
Acute Tox. 4 * H332 GHS07 H332
31.12.2008
Acute Tox. 4 * H302 GHS09 H302
Aquatic H411 Dgr H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
017-005-00-9 sodium chlorate 231-887-4 7775-09-9 Ox. Sol. 1 H271 GHS03 H271
EN
Acute Tox. 4 * H302 GHS07 H302
Aquatic H411 GHS09 H411
Chronic 2 Dgr
017-006-00-4 perchloric acid ... % 231-512-4 7601-90-3 Ox. Liq. 1 H271 GHS03 H271 Skin Corr. 1A; B
Skin Corr. 1A H314 GHS05 H314 H314: C ≥ 50 %
Dgr Skin Corr. 1B;
H314: 10 % ≤ C
< 50 %
Skin Irrit. 2;
017-007-00-X barium perchlorate 236-710-4 13465-95-7 Ox. Sol. 1 H271 GHS03 H271
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
017-008-00-5 potassium perchlorate 231-912-9 7778-74-7 Ox. Sol. 1 H271 GHS03 H271
Acute Tox. 4 * H302 GHS07 H302
Dgr
017-009-00-0 ammonium perchlorate 232-235-1 7790-98-9 Expl. 1.1 H201 GHS01 H201 EUH044 T
Ox. Sol. 1 H271 Dgr H271
017-010-00-6 sodium perchlorate 231-511-9 7601-89-0 Ox. Sol. 1 H271 GHS03 H271
Acute Tox. 4 * H302 GHS07 H302
Dgr
L 353/411
017-011-00-1 sodium hypochlorite, solution ... % Cl active 231-668-3 7681-52-9 Skin Corr. 1B H314 GHS05 H314 EUH031 EUH031: C ≥ 5 % B
Aquatic Acute 1 H400 GHS09 H400
Dgr
L 353/412
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
017-012-00-7 calcium hypochlorite 231-908-7 7778-54-3 Ox. Sol. 2 H272 GHS03 H272 EUH031 Skin Corr. 1B; T
H314: C ≥ 10 %
EN
Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 GHS07 H314 Skin Irrit. 2;
Aquatic Acute 1 H400 GHS09 H400 H315: 3 % ≤ C
< 10 %
Dgr
Eye Dam. 1; H31:
3 % ≤ C < 10 %
Eye Irrit. 2; H319:
0,5 % ≤ C < 3 %
STOT SE 3;
H335: C ≥ 3 %
017-014-00-8 ammonium chloride 235-186-4 12125-02-9 Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 Wng H319
017-016-00-9 methyltriphenylphosphonium chloride 418-400-2 1031-15-8 Acute Tox. 4 * H312 GHS05 H312
Acute Tox. 4 * H302 GHS07 H302
Skin Irrit. 2 H315 GHS09 H315
Eye Dam. 1 H318 Dgr H318
Aquatic H411 H411
Chronic 2
31.12.2008
017-019-00-5 (R)-1,2,3,4-tetrahydro-6,7-dimethoxy-1-ver- 415-110-8 54417-53-7 Acute Tox. 4 * H302 GHS07 H302
atrylisoquinoline hydrochloride Aquatic H412 Wng H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
017-020-00-0 ethyl propoxy aluminium chloride 421-790-7 13014-29-4 Water-react. 1 H260 GHS02 H260 EUH014
EN
Skin Corr. 1A H314 GHS05 H314
Dgr
019-002-00-8 potassium hydroxide; 215-181-3 1310-58-3 Acute Tox. 4 * H302 GHS05 H302 Skin Corr. 1A;
caustic potash Skin Corr. 1A H314 GHS07 H314 H314: C ≥ 5 %
Dgr Skin Corr. 1B;
H314: 2 % ≤ C
< 5%
Skin Irrit. 2;
H315: 0,5 % ≤ C
< 2%
Eye Irrit. 2; H319:
0,5 % ≤ C < 2 %
020-002-00-5 calcium cyanide 209-740-0 592-01-8 Acute Tox. 2 * H300 GHS06 H300 EUH032
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
020-003-00-0 reaction mass of: dicalcium (bis(2-hydroxy- 420-470-4 — Eye Irrit. 2 H319 GHS07 H319
5-tetra-propenylphenylmethyl)methylamine) Skin Irrit. 2 H315 Wng H315
dihydroxide; Skin Sens. 1 H317 H317
tri-calcium (tris(2-hydroxy-5-tetra-propenyl-
L 353/413
phenylmethyl)methylamine)tri-hydroxide;
poly[calcium ((2-hydroxy-5-tetra-propenyl-
phenylmethyl)methylamine)hydroxide]
L 353/414
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
022-001-00-5 titanium tetrachloride 231-441-9 7550-45-0 Skin Corr. 1B H314 GHS05 H314 EUH014
EN
Dgr
024-001-00-0 chromium (VI) trioxide 215-607-8 1333-82-0 Ox. Sol. 1 H271 GHS03 H271 STOT SE 3;
Carc. 1A H350 GHS06 H350 H335: C ≥ 1 %
Muta. 1B H340 GHS08 H340
Repr. 2 H361f GHS05 H361f ***
Acute Tox. 2 * *** GHS09 H330
Acute Tox. 3 * H330 Dgr H311
Acute Tox. 3 * H311 H301
STOT RE 1 H301 H372 **
Skin Corr. 1A H372 H314
Resp. Sens. 1 ** H334
Skin Sens. 1 H314 H317
Aquatic Acute 1 H334 H410
31.12.2008
Aquatic H317
Chronic 1 H400
H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
024-002-00-6 potassium dichromate 231-906-6 7778-50-9 Ox. Sol. 2 H272 GHS03 H272 STOT SE 3; 3
Carc. 1B H350 GHS06 H350 H335: C ≥ 5 %
Muta. 1B H340 GHS08 H340
Repr. 1B H360- GHS05 H360FD
Acute Tox. 2 * FD GHS09 H330
Acute Tox. 3 * H330 Dgr H301
STOT RE 1 H301 H372 **
Acute Tox. 4 * H372 H312
Skin Corr. 1B ** H314
024-003-00-1 ammonium dichromate 232-143-1 7789-09-5 Ox. Sol. 2 **** H272 GHS03 H272 STOT SE 3; G
Carc. 1B H350 GHS06 H350 H335: C ≥ 5 % 3
Muta. 1B H340 GHS08 H340 Resp. Sens.;
Repr. 1B H360- GHS05 H360FD H334: C ≥ 0,2 %
Acute Tox. 2 * FD GHS09 H330 Skin Sens.; H317:
H330 C ≥ 0,2 %
Acute Tox. 3 * Dgr H301
STOT RE 1 H301 H372 **
Acute Tox. 4 * H372 H312
Skin Corr. 1B ** H314
Resp. Sens. 1 H312 H334
Skin Sens. 1 H314 H317
Aquatic Acute 1 H334 H410
Aquatic H317
Chronic 1 H400
H410
L 353/415
L 353/416
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
024-004-00-7 sodium dichromate anhydrate 234-190-3 10588-01-9 Ox. Sol. 2 H272 GHS03 H272 STOT SE 3; 3
Carc. 1B H350 GHS06 H350 H335: C ≥ 5 %
Muta. 1B H340 GHS08 H340 Resp. Sens.;
Repr. 1B H360- GHS05 H360FD H334: C ≥ 0,2 %
Acute Tox. 2 * FD GHS09 H330 Skin Sens.; H317:
H330 C ≥ 0,2 %
Acute Tox. 3 * Dgr H301
STOT RE 1 H301 H372 **
Acute Tox. 4 * H372 H312
Skin Corr. 1B ** H314
024-004-01-4 sodium dichromate, dihydrate 234-190-3 7789-12-0 Ox. Sol. 2 H272 GHS03 H272 STOT SE 3; 3
Carc. 1B H350 GHS06 H350 H335: C ≥ 5 %
Muta. 1B H340 GHS08 H340 Resp. Sens.;
Repr. 1B H360- GHS05 H360FD H334: C ≥ 0,2 %
Acute Tox. 2 * FD GHS09 H330 Skin Sens.; H317:
H330 C ≥ 0,2 %
Acute Tox. 3 * Dgr H301
STOT RE 1 H301 H372 **
Acute Tox. 4 * H372 H312
Skin Corr. 1B ** H314
Resp. Sens. 1 H312 H334
Skin Sens. 1 H314 H317
Aquatic Acute 1 H334 H410
Aquatic H317
Chronic 1 H400
H410
31.12.2008
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
024-005-00-2 chromyl dichloride; 239-056-8 14977-61-8 Ox. Liq. 1 H271 GHS03 H271 Skin Corr. 1A; T
EN
chromic oxychloride Carc. 1B H350i GHS08 H350i H314: C ≥ 10 % 3
Muta. 1B H340 GHS05 H340 Skin Corr. 1B;
Skin Corr. 1A H314 GHS07 H314 H314: 5 % ≤ C
< 10 %
Skin Sens. 1 H317 GHS09 H317
Skin Irrit. 2;
Aquatic Acute 1 H400 Dgr H410 H315: 0,5 % ≤ C
Aquatic H410 < 5%
Chronic 1 Eye Irrit. 2; H319:
0,5 % ≤ C < 5 %
STOT SE 3;
H335: 0,5 % ≤ C
024-006-00-8 potassium chromate 232-140-5 7789-00-6 Carc. 1B H350i GHS08 H350i Skin Sens. 1; 3
Muta. 1B H340 GHS07 H340 H317: C ≥ 0,5 %
Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
024-007-00-3 zinc chromates including zinc potassium — — Carc. 1A H350 GHS08 H350 A
chromate Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/417
Aquatic H410 Dgr
Chronic 1
L 353/418
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 GHS07 H302
Aquatic Acute 1 H400 GHS09 H400
Aquatic H410 Dgr H410
Chronic 1
024-010-00-X dichromium tris(chromate); 246-356-2 24613-89-6 Ox. Sol. 1 H271 GHS03 H271 T
chromium III chromate; Carc. 1B H350 GHS08 H350
chromic chromate Skin Corr. 1A H314 GHS05 H314
Skin Sens. 1 H317 GHS07 H317
024-014-00-1 trisodium bis(2-(5-chloro-4-nitro-2-oxido- 402-870-0 93952-24-0 Eye Dam. 1 H318 GHS05 H318
phenylazo)-5-sulphonato-1-naphtholato) Aquatic H412 Dgr H412
chromate(1-) Chronic 3
31.12.2008
nylazo)-1-phenylpyrazololato)(1-(3-nitro-2- Eye Dam. 1 H318 GHS07 H318
oxido-5-sulfonatophenylazo)-2-naphtho- Aquatic H411 GHS09 H411
lato)chromate(1-) Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
024-016-00-2 tetradecylammonium bis(1-(5-chloro-2-oxi- 405-110-6 88377-66-6 STOT RE 2 * H373 GHS08 H373 **
dophenylazo)-2-naphtholato)chromate(1-) Aquatic ** Wng H413
Chronic 4 H413
024-018-00-3 sodium chromate 231-889-5 7775-11-3 Carc. 1B H350 GHS06 H350 Resp. Sens.; 3
Muta. 1B H340 GHS08 H340 H334: C ≥ 0,2 %
Repr. 1B H360- GHS05 H360FD Skin Sens.; H317:
Acute Tox. 2 * FD GHS09 H330 C ≥ 0,2 %
Acute Tox. 3 * H330 Dgr H301
STOT RE 1 H301 H372 **
Acute Tox. 4 * H372 H312
Skin Corr. 1B ** H314
Resp. Sens. 1 H312 H334
Skin Sens. 1 H314 H317
Aquatic Acute 1 H334 H410
Aquatic H317
Chronic 1 H400
H410
L 353/419
L 353/420
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
024-019-00-9 Main component: acetoacetic acid anilide/3- 419-230-1 — Skin Sens. 1 H317 GHS07 H317
amino-1-hydroxybenzene (ATAN-MAP): tri-
EN
Aquatic H412 Wng H412
sodium {6-[(2 or 3 or 4)-amino-(4 or 5 or Chronic 3
6)-hydroxyphenylazo]-5'-(phenylsulfamoyl)-
3-sulfonatonaphthalene-2-azobenzene-1,2'-
diolato}-{6''-[1-(phenylcarbamoyl)ethylazo]-
5'''-(phenylsulfamoyl)-3''-sulfonatonaphtha-
lene-2''-azobenzene-1'',2'''-diolato}chromate
(III);
by-product 1: acetoacetic acid anilide/ace-
toacetic acid anilide (ATAN-ATAN): triso-
dium bis{6-[1-(phenylcarbamoyl)ethylazo]-
5'-(phenylsulfonyl)-3-sulfonatonaphthalene-
025-001-00-3 manganese dioxide 215-202-6 1313-13-9 Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Wng H302
025-002-00-9 potassium permanganate 231-760-3 7722-64-7 Ox. Sol. 2 H272 GHS03 H272
Acute Tox. 4 * H302 GHS07 H302
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
025-004-00-X bis(N,N',N''-trimethyl-1,4,7-triazacyclono- 411-760-1 116633-53-5 Aquatic H411 GHS09 H411
nane)-trioxo-dimanganese (IV) di(hexafluo- Chronic 2
rophosphate) monohydrate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
025-005-00-5 reaction mass of: tri-sodium [29H, 31H- 417-660-4 — Aquatic Acute 1 H400 GHS09 H410
EN
phthalocyanine-C,C,C-trisulfonato (6-)-N29, Aquatic H410 Wng
N30,N31,N32] manganate (3-); Chronic 1
tetrasodium [29H,31H-phthalocyanine-C,C,
C,C-tetrasulfonato (6-)-N29,N30,N31,N32],
manganate (3-);
pentasodium [29H,31H-phthalocyanine-C,
C,C,C,C-pentasulfonato (6-)-N29,N30,N31,
N32] manganate (3-)
026-002-00-1 (η-cumene)-(η-cyclopentadienyl)iron(II) tri- 407-880-9 117549-13-0 Acute Tox. 4 * H302 GHS07 H302
fluoromethane-sulfonate Aquatic H412 Wng H412
Chronic 3
027-002-00-4 cobalt oxide 215-154-6 1307-96-6 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
027-003-00-X cobalt sulphide 215-273-3 1317-42-6 Skin Sens. 1 H317 GHS07 H317
Aquatic Acute 1 H400 GHS09 H410
L 353/421
Aquatic H410 Wng
Chronic 1
L 353/422
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
027-004-00-5 cobalt dichloride 231-589-4 7646-79-9 Carc. 1B H350i GHS08 H350i Carc. 1B; H350i: 1
EN
Acute Tox. 4 * H302 GHS07 H302 C ≥ 0,01 %
Resp. Sens. 1 H334 GHS09 H334 *
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
027-005-00-0 cobalt sulphate 233-334-2 10124-43-3 Carc. 1B H350i GHS08 H350i Carc. 1B; H350i: 1
Acute Tox. 4 * H302 GHS07 H302 C ≥ 0,01 %
028-003-00-2 nickel monoxide 215-215-7 1313-99-1 Carc. 1Ai H350i GHS08 H350i
Skin Sens. 1 H317 GHS07 H317
Aquatic H413 Dgr H413
Chronic 4
028-004-00-8 nickel dioxide 234-823-3 12035-36-8 Carc. 1Ai H350i GHS08 H350i
31.12.2008
Skin Sens. 1 H317 GHS07 H317
Aquatic H413 Dgr H413
Chronic 4
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
028-005-00-3 dinickel trioxide 215-217-8 1314-06-3 Carc. 1Ai H350i GHS08 H350i
EN
Skin Sens. 1 H317 GHS07 H317
Aquatic H413 Dgr H413
Chronic 4
028-006-00-9 nickel sulphide 240-841-2 16812-54-7 Carc. 1Ai H350i GHS08 H350i
Skin Sens. 1 H317 GHS07 H317
Aquatic Acute 1 H400 GHS07 H410
Aquatic H410 GHS09
Chronic 1 Dgr
L 353/423
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
L 353/424
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
029-001-00-4 copper chloride; 231-842-9 7758-89-6 Acute Tox. 4 * H302 GHS07 H302
EN
copper (I) chloride; Aquatic Acute 1 H400 GHS09 H400
cuprous chloride Aquatic H410 Wng H410
Chronic 1
029-002-00-X dicopper oxide; 215-270-7 1317-39-1 Acute Tox. 4 * H302 GHS07 H302
copper (I) oxide Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
029-004-00-0 copper sulphate 231-847-6 7758-98-7 Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 GHS09 H319
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
029-007-00-7 (trisodium (2-((3-(6-(2-chloro-5-sulfonato) 404-670-9 89797-01-3 Skin Sens. 1 H317 GHS07 H317 G
anilino)-4-(3-carboxypyridinio)-1,3,5-tria-
31.12.2008
Wng
zin-2-ylamino)-2-oxido-5-sulfonatopheny-
lazo)phenylmethylazo)-4-sulfonatoben-
zoato)copper(3-)) hydroxide
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
029-008-00-2 copper(II) methanesulfonate 405-400-2 54253-62-2 Acute Tox. 4 * H302 GHS05 H302
EN
Eye Dam. 1 H318 GHS07 H318
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
029-010-00-3 reaction mass of compounds from (dode- 407-700-9 101408-30-4 Skin Sens. 1 H317 GHS07 H317
029-011-00-9 sodium [29H,31H-phthalocyaninato- 412-730-0 150522-10-4 Skin Corr. 1B H314 GHS05 H314
(2-)-N29,N30,N31,N32]-((3-(N-methyl-N- Dgr
(2-hydroxyethyl)amino)propyl)amino)sulfo-
nyl-sulfonato, copper complex
029-012-00-4 sodium ((N-(3-trimethylammoniopropyl) 407-340-2 124719-24-0 Eye Dam. 1 H318 GHS05 H318
sulfamoyl)methylsulfonatophthalocyani- Dgr
nato)copper(II)
030-001-00-1 zinc powder — zinc dust (pyrophoric) 231-175-3 7440-66-6 Water-react. 1 H260 GHS02 H260 T
Pyr. Sol. 1 H250 GHS09 H250
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/425
030-001-01-9 zinc powder — zinc dust (stabilised) 231-175-3 7440-66-6 Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
L 353/426
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
030-003-00-2 zinc chloride 231-592-0 7646-85-7 Acute Tox. 4 * H302 GHS05 H302 STOT SE 3;
H335: C ≥ 5 %
EN
Skin Corr. 1B H314 GHS07 H314
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
030-004-00-8 dimethylzinc; [1] 208-884-1 544-97-8 [1] Pyr. Liq. 1 H250 GHS02 H250 EUH014
diethylzinc [2] [1] 557-20-0 [2] Water-react. 1 H260 GHS05 H260
209-161-3 Skin Corr. 1B H314 GHS09 H314
[2] Aquatic Acute 1 H400 Dgr H410
Aquatic H410
030-006-00-9 zinc sulphate (hydrous) (mono-, hexa- and 231-793-3 7446-19-7 [1] Acute Tox. 4 * H302 GHS05 H302
hepta hydrate); [1] [1] 7733-02-0 [2] Eye Dam. 1 H318 GHS07 H318
zinc sulphate (anhydrous) [2] 231-793-3 Aquatic Acute 1 H400 GHS09 H410
[2] Aquatic H410 Dgr
Chronic 1
31.12.2008
030-011-00-6 trizinc bis(orthophosphate) 231-944-3 7779-90-0 Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
030-013-00-7 zinc oxide 215-222-5 1314-13-2 Aquatic Acute 1 H400 GHS09 H410
EN
Aquatic H410 Wng
Chronic 1
033-005-00-1 arsenic acid and its salts — — Carc. 1A H350 GHS06 H350 A
Acute Tox. 3 * H331 GHS08 H331
Acute Tox. 3 * H301 GHS09 H301
L 353/427
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/428
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Press. Gas H330 GHS04 H330
Acute Tox. 2 * H373 GHS06 H373 **
STOT RE 2 * ** GHS08 H410
Aquatic Acute 1 H400 GHS09
Aquatic H410 Dgr
Chronic 1
034-002-00-8 selenium compounds except cadmium sul- — — Acute Tox. 3 * H331 GHS06 H331 A
phoselenide Acute Tox. 3 * H301 GHS08 H301
STOT RE 2 * H373 GHS09 H373 **
Aquatic Acute 1 ** Dgr H410
Aquatic H400
Chronic 1 H410
034-003-00-3 sodium selenite 233-267-9 10102-18-8 Acute Tox. 2 * H300 GHS06 H300 EUH031
Acute Tox. 3 * H331 GHS09 H331
Skin Sens. 1 H317 Dgr H317
Aquatic H411 H411
Chronic 2
31.12.2008
Skin Corr. 1A H314 GHS05 H314
Aquatic Acute 1 H400 GHS09 H400
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
035-002-00-0 hydrogen bromide 233-113-0 10035-10-6 Press. Gas H314 GHS04 H314 U
EN
Skin Corr. 1A H335 GHS05 H335
STOT SE 3 GHS07
Dgr
035-002-01-8 hydrobromic acid ... % — — Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B; B
STOT SE 3 H335 GHS07 H335 H314: C ≥ 40 %
Dgr Skin Irrit. 2;
H315: 10 % ≤
C < 40 %
035-003-00-6 potassium bromate 231-829-8 7758-01-2 Ox. Sol. 1 H271 GHS03 H271
Carc. 1B H350 GHS06 H350
Acute Tox. 3 * H301 GHS08 H301
Dgr
035-004-00-1 2-hydroxyethylammonium perbromide 407-440-6 — Ox. Sol. 2 **** H272 GHS03 H272
Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1A H314 GHS07 H314
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H400
040-001-00-3 zirconium powder (pyrophoric) 231-176-9 7440-67-7 Water-react. 1 H260 GHS02 H260 T
Pyr. Sol. 1 H250 Dgr H250
040-002-00-9 zirconium powder, dry (non pyrophoric) — — Self-heat. 1 H251 GHS02 H251 T
Dgr
L 353/429
Eye Irrit. 2 ** GHS07 H319
STOT SE 3 H319 Wng H335
H335
L 353/430
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
hexa-μ-oxotetra-μ3-oxodi-μ5-oxotetrade- Eye Dam. 1 H318 GHS05 H318
caoxooctamolybdate(4-) Aquatic H413 Dgr H413
Chronic 4
047-001-00-2 silver nitrate 231-853-9 7761-88-8 Skin Corr. 1B H314 GHS05 H314
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
048-001-00-5 cadmium compounds, with the exception of — — Acute Tox. 4 * H332 GHS07 H332 * A
cadmium sulphoselenide (xCdS.yCdSe), Acute Tox. 4 * H312 GHS09 H312 1
reaction mass of cadmium sulphide with Acute Tox. 4 * H302 Wng H302
zinc sulphide (xCdS.yZnS), reaction mass of Aquatic Acute 1 H400 H410
cadmium sulphide with mercury sulphide
(xCdS.yHgS), and those specified elsewhere Aquatic H410
in this Annex Chronic 1
048-002-00-0 cadmium (non-pyrophoric); [1] 231-152-8 7440-43-9 [1] Carc. 1B H350 GHS06 H350
cadmium oxide (non-pyrophoric) [2] [1] 1306-19-0 [2] Muta. 2 H341 GHS08 H341
215-146-2 Repr. 2 H361f- GHS09 H361fd
[2] Acute Tox. 2 * d Dgr H330
STOT RE 1 H330 H372 **
Aquatic Acute 1 H372 H410
31.12.2008
Aquatic **
Chronic 1 H400
H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
048-003-00-6 cadmium diformate; 224-729-0 4464-23-7 Acute Tox. 3 * H331 GHS06 H331 *
EN
cadmiumformate Acute Tox. 3 * H301 GHS08 H301 STOT RE 2;
Carc. 2 H351 GHS09 H351 H373: C ≥ 0,25 %
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
048-004-00-1 cadmium cyanide 208-829-1 542-83-6 Acute Tox. 2 * H330 GHS06 H330 EUH032 STOT RE 2;
048-006-00-2 cadmium fluoride 232-222-0 7790-79-6 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
Muta. 1B H340 GHS08 H340 ≥ 0,01 %
Repr. 1B H360- GHS09 H360FD * oral
Acute Tox. 2 * FD Dgr H330 STOT RE 1;
Acute Tox. 3 * H330 H301 H372: C ≥ 7 %
STOT RE 1 H301 H372 ** STOT RE 2: 0,1 %
H372 ≤ C < 7%
Aquatic Acute 1 H410
Aquatic **
L 353/431
Chronic 1 H400
H410
L 353/432
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
048-007-00-8 cadmium iodide 232-223-6 7790-80-9 Acute Tox. 3 * H331 GHS06 H331 *
EN
Acute Tox. 3 * H301 GHS08 H301 STOT RE 2;
Carc. 2 H351 GHS09 H351 H373: C ≥ 0,1 %
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
048-008-00-3 cadmium chloride 233-296-7 10108-64-2 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
Muta. 1B H340 GHS08 H340 ≥ 0,01 %
048-009-00-9 cadmium sulphate 233-331-6 10124-36-4 Carc. 1B H350 GHS06 H350 Carc. 1B; H350: C
Muta. 1B H340 GHS08 H340 ≥ 0,01 %
Repr. 1B H360- GHS09 H360FD * oral
Acute Tox. 2 * FD Dgr H330 STOT RE 1;
Acute Tox. 3 * H330 H301 H372: C ≥ 7 %
STOT RE 1 H301 H372 ** STOT RE 2;
H372 H373: 0,1 % ≤ C
Aquatic Acute 1 H410 < 7%
Aquatic **
Chronic 1 H400
H410
31.12.2008
** < 10 %
Aquatic H413
Chronic 4 H302
H413
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
048-011-00-X cadmium (pyrophoric) 231-152-8 7440-43-9 Pyr. Sol. 1 H250 GHS02 H250
EN
Carc. 1B H350 GHS06 H350
Muta. 2 H341 GHS08 H341
Repr. 2 H361f- GHS09 H361fd
Acute Tox. 2 * d Dgr H330
STOT RE 1 H330 H372 **
Aquatic Acute 1 H372 H410
Aquatic **
Chronic 1 H400
H410
050-002-00-0 cyhexatin (ISO); 236-049-1 13121-70-5 Acute Tox. 4 * H332 GHS07 H332
hydroxytricyclohexylstannane; Acute Tox. 4 * H312 GHS09 H312
tri(cyclohexyl)tin hydroxide Acute Tox. 4 * H302 Wng H302
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
050-003-00-6 fentin acetate (ISO); 212-984-0 900-95-8 Carc. 2 H351 GHS06 H351
triphenyltin acetate Repr. 2 H361d GHS08 H361d ***
Acute Tox. 2 * *** GHS05 H330
Acute Tox. 3 * H330 GHS09 H311
Acute Tox. 3 * H311 Dgr H301
STOT RE 1 H301 H372 **
STOT SE 3 H372 H335
Skin Irrit. 2 ** H315
Eye Dam. 1 H335 H318
Aquatic Acute 1 H315 H410
Aquatic H318
L 353/433
Chronic 1 H400
H410
L 353/434
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
050-004-00-1 fentin hydroxide (ISO); 200-990-6 76-87-9 Carc. 2 H351 GHS06 H351
EN
triphenyltin hydroxide Repr. 2 H361d GHS08 H361d ***
Acute Tox. 2 * *** GHS05 H330
Acute Tox. 3 * H330 GHS09 H311
Acute Tox. 3 * H311 Dgr H301
STOT RE 1 H301 H372 **
STOT SE 3 H372 H335
Skin Irrit. 2 ** H315
Eye Dam. 1 H335 H318
Aquatic Acute 1 H315 H410
H318
050-005-00-7 trimethyltin compounds, with the exception — — Acute Tox. 2 * H330 GHS06 H330 * A
of those specified elsewhere in this Annex Acute Tox. 1 H310 GHS09 H310 1
Acute Tox. 2 * H300 Dgr H300
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
050-006-00-2 triethyltin compounds, with the exception of — — Acute Tox. 2 * H330 GHS06 H330 * A
those specified elsewhere in this Annex Acute Tox. 1 H310 GHS09 H310 1
Acute Tox. 2 * H300 Dgr H300
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
050-007-00-8 tripropyltin compounds, with the exception — — Acute Tox. 3 * H331 GHS06 H331 * A
of those specified elsewhere in this Annex Acute Tox. 3 * H311 GHS09 H311 1
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
31.12.2008
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
050-008-00-3 tributyltin compounds, with the exception — — Acute Tox. 3 * H301 GHS06 H301 * oral A
EN
of those specified elsewhere in this Annex STOT RE 1 H372 GHS08 H372 ** STOT RE 1; 1
Acute Tox. 4 * ** GHS09 H312 H372: C ≥ 1 %
Eye Irrit. 2 H312 Dgr H319 STOT RE 2;
Skin Irrit. 2 H319 H315 H373: 0,25 % ≤ C
H315 < 1%
Aquatic Acute 1 H410
H400 * dermal
Aquatic
Chronic 1 H410 Eye Irrit. 2; H319:
C ≥ 1%
Skin Irrit. 2;
H315: C ≥ 1 %
050-011-00-X triphenyltin compounds, with the exception — — Acute Tox. 3 * H331 GHS06 H331 * A
of those specified elsewhere in this Annex Acute Tox. 3 * H311 GHS09 H311 1
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
050-012-00-5 tetracyclohexylstannane; [1] 215-910-5 1449-55-4 [1] Acute Tox. 4 * H332 GHS07 H332 * A
chlorotricyclohexylstannane; [2] [1] 3091-32-5 [2] Acute Tox. 4 * H312 GHS09 H312 1
butyltricyclohexylstannane [3] 221-437-5 7067-44-9 [3] Acute Tox. 4 * H302 Wng H302
[2]
L 353/435
Aquatic Acute 1 H400 H410
230-358-5 Aquatic H410
[3] Chronic 1
L 353/436
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
050-013-00-0 trioctyltin compounds, with the exception of — — Eye Irrit. 2 H319 GHS07 H319 Skin Irrit. 2; A
EN
those specified elsewhere in this Annex STOT SE 3 H335 Wng H335 H315: C ≥ 1 % 1
Skin Irrit. 2 H315 H315 Eye Irrit. 2; H319:
Aquatic H413 H413 C ≥ 1%
Chronic 4 STOT SE 3;
H335: C ≥ 1 %
050-017-00-2 fenbutatin oxide (ISO); 236-407-7 13356-08-6 Acute Tox. 2 * H330 GHS06 H330
bis(tris(2-methyl-2-phenylpropyl)tin)oxide Eye Irrit. 2 H319 GHS09 H319
Skin Irrit. 2 H315 Dgr H315
050-018-00-8 tin(II) methanesulphonate 401-640-7 53408-94-9 Skin Corr. 1B H314 GHS05 H314
Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 Dgr H317
050-019-00-3 azocyclotin (ISO); 255-209-1 41083-11-8 Acute Tox. 2 * H330 GHS06 H330
1-(tricyclohexylstannyl)-1H-1,2,4-triazole Acute Tox. 3 * H301 GHS05 H301
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Dgr H315
Eye Dam. 1 H318 H318
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
051-001-00-8 antimony trichloride 233-047-2 10025-91-9 Skin Corr. 1B H314 GHS05 H314 STOT SE 3;
Aquatic H411 GHS09 H411 H335: C ≥ 5 %
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
051-002-00-3 antimony pentachloride 231-601-8 7647-18-9 Skin Corr. 1B H314 GHS05 H314 STOT SE 3;
EN
Aquatic H411 GHS09 H411 H335: C ≥ 5 %
Chronic 2 Dgr
051-003-00-9 antimony compounds, with the exception of — — Acute Tox. 4 * H332 GHS07 H332 * A
the tetroxide (Sb2O4), pentoxide (Sb2O5), Acute Tox. 4 * H302 GHS09 H302 1
trisulphide (Sb2S3), pentasulphide (Sb2S5) Aquatic H411 Wng H411
and those specified elsewhere in this Annex Chronic 2
051-007-00-0 bis(4-dodecylphenyl)iodonium hexafluoro- 404-420-9 71786-70-4 Skin Sens. 1 H317 GHS07 H317
antimonate Aquatic H412 Wng H412
Chronic 3
L 353/437
Acute Tox. 4 * H312 GHS09 H312
Aquatic Acute 1 H400 Wng H400
L 353/438
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
053-002-00-9 hydrogen iodide 233-109-9 10034-85-2 Press. Gas H314 GHS04 H314 Skin Corr. 1A; U
EN
Skin Corr. 1A GHS05 H314: C ≥ 10 % 5
Dgr Skin Corr. 1B;
H314: 0,2 % ≤ C
< 10 %
Skin Irrit. 2;
H315: 0,02 % ≤ C
< 0,2 %
Eye Irrit. 2; H319:
0,02 % ≤ C
< 0,2 %
STOT SE 3;
H335: C ≥ 0,02 %
056-001-00-1 barium peroxide 215-128-4 1304-29-6 Ox. Sol. 2 H272 GHS03 H272
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
056-002-00-7 barium salts, with the exception of barium — — Acute Tox. 4 * H332 GHS07 H332 * A
sulphate, salts of 1-azo-2-hydroxynaphtha- Acute Tox. 4 * H302 Wng H302 1
lenyl aryl sulphonic acid, and of salts
specified elsewhere in this Annex
31.12.2008
056-003-00-2 barium carbonate 208-167-3 513-77-9 Acute Tox. 4 * H302 GHS07 H302
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
056-004-00-8 barium chloride 233-788-1 10361-37-2 Acute Tox. 3 * H301 GHS06 H301
EN
Acute Tox. 4 * H332 Dgr H332
072-001-00-4 hafnium tetra-n-butoxide 411-740-2 22411-22-9 Eye Dam. 1 H318 GHS05 H318
Skin Sens. 1 H317 GHS07 H317
Dgr
074-001-00-X hexasodium tungstate hydrate 412-770-9 12141-67-2 Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
074-002-00-5 Reaction products of tungsten hexachloride 408-250-6 — Flam. Liq. 2 H225 GHS02 H225
with 2-methylpropan-2-ol, nonylphenol and Acute Tox. 4 * H332 GHS05 H332
pentane-2,4-dione Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
076-001-00-5 osmium tetraoxide; 244-058-7 20816-12-0 Acute Tox. 2 * H330 GHS06 H330
osmic acid Acute Tox. 1 H310 GHS05 H310
Acute Tox. 2 * H300 Dgr H300
Skin Corr. 1B H314 H314
078-001-00-0 tetrachloroplatinates with the exception of — — Acute Tox. 3 * H301 GHS06 H301 A
those specified elsewhere in this Annex Eye Dam. 1 H318 GHS05 H318
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
078-002-00-6 diammonium tetrachloroplatinate 237-499-1 13820-41-2 Acute Tox. 3 * H301 GHS06 H301
Skin Irrit. 2 H315 GHS05 H315
L 353/439
Eye Dam. 1 H318 GHS08 H318
Resp. Sens. 1 H334 Dgr H334
Skin Sens. 1 H317 H317
L 353/440
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
078-003-00-1 disodium tetrachloroplatinate 233-051-4 10026-00-3 Acute Tox. 3 * H301 GHS06 H301
EN
Skin Irrit. 2 H315 GHS05 H315
Eye Dam. 1 H318 GHS08 H318
Resp. Sens. 1 H334 Dgr H334
Skin Sens. 1 H317 H317
078-004-00-7 dipotassium tetrachloroplatinate 233-050-9 10025-99-7 Acute Tox. 3 * H301 GHS06 H301
Skin Irrit. 2 H315 GHS05 H315
Eye Dam. 1 H318 GHS08 H318
Resp. Sens. 1 H334 Dgr H334
078-005-00-2 hexachloroplatinates with the exception of — — Acute Tox. 3 * H301 GHS06 H301 A
those specified elsewhere in this Annex Eye Dam. 1 H318 GHS05 H318
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
078-006-00-8 disodium hexachloroplatinate 240-983-5 16923-58-3 Acute Tox. 3 * H301 GHS06 H301
Eye Dam. 1 H318 GHS05 H318
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
078-007-00-3 dipotassium hexachloroplatinate 240-979-3 16921-30-5 Acute Tox. 3 * H301 GHS06 H301
Eye Dam. 1 H318 GHS05 H318
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
078-008-00-9 diammonium hexachloroplatinate 240-973-0 16919-58-7 Acute Tox. 3 * H301 GHS06 H301
Eye Dam. 1 H318 GHS05 H318
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
078-009-00-4 hexachloroplatinic acid 241-010-7 16941-12-1 Acute Tox. 3 * H301 GHS06 H301
31.12.2008
Skin Corr. 1B H314 GHS05 H314
Resp. Sens. 1 H334 GHS08 H334
Skin Sens. 1 H317 Dgr H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
STOT RE 2 * H373 GHS08 H373 **
Aquatic Acute 1 ** GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
080-002-00-6 inorganic compounds of mercury with the — — Acute Tox. 2 * H330 GHS06 H330 * A
exception of mercuric sulphide and those Acute Tox. 1 H310 GHS08 H310 STOT RE 2; 1
specified elsewhere in this Annex Acute Tox. 2 * H300 GHS09 H300 H373: C ≥ 0,1 %
STOT RE 2 * H373 Dgr H373 **
080-003-00-1 dimercury dichloride; 233-307-5 10112-91-1 Acute Tox. 4 * H302 GHS07 H302
mercurous chloride; Eye Irrit. 2 H319 GHS09 H319
calomel STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
080-004-00-7 organic compounds of mercury with the — — Acute Tox. 2 * H330 GHS06 H330 * A
exception of those specified elsewhere in Acute Tox. 1 H310 GHS08 H310 STOT RE 2; 1
this Annex Acute Tox. 2 * H300 GHS09 H300 H373: C ≥ 0,1 %
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
080-005-00-2 mercury difulminate; 211-057-8 628-86-4 Unst. Expl. H200 GHS01 H200
mercuric fulminate; Acute Tox. 3 * H331 GHS06 H331
fulminate of mercury Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
L 353/441
Aquatic Acute 1 ** H400
Aquatic H400 H410
Chronic 1 H410
L 353/442
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
080-005-01-X mercury difulminate; 211-057-8 628-86-4 Expl. 1.1 H201 GHS01 H201
mercuric fulminate; Acute Tox. 3 * H331 GHS06 H331
fulminate of mercury [≥ 20 % phlegmatiser] Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H400
Aquatic H400 H410
Chronic 1 H410
080-007-00-3 dimethylmercury; [1] 209-805-3 593-74-8 [1] Acute Tox. 2 * H330 GHS06 H330 * 1
diethylmercury [2] [1] 627-44-1 [2] Acute Tox. 1 H310 GHS08 H310 STOT RE 2;
211-000-7 Acute Tox. 2 * H300 GHS09 H300 H373: C ≥ 0,05 %
[2] STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
080-008-00-9 phenylmercury nitrate; [1] 200-242-9 55-68-5 [1] Acute Tox. 3 * H301 GHS06 H301
phenylmercury hydroxide; [2] [1] 100-57-2 [2] STOT RE 1 H372 GHS08 H372 **
basic phenylmercury nitrate [3] 202-866-7 8003-05-2 [3] Skin Corr. 1B ** GHS05 H314
[2] Aquatic Acute 1 H314 GHS09 H410
31.12.2008
-[3] Aquatic H400 Dgr
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
080-009-00-4 2-methoxyethylmercury chloride 204-659-7 123-88-6 Acute Tox. 3 * H301 GHS06 H301
EN
STOT RE 1 H372 GHS08 H372 **
Skin Corr. 1B ** GHS05 H314
Aquatic Acute 1 H314 GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
080-010-00-X mercury dichloride; 231-299-8 7487-94-7 Acute Tox. 2 * H300 GHS06 H300
mercuric chloride STOT RE 1 H372 GHS08 H372 **
Skin Corr. 1B ** GHS05 H314
H314
080-011-00-5 phenylmercury acetate 200-532-5 62-38-4 Acute Tox. 3 * H301 GHS06 H301
STOT RE 1 H372 GHS08 H372 **
Skin Corr. 1B ** GHS05 H314
Aquatic Acute 1 H314 GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
081-002-00-9 thallium compounds, with the exception of — — Acute Tox. 2 * H330 GHS06 H330 A
those specified elsewhere in this Annex Acute Tox. 2 * H300 GHS08 H300
STOT RE 2 * H373 GHS09 H373 **
Aquatic ** Dgr H411
Chronic 2 H411
081-003-00-4 dithallium sulphate; 231-201-3 7446-18-6 Acute Tox. 2 * H300 GHS06 H300
thallic sulphate STOT RE 1 H372 GHS08 H372 **
L 353/443
Skin Irrit. 2 ** GHS09 H315
Aquatic H315 Dgr H411
Chronic 2 H411
L 353/444
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
082-001-00-6 lead compounds with the exception of those — — Repr. 1A H360- GHS08 H360Df Repr. 2; H361f: C A
EN
specified elsewhere in this Annex Acute Tox. 4 * Df GHS07 H332 ≥ 2,5 % 1
Acute Tox. 4 * H332 GHS09 H302 *
STOT RE 2 * H302 Dgr H373 ** STOT RE 2;
Aquatic Acute 1 H373 H410 H373: C ≥ 0,5 %
Aquatic **
Chronic 1 H400
H410
082-002-00-1 lead alkyls — — Repr. 1A H360- GHS06 H360Df Repr. 1A; H360D: A
082-003-00-7 lead diazide; 236-542-1 13424-46-9 Unst. Expl. H200 GHS01 H200 1
lead azide Repr. 1A H360- GHS08 H360Df
Acute Tox. 4 * Df GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
STOT RE 2 * H302 Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
082-003-01-4 lead diazide; 236-542-1 13424-46-9 Expl. 1.1 H201 GHS01 H201 1
lead azide [≥ 20 % phlegmatiser] Repr. 1A H360- GHS08 H360Df
Acute Tox. 4 * Df GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
STOT RE 2 * H302 Dgr H373 **
Aquatic Acute 1 H373 H410
31.12.2008
Aquatic **
Chronic 1 H400
H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Repr. 1A H360- GHS09 H360Df
STOT RE 2 * Df Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
082-007-00-9 lead acetate, basic 215-630-3 1335-32-6 Carc. 2 H351 GHS08 H351 1
Repr. 1A H360- GHS09 H360Df
STOT RE 2 * Df Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
L 353/445
Eye Dam. 1 ** H318
H315
H318
L 353/446
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
082-009-00-X Lead sulfochromate yellow; 215-693-7 1344-37-2 Carc. 2 H351 GHS08 H351 1
EN
C.I. Pigment Yellow 34; Repr. 1A H360- GHS09 H360Df
[This substance is identified in the Colour STOT RE 2 * Df Dgr H373 **
Index by Colour Index Constitution Num- Aquatic Acute 1 H373 H410
ber, C.I. 77603.] Aquatic **
Chronic 1 H400
H410
082-010-00-5 Lead chromate molybdate sulfate red; 235-759-9 12656-85-8 Carc. 2 H351 GHS08 H351 1
C.I. Pigment Red 104; Repr. 1A H360- GHS09 H360Df
082-011-00-0 lead hydrogen arsenate 232-064-2 7784-40-9 Carc. 1A H350 GHS06 H350 1
Repr. 1A H360- GHS08 H360Df
Acute Tox. 3 * Df GHS09 H331
Acute Tox. 3 * H331 Dgr H301
STOT RE 2 * H301 H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
31.12.2008
STOT RE 2 * H373 GHS09 H373 **
Aquatic ** Dgr H411
Chronic 2 H411
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Press. Gas GHS04
Dgr
601-004-00-0 butane; [1] 203-448-7 106-97-8 [1] Flam. Gas 1 H220 GHS02 H220 CU
and isobutane [2] [1] 75-28-5 [2] Press. Gas GHS04
200-857-2 Dgr
[2]
601-004-01-8 butane (containing ≥ 0,1 % butadiene (203- 203-448-7 106-97-8 [1] Flam. Gas 1 H220 GHS02 H220 CSU
450-8)); [1] [1] 75-28-5 [2] Press. Gas H350 GHS04 H350
isobutane (containing ≥ 0,1 % butadiene 200-857-2 Carc. 1A H340 GHS08 H340
(203-450-8)) [2] [2] Muta. 1B Dgr
601-006-00-1 pentane 203-692-4 109-66-0 Flam. Liq. 2 H225 GHS02 H225 EUH066 C
Asp. Tox. 1 H304 GHS08 H304
STOT SE 3 H336 GHS07 H336
L 353/447
Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/448
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
601-007-00-7 hexane, reaction mass of isomers (contain- — — Flam. Liq. 2 H225 GHS02 H225 C
ing < 5 % n-hexane (203-777-6)) Asp. Tox. 1 H304 GHS08 H304
Skin Irrit. 2 H315 GHS07 H315
STOT SE 3 H336 GHS09 H336
Aquatic H411 Dgr H411
Chronic 2
31.12.2008
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
601-009-00-8 octane [and isomers] [1] 203-892-1 111-65-9 [1] Flam. Liq. 2 H225 GHS02 H225 C
[1] 540-84-1 [2] Asp. Tox. 1 H304 GHS08 H304
208-759-1 560-21-4 [3] Skin Irrit. 2 H315 GHS07 H315
[2] 563-16-6 [4] STOT SE 3 H336 GHS09 H336
209-207-2 564-02-3 [5] Aquatic Acute 1 H400 Dgr H410
[3]
565-75-3 [6] Aquatic H410
209-243-9 Chronic 1
[4] 583-48-2 [7]
584-94-1 [8]
L 353/449
L 353/450
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Press. Gas H336 GHS04 H336
STOT SE 3 GHS07
Dgr
601-012-00-4 but-1-ene; [1] 203-449-2 106-98-9 [1] Flam. Gas 1 H220 GHS02 H220 CU
601-014-00-5 isoprene (stabilised) 201-143-3 78-79-5 Flam. Liq. 1 H224 GHS02 H224 D
2-methyl-1,3-butadiene Carc. 1B H350 GHS08 H350
Muta. 2 H341 Dgr H341
Aquatic H412 H412
Chronic 3
601-015-00-0 acetylene; 200-816-9 74-86-2 Flam. Gas 1 H220 GHS02 H220 EUH006 U
ethyne Press. Gas GHS04
Dgr
31.12.2008
601-016-00-6 cyclopropane 200-847-8 75-19-4 Flam. Gas 1 H220 GHS02 H220 U
Press. Gas GHS04
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
601-017-00-1 cyclohexane 203-806-2 110-82-7 Flam. Liq. 2 H225 GHS02 H225
Asp. Tox. 1 H304 GHS08 H304
Skin Irrit. 2 H315 GHS07 H315
STOT SE 3 H336 GHS09 H336
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/451
Skin Irrit. 2 H315
H315
L 353/452
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Repr. 2 H361d GHS08 H361d ***
Asp. Tox. 1 *** GHS07 H304
STOT RE 2 * H304 Dgr H373 **
Skin Irrit. 2 H373 H315
STOT SE 3 ** H336
H315
H336
601-022-00-9 o-xylene; [1] 202-422-2 95-47-6 [1] Flam. Liq. 3 H226 GHS02 H226 * C
601-024-00-X cumene; [1] 202-704-5 98-82-8 [1] Flam. Liq. 3 H226 GHS02 H226 C
propylbenzene [2] [1] 103-65-1 [2] Asp. Tox. 1 H304 GHS08 H304
203-132-9 STOT SE 3 H335 GHS07 H335
[2] Aquatic H411 GHS09 H411
Chronic 2 Dgr
601-025-00-5 mesitylene; 203-604-4 108-67-8 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
1,3,5-trimethylbenzene STOT SE 3 H335 GHS07 H335 H335: C ≥ 25 %
Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Acute Tox. 4 * H332 GHS07 H332
Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
601-027-00-6 2-phenylpropene; 202-705-0 98-83-9 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
EN
α-methylstyrene Eye Irrit. 2 H319 GHS07 H319 H335: C ≥ 25 %
STOT SE 3 H335 GHS09 H335
Aquatic H411 Wng H411
Chronic 2
601-032-00-3 benzo[a]pyrene; 200-028-5 50-32-8 Carc. 1B H350 GHS08 H350 Carc. 1B; H350:
benzo[def]chrysene Muta. 1B H340 GHS07 H340 C ≥ 0,01 %
Repr. 1B H360- GHS09 H360FD
Skin Sens. 1 FD Dgr H317
L 353/453
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
L 353/454
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
601-037-00-0 n-hexane 203-777-6 110-54-3 Flam. Liq. 2 H225 GHS02 H225 STOT RE 2;
Repr. 2 H361f GHS08 H361f *** H373: C ≥ 5 %
Asp. Tox. 1 *** GHS07 H304
STOT RE 2 * H304 GHS09 H373 **
Skin Irrit. 2 H373 Dgr H315
STOT SE 3 ** H336
Aquatic H315 H411
Chronic 2 H336
H411
601-041-00-2 dibenz[a,h]anthracene 200-181-8 53-70-3 Carc. 1B H350 GHS08 H350 Carc. 1B; H350: C
31.12.2008
Aquatic Acute 1 H400 GHS09 H410 ≥ 0,01 %
Aquatic H410 Dgr
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
diphenyl STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
601-045-00-4 1,2,3,4-tetrahydronaphthalene 204-340-2 119-64-2 Eye Irrit. 2 H319 GHS07 H319 EUH019
Skin Irrit. 2 H315 GHS09 H315
Aquatic H411 Wng H411
Chronic 2
L 353/455
601-047-00-5 m-mentha-1,3(8)-diene 404-150-1 17092-80-7 Skin Irrit. 2 H315 GHS07 H315
Aquatic H411 GHS09 H411
Chronic 2 Wng
L 353/456
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Muta. 2 H341 GHS09 H341
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
601-053-00-8 nonylphenol; [1] 246-672-0 25154-52-3 [1] Repr. 2 H361f- GHS08 H361fd
4-nonylphenol, branched [2] [1] 84852-15-3 [2] Acute Tox. 4 * d GHS05 H302
284-325-5 Skin Corr. 1B H302 GHS07 H314
[2] Aquatic Acute 1 H314 GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
601-054-00-3 reaction mass of isomers of: dibenzylben- 405-570-8 — Aquatic Acute 1 H400 GHS09 H410
zene; Aquatic H410 Wng
dibenzyl(methyl)benzene; Chronic 1
dibenzyl(dimethyl)benzene;
dibenzyl(trimethyl)benzene
601-055-00-9 reaction mass of isomers of: mono-(2- 410-190-0 132983-41-6 Eye Irrit. 2 H319 GHS07 H319
31.12.2008
tetradecyl)naphthalenes; Aquatic H413 Wng H413
di-(2-tetradecyl)naphthalenes; Chronic 4
tri-(2-tetradecyl)naphthalenes
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
601-056-00-4 reaction mass of isomers of: methyldiphe- 405-470-4 73807-39-3 Skin Irrit. 2 H315 GHS07 H315
EN
nylmethane; Aquatic Acute 1 H400 GHS09 H410
dimethyldiphenylmethane Aquatic H410 Wng
Chronic 1
601-059-00-0 methyl 2-benzylidene-3-oxobutyrate 420-940-9 15768-07-7 Eye Irrit. 2 H319 GHS07 H319
Skin Irrit. 2 H315 GHS09 H315
Aquatic H411 Wng H411
Chronic 2
601-062-00-7 reaction mass of: branched triacontane; 417-030-9 151006-59-6 Aquatic H413 — H413
L 353/457
branched dotriacontane; Chronic 4
branched tetratriacontane;
branched hexatriacontane
L 353/458
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
601-063-00-2 reaction mass of isomers of branched 417-060-2 151006-61-0 Acute Tox. 4 * H332 GHS07 H332
EN
tetracosane Aquatic H413 Wng H413
Chronic 4
601-065-00-3 reaction mass of: (1'-α,3'-α,6'-α-2,2,3',7',7'- 416-930-9 — STOT RE 2 * H373 GHS08 H373 **
pentamethylspiro(1,3-dioxane-5,2'-norcar- Eye Dam. 1 ** GHS05 H318
601-066-00-9 1-(4-(trans-4-heptylcyclohexyl)phenyl) etha- 426-820-2 78531-60-9 Skin Sens. 1 H317 GHS07 H317
none Aquatic H413 Wng H413
Chronic 4
31.12.2008
601-071-00-6 1-dimethoxymethyl-2-nitro-benzene 423-830-9 20627-73-0 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
601-073-00-7 1-bromo-3,5-difluorobenzene 416-710-2 461-96-1 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 4 * H302 GHS08 H302
STOT RE 2 * H373 GHS07 H373 **
Skin Irrit. 2 ** GHS09 H315
Skin Sens. 1 H315 Wng H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
601-085-00-2 isopentane; 201-142-8 78-78-4 Flam. Liq. 1 H224 GHS02 H224 EUH066
2-methylbutane Asp. Tox. 1 H304 GHS08 H304
STOT SE 3 H336 GHS07 H336
Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/459
Carc. 2 H373 GHS08 H373 **
STOT RE 2 * ** Dgr
L 353/460
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
602-002-00-2 bromomethane; 200-813-2 74-83-9 Press. Gas H341 GHS04 H341 EUH059 U
EN
methylbromide Muta. 2 H331 GHS06 H331
Acute Tox. 3 * H301 GHS08 H301
Acute Tox. 3 * H373 GHS09 H373 **
STOT RE 2 * ** Dgr H319
Eye Irrit. 2 H319 H335
STOT SE 3 H335 H315
Skin Irrit. 2 H315 H400
Aquatic Acute 1 H400
Ozone EU-
H059
31.12.2008
Skin Irrit. 2 H373 H315
**
H315
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
tribromomethane Eye Irrit. 2 H319 GHS09 H319
Skin Irrit. 2 H315 Dgr H315
Aquatic H411 H411
Chronic 2
602-008-00-5 carbon tetrachloride; 200-262-8 56-23-5 Carc. 2 H351 GHS06 H351 EUH059 *
tetrachloromethane Acute Tox. 3 * H331 GHS08 H331 STOT RE 1;
Acute Tox. 3 * H311 Dgr H311 H372: C ≥ 1 %
Acute Tox. 3 * H301 H301 STOT RE 2;
L 353/461
STOT SE 3 H335 H335
Aquatic H412 H412
Chronic 3
L 353/462
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
ethylene dichloride Carc. 1B H350 GHS08 H350
Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 Dgr H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
602-013-00-2 1,1,1-trichloroethane; 200-756-3 71-55-6 Acute Tox. 4 * H332 GHS07 H332 EUH059 F
methyl chloroform Ozone EU- Wng
H059
602-018-00-X 1-chloropropane; [1] 208-749-7 540-54-5 [1] Flam. Liq. 2 H225 GHS02 H225 C
31.12.2008
2-chloropropane [2] [1] 75-29-6 [2] Acute Tox. 4 * H332 GHS07 H332
200-858-8 Acute Tox. 4 * H312 Dgr H312
[2] Acute Tox. 4 * H302 H302
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
n-propyl bromide Repr. 1B H360- GHS08 H360FD
STOT RE 2 * FD GHS07 H373 **
Eye Irrit. 2 H373 Dgr H319
STOT SE 3 ** H335
Skin Irrit. 2 H319 H315
STOT SE 3 H335 H336
H315
H336
602-022-00-1 1-chloropentane; [1] 208-846-4 543-59-9 [1] Flam. Liq. 2 H225 GHS02 H225 C
2-chloropentane; [2] [1] 625-29-6 [2] Acute Tox. 4 * H332 GHS07 H332
3-chloropentane [3] 210-885-7 616-20-6 [3] Acute Tox. 4 * H312 Dgr H312
[2] Acute Tox. 4 * H302 H302
210-467-4
[3]
602-023-00-7 vinyl chloride; 200-831-0 75-01-4 Press. Gas H220 GHS02 H220 DU
chloroethylene Flam. Gas 1 H350 GHS08 H350
Carc. 1A Dgr
L 353/463
602-024-00-2 bromoethylene 209-800-6 593-60-2 Press. Gas H220 GHS02 H220 U
Flam. Gas 1 H350 GHS08 H350
Carc. 1B Dgr
L 353/464
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
vinylidene chloride Carc. 2 H351 GHS08 H351
Acute Tox. 4 * H332 GHS07 H332
Dgr
602-026-00-3 1,2-dichloroethylene; [1] 208-750-2 540-59-0 [1] Flam. Liq. 2 H225 GHS02 H225 * C
cis-dichloroethylene; [2] [1] 156-59-2 [2] Acute Tox. 4 * H332 GHS07 H332
trans-dichloroethylene [3] 205-859-7 156-60-5 [3] Aquatic H412 Dgr H412
[2] Chronic 3
205-860-2
31.12.2008
Skin Irrit. 2 H335 H315
Aquatic Acute 1 H315 H400
H400
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
602-030-00-5 1,3-dichloropropene; [1] 208-826-5 542-75-6 [1] Flam. Liq. 3 H226 GHS02 H226 CD
EN
(Z)-1,3-dichloropropene [2] [1] 10061-01-5 [2] Acute Tox. 3 * H301 GHS06 H301
233-195-8 Acute Tox. 4 * H332 GHS09 H332
[2] Acute Tox. 4 * H312 Dgr H312
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/465
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/466
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
p-dichlorobenzene Eye Irrit. 2 H319 GHS09 H319
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
602-036-00-8 chloroprene (stabilised); 204-818-0 126-99-8 Flam. Liq. 2 H225 GHS02 H225 D
2-chlorobuta-1,3-diene (stabilised) Carc. 1B H350 GHS08 H350
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
31.12.2008
PCB Aquatic Acute 1 ** GHS09 H410 H373: C ≥
Aquatic H400 Wng 0,005 %
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
602-040-00-X 2-chlorotoluene; [1] 202-424-3 95-49-8 [1] Acute Tox. 4 * H332 GHS07 H332 C
3-chlorotoluene; [2] [1] 108-41-8 [2] Aquatic H411 GHS09 H411
4-chlorotoluene; [3] 203-580-5 106-43-4 [3] Chronic 2 Wng
chlorotoluene [4] [2] 25168-05-2 [4]
203-397-0
[3]
246-698-2
[4]
602-043-00-6 lindane (ISO); 200-401-2 58-89-9 Acute Tox. 3 * H301 GHS06 H301 M=10
γ-HCH or γ-BHC; Acute Tox. 4 * H332 GHS08 H332
γ-1,2,3,4,5,6-hexachlorocyclohexane Acute Tox. 4 * H312 GHS09 H312
STOT RE 2 * H373 Dgr H373 **
Lact. ** H362
Aquatic Acute 1 H362 H410
L 353/467
Aquatic H400
Chronic 1 H410
L 353/468
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
toxaphene; Acute Tox. 3 * H301 GHS08 H301
Acute Tox. 4 * H312 GHS09 H312
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 1 H310 GHS08 H310
Acute Tox. 3 * H301 GHS09 H301
STOT RE 1 H372 Dgr H372 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
602-051-00-X endrin (ISO); 200-775-7 72-20-8 Acute Tox. 2 * H300 GHS06 H300
1,2,3,4,10,10-hexachloro-6,7-epoxy- Acute Tox. 3 * H311 GHS09 H311
1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8- Aquatic Acute 1 H400 Dgr H410
dimethanonaphthalene Aquatic H410
Chronic 1
602-052-00-5 endosulfan (ISO); 204-079-4 115-29-7 Acute Tox. 3 * H311 GHS06 H311
1,2,3,4,7,7-hexachloro-8,9,10-trinorborn-2- Acute Tox. 3 * H301 GHS09 H301
en-5,6-ylenedimethyl sulphite Eye Irrit. 2 H319 Dgr H319
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
602-053-00-0 isobenzan (ISO); 206-045-4 297-78-9 Acute Tox. 1 H310 GHS06 H310
1,3,4,5,6,7,8,8-octachloro-1,3,3a,4,7,7a- Acute Tox. 2 * H300 GHS09 H300
hexahydro-4,7-methanoisobenzofuran Aquatic Acute 1 H400 Dgr H400
L 353/469
allyl iodide Skin Corr. 1B H314 GHS05 H314
Dgr
L 353/470
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
ethyl bromide Carc. 2 H351 GHS08 H351
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
31.12.2008
602-061-00-4 hexafluoropropene; 204-127-4 116-15-4 Press. Gas H332 GHS07 H332 U
hexafluoropropylene Acute Tox. 4 * H335 Wng H335
STOT SE 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Repr. 1B H360F GHS07 H360F ***
Acute Tox. 4 * *** Dgr H332
Acute Tox. 4 * H332 H312
Acute Tox. 4 * H312 H302
H302
L 353/471
602-068-00-2 ethylene bis(trichloroacetate) 219-732-9 2514-53-6 Skin Irrit. 2 H315 GHS07 H315
Wng
L 353/472
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Carc. 2 H351 GHS08 H351
STOT RE 2 * H373 Wng H373 **
**
602-070-00-3 3-chloro-4,5,α, α,α-pentafluorotoluene 401-930-3 77227-99-7 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 GHS09 H302
Aquatic Acute 1 H400 Wng H400
602-072-00-4 dichloro [(dichlorophenyl)methyl]methyl- 278-404-3 76253-60-6 Aquatic Acute 1 H400 GHS09 H410
benzene, reaction mass of isomers; Aquatic H410 Wng
(dichlorophenyl)(dichlorotolyl)methane, Chronic 1
reaction mass of isomers (IUPAC)
602-073-00-X 1,4-dichlorobut-2-ene 212-121-8 764-41-0 Carc. 1B H350 GHS06 H350 Carc. 1B; H350:
Acute Tox. 2 * H330 GHS08 H330 C ≥ 0,01 %
Acute Tox. 3 * H311 GHS05 H311 STOT SE 3;
Acute Tox. 3 * H301 GHS09 H301 H335: C ≥ 5 %
Skin Corr. 1B H314 Dgr H314
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
602-075-00-0 4,4,5,5-tetrachloro-1,3-dioxolan-2-one 404-060-2 22432-68-4 Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 Dgr H314
602-076-00-6 2,3,4-trichlorobut-1-ene 219-397-9 2431-50-7 Carc. 2 H351 GHS06 H351 Carc. 2; H351:
Acute Tox. 3 * H331 GHS08 H331 C ≥ 0,1 %
Acute Tox. 4 * H302 GHS09 H302
L 353/473
Aquatic H410
Chronic 1
L 353/474
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2,3-dichloropropylene Muta. 2 H341 GHS08 H341
Acute Tox. 4 * H332 GHS05 H332
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Eye Dam. 1 H318 H318
Aquatic H412 H412
Chronic 3
602-083-00-4 diphenyl ether, pentabromo derivative pen- 251-084-2 32534-81-9 STOT RE 2 * H373 GHS08 H373 **
tabromodiphenyl ether Lact. ** GHS09 H362
Aquatic Acute 1 H362 Wng H410
Aquatic H400
Chronic 1 H410
31.12.2008
602-084-00-X 1,1-dichloro-1-fluoroethane 404-080-1 1717-00-6 Aquatic H412 — H412 EUH059
Chronic 3 EU-
Ozone H059
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
602-085-00-5 2-bromopropane 200-855-1 75-26-3 Flam. Liq. 2 H225 GHS02 H225 EUH066
EN
Repr. 1A H360F GHS08 H360F ***
STOT RE 2 * *** Dgr H373 **
H373
**
L 353/475
Skin Irrit. 2 ** Wng H315
H315 H411
H411
L 353/476
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Carc. 2 H351 GHS08 H351
Skin Irrit. 2 H315 GHS05 H315
Eye Dam. 1 H318 GHS09 H318
Aquatic H411 Dgr H411
Chronic 2
602-094-00-4 diphenylether; octabromo derivate 251-087-9 32536-52-0 Repr. 1B H360- GHS08 H360Df
Df Dgr
602-096-00-5 malachite green hydrochloride; [1] 209-322-8 569-64-2 [1] Repr. 2 H361d GHS08 H361d ***
malachite green oxalate [2] [1] 2437-29-8 [2] Acute Tox. 4 * *** GHS05 H302
219-441-7 Eye Dam. 1 H302 GHS07 H318
[2] Aquatic Acute 1 H318 GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
31.12.2008
Acute Tox. 3 * H301 Dgr H301 STOT SE 2;
STOT SE 1 H370 H370 ** H371: 3 % ≤ C <
** 10 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
ethyl alcohol Dgr
603-006-00-7 pentanol isomers, with the exception fo 250-378-8 Flam. Liq. 3 H226 GHS02 H226 EUH066 C
those specified elsewhere in this Annex Acute Tox. 4 * H332 GHS07 H332
STOT SE 3 H335 Wng H335
603-008-00-8 4-methylpentan-2-ol; 203-551-7 108-11-2 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
methyl isobutyl carbinol STOT SE 3 H335 GHS07 H335 H335: C ≥ 25 %
Wng
L 353/477
Acute Tox. 4 * H302 Wng H302
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
L 353/478
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
603-010-00-9 2-methylcyclohexanol, mixed isomers; [1] 209-512-0 583-59-5 [1] Acute Tox. 4 * H332 GHS07 H332 C
cis-2-methylcyclohexanol; [2] [1] 7443-70-1 [2] Wng
trans-2-methylcyclohexanol [3] 231-187-9 7443-52-9 [3]
[2]
231-186-3
[3]
31.12.2008
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-015-00-6 allyl alcohol 203-470-7 107-18-6 Flam. Liq. 2 H225 GHS02 H225
EN
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H400
603-018-00-2 furfuryl alcohol 202-626-1 98-00-0 Acute Tox. 4 * H332 GHS07 H332 *
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
603-019-00-8 dimethyl ether 204-065-8 115-10-6 Flam. Gas 1 H220 GHS02 H220 U
Press. Gas GHS04
Dgr
603-020-00-3 ethyl methyl ether — 540-67-0 Flam. Gas 1 H220 GHS02 H220 U
Press. Gas GHS04
Dgr
603-021-00-9 methyl vinyl ether 203-475-4 107-25-5 Flam. Gas 1 H220 GHS02 H220 DU
Press. Gas GHS04
Dgr
603-022-00-4 diethyl ether; 200-467-2 60-29-7 Flam. Liq. 1 H224 GHS02 H224 EUH019
L 353/479
ether Acute Tox. 4 * H302 GHS07 H302 EUH066
STOT SE 3 H336 Dgr H336
L 353/480
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-023-00-X ethylene oxide; 200-849-9 75-21-8 Flam. Gas 1 H220 GHS02 H220 U
EN
oxirane Press. Gas H350 GHS04 H350
Carc. 1B H340 GHS06 H340
Muta. 1B H331 GHS08 H331
Acute Tox. 3 * H319 Dgr H319
Eye Irrit. 2 H335 H335
STOT SE 3 H315 H315
Skin Irrit. 2
603-025-00-0 tetrahydrofuran 203-726-8 109-99-9 Flam. Liq. 2 H225 GHS02 H225 EUH019 Eye Irrit. 2; H319:
Eye Irrit. 2 H319 GHS07 H319 C ≥ 25 %
STOT SE 3 H335 Dgr H335 STOT SE 3;
H335: C ≥ 25 %
31.12.2008
603-028-00-7 2-chloroethanol; 203-459-7 107-07-3 Acute Tox. 2 * H330 GHS06 H330
ethylene chlorohydrin Acute Tox. 1 H310 Dgr H310
Acute Tox. 2 * H300 H300
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 2 * H330 GHS08 H330
Acute Tox. 1 H310 Dgr H310
Acute Tox. 2 * H300 H300
603-030-00-8 2-aminoethanol; 205-483-3 141-43-5 Acute Tox. 4 * H332 GHS05 H332 STOT SE 3;
ethanolamine Acute Tox. 4 * H312 GHS07 H312 H335: C ≥ 5 %
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
603-032-00-9 ethylene dinitrate; 211-063-0 628-96-6 Unst. Expl. H200 GHS01 H200
ethylene glycol dinitrate Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 Dgr H300
STOT RE 2 * H373 H373 **
**
603-033-00-4 oxydiethylene dinitrate; 211-745-8 693-21-0 Unst. Expl H200 GHS01 H200
diethylene glycol dinitrate; Acute Tox. 2 * H330 GHS06 H330
digol dinitrate Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 Dgr H300
STOT RE 2 * H373 H373 **
Aquatic ** H412
Chronic 3 H412
603-033-01-1 oxydiethylene dinitrate; 211-745-8 693-21-0 Expl. 1.1 H201 GHS01 H201
diethylene glycol dinitrate; Acute Tox. 2 * H330 GHS06 H330
digol dinitrate; Acute Tox. 1 H310 GHS08 H310
[>25 % phlegmatiser] Acute Tox. 2 * H300 Dgr H300
L 353/481
STOT RE 2 * H373 H373 **
Aquatic ** H412
Chronic 3 H412
L 353/482
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-034-00-X glycerol trinitrate; 200-240-8 55-63-0 Unst. Expl. H200 GHS01 H200
EN
nitroglycerine Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 GHS09 H300
STOT RE 2 * H373 Dgr H373 **
Aquatic ** H411
Chronic 2 H411
603-034-01-7 glycerol trinitrate; 200-240-8 55-63-0 Expl. 1.1 H201 GHS01 H201
nitroglycerine; Acute Tox. 2 * H330 GHS06 H330
603-035-00-5 pentaerythritol tetranitrate; pentaerythrite 201-084-3 78-11-5 Unst. Expl. H200 GHS01 H200
tetranitrate; Dgr
P.E.T.N.
603-035-01-2 pentaerythritol tetranitrate; pentaerythrite 201-084-3 78-11-5 Expl. 1.1 H201 GHS01 H201 T
tetranitrate; Dgr
P.E.T.N.;
[>20 % phlegmatiser]
603-036-00-0 mannitol hexanitrate; 239-924-6 15825-70-4 Unst. Expl. H200 GHS01 H200
nitromannite Dgr
603-036-01-8 mannitol hexanitrate; 239-924-6 15825-70-4 Expl. 1.1 H201 GHS01 H201
nitromannite; Dgr
[>40 % phlegmatiser]
31.12.2008
603-037-00-6 cellulose nitrate; — — Expl. 1.1 H201 GHS01 H201 EUH001 T
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-038-00-1 allyl glycidyl ether; 203-442-4 106-92-3 Flam. Liq. 3 H226 GHS02 H226
EN
allyl 2,3-epoxypropyl ether; Carc. 2 H351 GHS08 H351
prop-2-en-1-yl 2,3-epoxypropyl ether Muta. 2 H341 GHS05 H341
Repr. 2 H361f GHS07 H361f ***
Acute Tox. 4 * *** Dgr H332
Acute Tox. 4 * H332 H302
STOT SE 3 H302 H335
Skin Irrit. 2 H335 H315
Eye Dam. 1 H315 H318
Skin Sens. 1 H318 H317
Aquatic H317 H412
603-039-00-7 butyl glycidyl ether; 219-376-4 2426-08-6 Flam. Liq. 3 H226 GHS02 H226
butyl 2,3-epoxypropyl ether Carc. 2 H351 GHS08 H351
Muta. 2 H341 GHS07 H341
Acute Tox. 4 * H332 Wng H332
Acute Tox. 4 * H302 H302
STOT SE 3 H335 H335
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
603-040-00-2 sodium methanolate; 204-699-5 124-41-4 [1] Self-heat 1 H251 GHS02 H251 EUH014 T
sodium methoxide; [1] [1] 865-33-8 [2] Skin Corr. 1B H314 GHS05 H314
potassium methanolate; 212-736-1 865-34-9 [3] Dgr
potassium methoxide; [2] [2]
lithium methanolate; 212-737-7
[3]
lithium methoxide [3]
603-041-00-8 potassium ethanolate; 213-029-0 917-58-8 [1] Self-heat 1 H251 GHS02 H251 EUH014 T
potassium ethoxide; [1] [1] 141-52-6 [2] Skin Corr. 1B H314 GHS05 H314
sodium ethanolate; 205-487-5 Dgr
sodium ethoxide [2] [2]
L 353/483
603-042-00-3 aluminium-tri-isopropoxide 209-090-8 555-31-7 Flam. Sol. 1 H228 GHS02 H228 T
Dgr
L 353/484
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2,4-dichloro-α-(pyrimidin-5-yl) benzhydryl Wng
alcohol
603-044-00-4 dicofol (ISO); 204-082-0 115-32-2 Acute Tox. 4 * H312 GHS07 H312
2,2,2-trichloro-1,1-bis(4-chlorophenyl)etha- Acute Tox. 4 * H302 GHS09 H302
nol Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
603-046-00-5 bis (chloromethyl) ether; 208-832-8 542-88-1 Flam. Liq. 2 H225 GHS02 H225 Carc. 1A; H350:
oxybis(chloromethane) Carc. 1A H350 GHS06 H350 C ≥ 0,001 %
Acute Tox. 2 * H330 GHS08 H330
Acute Tox. 3 * H311 Dgr H311
Acute Tox. 4 * H302 H302
603-047-00-0 2-dimethylaminoethanol; 203-542-8 108-01-0 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
N,N-dimethylethanolamine Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 5 %
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
603-048-00-6 2-diethylaminoethanol; 202-845-2 100-37-8 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
N,N-diethylethanolamine Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 5 %
Acute Tox. 4 * H312 GHS07 GHS09 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
31.12.2008
603-049-00-1 chlorfenethol (ISO); 201-246-3 80-06-8 Acute Tox. 4 * H302 GHS07 H302
1,1-bis (4-chlorophenyl) ethanol Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 Wng H302
603-054-00-9 di-n-butyl ether; 205-575-3 142-96-1 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
dibutyl ether Eye Irrit. 2 H319 GHS07 H319 H335: C ≥ 10 %
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Aquatic H412 H412
Chronic 3
603-055-00-4 propylene oxide; 200-879-2 75-56-9 Flam. Liq. 1 H224 GHS02 H224
1,2-epoxypropane; Carc. 1B H350 GHS08 H350
methyloxirane Muta. 1B H340 GHS07 H340
Acute Tox. 4 * H332 Dgr H332
Acute Tox. 4 * H312 H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
603-056-00-X [(p-tolyloxy)methyl]oxirane; [1] 218-574-8 2186-24-5 [1] Muta. 2 H341 GHS08 H341 C
[(m-tolyloxy)methyl]oxirane; [2] [1] 2186-25-6 [2] Skin Irrit. 2 H315 GHS07 H315
2,3-epoxypropyl o-tolyl ether; [3] 218-575-3 2210-79-9 [3] Skin Sens. 1 H317 GHS09 H317
[(tolyloxy)methyl]oxirane; [2] 26447-14-3 [4] Aquatic H411 Wng H411
cresyl glycidyl ether [4] 218-645-3 Chronic 2
L 353/485
[3]
247-711-4
[4]
L 353/486
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-057-00-5 benzyl alcohol 202-859-9 100-51-6 Acute Tox. 4 * H332 GHS07 H332
EN
Acute Tox. 4 * H302 Wng H302
603-058-00-0 1,3-propylene oxide 207-964-3 503-30-0 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Dgr H312
Acute Tox. 4 * H302 H302
603-062-00-2 tetrahydrofuran-2,5-diyldimethanol 203-239-0 104-80-3 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
STOT SE 3 H335 Wng H335 H335: C ≥ 10 %
Skin Irrit. 2 H315 H315
31.12.2008
STOT SE 3 H319 H335
Skin Irrit. 2 H335 H315
H315
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
monopropylene glycol methyl ether Wng
603-065-00-9 resorcinol diglycidyl ether; 202-987-5 101-90-6 Carc. 2 H351 GHS08 H351
1,3-bis(2,3-epoxypropoxy)benzene Muta. 2 H341 GHS07 H341
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
603-067-00-X phenyl glycidyl ether; 204-557-2 122-60-1 Carc. 1B H350 GHS08 H350
2,3-epoxypropyl phenyl ether; Muta. 2 H341 GHS07 H341
1,2-epoxy-3-phenoxypropane Acute Tox. 4 * H332 Dgr H332
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
L 353/487
Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
L 353/488
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Irrit. 2 H315 Wng H315
Aquatic H412 H412
Chronic 3
603-072-00-7 1,4-bis(2,3 epoxypropoxy)butane; 219-371-7 2425-79-8 Acute Tox. 4 * H332 GHS07 H332
butanedioldiglycidyl ether Acute Tox. 4 * H312 Wng H312
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
603-073-00-2 bis-[4-(2,3-epoxipropoxi)phenyl]propane 216-823-5 1675-54-3 Eye Irrit. 2 H319 GHS07 H319 Eye Irrit. 2; H319:
Skin Irrit. 2 H315 Wng H315 C ≥ 5%
Skin Sens. 1 H317 H317 Skin Irrit. 2;
H315: C ≥ 5 %
603-074-00-8 reaction product: bisphenol-A-(epichlorhy- 500-033-5 25068-38-6 Eye Irrit. 2 H319 GHS07 H319 Eye Irrit. 2; H319:
drin); Skin Irrit. 2 H315 GHS09 H315 C ≥ 5%
epoxy resin (number average molecular Skin Sens. 1 H317 Wng H317 Skin Irrit. 2;
weight ≤ 700) Aquatic H411 H411 H315: C ≥ 5 %
Chronic 2
603-075-00-3 chlormethyl methyl ether; 203-480-1 107-30-2 Flam. Liq. 2 H225 GHS02 H225
chlorodimethyl ether Carc. 1A H350 GHS08 H350
31.12.2008
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Dgr H312
Acute Tox. 4 * H302 H302
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-076-00-9 but-2-yne-1,4-diol; 203-788-6 110-65-6 Skin Corr. 1B H314 GHS06 H314 Skin Corr. 1B; D
H314: C ≥ 50 %
EN
2-butyne-1,4-diol Acute Tox. 3 * H331 GHS05 H331
Acute Tox. 3 * H301 GHS08 H301 Skin Irrit. 2;
Acute Tox. 4 * H312 Dgr H312 H315: 25 % ≤ C <
50 %
STOT RE 2 * H373 H373 **
** Eye Irrit. 2; H319:
Skin Sens. 1 H317 25 % ≤ C < 50 %
H317
603-080-00-0 2-methylaminoethanol; 203-710-0 109-83-1 Acute Tox. 4 * H312 GHS05 GHS07 H312 STOT SE 3;
N-methylethanolamine; Acute Tox. 4 * H302 Dgr H302 H335: C ≥ 5 %
N-methyl-2-ethanolamine; Skin Corr. 1B H314 H314
N-methyl-2-amino ethanol;
2-(methylamino)ethanol
L 353/489
603-083-00-7 1,1'-iminodipropan-2-ol; 203-820-9 110-97-4 Eye Irrit. 2 H319 GHS07 H319
di-isopropanolamine Wng
L 353/490
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
(epoxyethyl)benzene; Acute Tox. 4 * H312 GHS07 H312
phenyloxirane Eye Irrit. 2 H319 Dgr H319
603-085-00-8 bronopol (INN); 200-143-0 52-51-7 Acute Tox. 4 * H312 GHS05 H312
2-bromo-2-nitropropane-1,3-diol Acute Tox. 4 * H302 GHS07 H302
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Dgr H315
Eye Dam. 1 H318 H318
Aquatic Acute 1 H400 H400
31.12.2008
603-092-00-6 2-methyl-4-phenylpentanol 402-770-7 92585-24-5 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-093-00-1 cinmethylin (ISO); 402-410-9 87818-31-3 Acute Tox. 4 * H332 GHS07 H332
EN
exo-(±)-1-methyl-2-(2-methylbenzyloxy)-4- Aquatic H411 GHS09 H411
isopropyl-7-oxabicyclo(2.2.1)heptane Chronic 2 Dgr
603-100-00-8 1,2-dimethoxypropane 404-630-0 7778-85-0 Flam. Liq. 2 H225 GHS02 H225 EUH019
Dgr
L 353/491
603-101-00-3 tetrahydro-2-isobutyl-4-methylpyran-4-ol, 405-040-6 — Eye Irrit. 2 H319 GHS07 H319
mixed isomers (cis and trans) Wng
L 353/492
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Carc. 2 H351 GHS08 H351
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Dgr H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Aquatic H412 H412
Chronic 3
603-104-00-X fenarimol (ISO); 262-095-7 60168-88-9 Repr. 2 H361f- GHS08 GHS09 H361fd
2,4'-dichloro-α-(pyrimidin-5-yl)benzhydryl Lact. d Wng H362
alcohol Aquatic H362 H411
Chronic 2 H411
603-105-00-5 furan 203-727-3 110-00-9 Flam. Liq. 1 H224 GHS02 H224 EUH019
Carc. 1B H350 GHS08 H350
Muta. 2 H341 GHS07 H341
Acute Tox. 4 * H332 Dgr H332
Acute Tox. 4 * H302 H302
STOT RE 2 * H373 H373 **
Skin Irrit. 2 ** H315
Aquatic H315 H412
Chronic 3 H412
31.12.2008
603-107-00-6 2-(2-methoxyethoxy)ethanol; 203-906-6 111-77-3 Repr. 2 H361d GHS08 H361d ***
diethylene glycol monomethyl ether *** Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
iso-butanol STOT SE 3 H335 GHS05 H335
Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 Dgr H318
STOT SE 3 H336 H336
603-122-00-8 sodium 2-ethylhexanolate 406-150-7 38411-13-1 Flam. Sol. 1 H228 GHS02 H228 T
Skin Corr. 1B H314 GHS05 H314
Aquatic H412 Dgr H412
Chronic 3
L 353/493
decan-2-ol Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
L 353/494
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H410 Wng
Chronic 1
603-127-00-5 butan-2-ol; [1] 201-158-5 78-92-2 [1] Flam. Liq. 3 H226 GHS02 H226 C
(S)-butan-2-ol; [2] [1] 4221-99-2 [2] Eye Irrit. 2 H319 GHS07 H319
(R)-butan-2-ol; [3] 224-168-1 14898-79-4 [3] STOT SE 3 H335 Wng H335
(±)-butan-2-ol [4] [2] 15892-23-6 [4] STOT SE 3 H336 H336
238-967-8
[3]
240-029-8
[4]
603-130-00-1 reaction mass of isomers of: α-((dimethyl) 406-325-8 — Acute Tox. 4 * H302 GHS07 H302
biphenyl)-ω-hydroxypoly(oxyethylene) Aquatic H412 Wng H412
Chronic 3
603-131-00-7 reaction mass of: 1-deoxy-1-[methyl-(1- 407-290-1 — Eye Dam. 1 H318 GHS05 H318
31.12.2008
oxododecyl)amino]-D-glucitol; Dgr
1-deoxy-1-[methyl-(1-oxotetradecyl)amino]-
D-glucitol (3:1)
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Eye Dam. 1 H318 Dgr H318
Aquatic H412 H412
Chronic 3
603-133-00-8 reaction mass of: 3-[(4-amino-2-chloro-5- 408-240-1 — Acute Tox. 4 * H302 GHS07 H302
nitrophenyl)amino]-propane-1,2-diol; Aquatic H412 Wng H412
3,3'-(2-chloro-5-nitro-1,4-phenylenedii- Chronic 3
mino)bis(propan-1,2-diol)
603-137-00-X reaction mass of: 1-deoxy-1-[methyl-(1- 411-130-6 — Eye Dam. 1 H318 GHS05 H318
oxohexadecyl)amino]-D-glucitol; Dgr
1-deoxy-1-[methyl-(1-oxooctadecyl)amino]-
D-glucitol
L 353/495
603-139-00-0 bis(2-methoxyethyl) ether 203-924-4 111-96-6 Flam. Liq. 3 H226 GHS02 H226 EUH019
Repr. 1B H360- GHS08 H360FD
FD Dgr
L 353/496
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-140-00-6 2,2' -oxybisethanol; 203-872-2 111-46-6 Acute Tox. 4 * H302 GHS07 H302
EN
diethylene glycol Wng
603-144-00-8 reaction mass of: 2,6,9-trimethyl-2,5,9- 413-530-6 111850-00-1 Aquatic H411 GHS09 H411
cyclododecatrien-1-ol; Chronic 2
6,9-dimethyl-2-methylen-5,9-cyclododeca-
dien-1-ol
31.12.2008
methylamino]ethanol Skin Corr. 1B H314 GHS07 H314
Aquatic H412 Dgr H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Eye Dam. 1 H318 GHS07 H318
Aquatic H411 GHS09 H411
Chronic 2 Dgr
603-148-00-X 1,4-bis[(vinyloxy)methyl]cyclohexane 413-370-7 17351-75-6 Skin Sens. 1 H317 GHS07 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
603-149-00-5 reaction mass of diastereoisomers of 1-(1- 407-640-3 63767-86-2 Eye Irrit. 2 H319 GHS07 GHS09 H319
hydroxyethyl)-4-(1-methylethyl)cyclohexane Skin Irrit. 2 H315 Wng H315
603-150-00-0 (±) trans—3,3-dimethyl-5-(2,2,3-trimethyl- 411-580-3 107898-54-4 Skin Irrit. 2 H315 GHS07 H315
cyclopent-3-en-1-yl)-pent-4-en-2-ol Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
603-155-00-8 Reaction products of 2-(4,6-bis(2,4- 410-560-1 — Aquatic Acute 1 H400 GHS09 H410
L 353/497
dimethylphenyl)-1,3,5-triazin-2-yl)-5-hydro- Aquatic H410 Wng
xyphenol with ((C10-16, rich in C12-13 alky- Chronic 1
loxy)methyl)oxyrane
L 353/498
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
rane Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
603-158-00-4 reaction mass of 4 diastereoisomers of 412-460-3 — Skin Irrit. 2 H315 GHS07 GHS09 H315
603-160-00-5 1,2-diethoxypropane 412-180-1 10221-57-5 Flam. Liq. 2 H225 GHS02 H225 EUH019
Dgr
31.12.2008
603-164-00-7 2-butyl-4-chloro-4,5-dihydro-5-hydroxy- 412-420-5 133909-99-6 Aquatic H413 — H413
methyl-1-[2'-(2-triphenylmethyl-1,2,3,4- Chronic 4
2H-tetrazol-5-yl)-1,1'-biphenyl-4-methyl]-
1H-imidazole
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-165-00-2 reaction mass of: 4-allyl-2,6-bis(2,3-epoxy- 417-470-1 — Muta. 2 H341 GHS08 H341
EN
propyl)phenol; Skin Sens. 1 H317 GHS07 H317
4-allyl-6-[3-[6-[3-[6-[3-(4-allyl-2,6-bis(2,3- Wng
epoxypropyl)phenoxy)-2-hydroxypropyl]-4-
allyl-2-(2,3-epoxypropyl)phenoxy]-2-hydro-
xypropyl]-4-allyl-2-(2,3-epoxypropyl)phe-
noxy]-2-hydroxypropyl]-2-(2,3-epoxypro-
pyl)phenol;
4-allyl-6-[3-(4-allyl-2,6-bis(2,3-epoxypro-
pyl)phenoxy)-2-hydroxypropyl]-2-(2,3-epox-
ypropyl)phenol;
4-allyl-6-[3-[6-[3-(4-allyl-2,6-bis(2,3-epoxy-
L 353/499
Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/500
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-170-00-X reaction mass of: 2-methyl-1-(6-methylbi- 415-990-3 67739-11-1 Eye Irrit. 2 H319 GHS07 H319
EN
cyclo[2.2.1]hept-5-en-2-yl)pent-1-en-3-ol; Aquatic H411 GHS09 H411
2-methyl-1-(1-methylbicyclo[2.2.1]hept-5- Chronic 2 Wng
en-2-yl)-pent-1-en-3-ol;
2-methyl-1-(5-methylbicyclo[2.2.1]hept-5-
en-2-yl)pent-1-en-3-ol
31.12.2008
TEGDME; Df Dgr
triethylene glycol dimethyl ether;
triglyme
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
603-177-00-8 1-ethoxypropan-2-ol; 216-374-5 1569-02-4 [1] Flam. Liq. 3 H226 GHS02 H226
EN
2PG1EE; [1] 54839-24-6 [2] STOT SE 3 H336 GHS07 H336
1-ethoxy-2-propanol; 259-370-9 Wng
propylene glycol monoethyl ether; [1] [2]
2-ethoxy-1-methylethyl acetate;
2PG1EEA [2]
603-181-00-X tert-butyl methyl ether; 216-653-1 1634-04-4 Flam. Liq. 2 H225 GHS02 H225
MTBE; Skin Irrit. 2 H315 GHS07 H315
2-methoxy-2-methylpropane Dgr
603-183-00-0 2-[2-(2-butoxyethoxy)ethoxy]ethanol; 205-592-6 143-22-6 Eye Dam. 1 H318 GHS05 H318 Eye Dam. 1;
TEGBE; Dgr H318: C ≥ 30 %
triethylene glycol monobutyl ether; Eye Irrit. 2; H319:
butoxytriethylene glycol 20 % ≤ C < 30 %
L 353/501
603-184-00-6 2-(hydroxymethyl)-2-[[2-hydroxy-3-(isooc- 416-380-1 146925-83-9 Aquatic Acute 1 H400 GHS09 H410
tadecyloxy)propoxy]methyl]-1,3-propane- Aquatic H410 Wng
diol Chronic 1
L 353/502
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Eye Dam. 1 H318 GHS05 H318
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
603-189-00-3 reaction mass of complexes of: titanium, 405-250-8 — Aquatic H411 GHS09 H411
2,2'-oxydiethanol, ammonium lactate, nitri- Chronic 2
lotris(2-propanol) and ethylene glycol
603-197-00-7 tebuconazole (ISO); 403-640-2 107534-96-3 Repr. 2 H361d GHS08 H361d ***
1-(4-chlorophenyl)-4,4-dimethyl-3-(1,2,4- Acute Tox. 4 * *** GHS07 H302
triazol-1-ylmethyl)pentan-3-ol Aquatic H302 GHS09 H411
Chronic 2 H411 Wng
31.12.2008
603-199-00-8 etoxazol (ISO); — 153233-91-1 Aquatic Acute 1 H400 GHS09 H410 M = 100
(RS)-5-tert-butyl-2-[2-(2,6-difluorophenyl)- Aquatic H410 Wng
4,5-dihydro-1,3-oxazol-4-yl]phenetole Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
carbolic acid; Acute Tox. 3 * H331 GHS08 GHS05 H331 Skin Corr. 1B;
monohydroxybenzene; Acute Tox. 3 * H311 Dgr H311 H314: C ≥ 3 %
phenylalcohol Acute Tox. 3 * H301 H301 Skin Irrit. 2;
STOT RE 2 * H373 H373 ** H315: 1 % ≤ C <
** 3%
Skin Corr. 1B H314
H314 Eye Irrit. 2; H319:
1% ≤ C < 3%
604-003-00-3 sodium pentachlorophenolate; [1] 205-025-2 131-52-2 [1] Carc. 2 H351 GHS06 H351
potassium pentachlorophenolate [2] [1] 7778-73-6 [2] Acute Tox. 2 * H330 GHS08 H330
231-911-3 Acute Tox. 3 * H311 GHS09 H311
[2] Acute Tox. 3 * H301 Dgr H301
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
604-004-00-9 m-cresol; [1] 203-577-9 108-39-4 [1] Acute Tox. 3 * H311 GHS06 H311 * C
o-cresol; [2] [1] 95-48-7 [2] Acute Tox. 3 * H301 GHS05 H301
p-cresol; [3] 202-423-8 106-44-5 [3] Skin Corr. 1B H314 Dgr H314
mix-cresol [4] [2] 1319-77-3 [4]
203-398-6
L 353/503
[3]
215-293-2
[4]
L 353/504
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
604-005-00-4 1,4-dihydroxybenzene; 204-617-8 123-31-9 Carc. 2 H351 GHS08 H351
hydroquinone; Muta. 2 H341 GHS05 H341
quinol Acute Tox. 4 * H302 GHS07 H302
Eye Dam. 1 H318 GHS09 H318
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H400
604-006-00-X 3,4-xylenol; [1] 202-439-5 95-65-8 [1] Acute Tox. 3 * H311 GHS06 H311 C
604-008-00-0 2-chlorophenol; [1] 202-433-2 95-57-8 [1] Acute Tox. 4 * H332 GHS07 GHS09 H332 C
4-chlorophenol; [2] [1] 106-48-9 [2] Acute Tox. 4 * H312 Wng H312
3-chlorophenol; [3] 203-402-6 108-43-0 [3] Acute Tox. 4 * H302 H302
chlorophenol [4] [2] 25167-80-0 [4] Aquatic H411 H411
203-582-6 Chronic 2
[3]
31.12.2008
246-691-4
[4]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
1,2,3-trihydroxybenzene Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
Aquatic H412 H412
Chronic 3
604-012-00-2 4-chloro-o-cresol; 216-381-3 1570-64-5 Acute Tox. 3 * H331 GHS06 H331 STOT SE 3;
4-chloro-2-methyl phenol Skin Corr. 1A H314 GHS05 H314 H335: C ≥ 1 %
Aquatic Acute 1 H400 GHS09 H400
Dgr
L 353/505
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H400
L 353/506
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
hexachlorophene Acute Tox. 3 * H301 GHS09 H301
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
604-019-00-0 dichlorophen (ISO) 202-567-1 97-23-4 Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 GHS09 H319
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
604-020-00-6 2-phenylphenol (ISO) 201-993-5 90-43-7 Eye Irrit. 2 H319 GHS07 H319
31.12.2008
biphenyl-2-ol; STOT SE 3 H335 GHS09 H335
2-hydroxybiphenyl; Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H400
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
604-021-00-1 sodium 2-biphenylate; 205-055-6 132-27-4 Acute Tox. 4 * H302 GHS05 H302
EN
2-phenylphenol, sodium salt STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 GHS09 H315
Eye Dam. 1 H318 Wng H318
Aquatic Acute 1 H400 H400
L 353/507
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
L 353/508
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 GHS07 H302
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Eye Dam. 1 H318 H318
604-033-00-7 isobutyl but-3-enoate 401-170-2 24342-03-8 Flam. Liq. 3 H226 GHS02 H226
Wng
604-035-00-8 4-nonylphenol, reaction products with for- 404-160-6 — Skin Sens. 1 H317 GHS07 H317
maldehyde and dodecane-1-thiol Aquatic H413 Wng H413
Chronic 4
31.12.2008
604-036-00-3 4,4'-oxybis(ethylenethio)diphenol 404-590-4 90884-29-0 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
3,5-dimethylphenol Acute Tox. 3 * H301 GHS05 H301
Skin Corr. 1B H314 Dgr H314
604-038-00-4 4-chloro-3,5-dimethylphenol; [1] 201-793-8 88-04-0 [1] Acute Tox. 4 * H302 GHS07 H302
chloroxylenol [2] [1] 1321-23-9 [2] Eye Irrit. 2 H319 Wng H319
215-316-6 Skin Irrit. 2 H315 H315
[2] Skin Sens. 1 H317 H317
604-039-00-X ethyl 2-[4-[(6-chlorobenzoxazol-2-yl)oxy] 266-362-9 66441-23-4 Skin Sens. 1 H317 GHS07 H317
604-040-00-5 fomesafen (ISO); 276-439-9 72178-02-0 Acute Tox. 4 * H302 GHS07 H302
5-[2-chloro-4-(trifluoromethyl)phenoxy]-N- Wng
(methylsulphonyl)-2-nitrobenzamide
604-041-00-0 acifluorfen (ISO); 256-634-5 50594-66-6 [1] Acute Tox. 4 * H302 GHS05 H302
5-[2-chloro-4-(trifluoromethyl)phenoxy]-2- [1] 62476-59-9 [2] Skin Irrit. 2 H315 GHS07 H315
nitrobenzoic acid [1] 263-560-7 Eye Dam. 1 H318 GHS09 H318
sodium 5-[2-chloro-4-(trifluoromethyl) [2] Aquatic Acute 1 H400 Dgr H410
phenoxy]-2-nitrobenzoate; Aquatic H410
acifluorfen-sodium [2] Chronic 1
L 353/509
604-044-00-7 mequinol; 205-769-8 150-76-5 Acute Tox. 4 * H302 GHS07 H302
4-methoxyphenol; Eye Irrit. 2 H319 Wng H319
hydroquinone monomethyl ether Skin Sens. 1 H317 H317
L 353/510
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 GHS09 H315
Eye Dam. 1 H318 Dgr H318
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
604-054-00-1 reaction mass of: 2-methoxy-4-(tetrahydro- 412-020-0 — Skin Sens. 1 H317 GHS07 H317
4-methylene-2H-pyran-2-yl)-phenol; Aquatic H412 Wng H412
4-(3,6-dihydro-4-methyl-2H-pyran-2-yl)-2- Chronic 3
methoxyphenol
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Wng
604-057-00-8 reaction mass of: isomers of 2-(2H-benzo- 401-680-5 — Aquatic H411 GHS09 H411
triazol-2-yl)-4-methyl-(n)-dodecylphenol; Chronic 2
604-061-00-X reaction mass of: 2-chloro-5-sec-tetradecyl- 407-740-7 — Skin Irrit. 2 H315 GHS07 H315
hydroquinones where sec-tetradecyl = Skin Sens. 1 H317 Wng H317
1-methyltridecyl; Aquatic H412 H412
1-ethyldodecyl; Chronic 3
1-propylundecyl;
L 353/511
1-butyldecyl;
1-pentylnonyl;
1-hexyloctyl
L 353/512
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
nol Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
604-063-00-0 5,6-dihydroxyindole 412-130-9 3131-52-0 Acute Tox. 4 * H302 GHS05 GHS07 H302
Eye Dam. 1 H318 GHS09 H318
Aquatic H411 Dgr H411
Chronic 2
604-066-00-7 reaction mass of: phenol, 6-(1,1-dimethy- 414-550-8 — Aquatic Acute 1 H400 GHS09 H410
lethyl)-4-tetrapropyl-2-[(2-hydroxy-5-tetra- Aquatic H410 Wng
propylphenyl)methyl (C41-compound) and Chronic 1
methane, 2,2'-bis[6-(1,1-dimethyl-ethyl)-1-
hydroxy-4-tetrapropyl-phenyl)]- (C45-com-
pound);
2,6-bis(1,1-dimethylethyl)-4-tetra-propyl-
phenol and 2-(1,1-dimethylethyl)-4-tetra-
propyl-phenol;
2,6-bis[(6-(1,1-dimethylethyl)-1-hydroxy-4-
tetrapropylphenyl)methyl]-4-(tetrapropyl)
phenol and 2-[(6-(1,1-dimethylethyl)-1-
hydroxy-4-tetrapropylphenylmethyl]-6-[1-
hydroxy-4-tetrapropylphenyl)methyl]-4-(tet-
rapropyl)phenol
604-067-00-2 reaction mass of: 2,2'-[[(2-hydroxyethyl) 414-520-4 — Skin Irrit. 2 H315 GHS05 H315
imino]bis(methylene)bis[4-dodecylphenol]; Eye Dam. 1 H318 GHS09 H318
formaldehyde, oligomer with 4-dodecyl Aquatic Acute 1 H400 Dgr H410
phenol and 2-aminoethanol(n = 2);
31.12.2008
Aquatic H410
formaldehyde, oligomer with 4-dodecyl Chronic 1
phenol and 2-aminoethanol(n = 3, 4 and
higher)
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 Wng H302
hydrochloride Skin Sens. 1 H317 H317
604-070-00-9 triclosan; 222-182-2 3380-34-5 Eye Irrit. 2 H319 GHS07 H319 M = 100
2,4,4'-trichloro-2'-hydroxy-diphenyl-ether; Skin Irrit. 2 H315 GHS09 H315
L 353/513
605-004-00-1 2,4,6-trimethyl-1,3,5-trioxan; 204-639-8 123-63-7 Flam. Liq. 3 H226 GHS02 H226
paraldehyde Dgr
L 353/514
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
tane; Acute Tox. 4 * H302 GHS07 H302
metaldehyde Wng
605-009-00-9 crotonaldehyde; 224-030-0 4170-30-3 [1] Flam. Liq. 2 H225 GHS02 H225
2-butenal; [1] [1] 123-73-9 [2] Muta. 2 H341 GHS06 H341
(E)-2-butenal; 204-647-1 Acute Tox. 2 * H330 GHS08 H330
(E)-crotonaldehyde [2] [2] Acute Tox. 3 * H311 GHS05 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
STOT SE 3 ** H335
Skin Irrit. 2 H335 H315
Eye Dam. 1 H315 H318
Aquatic Acute 1 H318 H400
H400
31.12.2008
Acute Tox. 4 * H312 H312
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
o-chlorobenzaldehyde Dgr
605-013-00-0 chloralose (INN); 240-016-7 15879-93-3 Acute Tox. 4 * H332 GHS07 H332
(R)-1,2-O-(2,2,2-trichloroethylidene)-α-D- Acute Tox. 4 * H302 Wng H302
glucofuranose;
glucochloralose;
605-014-00-6 chloral hydrate; 206-117-5 302-17-0 Acute Tox. 3 * H301 GHS06 H301
2,2,2-trichloroethane-1,1-diol Eye Irrit. 2 H319 Dgr H319
Skin Irrit. 2 H315 H315
L 353/515
605-019-00-3 citral 226-394-6 5392-40-5 Skin Irrit. 2 H315 GHS07 H315
Skin Sens. 1 H317 Wng H317
L 353/516
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
5-allyl-1,3-benzodioxole Muta. 2 H341 GHS07 H341
Acute Tox. 4 * H302 Dgr H302
605-021-00-4 formaldehyde, reaction products with 294-145-9 91673-30-2 Skin Sens. 1 H317 GHS07 H317
butylphenol Wng
605-026-00-1 2,5,7,7-tetramethyloctanal 405-690-0 114119-97-0 Skin Irrit. 2 H315 GHS07 GHS09 H315
Skin Sens. 1 H317 Wng H317
Aquatic H411 H411
Chronic 2
605-027-00-7 reaction mass of: 3a,4,5,6,7,7a-hexahydro- 410-480-7 — Skin Sens. 1 H317 GHS07 H317
31.12.2008
4,7-methano-1H-indene-6-carboxaldehyde; Aquatic H411 GHS09 H411
3a,4,5,6,7,7a-hexahydro-4,7-methano-1H- Chronic 2 Wng
indene-5-carboxaldehyde
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
605-029-00-8 2-cyclohexylpropanal 412-270-0 2109-22-0 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
605-030-00-3 1-(p-methoxyphenyl)acetaldehyde oxime 411-510-1 3353-51-3 Skin Sens. 1 H317 GHS07 H317
Wng
606-001-00-8 acetone; 200-662-2 67-64-1 Flam. Liq. 2 H225 GHS02 H225 EUH066
propan-2-one; Eye Irrit. 2 H319 GHS07 H319
propanone STOT SE 3 H336 Dgr H336
606-002-00-3 butanone; 201-159-0 78-93-3 Flam. Liq. 2 H225 GHS02 H225 EUH066
ethyl methyl ketone Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H336 Dgr H336
606-004-00-4 4-methylpentan-2-one; 203-550-1 108-10-1 Flam. Liq. 2 H225 GHS02 H225 EUH066
isobutyl methyl ketone Acute Tox. 4 * H332 GHS07 H332
Eye Irrit. 2 H319 Dgr H319
STOT SE 3 H335 H335
L 353/517
606-005-00-X 2,6-dimethylheptan-4-one; 203-620-1 108-83-8 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
di-isobutyl ketone STOT SE 3 H335 GHS07 H335 H335: C ≥ 10 %
Wng
L 353/518
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
606-006-00-5 pentan-3-one; 202-490-3 96-22-0 Flam. Liq. 2 H225 GHS02 H225 EUH066
EN
diethyl ketone STOT SE 3 H335 GHS07 H335
STOT SE 3 H336 Dgr H336
31.12.2008
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H400
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
606-014-00-9 chlorophacinone (ISO); 223-003-0 3691-35-8 Acute Tox. 1 H310 GHS06 H310
EN
2-(2-(4-chlorophenyl)phenylacetyl)indan- Acute Tox. 2 * H300 GHS08 H300
1,3-dione Acute Tox. 3 * H331 GHS09 H331
STOT RE 1 H372 Dgr H372 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
606-016-00-X pindone (ISO); 201-462-8 83-26-1 Acute Tox. 3 * H301 GHS06 H301
2-pivaloylindan-1,3-dione STOT RE 1 H372 GHS08 H372 **
606-018-00-0 dichlone (ISO); 204-210-5 117-80-6 Acute Tox. 4 * H302 GHS07 H302
2,3-dichloro-1,4-naphthoquinone Eye Irrit. 2 H319 GHS09 H319
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
606-020-00-1 5-methylheptan-3-one 208-793-7 541-85-5 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3;
L 353/519
Eye Irrit. 2 H319 GHS07 H319 H335: C ≥ 10 %
STOT SE 3 H335 Wng H335
L 353/520
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Irrit. 2 H315 Wng H315
31.12.2008
606-029-00-0 pentane-2,4-dione; 204-634-0 123-54-6 Flam. Liq. 3 H226 GHS02 H226
acetylacetone Acute Tox. 4 * H302 GHS07 H302
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methyl butyl ketone; Repr. 2 H361f GHS08 H361f ***
butyl methyl ketone; STOT RE 1 *** GHS07 H372 **
methyl-n-butyl ketone STOT SE 3 H372 Dgr H336
**
H336
606-034-00-8 metribuzin (ISO); 244-209-7 21087-64-9 Acute Tox. 4 * H302 GHS07 H302
4-amino-6-tert-butyl-3-methylthio-1,2,4- Aquatic Acute 1 H400 GHS09 H410
triazin-5(4H)-one; Aquatic H410 Wng
4-amino-4,5-dihydro-6-(1,1-dimethylethyl)- Chronic 1
3-methylthio-1,2,4-triazin-5-one
606-035-00-3 chloridazon (ISO); 216-920-2 1698-60-8 Skin Sens. 1 H317 GHS07 H317
5-amino-4-chloro-2-phenylpyridazine-3- Aquatic Acute 1 H400 GHS09 H410
L 353/521
(2H)-one; Aquatic H410 Wng
pyrazon Chronic 1
L 353/522
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
chinomethionat (ISO); Acute Tox. 4 * *** GHS07 H332
6-methyl-1,3-dithiolo(4,5-b)quinoxalin-2- Acute Tox. 4 * H332 GHS09 H312
one Acute Tox. 4 * H312 Wng H302
STOT RE 2 * H302 H373 **
Eye Irrit. 2 H373 H319
Skin Sens. 1 ** H317
Aquatic Acute 1 H319 H410
Aquatic H317
Chronic 1 H400
H410
606-038-00-X diphacinone (ISO); 201-434-5 82-66-6 Acute Tox. 2 * H300 GHS06 H300
2-diphenylacetylindan-1,3-dione STOT RE 1 H372 GHS08 H372 **
** Dgr
31.12.2008
606-042-00-1 acetophenone 202-708-7 98-86-2 Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 Wng H319
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
606-046-00-3 reaction mass of cis- and trans-cyclohexadec- 401-700-2 3100-36-5 Aquatic Acute 1 H400 GHS09 H410
8-en-1-one Aquatic H410 Wng
Chronic 1
L 353/523
606-052-00-6 4-(N,N-dibutylamino)-2-hydroxy-2'-carbox- 410-410-5 54574-82-2 Aquatic H412 — H412
ybenzophenone Chronic 3
L 353/524
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
(RS)-5-methylamino-2-phenyl-4-(α,α,α-tri- Aquatic H410 Wng
fluoro-m-tolyl)furan-3(2H)-one Chronic 1
606-060-00-X reaction mass of: trans-2,4-dimethyl-2- 412-950-7 — Aquatic Acute 1 H400 GHS09 H410
(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl- Aquatic H410 Wng
naphthalene-2-yl)-1,3-dioxolane;
31.12.2008
Chronic 1
cis-2,4-dimethyl-2-(5,6,7,8-tetrahydro-
5,5,8,8-tetramethyl-naphthalene-2-yl)-1,3-
dioxolane
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
606-067-00-8 reaction mass of: 1-(2,3,6,7,8,9-hexahydro- 414-870-8 96792-67-5 Aquatic Acute 1 H400 GHS09 H410
1,1-dimethyl-1H-benz(g)inden-4-yl)etha- Aquatic H410 Wng
none; Chronic 1
1-(2,3,5,6,7,8-hexahydro-1,1-dimethyl-1H-
benz(f)inden-4-yl)ethanone;
1-(2,3,6,7,8,9-hexahydro-1,1-dimethyl-1H-
benz(g)inden-5-yl)ethanone;
1-(2,3,6,7,8,9-hexahydro-3,3-dimethyl-1H-
benz(g)inden-5-yl)ethanone
L 353/525
606-069-00-9 spiro[1,3-dioxolane-2,5'-(4',4',8',8'-tetra- 415-460-1 154171-76-3 Aquatic H411 GHS09 H411
methyl-hexahydro-3',9'-methanonaphtha- Chronic 2
lene)]
L 353/526
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
5-(3-butyryl-2,4,6-trimethylphenyl)-2-[1- Acute Tox. 4 * H302 GHS07 H302
(ethoxyimino)propyl]-3-hydroxycyclohex-2- Skin Irrit. 2 H315 GHS09 H315
en-1-one Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
31.12.2008
Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Sens. 1 H317 GHS07 H317
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
606-081-00-4 (3β, 5α, 6β)-3-(acetyloxy)-5-bromo-6- 419-790-7 4229-69-0 Skin Sens. 1 H317 GHS07 H317
hydroxy-androstan-17-one Aquatic H412 Wng H412
606-082-00-X reaction mass of: butan-2-one oxime; 406-930-7 STOT RE 1 H372 GHS08 H372 **
syn-O,O'-di(butan-2-one oxime)diethoxysi- Skin Sens. 1 ** GHS07 H317
lane Aquatic H317 Dgr H412
Chronic 3 H412
L 353/527
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
L 353/528
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
606-089-00-8 reaction mass of: 1,4-diamino-2-chloro-3- 423-220-2 12223-77-7 Aquatic H413 — H413
phenoxyanthraquinone; Chronic 4
1,4-diamino-2,3-bis-phenoxyanthraquinone
606-092-00-4 reaction mass of: (E)-oxacyclohexadec-12- 422-320-3 Aquatic Acute 1 H400 GHS09 H410
en-2-one; Aquatic H410 Wng
(E)-oxacyclohexadec-13-en-2-one; Chronic 1
a) (Z)-oxacyclohexadec-(12)-en-2-one and
b) (Z)-oxacyclohexadec-(13)-en-2-one
607-001-00-0 formic acid ... % 200-579-1 64-18-6 Skin Corr. 1A H314 GHS05 H314 Skin Corr. 1A; B
Dgr H314: C ≥ 90 %
Skin Corr. 1B;
H314: 10 % ≤ C
< 90 %
Skin Irrit. 2;
H315: 2 % ≤ C
< 10 %
Eye Irrit. 2; H319:
2 % ≤ C < 10 %
607-002-00-6 acetic acid ... % 200-580-7 64-19-7 Flam. Liq. 3 H226 GHS02 H226 Skin Corr. 1A; B
Skin Corr. 1A H314 GHS05 H314 H314: C ≥ 90 %
Dgr Skin Corr. 1B;
H314: 25 % ≤ C
< 90 %
Skin Irrit. 2;
H315: 10 % ≤ C
31.12.2008
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-003-00-1 chloroacetic acid 201-178-4 79-11-8 Acute Tox. 3 * H301 GHS06 H301
EN
Skin Corr. 1B H314 GHS05 H314
Aquatic Acute 1 H400 GHS09 H400
Dgr
607-004-00-7 TCA (ISO); 200-927-2 76-03-9 Skin Corr. 1A H314 GHS05 H314 STOT SE 3;
trichloroacetic acid Aquatic Acute 1 H400 GHS09 H410 H335: C ≥ 1 %
Aquatic H410 Dgr
Chronic 1
607-006-00-8 oxalic acid 205-634-3 144-62-7 Acute Tox. 4 * H312 GHS07 H312 *
Acute Tox. 4 * H302 Wng H302
607-008-00-9 acetic anhydride 203-564-8 108-24-7 Flam. Liq. 3 H226 GHS02 H226 Skin Corr. 1B;
Acute Tox. 4 * H332 GHS05 H332 H314: C ≥ 25 %
Acute Tox. 4 * H302 GHS07 H302 Skin Irrit. 2;
Skin Corr. 1B H314 Dgr H314 H315: 5 % ≤ C
< 25 %
Eye Dam. 1;
H318: 5 % ≤ C
< 25 %
Eye Irrit. 2; H319:
1% ≤ C < 5%
L 353/529
STOT SE 3;
H335: C ≥ 5 %
L 353/530
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-009-00-4 phthalic anhydride 201-607-5 85-44-9 Acute Tox. 4 * H302 GHS08 H302
EN
STOT SE 3 H335 GHS05 H335
Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 Dgr H318
Resp. Sens. 1 H334 H334
Skin Sens. 1 H317 H317
607-010-00-X propionic anhydride 204-638-2 123-62-6 Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B;
Dgr H314: C ≥ 25 %
Skin Irrit. 2;
607-011-00-5 acetyl chloride 200-865-6 75-36-5 Flam. Liq. 2 H225 GHS02 H225 EUH014
Skin Corr. 1B H314 GHS05 H314
Dgr
607-012-00-0 benzoyl chloride 202-710-8 98-88-4 Skin Corr. 1B H314 GHS05 H314
Dgr
607-013-00-6 dimethyl carbonate 210-478-4 616-38-6 Flam. Liq. 2 H225 GHS02 H225
Dgr
607-014-00-1 methyl formate 203-481-7 107-31-3 Flam. Liq. 1 H224 GHS02 H224
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
607-015-00-7 ethyl formate 203-721-0 109-94-4 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 4 * H332 GHS07 H332
31.12.2008
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-016-00-2 propyl formate; [1] 203-798-0 110-74-7 [1] Flam. Liq. 2 H225 GHS02 H225 C
[1]
EN
isopropyl formate [2] 625-55-8 [2] Eye Irrit. 2 H319 GHS07 H319
210-901-2 STOT SE 3 H335 Dgr H335
[2] STOT SE 3 H336 H336
607-017-00-8 butyl formate; [1] 209-772-5 592-84-7 [1] Flam. Liq. 2 H225 GHS02 H225 C
tert-butyl formate; [2] [1] 762-75-4 [2] Eye Irrit. 2 H319 GHS07 H319
isobutyl formate [3] 212-105-0 542-55-2 [3] STOT SE 3 H335 Dgr H335
[2]
208-818-1
[3]
607-019-00-9 methyl chloroformate 201-187-3 79-22-1 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 4 * H312 GHS05 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
607-020-00-4 ethyl chloroformate 208-778-5 541-41-3 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 Dgr H314
607-021-00-X methyl acetate 201-185-2 79-20-9 Flam. Liq. 2 H225 GHS02 H225 EUH066
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H336 Dgr H336
607-022-00-5 ethyl acetate 205-500-4 141-78-6 Flam. Liq. 2 H225 GHS02 H225 EUH066
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H336 Dgr H336
L 353/531
607-023-00-0 vinyl acetate 203-545-4 108-05-4 Flam. Liq. 2 H225 GHS02 H225 D
Dgr
L 353/532
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-024-00-6 propyl acetate; [1] 203-686-1 109-60-4 [1] Flam. Liq. 2 H225 GHS02 H225 EUH066 C
EN
isopropyl acetate [2] [1] 108-21-4 [2] Eye Irrit. 2 H319 GHS07 H319
203-561-1 STOT SE 3 H336 Dgr H336
[2]
607-025-00-1 n-butyl acetate 204-658-1 123-86-4 Flam. Liq. 3 H226 GHS02 H226 EUH066
STOT SE 3 H336 GHS07 H336
Wng
607-027-00-2 methyl propionate 209-060-4 554-12-1 Flam. Liq. 2 H225 GHS02 H225
Acute Tox. 4 * H332 GHS07 H332
Dgr
607-028-00-8 ethyl propionate 203-291-4 105-37-3 Flam. Liq. 2 H225 GHS02 H225
Dgr
607-029-00-3 n-butyl propionate; [1] 209-669-5 590-01-2 [1] Flam. Liq. 3 H226 GHS02 H226 C
sec-butyl propionate; [2] [1] 591-34-4 [2] Wng
iso-butyl propionate [3] - [2] 540-42-1 [3]
208-746-0
[3]
607-030-00-9 propyl propionate 203-389-7 106-36-5 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 4 * H332 GHS07 H332
Wng
31.12.2008
607-031-00-4 butyl butyrate 203-656-8 109-21-7 Flam. Liq. 3 H226 GHS02 H226 C
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-032-00-X ethyl acrylate 205-438-8 140-88-5 Flam. Liq. 2 H225 GHS02 H225 Skin Irrit. 2; D
EN
Acute Tox. 4 * H332 GHS07 H332 H315: C ≥ 5 %
Acute Tox. 4 * H312 Dgr H312 Eye Irrit. 2; H319:
Acute Tox. 4 * H302 H302 C ≥ 5%
Eye Irrit. 2 H319 H319 STOT SE 3;
H335: C ≥ 5 %
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-034-00-0 methyl acrylate; 202-500-6 96-33-3 Flam. Liq. 2 H225 GHS02 H225 D
methyl propenoate Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Dgr H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-035-00-6 methyl methacrylate; 201-297-1 80-62-6 Flam. Liq. 2 H225 GHS02 H225 D
methyl 2-methylprop-2-enoate; STOT SE 3 H335 GHS07 H335
methyl 2-methylpropenoate Skin Irrit. 2 H315 Dgr H315
Skin Sens. 1 H317 H317
L 353/533
Acute Tox. 4 * H312 H302
H302
L 353/534
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
ethylglycol acetate Acute Tox. 4 * FD GHS07 H332
Acute Tox. 4 * H332 Dgr H312
Acute Tox. 4 * H312 H302
H302
607-038-00-2 2-butoxyethyl acetate; 203-933-3 112-07-2 Acute Tox. 4 * H332 GHS07 H332
butylglycol acetate Acute Tox. 4 * H312 Wng H312
607-041-00-9 2,4,5-T (ISO); 202-273-3 93-76-5 Acute Tox. 4 * H302 GHS07 H302
2,4,5-trichlorophenoxy acetic acid Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
607-042-00-4 salts and esters of 2,4,5-T; — — Acute Tox. 4 * H302 GHS07 H302 A
salts and esters of 2,4,5-trichlorophenoxy Eye Irrit. 2 H319 GHS09 H319
acetic acid STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-043-00-X dicamba (ISO); 217-635-6 1918-00-9 Acute Tox. 4 * H302 GHS05 H302
EN
2,5-dichloro-6-methoxybenzoic acid; Eye Dam. 1 H318 GHS07 H318
3,6-dichloro-2-methoxybenzoic acid Aquatic H412 Dgr H412
Chronic 3
607-044-00-5 3,6-dichloro-o-anisic acid, compound with 218-951-7 2300-66-5 [1] Eye Irrit. 2 H319 GHS07 H319
dimethylamine (1:1); [1] [1] 10007-85-9 [2] Aquatic H412 Wng H412
potassium 3,6-dichloro-o-anisate [2] 233-002-7 Chronic 3
[2]
607-047-00-1 fenoprop (ISO); 202-271-2 93-72-1 Acute Tox. 4 * H302 GHS07 H302
2-(2,4,5-trichlorophenoxy)propionic acid Skin Irrit. 2 H315 GHS09 H315
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-049-00-2 mecoprop (ISO); 230-386-8 7085-19-0 [1] Acute Tox. 4 * H302 GHS05 H302 M=100
2-(4-chloro-o-tolyloxy) propionic acid; [1] 708519-0 [2] Skin Irrit. 2 H315 GHS07 H315
(RS)-2-(4-chloro-o-tolyloxy)propionic acid; 202-264-4 Eye Dam. 1 H318 GHS09 H318
L 353/535
[1] [2] Aquatic Acute 1 H400 Dgr H410
2-(4-chloro-2-methylphenoxy)propionic Aquatic H410
acid [2] Chronic 1
L 353/536
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 GHS09 H318
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-051-00-3 MCPA (ISO); 202-360-6 94-74-6 Acute Tox. 4 * H302 GHS05 H302
4-chloro-o-tolyloxyacetic acid Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 Dgr H318
607-053-00-4 MCPB (ISO); 202-365-3 94-81-5 Aquatic Acute 1 H400 GHS09 H410
4-(4-chloro-o-tolyloxy) butyric acid Aquatic H410 Wng
Chronic 1
607-054-00-X salts and esters of MCPB — — Acute Tox. 4 * H302 GHS07 H302 A
Wng
607-055-00-5 endothal-sodium (ISO); 204-959-8 129-67-9 Acute Tox. 3 * H301 GHS06 H301
disodium 7-oxabicyclo(2,2,1)heptane-2,3- Acute Tox. 4 * H312 Dgr H312
dicarboxylate Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
607-056-00-0 warfarin (ISO); [1] 201-377-6 81-81-2 [1] Repr. 1A H360- GHS08 H360D ***
(S)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2- [1] 5543-57-7 [2] STOT RE 1 D *** Dgr H372 **
benzopyrone; [2] 226-907-3 5543-58-8 [3] Aquatic H372 H412
(R)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2- [2] Chronic 3 **
benzopyrone [3] 226-908-9 H412
[3]
31.12.2008
607-057-00-6 coumachlor (ISO); 201-378-1 81-82-3 STOT RE 2 * H373 GHS08 H373 **
3-[1-(4-chlorophenyl)-3-oxobutyl]-4-hydro- Aquatic ** Wng H412
xycoumarin Chronic 3 H412
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-058-00-1 coumafuryl (ISO); 204-195-5 117-52-2 Acute Tox. 3 * H301 GHS06 H301
EN
fumarin; STOT RE 1 H372 GHS08 H372 **
(RS)-3-(1-(2-furyl)-3-oxobutyl)4-hydroxy- Aquatic ** Dgr H412
coumarin; Chronic 3 H412
4-hydroxy-3-[3-oxo-1-(2-furyl) butyl]cou-
marin
607-061-00-8 acrylic acid; 201-177-9 79-10-7 Flam. Liq. 3 H226 GHS02 H226 STOT SE 3; D
prop-2-enoic acid Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 1 %
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 GHS09 H302
Skin Corr. 1A H314 Dgr H314
Aquatic Acute 1 H400 H400
607-062-00-3 n-butyl acrylate 205-480-7 141-32-2 Flam. Liq. 3 H226 GHS02 H226 D
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-063-00-9 isobutyric acid 201-195-7 79-31-2 Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Wng H302
607-064-00-4 benzyl chloroformate 207-925-0 501-53-1 Skin Corr. 1B H314 GHS05 H314 STOT SE 3;
L 353/537
Aquatic Acute 1 H400 GHS09 H410 H335: C ≥ 5 %
Aquatic H410 Dgr
Chronic 1
L 353/538
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-065-00-X bromoacetic acid 201-175-8 79-08-3 Acute Tox. 3 * H331 GHS06 H331
EN
Acute Tox. 3 * H311 GHS05 H311
Acute Tox. 3 * H301 GHS09 H301
Skin Corr. 1A H314 Dgr H314
Aquatic Acute 1 H400 H400
607-066-00-5 dichloroacetic acid 201-207-0 79-43-6 Skin Corr. 1A H314 GHS05 H314
Aquatic Acute 1 H400 GHS09 H400
Dgr
607-068-00-6 iodoacetic acid 200-590-1 64-69-7 Acute Tox. 3 * H301 GHS06 H301
Skin Corr. 1A H314 GHS05 H314
Dgr
607-069-00-1 ethyl bromoacetate 203-290-9 105-36-2 Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 Dgr H310
Acute Tox. 2 * H300 H300
607-070-00-7 ethyl chloroacetate 203-294-0 105-39-5 Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H400
607-071-00-2 ethyl methacrylate 202-597-5 97-63-2 Flam. Liq. 2 H225 GHS02 H225 D
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-072-00-8 2-hydroxyethyl acrylate 212-454-9 818-61-1 Acute Tox. 3 * H311 GHS06 H311 * D
31.12.2008
Skin Corr. 1B H314 GHS05 H314 Skin Sens. 1;
Skin Sens. 1 H317 GHS09 H317 H317: C ≥ 0,2 %
Aquatic Acute 1 H400 Dgr H400
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-073-00-3 4-CPA (ISO); 204-581-3 122-88-3 Acute Tox. 4 * H302 GHS07 H302
EN
4-chlorophenoxyacetic acid Wng
L 353/539
ethyl 5-(1,2,3,5,6,7,8,9,10,10-decachloro-4-
hydroxypentacyclo(5,2,1,02,6,03,9,05,8)dec-4-
yl)-4-oxovalerate
L 353/540
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-080-00-1 chloroacetyl chloride 201-171-6 79-04-9 Acute Tox. 3 * H331 GHS06 H331 EUH014
EN
Acute Tox. 3 * H311 GHS08 H311 EUH029
Acute Tox. 3 * H301 GHS05 H301
STOT RE 1 H372 GHS09 H372 **
Skin Corr. 1A ** Dgr H314
Aquatic Acute 1 H314 H400
H400
607-081-00-7 fluoroacetic acid 205-631-7 144-49-0 Acute Tox. 2 * H300 GHS06 H300
Aquatic Acute 1 H400 GHS09 H400
Dgr
607-083-00-8 2,4-DB (ISO); 202-366-9 94-82-6 Acute Tox. 4 * H302 GHS07 H302
4-(2,4-dichlorophenoxy)butyric acid Aquatic H411 GHS09 H411
Chronic 2 Wng
607-085-00-9 benzyl benzoate 204-402-9 120-51-4 Acute Tox. 4 * H302 GHS07 H302
Wng
607-086-00-4 diallyl phthalate 205-016-3 131-17-9 Acute Tox. 4 * H302 GHS07 H302
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
607-088-00-5 methacrylic acid; 201-204-4 79-41-4 Acute Tox. 4 * H312 GHS05 H312 STOT SE 3; D
2-methylpropenoic acid Acute Tox. 4 * H302 GHS07 H302 H335: C ≥ 1 %
Skin Corr. 1A H314 Dgr H314
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-089-00-0 propionic acid ... % 201-176-3 79-09-4 Skin Corr. 1B H314 GHS05 H314 Skin Corr. 1B; B
EN
Dgr H314: C ≥ 25 %
Skin Irrit. 2;
H319: 10 % ≤ C
< 25 %
Eye Irrit. 2; H319:
10 % ≤ C < 25 %
STOT SE 3;
H335: C ≥ 10 %
607-091-00-1 trifluoroacetic acid . . . % 200-929-3 76-05-1 Acute Tox. 4 * H332 GHS05 H332 * B
607-092-00-7 methyl lactate; [1] 208-930-0 547-64-8 [1] Flam. Liq. 3 H226 GHS02 H226 C
methyl (±)-lactate; [2] [1] 2155-30-8 [2] Eye Irrit. 2 H319 GHS07 H319
methyl (R)-lactate; [3] 218-449-8 17392-83-5 [3] STOT SE 3 H335 Wng H335
methyl (S)-(-)-lactate [4] [2] 27871-49-4 [4]
241-420-6
[3]
248-704-9
[4]
607-093-00-2 propionyl chloride 201-170-0 79-03-8 Flam. Liq. 2 H225 GHS02 H225 EUH014 BD
L 353/541
Skin Corr. 1B H314 GHS05 H314
Dgr
L 353/542
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-094-00-8 peracetic acid . . . % 201-186-8 79-21-0 Flam. Liq. 3 H226 GHS02 H226 * BD
EN
Org. Perox. D H242 GHS05 H242 STOT SE 3;
**** H332 GHS07 H332 H335: C ≥ 1 %
Acute Tox. 4 * H312 GHS09 H312
Acute Tox. 4 * H302 Dgr H302
Acute Tox. 4 * H314 H314
Skin Corr. 1A H400 H400
Aquatic Acute 1
607-095-00-3 maleic acid 203-742-5 110-16-7 Acute Tox. 4 * H302 GHS07 H302
607-096-00-9 maleic anhydride 203-571-6 108-31-6 Acute Tox. 4 * H302 GHS08 H302
Skin Corr. 1B H314 GHS05 H314
Resp. Sens. 1 H334 GHS07 H334
Skin Sens. 1 H317 Dgr H317
607-097-00-4 benzene-1,2,4-tricarboxylic acid 1,2-anhy- 209-008-0 552-30-7 STOT SE 3 H335 GHS08 H335
dride; Eye Dam. 1 H318 GHS05 H318
trimellitic anhydride Resp. Sens. 1 H334 GHS07 H334
Skin Sens. 1 H317 Dgr H317
607-098-00-X benzene-1,2:4,5-tetracarboxylic dianhydride; 201-898-9 89-32-7 Eye Dam. 1 H318 GHS08 H318
benzene-1,2:4,5-tetracarboxylic dianhydride; Resp. Sens. 1 H334 GHS05 H334
pyromellitic dianhydride Skin Sens. 1 H317 Dgr H317
607-099-00-5 1,2,3,6-tetrahydrophthalic anhydride; [1] 201-605-4 85-43-8 [1] Eye Dam. 1 H318 GHS08 H318 C
cis-1,2,3,6-tetrahydrophthalic anhydride; [2] [1] 935-79-5 [2] Resp. Sens. 1 H334 GHS05 H334
3,4,5,6-tetrahydrophthalic anhydride; [3] 213-308-7 2426-02-0 [3] Skin Sens. 1 H317 Dgr H317
tetrahydrophthalic anhydride [4] [2] 26266-63-7 [4] Aquatic H412 H412
219-374-3 Chronic 3
31.12.2008
[3]
247-570-9
[4]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-100-00-9 benzophenone-3,3',4,4'-tetracarboxylic di- 219-348-1 2421-28-5 Eye Irrit. 2 H319 GHS07 H319 Eye Irrit. 2; H319:
anhydride; C ≥ 1%
EN
STOT SE 3 H335 Wng H335
4,4'-carbonyldi(phthalic anhydride) STOT SE 3;
H335: C ≥ 1 %
607-101-00-4 1,4,5,6,7,7-hexachlorobicyclo [2,2,1]hept-5- 204-077-3 115-27-5 Eye Irrit. 2 H319 GHS07 H319 Skin Irrit. 2;
ene-2,3-dicarboxylic anhydride chlorendic STOT SE 3 H335 Wng H335 H315: C ≥ 1 %
anhydride Skin Irrit. 2 H315 H315 Eye Irrit. 2; H319:
C ≥ 1%
STOT SE 3;
H335: C ≥ 1 %
607-103-00-5 succinic anhydride 203-570-0 108-30-5 Eye Irrit. 2 H319 GHS07 H319 Eye Irrit. 2; H319:
STOT SE 3 H335 Wng H335 C ≥ 1%
STOT SE 3;
H335: C ≥ 1 %
607-104-00-0 cyclopentane-1,2,3,4-tetracarboxylic dia- 227-964-7 6053-68-5 Eye Irrit. 2 H319 GHS07 H319 Eye Irrit. 2; H319:
nhydride STOT SE 3 H335 Wng H335 C ≥ 1%
STOT SE 3;
H335: C ≥ 1 %
607-105-00-6 8,9,10-trinorborn-5-ene-2,3-dicarboxylic 204-957-7 129-64-6 [1] Eye Dam. 1 H318 GHS08 H318 C
anhydride; [1] [1] 826-62-0 [2] Resp. Sens. 1 H334 GHS05 H334
1,2,3,6-tetrahydro-3,6-methanophthalic 212-557-9 2746-19-2 [3] Skin Sens. 1 H317 Dgr H317
anhydride; [2] [2]
(1α,2α,3β,6β)-1,2,3,6-tetrahydro-3,6-metha- 220-384-5
nophthalic anhydride [3] [3]
607-106-00-1 8,9-dinorborn-5-ene-2,3-dicarboxylic anhy- — 123748-85-6 Acute Tox. 4 * H302 GHS08 H302 STOT SE 3; C
dride Eye Irrit. 2 H319 GHS07 H319 H335: C ≥ 10 %
L 353/543
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Resp. Sens. 1 H334 H334
L 353/544
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-108-00-2 2-hydroxy-1-methylethylacrylate; [1] 220-852-9 2918-23-2 [1] Acute Tox. 3 * H331 GHS06 H331 * CD
2-hydroxypropylacrylate; [2] [1] 999-61-1 [2] Acute Tox. 3 * H311 GHS05 H311 Skin Sens. 1;
acrylic acid, monoester with propane-1,2- 213-663-8 25584-83-2 [3] Acute Tox. 3 * H301 Dgr H301 H317: C ≥ 0,2 %
diol [3] [2] Skin Corr. 1B H314 H314
247-118-0 Skin Sens. 1 H317 H317
[3]
607-110-00-3 pentaerythritol triacrylate 222-540-8 3524-68-3 Eye Irrit. 2 H319 GHS07 H319 D
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-111-00-9 2,2-bis(acryloyloxymethyl)butyl acrylate; 239-701-3 15625-89-5 Eye Irrit. 2 H319 GHS07 H319 D
trimethylolpropane triacrylate Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-112-00-4 2,2-dimethyltrimethylene diacrylate; 218-741-5 2223-82-7 Acute Tox. 3 * H311 GHS06 H311 * D
neopentyl glycol diacrylate Eye Irrit. 2 H319 Dgr H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-113-00-X isobutyl methacrylate 202-613-0 97-86-9 Flam. Liq. 3 H226 GHS02 H226 D
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H400
31.12.2008
607-114-00-5 ethylene dimethacrylate 202-617-2 97-90-5 STOT SE 3 H335 GHS07 H335 STOT SE 3; D
Skin Sens. 1 H317 Wng H317 H335: C ≥ 10 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-115-00-0 isobutyl acrylate 203-417-8 106-63-8 Flam. Liq. 3 H226 GHS02 H226 D
EN
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Wng H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-116-00-6 cyclohexyl acrylate 221-319-3 3066-71-5 STOT SE 3 H335 GHS07 H335 STOT SE 3; D
Skin Irrit. 2 H315 GHS09 H315 H335: C ≥ 10 %
Aquatic H411 Wng H411
Chronic 2
607-118-00-7 1-methyltrimethylene diacrylate; 243-105-9 19485-03-1 Acute Tox. 4 * H312 GHS05 H312 D
1,3-butylene glycol diacrylate Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 Dgr H317
607-119-00-2 tetramethylene diacrylate; 213-979-6 1070-70-8 Acute Tox. 4 * H312 GHS05 H312 D
1,4-butyleneglycol diacrylate Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 Dgr H317
607-120-00-8 2,2'-oxydiethyl diacrylate; 223-791-6 4074-88-8 Acute Tox. 3 * H311 GHS06 H311 * D
diethylene glycol diacrylate Eye Irrit. 2 H319 Dgr H319 Skin Sens. 1;
Skin Irrit. 2 H315 H315 H317: C ≥ 0,2 %
Skin Sens. 1 H317 H317
L 353/545
607-122-00-9 pentaerythritol tetraacrylate 225-644-1 4986-89-4 Eye Irrit. 2 H319 GHS07 H319 D
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
L 353/546
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-123-00-4 2,3-epoxypropyl methacrylate; 203-441-9 106-91-2 Acute Tox. 4 * H332 GHS07 H332 D
EN
glycidyl methacrylate Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-124-00-X 2-hydroxyethyl methacrylate 212-782-2 868-77-9 Eye Irrit. 2 H319 GHS07 H319 D
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-126-00-0 2,2'-(ethylenedioxy)diethyl diacrylate; 216-853-9 1680-21-3 Eye Irrit. 2 H319 GHS07 H319 D
triethylene glycol diacrylate Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-127-00-6 2-diethylaminoethyl methacrylate 203-275-7 105-16-8 Acute Tox. 4 * H332 GHS07 H332 D
Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-128-00-1 2-tert-butylaminoethyl methacrylate 223-228-4 3775-90-4 Eye Irrit. 2 H319 GHS07 H319 D
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
607-129-00-7 ethyl lactate; 202-598-0 97-64-3 [1] Flam. Liq. 3 H226 GHS02 H226 C
ethyl DL-lactate; [1] [1] 687-47-8 [2] STOT SE 3 H335 GHS05 H335
31.12.2008
ethyl (S)-2-hydroxypropionate; 211-694-1 Eye Dam. 1 H318 GHS07 H318
ethyl L-lactate; [2] Dgr
ethyl-(S)-lactate [2]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-130-00-2 pentyl acetate; [1] 211-047-3 628-63-7 [1] Flam. Liq. 3 H226 GHS02 H226 EUH066 C
EN
isopentyl acetate; [2] [1] 123-92-2 [2] Wng
1-methylbutyl acetate; [3] 204-662-3 626-38-0 [3]
2-methylbutyl acetat; [4] [2] 624-41-9 [4]
2(or 3)-methylbutyl acetate [5] 210-946-8 84145-37-9 [5]
[3]
210-843-8
[4]
282-263-3
[5]
607-132-00-3 2-dimethylaminoethyl methacrylate 220-688-8 2867-47-2 Acute Tox. 4 * H312 GHS07 H312 D
Acute Tox. 4 * H302 Wng H302
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
607-133-00-9 monoalkyl or monoaryl or monoalkylaryl — — Eye Irrit. 2 H319 GHS07 H319 STOT SE 3; A
esters of acrylic acid with the exception of STOT SE 3 H335 GHS09 H335 H335: C ≥ 10 %
those specified elsewhere in this Annex Skin Irrit. 2 H315 Wng H315
Aquatic H411 H411
Chronic 2
607-134-00-4 monoalkyl or monoaryl or monoalkyaryl — — Eye Irrit. 2 H319 GHS07 H319 STOT SE 3; A
esters of methacrylic acid with the exception STOT SE 3 H335 Wng H335 H335: C ≥ 10 %
of those specified elsewhere in this Annex Skin Irrit. 2 H315 H315
L 353/547
607-135-00-X butyric acid 203-532-3 107-92-6 Skin Corr. 1B H314 GHS05 H314
Dgr
L 353/548
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-136-00-5 butyryl chloride 205-498-5 141-75-3 Flam. Liq. 2 H225 GHS02 H225
EN
Skin Corr. 1B H314 GHS05 H314
Dgr
607-137-00-0 methyl acetoacetate 203-299-8 105-45-3 Eye Irrit. 2 H319 GHS07 H319
Wng
607-138-00-6 butyl chloroformate; 209-750-5 592-34-7 Flam. Liq. 3 H226 GHS02 H226
chloroformic acid butyl ester Acute Tox. 3 * H331 GHS06 H331
Skin Corr. 1B H314 GHS05 H314
607-139-00-1 2-chloropropionic acid 209-952-3 598-78-7 Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1A H314 GHS07 H314
Dgr
607-140-00-7 isobutyryl chloride 201-194-1 79-30-1 Flam. Liq. 2 H225 GHS02 H225
Skin Corr. 1A H314 GHS05 H314
Dgr
607-141-00-2 oxydiethylene bis(chloroformate) 203-430-9 106-75-2 Acute Tox. 4 * H302 GHS05 H302
Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 GHS09 H318
Aquatic H411 Dgr H411
Chronic 2
607-142-00-8 propyl chloroformate; 203-687-7 109-61-5 Flam. Liq. 2 H225 GHS02 H225
chloroformic acid propylester; Acute Tox. 3 * H331 GHS06 H331
n-propyl chloroformate Skin Corr. 1B H314 GHS05 H314
Dgr
607-143-00-3 valeric acid 203-677-2 109-52-4 Skin Corr. 1B H314 GHS05 H314
Aquatic H412 Dgr H412
Chronic 3
31.12.2008
607-144-00-9 adipic acid 204-673-3 124-04-9 Eye Irrit. 2 H319 GHS07 H319
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-145-00-4 methanesulphonic acid 200-898-6 75-75-2 Skin Corr. 1B H314 GHS05 H314
EN
Dgr
607-146-00-X fumaric acid 203-743-0 110-17-8 Eye Irrit. 2 H319 GHS07 H319
Wng
607-147-00-5 oxalic acid diethylester; 202-464-1 95-92-1 Acute Tox. 4 * H302 GHS07 H302
diethyl oxalate Eye Irrit. 2 H319 Wng H319
607-148-00-0 guanidinium chloride; 200-002-3 50-01-1 Acute Tox. 4 * H302 GHS07 H302
607-150-00-1 endothal (ISO); 205-660-5 145-73-3 Acute Tox. 3 * H301 GHS06 H301
7-oxabicyclo(2,2,1)heptane-2,3-dicarboxylic Acute Tox. 4 * H312 Dgr H312
acid Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
607-152-00-2 2,3,6-TBA (ISO); 200-026-4 50-31-7 Acute Tox. 4 * H302 GHS07 H302
2,3,6-trichlorobenzoic acid Aquatic H411 GHS09 H411
Chronic 2 Wng
607-153-00-8 benazolin (ISO); 223-297-0 3813-05-6 Eye Irrit. 2 H319 GHS07 H319
L 353/549
4-chloro-2,3-dihydro-2-oxo-1,3-benzothia- Skin Irrit. 2 H315 Wng H315
zol-3-ylacetic acid Aquatic H412 H412
Chronic 3
L 353/550
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-154-00-3 ethyl N-benzoyl-N-(3,4-dichlorophenyl)-DL- 244-845-5 22212-55-1 Acute Tox. 4 * H302 GHS07 H302
alaninate;
EN
Aquatic Acute 1 H400 GHS09 H410
benzoylprop-ethyl (ISO) Aquatic H410 Wng
Chronic 1
607-158-00-5 sodium salt of chloroacetic acid; 223-498-3 3926-62-3 Acute Tox. 3 * H301 GHS06 H301
sodium chloroacetate Skin Irrit. 2 H315 GHS09 H315
Aquatic Acute 1 H400 Dgr H400
607-159-00-0 chlorobenzilate (ISO); 208-110-2 510-15-6 Acute Tox. 4 * H302 GHS07 H302
ethyl 2,2-di(4-chlorophenyl)-2-hydroxyace- Aquatic Acute 1 H400 GHS09 H410
tate; Aquatic H410 Wng
ethyl 4,4'-dichlorobenzilate Chronic 1
31.12.2008
607-161-00-1 diethanolamine salt of 4-CPA — — Acute Tox. 4 * H302 GHS07 H302
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-162-00-7 2,2-dichloropropionic acid; 200-923-0 75-99-0 Acute Tox. 4 * H302 GHS05 H302
EN
dalapon Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 Dgr H318
Aquatic H412 H412
Chronic 3
607-165-00-3 diclofop-methyl (ISO) 257-141-8 51338-27-3 Acute Tox. 4 * H302 GHS07 H302
methyl 2-(4-(2,4-dichlorophenoxy)phenoxy) Skin Sens. 1 H317 GHS09 H317
propionate; Aquatic Acute 1 H400 Wng H410
methyl (RS)-2-[4-(2,4-dichlorophenoxy)phe- Aquatic H410
noxy]propionate; Chronic 1
607-166-00-9 medinoterb acetate (ISO); 219-634-6 2487-01-6 Acute Tox. 3 * H301 GHS06 H301
6-tert-butyl-3-methyl-2,4-dinitrophenyl Acute Tox. 4 * H312 Dgr H312
acetate
607-169-00-5 sodium fluoroacetate 200-548-2 62-74-8 Acute Tox. 2 * H330 GHS06 H330
L 353/551
Acute Tox. 1 H310 GHS09 H310
Acute Tox. 2 * H300 Dgr H300
Aquatic Acute 1 H400 H400
L 353/552
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
nium) oxalate; Acute Tox. 4 * H302 GHS09 H302
thiocyclam-oxalate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-174-00-2 reaction mass of dodecyl 3-(2,2,4,4-tetra- 400-580-9 — Skin Irrit. 2 H315 GHS07 H315
methyl-21-oxo-7-oxa-3,20-diazadispiro Aquatic H411 GHS09 H411
(5,1,11,2)henicosan-20-yl)propionate and Chronic 2 Wng
tetradecyl 3-(2,2,4,4-tetramethyl-21-oxo-7-
oxa-3,20-diazadispiro(5,1,11,2)henicosan-
20-yl)propionate
607-175-00-8 methyl 2-(2-nitrobenzylidene)acetoacetate 400-650-9 39562-27-1 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
607-176-00-3 reaction mass of α-3-(3-(2H-benzotriazol-2- 400-830-7 — Skin Sens. 1 H317 GHS07 H317
yl)-5-tert-butyl-4-hydroxyphenyl)propionyl- Aquatic H411 GHS09 H411
ω-hydroxypoly(oxyethylene) and α-3-(3-(2H- Chronic 2 Wng
benzotriazol-2-yl)-5-tert-butyl-4-hydroxy-
phenyl)propionyl-ω-3-(3-(2H-benzotriazol-
2-yl)-5-tert-butyl-4-hydroxyphenyl)propio-
nyloxypoly(oxyethylene)
31.12.2008
607-177-00-9 methyl 2-(3-(4-methoxy-6-methyl-1,3,5- 401-190-1 101200-48-0 Skin Sens. 1 H317 GHS07 H317
triazin-2-yl)3-methylureidosulphonyl) Wng
benzoate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-178-00-4 methyl α-((4,6-dimethoxypyrimidin-2-yl) 401-340-6 83055-99-6 Skin Sens. 1 H317 GHS07 H317
ureidosulphonyl)-o-toluate
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
607-179-00-X (benzothiazol-2-ylthio)succinic acid 401-450-4 95154-01-1 Skin Sens. 1 H317 GHS07 H317
Wng
607-180-00-5 potassium 2-hydroxycarbazole-1-carboxy- 401-630-2 96566-70-0 Acute Tox. 4 * H302 GHS07 H302
late Eye Irrit. 2 H319 Wng H319
STOT SE 3 H335 H335
607-181-00-0 3,5-dichloro-2,4-difluorobenzoyl fluoride 401-800-6 101513-70-6 Acute Tox. 3 * H331 GHS06 H331 EUH029
Skin Corr. 1B H314 GHS05 H314
Acute Tox. 4 * H302 Dgr H302
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
607-184-00-7 S-(3-trimethoxysilyl)propyl 19-isocyanato- 402-290-8 85702-90-5 Flam. Liq. 3 H226 GHS02 H226
11-(6-isocyanatohexyl)-10,12-dioxo- Resp. Sens. 1 H334 GHS08 H334
2,9,11,13-tetraazanonadecanethioate Skin Sens. 1 H317 Dgr H317
607-185-00-2 ethyl trans-3-dimethylaminoacrylate 402-650-4 1117-37-9 Skin Sens. 1 H317 GHS07 H317
Wng
L 353/553
607-186-00-8 quinclorac (ISO); 402-780-1 84087-01-4 Skin Sens. 1 H317 GHS07 H317
3,7-dichloroquinoline-8-carboxylic acid Wng
L 353/554
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-187-00-3 bis(2,2,6,6-tetramethyl-4-piperidyl) succi- 402-940-0 62782-03-0 Eye Irrit. 2 H319 GHS07 H319
nate
EN
Aquatic H412 Wng H412
Chronic 3
607-188-00-9 hydrogen sodium N-carboxylatoethyl-N- 402-970-4 — Skin Sens. 1 H317 GHS07 H317
octadec-9-enylmaleamate Aquatic H411 GHS09 H411
Chronic 2 Wng
607-189-00-4 trimethylenediaminetetraacetic acid 400-400-9 1939-36-2 Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
607-190-00-X methyl acrylamidomethoxyacetate (contain- 401-890-7 77402-03-0 Carc. 1B H350 GHS08 H350
ing ≥ 0,1 % acrylamid) Muta. 1B H340 GHS07 H340
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
607-191-00-5 isobutyl 3,4-epoxybutyrate 401-920-9 100181-71-3 Skin Irrit. 2 H315 GHS07 H315
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-192-00-0 disodium N-carboxymethyl-N-(2-(2-hydro- 402-360-8 92511-22-3 Eye Dam. 1 H318 GHS05 H318
xyethoxy)ethyl)glycinate Dgr
607-194-00-1 propylene carbonate 203-572-1 108-32-7 Eye Irrit. 2 H319 GHS07 H319
Wng
607-195-00-7 2-methoxy-1-methylethyl acetate 203-603-9 108-65-6 Flam. Liq. 3 H226 GHS02 H226
Eye Irrit. 2 H319 GHS07 H319
Wng
31.12.2008
607-196-00-2 heptanoic acid 203-838-7 111-14-8 Skin Corr. 1B H314 GHS05 H314
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-197-00-8 nonanoic acid 203-931-2 112-05-0 Skin Corr. 1B H314 GHS05 H314
EN
Dgr
607-198-00-3 propyl 3,4,5-trihydroxybenzoate 204-498-2 121-79-9 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 Wng H317
607-199-00-9 octyl 3,4,5-trihydroxybenzoate 213-853-0 1034-01-1 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 Wng H317
607-201-00-8 thiocarbonyl chloride 207-341-6 463-71-8 Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
607-205-00-X methyl chloroacetate 202-501-1 96-34-4 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H301 GHS05 H301
L 353/555
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Eye Dam. 1 H318 H318
L 353/556
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-206-00-5 isopropyl chloroacetate 203-301-7 105-48-6 Flam. Liq. 3 H226 GHS02 H226
EN
Acute Tox. 3 * H301 GHS06 H301
Eye Irrit. 2 H319 Dgr H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
607-207-00-0 haloxyfop-etotyl (ISO); 402-560-5 87237-48-7 Acute Tox. 4 * H302 GHS07 H302
2-ethoxyethyl 2-(4-(3-chloro-5-trifluoro- Aquatic Acute 1 H400 GHS09 H410
methyl-2-pyridyloxy)phenoxy)propionate; Aquatic H410 Wng
haloxyfop-(2-ethoxyethyl) Chronic 1
607-209-00-1 reaction mass of O,O'-diisopropyl (pen- 403-030-6 — Acute Tox. 4 * H302 GHS07 H302
tathio)dithioformate and O,O'-diisopropyl Skin Sens. 1 H317 GHS09 H317
(trithio)dithioformate and O,O'-diisopropyl Aquatic Acute 1 H400 Wng H410
(tetrathio)dithioformate
Aquatic H410
Chronic 1
607-210-00-7 methyl acrylamidoglycolate (containing 403-230-3 77402-05-2 Carc. 1B H350 GHS08 H350
≥ 0,1 % acrylamide) Muta. 1B H340 GHS05 H340
Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 Dgr H317
607-211-00-2 methyl 3-(3-tert-butyl-4-hydroxy-5-methyl- 403-270-1 6386-39-6 Acute Tox. 4 * H302 GHS07 H302
phenyl)propionate Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
607-212-00-8 poly(oxypropylenecarbonyl-co-oxy(ethy- 403-300-3 — Skin Sens. 1 H317 GHS07 H317
lethylene)carbonyl), containing 27 % hydro- Wng
xyvalerate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-213-00-3 ethyl 3,3-bis(tert-pentylperoxy)butyrate 403-320-2 67567-23-1 Org. Perox. D H242 GHS02 H242
****
EN
H226 GHS09 H226
Flam. Liq. 3 H411 Dgr H411
Aquatic
Chronic 2
607-214-00-9 N,N-hydrazinodiacetic acid 403-510-5 19247-05-3 Acute Tox. 3 * H301 GHS06 H301
STOT RE 2 * H373 GHS08 H373 **
Skin Sens. 1 ** Dgr H317
Aquatic H317 H412
Chronic 3 H412
607-216-00-X glutamic acid, reaction products with N- 403-950-8 — Acute Tox. 2 * H330 GHS06 H330
(C12-14alkyl)propylenediamine Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 GHS09 H314
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-218-00-0 dichlorprop-P (ISO); 403-980-1 15165-67-0 Acute Tox. 4 * H302 GHS05 H302
(+)-R-2-(2,4-dichlorophenoxy)propionic Skin Irrit. 2 H315 GHS07 H315
acid Eye Dam. 1 H318 Dgr H318
Skin Sens. 1 H317 H317
607-219-00-6 bis(2-ethylhexyl) dithiodiacetate 404-510-8 62268-47-7 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
L 353/557
607-221-00-7 6-docosyloxy-1-hydroxy-4-(1-(4-hydroxy-3- 404-550-6 — Skin Sens. 1 H317 GHS07 H317
methylphenanthren-1-yl)-3-oxo-2-oxaphe- Aquatic H413 Wng H413
nalen-1-yl)naphthalene-2-carboxylic acid Chronic 4
L 353/558
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-222-00-2 6-(2,3-dimethylmaleimido)hexyl methacry- 404-870-6 63740-41-0 Skin Sens. 1 H317 GHS07 H317
EN
late Aquatic H411 GHS09 H411
Chronic 2 Wng
607-223-00-8 transfluthrin (ISO); 405-060-5 118712-89-3 Skin Irrit. 2 H315 GHS07 H315
2,3,5,6-tetrafluorobenzyl trans-2-(2,2- Aquatic Acute 1 H400 GHS09 H410
dichlorovinyl)-3,3-dimethylcyclopropanecar- Aquatic H410 Wng
boxylate Chronic 1
607-226-00-4 reaction mass of 2-acryloyloxyethyl hydro- 405-360-6 — Skin Irrit. 2 H315 GHS05 H315
gen cyclohexane-1,2-dicarboxylate and 2- Eye Dam. 1 H318 GHS07 H318
methacryloyloxyethyl hydrogen cyclohex- Skin Sens. 1 H317 Dgr H317
ane-1,2-dicarboxylate
Aquatic H412 H412
Chronic 3
607-227-00-X potassium 2-amino-2-methylpropionate 405-560-3 120447-91-8 Acute Tox. 4 * H302 GHS05 H302
octahydrate Skin Corr. 1A H314 GHS07 H314
Dgr
31.12.2008
607-228-00-5 bis(2-methoxyethyl) phthalate 204-212-6 117-82-8 Repr. 1B H360- GHS08 H360Df
Df Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 Wng H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
607-230-00-6 2-ethylhexanoic acid 205-743-6 149-57-5 Repr. 2 H361d GHS08 H361d ***
*** Wng
607-232-00-7 pyridate (ISO); 259-686-7 55512-33-9 Skin Irrit. 2 H315 GHS07 H315
O-(6-chloro-3-phenylpyridazin-4-yl) S-octyl Skin Sens. 1 H317 GHS09 H317
thiocarbonate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-233-00-2 hexyl acrylate 219-698-5 2499-95-8 Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
607-235-00-3 mecrilate; 205-275-2 137-05-3 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
methyl 2-cyanoacrylate STOT SE 3 H335 Wng H335 H335: C ≥ 10 %
Skin Irrit. 2 H315 H315
L 353/559
607-236-00-9 ethyl 2-cyanoacrylate 230-391-5 7085-85-0 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
STOT SE 3 H335 Wng H335 H335: C ≥ 10 %
Skin Irrit. 2 H315 H315
L 353/560
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
5-carboxylate; Chronic 2
flurazole
607-240-00-0 cis-1,2,3,6-tetrahydro-4-methylphthalic 216-906-6 1694-82-2 [1] Eye Dam. 1 H318 GHS08 H318 C
anhydride; [1] [1] 3425-89-6 [2] Resp. Sens. 1 H334 GHS05 H334
1,2,3,6-tetrahydro-4-methylphthalic anhy- 222-323-8 5333-84-6 [3] Skin Sens. 1 H317 Dgr H317
dride; [2] [2] 11070-44-3 [4]
1,2,3,6-tetrahydro-3-methylphthalic anhy- 226-247-6 26590-20-5 [5]
dride; [3] [3]
34090-76-1 [6]
tetrahydromethylphthalic anhydride; [4] 234-290-7
[4] 42498-58-8 [7]
1,2,3,6-tetrahydromethylphthalic anhydride;
[5] 247-830-1
tetrahydro-4-methylphthalic anhydride; [6] [5]
2,3,5,6-tetrahydro-2-methylphthalic anhy- 251-823-9
dride [7] [6]
255-853-3
[7]
607-241-00-6 hexahydro-4-methylphthalic anhydride; [1] 243-072-0 19438-60-9 [1] Eye Dam. 1 H318 GHS08 H318 C
hexahydromethylphthalic anhydride; [2] [1] 25550-51-0 [2] Resp. Sens. 1 H334 GHS05 H334
hexahydro-1-methylphthalic anhydride; [3] 247-094-1 48122-14-1 [3] Skin Sens. 1 H317 Dgr H317
hexahydro-3-methylphthalic anhydride [4] [2] 57110-29-9 [4]
256-356-4
31.12.2008
[3]
260-566-1
[4]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-242-00-1 tetrachlorophthalic anhydride 204-171-4 117-08-8 Eye Dam. 1 H318 GHS08 H318
EN
Resp. Sens. 1 H334 GHS05 H334
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-243-00-7 sodium 3,6-dichloro-o-anisate; [1] 217-846-3 1982-69-0 [1] Aquatic H412 — H412
3,6-dichloro-o-anisic acid, compound with [1] 25059-78-3 [2] Chronic 3
2,2'-iminodiethanol (1:1); [2] 246-590-5
607-244-00-2 isooctyl acrylate 249-707-8 29590-42-9 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
STOT SE 3 H335 GHS09 H335 H335: C ≥ 10 %
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
607-245-00-8 tert-butyl acrylate 216-768-7 1663-39-4 Flam. Liq. 2 H225 GHS02 H225 D
Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Dgr H312
Acute Tox. 4 * H302 H302
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
607-246-00-3 allyl methacrylate; 202-473-0 96-05-9 Flam. Liq. 3 H226 GHS02 H226
2-methyl-2-propenoic acid 2-propenyl ester Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 4 * H312 GHS09 H312
L 353/561
Acute Tox. 4 * H302 Dgr H302
Aquatic Acute 1 H400 H400
L 353/562
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-247-00-9 dodecyl methacrylate 205-570-6 142-90-5 Eye Irrit. 2 H319 GHS07 H319 STOT SE 3;
H335: C ≥ 10 %
EN
STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
607-248-00-4 naptalam-sodium (ISO); 205-073-4 132-67-2 Acute Tox. 4 * H302 GHS07 H302
sodium N-naphth-1-ylphthalamate Wng
607-251-00-0 2-methoxypropyl acetate 274-724-2 70657-70-4 Flam. Liq. 3 H226 GHS02 H226
Repr. 1B H360- GHS08 H360D ***
STOT SE 3 D *** GHS07 H335
H335 Dgr
607-252-00-6 lambda-cyhalothrin (ISO); 415-130-7 91465-08-6 Acute Tox. 2 * H330 GHS06 H330
reaction mass of (S)-α-cyano-3-phenoxy- Acute Tox. 3 * H301 GHS09 H301
benzyl(Z)-(1R)-cis-3-(2-chloro-3,3,3-triflu- Acute Tox. 4 * H312 Dgr H312
oropropenyl)-2,2-dimethylcyclopropanecar- Aquatic Acute 1 H400 H410
boxylate and (R)-α-cyano-3-phenoxybenzyl
(Z)-(1S)-cis-3-(2-chloro-3,3,3-trifluoropro- Aquatic H410
penyl)-2,2-dimethylcyclopropanecarboxylate Chronic 1
(1:1)
31.12.2008
boxylate; Aquatic Acute 1 H400 Dgr H410
cyfluthrin Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 2 * H300 GHS09 H300
boxylate; Aquatic Acute 1 H400 Dgr H410
beta-cyfluthrin Aquatic H410
Chronic 1
607-257-00-3 isopropyl propionate 211-300-8 637-78-5 Flam. Liq. 2 H225 GHS02 H225
Dgr
607-259-00-4 methyl 2R,3S-(-)-3-(4-methoxyphenyl)oxira- 404-130-2 105560-93-8 Eye Dam. 1 H318 GHS05 H318
necarboxylate Skin Sens. 1 H317 GHS07 H317
Aquatic H412 Dgr H412
Chronic 3
607-260-00-X ethyl 2-(3-nitrobenzylidene)acetoacetate 404-490-0 39562-16-8 Eye Dam. 1 H318 GHS05 H318
Skin Sens. 1 H317 GHS07 H317
Aquatic H412 Dgr H412
Chronic 3
607-261-00-5 iso(C10-C14)alkyl (3,5-di-tert-butyl-4-hydro- 404-800-4 118832-72-7 Aquatic Acute 1 H400 GHS09 H410
xyphenyl)methylthioacetate Aquatic H410 Wng
Chronic 1
L 353/563
607-262-00-0 7-chloro-1-cyclopropyl-6-fluoro-1,4-dihy- 405-050-0 86393-33-1 Acute Tox. 4 * H302 GHS07 H302
dro-4-oxoquinoline-3-carboxylic acid Aquatic H412 Wng H412
Chronic 3
L 353/564
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-263-00-6 potassium iron(III) 1,3-propanediamine-N, 405-680-6 — Self-heat. 2 **** H252 GHS02 H252
EN
N,N',N'-tetraacetate hemihydrate Aquatic H411 GHS09 H411
Chronic 2 Wng
607-264-00-1 2-chloro-4-(methylsulfonyl)benzoic acid 406-520-8 53250-83-2 Eye Dam. 1 H318 GHS05 H318
Dgr
607-266-00-2 reaction mass of: hydroxyaluminium bis[2- 406-890-0 130296-87-6 Acute Tox. 4 * H302 GHS07 H302
hydroxy-3,5-di-tert-butylbenzoate]; Aquatic Acute 1 H400 GHS09 H410
3,5-di-tert-butyl-salicylic acid Aquatic H410 Wng
Chronic 1
607-267-00-8 tert-butyl (5S,6R,7R)-3-bromomethyl-5,8- 407-620-4 33610-13-8 Resp. Sens. 1 H334 GHS08 H334
dioxo-7-(2-(2-phenylacetamido)-5-thia-1- Skin Sens. 1 H317 Dgr H317
azabicyclo[4.2.0] oct-2-ene-2-carboxylate Aquatic H412 H412
Chronic 3
607-268-00-3 2-methylpropyl (R)-2-hydroxypropanoate 407-770-0 61597-96-4 Eye Irrit. 2 H319 GHS07 H319
Wng
607-269-00-9 (R)-2-(4-hydroxyphenoxy)propanoic acid 407-960-3 94050-90-5 Eye Dam. 1 H318 GHS05 H318
Dgr
31.12.2008
607-271-00-X 2-isopropyl-5-methylcyclohexyloxycarbony- 417-420-9 156324-82-2 Eye Irrit. 2 H319 GHS07 H319
loxy-2-hydroxypropane Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-272-00-5 fluroxypyr-meptyl (ISO); 279-752-9 81406-37-3 [1] Aquatic Acute 1 H400 GHS09 H410
[1]
EN
methylheptyl, O-(4-amino-3,5-dichloro-6- 154486-27-8 Aquatic H410 Wng
fluoro-2-pyridyloxy) acetate; [1] - [2] [2] Chronic 1
fluroxypyr-butometyl (ISO);
2-butoxy-1-methylethyl, O-(4-amino-3,5-
dichloro-6-fluoro-2-pyridyloxy) acetate [2]
607-275-00-1 sodium benzoyloxybenzene-4-sulfonate 405-450-5 66531-87-1 Skin Sens. 1 H317 GHS07 H317
Wng
607-277-00-2 reaction mass of: 2-(hexylthio)ethylamine 405-720-2 — Acute Tox. 4 * H302 GHS05 H302
hydrochloride; Eye Dam. 1 H318 GHS07 H318
sodium propionate Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
607-278-00-8 reaction mass of isomers of: sodium phe- 405-760-0 — Eye Dam. 1 H318 GHS05 H318
nethylnaphthalenesulfonate; Skin Sens. 1 H317 GHS07 H317
sodium naphthylethylbenzenesulfonate Aquatic H412 Dgr H412
Chronic 3
607-279-00-3 reaction mass of n-octadecylaminodiethyl 405-960-8 — Skin Sens. 1 H317 GHS07 H317
L 353/565
bis(hydrogen maleate); Aquatic H411 GHS09 H411
n-octadecylaminodiethyl hydrogen maleate Chronic 2 Wng
hydrogenphthalate
L 353/566
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-280-00-9 sodium 4-chloro-1-hydroxybutane-1-sulfo- 406-190-5 54322-20-2 Acute Tox. 4 * H302 GHS07 H302
nate
EN
Eye Irrit. 2 H319 Wng H319
Skin Sens. 1 H317 H317
607-281-00-4 reaction mass of branched and linear C7-C9 407-000-3 127519-17-9 Aquatic H411 GHS09 H411
alkyl 3-[3-(2H-benzotriazol-2-yl)-5-(1,1- Chronic 2
dimethylethyl)-4-hydroxyphenyl]propio-
nates
607-284-00-0 reaction mass of: sodium 3,3'-(1,4-phenyle- 410-040-4 136213-76-8 Aquatic H411 GHS09 H411
nebis(carbonylimino-3,1-propanediyli- Chronic 2
mino))bis(10-amino-6,13-dichloro-4,11-tri-
phenodioxazinedisulfonate);
lithium 3,3'-(1,4-phenylenebis-(carbonyli-
mino-3,1-propanediyl-imino))bis(10-amino-
6,13-dichloro)-4,11-triphenodioxazinedisul-
fonate (9:1)
607-285-00-6 reaction mass of: 7-(((3-aminophenyl)sulfo- 410-065-0 — Skin Sens. 1 H317 GHS07
nyl)amino)-naphthalene-1,3-disulfonic acid; Wng
sodium 7-(((3-aminophenyl)sulfonyl)
amino)-naphthalene-1,3-disulfonate;
potassium 7-(((3-aminophenyl)sulfonyl)
amino)-naphthalene-1,3-disulfonate
31.12.2008
607-286-00-1 reaction mass of: sodium/potassium 7-[[[3- 410-070-8 141880-36-6 Skin Sens. 1 H317 GHS07 H317
[[4-((2-hydroxy-naphthyl)azo)phenyl]azo] Aquatic H412 Wng H412
phenyl]sulfonyl]amino]-naphthalene-1,3- Chronic 3
disulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
607-288-00-2 tetrasodium (c-(3-(1-(3-(e-6-dichloro-5-cya- 410-160-7 148732-74-5 Eye Irrit. 2 H319 GHS07 H319
nopyrimidin-f-yl(methyl)amino)propyl)-1,6- Skin Sens. 1 H317 Wng H317
dihydro-2-hydroxy-4-methyl-6-oxo-3-pyri- Aquatic H412 H412
dylazo)-4-sulfonatophenylsulfamoyl)phtha- Chronic 3
locyanine-a,b,d-trisulfonato(6-))nickelato II,
where a is 1 or 2 or 3 or 4,b is 8 or 9 or 10
or 11,c is 15 or 16 or 17 or 18, d is 22 or
23 or 24 or 25 and where e and f together
are 2 and 4 or 4 and 2 respectively
607-290-00-3 reaction mass (ratio not known) of: ammo- 410-540-2 — Skin Irrit. 2 H315 GHS07 H315
nium 1-C14-C18-alkyloxycarbonyl-2-(3-ally- Skin Sens. 1 H317 GHS09 H317
loxy-2-hydroxypropoxycarbonyl)ethane-1- Aquatic Acute 1 H400 Wng H410
sulfonate;
Aquatic H410
ammonium 2-C14-C18-alkyloxycarbonyl-1- Chronic 1
(3-allyloxy-2-hydroxypropoxycarbonyl)
ethane-1-sulfonate
607-292-00-4 reaction mass of: [1-(methoxymethyl)-2- 410-640-6 — Skin Irrit. 2 H315 GHS05 H315
(C12-alkoxy)-ethoxy]acetic acid; Eye Dam. 1 H318 GHS09 H318
[1-(methoxymethyl)-2-(C14-alkoxy)-ethoxy] Aquatic Acute 1 H400 Dgr H410
acetic acid Aquatic H410
Chronic 1
607-293-00-X reaction mass of: N-aminoethylpiperazo- 410-650-0 — Eye Dam. 1 H318 GHS05 H318
nium mono-2,4,6-trimethylnonyldiphenyl Skin Sens. 1 H317 GHS07 H317
ether di-sulfonate; Aquatic H411 GHS09 H411
N-aminoethylpiperazonium di-2,4,6-tri- Chronic 2 Dgr
methylnonyldiphenyl ether di-sulfonate
L 353/567
607-294-00-5 sodium 2-benzoyloxy-1-hydroxyethane-sul- 410-680-4 — Skin Sens. 1 H317 GHS07 H317
fonate Wng
L 353/568
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-295-00-0 reaction mass of: tetrasodium phospho- 410-800-5 — Skin Sens. 1 H317 GHS07 H317
EN
noethane-1,2-dicarboxylate; Aquatic H411 GHS09 H411
hexasodium phosphonobutane-1,2,3,4-tet- Chronic 2 Wng
racarboxylate
607-296-00-6 reaction mass of: pentaerythriol tetraesters 410-830-9 — Aquatic H413 — H413
with heptanoic acid and 2-ethylhexanoic Chronic 4
acid
607-297-00-1 (E-E )-3,3'-(1,4-phenylenedimethylidene)bis 410-960-6 92761-26-7 Eye Dam. 1 H318 GHS05 H318
607-299-00-2 methyl 3-(acetylthio)-2-methyl-propanoate 411-040-7 97101-46-7 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-301-00-1 reaction mass of: dodecanoic acid; 411-860-5 — Skin Sens. 1 H317 GHS07 H317
poly(1-7)lactate esters of dodecanoic acid Aquatic H411 GHS09 H411
Chronic 2 Wng
607-302-00-7 reaction mass of: tetradecanoic acid; 411-910-6 — Skin Irrit. 2 H315 GHS05 H315
poly(1-7)lactate esters of tetradecanoic acid Eye Dam. 1 H318 GHS07 H318
31.12.2008
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
oxoquinoline-3-carboxylic acid Aquatic *** Wng H412
Chronic 3 H412
607-304-00-8 fluazifop-butyl (ISO); 274-125-6 69806-50-4 Repr. 1B H360- GHS08 H360D ***
butyl (RS)-2-[4-(5-trifluoromethyl-2-pyridy- Aquatic Acute 1 D *** GHS09 H410
loxy)phenoxy]propionate Aquatic H400 Dgr
Chronic 1 H410
L 353/569
[4-difluoromethyl-4,5-dihydro-3-methyl-5- Chronic 1
oxo-1H-1,2,4-triazol-1-yl]phenyl]propio-
nate
L 353/570
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methyl (E)-2-methoxyimino-[2-(o-tolyloxy- Aquatic Acute 1 H400 GHS09 H410
methyl)phenyl]acetate Aquatic H410 Wng
Chronic 1
607-312-00-1 methoxyacetic acid 210-894-6 625-45-6 Repr. 1B H360- GHS08 H360FD STOT SE 3;
607-313-00-7 neodecanoyl chloride 254-875-0 40292-82-8 Acute Tox. 2 * H330 GHS06 H330 STOT SE 3;
Acute Tox. 4 * H302 GHS06 H302 H335: C ≥ 5 %
Skin Corr. 1B H314 Dgr H314
607-315-00-8 glyphosate (ISO); 213-997-4 1071-83-6 Eye Dam. 1 H318 GHS05 H318
N-(phosphonomethyl)glycine Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
607-318-00-4 dibutyl phthalate; 201-557-4 84-74-2 Repr. 1B H360- GHS08 H360Df
DBP Aquatic Acute 1 Df GHS09 H400
H400 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-319-00-X deltamethrin (ISO); 258-256-6 52918-63-5 Acute Tox. 3 * H331 GHS06 H331
EN
(S)-α-cyano-3-phenoxybenzyl (1R, 3R)-3- Acute Tox. 3 * H301 GHS09 H301
(2,2-dibromovinyl)-2,2-dimethylcyclopropa- Aquatic Acute 1 H400 Dgr H410
necarboxylate Aquatic H410
Chronic 1
607-320-00-5 bis[4-(ethenyloxy)butyl] 1,3-benzenedicar- 413-930-0 130066-57-8 Skin Sens. 1 H317 GHS07 H317
boxylate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
607-324-00-7 reaction mass of: N,N-di(hydrogenated alkyl 413-800-3 — Aquatic H413 — H413
C14-C18)phtalamic acid; Chronic 4
dihydrogenated alkyl (C14-C18)amine
607-325-00-2 (S)-2-chloropropionic acid 411-150-5 29617-66-1 Acute Tox. 4 * H312 GHS05 H312
Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1A H314 Dgr H314
607-326-00-8 reaction mass of: isobutyl hydrogen 2-(α- 410-720-0 141847-13-4 Eye Dam. 1 H318 GHS05 H318
2,4,6-trimethylnon-2-enyl)succinate; Aquatic H411 GHS09 H411
isobutyl hydrogen 2-(ß-2,4,6-trimetyhyl- Chronic 2 Dgr
non-2-enyl)succinate
L 353/571
607-327-00-3 2-(2-iodoethyl)-1,3-propanediol diacetate 411-780-0 127047-77-2 Acute Tox. 4 * H302 GHS07 H302
Aquatic H411 GHS09 H411
Chronic 2 Wng
L 353/572
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-328-00-9 methyl 4-bromomethyl-3-methoxybenzoate 410-310-1 70264-94-7 Skin Irrit. 2 H315 GHS05 H315
EN
Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-329-00-4 reaction mass of: sodium 2-(C12-18-n-alkyl) 411-250-9 — Skin Sens. 1 H317 GHS07 H317
amino-1,4-butandioate; Wng
sodium 2-octadecenyl-amino-1,4-butandio-
ate
607-332-00-0 cyclopentyl chloroformate 411-460-0 50715-28-1 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 4 * H302 GHS08 H302
STOT RE 2 * H373 GHS05 H373 **
Eye Dam. 1 ** Dgr H318
Skin Sens. 1 H318 H317
H317
607-333-00-6 reaction mass of: dodecyl N-(2,2,6,6-tetra- 405-670-1 — Acute Tox. 4 * H302 GHS08 H302
methylpiperidin-4-yl)-β-alaninate; STOT RE 2 * H373 GHS05 H373 **
tetradecyl N-(2,2,6,6-tetramethylpiperidin- Skin Corr. 1B ** GHS07 H314
31.12.2008
4-yl)-β-alaninate Aquatic Acute 1 H314 GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-334-00-1 ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4- 405-880-3 100501-62-0 Skin Sens. 1 H317 GHS07 H317
oxoquinoline-3-carboxylate
EN
Aquatic H412 Wng H412
Chronic 3
607-335-00-7 methyl (R)-2-(4-(3-chloro-5-trifluoro- 406-250-0 72619-32-0 Acute Tox. 4 * H302 GHS07 H302
methyl-2-pyridyloxy)phenoxy)propionate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
607-337-00-8 di-tert-(C12-14)-alkylammonium 2-benzothia- 406-052-4 125078-60-6 Flam. Liq. 3 H226 GHS02 H226
zolylthiosuccinate Acute Tox. 4 * H302 GHS05 H302
Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 GHS09 H318
Aquatic H411 Dgr H411
Chronic 2
607-338-00-3 2-methylpropyl 2-hydroxy-2-methylbut-3- 406-235-9 72531-53-4 Eye Irrit. 2 H319 GHS07 H319
enoate Skin Irrit. 2 H315 Wng H315
L 353/573
607-342-00-5 4-chlorobutyl veratrate 410-950-1 69788-75-6 Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Wng
L 353/574
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
607-344-00-6 reaction mass of: 3-(N-(3-dimethylamino- 407-810-7 — STOT RE 2 * H373 GHS08 H373 **
propyl)-(C4-8)perfluoroalkylsulfonamido) ** Wng
propionic acid;
N-[dimethyl-3-(C4-8-perfluoroalkylsulfona-
mido)propylammonium propionate;
3-(N-(3-dimethyl-propylammonium)-(C4-8)
perfluoroalkylsulfonamido)propionic acid
propionate
607-347-00-2 sodium (R)-2-(2,4-dichlorophenoxy)propio- 413-340-3 119299-10-4 Acute Tox. 4 * H302 GHS05 H302
nate Skin Irrit. 2 H315 GHS07 H315
Eye Dam. 1 H318 Dgr H318
Skin Sens. 1 H317 H317
31.12.2008
607-351-00-4 methyl O-(4-amino-3,5-dichloro-6-fluoro- 407-550-4 69184-17-4 Aquatic H411 GHS09 H411
pyridin-2-yloxy)acetate Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
607-353-00-5 reaction mass of: ethyl exo-tricyclo 407-520-0 80657-64-3 Skin Irrit. 2 H315 GHS07 H315
[5.2.1.02,6]decane-endo-2-carboxylate; Aquatic H411 GHS09 H411
ethyl endo-tricyclo[5.2.1.02,6]decane-exo-2- Chronic 2 Wng
carboxylate
607-357-00-7 reaction mass of: trans-4-acetoxy-4-methyl- 412-450-9 131766-73-9 Skin Sens. 1 H317 GHS07 H317
2-propyl-tetrahydro-2H-pyran; Wng
cis-4-acetoxy-4-methyl-2-propyl-tetrahydro-
2H-pyran
607-360-00-3 sodium 3-acetoacetylamino-4-methoxytolyl- 411-680-7 133167-77-8 Skin Sens. 1 H317 GHS07 H317
6-sulfonate Wng
L 353/575
607-361-00-9 methyl (R)-2-(4-hydroxyphenoxy)propionate 411-950-4 96562-58-2 Eye Dam. 1 H318 GHS05 H318
Aquatic H412 Dgr H412
Chronic 3
L 353/576
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-362-00-4 reaction mass of: (3-methoxy)propylammo- 413-500-2 — Skin Irrit. 2 H315 GHS05 H315
EN
nium/[tris-(2-hydroxyethyl)]ammonium 2- Eye Dam. 1 H318 GHS09 H318
(2-(bis(2-hydroxyethyl)amino)ethoxycarbo- Aquatic H411 Dgr H411
nylmethyl)hexadec-4-enoate; Chronic 2
(3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(2-(bis(2-
hydroxyethyl)amino)ethoxycarbonylmethyl)
tetradec-4-enoate;
(3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(3-methoxy-
propylcarbamoylmethyl)hexadec-4-enoate;
(3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(3-methoxy-
607-366-00-6 3,5-dimethylbenzoyl chloride 413-010-9 6613-44-1 Skin Corr. 1B H314 GHS05 H314
Skin Sens. 1 H317 GHS07 H317
Dgr
607-367-00-1 potassium bis(N-carboxymethyl)-N-methyl- 411-640-9 153352-59-1 Acute Tox. 4 * H302 GHS07 H302
glycinato-(2-)N,O,O,N)-ferrate-(1-) monohy- Wng
drate
31.12.2008
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-369-00-2 reaction mass of: trans-(2R)-5-acetoxy-1,3- 411-660-8 147027-04-1 Acute Tox. 4 * H302 GHS05 H302
EN
oxathiolane-2-carboxylic acid; Skin Irrit. 2 H315 GHS07 H315
cis-(2R)-5-acetoxy-1,3-oxathiolane-2-car- Eye Dam. 1 H318 Dgr H318
boxylic acid Skin Sens. 1 H317 H317
607-373-00-4 (±) tetrahydrofurfuryl (R)-2-[4-(6-chloroqui- 414-200-4 119738-06-6 Muta. 2 H341 GHS08 H341
noxalin-2-yloxy)phenyloxy]propionate Repr. 1B H360- GHS07 H360Df
Acute Tox. 4 * Df GHS09 H302
STOT RE 2 * H302 Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
607-375-00-5 reaction mass of: cis-4-hydroxy-3-(1,2,3,4- 421-960-0 90035-08-8 Acute Tox. 2 * H330 GHS06 H330
tetrahydro-3-(4-(4-trifluoromethylbenzy- Acute Tox. 1 H310 GHS08 H310
loxy)phenyl)-1-naphthyl)coumarin; Acute Tox. 2 * H300 GHS09 H300
trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4- STOT RE 1 H372 Dgr H372 **
(4-trifluoromethylbenzyloxy)phenyl)-1-
L 353/577
Aquatic Acute 1 ** H410
naphthyl)coumarin
Aquatic H400
Chronic 1 H410
L 353/578
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-376-00-0 benzyl 2,4-dibromobutanoate 420-710-8 23085-60-1 Repr. 2 H361f GHS08 H361f ***
***
EN
Skin Irrit. 2 GHS07 H315
Skin Sens. 1 H315 GHS09 H317
Aquatic Acute 1 H317 Wng H410
Aquatic H400
Chronic 1 H410
607-377-00-6 trans-4-cyclohexyl-L-proline monohy- 419-160-1 90657-55-9 Repr. 2 H361f GHS08 H361f ***
drochloride Acute Tox. 4 * *** GHS05 H302
Skin Irrit. 2 H302 GHS07 H315
Eye Dam. 1 H315 Dgr H318
607-378-00-1 ammonium (Z)-α-methoxyimino-2-furyla- 405-990-1 97148-39-5 Flam. Sol. 2 H228 GHS02 H228 T
cetate Dgr
607-380-00-2 reaction mass of: ammonium-1,2-bis(hexy- 407-320-3 — Skin Irrit. 2 H315 GHS05 H315
loxycarbonyl)ethanesulfonate; Eye Dam. 1 H318 Dgr H318
ammonium-1-hexyloxycarbonyl-2-octyloxy- Aquatic H412 H412
carbonylethanesulfonate; Chronic 3
ammonium-2-hexyloxycarbonyl-1-octyloxy-
carbonylethanesulfonate
31.12.2008
acid Skin Sens. 1 H317 GHS07 H317
Aquatic H412 Dgr H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-383-00-9 reaction mass of: 2,2,6,6-tetramethylpiper- 415-430-8 86403-32-9 Eye Dam. 1 H318 GHS05 H318
EN
idin-4-yl-hexadecanoate; Skin Sens. 1 H317 GHS07 H317
2,2,6,6-tetramethylpiperidin-4-yl-octade- Aquatic Acute 1 H400 GHS09 H410
canoate Aquatic H410 Dgr
Chronic 1
607-384-00-4 reaction mass of: esters of C14-C15 branched 413-750-2 171090-93-0 Aquatic H413 — H413
alcohols with 3,5-di-t-butyl-4-hydroxyphe- Chronic 4
nyl propionic acid;
C15 branched and linear alkyl 3,5-bis(1,1-
dimethylethyl)-4-hydroxybenzenepropano-
607-385-00-X Copolymer of vinyl-alcohol and vinyl acetate 414-590-6 125229-74-5 Aquatic H411 GHS09 H411
partially acetilized with 4-(2-(4-formylphe- Chronic 2
nyl)ethenyl)-1-methylpyridinium methylsul-
fate
607-386-00-5 reaction mass of: tetradecanoic acid (42,5- 412-580-6 174591-51-6 Skin Irrit. 2 H315 GHS05 H315
47,5 %); Eye Dam. 1 H318 GHS07 H318
poly(1-7)lactate esters of tetradecanoic acid Skin Sens. 1 H317 GHS09 H317
(52,5- 57,5 %) Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-387-00-0 reaction mass of: dodecanoic acid (35-40 %); 412-590-0 58856-63-6 Skin Irrit. 2 H315 GHS05 H315
poly(1-7)lactate esters of dodecanoic acid Eye Dam. 1 H318 GHS07 H318
(60-65 %) Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
607-388-00-6 4-ethylamino-3-nitrobenzoic acid 412-090-2 2788-74-1 Acute Tox. 4 * H302 GHS07 H302
L 353/579
Skin Sens. 1 H317 Wng H317
Aquatic H412 H412
Chronic 3
L 353/580
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-389-00-1 trisodium N,N-bis(carboxymethyl)-3-amino- 414-130-4 119710-96-2 Acute Tox. 4 * H302 GHS07 H302
2-hydroxypropionate
EN
Wng
607-394-00-9 5-methylpyrazine-2-carboxylic acid 413-260-9 5521-55-1 Eye Dam. 1 H318 GHS05 H318
Dgr
607-395-00-4 reaction mass of: sodium 1-tridecyl-4-allyl- 410-230-7 — Skin Corr. 1B H314 GHS05 H314
(2 or 3)-sulfobutanedioate; Skin Sens. 1 H317 GHS07 H317
sodium 1-dodecyl-4-allyl-(2 or 3)-sulfobu- Aquatic H411 GHS09 H411
tanedioate Chronic 2 Dgr
607-397-00-5 reaction mass of: Ca salicylates (branched 415-930-6 — Skin Sens. 1 H317 GHS07 H317
C10-14 and C18-30 alkylated); Wng
Ca phenates (branched C10-14 and C18-30
alkylated);
Ca sulfurized phenates (branched C10-14 and
C18-30 alkylated)
31.12.2008
607-398-00-0 ethyl N-(5-chloro-3-(4-(diethylamino)-2- 414-820-5 125630-94-6 Aquatic Acute 1 H400 GHS09 H410
methylphenylimino)-4-methyl-6-oxo-1,4- Aquatic H410 Wng
cyclohexadienyl)carbamate Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-399-00-6 2,2-dimethyl 3-methyl-3-butenyl propano- 415-610-6 104468-21-5 Skin Irrit. 2 H315 GHS07 H315
ate
EN
Aquatic H412 Wng H412
Chronic 3
607-400-00-X methyl 3-[[(dibutylamino)thioxomethyl] 414-400-1 32750-89-3 Aquatic Acute 1 H400 GHS09 H410
thio]propanoate Aquatic H410 Wng
Chronic 1
607-401-00-5 ethyl 3-hydroxy-5-oxo-3-cyclohexene-1-car- 414-450-4 88805-65-6 Skin Irrit. 2 H315 GHS05 H315
boxylate Eye Dam. 1 H318 GHS07 H318
607-403-00-6 reaction mass of: bis(1S,2S,4S)-(1-benzyl-4- 414-810-0 — STOT RE 2 * H373 GHS08 H373 **
tert-butoxycarboxamido-2-hydroxy-5-phe- Eye Dam. 1 ** GHS05 H318
nyl)pentylammonium succinate; Aquatic Acute 1 H318 GHS09 H410
isopropyl alcohol Aquatic H400 Dgr
Chronic 1 H410
607-404-00-1 reaction mass of: ((Z)-3,7-dimethyl-2,6- 415-190-4 — Skin Sens. 1 H317 GHS07 H317
octadienyl)oxycarbonylpropanoic acid; Wng
di-((E)-3,7-dimethyl-2,6-octadienyl) butan-
dioate;
di-((Z)-3,7-dimethyl-2,6-octadienyl) butan-
dioate;
(Z)-3,7-dimethyl-2,6-octadienyl butandio-
ate;
((E)-3,7-dimethyl-2,6-octadienyl)oxycarbo-
nylpropanoic acid
L 353/581
607-406-00-2 potassium 2,5-dichlorobenzoate 415-700-5 184637-62-5 Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
Dgr
L 353/582
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-407-00-8 ethyl 2-carboxy-3-(2-thienyl)propionate 415-680-8 143468-96-6 Skin Irrit. 2 H315 GHS05 H315
EN
Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 Dgr H317
607-412-00-5 ethyl 2-(1-cyanocyclohexyl)acetate 415-970-4 133481-10-4 Acute Tox. 4 * H302 GHS08 H302
STOT RE 2 * H373 GHS07 H373 **
Aquatic ** Wng H412
Chronic 3 H412
31.12.2008
607-413-00-0 trans-4-phenyl-L-proline 416-020-1 96314-26-0 Repr. 2 H361f GHS08 H361f ***
Skin Sens. 1 *** GHS07 H317
H317 Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2,4,6-triyltriimino)tribenzoate Chronic 4
607-418-00-8 2-ethylhexyl 4-aminobenzoate 420-170-3 26218-04-2 Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
607-420-00-9 2,2-bis(hydroxymethyl)butanoic acid 424-090-1 10097-02-6 Eye Dam. 1 H318 GHS05 H318
Aquatic H412 Dgr H412
Chronic 3
607-421-00-4 cypermethrin cis/trans +/- 40/60; 257-842-9 52315-07-8 Acute Tox. 4 * H332 GHS07 H332
(RS)-α-cyano-3-phenoxybenzyl Acute Tox. 4 * H302 GHS09 H302
(1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)- STOT SE 3 H335 Wng H335
2,2-dimethylcyclopropanecarboxylate Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/583
Aquatic Acute 1 H335 Dgr H410
Aquatic H400
Chronic 1 H410
L 353/584
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-423-00-5 esters of mecoprop and of mecoprop-P — — Acute Tox. 4 * H302 GHS07 H302 A
EN
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
607-426-00-1 1,2-benzenedicarboxylic acid, dipentylester, 284-032-2 84777-06-0 [1] Repr. 1B H360- GHS08 H360FD
branched and linear; [1] [1] - [2] Aquatic Acute 1 FD GHS09 H400
n-pentyl-isopentylphthalate; [2] - [2] 131-18-0 [3] H400 Dgr
di-n-pentyl phthalate; [3] 205-017-9 605-50-5 [4]
diisopentylphthalate [4] [3]
210-088-4
[4]
607-427-00-7 bromoxynil heptanoate (ISO); 260-300-4 56634-95-8 Repr. 2 H361d GHS08 H361d ***
2,6-dibromo-4-cyanophenyl heptanoate Acute Tox. 4 * *** GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
Skin Sens. 1 H302 Wng H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
31.12.2008
benzyl butyl phthalate e Aquatic Acute 1 Df GHS09 H410
Aquatic H400 Dgr
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-431-00-9 prallethrin (ISO); 245-387-9 23031-36-9 Acute Tox. 3 * H331 GHS06 H331
EN
ETOC; Acute Tox. 4 * H302 GHS09 H302
2-methyl-4-oxo-3-(prop-2-ynyl)cyclopent-2- Aquatic Acute 1 H400 Dgr H410
en-1-yl 2,2-dimethyl-3-(2-methylprop-1- Aquatic H410
enyl)cyclopropanecarboxylate Chronic 1
607-432-00-4 S-metolachlor; - [1] 87392-12-9 [1] Skin Sens. 1 H317 GHS07 H317
reaction mass of (S)-2-chloro-N-(2-ethyl-6- - [2] 178961-20-1 Aquatic Acute 1 H400 GHS09 H410
methyl-phenyl)-N-(2-methoxy-1-methyl- [2] Aquatic H410 Wng
ethyl)-acetamide (80-100 %); [1] (R)-2- Chronic 1
chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-
607-433-00-X cypermethrin cis/trans +/- 80/20; 257-842-9 52315-07-8 Acute Tox. 4 * H302 GHS07 H302
(RS)-α-cyano-3-phenoxybenzyl (1RS; 3RS; STOT SE 3 H335 GHS09 H335
1RS, 3SR)-3-(2,2-dichlorovinyl)-2,2- Skin Irrit. 2 H315 Wng H315
dimethylcyclopropanecarboxylate Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
607-434-00-5 mecoprop-P [1] and its salts; 240-539-0 16484-77-8 Acute Tox. 4 * H302 GHS05 H302
(R)-2-(4-chloro-2-methylphenoxy)propionic Eye Dam. 1 H318 GHS07 H318
acid Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/585
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/586
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Wng
607-439-00-2 methyl tetrahydro-2-furancarboxylate 420-670-1 37443-42-8 Eye Dam. 1 H318 GHS05 H318
Dgr
607-442-00-9 benzyl [hydroxy-(4-phenylbutyl)phosphinyl] 416-050-5 87460-09-1 Eye Dam. 1 H318 GHS05 H318
acetate Dgr
607-444-00-X reaction mass of: cis-1,4-dimethylcyclohexyl 416-230-3 35541-81-2 Aquatic H413 — H413
dibenzoate; Chronic 4
trans-1,4-dimethylcyclohexyl dibenzoate
607-445-00-5 Iron (III) tris(4-methylbenzenesulfonate) 420-960-8 77214-82-5 Eye Dam. 1 H318 GHS05 H318
Dgr
607-446-00-0 methyl 2-[4-(2-chloro-4-nitrophenylazo)-3- 416-240-8 155522-12-6 Skin Sens. 1 H317 GHS07 H317
(1-oxopropyl)amino]phenylaminopropio- Aquatic H413 Wng H413
nate Chronic 4
31.12.2008
607-447-00-6 sodium 4-[4-(4-hydroxyphenylazo)phenyla- 416-370-5 156738-27-1 Skin Sens. 1 H317 GHS07 H317
mino]-3-nitrobenzenesulfonate Aquatic H412 Wng H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-448-00-1 2,3,5,6-tetrafluorobenzoic acid 416-800-1 652-18-6 Skin Irrit. 2 H315 GHS05 H315
EN
Eye Dam. 1 H318 Dgr H318
607-449-00-7 reaction mass of: 4,4',4''-[(2,4,6-trioxo-1,3,5 417-080-1 — Self-react. D H242 GHS02 H242
(2H,4H,6H)-triazine-1,3,5-triyl)tris[methy- **** H317 GHS07 H317
lene(3,5,5-trimethyl-3,1-cyclohexanediyl) Skin Sens. 1 H400 GHS09 H410
iminocarbonyloxy-2,1-ethanediyl(ethyl) Aquatic Acute 1
amino]]trisbenzenediazoniumtri[bis(2- H410 Dgr
methylpropyl)naphthalenesulfonate]; Aquatic
Chronic 1
4,4',4'',4'''-[[5,5'-[carbonylbis[imino(1,5,5-
trimethyl-3,1-cyclohexanediyl)methylene]]-
2,4,6-trioxo-1,3,5(2H,4H,6H)-triazine-
607-453-00-9 4-benzyl-2,6-dihydroxy-4-aza-heptylene bis 418-100-1 172964-15-7 Skin Sens. 1 H317 GHS07 H317
(2,2-dimethyloctanoate) Aquatic H413 Wng H413
Chronic 4
607-454-00-4 reaction mass of: trans-2-(1-methylethyl)- 418-170-3 116193-72-7 Eye Dam. 1 H318 GHS05 H318
1,3-dioxane-5-carboxylic acid; Aquatic H412 Dgr H412
cis-2-(1-methylethyl)-1,3-dioxane-5-car- Chronic 3
boxylic acid
L 353/587
nylamino)-1,3,5-triazin-2-ylamino]-2,2- Wng
dimethyl-propylamino)-anthraquinone-2-
sulfonic acid, sodium/lithium salt
L 353/588
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-456-00-5 3-amino-4-chlorobenzoic acid, hexadecyl 419-700-6 143269-74-3 Aquatic H411 GHS09 H411
EN
ester Chronic 2
607-457-00-0 tetrasodium dihydrogen 1,1''-dihydroxy- 420-350-1 172277-97-3 Eye Dam. 1 H318 GHS05 H318
8,8''-[p-phenylbis(imino-{6-[4-(2-ami- Aquatic H411 GHS09 H411
noethyl)piperazin-1-yl]}-1,3,5-triazine-4,2- Chronic 2 Dgr
diyl-imino)]bis(2,2'-azonaphthalene-1',3,6-
trisulfonate)
607-458-00-6 reaction mass of: 2-ethyl-[2,6-dibromo-4- 420-850-1 — Aquatic H411 GHS09 H411
607-461-00-2 reaction mass of: pentasodium 2-{4-{3- 421-160-1 — Aquatic H412 — H412
methyl-4-[6-sulfonato-4-(2-sulfonato-phe- Chronic 3
nylazo)-naphthalen-1-ylazo]-phenylamino}-
6-[3-(2-sulfato-ethanesulfonyl)-phenyla-
mino]-1,3,5-triazin-2-ylamino}-benzene-
1,4-disulfonate;
pentasodium 2-{4-{3-methyl-4-[7-sulfonato-
31.12.2008
4-(2-sulfonato-phenylazo)-naphthalen-1-
ylazo]-phenylamino}-6-[3-(2-sulfato-ethane-
sulfonyl)-phenylamino]-1,3,5-triazin-2-yla-
mino}-benzene-1,4-disulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-462-00-8 reaction mass of: 1-hexyl acetate; 421-230-1 88230-35-7 Aquatic H411 GHS09 H411
Chronic 2
EN
2-methyl-1-pentyl acetate;
3-methyl-1-pentyl acetate;
4-methyl-1-pentyl acetate;
other mixed linear and branched C6-alkyl
acetates
607-466-00-X reaction mass of: phenyl 1-(1-[2-chloro-5- 421-480-1 — Aquatic H411 GHS09 H411
(hexadecyloxycarbonyl)phenylcarbamoyl]- Chronic 2
3,3-dimethyl-2-oxobutyl)-1H-2,3,3a,7a-tet-
rahydrobenzotriazole-5-carboxylate;
phenyl 2-(1-(2-chloro-5-(hexadecyloxycar-
bonyl)phenylcarbamoyl)-3,3-dimethyl-2-
oxobutyl)-1H-2,3,3a,7a-tetrahydrobenzo-
triazole-5-carboxylate;
phenyl 3-(1-(2-chloro-5-(hexadecyloxycar-
bonyl)phenylcarbamoyl)-3,3-dimethyl-2-
oxobutyl)-1H-2,3,3a,7a-tetrahydrobenzo-
triazole-5-carboxylate
L 353/589
Aquatic Acute 1 H314 Dgr H410
Aquatic H400
Chronic 1 H410
L 353/590
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-468-00-0 reaction mass of: monosodium 4-((4-(5- 419-450-8 — Skin Sens. 1 H317 GHS07 H317
EN
sulfonato-2-methoxyphenylamino)-6- Wng
chloro-1,3,5-triazine-2-yl)amino)-2-((1,4-
dimethyl-6-oxido-2-oxo-5-sulfonatomethyl-
1,2-dihydropyridine-3-yl)azo)benzenesulfo-
nate;
disodium 4-((4-(5-sulfonato-2-methoxyphe-
nylamino)-6-chloro-1,3,5-triazine-2-yl)
amino)-2-((1,4-dimethyl-6-oxido-2-oxo-5-
sulfonatomethyl-1,2-dihydropyridine-3-yl)
azo)benzenesulfonate;
trisodium 4-((4-(5-sulfonato-2-methoxyphe-
nylamino)-6-chloro-1,3,5-triazine-2-yl)
607-470-00-1 potassium sodium 6,13-dichloro-3,10-bis 414-100-0 154336-20-6 Eye Dam. 1 H318 GHS05 H318
{2-[4-[3-(2-hydroxysulphonyloxyethanesul- Aquatic H412 Dgr H412
fonyl)phenylamino]-6-(2,5-disulfonatophe- Chronic 3
nylamino)-1,3,5-triazin-2-ylamino]ethyla-
mino}benzo[5,6][1,4]oxazino[2,3-b]phe-
noxazine-4,11-disulfonate
607-472-00-2 ammonium iron(III) trimethylenediaminete- 400-660-3 111687-36-6 Aquatic H411 GHS09 H411
traacetate hemihydrate Chronic 2
31.12.2008
607-474-00-3 (4-(4-(4-dimethylaminobenzyliden-1-yl)-3- 410-430-4 117573-89-4 Aquatic H413 — H413
methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid Chronic 4
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-475-00-9 reaction mass of: tetrasodium 7-(4-[4- 412-940-2 148878-18-6 Skin Sens. 1 H317 GHS07 H317
EN
chloro-6-[methyl-(3-sulfonatophenyl) Wng
amino]-1,3,5-triazin-2-ylamino]-2-ureido-
phenylazo)naphthalene-1,3,6-trisulfonate;
tetrasodium 7-(4-[4-chloro-6-[methyl-(4-
sulfonatophenyl)amino]-1,3,5-triazin-2-yla-
mino]-2-ureidophenylazo)naphthalene-
1,3,6-trisulfonate (1:1)
607-476-00-4 trisodium N,N-bis(carboxymethyl)-β-alanine 414-070-9 129050-62-0 Skin Corr. 1B H314 GHS05 H314
Aquatic H412 Dgr H412
607-478-00-5 tetramethylammonium hydrogen phthalate 416-900-5 79723-02-7 Acute Tox. 3 * H301 GHS06 H301
STOT RE 2 * H373 GHS08 H373 **
Aquatic Acute 1 ** GHS09 H400
H400 Dgr
607-487-00-4 reaction mass of: disodium 4-(3-ethoxycar- 402-660-9 — Repr. 1B H360- GHS08 H360D ***
bonyl-4-(5-(3-ethoxycarbonyl-5-hydroxy-1- Aquatic D *** Dgr H412
(4-sulfonatophenyl)pyrazol-4-yl)penta-2,4- Chronic 3 H412
dienylidene)-4,5-dihydro-5-oxopyrazol-1-yl)
benzenesulfonate;
trisodium 4-(3-ethoxycarbonyl-4-(5-(3-
ethoxycarbonyl-5-oxido-1-(4-sulfonatophe-
nyl)pyrazol-4-yl)penta-2,4-dienylidene)-4,5-
dihydro-5-oxopyrazol-1-yl)benzenesulfonate
L 353/591
607-488-00-X ethyl (2-acetylamino-5-fluoro-4-isothiocya- 414-210-9 147379-38-2 Aquatic Acute 1 H400 GHS09 H410
natophenoxy)acetate Aquatic H410 Wng
Chronic 1
L 353/592
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-489-00-5 reaction mass of: 2-ethylhexyl linolenate, 414-890-7 71302-79-9 Skin Sens. 1 H317 GHS07 H317
linoleate and oleate;
EN
Wng
2-ethylhexyl epoxyoleate;
2-ethylhexyl diepoxylinoleate;
2-ethylhexyl triepoxylinolenate
607-493-00-7 methyl (3aR,4R,7aR)-2-methyl-4-(1S,2R,3- 415-670-3 78850-37-0 Eye Dam. 1 H318 GHS05 H318
triacetoxypropyl)-3a,7a-dihydro-4H-pyrano Dgr
[3,4-d]oxazole-6-carboxylate
607-495-00-8 sodium 4-sulfophenyl-6-((1-oxononyl) 417-550-6 168151-92-6 Skin Sens. 1 H317 GHS07 H317
amino)hexanoate Wng
31.12.2008
1,2-ethanediyl-bis(2-hexadecenylsuccinate) Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
hydroxy)phenyl]ethanoate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
607-501-00-9 reaction mass of: triphenylthiophosphate 421-820-9 192268-65-8 Aquatic H413 — H413
and tertiary butylated phenyl derivatives Chronic 4
607-506-00-6 reaction mass of: strontium (4-chloro-2- 422-970-8 Aquatic H411 GHS09 H411
((4,5-dihydro-3-methyl-5-oxo-1-(3-sulfona- Chronic 2
tophenyl)-1H-pyrazol-4-yl)azo)-5-methyl)
benzenesulfonate;
disodium (4-chloro-2-((4,5-dihydro-3-
methyl-5-oxo-1-(3-sulfonatophenyl)-1H-
pyrazol-4-yl)azo)-5-methyl)benzenesulfo-
nate
607-507-00-1 potassium,sodium 2,4-diamino-3-[4-(2-sul- 422-980-2 187026-95-5 Eye Dam. 1 H318 GHS05 H318
L 353/593
fonatoethoxysulfonyl)phenylazo]-5-[4-(2- Dgr
sulfonatoethoxysulfonyl)-2-sulfonatopheny-
lazo]-benzenesulfonate
L 353/594
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
nylene-(5-hydroxy-3-methylpyrazole-1,4- Dgr
diyl)azo-4,1-phenylenesulfonylimino-(4-
amino-6-hydroxypyrimidine-2,5-diyl)azo-
4,1-phenylenesulfonylimino(4-amino-6-
hydroxypyrimidine-2,5-diyl)azo]bis(benze-
nesulfonate)]
607-515-00-5 reaction mass of: disodium hexyldiphenyl 429-650-7 147732-60-3 Eye Irrit. 2 H319 GHS07 H319
ether disulphonate; Aquatic H411 GHS09 H411
disodium dihexyldiphenyl ether disulpho- Chronic 2 Wng
nate
607-517-00-6 (S)-α-(acetylthio)benzenepropanoic acid 430-300-0 76932-17-7 Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 Dgr H317
31.12.2008
607-526-00-5 cartap (ISO); — 15263-53-3 Aquatic Acute 1 H400 GHS09 H410
1,3-bis(carbamoylthio)-2-(dimethylamino) Aquatic H410 Wng
propane Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
607-527-00-0 reaction mass of: 1-(1'H,1'H,2'H,2'H-tride- 423-180-6 — STOT RE 2 * H373 GHS08 H373 **
EN
cafluorooctyl)-12-(1''H,1''H,2''H,2''H-tride- ** Wng
cafluorooctyl)dodecanedioate;
1-(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-heptdecafluorodecyl)
dodecanedioate;
1-(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-heneicosafluorododecyl)
dodecanedioate;
1-(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-pentacosafluorotetrade-
cyl)dodecanedioate;
607-696-00-0 pentyl formate 211-340-6 638-49-3 Flam. Liq. 3 H226 GHS02 H226 C
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
L 353/595
Acute Tox. 3 * H301 Dgr H301
Aquatic H411 H411
Chronic 2
L 353/596
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
608-003-00-4 acrylonitrile 203-466-5 107-13-1 Flam. Liq. 2 H225 GHS02 H225 * D
Carc. 1B H350 GHS06 H350
Acute Tox. 3 * H331 GHS08 H331
Acute Tox. 3 * H311 GHS05 H311
Acute Tox. 3 * H301 GHS09 H301
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Eye Dam. 1 H318 H318
Skin Sens. 1 H317 H317
Aquatic H411 H411
608-006-00-0 bromoxynil (ISO) 216-882-7 1689-84-5 Repr. 2 H361d GHS06 H361d *** M = 10
3,5-dibromo-4-hydroxybenzonitrile; Acute Tox. 2 * *** GHS08 H330
bromoxynil phenol Acute Tox. 3 * H330 GHS09 H301
Skin Sens. 1 H301 Dgr H317
Aquatic Acute 1 H317 H410
31.12.2008
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
608-007-00-6 ioxynil (ISO) 216-881-1 1689-83-4 Repr. 2 H361d GHS06 H361d *** M = 10
EN
4-hydroxy-3,5-diiodobenzonitrile Acute Tox. 3 * *** GHS08 H331
Acute Tox. 3 * H331 GHS09 H301
Acute Tox. 4 * H301 Dgr H312
STOT RE 2 * H312 H373 **
Eye Irrit. 2 H373 H319
Aquatic Acute 1 ** H410
Aquatic H319
Chronic 1 H400
H410
L 353/597
Aquatic Acute 1 H410 GHS09
Aquatic Dgr
Chronic 1
L 353/598
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 Wng H302
608-015-00-X dichlobenil (ISO); 214-787-5 1194-65-6 Acute Tox. 4 * H312 GHS07 H312
2,6-dichlorobenzonitrile Aquatic H411 GHS09 H411
Chronic 2 Wng
608-017-00-0 bromoxynil octanoate (ISO); 216-885-3 1689-99-2 Repr. 2 H361d GHS06 H361d *** M = 10
2,6-dibromo-4-cyanophenyl octanoate Acute Tox. 3 * *** GHS08 H331
Acute Tox. 4 * H331 GHS09 H302
Skin Sens. 1 H302 Dgr H317
31.12.2008
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
608-018-00-6 ioxynil octanoate (ISO); 223-375-4 3861-47-0 Repr. 2 H361d GHS06 H361d *** M = 10
EN
4-cyano-2,6-diiodophenyl octanoate Acute Tox. 3 * *** GHS08 H301
Eye Irrit. 2 H301 GHS09 H319
Skin Sens. 1 H319 Dgr H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
608-023-00-3 fenbuconazole (ISO); 406-140-2 114369-43-6 Aquatic Acute 1 H400 GHS09 H410
4-(4-chlorophenyl)-2-phenyl-2-[(1H-1,2,4- Aquatic H410 Wng
triazol-1-yl)methyl]butanenitrile Chronic 1
L 353/599
Skin Sens. 1 ** Wng H317
Aquatic H317 H412
Chronic 3 H412
L 353/600
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
608-027-00-5 reaction mass of: 3-(4-ethylphenyl)-2,2- 412-660-0 — Aquatic H411 GHS09 H411
EN
dimethylpropanenitrile; Chronic 2
3-(2-ethylphenyl)-2,2-dimethylpropaneni-
trile;
3-(3-ethylphenyl)-2,2-dimethylpropaneni-
trile
31.12.2008
608-035-00-9 (±)-α-[(2-acetyl-5-methylphenyl)-amino]- 419-290-9 — Skin Sens. 1 H317 GHS07 H317
2,6-dichlorobenzene-aceto-nitrile Aquatic H413 Wng H413
Chronic 4
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
vinyl)benzonitrile Chronic 4
608-037-00-X reaction mass of: (E)-2,12-tridecadiennitrile; 422-190-8 Aquatic Acute 1 H400 GHS09 H410
(E)-3,12-tridecadiennitrile; Aquatic H410 Wng
(Z)-3,12-tridecadiennitrile Chronic 1
608-065-00-2 salts of bromoxynil with the exception of — — Repr. 2 H361d GHS06 H361d *** M = 10 A
those specified elsewhere in this Annex Acute Tox. 2 * *** GHS08 H330
Acute Tox. 3 * H330 GHS09 H301
Skin Sens. 1 H301 Dgr H317
L 353/601
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
L 353/602
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
608-066-00-8 salts of ioxynil with the exception of those — — Repr. 2 H361d GHS06 H361d *** M = 10 A
EN
specified elsewhere in this Annex Acute Tox. 3 * *** GHS08 H331
Acute Tox. 3 * H331 GHS09 H301
Acute Tox. 4 * H301 Dgr H312
STOT RE 2 * H312 H373 **
Eye Irrit. 2 H373 H319
Aquatic Acute 1 ** H410
Aquatic H319
Chronic 1 H400
H410
609-004-00-2 dinitrobenzene; [1] 246-673-6 25154-54-5 [1] Acute Tox. 2 * H330 GHS06 H330
1,4-dinitrobenzene; [2] [1] 100-25-4 [2] Acute Tox. 1 H310 GHS08 H310
1,3-dinitrobenzene; [3] 202-833-7 99-65-0 [3] Acute Tox. 2 * H300 GHS09 H300
1,2-dinitrobenzene [4] [2] 528-29-0 [4] STOT RE 2 * H373 Dgr H373 **
202-776-8
31.12.2008
Aquatic Acute 1 ** H410
[3] H400
Aquatic
208-431-8 Chronic 1 H410
[4]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 GHS09 H300
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
L 353/603
Aquatic ** H411
Chronic 2 H411
L 353/604
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
picric acid Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 Dgr H311
Acute Tox. 3 * H301 H301
31.12.2008
Acute Tox. 4 * H302 Wng H302
STOT RE 2 * H373 H373 **
**
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
609-016-00-8 dinitrophenol (reaction mass of isomers); [1] 247-096-2 25550-58-7 [1] Acute Tox. 3 * H331 GHS06 H331
2,4(or 2,6)-dinitrophenol [2] [1] 71629-74-8 [2] Acute Tox. 3 * H311 GHS08 H311
275-732-9 Acute Tox. 3 * H301 GHS09 H301
[2] STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
609-019-00-4 lead 2,4,6-trinitro-m-phenylene dioxide; 239-290-0 15245-44-0 Unst. Expl H200 GHS01 H200 1
lead 2,4,6-trinitroresorcinoxide; Repr. 1A H360- GHS08 H360Df
lead styphnate Acute Tox. 4 * Df GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
STOT RE 2 * H302 Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
Chronic 1 H400
H410
609-019-01-1 lead 2,4,6-trinitro-m-phenylene dioxide; 239-290-0 15245-44-0 Expl. 1.1 H201 GHS01 H201 1
lead 2,4,6-trinitroresorcinoxide; Repr. 1A H360- GHS08 H360Df
lead styphnate (≥ 20 % phlegmatiser) Acute Tox. 4 * Df GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
STOT RE 2 * H302 Dgr H373 **
Aquatic Acute 1 H373 H410
Aquatic **
L 353/605
Chronic 1 H400
H410
L 353/606
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
609-020-00-X DNOC (ISO); 208-601-1 534-52-1 Muta. 2 H341 GHS06 H341 EUH044
EN
4,6-dinitro-o-cresol Acute Tox. 2 * H330 GHS08 H330
Acute Tox. 1 H310 GHS05 H310
Acute Tox. 2 * H300 GHS07 H300
Skin Irrit. 2 H315 GHS09 H315
Eye Dam. 1 H318 Dgr H318
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
609-022-00-0 ammonium salt of DNOC; 221-037-0 2980-64-5 Acute Tox. 2 * H330 GHS06 H330
ammonium 4,6-dinitro-o-tolyl oxide Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 GHS09 H300
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
609-023-00-6 dinocap (ISO) 254-408-0 39300-45-3 Repr. 1B H360- GHS08 H360D ***
Acute Tox. 4 * D *** GHS07 H332
STOT RE 2 * H332 GHS09 H373 **
Skin Irrit. 2 H373 Dgr H315
Skin Sens. 1 ** H317
Aquatic Acute 1 H315 H410
31.12.2008
Aquatic H317
Chronic 1 H400
H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
609-024-00-1 binapacryl (ISO); 207-612-9 485-31-4 Repr. 1B H360- GHS08 H360D ***
EN
2-sec-butyl-4,6-dinitrophenyl-3-methylcro- Acute Tox. 4 * D *** GHS07 H312
tonate Acute Tox. 4 * H312 GHS09 H302
Aquatic Acute 1 H302 Dgr H410
Aquatic H400
Chronic 1 H410
609-026-00-2 salts and esters of dinoseb, with the — — Repr. 1B H360- GHS06 H360Df EUH044 A
exception of those specified elsewhere in Acute Tox. 3 * Df GHS08 H311
this Annex Acute Tox. 3 * H311 GHS09 H301
Eye Irrit. 2 H301 Dgr H319
Aquatic Acute 1 H319 H410
Aquatic H400
Chronic 1 H410
609-028-00-3 dinex (ISO); 205-042-5 131-89-5 Acute Tox. 3 * H331 GHS06 H331
2-cyclohexyl-4,6-dinitrophenol Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
L 353/607
Aquatic H410
Chronic 1
L 353/608
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
609-029-00-9 salts and esters of dinex — — Acute Tox. 3 * H331 GHS06 H331 A
EN
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
609-030-00-4 dinoterb (ISO); 215-813-8 1420-07-1 Repr. 1B H360- GHS06 H360D *** EUH044
609-031-00-X salts and esters of dinoterb — — Repr. 1B H360- GHS06 H360D *** A
Acute Tox. 2 * D *** GHS08 H300
Acute Tox. 3 * H300 GHS09 H311
Aquatic Acute 1 H311 Dgr H410
Aquatic H400
Chronic 1 H410
609-032-00-5 bromofenoxim (ISO); 236-129-6 13181-17-4 Acute Tox. 4 * H302 GHS07 H302
3,5-dibromo-4-hydroxybenzaldehyde-O- Aquatic Acute 1 H400 GHS09 H410
(2,4-dinitrophenyl)-oxime Aquatic H410 Wng
Chronic 1
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
609-034-00-6 salts and esters of dinosam — — Acute Tox. 3 * H331 GHS06 H331 A
EN
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/609
Aquatic Acute 1 Dgr H410
Aquatic H400
Chronic 1 H410
L 353/610
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H400
H400
609-042-00-X pendimethalin (ISO); 254-938-2 40487-42-1 Skin Sens. 1 H317 GHS07 H317
N-(1-ethylpropyl)-2,6-dinitro-3,4-xylidine Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
609-043-00-5 quintozene (ISO); 201-435-0 82-68-8 Skin Sens. 1 H317 GHS07 H317
pentachloronitrobenzene Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
609-044-00-0 tecnazene (ISO); 204-178-2 117-18-0 Acute Tox. 4 * H302 GHS07 H302
1,2,4,5-tetrachloro-3-nitrobenzene Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
609-045-00-6 reaction mass of: 4,6-dinitro-2-(3-octyl) — 8069-76-9 Acute Tox. 4 * H302 GHS07 H302
phenyl methyl carbonate and 4,6-dinitro-2- Aquatic Acute 1 H400 GHS09 H410
(4-octyl)phenyl methyl carbonate; Aquatic H410 Wng
dinocton-6 Chronic 1
609-046-00-1 trifluralin (ISO) (containing < 0.5 ppm 216-428-8 1582-09-8 Eye Irrit. 2 H319 GHS07 H319
NPDA); Skin Sens. 1 H317 GHS09 H317
α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p- Aquatic Acute 1 H400 Wng H410
toluidine (containing < 0.5 ppm NPDA); Aquatic H410
2,6-dinitro-N,N-dipropyl-4-trifluoromethy- Chronic 1
31.12.2008
laniline (containing < 0.5 ppm NPDA);
N,N-dipropyl-2,6-dinitro-4-trifluoromethy-
laniline (containing < 0.5 ppm NPDA)
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
609-047-00-7 2-nitroanisole 202-052-1 91-23-6 Carc. 1B H350 GHS08 H350
Acute Tox. 4 * H302 GHS07 H302
Dgr
609-048-00-2 sodium 3-nitrobenzenesulphonate 204-857-3 127-68-4 Eye Irrit. 2 H319 GHS07 H319
Skin Sens. 1 H317 Wng H317
L 353/611
Chronic 1
H410
L 353/612
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Muta. 2 H341 GHS08 H341
Repr. 2 H361f GHS09 H361f ***
Acute Tox. 3 * *** Dgr H331
Acute Tox. 3 * H331 H311
Acute Tox. 3 * H311 H301
STOT RE 2 * H301 H373 **
Aquatic H373 H411
Chronic 2 **
H411
609-054-00-5 2,3-dinitrophenol; [1] 200-628-7 66-56-8 [1] Acute Tox. 3 * H331 GHS06 H331
2,5-dinitrophenol; [2] [1] 329-71-5 [2] Acute Tox. 3 * H311 GHS08 H311
2,6-dinitrophenol; [3] 206-348-1 573-56-8 [3] Acute Tox. 3 * H301 GHS09 H301
3,4-dinitrophenol; [4] [2] 577-71-9 [4] STOT RE 2 * H373 Dgr H373 **
salts of dinitrophenol [5] 209-357-9 - [5] Aquatic ** H411
[3] Chronic 2 H411
31.12.2008
209-415-3
[4]
- [5]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Muta. 2 H341 GHS08 H341
Repr. 2 H361f GHS09 H361f ***
Acute Tox. 3 * *** Dgr H331
Acute Tox. 3 * H331 H311
Acute Tox. 3 * H311 H301
STOT RE 2 * H301 H373 **
Aquatic H373 H411
Chronic 2 **
H411
L 353/613
Aquatic H317 H411
Chronic 2 H411
L 353/614
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
31.12.2008
Acute Tox. 4 * *** Dgr H302
Aquatic H302 H411
Chronic 2 H411
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
609-066-00-0 lithium sodium 3-amino-10-{4-(10-amino- 418-870-9 154212-58-5 Acute Tox. 4 * H332 GHS08 H332
6,13-dichloro-4,11-disulfonatobenzo[5,6]
EN
Acute Tox. 4 * H312 GHS07 H312
[1,4]oxazino[2,3-b]phenoxazine-3-yla- Acute Tox. 4 * H302 Dgr H302
mino)-6-[methyl(2-sulfonato-ethyl)amino]-
1,3,5-triazin-2-ylamino}-6,13-dichloro- STOT SE 2 ** H371 H371 **
benzo[5,6][1,4]oxazino[2,3-b]phenoxazine- **
4,11-disulfonate
609-067-00-6 sodium and potassium 4-(3-aminopropyla- 416-280-6 156769-97-0 Skin Sens. 1 H317 GHS07 H317
mino)-2,6-bis[3-(4-methoxy-2-sulfopheny- Wng
lazo)-4-hydroxy-2-sulfo-7-naphthylamino]-
1,3,5-triazine
609-071-00-8 reaction mass of: 2-methylsulfanyl-4,6-bis- 423-520-3 156137-33-6 Skin Sens. 1 H317 GHS07 H317
(2-hydroxy-4-methoxy-phenyl)-1,3,5-tria- Wng
zine;
2-(4,6-bis-methylsulfanyl-1,3,5-triazin-2-yl)-
5-methoxy-phenol
L 353/615
610-002-00-9 1,1-dichloro-1-nitroethane 209-854-0 594-72-9 Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 Dgr H311
Acute Tox. 3 * H301 H301
L 353/616
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
Aquatic Acute 1 ** H410
Aquatic H400
Chronic 1 H410
610-006-00-0 chloronitroanilines with the exception of — — Acute Tox. 2 * H330 GHS06 H330 AC
those specified elsewhere in this Annex Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 GHS09 H300
STOT RE 2 * H373 Dgr H373 **
Aquatic ** H411
Chronic 2 H411
31.12.2008
610-008-00-1 2,6-dichloro-4-nitroanisole 403-350-6 17742-69-7 Acute Tox. 3 * H301 GHS06 H301
Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
611-003-00-7 fenaminosulf (ISO); 205-419-4 140-56-7 Acute Tox. 3 * H301 GHS06 H301
sodium 4-dimethylaminobenzenediazosul- Acute Tox. 4 * H312 Dgr H312
phonate Aquatic H412 H412
Chronic 3
L 353/617
(1,1'-biphenyl)-4-yl)azo]salicylato(4-)}cup-
rate(2-);
CI Direct Brown 95
L 353/618
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-amino-2',3-dimethylazobenzene; Skin Sens. 1 H317 Dgr H317
fast garnet GBC base;
AAT;
o-aminoazotoluene
611-007-00-9 tricyclazole (ISO); 255-559-5 41814-78-2 Acute Tox. 4 * H302 GHS07 H302
5-methyl-1,2,4-triazolo(3,4-b)benzo-1,3- Wng
thiazole;
611-012-00-6 reaction mass of 2,2-iminodiethanol 6- 403-410-1 114565-65-0 Skin Sens. 1 H317 GHS07 H317
methyl-2-(4-(2,4,6-triaminopyrimidin-5- Wng
ylazo)phenyl)benzothiazole-7-sulfonate and
2-methylaminoethanol 6-methyl-2-(4-
(2,4,6-triaminopyrimidin-5-ylazo)phenyl)
31.12.2008
benzothiazole-7-sulfonate and N,N-diethyl-
propane-1,3-diamine 6-methyl-2-(4-(2,4,6-
triaminopyrimidin-5-ylazo)phenyl)ben-
zothiazole-7-sulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-013-00-1 trilithium-1-hydroxy-7-(3-sulfonatoanilino)- 403-650-7 117409-78-6 Expl. 1.3 **** H203 GHS01 H203
EN
2-(3-methyl-4-(2-methoxy-4-(3-sulfonato- Aquatic H411 GHS09 H411
phenylazo)phenylazo)phenylazo)naphtha- Chronic 2 Dgr
lene-3-sulfonate
611-014-00-7 (tetrasodium 1-(4-(3-acetamido-4-(4'-nitro- 404-250-5 115099-55-3 Skin Sens. 1 H317 GHS07 H317
2,2'-disulfonatostilben-4-ylazo)anilino)-6- Wng
(2,5-disulfonatoanilino)-1,3,5-triazin-2-yl)-
3-carboxypyridinium) hydroxide
611-016-00-8 reaction mass of 1,1'-((dihydroxyphenylene) 404-540-1 — Skin Sens. 1 H317 GHS07 H317
bis(azo-3,1-phenylenazo(1-(3-dimethylami- Wng
nopropyl)-1,2-dihydro-6-hydroxy-4-methyl-
2-oxopyridine-5,3-diyl)))dipyridinium
dichloride dihydrochloride, mixed isomers
and 1-(1-(3-dimethylaminopropyl)-5-(3-((4-
(1-(3-dimethylaminopropyl)-1,6-dihydro-2-
hydroxy-4-methyl-6-oxo-5-pyridinio-3-pyri-
dylazo)phenylazo)-2,4(or2,6 or3,5)-dihy-
droxyphenylazo)phenylazo)-1,2-dihydro-6-
hydroxy-4-methyl-2-oxo-3-pyridyl)pyridi-
nium dichloride
L 353/619
611-019-00-4 tetralithium 6-amino-4-hydroxy-3-(7-sulfo- 405-150-4 106028-58-4 Skin Sens. 1 H317 GHS07 H317
nato-4-(4-sulfonatophenylazo)-1-naphthy- Wng
lazo)naphthalene-2,7-disulfonate
L 353/620
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-020-00-X tetrakis(tetramethylammonium) 6-amino-4- 405-170-3 116340-05-7 Acute Tox. 3 * H301 GHS06 H301
EN
hydroxy-3-(7-sulfonato-4-(4-sulfonatophe- Skin Sens. 1 H317 Dgr H317
nylazo)-1-naphthylazo)naphthalene-2,7-dis- Aquatic H412 H412
ulfonate Chronic 3
31.12.2008
nyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy- Repr. 2 H361d Dgr H361d ***
6-(phenylazo)naphtalene-2,7-disulphonate; ***
C.I. Direct Black 38
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Repr. 2 H361d Dgr H361d ***
2,7-disulphonate]; ***
C.I. Direct Blue 6
L 353/621
611-034-00-6 N-(5-(bis(2-methoxyethyl)amino)-2-((5- 402-430-8 105076-77-5 Aquatic H413 — H413
nitro-2,1-benzisothiazol-3-yl)azo)phenylace- Chronic 4
tamide
L 353/622
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-035-00-1 tetralithium 6-amino-4-hydroxy-3-[7-sulfo- 403-660-1 107246-80-0 Skin Sens. 1 H317 GHS07 H317
EN
nato-4-(5-sulfonato-2-naphthylazo)-1- Aquatic H411 GHS09 H411
naphthylazo]naphthalene-2,7-disulfonate Chronic 2 Wng
611-037-00-2 3(or 5)-(4-(N-benzyl-N-ethylamino)-2- 406-055-0 124584-00-5 Acute Tox. 4 * H302 GHS05 H302
methylphenylazo)-1,4-dimethyl-1,2,4-tria- Eye Dam. 1 H318 GHS07 H318
31.12.2008
mino)-2-sulfonatophenylazo]-4-hydroxy-6- Chronic 3
(4-vinylsulfonylphenylazo)naphthalene-2,7-
disulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-043-00-5 reaction mass of: trisodium N(1')-N(2):N 402-850-1 — Eye Dam. 1 H318 GHS05 H318
EN
(1''')-N(2'')-η-6-[2-amino-4-(or 6)-hydroxy- Aquatic H412 Dgr H412
(or 4-amino-2-hydroxy)phenylazo]-6''-(1- Chronic 3
carbaniloyl-2-hydroxyprop-1-enylazo)-
5',5'''-disulfamoyl-3,3''-disulfonatobis
(naphthalene-2,1'-azobenzene-1,2'-diolato-
O(1),O(2'))-chromate;
trisodium N(1')-N(2):N(1''')-N(2'')-η-6,6''-bis
(1-carbaniloyl-2-hydroxyprop-1-enylazo)-
5',5'''-disulfamoyl-3,3''-disulfonatobis
(naphthalene-2,1'azobenzene-1,2'-diolato-
O(1),O(2'))-chromate;
trisodium N(1')-N(2):N(1''')-N(2'')-η-6,6''-bis
611-044-00-0 reaction mass of: tert-alkyl(C12-C14)ammo- 403-720-7 117527-94-3 Aquatic H411 GHS09 H411
nium bis[1-[(2-hydroxy-5-nitrophenyl)azo]- Chronic 2
2-naphthalenolato(2-)]-chromate(1-);
tert-alkyl(C12-C14)ammonium bis[1-[(2-
hydroxy-4-nitrophenyl)azo]-2-naphthaleno-
lato(2-)]-chromate(1-);
tert-alkyl(C12-C14)ammonium bis[1-[[5-(1,1-
dimethylpropyl)-2-hydroxy-3-nitrophenyl]
azo]-2-naphthalenolato(2-)]-chromate(1-);
tert-alkyl(C12-C14)ammonium [[1-[(2-
hydroxy-5-nitrophenyl)azo]-2-naphthaleno-
lato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-
2-naphthalenolato(2-)]]-chromate(1-);
tert-alkyl(C12-C14)ammonium [[1-[[5-(1,1-
dimethylpropyl)-2-hydroxy-3-nitrophenyl]
azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-
5-nitrophenyl)azo]-2-naphthaleno-
lato(2-)]]-chromate(1-);
tert-alkyl(C12-C14)ammonium ((1-(4(or 5)-
nitro-2-oxidophenylazo)-2-naphtholato)(1-
(3-nitro-2-oxido-5-pentylphenylazo)-2-
naphtholato))chromate(1-)
L 353/623
611-045-00-6 2-[4-[N-(4-acetoxybutyl)-N-ethyl]amino- 404-830-8 — Aquatic H413 — H413
2-methylphenylazo]-3-acetyl-5-nitrothio- Chronic 4
phene
L 353/624
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
STOT RE 2 * H373 GHS08 H373 **
Skin Sens. 1 ** GHS09 H317
Aquatic Acute 1 H317 Dgr H410
Aquatic H400
Chronic 1 H410
611-047-00-7 reaction mass of: 2-[[4-[N-ethyl-N-(2-acet- 407-890-3 111381-11-4 Aquatic H413 — H413
oxyethyl)amino]phenyl]azo]-5,6-dichloro- Chronic 4
benzothiazole;
2-[[4-[N-ethyl-N-(2-acetoxyethyl)amino]
611-048-00-2 reaction mass of: 2-[[4-[bis(2-acetoxyethyl) 407-900-6 111381-12-5 Aquatic H413 — H413
amino]phenyl]azo]-5,6-dichlorobenzothia- Chronic 4
zole;
2-[[4-[bis(2-acetoxyethyl)amino]phenyl]
azo]-6,7-dichlorobenzothiazole (1:1)
611-049-00-8 reaction mass of 7-[4-(3-diethylaminopro- 408-000-6 118658-98-3 STOT RE 2 * H373 GHS08 H373 **
pylamino)-6-(3-diethylammoniopropyla- Skin Sens. 1 ** Wng H317
mino)-1,3,5-triazin-2-ylamino]-4-hydroxy- Aquatic H317 H412
3-(4-phenylazophenylazo)-naphthalene- Chronic 3 H412
2-sulfonate, acetic acid, lactic acid (2:1:1)
611-053-00-X 2,2'-azobis[2-methylpropionamidine] dihy- 221-070-0 2997-92-4 Acute Tox. 4 * H302 GHS07 H302
drochloride Skin Sens. 1 H317 Wng H317
31.12.2008
611-055-00-0 C.I. Disperse Yellow 3; 220-600-8 2832-40-8 Carc. 2 H351 GHS08 H351
N-[4-[(2-hydroxy-5-methylphenyl)azo]phe- Skin Sens. 1 H317 GHS07 H317
nyl]acetamide Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-056-00-6 C.I. Solvent Yellow 14; 212-668-2 842-07-9 Carc. 2 H351 GHS08 H351
EN
1-phenylazo-2-naphthol Muta. 2 H341 GHS07 H341
Skin Sens. 1 H317 Wng H317
Aquatic H413 H413
Chronic 4
611-059-00-2 octasodium 2-(6-(4-chloro-6-(3-(N-methyl- 412-960-1 148878-21-1 Eye Dam. 1 H318 GHS05 H318
N-(4-chloro-6-(3,5-disulfonato-2-naphthy- Skin Sens. 1 H317 GHS07 H317
lazo)-1-hydroxy-6-naphthylamino)-1,3,5- Aquatic H412 Dgr H412
triazin-2-yl)aminomethyl)phenylamino)- Chronic 3
1,3,5-triazin-2-ylamino)-3,5-disulfonato-
1-hydroxy-2-naphthylazo)naphthalene-
1,5-disulfonate
611-060-00-8 reaction mass of: sodium 5-[8-[4-[4-[4-[7- 413-180-4 187285-15-0 Eye Dam. 1 H318 GHS05 H318
(3,5-dicarboxylatophenylazo)-8-hydroxy- Dgr
3,6-disulfonatonaphthalen-1-ylamino]-6-
hydroxy-1,3,5-triazin-2-yl]-2,5-dimethylpi-
perazin-1-yl]-6-hydroxy-1,3,5-triazin-2-yla-
mino]-1-hydroxy-3,6-disulfonatonaphtha-
len-2-ylazo]-isophthalate;
ammonium 5-[8-[4-[4-[4-[7-(3,5-dicarbox-
ylatophenylazo)-8-hydroxy-3,6-disulfonato-
naphthalen-1-ylamino]-
6-hydroxy-1,3,5-triazin-2-yl]-2,5-dimethyl-
piperazin-1-yl]-6-hydroxy-1,3,5-triazin-2-
ylamino]-1-hydroxy-3,6-disulfonato-
naphthalen-2-ylazo]-isophthalate;
5-[8-[4-[4-[4-[7-(3,5-dicarboxylatopheny-
lazo)-8-hydroxy-3,6-disulfonatonaphthalen-
1-ylamino]-6-hydroxy-1,3,5-triazin-2-yl]-
2,5-dimethylpiperazin-1-yl]-6-hydroxy-
L 353/625
1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-dis-
ulfonaphthalen-
2-ylazo]-isophthalic acid
L 353/626
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
imidin-4-ylamino)benzamido]-2-sulfonato- Skin Sens. 1 H317 GHS07 H317
phenylazo]-1-ethyl-6-hydroxy-4-methyl- Dgr
2-oxo-3-pyridylmethylsulfonate
611-066-00-0 tetrasodium 5-[4-chloro-6-(N-ethyl-anilino)- 411-540-5 130201-57-9 Eye Dam. 1 H318 GHS05 H318
31.12.2008
1,3,5-triazin-2-ylamino]-4-hydroxy-3-(1,5- Skin Sens. 1 H317 GHS07 H317
disulfonatonaphthalen-2-ylazo)-naphtha- Aquatic H411 GHS09 H411
lene-2,7-disulfonate Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-067-00-6 reaction mass of: bis(tris(2-(2-hydroxy(1- 406-910-8 — Acute Tox. 4 * H302 GHS05 H302
EN
methyl)ethoxy)ethyl)ammonium) 7-anilino- Eye Dam. 1 H318 GHS07 H318
4-hydroxy-3-(2-methoxy-5-methyl-4-(4-sul- Aquatic H412 Dgr H412
fonatophenylazo)phenylazo)naphthalene-2- Chronic 3
sulfonate;
bis(tris(2-(2-hydroxy(2-methyl)ethoxy)ethyl)
ammonium) 7-anilino-4-hydroxy-3-(2-
methoxy-5-methyl-4-(4-sulfonatopheny-
lazo)phenylazo)naphthalene-2-sulfonate
611-070-00-2 reaction mass of: disodium (6-(4-anisidino)- 405-665-4 — Skin Sens. 1 H317 GHS07 H317
3-sulfonato-2-(3,5-dinitro-2-oxidopheny- Aquatic Acute 1 H400 GHS09 H410
lazo)-1-naphtholato)(1-(5-chloro-2-oxido- Aquatic H410 Wng
phenylazo)-2-naphtholato)chromate(1-); Chronic 1
trisodium bis(5-(4-anisidino)-3-sulfonato-2-
(3,5-dinitro-2-oxidophenylazo)-1-naphtho-
lato)chromate(1-)
611-071-00-8 tris(tetramethylammonium) 5-hydroxy-1-(4- 406-073-9 131013-81-5 Acute Tox. 3 * H301 GHS06 H301
sulphonatophenyl)-4-(4-sulphonatopheny- Aquatic H412 Dgr H412
lazo)pyrazole-3-carboxylate Chronic 3
L 353/627
611-073-00-9 dimethyl 3,3'-(N-(4-(4-bromo-2,6-dicyano- 407-310-9 122630-55-1 Aquatic H413 — H413
phenylazo)-3-hydroxyphenyl)imino)dipro- Chronic 4
pionate
L 353/628
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-074-00-4 reaction mass of: sodium/potassium (3-(4- 407-100-7 — Skin Sens. 1 H317 GHS07 H317
(5-(5-chloro-2,6-difluoropyrimidin-4-yla- Wng
EN
mino)-2-methoxy-3-sulfonatophenylazo)-2-
oxidophenylazo)-2,5,7-trisulfonato-4-
naphtholato)copper(II);
sodium/potassium (3-(4-(5-(5-chloro-4,6-
difluoropyrimidin-2-ylamino)-2-methoxy-3-
sulfonatophenylazo)-2-oxidophenylazo)-
2,5,7-trisulfonato-4-naphtholato)copper(II)
611-075-00-X reaction mass of: tris(3,5,5-trimethylhexy- 406-000-0 — Eye Dam. 1 H318 GHS05 H318
lammonium) 4-amino-3-(4-(4-(2-amino-4- Aquatic H411 GHS09 H411
611-077-00-0 dilithium disodium (5,5'-diamino-(μ-4,4'- 407-230-4 126637-70-5 Acute Tox. 4 * H302 GHS07 H302
dihydroxy-1:2-κ-2,O4,O4',-3,3'-[3,3'-dihy- Skin Sens. 1 H317 Wng H317
droxy-1:2-κ-2-O3,O3'-biphenyl-4,4'-ylene-
bisazo-1:2-(N3,N4-η:N3',N4'-η)]-dinaphtha-
lene-2,7-disulfonato(8)))dicuprate(2-)
611-079-00-1 disodium 7-[4-chloro-6-(N-ethyl-o-tolui- 410-390-8 147703-64-8 Eye Dam. 1 H318 GHS05 H318
dino)-1,3,5-triazin-2-ylamino]-4-hydroxy-3- Dgr
(4-methoxy-2-sulfonatophenylazo)-2-
naphthalenesulfonate
31.12.2008
611-080-00-7 sodium 3-(2-acetamido-4-(4-(2-hydroxybu- 410-150-2 147703-65-9 Skin Sens. 1 H317 GHS07 H317
toxy)phenylazo)phenylazo)benzenesulfonate Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-081-00-2 tetrasodium [7-(2,5-dihydroxy-KO2-7-sulfo- 411-470-5 141048-13-7 Skin Sens. 1 H317 GHS07 H317
EN
nato-6-[4-(2,5,6-trichloro-pyrimidin-4-yla- Aquatic H412 Wng H412
mino)phenylazo]-(N1,N7-N)-1-naphthy- Chronic 3
lazo)-8-hydroxy-KO8-naphthalene-1,3,5-tri-
sulfonato(6-)]cuprate(II)
611-082-00-8 reaction mass of: pentasodium bis(1-(3(or 407-570-3 — Aquatic H411 GHS09 H411
5)-(4-anilino-3-sulfonatophenylazo)-4- Chronic 2
hydroxy-2-oxidophenylazo)-6-nitro-4-sulfo-
nato-2-naphtholato)ferrate(1-);
pentasodium [(1-(3-(4-anilino-3-sulfonato-
phenylazo)-4-hydroxy-2-oxidophenylazo)-
611-083-00-3 reaction mass of: 2-[N-ethyl-4-[(5,6- 411-560-4 — STOT RE 1 H372 GHS08 H372 **
dichlorobenzothiazol- Skin Sens. 1 ** GHS07 H317
2-yl)azo]-m-toludino]ethyl acetate; Aquatic H317 GHS09 H411
2-[N-ethyl-4-[(6,7-dichlorobenzothiazol-2- Chronic 2 H411 Dgr
yl)azo]-m-toludino]ethyl acetate (1:1)
611-085-00-4 reaction mass of: 3-cyano-5-(2-cyano-4- 411-880-4 — Skin Sens. 1 H317 GHS07 H317
nitro-phenylazo)-2-(2-hydroxy-ethylamino)- Aquatic H411 GHS09 H411
4-methyl-6-[3-(2-phenoxyethoxy)propyla- Chronic 2 Wng
mino]pyridine;
3-cyano-5-(2-cyano-4-nitro-phenylazo)-6-
(2-hydroxy-ethylamino)-4-methyl-2-[3-(2-
phenoxyethoxy)propylamino]pyridine;
3-cyano-5-(2-cyano-4-nitro-phenylazo)-2-
amino-4-methyl-6-[3-(3-hydroxypropoxy)
propylamino]pyridine;
L 353/629
3-cyano-5-(2-cyano-4-nitro-phenylazo)-6-
amino-4-methyl-2-[3-(3-methoxypropoxy)
propylamino]pyridine
L 353/630
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
hydroxy-3,5-dinitrophenyl)azo]phenyl]azo]- Chronic 3
2-naphthalenesulfonate], iron complex,
monohydrate
611-091-00-7 sodium (1,0-1,95)/lithium (0,05-1) 5-((5- 413-470-0 134595-59-8 Skin Sens. 1 H317 GHS07 H317
((5-chloro-6-fluoro-pyrimidin-4-yl)amino)-
31.12.2008
Wng
2-sulfonatophenyl)azo)-1,2-dihydro-6-
hydroxy-1,4-dimethyl-2-oxo-3-pyridine-
methylsulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
nitrophenyl)azo)-3-methyl-5-hydroxy-(1H)
pyrazol-1-yl)benzenesulfonamidato)chro-
mate
611-093-00-8 sodium 2-(4-(4-fluoro-6-(2-sulfo-ethyla- 410-770-3 146177-84-6 Skin Sens. 1 H317 GHS07 H317
mino)-[1,3,5]triazin-2-ylamino)-2-ureido- Wng
phenylazo)-5-(4-sulfophenylazo)benzene-
1-sulfonate
611-094-00-3 reaction mass of: 2-[2-acetylamino-4-[N,N- 411-600-0 143145-93-1 Aquatic H413 — H413
611-096-00-4 methyl N-[3-acetylamino)-4-(2-cyano-4- 413-040-2 149850-30-6 Skin Sens. 1 H317 GHS07 H317
nitrophenylazo)phenyl]-N-[(1-methoxy) Wng
acetyl]glycinate
611-097-00-X reaction mass of iron complexes of: 1,3- 414-150-3 — Skin Sens. 1 H317 GHS07 H317
dihydroxy-4-[(5-phenylaminosulfonyl)-2- Aquatic H411 GHS09 H411
hydroxyphenylazo]-n-(5-amino-sulfonyl-2- Chronic 2 Wng
hydroxyphenylazo)benzene and: 1,3-dihy-
droxy-4-[(5-phenylaminosulfonyl)-2-hydro-
xyphenylazo]-n-[4-(4-nitro-2-sulfophenyla-
mino)phenylazo]benzene (n=2,5,6)
L 353/631
(dimethylamino)propyl)-1,2-dihydro-6- Aquatic H411 GHS09 H411
hydroxy-4-methyl-2-oxopyridine-5,3-diyl)))- Chronic 2 Dgr
1,1'-dipyridinium dichloride dihydro-
chloride
L 353/632
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-100-00-4 potassium sodium 3,3'-(3(or4)-methyl-1,2- 403-810-6 140876-13-7 Eye Dam. 1 H318 GHS05 H318
EN
phenylenebis(imino(6-chloro)-1,3,5-tria- Dgr
zine-4,2-diylimino(2-acetamido-5-meth-
oxy)-4,1-phenylenazo)dinaphthalene-1,5-
disulfonate
611-104-00-6 reaction mass of: trisodium (2,4(or 2,6 or 406-870-1 — Skin Sens. 1 H317 GHS07 H317
4,6)-bis(3,5-dinitro-2-oxidophenylazo)-5- Aquatic H411 GHS09 H411
hydroxyphenolato)(2(or 4or 6)-(3,5-dinitro- Chronic 2 Wng
2-oxidophenylazo)-5-hydroxy-4(or 2or 6)-
(4-(4-nitro-2-sulfonatoanilino)phenylazo)
phenolato)ferrate(1-);
trisodium bis(2,4(or 2,6 or 4,6)-bis(3,5-
dinitro-2-oxidophenylazo)-5-hydroxypheno-
lato)ferrate(1-);
trisodium (2,4(or 2,6 or 4,6)-bis(3,5-dinitro-
2-oxidophenylazo)-5-hydroxyphenolato)(2
(or 4 or 6)-(3,5-dinitro-2-oxidophenylazo)-
5-hydroxy-4(or 2 or 6)-(4-nitro-2-sulfona-
tophenylazo)phenolato)ferrate(1-);
trisodium (2,4(or 2,6 or 4,6)-bis(3,5-dinitro-
2-oxidophenylazo)-5-hydroxyphenolato)(2
(or 4 or 6)-(3,5-dinitro-2-oxidophenylazo)-
5-hydroxy-4(or 2 or 6)-(3-sulfonatopheny-
lazo)phenolato)ferrate(1-);
disodium 3,3'-(2,4-dihydroxy-1,3(or 1,5 or
3,5)-phenylenediazo)dibenzenesulfonate
611-105-00-1 sodium 4-(4-chloro-6-(N-ethylanilino)- 407-800-2 136213-75-7 Skin Sens. 1 H317 GHS07 H317
31.12.2008
1,3,5-triazin-2-ylamino)-2-(1-(2-chlorophe- Aquatic H411 GHS09 H411
nyl)-5-hydroxy-3-methyl-1H-pyrazol-4- Chronic 2 Wng
ylazo)benzenesulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-106-00-7 hexasodium 4,4'-dihydroxy-3,3'-bis[2-sulfo- 410-180-6 157627-99-1 Eye Dam. 1 H318 GHS05 H318
nato-4-(4-sulfonatophenylazo)phenylazo]-
EN
Dgr
7,7'[p-phenylenebis[imino(6-chloro-1,3,5-
triazine-4,2-diyl)imino]]dinaphthalene-2-
sulfonate
611-107-00-2 potassium sodium 4-(4-chloro-6-(3,6-disul- 412-490-7 — Skin Sens. 1 H317 GHS07 H317
fonato-7-(5,8-disulfonato-naphthalen-2- Wng
ylazo)-8-hydroxy-naphthalen-1-ylamino)-
1,3,5-triazin-2-ylamino)-5-hydroxy-6-(4-(2-
sulfatoethanesulfonyl)-phenylazo)-naphtha-
lene-1,7-disulfonate
611-109-00-3 reaction products of: copper(II) sulfate and 407-710-3 — Aquatic H411 GHS09 H411
tetrasodium 2,4-bis[6-(2-methoxy-5-sulfo- Chronic 2
natophenylazo)-5-hydroxy-7-sulfonato-2-
naphthylamino]-6-(2-hydroxyethylamino)-
1,3,5-triazine (2:1)
611-110-00-9 tetra-sodium/lithium 4,4'-bis-(8-amino-3,6- 408-210-8 124605-82-9 Skin Sens. 1 H317 GHS07 H317
disulfonato-1-naphthol-2-ylazo)-3-methyla- Aquatic H411 GHS09 H411
zobenzene Chronic 2 Wng
611-113-00-5 lithium sodium (2-(((5-((2,5-dichlorophenyl) 414-280-0 149626-00-6 Aquatic H411 GHS09 H411
azo)-2-hydroxyphenyl)methylene)amino) Chronic 2
L 353/633
benzoato(2-))(2-((4,5-dihydro-3-methyl-5-
oxo-1-phenyl-1H-pyrazol-4-yl)azo)-5-sulfo-
benzoato(3-)) chromate(2-)
L 353/634
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-114-00-0 lithium sodium (4-((5-chloro-2-hydroxy- 414-250-7 149564-66-9 Acute Tox. 4 * H302 GHS05 H302
EN
phenyl)azo)-2,4-dihydro-5-methyl-3H-pyra- Eye Dam. 1 H318 GHS07 H318
zol-3-onato(2-))(3-((4,5-dihydro-3-methyl- Aquatic H412 Dgr H412
1-(4-methylphenyl)-5-oxo-1H-pyrazol-4-yl) Chronic 3
azo)-4-hydroxy-5-nitrobenzenesulfonato
(3-)) chromate(2-)
611-115-00-6 trilithium bis(4-((4-(diethylamino)-2-hydro- 414-290-5 149564-65-8 Acute Tox. 4 * H302 GHS07 H302
xyphenyl)azo)-3-hydroxy-1-naphthalenesul- Aquatic H412 Wng H412
fonato(3-))chromate(3-) Chronic 3
31.12.2008
2-sulfophenylazo}-2-ureido-phenyl-amino]- Wng
6-fluoro-1,3,5-triazin-2-ylamino]-propane,
sodium salt
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-119-00-8 tetrasodium 4-[4-chloro-6-(4-methyl-2-sul- 415-400-4 148878-22-2 Eye Dam. 1 H318 GHS05 H318
EN
fophenylamino)-1,3,5-triazin-2-ylamino]-6- Skin Sens. 1 H317 GHS07 H317
(4,5-dimethyl-2-sulfophenylazo)-5-hydroxy- Dgr
naphthalene-2,7-disulfonate
611-121-00-9 main component 6 (isomer): asym. 1:2 417-280-9 30785-74-1 Eye Dam. 1 H318 GHS05 H318
Cr(III)-complex of: A: 3-hydro- Aquatic Acute 1 H400 GHS09 H410
xy-4-(2-hydroxy-naphthalene-1-ylazo) Aquatic H410 Dgr
naphthalene-1-sulfonic acid, Na-salt and B: Chronic 1
1-[2-hydroxy-5-(4-methoxy-phenylazo)phe-
nylazo]naphthalene-2-ol;
main component 8 (isomer): asym. 1:2 Cr-
complex of: A: 3-hydroxy-4-(2-hydroxy-
naphthalene-1-ylazo)-naphthalene-1-sulfo-
nic acid, Na-salt and B: 1-[2-hydroxy-5-(4-
methoxy-phenylazo)-phenylazo]-naphtha-
lene-2-ol
611-122-00-4 hexasodium (di[N-(3-(4-[5-(5-amino-3- 417-250-5 151436-99-6 Eye Dam. 1 H318 GHS05 H318
methyl-1-phenylpyrazol-4-yl-azo)-2,4-dis- Skin Sens. 1 H317 GHS07 H317
ulfo-anilino]-6-chloro-1,3,5-triazin-2-yla- Dgr
mino)phenyl)-sulfamoyl](di-sulfo)-phthalo-
cyaninato)nickel
L 353/635
mino)-1,3,5-triazin-6-ylamino)propyldiethy-
lammonium lactate
L 353/636
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
611-124-00-5 reaction mass of: pentasodium 5-amino- 424-320-9 Eye Dam. 1 H318 GHS05 H318
EN
3-(5-{4-chloro-6-[4-(2-sulfoxyethoxysulfo- Aquatic H411 GHS09 H411
nato)phenylamino]-1,3,5-triazin-2-yla- Chronic 2 Dgr
mino}-2-sulfonatophenylazo)-6-[5-(2,3-
dibromopropionylamino)-2-sulfonatophe-
nylazo]-4-hydroxynaphthalene-2,7-disulfo-
nate;
pentasodium 5-amino-6-[5-(2-bromoacry-
loylamino)-2-sulfonatophenylazo]-3-(5-{4-
chloro-6-[4-(2-sulfoxyethoxysulfonato)phe-
nylamino]-1,3,5-triazin-2-ylamino}-2-sulfo-
natophenylazo)-4-hydroxynaphthalene-2,7-
disulfonate;
611-125-00-0 reaction mass of: Disodium 6-[3-carboxy- 423-940-7 — Eye Dam. 1 H318 GHS05 H318
4,5-dihydro-5-oxo-4-sulfonatophenyl)pyra- Aquatic H411 GHS09 H411
zolin-4-yl-azo]-3-[2-oxido-4-(ethensulfo- Chronic 2 Dgr
nyl)-5-methoxyphenylazo]-4-oxidonaphtha-
lene-2-sulfonate copper (II) complex;
Disodium 6-[3-carboxy-4,5-dihydro-5-oxo-
4-sulfonatophenyl)pyrazolin-4-yl-azo]-3-[2-
oxido-4-(2-hydroxyethylsulfonyl)-5-methox-
yphenylazo]-4-oxidonaphthalene-2-sulfo-
nate copper (II) complex
31.12.2008
triazin-2-ylamino)-2-sulfonatophenylazo)-5- Aquatic H412 Dgr H412
hydroxy-3-(4-(2-sulfatoethanesulfonyl)phe- Chronic 3
nylazo)naphthalene-2,7-disulfonate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
nylazo)-2,7-disulfonicacid-5-hydroxynapht- Skin Sens. 1 H317 GHS07 H317
4-ylamino]-1,3,5-triazin-2-yl}-N-(2-hydro- Dgr
xyethyl)ethane-1,2-diamine, sodium salt
611-129-00-2 reaction mass of: 5-[(4-[(7-amino-1- 418-230-9 163879-69-4 Expl. 1.3 **** H203 GHS01 H203
hydroxy-3-sulfo-2-naphthyl)azo]-2,5- Repr. 2 H361f GHS08 H361f ***
diethoxyphenyl)azo]-2-[(3-phosphonophe- STOT RE 2 * *** GHS07 H373 **
nyl)azo]benzoic acid; H373
Skin Sens. 1 GHS09 H317
5-[(4-[(7-amino-1-hydroxy-3-sulfo-2- **
naphthyl)azo]-2,5-diethoxyphenyl)azo]-3- Aquatic Dgr H411
Chronic 2 H317
611-130-00-8 tetra-ammonium 2-[6-[7-(2-carboxylato- 418-520-5 183130-96-3 Eye Irrit. 2 H319 GHS07 H319
phenylazo)-8-hydroxy-3,6-disulfonato-1- Aquatic Acute 1 H400 GHS09 H410
naphthylamino]-4-hydroxy-1,3,5-triazin-2- Aquatic H410 Wng
ylamino]benzoate Chronic 1
611-132-00-9 pentasodium bis{7-[4-(1-butyl-5-cyano-1,2- 419-210-2 178452-71-6 Eye Dam. 1 H318 GHS05 H318
dihydro-2-hydroxy-4-methyl-6-oxo-3-pyri- Aquatic H412 Dgr H412
dylazo)phenylsulfonylamino]-5'-nitro-3,3'- Chronic 3
disulfonatonaphthalene-2-azobenzene-1,2'-
diolato} chromate (III)
611-133-00-4 Product by process iron complex of azo 419-260-5 — Eye Dam. 1 H318 GHS05 H318
dyestuffs obtained by coupling a mixture of Aquatic H411 GHS09 H411
diazotized 2-amino-1-hydroxybenzene-4- Chronic 2 Dgr
sulfanilide and 2-amino-1-hydroxybenzene-
4-sulfonamide with resorcin, the obtained
mixture being subsequently submitted to a
second coupling reaction with a mixture of
diazotized 3-aminobenzene-1-sulfonic acid
L 353/637
(metanilic acid) and 4'-amino-4-nitro-1,1'-
diphenylamine-2-sulfonic acid and metalli-
zation with ferric chloride, sodium salt
L 353/638
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
phenylamino]-1,3,5-triazin-2-ylamino]-5- Chronic 2 Dgr
sulfonatophenylazo]-benzylidenehydra-
zino}-4-sulfonatobenzoate, copper complex
611-135-00-5 reaction product of: 2-[[4-amino-2-ureido- 424-250-9 — Eye Dam. 1 H318 GHS05 H318
phenylazo]-5-[(2-(sulfooxy)ethyl)sulfonyl]] Aquatic H412 Dgr H412
benzenesulfonic acid with 2,4,6-trifluoro- Chronic 3
pyrimidine and partial hydrolysis to the
corresponding vinylsulfonyl derivative,
mixed potassium/sodium salt
612-001-00-9 mono-methylamine; [1] 200-820-0 74-89-5 [1] Flam. Gas 1 H220 GHS02 H220 * U
di-methylamine; [2] [1] 124-40-3 [2] Press. Gas H332 GHS04 H332 Skin Irrit. 2; 5
tri-methylamine [3] 204-697-4 75-50-3 [3] Acute Tox. 4 * H335 GHS05 H335 H315: C ≥ 5 %
[2] STOT SE 3 H315 GHS07 H315 Eye Dam. 1;
200-875-0 Skin Irrit. 2 H318 Dgr H318 H318: C ≥ 5 %
[3]
31.12.2008
Eye Dam. 1 Eye Irrit. 2; H319:
0,5 % ≤ C < 5 %
STOT SE 3;
H335: C ≥ 5 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-001-01-6 mono-methylamine ... %; [1] 200-820-0 74-89-5 [1] Flam. Liq. 1 H224 GHS02 H224 * B
EN
di-methylamine ... %; [2] [1] 124-40-3 [2] Acute Tox. 4 * H332 GHS05 H332 STOT SE 3;
tri-methylamine ... % [3] 204-697-4 75-50-3 [3] Acute Tox. 4 * H302 GHS07 H302 H335: C ≥ 5 %
[2] Skin Corr. 1B H314 Dgr H314
200-875-0
[3]
612-003-00-X diethylamine 203-716-3 109-89-7 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3;
Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 1 %
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1A H314 H314
612-004-00-5 triethylamine 204-469-4 121-44-8 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3;
Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 1 %
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1A H314 H314
612-005-00-0 butylamine 203-699-2 109-73-9 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3;
Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 1 %
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1A H314 H314
L 353/639
Skin Corr. 1B H314 GHS07 H314
Resp. Sens. 1 H334 Dgr H334
Skin Sens. 1 H317 H317
L 353/640
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
isopropylamine Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
612-010-00-8 chloroanilines (with exception of those — — Acute Tox. 3 * H331 GHS06 H331 C
specified elsewhere in this Annex) Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
**
31.12.2008
Aquatic Acute 1 H410
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
612-012-00-9 o-nitroaniline; [1] 201-855-4 88-74-4 [1] Acute Tox. 3 * H331 GHS06 H331 C
m-nitroaniline; [2] [1] 99-09-2 [2] Acute Tox. 3 * H311 GHS08 H311
p-nitroaniline [3] 202-729-1 100-01-6 [3] Acute Tox. 3 * H301 Dgr H301
[2] STOT RE 2 * H373 H373 **
202-810-1 Aquatic ** H412
[3]
612-013-00-4 3-aminobenzene sulphonic acid; 204-473-6 121-47-1 Acute Tox. 4 * H332 GHS07 H332
metanilic acid Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
612-014-00-X sulphanilic acid; 204-482-5 121-57-3 Eye Irrit. 2 H319 GHS07 H319
4-aminobenzenesulphonic acid Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
L 353/641
Aquatic H411 H411
Chronic 2
L 353/642
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
tetryl Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 Dgr H301
STOT RE 2 * H373 H373 **
**
612-019-00-7 dipicrylamine, ammonium salt 220-639-0 2844-92-0 Expl. 1.1 H201 GHS01 H201 EUH001
Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 GHS09 H300
STOT RE 2 * H373 Dgr H373 **
Aquatic ** H411
Chronic 2 H411
612-022-00-3 2-naphthylamine 202-080-4 91-59-8 Carc. 1A H350 GHS08 H350 Carc. 1A; H350:
Acute Tox. 4 * H302 GHS07 H302 C ≥ 0,01 %
31.12.2008
Aquatic H411 GHS09 H411
Chronic 2 Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
612-023-00-9 phenylhydrazine; [1] 202-873-5 100-63-0 [1] Carc. 1B H350 GHS06 H350
phenylhydrazinium chloride; [2] [1] 59-88-1 [2] Muta. 2 H341 GHS08 H341
phenylhydrazine hydrochloride; [3] 200-444-7 27140-08-5 [3] Acute Tox. 3 * H331 GHS09 H331
phenylhydrazinium sulphate (2:1) [4] [2] 52033-74-6 [4] Acute Tox. 3 * H311 Dgr H311
248-259-0 Acute Tox. 3 * H301 H301
[3]
STOT RE 1 H372 H372 **
257-622-2 **
[4] Eye Irrit. 2 H319
Skin Irrit. 2 H319 H315
Skin Sens. 1 H315 H317
Aquatic Acute 1 H317 H400
H400
612-025-00-X nitrotoluidines, with the exception of those — — Acute Tox. 3 * H331 GHS06 H331 C
specified elsewhere in this Annex Acute Tox. 3 * H311 GHS08 H311
Acute Tox. 3 * H301 GHS09 H301
STOT RE 2 * H373 Dgr H373 **
Aquatic ** H411
Chronic 2 H411
L 353/643
Aquatic H400
Chronic 1 H410
L 353/644
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-027-00-0 xylidines with the exception of those — — Acute Tox. 3 * H331 GHS06 H331 C
EN
specified elsewhere in this Annex; Acute Tox. 3 * H311 GHS08 H311
dimethyl anilines with the exception of Acute Tox. 3 * H301 GHS09 H301
those specified elsewhere in this Annex STOT RE 2 * H373 Dgr H373 **
Aquatic ** H411
Chronic 2 H411
612-029-00-1 benzene-1,4-diamine dihydrochloride; 210-834-9 624-18-0 Acute Tox. 3 * H331 GHS06 H331
p-phenylenediamine dihydrochloride Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Eye Irrit. 2 H319 H319
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
612-030-00-7 2-methyl-p-phenylenediamine sulphate [1] 210-431-8 615-50-9 [1] Acute Tox. 3 * H301 GHS06 H301
[1] 6369-59-1 [2] Acute Tox. 4 * H332 GHS09 H332
228-871-4 Acute Tox. 4 * H312 Dgr H312
[2] Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
612-031-00-2 N,N-dimethylbenzene-1,3-diamine; [1] 220-623-3 2836-04-6 [1] Acute Tox. 3 * H331 GHS06 H331 C
31.12.2008
4-amino-N,N-dimethylaniline; [1] 99-98-9 [2] Acute Tox. 3 * H311 Dgr H311
3-amino-N,N'-dimethylaniline [2] 202-807-5 Acute Tox. 3 * H301 H301
[2]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
L 353/645
612-037-00-5 salts of 3,3'-dimethoxybenzidine; — — Carc. 1B H350 GHS08 H350 A
salts of o-dianisidine Acute Tox. 4 * H302 GHS07 H302
Dgr
L 353/646
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-methoxy-2-nitroaniline Acute Tox. 1 H310 GHS08 H310
Acute Tox. 2 * H300 Dgr H300
STOT RE 2 * H373 H373 **
Aquatic ** H412
Chronic 3 H412
612-042-00-2 benzidine; 202-199-1 92-87-5 Carc. 1A H350 GHS08 H350 Carc. 1A; H350:
1,1'-biphenyl-4,4'-diamine; Acute Tox. 4 * H302 GHS07 H302 C ≥ 0,01 %
4,4'-diaminobiphenyl; Aquatic Acute 1 H400 GHS09 H410
biphenyl-4,4'-ylenediamine Aquatic H410 Dgr
Chronic 1
31.12.2008
612-044-00-3 N,N'-diacetylbenzidine 210-338-2 613-35-4 Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic H411 H411
Chronic 2
612-049-00-0 di-n-butylamine; [1] 203-921-8 111-92-2 [1] Flam. Liq. 3 H226 GHS02 H226
di-sec-butylamine [2] [1] 626-23-3 [2] Acute Tox. 4 * H332 GHS07 H332
210-937-9 Acute Tox. 4 * H312 Wng H312
[2] Acute Tox. 4 * H302 H302
L 353/647
Aquatic H411
Chronic 2 H317
H411
L 353/648
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-052-00-7 (S)-sec-butylamine; 208-164-7 513-49-5 [1] Flam. Liq. 2 H225 GHS02 H225 C
EN
(S)-2-aminobutane; [1] [1] 13250-12-9 [2] Acute Tox. 4 * H332 GHS05 H332
(R)-sec-butylamine; 236-232-6 13952-84-6 [3] Acute Tox. 4 * H302 GHS07 H302
(R)-2-aminobutane; [2] [2] Skin Corr. 1A H314 GHS09 H314
sec-butylamine; 237-732-7 Aquatic Acute 1 H400 Dgr H400
[3]
2-aminobutane [3]
612-055-00-3 N-methyl-o-toluidine; [1] 210-260-9 611-21-2 [1] Acute Tox. 3 * H331 GHS06 H331 C
N-methyl-m-toluidine; [2] [1] 696-44-6 [2] Acute Tox. 3 * H311 GHS08 H311
N-methyl-p-toluidine [3] 211-795-0 623-08-5 [3] Acute Tox. 3 * H301 Dgr H301
[2] STOT RE 2 * H373 H373 **
210-769-6 Aquatic ** H412
[3] Chronic 3 H412
612-056-00-9 N,N-dimethyl-p-toluidine; [1] 202-805-4 99-97-8 [1] Acute Tox. 3 * H331 GHS06 H331 * C
N,N-dimethyl-m-toluidine; [2] [1] 121-72-2 [2] Acute Tox. 3 * H311 GHS08 H311
N,N-dimethyl-o-toluidine [3] 204-495-6 609-72-3 [3] Acute Tox. 3 * H301 Dgr H301
[2]
31.12.2008
STOT RE 2 * H373 H373 **
210-199-8 Aquatic ** H412
[3] Chronic 3 H412
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Resp. Sens. 1 H334 GHS05 H334
Skin Sens. 1 H317 Dgr H317
Aquatic H412 H412
Chronic 3
L 353/649
Skin Corr. 1B H314 Dgr H314
Skin Sens. 1 H317 H317
L 353/650
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
dipropylenetriamine Acute Tox. 3 * H311 GHS05 H311
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1A H314 H314
Skin Sens. 1 H317 H317
612-065-00-8 polyethlyenepolyamines with the exception — — Acute Tox. 4 * H312 GHS05 H312
of those specified elsewhere in this Annex Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1B H314 GHS09 H314
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
3,3'-dichlorobiphenyl-4,4'-ylenediamine Acute Tox. 4 * H312 GHS07 H312
Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/651
salts of xenylamine; Acute Tox. 4 * H302 GHS07 H302
salts of 4-aminobiphenyl Dgr
L 353/652
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H332 GHS05 H332
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 Dgr H302
Skin Corr. 1B H314 H314
Aquatic H412 H412
Chronic 3
612-077-00-3 dimethylnitrosoamine; 200-549-8 62-75-9 Carc. 1B H350 GHS06 H350 Carc. 1B; H350:
N-nitrosodimethylamine Acute Tox. 2 * H330 GHS08 H330 C ≥ 0,001 %
Acute Tox. 3 * H301 GHS09 H301
STOT RE 1 H372 Dgr H372 **
Aquatic ** H411
Chronic 2 H411
31.12.2008
salts of 4,4'-methylenebis(2-chloroaniline) Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
N,N-diethyl-p-phenylendiamine Skin Corr. 1B H314 GHS05 H314
Dgr
612-083-00-6 1-methyl-3-nitro-1-nitrosoguanidine 200-730-1 70-25-7 Carc. 1B H350 GHS08 H350 Carc. 1B; H350:
Acute Tox. 4 * H332 GHS07 H332 C ≥ 0,01 %
Eye Irrit. 2 H319 GHS09 H319
Skin Irrit. 2 H315 Dgr H315
Aquatic H411 H411
Chronic 2
612-086-00-2 amitraz (ISO); 251-375-4 33089-61-1 Acute Tox. 4 * H302 GHS08 H302 M = 10
N,N-bis(2,4-xylyliminomethyl) methylamine STOT RE 2 * H373 GHS07 H373 **
Skin Sens. 1 ** GHS09 H317
L 353/653
Aquatic Acute 1 H317 Wng H410
Aquatic H400
Chronic 1 H410
L 353/654
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H312 GHS05 H312
Acute Tox. 4 * H302 GHS09 H302
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Eye Dam. 1 H318 H318
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
aniline Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
fluoroaniline hydrochloride Acute Tox. 4 * ** GHS05 H302
Eye Dam. 1 H302 GHS07 H318
Skin Sens. 1 H318 GHS09 H317
Aquatic Acute 1 H317 Dgr H410
Aquatic H400
Chronic 1 H410
612-098-00-8 nitrosodipropylamine 210-698-0 621-64-7 Carc. 1B H350 GHS08 H350 Carc. 1B; H350:
Acute Tox. 4 * H302 GHS07 H302 C ≥ 0,001 %
Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/655
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
L 353/656
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H312 GHS05 H312
Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1A H314 Dgr H314
612-107-00-5 1-phenylethylamine; [1] 202-706-6 98-84-0 [1] Acute Tox. 4 * H312 GHS05 H312
31.12.2008
DL-α-methylbenzylamine [2] [1] 618-36-0 [2] Acute Tox. 4 * H302 GHS07 H302
210-545-8 Skin Corr. 1B H314 Dgr H314
[2]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Corr. 1B H314 GHS07 H314
Dgr
L 353/657
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
L 353/658
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
but-2-ylamino)ethyl)benzamide hydrogen Skin Sens. 1 H317 GHS07 H317
2,3-bis(benzoyloxy)succinate Aquatic H412 Wng H412
Chronic 3
612-115-00-9 dimethyldioctadecylammonium hydrogen 404-050-8 123312-54-9 Eye Irrit. 2 H319 GHS07 H319
sulfate Aquatic H413 Wng H413
Chronic 4
612-117-00-X C12-14-tert-alkylamine, methylphosphonic 404-750-3 119415-07-5 Acute Tox. 4 * H302 GHS05 H302
acid salt Skin Corr. 1B H314 GHS07 H314
Aquatic H411 GHS09 H411
Chronic 2 Dgr
612-118-00-5 A reaction mass of: (1,3-dioxo-2H-benz(de) 405-080-4 — Eye Dam. 1 H318 GHS05 H318
isoquinolin-2-ylpropyl)hexadecyldimethy- Aquatic Acute 1 H400 GHS09 H410
lammonium 4-toluenesulfonate; Aquatic H410 Dgr
(1,3-dioxo-2H-benz(de)isoquinolin-2-ylpro- Chronic 1
pyl)hexadecyldimethylammonium bromide
31.12.2008
612-120-00-6 aclonifen (ISO); 277-704-1 74070-46-5 Aquatic Acute 1 H400 GHS09 H410
2-chloro-6-nitro-3-phenoxyaniline Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-121-00-1 amines, polyethylenepoly-; 268-626-9 68131-73-7 Acute Tox. 4 * H312 GHS05 H312
EN
HEPA Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1B H314 GHS09 H314
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
612-123-00-2 hydroxylammonium chloride; 226-798-2 5470-11-1 [1] Met. Corr. 1 H290 GHS08 H290 GT
hydroxylamine hydrochloride; [1] [1] 10039-54-0 [2] Acute Tox. 4 * H302 GHS05 H302
bis(hydroxylammonium) sulphate; 233-118-8 10046-00-1 [3] STOT RE 2 * H373 GHS07 H373 **
hydroxylamine sulphate (2:1); [2] [2] Eye Irrit. 2 ** GHS09 H319
hydroxylammonium hydrogensulphate; 233-154-4 Skin Irrit. 2 H319 Wng H315
[3] H315
hydroxylamine sulphate (1:1) [3] Skin Sens. 1 H317
Aquatic Acute 1 H317 H400
H400
612-124-00-8 N,N,N-trimethylanilinium chloride 205-319-0 138-24-9 Acute Tox. 3 * H311 GHS06 H311
Acute Tox. 3 * H301 Dgr H301
L 353/659
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
L 353/660
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-methyl-m-phenylenediamine sulfate Acute Tox. 3 * H301 GHS08 H301
Acute Tox. 4 * H312 GHS09 H312
Eye Irrit. 2 H319 Dgr H319
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
612-129-00-5 diisopropylamine 203-558-5 108-18-9 Flam. Liq. 2 H225 GHS02 H225 STOT SE 3;
Acute Tox. 4 * H332 GHS05 H332 H335: C ≥ 5 %
Acute Tox. 4 * H302 GHS07 H302
Skin Corr. 1B H314 Dgr H314
612-130-00-0 2,6-diamino-3,5-diethyltoluene; 218-255-3 2095-01-4 [1] Acute Tox. 4 * H312 GHS08 H312 C
4,6-diethyl-2-methyl-1,3-benzenediamine; [1] 2095-02-5 [2] Acute Tox. 4 * H302 GHS07 H302
[1] 218-256-9 68479-98-1 [3] STOT RE 2 * H373 GHS09 H373 **
2,4-diamino-3,5-diethyltoluene; [2] Eye Irrit. 2 ** Wng H319
2,4-diethyl-6-methyl-1,3-benzenediamine; 270-877-4 Aquatic Acute 1 H319 H410
[2] [3] H400
Aquatic
diethylmethylbenzenediamine [3] Chronic 1 H410
31.12.2008
612-131-00-6 didecyldimethylammonium chloride 230-525-2 7173-51-5 Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 GHS07 H314
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
N,N'-diphenyl-1,4-benzenediamine Aquatic H412 Wng H412
Chronic 3
612-136-00-3 N-isopropyl-N'-phenyl-p-phenylenediamine 202-969-7 101-72-4 Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1;
Skin Sens. 1 H317 GHS09 H317 H317: C ≥ 0,1 %
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
L 353/661
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/662
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-138-00-4 furalaxyl (ISO); 260-875-1 57646-30-7 Acute Tox. 4 * H302 GHS07 H302
EN
methyl N-(2,6-dimethylphenyl)-N-(2-furyl- Aquatic H412 Wng H412
carbonyl)-DL-alaninate Chronic 3
612-140-00-5 quaternary ammonium compounds, benzyl- 264-151-6 63449-41-2 Acute Tox. 4 * H312 GHS05 H312
C8-18-alkyldimethyl, chlorides Acute Tox. 4 * H302 GHS07 H302
612-143-00-1 N5,N5-diethyltoluene-2,5-diamine monohy- 218-130-3 2051-79-8 Acute Tox. 3 * H301 GHS06 H301
drochloride; Eye Irrit. 2 H319 GHS09 H319
4-diethylamino-2-methylaniline monohy- Skin Sens. 1 H317 Dgr H317
drochloride Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
612-145-00-2 o-phenylenediamine 202-430-6 95-54-5 Carc. 2 H351 GHS06 H351
Muta. 2 H341 GHS08 H341
Acute Tox. 3 * H301 GHS09 H301
Acute Tox. 4 * H332 Dgr H332
Acute Tox. 4 * H312 H312
Eye Irrit. 2 H319 H319
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
L 353/663
Chronic 1
L 353/664
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H331 GHS08 H331
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Eye Irrit. 2 H319 H319
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
612-151-00-5 diaminotoluene, technical product - reaction 246-910-3 25376-45-8 [1] Carc. 1B H350 GHS06 H350
mass of [2] and [3]; [1] 95-80-7 [2] Acute Tox. 3 * H301 GHS08 H301
methyl-phenylenediamine; [1] 202-453-1 823-40-5 [3] Acute Tox. 4 * H332 GHS09 H332
4-methyl-m-phenylene diamine; [2] [2] Acute Tox. 4 * H312 Dgr H312
2-methyl-m-phenylene diamine [3] 212-513-9 Eye Irrit. 2 H319 H319
[3]
31.12.2008
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
diamine Acute Tox. 4 * H332 GHS08 H332
Acute Tox. 4 * H302 GHS05 H302
STOT RE 2 * H373 GHS07 H373 **
Skin Corr. 1A ** Dgr H314
Aquatic H314 H412
Chronic 3 H412
612-156-00-2 reaction mass of: trihexadecylmethylammo- 405-620-9 — Eye Dam. 1 H318 GHS05 H318
nium chloride; Aquatic Acute 1 H400 GHS09 H410
dihexadecyldimethylammonium chloride Aquatic H410 Dgr
Chronic 1
L 353/665
benzald-oximate) copper (II) C12-alkyl group Chronic 4
is branched;
4-dodecylsalicylaldoxime
L 353/666
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-159-00-9 Reaction products of: trimethylhexamethy- 410-880-1 — Acute Tox. 4 * H302 GHS05 H302
EN
lene diamine (a mixture of 2,2,4-trimethyl- Skin Corr. 1B H314 GHS07 H314
1,6-hexanediamine and 2,4,4-trimethyl-1,6- Aquatic Acute 1 H400 GHS09 H410
hexanediamine, EINECS listed), Epoxide 8
(mono[(C10-C16-alkyloxy)methyl]oxirane Aquatic H410 Dgr
derivatives) and p-toluene-sulfonic acid Chronic 1
612-162-00-5 dimethyldioctadecylammonium chloride; 203-508-2 107-64-2 Eye Dam. 1 H318 GHS05 H318
DODMAC Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
mefenoxam; Eye Dam. 1 H318 GHS07 H318
(R)-2-[(2,6-dimethylphenyl)-methoxyacetyla- Dgr
mino]propionic acid methyl ester
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 GHS05 H302
STOT RE 2 * H373 GHS07 H373 **
Skin Corr. 1B ** Dgr H314
Skin Sens. 1 H314 H317
Aquatic H317 H412
Chronic 3 H412
612-170-00-9 4-chlorophenyl cyclopropyl ketone O-(4- 405-260-2 — Acute Tox. 4 * H302 GHS07 H302
aminobenzyl)oxime Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
L 353/667
diethyldiphenylmethane Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
L 353/668
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
STOT RE 2 * H373 GHS05 H373 **
Skin Corr. 1A ** GHS07 H314
Aquatic H314 Dgr H412
Chronic 3 H412
612-173-00-5 lithium 1-amino-4-(4-tert-butylanilino) 411-140-0 125328-86-1 Eye Dam. 1 H318 GHS05 H318
anthraquinone-2-sulfonate Skin Sens. 1 H317 GHS07 H317
Aquatic H411 GHS09 H411
Chronic 2 Dgr
612-175-00-6 2-(O-aminooxy)ethylamine dihydrochloride 412-310-7 37866-45-8 Skin Sens. 1 H317 GHS07 H317
Aquatic H412 Wng H412
Chronic 3
612-176-00-1 polymer of 1,3-dibromopropane and N,N- 410-570-6 143747-73-3 Aquatic Acute 1 H400 GHS09 H410
diethyl-N',N'-dimethyl-1,3-propanediamine Aquatic H410 Wng
Chronic 1
612-178-00-2 1,4,7,10-tetraazacyclododecane disulfate 412-080-8 112193-77-8 Acute Tox. 4 * H302 GHS05 H302
STOT SE 3 H335 GHS07 H335
Eye Dam. 1 H318 Dgr H318
Aquatic H412 H412
Chronic 3
31.12.2008
612-179-00-8 1-(2-propenyl)pyridinium chloride 412-740-5 25965-81-5 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 Wng H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Skin Corr. 1B H314 GHS07 H314
Aquatic H411 GHS09 H411
Chronic 2 Dgr
L 353/669
Eye Dam. 1 H315 Dgr H318
Aquatic H318 H411
Chronic 2 H411
L 353/670
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
line) Chronic 2
612-189-00-2 4-amino-2-(aminomethyl)phenol dihy- 412-510-4 135043-64-0 Acute Tox. 4 * H302 GHS07 H302
drochloride Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
612-191-00-3 polymer of allylamine hydrochloride 415-050-2 71550-12-4 Acute Tox. 4 * H302 GHS07 H302
Skin Sens. 1 H317 Wng H317
31.12.2008
methyl-1-propanammonium chloride Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
612-195-00-5 bis[tributyl 4-(methylbenzyl)ammonium] 415-210-1 160236-81-7 Acute Tox. 4 * H332 GHS05 H332
EN
1,5-naphthalenedisulfonate Acute Tox. 4 * H302 GHS07 H302
Eye Dam. 1 H318 GHS09 H318
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
612-196-00-0 4-chloro-o-toluidine; [1] 202-441-6 95-69-2 [1] Carc. 1B H350 GHS06 H350
4-chloro-o-toluidine hydrochloride [2] [1] 3165-93-3 [2] Muta. 2 H341 GHS08 H341
221-627-8 Acute Tox. 3 * H331 GHS09 H331
612-197-00-6 2,4,5-trimethylaniline; [1] 205-282-0 137-17-7 [1] Carc. 1B H350 GHS06 H350
2,4,5-trimethylaniline hydrochloride [2] [1] - [2] 21436-97-5 [2] Acute Tox. 3 * H331 GHS08 H331
Acute Tox. 3 * H311 GHS09 H311
Acute Tox. 3 * H301 Dgr H301
Aquatic H411 H411
Chronic 2
612-198-00-1 4,4'-thiodianiline and its salts 205-370-9 139-65-1 Carc. 1B H350 GHS08 H350
Acute Tox. 4 * H302 GHS07 H302
Aquatic H411 GHS09 H411
Chronic 2 Dgr
612-199-00-7 4,4'-oxydianiline and its salts; 202-977-0 101-80-4 Carc. 1B H350 GHS06 H350
p-aminophenyl ether Muta. 1B H340 GHS08 H340
Repr. 2 H361f GHS09 H361f ***
Acute Tox. 3 * *** Dgr H331
Acute Tox. 3 * H331 H311
H311
L 353/671
Acute Tox. 3 * H301
Aquatic H301 H411
Chronic 2 H411
L 353/672
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-methoxy-m-phenylenediamine; [1] [1] 39156-41-7 [2] Muta. 2 H341 GHS07 H341
2,4-diaminoanisole sulphate [2] 254-323-9 Acute Tox. 4 * H302 GHS09 H302
[2] Aquatic H411 Dgr H411
Chronic 2
612-204-00-2 C.I. Basic Violet 3; 208-953-6 548-62-9 Carc. 2 H351 GHS08 H351
4-[4,4'-bis(dimethylamino) benzhydryli- Acute Tox. 4 * H302 GHS05 H302
dene]cyclohexa-2,5-dien-1-ylidene]dimethy- Eye Dam. 1 H318 GHS07 H318
lammonium chloride Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
612-205-00-8 C.I. Basic Violet 3 with ≥ 0,1 % of Michler's 208-953-6 548-62-9 Carc. 1B H350 GHS08 H350
ketone (EC no. 202-027-5) Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 GHS07 H318
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
31.12.2008
3-anilino-5-methyl-5-(4-phenoxyphenyl)- Aquatic Acute 1 ** GHS09 H410
1,3-oxazolidine-2,4-dione Aquatic H400 Wng
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
p-phenetidine Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
Skin Sens. 1 H317 H317
L 353/673
612-214-00-7 4-(2,2-diphenylethenyl)-N,N-di-phenylben- 421-390-2 89114-90-9 Aquatic H413 — H413
zenamine Chronic 4
L 353/674
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
613-004-00-8 crimidine (ISO); 208-622-6 535-89-7 Acute Tox. 2 * H300 GHS06 H300
2-chloro-6-methylpyrimidin-4-yldimethyla- Dgr
mine
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-007-00-4 desmetryne (ISO); 213-800-1 1014-69-3 Acute Tox. 4 * H312 GHS07 H312
EN
6-isopropylamino-2-methylamino- Acute Tox. 4 * H302 GHS09 H302
4-methylthio-1,3,5-triazine Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
613-008-00-X dazomet (ISO); 208-576-7 533-74-4 Acute Tox. 4 * H302 GHS07 H302
tetrahydro-3,5-dimethyl-1,3,5-thiadiazine- Eye Irrit. 2 H319 GHS09 H319
2-thione Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
613-010-00-0 ametryn (ISO); 212-634-7 834-12-8 Acute Tox. 4 * H302 GHS07 H302
2-ethylamino-4-isopropylamino- Aquatic Acute 1 H400 GHS09 H410
6-methylthio-1,3,5-triazine Aquatic H410 Wng
Chronic 1
613-011-00-6 amitrole (ISO); 200-521-5 61-82-5 Repr. 2 H361d GHS08 H361d ***
1,2,4-triazol-3-ylamine STOT RE 2 * *** GHS09 H373 **
Aquatic H373 Wng H411
Chronic 2 **
H411
613-012-00-1 bentazone (ISO); 246-585-8 25057-89-0 Acute Tox. 4 * H302 GHS07 H302
3-isopropyl-2,1,3-benzothiadiazine-4-one- Eye Irrit. 2 H319 Wng H319
2,2-dioxide Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
613-013-00-7 cyanazine (ISO); 244-544-9 21725-46-2 Acute Tox. 4 * H302 GHS07 H302
L 353/675
2-(4-chloro-6-ethylamino-1,3,5-triazine- Aquatic Acute 1 H400 GHS09 H410
2-ylamino)-2-methylpropionitrile Aquatic H410 Wng
Chronic 1
L 353/676
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
6-ethoxy-1,2-dihydro-2,2,4-trimethylquino- Wng
line
613-015-00-8 fenazaflor (ISO); 238-134-9 14255-88-0 Acute Tox. 4 * H312 GHS07 H312
phenyl 5,6-dichloro-2-trifluoromethyl- Acute Tox. 4 * H302 GHS09 H302
benzimidazole-1-carboxylate Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
613-017-00-9 bis (8-hydroxyquinolinium) sulphate 205-137-1 134-31-6 Acute Tox. 4 * H302 GHS07 H302
Wng
613-020-00-5 tridemorph (ISO); 246-347-3 24602-86-6 Repr. 1B H360- GHS08 H360D ***
2,6-dimethyl-4-tridecylmorpholine Acute Tox. 4 * D *** GHS07 H332
Acute Tox. 4 * H332 GHS09 H302
Skin Irrit. 2 H302 Dgr H315
31.12.2008
Aquatic Acute 1 H315 H410
Aquatic H400
Chronic 1 H410
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-021-00-0 dithianon (ISO); 222-098-6 3347-22-6 Acute Tox. 4 * H302 GHS07 H302
EN
5,10-dihydro-5,10-dioxonaphtho(2,3-b) Aquatic Acute 1 H400 GHS09 H410
(1,4)dithiazine-2,3-dicarbonitrile Aquatic H410 Wng
Chronic 1
613-022-00-6 pyrethrins including cinerins, with the — — Acute Tox. 4 * H332 GHS07 H332 A
exception of those specified elsewhere in Acute Tox. 4 * H312 GHS09 H312
this Annex Acute Tox. 4 * H302 Wng H302
Aquatic Acute 1 H400 H410
Aquatic H410
613-026-00-8 cinerin II; 204-454-2 121-20-0 Acute Tox. 4 * H302 GHS07 H302
L 353/677
3-(but-2-enyl)-2-methyl-4-oxocyclopent-2- Aquatic Acute 1 H400 GHS09 H410
enyl 2,2-dimethyl-3-(3-methoxy-2-methyl- Aquatic H410 Wng
3-oxoprop-1-enyl)cyclopropanecarboxylate Chronic 1
L 353/678
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H331 GHS06 H331
Acute Tox. 3 * H311 GHS05 H311
Skin Corr. 1B H314 Dgr H314
613-029-00-4 dichloro-1,3,5-triazinetrione; 220-487-5 2782-57-2 Ox. Sol. 2 H272 GHS03 H272 EUH031 T
dichloroisocyanuric acid Acute Tox. 4 * H302 GHS07 H302
Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Dgr H335
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
613-030-00-X troclosene potassium; [1] 218-828-8 2244-21-5 [1] Ox. Sol. 2 H272 GHS03 H272 EUH031 *
troclosene sodium [2] [1] 2893-78-9 [2] Acute Tox. 4 * H302 GHS07 H302 STOT SE 3;
220-767-7 Eye Irrit. 2 H319 GHS09 H319 H335: C ≥ 10 %
[2] STOT SE 3 H335 Dgr H335 EUH031:
Aquatic Acute 1 H400 H410 C ≥ 10 %
Aquatic H410
Chronic 1
613-030-01-7 troclosene sodium, dihydrate 220-767-7 51580-86-0 Acute Tox. 4 * H302 GHS07 H302 EUH031
Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Wng H335
31.12.2008
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-031-00-5 symclosene; 201-782-8 87-90-1 Ox. Sol. 2 H272 GHS03 H272 EUH031
EN
trichloroisocyanuric acid; Acute Tox. 4 * H302 GHS07 H302
trichloro-1,3,5-triazinetrion Eye Irrit. 2 H319 GHS09 H319
STOT SE 3 H335 Dgr H335
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
613-033-00-6 2-methylaziridine; 200-878-7 75-55-8 Flam. Liq. 2 H225 GHS02 H225 Carc. 1B; H350:
propyleneimine Carc. 1B H350 GHS06 H350 C ≥ 0,01 %
Acute Tox. 2 * H330 GHS08 H330
Acute Tox. 1 H310 GHS05 H310
Acute Tox. 2 * H300 GHS09 H300
Eye Dam. 1 H318 Dgr H318
Aquatic H411 H411
Chronic 2
L 353/679
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
L 353/680
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-picoline Acute Tox. 3 * H311 GHS06 H311
Acute Tox. 4 * H332 Dgr H332
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
STOT SE 3 H335 H335
Skin Irrit. 2 H315 H315
613-039-00-9 ethylene thiourea; 202-506-9 96-45-7 Repr. 1B H360- GHS08 H360D ***
imidazolidine-2-thione; Acute Tox. 4 * D *** GHS07 H302
2-imidazoline-2-thiol H302 Dgr
613-040-00-4 azaconazole (ISO); 262-102-3 60207-31-0 Acute Tox. 4 * H302 GHS07 H302
1-{[2-(2,4-dichlorophenyl)-1,3-dioxolan- Wng
2-yl]methyl}-1H-1,2.4-triazole
613-041-00-X morpholine-4-carbonyl chloride 239-213-0 15159-40-7 Carc. 2 H351 GHS08 H351 EUH014
Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
613-042-00-5 imazalil (ISO); 252-615-0 35554-44-0 Acute Tox. 4 * H332 GHS05 H332
1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]- Acute Tox. 4 * H302 GHS07 H302
1H-imidazole Eye Dam. 1 H318 GHS09 H318
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
613-043-00-0 imazalil sulphate (ISO) powder; 261-351-5 58594-72-2 [1] Acute Tox. 4 * H302 GHS07 H302
1- [2-(allyloxy)ethyl-2-(2,4-dichlorophe- [1] 83918-57-4 [2] Skin Sens. 1 H317 GHS09 H317
nyl)]-1H-imidazolium hydrogen sulphate; 281-291-3
31.12.2008
Aquatic Acute 1 H400 Wng H410
[1] [2] Aquatic H410
(±)-1- [2-(allyloxy)ethyl-2-(2,4-dichlorophe- Chronic 1
nyl)]-1H-imidazolium hydrogen sulphate [2]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-043-01-8 imazalil sulphate (ISO), aqueous solution; 261-351-5 58594-72-2 [1] Acute Tox. 4 * H302 GHS05 H302 Skin Corr. 1B;
EN
1- [2-(allyloxy)ethyl-2-(2,4-dichlorophe- [1] 83918-57-4 [2] Skin Corr. 1B H314 GHS07 H314 H314: C ≥ 50 %
nyl)]-1H-imidazolium hydrogen sulphate; 281-291-3 Skin Sens. 1 H317 GHS09 H317 Skin Irrit. 2;
[1] [2] Aquatic Acute 1 H400 Wng H410 H315: 30 % ≤ C
(±)-1- [2-(allyloxy)ethyl-2-(2,4-dichlorophe- < 50 %
Aquatic H410
nyl)]-1H-imidazolium hydrogen sulphate [2] Chronic 1 Eye Dam. 1;
H318: 15 % ≤ C
< 50 %
Eye Irrit. 2; H319:
5 % ≤ C < 15 %
L 353/681
Aquatic H410
Chronic 1
L 353/682
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methyl benzimidazol-2-ylcarbamate Repr. 1B H360- GHS09 H360FD
Aquatic Acute 1 FD Dgr H410
Aquatic H400
Chronic 1 H410
613-050-00-9 carbadox (INN); 229-879-0 6804-07-5 Flam. Sol. 1 H228 GHS02 H228 T
methyl 3-(quinoxalin-2-ylmethylene)carba- Carc. 1B H350 GHS08 H350
zate 1,4-dioxide; Acute Tox. 4 * H302 GHS07 H302
2-(methoxycarbonylhydrazonomethyl)qui- Dgr
noxaline 1,4-dioxide
613-051-00-4 molinate (ISO); 218-661-0 2212-67-1 Carc. 2 H351 GHS08 H351 M = 100
S-ethyl 1-perhydroazepinecarbothioate; Repr. 2 H361f GHS07 H361f ***
S-ethyl perhydroazepine-1-carbothioate Acute Tox. 4 * *** GHS09 H332
Acute Tox. 4 * H332 Wng H302
STOT RE 2 * H302 H373 **
Skin Sens. 1 H373 H317
Aquatic Acute 1 ** H410
Aquatic H317
Chronic 1 H400
H410
613-052-00-X trifenmorph (ISO); 215-812-2 1420-06-0 Acute Tox. 4 * H302 GHS07 H302
31.12.2008
4-tritylmorpholine Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-053-00-5 anilazine (ISO); 202-910-5 101-05-3 Eye Irrit. 2 H319 GHS07 H319
EN
2-chloro-N-(4,6-dichloro-1,3,5-triazin-2-yl) Skin Irrit. 2 H315 GHS09 H315
aniline Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
613-054-00-0 thiabendazol (ISO); 205-725-8 148-79-8 Aquatic Acute 1 H400 GHS09 H410
2-(thiazole-4-yl)benzimidazole Aquatic H410 Wng
Chronic 1
613-057-00-7 dodemorph (ISO); 216-474-9 1593-77-7 Eye Irrit. 2 H319 GHS07 H319
4-cyclododecyl-2,6-dimethylmorpholine STOT SE 3 H335 GHS09 H335
Skin Irrit. 2 H315 Wng H315
Aquatic H411 H411
Chronic 2
613-058-00-2 permethrin (ISO); 258-067-9 52645-53-1 Acute Tox. 4 * H332 GHS07 H332 M = 1 000
m-phenoxybenzyl 3-(2,2-dichlorovinyl)- Acute Tox. 4 * H302 GHS09 H302
2,2-dimethylcyclopropanecarboxylate Skin Sens. 1 H317 Wng H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
613-059-00-8 profluralin (ISO); 247-656-6 26399-36-0 Eye Irrit. 2 H319 GHS07 H319
N-(cyclopropylmethyl)-α,α,α-trifluoro- Aquatic Acute 1 H400 GHS09 H410
2,6-dinitro-N-propyl-p-toluidine Aquatic H410 Wng
Chronic 1
613-060-00-3 resmethrin (ISO); 233-940-7 10453-86-8 Acute Tox. 4 * H302 GHS07 H302
L 353/683
5-benzyl-3-furylmethyl (±)-cis-trans-chry- Aquatic Acute 1 H400 GHS09 H410
santhemate Aquatic H410 Wng
Chronic 1
L 353/684
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2β,5β,8β-trimethylperhydro-8bα,9-epoxy- Acute Tox. 4 * H302 GHS09 H302
5,8-ethanocyclopenta[1,2-b]indenyl) pyr- Aquatic Acute 1 H400 Wng H410
role-2-carboxylate;
Aquatic H410
ryania Chronic 1
613-065-00-0 simetryn (ISO); 213-801-7 1014-70-6 Acute Tox. 4 * H302 GHS07 H302
2,4-bis(ethylamino)-6-methylthio-1,3,5-tria- Aquatic Acute 1 H400 GHS09 H410
zine Aquatic H410 Wng
Chronic 1
613-066-00-6 terbumeton (ISO); 251-637-8 33693-04-8 Acute Tox. 4 * H302 GHS07 H302
2-tert-butylamino-4-ethylamino-6-methoxy- Aquatic Acute 1 H400 GHS09 H410
1,3,5-triazine Aquatic H410 Wng
Chronic 1
31.12.2008
2-chloro-4,6-bis(isopropylamino)-1,3,5-tria- Aquatic Acute 1 H400 GHS09 H410
zine Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2-chloro-4-ethylamine-6-isopropylamine- Skin Sens. 1 ** GHS09 H317
1,3,5-triazine Aquatic Acute 1 H317 Wng H410
Aquatic H400
Chronic 1 H410
L 353/685
Eye Dam. 1 H318 Dgr H318
Aquatic H412 H412
Chronic 3
L 353/686
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-075-00-5 1,3-dichloro-5-ethyl-5-methylimidazolidine- 401-570-7 89415-87-2 Ox. Sol. 1 **** H271 GHS03 H271
EN
2,4-dione Acute Tox. 3 * H331 GHS06 H331
Skin Corr. 1B H314 GHS05 H314
Acute Tox. 4 * H302 GHS09 H302
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H400
31.12.2008
613-081-00-8 1-butyl-2-methylpyridinium bromide 402-680-8 26576-84-1 Acute Tox. 4 * H302 GHS07 H302
Aquatic H412 Wng H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 Wng H302
Aquatic H412 H412
Chronic 3
613-085-00-X reaction mass of 1,1'-(methylenebis(4,1- 401-970-1 — Skin Sens. 1 H317 GHS07 H317
phenylene))dipyrrole-2,5-dione and N-(4-(4- Aquatic Acute 1 H400 GHS09 H410
(2,5-dioxopyrrol-1-yl)benzyl)phenyl)aceta- Aquatic H410 Wng
mide and 1-(4-(4-(5-oxo-2H-2-furylidena- Chronic 1
mino)benzyl)phenyl)pyrrole-2,5-dione
L 353/687
Aquatic H412 H412
Chronic 3
L 353/688
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-088-00-6 1,2-benzisothiazol-3(2H)-one; 220-120-9 2634-33-5 Acute Tox. 4 * H302 GHS05 H302 Skin Sens. 1;
EN
1,2-benzisothiazolin-3-one Skin Irrit. 2 H315 GHS07 H315 H317: C ≥ 0,05 %
Eye Dam. 1 H318 GHS09 H318
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H400
613-089-00-1 diquat dibromide; [1] 201-579-4 85-00-7 [1] Acute Tox. 2 * H330 GHS06 H330
diquat dichloride; [2] [1] 4032-26-2 [2] STOT RE 1 H372 GHS08 H372 **
613-090-00-7 paraquat dichloride; 217-615-7 1910-42-5 [1] Acute Tox. 2 * H330 GHS06 H330
1,1-dimethyl-4,4'-bipyridinium dichloride; [1] 2074-50-2 [2] Acute Tox. 3 * H311 GHS08 H311
[1] 218-196-3 Acute Tox. 3 * H301 GHS09 H301
paraquat dimethylsulfate; [2] STOT RE 1 H372 Dgr H372 **
1,1-dimethyl-4,4'-bipyridinium dimethyl Eye Irrit. 2 ** H319
sulphate [2] STOT SE 3 H319 H335
Skin Irrit. 2 H335 H315
Aquatic Acute 1 H315 H410
Aquatic H400
Chronic 1 H410
613-091-00-2 morfamquat dichloride; [1] 225-062-8 4636-83-3 [1] Acute Tox. 4 * H302 GHS07 H302
morfamquat sulfate [2] [1] 29873-36-7 [2] Eye Irrit. 2 H319 Wng H319
[2] STOT SE 3 H335 H335
31.12.2008
Skin Irrit. 2 H315 H315
Aquatic H412 H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
613-093-00-3 hexasodium 6,13-dichloro-3,10-bis((4-(2,5- 400-050-7 85153-92-0 Resp. Sens. 1 H334 GHS08 H334
disulfonatoanilino)-6-fluoro-1,3,5-triazin- Skin Sens. 1 H317 Dgr H317
2-ylamino)prop-3-ylamino)-5,12-dioxa-
7,14-diazapentacene-4,11-disulfonate
613-095-00-4 sodium 3-(2H-benzotriazol-2-yl)-5-sec- 403-080-9 92484-48-5 Eye Dam. 1 H318 GHS05 H318
butyl-4-hydroxybenzenesulfonate Dgr
L 353/689
613-100-00-X 2,9-bis(3-(diethylamino)propylsulfamoyl) 404-230-6 — Skin Sens. 1 H317 GHS07 H317
quino(2,3-b)acridine-7,14-dione Aquatic H413 Wng H413
Chronic 4
L 353/690
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H412 Wng H412
Chronic 3
613-103-00-6 sodium 5-n-butylbenzotriazole 404-450-2 118685-34-0 Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 GHS09 H317
613-105-00-7 hexakis(tetramethylammonium) 4,4'-vinyle- 405-160-9 124537-30-0 Acute Tox. 3 * H301 GHS06 H301
nebis((3-sulfonato-4,1-phenylene)imino Skin Sens. 1 H317 Dgr H317
(6-morpholino-1,3,5-triazine-4,2-diyl) Aquatic H412 H412
imino)bis(5-hydroxy-6-phenylazonaphtha- Chronic 3
lene-2,7-disulfonate)
613-107-00-8 hexasodium 2,2'-vinylenebis((3-sulfonato- 405-280-1 76508-02-6 Eye Irrit. 2 H319 GHS07 H319
4,1-phenylene)imino(6-(N-cyanoethyl-N- Wng
(2-hydroxypropyl)amino)-1,3,5-triazine-4,2-
diyl)imino)dibenzene-1,4-disulfonate
31.12.2008
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-109-00-9 bis(piperidinothiocarbonyl) disulphide 202-328-1 94-37-1 Eye Irrit. 2 H319 GHS07 H319
EN
STOT SE 3 H335 Wng H335
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
613-110-00-4 dimepiperate (ISO); 262-784-2 61432-55-1 Acute Tox. 4 * H302 GHS07 H302
S-(1-methyl-1-phenylethyl) piperidine-1-car- Aquatic H411 GHS09 H411
bothioate Chronic 2 Wng
613-112-00-5 octhilinone (ISO); 247-761-7 26530-20-1 Acute Tox. 3 * H331 GHS06 H331 Skin Sens. 1;
2-octyl-2H-isothiazol-3-one Acute Tox. 3 * H311 GHS05 H311 H317: C ≥ 0,05 %
Acute Tox. 4 * H302 GHS09 H302
Skin Corr. 1B H314 Dgr H314
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
613-114-00-6 2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl) 225-208-0 4719-04-4 Acute Tox. 4 * H302 GHS07 H302 Skin Sens. 1;
triethanol; Skin Sens. 1 H317 Wng H317 H317: C ≥ 0,1 %
1,3,5-tris(2-hydroxyethyl)hexahydro-
1,3,5-triazine
613-115-00-1 hymexazol (ISO); 233-000-6 10004-44-1 Acute Tox. 4 * H302 GHS05 H302
L 353/691
3-hydroxy-5-methylisoxazole Eye Dam. 1 H318 GHS07 H318
Aquatic H412 Dgr H412
Chronic 3
L 353/692
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-116-00-7 tolylfluanid (ISO); 211-986-9 731-27-1 Acute Tox. 3 * H331 GHS06 H331
EN
dichloro-N-[(dimethylamino)sulphonyl] STOT RE 2 * H373 GHS08 H373 **
fluoro-N-(p-tolyl)methanesulphenamide Eye Irrit. 2 ** GHS09 H319
STOT SE 3 H319 Dgr H335
Skin Irrit. 2 H335 H315
Skin Sens. 1 H315 H317
Aquatic Acute 1 H317 H410
Aquatic H400
Chronic 1 H410
613-118-00-8 flubenzimine (ISO); 253-703-1 37893-02-0 Eye Irrit. 2 H319 GHS07 H319
N-[3-phenyl-4,5-bis[(trifluoromethyl)imino] Aquatic Acute 1 H400 GHS09 H410
thiazolidin-2-ylidene]aniline Aquatic H410 Wng
Chronic 1
613-119-00-3 (benzothiazol-2-ylthio)methyl thiocyanate; 244-445-0 21564-17-0 Acute Tox. 2 * H330 GHS06 H330
TCMTB Acute Tox. 4 * H302 GHS09 H302
Eye Irrit. 2 H319 Dgr H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
31.12.2008
(5-bezylfur-3-yl)methyl(1R)-trans- Aquatic H410 Wng
2,2-dimethyl-3-(2-methylpropenyl)cyclopro- Chronic 1
panecarboylate
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-121-00-4 chlorsulfuron (ISO); 265-268-5 64902-72-3 Aquatic Acute 1 H400 GHS09 H410
EN
2-chloro-N-[[(4-methoxy-6-methyl-1,3,5- Aquatic H410 Wng
triazin-2-yl)amino]carbonyl]benzenesulpho- Chronic 1
namide
613-124-00-0 fenpropimorph (ISO); 266-719-9 67564-91-4 Repr. 2 H361d GHS08 H361d ***
cis-4-[3-(p-tert-butylphenyl)-2-methylpro- Acute Tox. 4 * *** GHS07 H302
pyl]-2,6-dimethylmorpholine Skin Irrit. 2 H302 GHS09 H315
Aquatic H315 Wng H411
Chronic 2 H411
L 353/693
613-127-00-7 1,1-dimethylpiperidinium chloride; 246-147-6 24307-26-4 Acute Tox. 4 * H302 GHS07 H302
mepiquat chloride Aquatic H412 Wng H412
Chronic 3
L 353/694
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-128-00-2 prochloraz (ISO); 266-994-5 67747-09-5 Acute Tox. 4 * H302 GHS07 H302
EN
N-propyl-N-[2-(2,4,6-trichlorophenoxy) Aquatic Acute 1 H400 GHS09 H410
ethyl]-1H-imidazole-1-carboxamide Aquatic H410 Wng
Chronic 1
613-129-00-8 metamitron (ISO); 255-349-3 41394-05-2 Acute Tox. 4 * H302 GHS07 H302
4-amino-3-methyl-6-phenyl-1,2,4-triazin- Aquatic Acute 1 H400 GHS09 H400
5-one Wng
613-132-00-4 hexazinone (ISO); 257-074-4 51235-04-2 Acute Tox. 4 * H302 GHS07 H302
3-cyclohexyl-6-dimethylamino-1-methyl- Eye Irrit. 2 H319 GHS09 H319
1,2,3,4-tetrahydro-1,3,5-triazine-2,4-dione Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
613-135-00-0 di(benzothiazol-2-yl) disulphide 204-424-9 120-78-5 Skin Sens. 1 H317 GHS07 H317 EUH031
31.12.2008
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
613-137-00-1 methabenzthiazuron (ISO); 242-505-0 18691-97-9 Aquatic Acute 1 H400 GHS09 H410
1-(1,3-benzothiazol-2-yl)1,3-dimethylurea Aquatic H410 Wng
Chronic 1
L 353/695
613-144-00-X reaction products of: poly(vinyl acetate), 406-460-2 125139-08-4 Aquatic H412 — H412
partially hydrolyzed, with (E)-2-(4-formyl- Chronic 3
styryl)-3,4-dimethylthiazoliummethyl sulfate
L 353/696
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
613-146-00-0 N-ethyl-N-methylpiperidinium iodide 407-780-5 4186-71-4 Acute Tox. 4 * H302 GHS07 H302
Aquatic H411 GHS09 H411
Chronic 2 Wng
613-149-00-7 pyridaben (ISO); 405-700-3 96489-71-3 Acute Tox. 3 * H331 GHS06 H331
2-tert-butyl-5-(4-tert-butylbenzylthio)- Acute Tox. 3 * H301 GHS09 H301
4-chloropyridazin-3(2H)-one Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
613-152-00-3 phenyl N-(4,6-dimethoxypyrimidin-2-yl)car- 406-600-2 89392-03-0 Skin Sens. 1 H317 GHS07 H317
bamate Aquatic H411 GHS09 H411
Chronic 2 Wng
31.12.2008
613-154-00-4 2-amino-4-chloro-6-methoxypyrimidine 410-050-9 5734-64-5 Acute Tox. 4 * H302 GHS07 H302
Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H302 GHS07 H302
Aquatic H412 Wng H412
Chronic 3
613-159-00-1 fenazaquin (ISO); 410-580-0 120928-09-8 Acute Tox. 3 * H301 GHS06 H301
4-[2-[4-(1,1-dimethylethyl)phenyl]-ethoxy] Acute Tox. 4 * H332 GHS09 H332
quinazoline Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/697
1-(4,6-dimethoxypyrimidin-2-yl)-3-[1- Aquatic H410 Wng
methyl-4-(2-methyl-2H-tetrazol-5-yl)pyra- Chronic 1
zol-5-ylsulfonyl]urea
L 353/698
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
N-(4-fluorophenyl)-N-isopropyl-2-(5-tri- STOT RE 2 * H373 GHS07 H373 **
fluoromethyl-[1,3,4]thiadiazol-2-yloxy)acet- Skin Sens. 1 ** GHS09 H317
amide Aquatic Acute 1 H317 Wng H410
Aquatic H400
Chronic 1 H410
613-167-00-5 reaction mass of: 5-chloro-2-methyl-4-iso- — 55965-84-9 Acute Tox. 3 * H331 GHS06 H331 Skin Corr. 1B;
thiazolin-3-one [EC no. 247-500-7] Acute Tox. 3 * H311 GHS05 H311 H314: C ≥ 0,6 %
and 2-methyl-2H -isothiazol-3-one [EC Acute Tox. 3 * H301 GHS09 H301 Skin Irrit. 2;
no. 220-239-6] (3:1); Skin Corr. 1B H314 Dgr H314 H315: 0,06 %
reaction mass of: 5-chloro-2-methyl-4-iso- ≤ C < 0,6 %
Skin Sens. 1 H317 H317
thiazolin-3-one [EC no. 247-500-7] Eye Irrit. 2; H319:
Aquatic Acute 1 H400 H410 0,06 % ≤
and 2-methyl-4-isothiazolin-3-one [EC
no. 220-239-6] (3:1) Aquatic H410 C < 0,6 %
Chronic 1 Skin Sens. 1;
H317:
C ≥ 0,0015 %
31.12.2008
STOT SE 3 ** H335
Eye Dam. 1 H335 H318
H318
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 GHS09 H302
Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
613-171-00-7 hexaconazole (ISO); 413-050-7 79983-71-4 Acute Tox. 4 * H302 GHS07 H302
(RS)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4- Skin Sens. 1 H317 GHS09 H317
triazol-1-yl)hexan-2-ol Aquatic H411 Wng H411
Chronic 2
613-173-00-8 fluquinconazole (ISO); 411-960-9 136426-54-5 Acute Tox. 3 * H331 GHS06 H331
3-(2,4-dichlorophenyl)-6-fluoro-2-(1H- Acute Tox. 3 * H301 GHS08 H301
1,2,4-triazol-1-yl)quinazolin-4-(3H)-one STOT RE 1 H372 GHS09 H372 **
Acute Tox. 4 * ** Dgr H312
Skin Irrit. 2 H312 H315
Aquatic Acute 1 H315 H410
L 353/699
Aquatic H400
Chronic 1 H410
L 353/700
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
zol-1-yl)propyl-1,1,2,2-tetrafluoroethylether Acute Tox. 4 * H332 GHS07 H332
Acute Tox. 4 * H302 GHS09 H302
Aquatic H411 Wng H411
Chronic 2
613-178-00-5 4-ethyl-2-methyl-2-isopentyl-1,3-oxazoli- 410-470-2 137796-06-6 Skin Corr. 1B H314 GHS05 H314 STOT SE 3;
dine Skin Sens. 1 H317 GHS07 H317 H335: C ≥ 5 %
Dgr
613-179-00-0 lithium 3-oxo-1,2(2H)-benzisothiazol-2-ide 411-690-1 111337-53-2 Acute Tox. 4 * H302 GHS05 H302
Skin Corr. 1B H314 GHS07 H314
Skin Sens. 1 H317 Dgr H317
Aquatic H411 H411
Chronic 2
31.12.2008
613-180-00-6 N-(1,1-dimethylethyl)bis(2-benzothiazole- 407-430-1 3741-80-8 Aquatic Acute 1 H400 GHS09 H410
sulfen)amide Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
α-(4-trifluoromethylstyryl)-α-(4-trifluoro- Acute Tox. 4 * ** GHS07 H302
methyl)cinnamylidenehydrazone Eye Irrit. 2 H302 GHS09 H319
Aquatic Acute 1 H319 Dgr H410
Aquatic H400
Chronic 1 H410
613-183-00-2 reaction mass of: 5-(N-methylperfluorooc- 413-640-4 — STOT RE 2 * H373 GHS08 H373 **
tylsulfonamido)methyl-3-octadecyl-1,3-oxa- Aquatic Acute 1 ** GHS09 H410
zolidin-2-one; Aquatic H400 Wng
5-(N-methylperfluoroheptylsulfonamido) Chronic 1 H410
methyl-3-octadecyl-1,3-oxazolidin-2-one
L 353/701
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Wng H411
Chronic 2
L 353/702
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
4-piperidinone Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
31.12.2008
613-195-00-8 2,2-(1,4-phenylene)bis((4H—3,1-benzoxa- 418-280-1 18600-59-4 Skin Sens. 1 H317 GHS07 H317
zine-4-one) Aquatic H413 Wng H413
Chronic 4
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
6-[(4-methoxy-2-sulfophenyl)azo]-7-sulfo- Dgr
2-naphthalenyl]amino]-1,3,5-triazin-2-yl]
amino]-1-methylethyl]amino]-1,3,5-triazin-
2-yl]amino]-3-[[4-(ethenylsulfonyl)phenyl]
azo]-4-hydroxy-naphtalene-2,7-disulfonic
acid, sodium salt
613-197-00-9 reaction mass of: 2,4,6-tri(butylcarbamoyl)- 420-390-1 187547-46-2 Skin Sens. 1 H317 GHS07 H317
1,3,5-triazine; Aquatic H411 GHS09 H411
2,4,6-tri(methylcarbamoyl)-1,3,5-triazine; Chronic 2 Wng
613-199-00-X reaction mass of: 1,3,5-tris(3-aminomethyl- 421-550-1 — Carc. 1B H350 GHS08 H350
phenyl)-1,3,5-(1H,3H,5H)-triazine- Repr. 1B H360- Dgr H360D ***
2,4,6-trione; Skin Sens. 1 D *** H317
reaction mass of oligomers of 3,5-bis Aquatic H317 H412
(3-aminomethylphenyl)-1-poly[3,5-bis(3- Chronic 3 H412
aminomethylphenyl)-2,4,6-trioxo-1,3,5-
(1H,3H,5H)-triazin-1-yl]-1,3,5-(1H,3H,5H)-
triazine-2,4,6-trione
613-200-00-3 Reaction product of: copper, (29H,31H- 420-980-7 — Eye Dam. 1 H318 GHS05 H318
phthalocyaninato(2-)-N29,N30,N31,N32)-, Dgr
chlorosulfuric acid and 3-(2-sulfooxyethyl-
sulfonyl)aniline, sodium salts
613-201-00-9 (R)-5-bromo-3-(1-methyl-2-pyrrolidinyl 422-390-5 143322-57-0 Repr. 2 H361f GHS08 H361f *** EUH070
methyl)-1H-indole STOT RE 1 *** GHS07 H372 **
Acute Tox. 4 * H372 GHS09 H332
Acute Tox. 4 * ** Dgr H302
Skin Sens. 1 H332 H317
Aquatic Acute 1 H302 H410
H317
L 353/703
Aquatic
Chronic 1 H400
H410
L 353/704
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
(E)-4,5-dihydro-6-methyl-4-(3-pyridyl- Aquatic H412 Wng H412
methyleneamino)-1,2,4-triazin-3(2H)-one Chronic 3
613-203-00-X pyraflufen-ethyl; [1] -[1] 129630-19-9 Aquatic Acute 1 H400 GHS09 H410
pyraflufen [2] -[2] [1] Aquatic H410 Wng
129630-17-7 Chronic 1
[2]
613-204-00-5 oxadiargyl (ISO); 254-637-6 39807-15-3 Repr. 2 H361d GHS08 H361d ***
3-[2,4-dichloro-5-(2-propynyloxy)phenyl]- STOT RE 2 * *** GHS09 H373 **
31.12.2008
613-210-00-8 2-(3-chloropropyl)-2,5,5-trimethyl-1,3-diox- 417-650-1 88128-57-8 STOT RE 2 * H373 GHS08 H373 **
ane Aquatic ** Wng H412
Chronic 3 H412
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H412 Wng H412
Chronic 3
L 353/705
Skin Sens. 1 H317 GHS09 H317
Aquatic H411 Dgr H411
Chronic 2
L 353/706
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
azole Chronic 2 Wng
31.12.2008
amino)-2-methylphenylazo)benzoylamino)- Aquatic Acute 1 H400 GHS09 H410
phenylazo)-3-methylphenyl)amino)ethyl)- Aquatic H410 Dgr
pyridinium dichloride Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
613-227-00-0 (±)-[(R*,R*) and (R*,S*)]-6-fluoro-3,4-dihy- 419-600-2 99199-90-3 Skin Sens. 1 H317 GHS07 H317
EN
dro-2-oxiranyl-2H-1-benzopyran Aquatic H411 GHS09 H411
Chronic 2 Wng
614-001-00-4 nicotine (ISO); 200-193-3 54-11-5 Acute Tox. 1 H310 GHS06 H310
3-(N-methyl-2-pyrrolidinyl)pyridine Acute Tox. 3 * H301 GHS09 H301
Aquatic H411 Dgr H411
Chronic 2
L 353/707
Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/708
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 2 * H300 Dgr H300
614-007-00-7 brucine sulphate; [1] 225-432-9 4845-99-2 [1] Acute Tox. 2 * H330 GHS06 H330 A
brucine nitrate; [2] [1] 5786-97-0 [2] Acute Tox. 2 * H300 Dgr H300
227-317-9
31.12.2008
614-014-00-5 hyoscine 200-090-3 51-34-3 Acute Tox. 2 * H330 GHS06 H330
Acute Tox. 1 H310 Dgr H310
Acute Tox. 2 * H300 H300
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 1 H310 Dgr H310
Acute Tox. 2 * H300 H300
L 353/709
Acute Tox. 3 * H301 GHS08 H301
STOT RE 2 * H373 Dgr H373 **
**
L 353/710
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Acute Tox. 3 * H301 GHS08 H301
STOT RE 2 * H373 Dgr H373 **
**
614-027-00-6 bufa-4,20,22-trienolide, 6-(acetyloxy)-3-(β- 208-077-4 507-60-8 Acute Tox. 2 * H300 GHS06 H300
D-glucopyranosyloxy)-8,14-dihydroxy-, (3β, Dgr
6β)-;
red squill;
614-028-00-1 reaction mass of: 2-ethylhexyl mono-D- 414-420-0 — Eye Dam. 1 H318 GHS05 H318
glucopyranoside; Dgr
2-ethylhexyl di-D-glucopyranoside
614-029-00-7 constitutional isomers of penta-O-allyl-β-D- 419-640-0 68784-14-5 Acute Tox. 4 * H302 GHS07 H302
fructofuranosyl-α-D-glucopyranoside; Wng
constitutional isomers of hexa-O-allyl-β-D-
fructofuranosyl-α-D-glucopyranoside;
constitutional isomers of hepta-O-allyl-β-D-
fructofuransoyl-α-D-glucopyranoside
615-001-00-7 methyl isocyanate 210-866-3 624-83-9 Flam. Liq. 2 H225 GHS02 H225
Repr. 2 H361d GHS06 H361d ***
Acute Tox. 2 * *** GHS06 H330
Acute Tox. 3 * H330 GHS08 H311
Acute Tox. 3 * H311 GHS05 H301
STOT SE 3 H301 Dgr H335
Skin Irrit. 2 H335 H315
Eye Dam. 1 H315 H318
H318
31.12.2008
Resp. Sens. 1 H334
Skin Sens. 1 H334 H317
H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-002-00-2 methyl isothiocyanate 209-132-5 556-61-6 Acute Tox. 3 * H331 GHS06 H331
EN
Acute Tox. 3 * H301 GHS05 H301
Skin Corr. 1B H314 GHS09 H314
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
615-003-00-8 thiocyanic acid 207-337-4 463-56-9 Acute Tox. 4 * H332 GHS07 H332 EUH032
Acute Tox. 4 * H312 Wng H312
615-004-00-3 salts of thiocyanic acid — — Acute Tox. 4 * H332 GHS07 H332 EUH032 A
Acute Tox. 4 * H312 Wng H312
Acute Tox. 4 * H302 H302
Aquatic H412 H412
Chronic 3
615-005-00-9 4,4'-methylenediphenyl diisocyanate; 202-966-0 101-68-8 [1] Acute Tox. 4 * H332 GHS08 H332 Eye Irrit.; H319: C
diphenylmethane-4,4'-diisocyanate; [1] [1] 2536-05-2 [2] Eye Irrit. 2 H319 GHS07 H319 C ≥ 5% 2
2,2'-methylenediphenyl diisocyanate; 219-799-4 5873-54-1 [3] STOT SE 3 H335 Dgr H335 STOT SE 3;
diphenylmethane-2,2'-diisocyanate; [2] [2] 26447-40-5 [4] Skin Irrit. 2 H315 H315 H335: C ≥ 5 %
o-(p-isocyanatobenzyl)phenyl isocyanate; 227-534-9 Resp. Sens. 1 H334 H334 Skin Irrit. 2;
[3] H315: C ≥ 5 %
diphenylmethane-2,4'-diisocyanate; [3] Skin Sens. 1 H317 H317
247-714-0 Resp. Sens. 1;
methylenediphenyl diisocyanate [4] [4] H334: C ≥ 0,1 %
615-006-00-4 2-methyl-m-phenylene diisocyanate; 202-039-0 91-08-7 [1] Carc. 2 H351 GHS06 H351 Resp. Sens. 1; C
toluene-2,4-di-isocyanate; [1] [1] 584-84-9 [2] Acute Tox. 2 * H330 GHS08 H330 H334: C ≥ 0,1 %
4-methyl-m-phenylene diisocyanate; 209-544-5 26471-62-5 [3] Eye Irrit. 2 H319 Dgr H319
toluene-2,6-di-isocyanate; [2] [2] STOT SE 3 H335 H335
m-tolylidene diisocyanate; 247-722-4 Skin Irrit. 2 H315 H315
[3]
toluene-diisocyanate [3] Resp. Sens. 1 H334 H334
L 353/711
Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
L 353/712
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-007-00-X 1,5-naphthylene diisocyanate 221-641-4 3173-72-6 Acute Tox. 4 * H332 GHS08 H332
EN
Eye Irrit. 2 H319 GHS07 H319
STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Resp. Sens. 1 H334 H334
Aquatic H412 H412
Chronic 3
615-009-00-0 4,4'-methylenedi(cyclohexyl isocyanate); 225-863-2 5124-30-1 Acute Tox. 3 * H331 GHS06 H331 * 2
dicyclohexylmethane-4,4'-di-isocyanate Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1;
STOT SE 3 H335 Dgr H335 H334: C ≥ 0,5 %
Skin Irrit. 2 H315 H315 Skin Sens. 1;
Resp. Sens. 1 H334 H334 H317: C ≥ 0,5 %
Skin Sens. 1 H317 H317
615-010-00-6 2,2,4-trimethylhexamethylene-1,6-di-isocya- 241-001-8 16938-22-0 [1] Acute Tox. 3 * H331 GHS06 H331 * C
nate; [1] [1] 15646-96-5 [2] Eye Irrit. 2 H319 GHS08 H319 Resp. Sens. 1; 2
2,4,4-trimethylhexamethylene-1,6-di-isocya- 239-714-4 STOT SE 3 H335 Dgr H335 H334: C ≥ 0,5 %
nate [2] [2] Skin Irrit. 2 H315 H315 Skin Sens. 1;
Resp. Sens. 1 H334 H334 H317: C ≥ 0,5 %
31.12.2008
Skin Irrit. 2 H315 H315 Skin Sens. 1;
Resp. Sens. 1 H334 H334 H317: C ≥ 0,5 %
Skin Sens. 1 H317 H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-012-00-7 4-isocyanatosulphonyltoluene; 223-810-8 4083-64-1 Eye Irrit. 2 H319 GHS08 H319 EUH014 Eye Irrit.; H319:
EN
tosyl isocyanate STOT SE 3 H335 GHS07 H335 C ≥ 5%
Skin Irrit. 2 H315 Dgr H315 STOT SE 3;
Resp. Sens. 1 H334 H334 H335: C ≥ 5 %
Skin Irrit. 2;
H315: C ≥ 5 %
615-015-00-3 1,7,7-trimethylbicyclo(2,2,1)hept-2-yl thio- 204-081-5 115-31-1 Acute Tox. 4 * H302 GHS07 H302
cyanatoacetate; Aquatic Acute 1 H400 GHS09 H410
isobornyl thiocyanoacetate Aquatic H410 Wng
Chronic 1
615-016-00-9 potassium cyanate 209-676-3 590-28-3 Acute Tox. 4 * H302 GHS07 H302
Wng
615-017-00-4 calcium cyanamide 205-861-8 156-62-7 Acute Tox. 4 * H302 GHS05 H302
STOT SE 3 H335 GHS07 H335
Eye Dam. 1 H318 Dgr H318
615-018-00-X 2-(2-butoxyethoxy)ethyl thiocyanate 203-985-7 112-56-1 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 3 * H311 GHS06 H311
Acute Tox. 3 * H301 Dgr H301
L 353/713
Acute Tox. 4 * H302 GHS05 H302
Eye Dam. 1 H318 Dgr H318
Skin Sens. 1 H317 H317
L 353/714
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-020-00-0 methylene dithiocyanate 228-652-3 6317-18-6 Acute Tox. 2 * H330 GHS06 H330
EN
Acute Tox. 3 * H301 GHS05 H301
Skin Corr. 1B H314 GHS09 H314
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H400
615-023-00-7 2-(isocyanatosulfonylmethyl)benzoic acid 410-900-9 83056-32-0 Flam. Liq. 3 H226 GHS02 H226 EUH014
methyl ester; Muta. 2 H341 GHS08 H341
(alt.):methyl 2-(isocyanatosulfonylmethyl) Acute Tox. 4 * H332 GHS05 H332
benzoate STOT RE 2 * H373 GHS07 H373 **
Eye Dam. 1 ** Dgr H318
Resp. Sens. 1 H318 H334
H334
31.12.2008
Skin Sens. 1 H317 Dgr H317
Aquatic H411 H411
Chronic 2
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-025-00-8 4,4'-ethylidenediphenyl dicyanate 405-740-1 47073-92-7 Acute Tox. 4 * H332 GHS08 H332
EN
Acute Tox. 4 * H302 GHS05 H302
STOT RE 2 * H373 GHS07 H373 **
Eye Dam. 1 ** GHS09 H318
Aquatic Acute 1 H318 Dgr H410
Aquatic H400
Chronic 1 H410
615-026-00-3 4,4'-methylenebis(2,6-dimethylphenyl cya- 405-790-4 101657-77-6 Skin Sens. 1 H317 GHS07 H317
nate) Aquatic H412 Wng H412
Chronic 3
615-030-00-5 alkali salts, alkali earth salts and other salts — — Acute Tox. 4 * H332 GHS07 H332 EUH032 A
of thiocyanic acid not mentioned elsewhere Acute Tox. 4 * H312 Wng H312
in this Annex Acute Tox. 4 * H302 H302
Aquatic H412 H412
Chronic 3
615-031-00-0 thallium salt of thiocyanic acid 222-571-7 3535-84-0 Acute Tox. 4 * H332 GHS07 H332 EUH032 A
Acute Tox. 4 * H312 GHS09 H312
L 353/715
Acute Tox. 4 * H302 Wng H302
Aquatic H411 H411
Chronic 2
L 353/716
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
615-032-00-6 metal salts of thiocyanic acid not mentioned — — Acute Tox. 4 * H332 GHS07 H332 EUH032 A
EN
elsewhere in this Annex Acute Tox. 4 * H312 GHS09 H312
Acute Tox. 4 * H302 Wng H302
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
616-004-00-6 allidochlor (ISO); 202-270-7 93-71-0 Acute Tox. 4 * H312 GHS07 H312
N,N-diallylchloroacetamide Acute Tox. 4 * H302 GHS09 H302
Eye Irrit. 2 H319 Wng H319
Skin Irrit. 2 H315 H315
Aquatic H411 H411
Chronic 2
31.12.2008
616-005-00-1 chlorthiamid (ISO); 217-637-7 1918-13-4 Acute Tox. 4 * H302 GHS07 H302
2,6-dichloro (thiobenzamide) Wng
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
616-006-00-7 dichlofluanid (ISO); 214-118-7 1085-98-9 Acute Tox. 4 * H332 GHS07 H332
EN
N-dichlorofluoromethylthio-N',N'-dimethyl- Eye Irrit. 2 H319 GHS09 H319
N-phenylsulphamide Skin Sens. 1 H317 Wng H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
616-007-00-2 diphenamid (ISO); 213-482-4 957-51-7 Acute Tox. 4 * H302 GHS07 H302
N,N-dimethyl-2,2-diphenylacetamide Aquatic H412 Wng H412
Chronic 3
616-009-00-3 propanil (ISO); 211-914-6 709-98-8 Acute Tox. 4 * H302 GHS07 H302
3',4'-dichloropropionanilide Aquatic Acute 1 H400 GHS09 H400
Wng
616-010-00-9 tosylchloramide sodium 204-854-7 127-65-1 Acute Tox. 4 * H302 GHS08 H302 EUH031
Skin Corr. 1B H314 GHS05 H314
Resp. Sens. 1 H334 GHS07 H334
Dg
616-011-00-4 N,N-dimethylacetamide 204-826-4 127-19-5 Repr. 1B H360- GHS08 H360D *** Repr. 1B; H360D:
Acute Tox. 4 * D *** GHS07 H332 C ≥ 5%
Acute Tox. 4 * H332 Dgr H312
H312
L 353/717
616-013-00-5 butyraldehyde oxime 203-792-8 110-69-0 Acute Tox. 3 * H311 GHS06 H311
Acute Tox. 4 * H302 Dgr H302
Eye Irrit. 2 H319 H319
L 353/718
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
ethyl methyl ketoxime; Acute Tox. 4 * H312 GHS05 H312
ethyl methyl ketone oxime Eye Dam. 1 H318 GHS07 H318
Skin Sens. 1 H317 Dgr H317
616-015-00-6 alachlor (ISO); 240-110-8 15972-60-8 Carc. 2 H351 GHS08 H351 M=10
2-chloro-2',6'-diethyl-N-(methoxymethyl) Acute Tox. 4 * H302 GHS07 H302
acetanilide Skin Sens. 1 H317 GHS09 H317
Aquatic Acute 1 H400 Wng H410
Aquatic H410
616-017-00-7 cartap hydrochloride 239-309-2 15263-52-2 Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 GHS09 H302
Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
616-019-00-8 perfluidone (ISO); 253-718-3 37924-13-3 Acute Tox. 4 * H302 GHS07 H302
1,1,1-trifluoro-N-(4-phenylsulphonyl-o- Eye Irrit. 2 H319 Wng H319
tolyl)methanesulphonamide;
616-020-00-3 tebuthiuron (ISO); 251-793-7 34014-18-1 Acute Tox. 4 * H302 GHS07 H302
31.12.2008
1-(5-tert-butyl-1,3,4-thiadiazol-2-yl)- Aquatic Acute 1 H400 GHS09 H410
1,3-dimethylurea Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
616-021-00-9 thiazafluron (ISO); 246-901-4 25366-23-8 Acute Tox. 4 * H302 GHS07 H302
EN
1,3-dimethyl-1-(5-trifluoromethyl-1,3,4- Aquatic Acute 1 H400 GHS09 H410
thiadiazol-2-yl)urea Aquatic H410 Wng
Chronic 1
L 353/719
616-029-00-2 N,N'-ethylenebis(vinylsulfonylacetamide) 404-790-1 66710-66-5 Eye Dam. 1 H318 GHS05 H318
Skin Sens. 1 H317 GHS07 H317
Dgr
L 353/720
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
616-030-00-8 ethidimuron (ISO); 250-010-6 30043-49-3 Skin Sens. 1 H317 GHS07 H317
EN
1-(5-ethylsulphonyl-1,3,4-thiadiazol-2-yl)- Aquatic Acute 1 H400 GHS09 H410
1,3-dimethylurea Aquatic H410 Wng
Chronic 1
616-031-00-3 dimethachlor (ISO); 256-625-6 50563-36-5 Acute Tox. 4 * H302 GHS07 H302
2-chloro-N-(2,6-dimethylphenyl)-N- Skin Sens. 1 H317 GHS09 H317
(2-methoxyethyl)acetamide; Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
616-033-00-4 cyprofuram (ISO); 274-050-9 69581-33-5 Acute Tox. 3 * H301 GHS06 H301
N-(3-chlorophenyl)-N-(tetrahydro-2-oxo- Acute Tox. 4 * H312 GHS09 H312
3-furyl)cyclopropanecarboxamide Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
616-035-00-5 cymoxanil (ISO); 261-043-0 57966-95-7 Acute Tox. 4 * H302 GHS07 H302
2-cyano-N-[(ethylamino)carbonyl]-2-(meth- Skin Sens. 1 H317 GHS09 H317
oxyimino)acetamide Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
616-036-00-0 2-chloracetamide 201-174-2 79-07-2 Repr. 2 H361f GHS06 H361f *** Skin Sens. 1;
31.12.2008
Acute Tox. 3 * *** GHS08 H301 H317: C ≥ 0,1 %
Skin Sens. 1 H301 Dgr H317
H317
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
616-037-00-6 acetochlor (ISO); 251-899-3 34256-82-1 Acute Tox. 4 * H332 GHS07 H332
EN
2-chloro-N-(ethoxymethyl)-N-(2-ethyl- STOT SE 3 H335 GHS09 H335
6-methylphenyl)acetamide Skin Irrit. 2 H315 Wng H315
Skin Sens. 1 H317 H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
616-040-00-2 potassium N-(4-toluenesulfonyl)-4-toluene- 406-650-5 97888-41-0 Eye Dam. 1 H318 GHS05 H318
sulfonamide Dgr
L 353/721
616-045-00-X 2'-(4-chloro-3-cyano-5-formyl-2-thieny- 405-190-2 122371-93-1 Skin Sens. 1 H317 GHS07 H317
lazo)-5'-diethylamino-2-methoxyacetanilide Aquatic H413 Wng H413
Chronic 4
L 353/722
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
1,2,4-triazol-4-yl)propyl)-2-(2,4-di-tert-pen- Aquatic H410 Wng
tylphenoxy)octanamide Chronic 1
616-047-00-0 reaction mass of: 2,2',2'',2'''-(ethylenedinitri- 406-640-0 — Skin Sens. 1 H317 GHS07 H317
lotetrakis-N,N-di(C16)alkylacetamide; Wng
2,2',2'',2'''-(ethylenedinitrilotetrakis-N,N-di
(C18)alkylacetamide
616-050-00-7 lufenuron (ISO); 410-690-9 103055-07-8 Skin Sens. 1 H317 GHS07 H317
N-[2,5-dichloro-4-(1,1,2,3,3,3-hexafluoro- Aquatic Acute 1 H400 GHS09 H410
propoxy)-phenyl-aminocarbonyl]-2,6- Aquatic H410 Wng
difluorobenzamide Chronic 1
616-051-00-2 reaction mass of: 2,4 -bis(N'-(4-methylphe- 411-070-0 — Aquatic H413 — H413
nyl)-ureido)-toluene; Chronic 4
2,6 -bis(N'-(4-methylphenyl)-ureido)-toluene
31.12.2008
3-(3,5-dichlorophenyl)-2,4-dioxo-N-isopro- Aquatic Acute 1 H400 GHS09 H410
pylimidazolidine-1-carboxamide Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
3,5-dichloro-N-(1,1-dimethylprop-2-ynyl) Aquatic Acute 1 H400 GHS09 H410
benzamide Aquatic H410 Wng
Chronic 1
616-060-00-1 Condensation product of: 3-(7-carboxyhept- 413-770-1 — Acute Tox. 4 * H302 GHS05 H302
1-yl)-6-hexyl-4-cyclohexene-1,2-dicar- Skin Corr. 1B H314 GHS07 H314
boxylic acid with polyamines (primarily Skin Sens. 1 H317 GHS09 H317
amino-ethyl-piperazine and triethylenetetra-
L 353/723
mine) Aquatic Acute 1 H400 Dgr H410
Aquatic H410
Chronic 1
L 353/724
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H412 Wng H412
Chronic 3
616-068-00-5 potassium 4-(11-methacrylamidoundecana- 406-500-9 174393-75-0 Skin Sens. 1 H317 GHS07 H317
mido)benzenesulfonate Wng
31.12.2008
616-069-00-0 1-hydroxy-5-(2-methylpropyloxycarbonyla- 406-210-2 110560-22-0 Aquatic H413 — H413
mino)-N-(3-dodecyloxypropyl)-2-naphthoa- Chronic 4
mide
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methylenebis(4,1-phenylene)diurea; Chronic 4
3-cyclohexyl-1-(4-(4-(3-octadecylureido)
benzyl)phenyl)urea;
3,3'-dioctadecyl-1,1'-methylenebis(4,1-phe-
nylene)diurea
616-071-00-1 reaction mass of: bis(N-cyclohexyl-N'-phe- 406-550-1 — Skin Sens. 1 H317 GHS07 H317
nyleneureido)methylene; Aquatic H413 Wng H413
bis(N-octadecyl-N'-phenyleneureido)methy- Chronic 4
L 353/725
616-076-00-9 tebufenozide (ISO); 412-850-3 112410-23-8 Aquatic H411 GHS09 H411
N-tert-butyl-N'-(4-ethylbenzoyl)-3,5- Chronic 2
dimethylbenzohydrazide
L 353/726
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
616-077-00-4 reaction mass of: 2-(9-methyl-1,3,8,10-tet- 411-310-4 — Eye Dam. 1 H318 GHS05 H318
raoxo-2,3,9,10-tetrahydro-(1H,8H)-anthra
EN
Dgr
[2,1,9-def: 6,5,10-d'e'f']diisoquinolin-2-
ylethansulfonic acid;
potassium 2-(9-methyl-1,3,8,10-tetraoxo-
2,3,9,10-tetrahydro-(1H,8H)-anthra[2,1,9-
def: 6,5,10-d'e'f']diisoquinolin-2-ylethansul-
fate
31.12.2008
616-085-00-8 3-(2,4-dichlorophenyl)-6-fluoro-quinazo- 412-190-6 168900-02-5 Aquatic Acute 1 H400 GHS09 H410
line-2,4(1H,3H)-dione Aquatic H410 Wng
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2,5-cyclohexadiene
616-087-00-9 reaction mass of: 7,9,9-trimethyl-3,14- 412-260-6 52658-19-2 Eye Irrit. 2 H319 GHS07 H319
dioxa-4,13-dioxo-5,12-diazahexadecane- Skin Sens. 1 H317 GHS09 H317
1,16-diyl-prop-2-enoate; Aquatic H411 Wng H411
7,7,9-trimethyl-3,14-dioxa-4,13-dioxo- Chronic 2
5,12-diazahexadecan-1,16-diyl-prop-2-eno-
ate
616-091-00-0 1,3,5-tris-[(2S and 2R)-2,3-epoxypropyl]- 423-400-0 59653-74-6 Muta. 1B H340 GHS06 H340
1,3,5-triazine-2,4,6-(1H,3H,5H)-trione Acute Tox. 3 * H331 GHS08 H331
Acute Tox. 4 * H302 GHS05 H302
STOT RE 2 * H373 Dgr H373 **
Eye Dam. 1 ** H318
Skin Sens. 1 H318 H317
H317
616-092-00-6 Polymeric reaction product of bicyclo[2.2.1] 404-035-6 — Skin Sens. 1 H317 GHS07 H317
hepta-2,5-diene, ethene, 1,4-hexadiene, 1- Aquatic H413 Wng H413
propene with N,N-di-2-propenylformamide Chronic 4
L 353/727
616-093-00-1 Reaction products of: aniline-terephthalal- 406-620-1 129217-90-9 Skin Sens. 1 H317 GHS07 H317
dehyde-o-toluidine condensate with maleic Aquatic H411 GHS09 H411
anhydride Chronic 2 Wng
L 353/728
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Chronic 4
616-102-00-9 reaction mass of: α-[3-(3-mercaptopropa- 415-870-0 — Skin Sens. 1 H317 GHS07 H317
noxycarbonylamino)methylphenylaminocar- Aquatic H411 GHS09 H411
bonyl]-ω-[3-(3-mercaptopropanoxycarbony- Chronic 2 Wng
lamino)methylphenylaminocarbonyloxy]-
poly-(oxyethylene-co-oxypropylene);
1,2-(or 1,3-)bis[α-(3-mercaptopropanoxy-
carbonylamino)methylphenylaminocarbo-
nyl)-ω-oxy-poly(oxyethylene-co-oxypropy-
lene)]-3-(or 2-)propanol;
31.12.2008
1,2,3-tris[α-(3-mercaptopropanoxycarbonyl-
amino)methylphenylaminocarbonyl)-ω-oxy-
poly-(oxyethylene-co-oxypropylene)]pro-
pane]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
methyl-7,7-dioxo-4H-thieno[2,3-b]thio- Aquatic Acute 1 H400 GHS09 H410
pyran-2-sulfonamide Aquatic H410 Wng
Chronic 1
616-104-00-X benalaxyl (ISO); 275-728-7 71626-11-4 Aquatic Acute 1 H400 GHS09 H410
methyl N-(2,6-dimethylphenyl)-N-(phenyla- Aquatic H410 Wng
cetyl)-DL-alaninate Chronic 1
616-106-00-0 phenmedipham (ISO); 237-199-0 13684-63-4 Aquatic Acute 1 H400 GHS09 H410
methyl 3-(3-methylcarbaniloyloxy)carbani- Aquatic H410 Wng
late Chronic 1
616-110-00-2 cyclanilide (ISO); 419-150-7 113136-77-9 Acute Tox. 4 * H302 GHS07 H302
1-(2,4-dichloroanilinocarbonyl)cyclopropa- Aquatic H411 GHS09 H411
necarboxylic acid Chronic 2 Wng
L 353/729
616-111-00-8 fenhexamid (ISO); 422-530-5 126833-17-8 Aquatic H411 GHS09 H411
N-(2,3-dichlor-4-hydroxyphenyl)-1-methyl- Chronic 2
cyclohexancarboxamid
L 353/730
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
carbamoylsulfamoyl]benzoate Aquatic H400 Wng
Chronic 1 H410
616-113-00-9 desmedipham (ISO); 237-198-5 13684-56-5 Aquatic Acute 1 H400 GHS09 H410 M=10
ethyl 3-phenylcarbamoyloxyphenylcarba- Aquatic H410 Wng
mate Chronic 1
616-120-00-7 reaction mass of: N-(3-dimethylamino-4- 420-600-1 — STOT RE 2 * H373 GHS08 H373 **
methyl-phenyl)-benzamide; Aquatic ** GHS09 H411
31.12.2008
N-(3-dimethylamino-2-methyl-phenyl)-ben- Chronic 2 H411 Wng
zamide;
N-(3-dimethylamino-3-methyl-phenyl)-ben-
zamide
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Aquatic H411 GHS09 H411
Chronic 2 Wng
616-124-00-9 lithium bis(trifluoromethylsulfonyl)imide 415-300-0 90076-65-6 Acute Tox. 3 * H311 GHS06 H311
Acute Tox. 3 * H301 GHS05 H301
616-127-00-5 reaction mass of: N,N'-Ethane-1,2-diylbis 430-050-2 — Skin Sens. 1 H317 GHS07 H317
(decanamide); Aquatic H411 GHS09 H411
12-Hydroxy-N-[2-[1-oxydecyl)amino]ethyl] Chronic 2 Wng
octadecanamide;
N,N'-Ethane-1,2-diylbis(12-hydroxyoctade-
canamide)
L 353/731
616-132-00-2 N-[4-(4-cyano-2-furfurylidene-2,5-dihydro- 423-250-6 130016-98-7 Aquatic Acute 1 H400 GHS09 H410
5-oxo-3-furyl)phenyl]butane-1-sulfonamide Aquatic H410 Wng
Chronic 1
L 353/732
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Eye Dam. 1 H318 GHS07 H318
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
617-001-00-2 di-tert-butyl peroxide 203-733-6 110-05-4 Org. Perox. E H242 GHS02 H242
Flam. Liq. 2 H225 Dgr H225
617-002-00-8 α, α-dimethylbenzyl hydroperoxide; 201-254-7 80-15-9 Org. Perox. E H242 GHS02 H242 Skin Corr. 1B;
cumene hydroperoxide Acute Tox. 3 * H331 GHS06 H331 H314: C ≥ 10 %
Acute Tox. 4 * H312 GHS08 H312 Skin Irrit. 2;
Acute Tox. 4 * H302 GHS05 H302 H315: 3 % ≤ C
< 10 %
STOT RE 2 * H373 GHS09 H373 **
** Eye Dam. 1;
Skin Corr. 1B Dgr H314 H318: 3 % ≤ C
Aquatic H314 H411 < 10 %
Chronic 2 H411 Eye Irrit. 2; H319:
31.12.2008
1% ≤ C < 3%
STOT SE 3;
H335: C < 10 %
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
617-003-00-3 dilauroyl peroxide 203-326-3 105-74-8 Org. Perox. D H242 GHS02 H242
EN
Dgr
617-004-00-9 1,2,3,4-tetrahydro-1-naphthyl hydroperox- 212-230-0 771-29-9 Org. Perox. D H242 GHS02 H242 STOT SE 3;
ide Acute Tox. 4 * H302 GHS05 H302 H335: C ≥ 5 %
Skin Corr. 1B H314 GHS07 H314
Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Dgr
Chronic 1
617-007-00-5 tert-butyl α, α-dimethylbenzyl peroxide 222-389-8 3457-61-2 Org. Perox. E H242 GHS02 H242
Skin Irrit. 2 H315 GHS07 H315
Aquatic H411 GHS09 H411
Chronic 2 Wng
617-008-00-0 dibenzoyl peroxide; 202-327-6 94-36-0 Org. Perox. B H241 GHS01 H241 T
benzoyl peroxide Eye Irrit. 2 H319 GHS02 H319
Skin Sens. 1 H317 GHS07 H317
Wng
617-010-00-1 1-hydroperoxycyclohexyl 1-hydroxycyclo- 201-091-1 78-18-2 [1] Org. Perox. A H240 GHS01 H240 STOT SE 3; CT
hexyl peroxide; [1] [1] 2407-94-5 [2] Acute Tox. 4 * H302 GHS05 H302 H335: C ≥ 5 %
1,1'-dioxybiscyclohexan-1-ol; [2] 219-306-2 2699-11-8 [3] Skin Corr. 1B H314 GHS07 H314
cyclohexylidene hydroperoxide; [3] [2] 12262-58-7 [4] Dgr
cyclohexanone, peroxide [4] 220-279-4
L 353/733
[> 91 % solution] [3]
235-527-7
[4]
L 353/734
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
617-010-01-9 1-hydroperoxycyclohexyl 1-hydroxycyclo- 201-091-1 78-18-2 [1] Org. Perox. C H242 GHS02 H242 STOT SE 3; CT
EN
hexyl peroxide; [1] [1] 2407-94-5 [2] Acute Tox. 4 * H302 GHS05 H302 H335: C ≥ 5 %
1,1'-dioxybiscyclohexan-1-ol; [2] 219-306-2 2699-11-8 [3] Skin Corr. 1B H314 GHS07 H314
cyclohexylidene hydroperoxide; [3] [2] 12262-58-7 [4] Dgr
cyclohexanone, peroxide [4] 220-279-4
[≤ 91 % solution] [3]
235-527-7
[4]
617-012-00-2 8-p-menthyl hydroperoxide; 201-281-4 80-47-7 Org. Perox. D H242 GHS02 H242 STOT SE 3;
p-menthane hydroperoxide Skin Corr. 1B H314 GHS05 H314 H335: C ≥ 5 %
617-013-00-8 O,O-tert-butyl O-docosyl monoperoxyoxa- 404-300-6 116753-76-5 Org. Perox. C H242 GHS02 H242
late **** H400 GHS09 H410
Aquatic Acute 1 H410 Dgr
Aquatic
Chronic 1
617-014-00-3 6-(nonylamino)-6-oxo-peroxyhexanoic acid 406-680-9 104788-63-8 Org. Perox. C H242 GHS02 H242
**** H318 GHS05 H318
Eye Dam. 1 H317 GHS07 H317
Skin Sens. 1 H400 GHS09 H400
Aquatic Acute 1 Dgr
31.12.2008
Aquatic Acute 1 H410
Aquatic
Chronic 1
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
617-017-00-X reaction mass of: 2,2'-bis(tert-pentylperoxy)- 412-140-3 32144-25-5 Org. Perox. D H242 GHS02 H242 T
p-diisopropylbenzene; ****
EN
H413 Dgr H413
2,2'-bis(tert-pentylperoxy)-m-diisopropyl- Aquatic
benzene Chronic 4
617-018-00-5 reaction mass of: 1-methyl-1-(3-(1-methy- 410-840-3 71566-50-2 Org. Perox. C H242 GHS02 H242 T
lethyl)phenyl)ethyl-1-methyl-1-phenylethyl- **** H411 GHS09 H411
peroxide, 63 % by weight; Aquatic Dgr
1-methyl-1-(4-(1-methylethyl)phenyl)ethyl- Chronic 2
1-methyl-1-phenylethylperoxide, 31 % by
weight
617-020-00-6 1,3-di(prop-2,2-diyl)benzene bis(neodeca- 420-060-5 117663-11-3 Flam. Liq. 3 H226 GHS02 H226
noylperoxide) Org. Perox. D H242 GHS09 H242
**** H411 Dgr H411
Aquatic
Chronic 2
647-003-00-9 cellobiohydrolase, exo- 253-465-9 37329-65-0 Resp. Sens. 1 H334 GHS08 H334
Dgr
647-004-00-4 cellulases with the exception of those — — Resp. Sens. 1 H334 GHS08 H334 A
specified elsewhere in this Annex Dgr
647-005-00-X bromelain, juice 232-572-4 9001-00-7 Eye Irrit. 2 H319 GHS08 H319
L 353/735
STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 Dgr H315
Resp. Sens. 1 H334 H334
L 353/736
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 Dgr H315
Resp. Sens. 1 H334 H334
31.12.2008
Skin Irrit. 2 H315 GHS05 GHS07 H315
Eye Dam. 1 H318 Dgr H318
Resp. Sens. 1 H334 H334
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
647-013-00-3 proteinase, microbial neutral 232-966-6 9068-59-1 Eye Irrit. 2 H319 GHS08 H319
EN
STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 Dgr H315
Resp. Sens. 1 H334 H334
647-014-00-9 proteases with the exception of those — — Eye Irrit. 2 H319 GHS08 H319
specified elsewhere in this Annex STOT SE 3 H335 GHS07 H335
Skin Irrit. 2 H315 Dgr H315
Resp. Sens. 1 H334 H334
647-016-00-X amylases with the exception of those — — Resp. Sens. 1 H334 GHS08 H334
specified elsewhere in this Annex Dgr
648-001-00-0 Distillates (coal tar), benzole fraction; 283-482-7 84650-02-2 Carc. 1B H350 GHS08 H350 H
Light Oil; Dgr
[A complex combination of hydrocarbons
obtained by the distillation of coal tar. It
consists of hydrocarbons having carbon
numbers primarily in the range of C4 to C10
and distilling in the approximate range of
80 oC to 160 oC (175 oF to 320 oF).]
648-002-00-6 Tar oils, brown-coal; 302-674-4 94114-40-6 Carc. 1B H350 GHS08 H350 HJ
Light Oil; Dgr
[The distillate from lignite tar boiling in the
range of approximately 80 oC to 250 oC
(176 oF to 482 oF). Composed primarily of
aliphatic and aromatic hydrocarbons and
monobasic phenols.]
648-003-00-1 Benzol forerunnings (coal); 266-023-5 65996-88-5 Carc. 1B H350 GHS08 H350 HJ
Light Oil Redistillate, low boiling; Dgr
[The distillate from coke oven light oil
L 353/737
having an approximate distillation range
below 100 oC (212 oF). Composed primarily
of C4 to C6 aliphatic hydrocarbons.]
L 353/738
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-004-00-7 Distillates (coal tar), benzole fraction, BTX- 309-984-9 101896-26-8 Carc. 1B H350 GHS08 H350 HJ
EN
rich; Dgr
Light Oil Redistillate, low boiling;
[A residue from the distillation of crude
benzole to remove benzole fronts. Com-
posed primarily of benzene, toluene and
xylenes boiling in the range of approxi-
mately 75 oC to 200 oC (167 oF to 392 oF).]
648-005-00-2 Aromatic hydrocarbons, C6-10, C8-rich; 292-697-5 90989-41-6 Carc. 1B H350 GHS08 H350 HJ
648-006-00-8 Solvent naphtha (coal), light; 287-498-5 85536-17-0 Carc. 1B H350 GHS08 H350 HJ
Light Oil Redistillate, low boiling Dgr
648-007-00-3 Solvent naphtha (coal), xylene-styrene cut; 287-502-5 85536-20-5 Carc. 1B H350 GHS08 H350 HJ
Light Oil Redistillate, intermediate boiling Dgr
648-008-00-9 Solvent naphtha (coal), coumarone-styrene 287-500-4 85536-19-2 Carc. 1B H350 GHS08 H350 HJ
contg.; Dgr
Light Oil Redistillate, intermediate boiling
648-009-00-4 Naphtha (coal), distn. residues; 292-636-2 90641-12-6 Carc. 1B H350 GHS08 H350 HJ
Light Oil Redistillate, high boiling; Dgr
[The residue remaining from the distillation
of recovered naphtha. Composed primarily
of naphthalene and condensation products
of indene and styrene.]
31.12.2008
648-010-00-X Aromatic hydrocarbons, C8; 292-694-9 90989-38-1 Carc. 1B H350 GHS08 H350 HJ
Light Oil Redistillate, high boiling Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-012-00-0 Aromatic hydrocarbons, C8-9, hydrocarbon 295-281-1 91995-20-9 Carc. 1B H350 GHS08 H350 HJ
EN
resin polymn. by-product; Dgr
Light Oil Redistillate, high boiling;
[A complex combination of hydrocarbons
obtained from the evaporation of solvent
under vacuum from polymerized hydrocar-
bon resin. It consists predominantly of
aromatic hydrocarbons having carbon
numbers predominantly in the range of C8
through C9 and boiling in the range of
approximately 120 oC to 215 oC (248 oF to
419 oF).]
648-014-00-1 Extract residues (coal), benzole fraction alk., 295-323-9 91995-61-8 Carc. 1B H350 GHS08 H350 HJ
acid ext.; Dgr
Light Oil Extract Residues, low boiling;
[The redistillate from the distillate, freed of
tar acids and tar bases, from bituminous coal
high temperature tar boiling in the approx-
imate range of 90 oC to 160 oC (194 oF to
320 oF). It consists predominantly of
benzene, toluene and xylenes.]
648-015-00-7 Extract residues (coal tar), benzole fraction 309-868-8 101316-63-6 Carc. 1B H350 GHS08 H350 HJ
alk., acid ext.; Dgr
Light Oil Extract Residues, low boiling;
[A complex combination of hydrocarbons
obtained by the redistillation of the distillate
of high temperature coal tar (tar acid and tar
base free). It consists predominantly of
unsubstituted and substituted mononuclear
L 353/739
aromatic hydrocarbons boiling in the range
of 85 oC-195 oC (185 oF-383 oF).]
L 353/740
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-016-00-2 Extract residues (coal), benzole fraction acid; 298-725-2 93821-38-6 Carc. 1B H350 GHS08 H350 HJ
Light Oil Extract Residues, low boiling; Dgr
[An acid sludge by-product of the sulphuric
acid refining of crude high temperature coal.
Composed primarily of sulfuric acid and
organic compounds.]
648-018-00-3 Extract residues (coal), light oil alk., acid ext., 309-867-2 101316-62-5 Carc. 1B H350 GHS08 H350 HJ
indene fraction; Dgr
Light Oil Extract Residues, intermediate
boiling
648-019-00-9 Extract residues (coal), light oil alk., indene 292-626-8 90641-03-5 Carc. 1B H350 GHS08 H350 HJ
naphtha fraction; Dgr
Light Oil Extract Residues, high boiling;
[The distillate from aromatic hydrocarbons,
coumarone, naphthalene and indene rich
prefractionator bottoms or washed carbolic
oils, having an approximate boiling range of
155 oC to 180 oC (311 oF to 356 oF).
31.12.2008
Composed primarily of indene, indan and
trimethylbenzenes.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-020-00-4 Solvent naphtha (coal); 266-013-0 65996-79-4 Carc. 1B H350 GHS08 H350 HJ
EN
Light Oil Extract Residues, high boiling; Dgr
[The distillate from either high temperature
coal tar, coke oven light oil, or coal tar oil
alkaline extract residue having an approx-
imate distillation range of 130 oC to 210 oC
(266 oF to 410 oF) Composed primarily of
indene and other polycyclic ring systems
containing a single aromatic ring. May
contain phenolic compounds and aromatic
nitrogen bases.]
648-022-00-5 Distillates (coal tar), light oils, acid exts.; 292-609-5 90640-87-2 Carc. 1B H350 GHS08 H350 HJ
Light Oil Extract Residues, high boiling; Dgr
[This oil is a complex mixture of aromatic
hydrocarbons, primarily indene, naphtha-
lene, coumarone, phenol, and o-, m- and p-
cresol and boiling in the range of 140 oC to
215 oC (284 oF to 419 oF).]
648-023-00-0 Distillates (coal tar), light oils; 283-483-2 84650-03-3 Carc. 1B H350 GHS08 H350 HJ
Carbolic Oil; Dgr
[A complex combination of hydrocarbons
obtained by distillation of coal tar. It consists
of aromatic and other hydrocarbons, phe-
nolic compounds and aromatic nitrogen
L 353/741
compounds and distills at the approximate
range of 150 oC to 210 oC (302 oF to
410 oF).]
L 353/742
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-024-00-6 Tar oils, coal; 266-016-7 65996-82-9 Carc. 1B H350 GHS08 H350 HJ
EN
Carbolic Oil; Dgr
[The distillate from high temperature coal
tar having an approximate distillation range
of 130 oC to 250 oC (266 oF to 410 oF).
Composed primarily of naphthalene, alkyl-
naphthalenes, phenolic compounds, and
aromatic nitrogen bases.]
648-026-00-7 Extract residues (coal), light oil alk., acid ext.; 292-624-7 90641-01-3 Carc. 1B H350 GHS08 H350 HJ
Carbolic Oil Extract Residue; Dgr
648-027-00-2 Extract residues (coal), tar oil alk.; 266-021-4 65996-87-4 Carc. 1B H350 GHS08 H350 HJ
Carbolic Oil Extract Residue; Dgr
[The residue obtained from coal tar oil by an
alkaline wash such as aqueous sodium
hydroxide after the removal of crude coal tar
acids. Composed primarily of naphthalenes
and aromatic nitrogen bases.]
648-028-00-8 Extract oils (coal), light oil; 292-622-6 90640-99-6 Carc. 1B H350 GHS08 H350 HJ
Acid Extract; Dgr
[The aqueous extract produced by an acidic
wash of alkali-washed carbolic oil. Com-
posed primarily of acid salts of various
aromatic nitrogen bases including pyridine,
quinoline and their alkyl derivatives.]
648-029-00-3 Pyridine, alkyl derivs.; 269-929-9 68391-11-7 Carc. 1B H350 GHS08 H350 HJ
Crude Tar Bases; Dgr
[The complex combination of polyalkylated
pyridines derived from coal tar distillation or
as high-boiling distillates approximately
31.12.2008
above 150 oC (302 oF) from the reaction of
ammonia with acetaldehyde, formaldehyde
or paraformaldehyde.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-030-00-9 Tar bases, coal, picoline fraction; 295-548-2 92062-33-4 Carc. 1B H350 GHS08 H350 HJ
EN
Distillate Bases; Dgr
[Pyridine bases boiling in the range of
approximately 125 oC to 160 oC (257 oF
320 oF) obtained by distillation of neutra-
lized acid extract of the base-containing tar
fraction obtained by the distillation of
bituminous coal tars. Composed chiefly of
lutidines and picolines.]
648-031-00-4 Tar bases, coal, lutidine fraction; 293-766-2 91082-52-9 Carc. 1B H350 GHS08 H350 HJ
648-032-00-X Extract oils (coal), tar base, collidine fraction; 273-077-3 68937-63-3 Carc. 1B H350 GHS08 H350 HJ
Distillate Bases; Dgr
[The extract produced by the acidic extrac-
tion of bases from crude coal tar aromatic
oils, neutralization, and distillation of the
bases. Composed primarily of collidines,
aniline, toluidines, lutidines, xylidines.]
648-033-00-5 Tar bases, coal, collidine fraction; 295-543-5 92062-28-7 Carc. 1B H350 GHS08 H350 HJ
Distillate Bases; Dgr
[The distillation fraction boiling in the range
of approximately 181 oC to 186 oC (356 oF
to 367 oF) from the crude bases obtained
from the neutralized, acid-extracted base-
containing tar fractions obtained by the
distillation of bituminous coal tar. It con-
tains chiefly aniline and collidines.]
648-034-00-0 Tar bases, coal, aniline fraction; 295-541-4 92062-27-6 Carc. 1B H350 GHS08 H350 HJ
Distillate Bases; Dgr
[The distillation fraction boiling in the range
of approximately 180 oC to 200 oC (356 oF
to 392 oF) from the crude bases obtained by
dephenolating and debasing the carbolated
L 353/743
oil from the distillation of coal tar. It
contains chiefly aniline, collidines, lutidines
and toluidines.]
L 353/744
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-035-00-6 Tar bases, coal, toluidine fraction; 293-767-8 91082-53-0 Carc. 1B H350 GHS08 H350 HJ
EN
Distillate Bases Dgr
648-036-00-1 Distillates (petroleum), alkene-alkyne manuf. 295-292-1 91995-31-2 Carc. 1B H350 GHS08 H350 HJ
pyrolysis oil, mixed with high-temp. coal tar, Dgr
indene fraction;
Redistillates;
[A complex combination of hydrocarbons
obtained as a redistillate from the fractional
distillation of bituminous coal high tem-
648-037-00-7 Distillates (coal), coal tar-residual pyrolysis 295-295-8 91995-35-6 Carc. 1B H350 GHS08 H350 HJ
oils, naphthalene oils; Dgr
Redistillates;
[The redistillate obtained from the fractional
distillation of bituminous coal high tem-
perature tar and pyrolysis residual oils and
boiling in the range of approximately
190 oC to 270 oC (374 oF to 518 oF).
Composed primarily of substituted dinuclear
aromatics.]
648-038-00-2 Extract oils (coal), coal tar-residual pyrolysis 295-329-1 91995-66-3 Carc. 1B H350 GHS08 H350 HJ
oils, naphthalene oil, redistillate; Dgr
Redistillates;
[The redistillate from the fractional distilla-
tion of dephenolated and debased methyl-
naphthalene oil obtained from bituminous
coal high temperature tar and pyrolysis
residual oils boiling in the approximate
range of 220 oC to 230 oC (428 oF to
31.12.2008
446 oF). It consists predominantly of
unsubstituted and substituted dinuclear
aromatic hydrocarbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-039-00-8 Extract oils (coal), coal tar-residual pyrolysis 310-170-0 122070-79-5 Carc. 1B H350 GHS08 H350 HJ
EN
oils, naphthalene oils; Dgr
Redistillates;
[A neutral oil obtained by debasing and
dephenolating the oil obtained from the
distillation of high temperature tar and
pyrolysis residuel oils which has a boiling
range of 225 oC to 255 oC (437 oF to
491 oF). Composed primarily of substituted
dinuclear aromatic hydrocarbons.]
648-041-00-9 Absorption oils, bicyclo arom. and hetero- 309-851-5 101316-45-4 Carc. 1B H350 GHS08 H350 HM
cyclic hydrocarbon fraction; Dgr
Wash Oil Redistillate;
[A complex combination of hydrocarbons
obtained as a redistillate from the distillation
of wash oil. It consists predominantly of 2-
ringed aromatic and heterocyclic hydrocar-
bons boiling in the range of approximately
260 oC to 290 oC (500 oF to 554 oF).]
648-042-00-4 Distillates (coal tar), upper, fluorene-rich; 284-900-0 84989-11-7 Carc. 1B H350 GHS08 H350 HM
Wash Oil Redistillate; Dgr
[A complex combination of hydrocarbons
obtained by the crystallization of tar oil. It
L 353/745
consists af aromatic and polycyclic hydro-
carbons primarily fluorene and some ace-
naphthene.]
L 353/746
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-043-00-X Creosote oil, acenaphthene fraction, ace- 292-606-9 90640-85-0 Carc. 1B H350 GHS08 H350 H
naphthene-free; Dgr
Wash Oil Redistillate;
[The oil remaining after removal by a
crystallization process of acenaphthene from
acenaphthene oil from coal tar. Composed
primarily of naphthalene and alkylnaphtha-
lenes.]
648-045-00-0 Distillates (coal tar), upper; 266-026-1 65996-91-0 Carc. 1B H350 GHS08 H350 HM
Heavy Anthracene Oil; Dgr
[The distillate from coal tar having an
approximate distillation range of 220 oC to
450 oC (428 oF to 842 oF). Composed
primarily of three to four membered con-
densed ring aromatic hydrocarbons and
other hydrocarbons.]
648-046-00-6 Anthracene oil, acid ext.; 295-274-3 91995-14-1 Carc. 1B H350 GHS08 H350 HM
Anthracene Oil Extract Residue; Dgr
[A complex combination of hydrocarbons
from the base-freed fraction obtained from
the distillation of coal tar and boiling in the
range of approximately 325 oC to 365 oC
31.12.2008
(617 oF to 689 oF). It contains predomi-
nantly anthracene and phenanthrene and
their alkyl derivatives.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-047-00-1 Distillates (coal tar); 266-027-7 65996-92-1 Carc. 1B H350 GHS08 H350 HM
EN
Heavy Anthracene Oil; Dgr
[The distillate from coal tar having an
approximate distillation range of 100 oC to
450 oC (212 oF to 842 oF). Composed
primarily of two to four membered con-
densed ring aromatic hydrocarbons, pheno-
lic compounds, and aromatic nitrogen
bases.]
648-049-00-2 Distillates (coal tar), pitch; 309-855-7 101316-49-8 Carc. 1B H350 GHS08 H350 HM
Heavy Anthracene Oil; Dgr
[The oil obtained from condensation of the
vapors from the heat treatment of pitch.
Composed primarily of two- to four-ring
aromatic compounds boiling in the range of
200 oC to greater than 400 oC (392 oF to
greater than 752 oF).]
648-050-00-8 Distillates (coal tar), heavy oils, pyrene 295-304-5 91995-42-5 Carc. 1B H350 GHS08 H350 HM
fraction; Dgr
Heavy Anthracene Oil Redistillate;
[The redistillate obtained from the fractional
distillation of pitch distillate boiling in the
range of approximately 350 oC to 400 oC
(662 oF to 752 oF). Consists predominantly
L 353/747
of tri- and polynuclear aromatics and
heterocyclic hydrocarbons.]
L 353/748
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-051-00-3 Distillates (coal tar), pitch, pyrene fraction; 295-313-4 91995-52-7 Carc. 1B H350 GHS08 H350 HM
Heavy Anthracene Oil Redistillate; Dgr
[The redistillate obtained from the fractional
distillation of pitch distillate and boiling in
the range of approximately 380 oC to
410 oC (7160 to 770 oF). Composed
primarily of tri- and polynuclear aromatic
hydrocarbons and heterocyclic compounds.]
648-053-00-4 Paraffin waxes (coal), brown-coal high-temp 308-297-1 97926-77-7 Carc. 1B H350 GHS08 H350 HM
tar, clay-treated; Dgr
Coal Tar Extract;
[A complex combination of hydrocarbons
obtained by the treatment of lignite carbo-
nization tar with bentonite for removal of
trace constituents and impurities. It consists
predominantly of saturated straight and
branched chain hydrocarbons having carbon
numbers predominantly greater than C12.]
31.12.2008
648-054-00-X Pitch; 263-072-4 61789-60-4 Carc. 1B H350 GHS08 H350 HM
Pitch Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-055-00-5 Pitch, coal tar, high-temp.; 266-028-2 65996-93-2 Carc. 1B H350 GHS08 H350 H
EN
Pitch; Dgr
[The residue from the distillation of high
temperature coal tar. A black solid with an
approximate softening point from 30 oC to
180 oC (86 oF to 356 oF). Composed
primarily of a complex mixture of three or
more membered condensed ring aromatic
hydrocarbons.]
648-057-00-6 Pitch, coal tar, high-temp., secondary; 302-650-3 94114-13-3 Carc. 1B H350 GHS08 H350 HM
Pitch Redistillate; Dgr
[The residue obtained during the distillation
of high boiling fractions from bituminous
coal high temperature tar and/or pitch coke
oil, with a softening point of 140 oC to
170 oC (284 oF to 392 oF) according to DIN
52025. Composed primarily of tri- and
polynuclear aromatic compounds which
also contain heteroatoms.]
648-058-00-1 Residues (coal tar), pitch distn.; 295-507-9 92061-94-4 Carc. 1B H350 GHS08 H350 HM
Pitch Redistillate; Dgr
[Residue from the fractional distillation of
pitch distillate boiling in the range of
approximately 400 oC to 470 oC (752 oF to
846 oF). Composed primarily of polynuclear
L 353/749
aromatic hydrocarbons, and heterocyclic
compounds.]
L 353/750
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-059-00-7 Tar, coal, high-temp., distn. and storage 295-535-1 92062-20-9 Carc. 1B H350 GHS08 H350 HM
residues;
EN
Dgr
Coal Tar Solids Residue;
[Coke- and ash-containing solid residues
that separate on distillation and thermal
treatment of bituminous coal high tem-
perature tar in distillation installations and
storage vessels. Consists predominantly of
carbon and contains a small quantity of
hetero compounds as well as ash compo-
nents.]
648-061-00-8 Tar, coal, high-temp., residues; 309-726-5 100684-51-3 Carc. 1B H350 GHS08 H350 HM
Coal Tar Solids Residue; Dgr
[Solids formed during the coking of
bituminous coal to produce crude bitumin-
ous coal high temperature tar. Composed
primarily of coke and coal particles, highly
aromatized compounds and mineral sub-
stances.]
648-062-00-3 Tar, coal, high-temp., high-solids; 273-615-7 68990-61-4 Carc. 1B H350 GHS08 H350 HM
Coal Tar Solids Residue; Dgr
[The condensation product obtained by
cooling, to approximately ambient tem-
perature, the gas evolved in the high
temperature (greater than 700 oC (1292 oF))
destructive distillation of coal. Composed
primarily of a complex mixture of con-
densed ring aromatic hydrocarbons with a
high solid content of coal-type materials.]
648-063-00-9 Waste solids, coal-tar pitch coking; 295-549-8 92062-34-5 Carc. 1B H350 GHS08 H350 HM
Coal Tar Solids Residue; Dgr
31.12.2008
[The combination of wastes formed by the
coking of bituminous coal tar pitch. It
consists predominantly of carbon.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-064-00-4 Extract residues (coal), brown; 294-285-0 91697-23-3 Carc. 1B H350 GHS08 H350 HM
EN
Coal Tar Extract; Dgr
[The residue from extraction of dried coal.]
648-065-00-X Paraffin waxes (coal), brown-coal-high-temp. 295-454-1 92045-71-1 Carc. 1B H350 GHS08 H350 HM
tar; Dgr
Coal Tar Extract;
[A complex combination of hydrocarbons
obtained from lignite carbonization tar by
648-066-00-5 Paraffin waxes (coal), brown-coal-high-temp. 295-455-7 92045-72-2 Carc. 1B H350 GHS08 H350 HM
tar, hydrotreated; Dgr
Coal Tar Extract;
[A complex combination of hydrocarbons
obtained from lignite carbonization tar by
solvent crystallisation (solvent deoiling), by
sweating or an adducting process treated
with hydrogen in the presence of a catalyst.
It consists predominantly of straight and
branched chain saturated hydrocarbons
having carbon numbers predominantly
greater than C12.]
648-067-00-0 Paraffin waxes (coal), brown-coal high-temp 308-298-7 97926-78-8 Carc. 1B H350 GHS08 H350 HM
tar, silicic acid-treated; Dgr
Coal Tar Extract;
[A complex combination of hydrocarbons
obtained by the treatment of lignite carbo-
nization tar with silicic acid for removal of
trace constituents and impurities. It consists
predominantly of saturated straight and
L 353/751
branched chain hydrocarbons having carbon
numbers predominantly greater than C12.]
L 353/752
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-068-00-6 Tar, coal, low-temp., distn. residues; 309-887-1 101316-85-2 Carc. 1B H350 GHS08 H350 HM
Tar Oil, intermediate boiling; Dgr
[Residues from fractional distillation of
low temperature coal tar to remove oils that
boil in a range up to approximately 300 oC
(572 oF). Composed primarily of aromatic
compounds.]
648-069-00-1 Pitch, coal tar, low-temp; 292-651-4 90669-57-1 Carc. 1B H350 GHS08 H350 HM
648-070-00-7 Pitch, coal tar, low-temp., oxidized; 292-654-0 90669-59-3 Carc. 1B H350 GHS08 H350 HM
Pitch Residue, oxidised; Dgr
[The product obtained by air-blowing, at
elevated temperature, low-temperature coal
tar pitch. It has a softening-point within the
approximate range of 70 oC to 180 oC
(158 oF to 356 oF). Composed primarily of a
complex mixture of hydrocarbons.]
648-071-00-2 Pitch, coal tar, low-temp., heat-treated; 292-653-5 90669-58-2 Carc. 1B H350 GHS08 H350 HM
Pitch Residue, oxidised; Dgr
Pitch Residue, heat-treated;
[A complex black solid obtained by the heat
treatment of low temperature coal tar pitch.
It has a softening point within the approx-
31.12.2008
imate range of 50 oC to 140 oC (122 oF to
284 oF). Composed primarily of a complex
mixture of aromatic compounds.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-072-00-8 Distillates (coal-petroleum), condensed-ring 269-159-3 68188-48-7 Carc. 1B H350 GHS08 H350 HM
arom; Dgr
Distillates;
[The distillate from a mixture of coal and tar
and aromatic petroleum streams having an
approximate distillation range of 220 oC to
450 oC (428 oF to 842 oF). Composed
primarily of 3- to 4-membered condensed
ring aromatic hydrocarbons.]
648-074-00-9 Aromatic hydrocarbons, C20-28, polycyclic, 309-957-1 101794-75-6 Carc. 1B H350 GHS08 H350 HM
mixed coal-tar pitch-polyethylene pyrolysis- Dgr
derived;
Pyrolysis Products;
[A complex combination of hydrocarbons
obtained from mixed coal tar pitch-poly-
ethylene pyrolysis. Composed primarily of
polycyclic aromatic hydrocarbons having
carbon numbers predominantly in the range
of C20 through C28 and having a softening
point of 100 oC to 220 oC (212 oF to
L 353/753
428 oF) according to DIN 52025.]
L 353/754
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-075-00-4 Aromatic hydrocarbons, C20-28, polycyclic, 309-958-7 101794-76-7 Carc. 1B H350 GHS08 H350 HM
EN
mixed coal-tar pitch-polystyrene pyrolysis- Dgr
derived;
Pyrolysis Products;
[A complex combination of hydrocarbons
obtained from mixed coal tar pitch-poly-
styrene pyrolysis. Composed primarily of
polycyclic aromatic hydrocarbons having
carbon numbers predominantly in the range
of C20 through C28 and having a softening
point of 100 oC to 220 oC (212 oF to
428 oF) according to DIN 52025.]
648-077-00-5 Phenanthrene, distn. residues; 310-169-5 122070-78-4 Carc. 1B H350 GHS08 H350 HM
Heavy Anthracene Oil Redistillate; Dgr
[Residue from the distillation of crude
phenanthrene boiling in the approximate
range of 340 oC to 420 oC (644 oF to
788 oF). It consists predominantly of
phenanthrene, anthracene and carbazole.]
648-078-00-0 Distillates (coal tar), upper, fluorene-free; 284-899-7 84989-10-6 Carc. 1B H350 GHS08 H350 HM
Wash Oil Redistillate; Dgr
[A complex combination of hydrocarbons
obtained by the crystallization of tar oil. It
31.12.2008
consists of aromatic polycyclic hydrocar-
bons, primarily diphenyl, dibenzofuran and
acenaphthene.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Anthracene oil; Dgr
[A complex combination of polycyclic
aromatic hydrocarbons obtained from coal
tar having an approximate distillation range
of 300 oC ot 400 oC (572 oF to 752 oF).
Composed primarily of phenanthrene,
anthracene and carbazole.]
648-082-00-2 Tar, coal, high-temp.; 266-024-0 65996-89-6 Carc. 1A H350 GHS08 H350 H
Coal tar; Dgr
[The condensation product obtained by
cooling, to approximately ambient tem-
perature, the gas evolved in the high
temperature (greater than 700 oC (1292 oF))
destructive distillation of coal. A black
viscous liquid denser than water. Composed
primarily of a complex mixture of con-
densed ring aromatic hydrocarbons. May
L 353/755
contain minor amounts of phenolic com-
pounds and aromatic nitrogen bases.]
L 353/756
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-083-00-8 Tar, coal, low-temp.; 266-025-6 65996-90-9 Carc. 1A H350 GHS08 H350 H
EN
Coal oil; Dgr
[The condensation product obtained by
cooling, to approximately ambient tem-
perature, the gas evolved in low temperature
(less than 700 oC (1292 oF)) destructive
distillation of coal. A black viscous liquid
denser than water. Composed primarily of
condensed ring aromatic hydrocarbons,
phenolic compounds, aromatic nitrogen
bases, and their alkyl derivatives.]
648-085-00-9 Distillates (coal tar), naphthalene oils; 283-484-8 84650-04-4 Carc. 1B H350 GHS08 H350 HJM
Naphthalene Oil; Dgr
[A complex combination of hydrocarbons
obtained by the distillation of coal tar. It
consists primarily of aromatic and other
hydrocarbons, phenolic compounds and
aromatic nitrogen compounds and distills in
the approximate range of 200 oC to 250 oC
(392 oF to 482 oF).]
648-086-00-4 Distillates (coal tar), naphthalene oils, 284-898-1 84989-09-3 Carc. 1B H350 GHS08 H350 HJM
naphthalene-low; Dgr
Naphthalene Oil Redistillate;
[A complex combination of hydrocarbons
obtained by crystallization of naphthalene
31.12.2008
oil. Composed primarily of naphthalene,
alkyl naphthalenes and phenolic com-
pounds.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-087-00-X Distillates (coal tar), naphthalene oil crystn. 295-310-8 91995-49-2 Carc. 1B H350 GHS08 H350 HJM
EN
mother liquor; Dgr
Naphthalene Oil Redistillate;
[A complex combination of organic com-
pounds obtained as a filtrate from the
crystallization of the naphthalene fraction
from coal tar and boiling in the range of
approximately 200 oC to 230 oC (392 oF to
446 oF). Contains chiefly naphthalene,
thionaphthene and alkylnaphthalenes.]
648-089-00-0 Extract residues (coal), naphthalene oil, alk., 310-167-4 121620-48-2 Carc. 1B H350 GHS08 H350 HJM
naphthalene-low; Dgr
Naphthalene Oil Extract Residue;
[A complex combination of hydrocarbons
remaining after the removal of naphthalene
from alkali-washed naphthalene oil by a
crystallization process. It is composed
primarily of naphthalene and alkyl
naphthalenes.]
648-090-00-6 Distillates (coal tar), naphthalene oils, 292-612-1 90640-90-7 Carc. 1B H350 GHS08 H350 HJM
naphthalene-free, alk. exts.; Dgr
Naphthalene Oil Extract Residue;
[The oil remaining after the removal of
phenolic compounds (tar acids) from
drained naphthalene oil by an alkali wash.
L 353/757
Composed primarily of naphthalene and
alkyl naphthalenes.]
L 353/758
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-091-00-1 Extract residues (coal), naphthalene oil alk., 292-627-3 90641-04-6 Carc. 1B H350 GHS08 H350 HJM
EN
distn. overheads; Dgr
Naphthalene Oil Extract Residue;
[The distillation from alkali-washed
naphthalene oil having an approximate
distillation range of 180 oC to 220 oC
(356 oF to 428 oF). Composed primarily of
naphthalene, alkylbenzenes, indene and
indan.]
648-093-00-2 Distillates (coal tar), naphthalene oils, 309-972-3 101794-91-6 Carc. 1B H350 GHS08 H350 HJM
indole-methylnaphthalene fraction; Dgr
Methylnaphthalene Oil;
[A distillate from the fractional distillation of
high temperature coal tar. Composed pri-
marily of indole and methylnaphthalene
boiling in the range of approximately
235 oC to 255 oC (455 oF to 491 oF).]
648-094-00-8 Distillates (coal tar), naphthalene oils, acid 295-309-2 91995-48-1 Carc. 1B H350 GHS08 H350 HJM
exts.; Dgr
Methylnaphthalene Oil Extract Residue;
[A complex combination of hydrocarbons
obtained by debasing the methylnaphtha-
lene fraction obtained by the distillation of
coal tar and boiling in the range of
approximately 230 oC to 255 oC (446 oF to
31.12.2008
491 oF). Contains chiefly 1(2)-methyl-
naphthalene, naphthalene, dimethyl-
naphthalene and biphenyl.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-095-00-3 Extract residues (coal), naphthalene oil alk., 292-628-9 90641-05-7 Carc. 1B H350 GHS08 H350 HJM
EN
distn. residues; Dgr
Methylnaphthalene Oil Extract Residue;
[The residue from the distillation of alkali-
washed naphthalene oil having an approx-
imate distillation range of 220 oC to 300 oC
(428 oF to 572 oF). Composed primarily of
naphthalene, alkylnaphthalenes and aro-
matic nitrogen bases.]
648-097-00-4 Distillates (coal tar), benzole fraction, distn. 310-165-3 121620-46-0 Carc. 1B H350 GHS08 H350 HJM
residues; Dgr
Wash Oil;
[A complex combination of hydrocarbons
obtained from the distillation of crude
benzole (high temperature coal tar). It
may be a liquid with the approximate
distillation range of 150 oC to 300 oC
(302 oF to 572 oF) or a semi-solid or solid
with a melting point up to 70 oC (158 oF). It
is composed primarily of naphthalene and
alkyl naphthalenes.]
648-098-00-X Creosote oil, acenaphthene fraction; 292-605-3 90640-84-9 Carc. 1B H350 GHS08 H350 H
Wash Oil; Dgr
[A complex combination of hydrocarbons
produced by the distillation of coal tar and
boiling in the range of approximately
L 353/759
240 oC to 280 oC (464 oF to 536 oF).
Composed primarily of acenaphthene,
naphthalene and alkyl naphthalene.]
L 353/760
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
[A complex combination of hydrocarbons Dgr
obtained by the distillation of coal tar. It
consists primarily of aromatic hydrocarbons
and may contain appreciable quantities of
tar acids and tar bases. It distills at the
approximate range of 200 oC to 325 oC
(392 oF to 617 oF).]
648-100-00-9 Creosote oil, high-boiling distillate; 274-565-9 70321-79-8 Carc. 1B H350 GHS08 H350 H
Wash Oil; Dgr
648-102-00-X Extract residues (coal), creosote oil acid; 310-189-4 122384-77-4 Carc. 1B H350 GHS08 H350 H
Wash Oil Extract Residue; Dgr
[A complex combination of hydrocarbons
from the base-freed fraction from the
distillation of coal tar, boiling in the range of
approximately 250 oC to 280 oC (482 oF to
536 oF). It consists predominantly of
biphenyl and isomeric diphenylnaphtha-
lenes.]
648-103-00-5 Anthracene oil, anthracene paste; 292-603-2 90640-81-6 Carc. 1B H350 GHS08 H350 HJM
Anthracene Oil Fraction; Dgr
31.12.2008
[The anthracene-rich solid obtained by the
crystallization and centrifuging of anthra-
cene oil. It is composed primarily of
anthracene, carbazole and phenanthrene.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-104-00-0 Anthracene oil, anthracene-low; 292-604-8 90640-82-7 Carc. 1B H350 GHS08 H350 HJM
EN
Anthracene Oil Fraction; Dgr
[The oil remaining after the removal, by a
crystallization process, of an anthracene-rich
solid (anthracene paste) from anthracene oil.
It is composed primarily of two, three and
four membered aromatic compounds.]
648-105-00-6 Residues (coal tar), anthracene oil distn.; 295-505-8 92061-92-2 Carc. 1B H350 GHS08 H350 HJM
648-106-00-1 Anthracene oil, anthracene paste, anthracene 295-275-9 91995-15-2 Carc. 1B H350 GHS08 H350 HJM
fraction; Dgr
Anthracene Oil Fraction;
[A complex combination of hydrocarbons
from the distillation of anthracene obtained
by the crystallization of anthracene oil from
bituminous high temperature tar and boiling
in the range of 330 oC to 350 oC (626 oF to
662 oF). It contains chiefly anthracene,
carbazole and phenanthrene.]
648-107-00-7 Anthracene oil, anthracene paste, carbazole 295-276-4 91995-16-3 Carc. 1B H350 GHS08 H350 HJM
fraction; Dgr
Anthracene Oil Fraction;
[A complex combination of hydrocarbons
from the distillation of anthracene obtained
by crystallization of anthrancene oil from
bituminous coal high temperature tar and
boiling in the approximate range of 350 oC
to 360 oC (662 oF to 680 oF). It contains
L 353/761
chiefly anthacene, carbazole and phenan-
threne.]
L 353/762
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-108-00-2 Anthracene oil, anthracene paste, distn. 295-278-5 91995-17-4 Carc. 1B H350 GHS08 H350 HJM
EN
lights; Dgr
Anthracene Oil Fraction;
[A complex combination of hydrocarbons
from the distillation of anthracene obtained
by crystallization of anthracene oil from
bituminous light temperature tar and boiling
in the range of approximately 290 oC to
340 oC (554 oF to 644 oF). It contains
chiefly trinuclear aromatics and their dihy-
dro derivatives.]
648-110-00-3 Extract residues (coal), low temp. coal atar 310-191-5 122384-78-5 Carc. 1B H350 GHS08 H350 HJM
alk.; Dgr
[The residue from low temperature coal tar
oils after an alkaline wash, such as aqueous
sodium hydroxide, to remove crude coal tar
acids. Composed primarily of hydrocarbons
and aromatic nitrogen bases.]
648-111-00-9 Phenols, ammonia liquor ext.; 284-881-9 84988-93-2 Carc. 1B H350 GHS08 H350 HJM
Alkaline Extract; Dgr
[The combination of phenols extracted,
using isobutyl acetate, from the ammonia
liquor condensed from the gas evolved in
low-temperature (less than 700 oC
31.12.2008
(1292 oF)) destructive distillation of coal. It
consists predominantly of a mixture of
monohydric and dihydric phenols.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-112-00-4 Distillates (coal tar), light oils, alk. exts.; 292-610-0 90640-88-3 Carc. 1B H350 GHS08 H350 HJM
EN
Alkaline Extract; Dgr
[The aqueous extract from carbolic oil
produced by an alkaline wash such as
aqueous sodium hydroxide. Composed pri-
marily of the alkali salts of various phenolic
compounds.]
648-113-00-X Extracts, coal tar oil alk.; 266-017-2 65996-83-0 Carc. 1B H350 GHS08 H350 HJM
Alkaline Extract; Dgr
[The extract from coal tar oil produced by
648-114-00-5 Distillates (coal tar), naphthalene oils, alk. 292-611-6 90640-89-4 Carc. 1B H350 GHS08 H350 HJM
exts.; Dgr
Alkaline Extract;
[The aqueous extract from naphthalene oil
produced by an alkaline wash such as
aqueous sodium hydroxid. Composed pri-
marily of the alkali salts of various phenolic
compounds.]
648-115-00-0 Extract residues (coal), tar oil alk., carbo- 292-629-4 90641-06-8 Carc. 1B H350 GHS08 H350 HJM
nated, limed; Dgr
Crude Phenols;
[The product obtained by treatment of coal
tar oil alkaline extract with CO2 and CaO.
Composed primarily of CaCO3, Ca(OH)2,
Na2CO3 and other organic and inorganic
impurities.]
648-116-00-6 Tar acids, coal, crude; 266-019-3 65996-85-2 Carc. 1B H350 GHS08 H350 HJM
Crude Phenols; Dgr
[The reaction product obtained by neutra-
lizing coal tar oil alkaline extract with an
acidic solution, such as aqueous sulfuric
L 353/763
acid, or gaseous carbon dioxide, to obtain
the free acids. Composed primarily of tar
acids such as phenol, cresols, and xylenols.]
L 353/764
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-117-00-1 Tar acids, brown-coal, crude; 309-888-7 101316-86-3 Carc. 1B H350 GHS08 H350 HJM
EN
Crude Phenols; Dgr
[An acidified alkaline extract of brown coal
tar distillate. Composed primarily of phenol
and phenol homologs.]
648-118-00-7 Tar acids, brown-coal gasification; 295-536-7 92062-22-1 Carc. 1B H350 GHS08 H350 HJM
Crude Phenols; Dgr
[A complex combination of organic com-
pounds obtained from brown coal gasifica-
tion. Composed primarily of C6-10 hydroxy
aromatic phenols and their homologs.]
648-120-00-8 Tar acids, methylphenol fraction; 284-892-9 84989-04-8 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[The fraction of tar acid rich in 3- and 4-
methylphenol, recovered by distillation of
low-temperature coal tar crude tar acids.]
648-121-00-3 Tar acids, polyalkylphenol fraction; 284-893-4 84989-05-9 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[The fraction of tar aicds, recovered by
distillation of low-temperature coal tar crude
tar acids, having an approximate boiling
range of 225 oC to 320 oC (437 oF to
608 oF). Composed primarily of polyalk-
ylphenols.]
648-122-00-9 Tar acids, xylenol fraction; 284-895-5 84989-06-0 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
31.12.2008
[The fraction of tar acids, rich in 2,4- and
2,5-dimethylphenol, recovered by distilla-
tion of low-temperature coal tar crude tar
acids.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-123-00-4 Tar acids, ethylphenol fraction; 284-891-3 84989-03-7 Carc. 1B H350 GHS08 H350 HJM
EN
Distillate Phenols; Dgr
[The fraction of tar acids, rich in 3- and 4-
ethylphenol, recovered by distillation of
low-temperature coal tar crude tar acids.]
648-124-00-X Tar acids, 3,5-xylenol fraction; 284-896-0 84989-07-1 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[The fraction of tar acids, rich in 3,5-
dimethylphenol, recovered by distillation of
648-125-00-5 Tar acids, residues, distillates, first-cut; 270-713-1 68477-23-6 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[The residue from the distillation in the
range of 235 oC to 355 oC (481 oF to
697 oF) of light carbolic oil.]
648-126-00-0 Tar acids, cresylic, residues; 271-418-0 68555-24-8 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[The residue from crude coal tar acids after
removal of phenol, cresols, xylenols and any
higher boiling phenols. A black solid with a
melting point approximately 80 oC (176 oF).
Composed primarily of polyalkyphenols,
resin gums, and inorganic salts.]
648-127-00-6 Phenols, C9-11; 293-435-2 91079-47-9 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols Dgr
648-128-00-1 Tar acids, cresylic; 295-540-9 92062-26-5 Carc. 1B H350 GHS08 H350 HJM
Distillate Phenols; Dgr
[A complex combination of organic com-
pounds obtained from brown coal and
L 353/765
boiling in the range of approximately
200 oC to 230 oC (392 oF to 446 oF). It
contains chiefly phenols and pyridine bases.]
L 353/766
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-129-00-7 Tar acids, brown-coal, C2-alkylphenol frac- 302-662-9 94114-29-1 Carc. 1B H350 GHS08 H350 HJM
tion; Dgr
Distillate Phenols;
[The distillate from the acidification of
alkaline washed lignite tar distillate boiling
in the range of approximately 200 oC to
230 oC (392 oF to 446 oF). Composed
primarily of m- and p-ethylphenol as well as
cresols and xylenols.]
648-131-00-8 Tar bases, quinoline derivs.; 271-020-7 68513-87-1 Carc. 1B H350 GHS08 H350 HJM
Distillate Bases Dgr
648-132-00-3 Tar bases, coal, quinoline derivs. fraction; 274-560-1 70321-67-4 Carc. 1B H350 GHS08 H350 HJM
Distillate Bases Dgr
648-133-00-9 Tar bases, coal, distn. residues; 295-544-0 92062-29-8 Carc. 1B H350 GHS08 H350 HJM
Distillate Bases; Dgr
[The distillation residue remaining after the
distillation of the neutralized, acid-extracted
base-containing tar fractions obtained by the
31.12.2008
distillation of coal tars. It contains chiefly
aniline, collidines, quinoline and quinoline
derivatives and toluidines.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-134-00-4 Hydrocarbon oils, arom., mixed with poly- 309-745-9 100801-63-6 Carc. 1B H350 GHS08 H350 HJM
EN
ethylene and polypropylene, pyrolyzed, light Dgr
oil fraction;
Heat Treatment Products;
[The oil obtained from the heat treatment of
a polyethylene/polypropylene mixture with
coal tar pitch or aromatic oils. It consists
predominantly of benzene and its homologs
boiling in a range of approximately 70 oC to
120 oC (158 oF to 248 oF).]
648-136-00-5 Hydrocarbon oils, arom., mixed with poly- 309-749-0 100801-66-9 Carc. 1B H350 GHS08 H350 HJM
styrene, pyrolyzed, light oil fraction; Dgr
Heat Treatment Products;
[The oil obtained from the heat treatment of
polystyrene with coal tar pitch or aromatic
oils. It consists predominantly of benzene
and its homologs boiling in a range of
approximately 70 oC to 210 oC (158 oF to
410 oF).]
648-137-00-0 Extract residues (coal), tar oil alk., naphtha- 277-567-8 73665-18-6 Carc. 1B H350 GHS08 H350 HJM
lene distn. residues; Dgr
Naphthalene Oil Extract Residue;
[The residue obtained from chemical oil
extracted after the removal of naphthalene
by distillation composed primarily of two to
L 353/767
four membered condensed ring aromatic
hydrocarbons and aromatic nitrogen bases.]
L 353/768
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-138-00-6 Creosote oil, low-boiling distillate; 274-566-4 70321-80-1 Carc. 1B H350 GHS08 H350 H
EN
Wash Oil; Dgr
[The low-boiling distillation fraction
obtained from the high temperature carbo-
nization of bituminous coal, which is further
refined to remove excess crystalline salts. It
consists primarily of creosote oil with some
of the normal polynuclear aromatic salts,
which are components of coal tar distillate,
removed. It is crystal free at approximately
38 oC (100 oF).]
648-140-00-7 Extract oils (coal), tar base; 266-020-9 65996-86-3 Carc. 1B H350 GHS08 H350 HJM
Acid Extract; Dgr
[The extract from coal tar oil alkaline extract
residue produced by an acidic wash such as
aqueous sulfuric acid after distillatin to
remove naphthalene. Composed primarily
of the acid salts of various aromatic nitrogen
bases including pyridine, quinoline, and
their alkyl derivatives.]
648-141-00-2 Tar bases, coal, crude; 266-018-8 65996-84-1 Carc. 1B H350 GHS08 H350 HJM
Crude Tar Bases; Dgr
[The reaction product obtained by neutra-
lizing coal tar base extract oil with an
alkaline solution, such as aqueous sodium
hydroxide, to obtain the free bases. Com-
posed primarily of such organic bases as
acridine, phenanthridine, pyridine, quinoline
and their alkyl derivatives.]
648-142-00-8 Residues (coal), liq. solvent extn.; 302-681-2 94114-46-2 Carc. 1B H350 GHS08 H350 HM
[A cohesive powder composed of coal Dgr
31.12.2008
mineral matter and undissolved coal
remaining after extraction of coal by a liquid
solvent.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-143-00-3 Coal liquids, liq. solvent extn. soln.; 302-682-8 94114-47-3 Carc. 1B H350 GHS08 H350 HM
EN
[The product obtained by filtration of coal Dgr
mineral matter and undissolved coal from
coal extract solution produced by digesting
coal in a liquid solvent. A black, viscous,
highly complex liquid combination com-
posed primarily of aromatic and partly
hydro-genated aromatic hydrocarbons, aro-
matic nitrogen compounds, aromatic sulfur
compounds, phenolic and other aromatic
oxygen compounds and their alkyl deriva-
tives.]
648-146-00-X Tar, brown-coal, low-temp.; 309-886-6 101316-84-1 Carc. 1A H350 GHS08 H350 H
[A tar obtained from low temperature Dgr
carbonization and low temperature gasifi-
cation of brown coal. Composed primarily
L 353/769
of aliphatic, naphthenic and cyclic aromatic
hydrocarbons, heteroaromatic hydrocarbons
and cyclic phenols.]
L 353/770
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
648-147-00-5 Light oil (coal), coke-oven; 266-012-5 65996-78-3 Carc. 1B H350 GHS08 H350 HJ
Crude benzole; Dgr
[The volatile organic liquid extracted from
the gas evolved in the high temperature
(greater than 700 oC (1292 oF)) destructive
distillation of coal. Composed primarily of
benzene, toluene, and xylenes. May contain
other minor hydrocarbon constituents.]
648-149-00-6 Distillates (coal), solvent extn., hydrocracked; 302-689-6 94114-53-1 Carc. 1B H350 GHS08 H350 HJ
[Distillate obtained by hydrocracking of coal Dgr
extract or solution produced by the liquid
solvent extraction or supercritical gas
extraction process and boiling in the range
of approximately 30 oC to 300 oC (86 oF to
572 oF). Composed primarily of aromatic,
hydrogenated aromatic and naphthenic
compounds, their alkyl derivatives and
alkanes with carbon numbers predomi-
nantly in the range of C4 through C14.
Nitrogen, sulfur and oxygen-containing
31.12.2008
aromatic and hydrogenated aromatic com-
pounds are also present.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-150-00-1 Naphtha (coal), solvent extn., hydrocracked; 302-690-1 94114-54-2 Carc. 1B H350 GHS08 H350 HJ
EN
[Fraction of the distillate obtained by Dgr
hydrocracking of coal extract or solution
produced by the liquid solvent extraction or
supercritical gas extraction processes and
boiling in the range of approximately 30 oC
to 180 oC (86 oF to 356 oF). Composed
primarily of aromatic, hydrogenated aro-
matic and naphthenic compounds, their
alkyl derivatives and alkanes with carbon
numbers predominantly in the range of C4
to C9. Nitrogen, sulfur and oxygen-contain-
ing aromatic and hydrogenated aromatic
648-151-00-7 Gasoline, coal solvent extn., hydrocracked 302-691-7 94114-55-3 Carc. 1B H350 GHS08 H350 H
naphtha; Dgr
[Motor fuel produced by the reforming of
the refined naphtha fraction of the products
of hydrocracking of coal extract or solution
produced by the liquid solvent extraction or
supercritical gas extraction processes and
boiling in the range of approximately 30 oC
to 180 oC (86 oF to 356 oF). Composed
primarily of aromatic and naphthenic
hydrocarbons, their alkyl derivatives and
alkyl hydrocarbons having carbon numbers
in the range of C4 through C9.]
648-152-00-2 Distillates (coal), solvent extn., hydrocracked 302-692-2 94114-56-4 Carc. 1B H350 GHS08 H350 HJ
middle; Dgr
[Distillate obtained from the hydrocracking
of coal extract or solution produced by the
liquid solvent extraction or supercritical gas
extraction processes and boiling in the range
of approximately 180 oC to 300 oC (356 oF
to 572 oF). Composed primarily of two-ring
aromatic, hydrogenated aromatic and
naphthenic compounds, their alkyl deriva-
tives and alkanes having carbon numbers
L 353/771
predominantly in the range of C9 through
C14. Nitrogen, sulfur and oxygen-containing
compounds are also present.]
L 353/772
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-153-00-8 Distillates (coal), solvent extn., hydrocracked 302-693-8 94114-57-5 Carc. 1B H350 GHS08 H350 HJ
EN
hydrogenated middle; Dgr
[Distillate from the hydrogenation of
hydrocracked middle distillate from coal
extract or solution produced by the liquid
solvent extraction or supercritical gas
extraction processes and boiling in the range
of approximately 180 oC to 280 oC (356 oF
to 536 oF). Composed primarily of hydro-
genated two- ring carbon compounds and
their alkyl derivatives having carbon num-
bers predominantly in the range of C9
648-154-00-3 Fuels, jet aircraft, coal solvent extn., hydro- 302-694-3 94114-58-6 Carc. 2 H351 GHS08 H350 H
cracked hydrogenated; Wng
[Jet engine fuel produced by hydrogenation
of the middle distillate fraction of the
products of hydrocracking of coal extract or
solution produced by the liquid solvent
extraction or supercritical gas extraction
processes and boiling in the range of
approximately 180 oC to 225 oC (356 oF to
473 oF). Composed primarily of hydroge-
nated two-ring hydrocarbons and their alkyl
derivatives having carbon numbers predo-
minantly in the range of C10 through C12.]
648-155-00-9 Fuels, diesel, coal solvent extn., hydro- 302-695-9 94114-59-7 Carc. 2 H351 GHS08 H350 H
cracked hydrogenated; Wng
[Diesel engine fuel produced by the hydro-
genation of the middle distillate fraction of
the products of hydrocracking of coal
extract or solution produced by the liquid
solvent extraction or supercritical gas
extraction processes and boiling in the range
of approximately 200 oC to 280 oC (392 oF
to 536 oF). Composed primarily of hydro-
genated two-ring hydrocarbons and their
31.12.2008
alkyl derivatives having carbon numbers
predominantly in the range of C11 through
C14.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
648-156-00-4 Light oil (coal), semi-coking process; 292-635-7 90641-11-5 Carc. 1B H350 GHS08 H350 HJ
EN
Fresh oil; Dgr
[The volatile organic liquid condensed from
the gas evolved in the low temperature (less
than 700 oC (1292 oF) destructive distilla-
tion of coal. Composed primarily of C6-10
hydrocarbons.]
649-001-00-3 Extracts (petroleum), light naphthenic dis- 265-102-1 64742-03-6 Carc. 1B H350 GHS08 H350 H
tillate solvent Dgr
649-003-00-4 Extracts (petroleum), light paraffinic distil- 265-104-2 64742-05-8 Carc. 1B H350 GHS08 H350 H
late solvent Dgr
649-004-00-X Extracts (petroleum), heavy naphthenic dis- 265-111-0 64742-11-6 Carc. 1B H350 GHS08 H350 H
tillate solvent Dgr
649-005-00-5 Extracts (petroleum), light vacuum gas oil 295-341-7 91995-78-7 Carc. 1B H350 GHS08 H350 H
solvent Dgr
649-006-00-0 hydrocarbons C26-55, arom-rich 307-753-7 97722-04-8 Carc. 1B H350 GHS08 H350 H
Dgr
649-007-00-6 fatty acids, tall-oil, reaction products with 400-160-5 — Skin Irrit. 2 H315 GHS07 H315
iminodiethanol and boric acid Aquatic H411 GHS09 H411
Chronic 2 Wng
649-008-00-1 Residues (petroleum), atm. tower; 265-045-2 64741-45-3 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex residuum from the atmospheric
distillation of crude oil. It consists of
hydrocarbons having carbon numbers pre-
dominantly greater than C20 and boiling
above approximately 350 oC (662 oF). This
L 353/773
stream is likely to contain 5 wt. % or more
of 4- to 6-membered condensed ring
aromatic hydrocarbons.]
L 353/774
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-009-00-7 Gas oils (petroleum), heavy vacuum; 265-058-3 64741-57-7 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
produced by the vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C20 through C50 and boiling in the range
of approximately 350 oC to 600 oC (662 oF
to 1112 oF). This stream is likely to contain
5 wt. % or more of 4-to 6-membered
condensed ring aromatic hydrocarbons.]
649-011-00-8 Clarified oils (petroleum), catalytic cracked; 265-064-6 64741-62-4 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
produced as the residual fraction from
distillation of the products from a catalytic
cracking process. It consists of hydrocarbons
having carbon numbers predominantly
greater than C20 and boiling above
approximately 350 oC (662 oF). This stream
is likely to contain 5 wt. % or more of 4- to
31.12.2008
6-membered condensed ring aromatic
hydrocarbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-012-00-3 Residues (petroleum), hydrocracked; 265-076-1 64741-75-9 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
produced as the residual fraction from
distillation of the products of a hydrocrack-
ing process. It consists of hydrocarbons
having carbon numbers predominantly
greater than C20 and boiling above
approximately 350 oC (662 oF).]
649-014-00-4 Distillates (petroleum), heavy thermal 265-082-4 64741-81-7 Carc. 1B H350 GHS08 H350 H
cracked; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
from the distillation of the products from a
thermal cracking process. It consists pre-
dominantly of unsaturated hydrocarbons
having carbon numbers predominantly in
the range of C15 through C36 and boiling in
the range of approximately 260 oC to
480 oC (500 oF to 896 oF). This stream is
likely to contain 5 wt. % or more of 4- to 6-
L 353/775
membered condensed ring aromatic hydro-
carbons.]
L 353/776
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-015-00-X Gas oils (petroleum), hydrotreated vacuum; 265-162-9 64742-59-2 Carc. 1B H350 GHS08 H350 H
EN
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C13
through C50 and boiling in the range of
approximately 230 oC to 600 oC (446 oF to
1112 oF). This stream is likely to contain
5 wt.% or more of 4- to 6-membered
condensed ring aromatic hydrocarbons.]
649-017-00-0 Gas oils (petroleum), hydrodesulfurized 265-189-6 64742-86-5 Carc. 1B H350 GHS08 H350 H
heavy vacuum; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained from a catalytic hydrodesulfuriza-
tion process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50 and boiling in
the range of approximately 350 oC to
600 oC (662 oF to 1112 oC). This stream is
31.12.2008
likely to contain 5 wt. % or more of 4- to 6-
membered condensed ring aromatic hydro-
carbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-018-00-6 Residues (petroleum), steam-cracked; 265-193-8 64742-90-1 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
obtained as the residual fraction from the
distillation of the products of a steam
cracking process (including steam cracking
to produce ethylene). It consists predomi-
nantly of unsaturated hydrocarbons having
carbon numbers predominantly greater than
C14 and boiling above approximately 260 oC
(500 oF). This stream is likely to contain
5 wt. % or more of 4- to 6-membered
649-019-00-1 Residues (petroleum), atmospheric; 269-777-3 68333-22-2 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex residuum from atmospheric
distillation of crude oil. It consists of
hydrocarbons having carbon numbers pre-
dominantly greater than C11 and boiling
above approximately 200 oC (392 oF). This
stream is likely to contain 5 wt. % or more
of 4-to 6-membered condensed ring aro-
matic hydrocarbons.]
649-020-00-7 Clarified oils (petroleum), hydrodesulfurized 269-782-0 68333-26-6 Carc. 1B H350 GHS08 H350 H
catalytic cracked; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained by treating catalytic cracked clar-
ified oil with hydrogen to convert organic
sulfur to hydrogen sulfide which is removed.
It consists of hydrocarbons having carbon
numbers predominantly greater than C20
and boiling above approximately 350 oC
(662 oF). This stream is likely to contain
L 353/777
5 wt. % or more of 4-to 6-membered
condensed ring aromatic hydrocarbons.]
L 353/778
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-021-00-2 Distillates (petroleum), hydrodesulfurized 269-783-6 68333-27-7 Carc. 1B H350 GHS08 H350 H
EN
intermediate catalytic cracked; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained by treating intermediate catalytic
cracked distillates with hydrogen to convert
organic sulfur to hydrogen sulfide which is
removed. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C11 through C30 and boiling in the range
of approximately 205 oC to 450 oC (401 oF
to 842 oF). It contains a relatively large
649-022-00-8 Distillates (petroleum), hydrodesulfurized 269-784-1 68333-28-8 Carc. 1B H350 GHS08 H350 H
heavy catalytic cracked; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained by treatment of heavy catalytic
cracked distillates with hydrogen to convert
organic sulfur to hydrogen sulfide which is
removed. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C15 through C35 and boiling in the range
of approximately 260 oC to 500 oC (500 oF
to 932 oF). This stream is likely to contain
5 wt. % or more of 4- to 6-membered
condensed ring aromatic hydrocarbons.]
649-023-00-3 Fuel oil, residues-straight-run gas oils, high- 270-674-0 68476-32-4 Carc. 1B H350 GHS08 H350 H
sulfur; Dgr
Heavy Fuel oil
649-024-00-9 Fuel oil, residual; 270-675-6 68476-33-5 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[The liquid product from various refinery
31.12.2008
streams, usually residues. The composition is
complex and varies with the source of the
crude oil.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-025-00-4 Residues (petroleum), catalytic reformer 270-792-2 68478-13-7 Carc. 1B H350 GHS08 H350 H
EN
fractionator residue distn.; Dgr
Heavy Fuel oil;
[A complex residuum from the distillation of
catalytic reformer fractionator residue. It
boils approximately above 399 oC (750 oF).]
649-026-00-X Residues (petroleum), heavy coker gas oil 270-796-4 68478-17-1 Carc. 1B H350 GHS08 H350 H
and vacuum gas oil; Dgr
649-027-00-5 Residues (petroleum), heavy coker and light 270-983-0 68512-61-8 Carc. 1B H350 GHS08 H350 H
vacuum; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
produced as the residual fraction from the
distillation of heavy coker gas oil and light
vacuum gas oil. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly greater than C13 and boiling
above approximately 230 oC (446 oF).]
649-028-00-0 Residues (petroleum), light vacuum; 270-984-6 68512-62-9 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex residuum from the vacuum
distillation of the residuum from the
atmospheric distillation of crude oil. It
consists of hydrocarbons having carbon
numbers predominantly greater than C13
L 353/779
and boiling above approximately 230 oC
(446 oF).]
L 353/780
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-029-00-6 Residues (petroleum), steam-cracked light; 271-013-9 68513-69-9 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex residuum from the distillation of
the products from a steam-cracking process.
It consists predominantly of aromatic and
unsaturated hydrocarbons having carbon
numbers greater than C7 and boiling in the
range of approximately 101 oC to 555 oC
(214 oF to 1030 oF).]
649-031-00-7 Residues (petroleum), topping plant, low- 271-763-7 68607-30-7 Carc. 1B H350 GHS08 H350 H
sulfur; Dgr
Heavy Fuel oil;
[A low-sulfur complex combination of
hydrocarbons produced as the residual
fraction from the topping plant distillation
of crude oil. It is the residuum after the
straight-run gasoline cut, kerosene cut and
gas oil cut have been removed.]
649-032-00-2 Gas oils (petroleum), heavy atmospheric; 272-184-2 68783-08-4 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
obtained by the distillation of crude oil. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C7
through C35 and boiling in the range of
31.12.2008
approximately 121 oC to 510 oC (250 oF to
950 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-033-00-8 Residues (petroleum), coker scrubber, Con- 272-187-9 68783-13-1 Carc. 1B H350 GHS08 H350 H
EN
densed-ring-arom.-contg.; Dgr
Heavy Fuel oil;
[A very complex combination of hydrocar-
bons produced as the residual fraction from
the distillation of vaccum residuum and the
products from a thermal cracking process. It
consists predominantly of hydrocarbons
having carbon numbers predominantly
greater than C20 and boiling above
approximately 350 oC (662 oF). This stream
is likely to contain 5 wt.% or more of 4- to
6-membered condensed rind aromatic
649-034-00-3 Distillates (petroleum), petroleum residues 273-263-4 68955-27-1 Carc. 1B H350 GHS08 H350 H
vacuum; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
produced by the vacuum distillation of the
residuum from the atmospheric distillation
of crude oil.]
649-035-00-9 Residues (petroleum), steam-cracked, resi- 273-272-3 68955-36-2 Carc. 1B H350 GHS08 H350 H
nous; Dgr
Heavy Fuel oil;
[A complex residuum from the distillation of
steam-cracked petroleum residues.]
649-036-00-4 Distillates (petroleum), intermediate 274-683-0 70592-76-6 Carc. 1B H350 GHS08 H350 H
vacuum; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
produced by the vacuum, distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C14 through C42 and boiling in the range
of approximately 250 oC to 545 oC (482 oF
L 353/781
to 1013 oF). This stream is likely to contain
5 wt. % or more of 4- to 6-membered
condensed ring aromatic hydrocarbons.]
L 353/782
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-037-00-X Distillates (petroleum), light vacuum; 274-684-6 70592-77-7 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
produced by the vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C11 through C35 and boiling in the range
of approximately 250 oC to 545 oC (482 oF
to 1013 oF).]
649-039-00-0 Gas oils (petroleum), hydrodesulfurized 285-555-9 85117-03-9 Carc. 1B H350 GHS08 H350 H
coker heavy vacuum; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained by hydrodesulfurization of heavy
coker distillate stocks, It consists predomi-
nantly of hydrocarbons having carbon
numbers predominantly in the range C18 to
C44 and boiling in the range of approxi-
mately 304 oC to 548 oC (579 oF to
1018 oF). Likely to contain 5 % or more of
31.12.2008
4- to 6-membered condensed ring aromatic
hydrocarbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-040-00-6 Residues (petroleum), steam-cracked, distil- 292-657-7 90669-75-3 Carc. 1B H350 GHS08 H350 H
EN
lates; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained during the production of refined
petroleum tar by the distillation of steam
cracked tar. It consists predominantly of
aromatic and other hydrocarbons and
organic sulfur compounds.]
649-042-00-7 Fuel oil, heavy, high-sulfur; 295-396-7 92045-14-2 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
obtained by the distillation of crude petro-
leum. It consists predominantly of aliphatic,
aromatic and cycloaliphatic hydrocarbons
having carbon numbers predominantly
higher than C25 and boiling above approxi-
mately 400 oC (752 oF).]
649-043-00-2 Residues (petroleum), catalytic cracking; 295-511-0 92061-97-7 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
produced as the residual fraction from the
distillation of the products from a catalytic
cracking process. It consists predominantly
L 353/783
of hydrocarbons having carbon numbers
predominantly greater than C11 and boiling
above approximately 200 oC (392 oF).]
L 353/784
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-044-00-8 Distillates (petroleum), intermediate catalytic 295-990-6 92201-59-7 Carc. 1B H350 GHS08 H350 H
EN
cracked, thermally degraded; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
produced by the distillation of products
from a catalytic cracking process which has
been used as a heat transfer fluid. It consists
predominantly of hydrocarbons boiling in
the range of approximately 220 oC to
450 oC (428 oF to 842 oF). This stream is
likely to contain organic sulfur compounds.]
649-046-00-9 Residues, steam cracked, thermally treated; 308-733-0 98219-64-8 Carc. 1B H350 GHS08 H350 H
Heavy Fuel oil; Dgr
[A complex combination of hydrocarbons
obtained by the treatment and distillation of
raw steam-cracked naphtha. It consists
predominantly of unsaturated hydrocarbons
boiling in the range above approximately
180 oC (356 oF).]
649-047-00-4 Distillates (petroleum), hydrodesulfurized 309-863-0 101316-57-8 Carc. 1B H350 GHS08 H350 H
full-range middle; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
obtained by treating a petroleum stock with
hydrogen. It consists predominantly of
hydrocarbons having carbon numbers pre-
31.12.2008
dominantly in the range of C9 through C25
and boiling in the range of approximately
150 oC to 400 oC (302 oF to 752 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-048-00-X Residues (petroleum), catalytic reformer 265-069-3 64741-67-9 Carc. 1B H350 GHS08 H350 H
EN
fractionator; Dgr
Heavy Fuel oil;
[A complex combination of hydrocarbons
produced as the residual fraction from
distillation of the product from a catalytic
reforming process. It consists of predomi-
nantly aromatic hydrocarbons having car-
bon numbers predominantly in the range of
C10 through C25 and boiling in the range of
approximately 160 oC to 400 oC (320 oF to
725 oF). This stream is likely to contain
5 wt. % or more of 4- or 6-membered
649-050-00-0 Distillates (petroleum), light paraffinic; 265-051-5 64741-50-0 Carc. 1A H350 GHS08 H350 H
Unrefined or mildly refined baseoil; Dgr
[A complex combination of hydrocarbons
produced by vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C15 through C30 and produces a finished
oil with a viscosity of less than 100 SUS at
100 oF (19cSt at 40 oC). It contains a
L 353/785
relatively large proportion of saturated
aliphatic hydrocarbons normally present in
this distillation range of crude oil.]
L 353/786
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-051-00-6 Distillates (petroleum), heavy paraffinic; 265-052-0 64741-51-1 Carc. 1A H350 GHS08 H350 H
Unrefined or mildly refined baseoil; Dgr
[A complex combination of hydrocarbons
produced by vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C20 through C50 and produces a finished
oil with a viscosity of at least 100 SUS at
100 oF (19cSt at 40 oC). It contains a
relatively large proportion of saturated
649-052-00-1 Distillates (petroleum), light naphthenic; 265-053-6 64741-52-2 Carc. 1A H350 GHS08 H350 H
Unrefined or mildly refined baseoil; Dgr
[A complex combination of hydrocarbons
produced by vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C15 through C30 and produces a finished
oil with a viscosity of less than 100 SUS at
100 oF (19cSt at 40 oC). It contains relatively
few normal paraffins.]
649-053-00-7 Distillates (petroleum), heavy naphthenic; 265-054-1 64741-53-3 Carc. 1A H350 GHS08 H350 H
Unrefined or mildly refined baseoil; Dgr
[A complex combination of hydrocarbons
produced by vacuum distillation of the
residuum from atmospheric distillation of
crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range
of C20 through C50 and produces a finished
oil with a viscosity of at least 100 SUS at
31.12.2008
100 oF (19cSt at 40 oC). It contains relatively
few normal paraffins.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-054-00-2 Distillates (petroleum), acid-treated heavy 265-117-3 64742-18-3 Carc. 1A H350 GHS08 H350 H
naphthenic; Dgr
Unrefined or mildly refined baseoil;
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
treating process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50 and produces a
finished oil with a viscosity of at least
100 SUS at 100 oF (19cSt at 40 oC). It con-
tains relatively few normal paraffins.]
649-056-00-3 Distillates (petroleum), acid-treated heavy 265-119-4 64742-20-7 Carc. 1A H350 GHS08 H350 H
paraffinic; Dgr
Unrefined or mildly refined baseoil;
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
process. It consists predominantly of satu-
rated hydrocarbons having carbon numbers
predominantly in the range of C20 through
C50 and produces a finished oil having a
viscosity of a least 100 SUS at 100 oF (19cSt
L 353/787
at 40 oC).]
L 353/788
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-057-00-9 Distillates (petroleum), acid-treated light 265-121-5 64742-21-8 Carc. 1A H350 GHS08 H350 H
paraffinic; Dgr
Unrefined or mildly refined baseoil;
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
treating process. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil
having a viscosity of less than 100 SUS at
100 oF (19cSt at 40 oC).]
649-059-00-X Distillates (petroleum), chemically neutra- 265-128-3 64742-28-5 Carc. 1A H350 GHS08 H350 H
lized light paraffinic; Dgr
Unrefined or mildly refined baseoil;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C15 through C30 and produces a
31.12.2008
finished oil with a viscosity less than
100 SUS at 100 oF (19cSt at 40 oC).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-060-00-5 Distillates (petroleum), chemically neutra- 265-135-1 64742-34-3 Carc. 1A H350 GHS08 H350 H
EN
lized heavy naphthenic; Dgr
Unrefined or mildly refined baseoil;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50 and produces a
finished oil with a viscosity of at least
100 SUS at 100 oF (19cSt at 40 oC). It con-
tains relatively few normal paraffins.]
649-062-00-6 Gases (petroleum), catalytic cracked naphtha 270-755-0 68477-73-6 Flam. Gas 1 H220 GHS02 H220 HKU
depropanizer overhead, C3-rich acid-free; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from fractionation of catalytic
cracked hydrocarbons and treated to remove
acidic impurities. It consists of hydrocarbons
having carbon numbers in the range of C2
through C4, predominantly C3.]
649-063-00-1 Gases (petroleum), catalytic cracker; 270-756-6 68477-74-7 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the distillation of the products Muta. 1B Dgr
from a catalytic cracking process. It consists
L 353/789
predominantly of aliphatic hydrocarbons
having carbon numbers predominantly in
the range of C1 through C6.]
L 353/790
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-064-00-7 Gases (petroleum), catalytic cracker, C1-5- 270-757-1 68477-75-8 Flam. Gas 1 H220 GHS02 H220 HKU
EN
rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the distillation of products
from a catalytic cracking process. It consists
of aliphatic hydrocarbons having carbon
numbers in the range of C1 through C6,
predominantly C1 through C5.]
649-066-00-8 Gases (petroleum), catalytic reformer, C1-4- 270-760-8 68477-79-2 Flam. Gas 1 H220 GHS02 H220 HKU
rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by distillation of products from a
catalytic reforming process. It consists of
hydrocarbons having carbon numbers in the
range of C1 through C6, predominantly C1
through C4.]
649-067-00-3 Gases (petroleum), C3-5 olefinic-paraffinic 270-765-5 68477-83-8 Flam. Gas 1 H220 GHS02 H220 HKU
alkylation feed; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of olefinic and Muta. 1B Dgr
paraffinic hydrocarbons having carbon
numbers in the range of C3 through C5
31.12.2008
which are used as alkylation feed. Ambient
temperatures normally exceed the critical
temperature of these combinations.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-068-00-9 Gases (petroleum), C4-rich; 270-767-6 68477-85-0 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by distillation of products from a Muta. 1B Dgr
catalytic fractionation process. It consists of
aliphatic hydrocarbons having carbon
numbers in the range of C3 through C5,
predominantly C4.]
649-070-00-X Gases (petroleum), deisobutanizer tower 270-769-7 68477-87-2 Flam. Gas 1 H220 GHS02 H220 HKU
overheads; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the atmospheric distillation of a
butane-butylene stream. It consists of ali-
phatic hydrocarbons having carbon num-
bers predominantly in the range of C3
through C4.]
649-071-00-5 Gases (petroleum), depropanizer dry, pro- 270-772-3 68477-90-7 Flam. Gas 1 H220 GHS02 H220 HKU
pene-rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the distillation of products
from the gas and gasoline fractions of a
catalytic cracking process. It consists pre-
L 353/791
dominantly of propylene with some ethane
and propane.]
L 353/792
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-072-00-0 Gases (petroleum), depropanizer overheads; 270-773-9 68477-91-8 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by distillation of products from Muta. 1B Dgr
the gas and gasoline fractions of a catalytic
cracking process. It consists of aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C2 through C4.]
649-074-00-1 Gases (petroleum), Girbatol unit feed; 270-778-6 68477-95-2 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
that is used as the feed into the Girbatol unit Muta. 1B Dgr
to remove hydrogen sulfide. It consists of
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C2
through C4.]
649-075-00-7 Gases (petroleum), isomerized naphtha 270-782-8 68477-99-6 Flam. Gas 1 H220 GHS02 H220 HKU
fractionator, C4-rich, hydrogen sulfide-free; Press. Gas H350 GHS04 H350
31.12.2008
Petroleum gas Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-076-00-2 Tail gas (petroleum), catalytic cracked clar- 270-802-5 68478-21-7 Flam. Gas 1 H220 GHS02 H220 HKU
EN
ified oil and thermal cracked vacuum residue Press. Gas H350 GHS04 H350
fractionation reflux drum; Carc. 1A H340 GHS08 H340
Petroleum gas; Muta. 1B Dgr
[A complex combination of hydrocarbons
obtained from fractionation of catalytic
cracked clarified oil and thermal cracked
vacuum residue. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C6.]
649-078-00-3 Tail gas (petroleum), catalytic cracker, cata- 270-804-6 68478-24-0 Flam. Gas 1 H220 GHS02 H220 HKU
lytic reformer and hydrodesulfurizer com- Press. Gas H350 GHS04 H350
bined fractionater; Carc. 1A H340 GHS08 H340
Petroleum gas; Muta. 1B Dgr
[A complex combination of hydrocarbons
obtained from the fractionation of products
from catalytic cracking, catalytic reforming
and hydrodesulfurizing processes treated to
remove acidic impurities. It consists pre-
dominantly of hydrocarbons having cabon
numbers predominantly in the range of C1
through C5.]
649-079-00-9 Tail gas (petroleum), catalytic reformed 270-806-7 68478-26-2 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha fractionation stabilizer; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the fractionation stabilization
of catalytic reformed naphtha. It consists
L 353/793
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C1 through C4.]
L 353/794
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-080-00-4 Tail gas (petroleum), saturate gas plant 270-813-5 68478-32-0 Flam. Gas 1 H220 GHS02 H220 HKU
EN
mixed stream, C4-rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the fractionation stabilization
of straight-run naphtha, distillation tail gas
and catalytic reformed naphtha stabilizer tail
gas. It consists of hydrocarbons having
carbon numbers in the range of C3 through
C6, predominantly butane and isobutane.]
649-082-00-5 Tail gas (petroleum), vacuum residues ther- 270-815-6 68478-34-2 Flam. Gas 1 H220 GHS02 H220 HKU
mal cracker; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the thermal cracking of
vacuum residues. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C1 through C5.]
649-083-00-0 Hydrocarbons, C3-4-rich, petroleum distil- 270-990-9 68512-91-4 Flam. Gas 1 H220 GHS02 H220 HKU
late; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by distillation and condensation of
31.12.2008
crude oil. It consists of hydrocarbons having
carbon numbers in the range of C3 through
C5, predominantly C3 through C4.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-084-00-6 Gases (petroleum), full-range straight-run 271-000-8 68513-15-5 Flam. Gas 1 H220 GHS02 H220 HKU
EN
naphtha dehexanizer off; Press. Gas H350 GHS04 H350
petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the fractionation of the full-
range straight-run naphtha. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C2 through C6.]
649-085-00-1 Gases (petroleum), hydrocracking depropa- 271-001-3 68513-16-6 Flam. Gas 1 H220 GHS02 H220 HKU
649-086-00-7 Gases (petroleum), light straight-run 271-002-9 68513-17-7 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha stabilizer off; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the stabilization of light
straight-run naphtha. It consists of saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C2
through C6.]
649-087-00-2 Residues (petroleum), alkylation splitter, C4- 271-010-2 68513-66-6 Flam. Gas 1 H220 GHS02 H220 HKU
rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex residuum from the distillation of Muta. 1B Dgr
streams various refinery operations. It con-
sists of hydrocarbons having carbon num-
bers in the range of C4 through C5,
L 353/795
predominantly butane and boiling in the
range of approximately - 11.7 oC to 27.8 oC
(11 oF to 82 oF).]
L 353/796
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-088-00-8 Hydrocarbons, C1-4; 271-032-2 68514-31-8 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
provided by thermal cracking and absorber Muta. 1B Dgr
operations and by distillation of crude oil. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C1
through C4 and boiling in the range of
approximately minus 164 oC to minus
0.5 oC (- 263 oF to 31 oF).]
649-090-00-9 Hydrocarbons, C1-3; 271-259-7 68527-16-2 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
having carbon numbers predominantly in Muta. 1B Dgr
the range of C1 through C3 and boiling in
the range of approximately minus 164 oC to
minus 42 oC (- 263 oF to - 44 oF).]
649-091-00-4 Hydrocarbons, C1-4, debutanizer fraction; 271-261-8 68527-19-5 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-092-00-X Gases (petroleum), C1-5, wet; 271-624-0 68602-83-5 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
31.12.2008
produced by the distillation of crude oil and/ Muta. 1B Dgr
or the cracking of tower gas oil. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C5.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-093-00-5 Hydrocarbons, C2-4; 271-734-9 68606-25-7 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-094-00-0 Hydrocarbons, C3; 271-735-4 68606-26-8 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
649-095-00-6 Gases (petroleum), alkylation feed; 271-737-5 68606-27-9 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the catalytic cracking of gas oil. Muta. 1B Dgr
It consists of hydrocarbons having carbon
numbers predominantly in the range of C3
through C4.]
649-096-00-1 Gases (petroleum), depropanizer bottoms 271-742-2 68606-34-8 Flam. Gas 1 H220 GHS02 H220 HKU
fractionation off; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the fractionation of depro-
panizer bottoms. It consists predominantly
of butane, isobutane and butadiene.]
649-097-00-7 Gases (petroleum), refinery blend; 272-183-7 68783-07-3 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination obtained from Carc. 1A H340 GHS08 H340
various processes. It consists of hydrogen, Muta. 1B Dgr
hydrogen sulfide and hydrocarbons having
L 353/797
carbon numbers predominantly in the range
of C1 through C5.]
L 353/798
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-098-00-2 Gases (petroleum), catalytic cracking; 272-203-4 68783-64-2 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the distillation of the products Muta. 1B Dgr
from a catalytic cracking process. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C3 through C5.]
649-099-00-8 Gases (petroleum), C2-4, sweetened; 272-205-5 68783-65-3 Flam. Gas 1 H220 GHS02 H220 HKU
649-100-00-1 Gases (petroleum), crude oil fractionation 272-871-7 68918-99-0 Flam. Gas 1 H220 GHS02 H220 HKU
off; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the fractionation of crude oil. It
consists of saturated aliphatic hydrocarbons
having carbon numbers predominantly in
the range of C1 through C5.]
649-101-00-7 Gases (petroleum), dehexanizer off; 272-872-2 68919-00-6 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
obtained by the fractionation of combined Muta. 1B Dgr
naphtha streams. It consists of saturated
31.12.2008
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C1
through C5.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-102-00-2 Gases (petroleum), light straight run gasoline 272-878-5 68919-05-1 Flam. Gas 1 H220 GHS02 H220 HKU
EN
fractionation stabilizer off; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the fractionation of light
straight-run gasoline. It consists of saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C1
through C5.]
649-104-00-3 Gases (petroleum), straight-run naphtha 272-882-7 68919-09-5 Flam. Gas 1 H220 GHS02 H220 HKU
catalytic reforming off; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the catalytic reforming of
straight-run naphtha and fractionation of
the total effluent. It consists of methane,
ethane, and propane.]
649-105-00-9 Gases (petroleum), fluidized catalytic cracker 272-893-7 68919-20-0 Flam. Gas 1 H220 GHS02 H220 HKU
splitter overheads; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the fractionation of the charge
L 353/799
to the C3 -C4 splitter. It consists predomi-
nantly of C3 hydrocarbons.]
L 353/800
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-106-00-4 Gases (petroleum), straight-run stabilizer off; 272-883-2 68919-10-8 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
obtained from the fractionation of the liquid Muta. 1B Dgr
from the first tower used in the distillation
of crude oil. It consists of saturated aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C4.]
649-108-00-5 Tail gas (petroleum), catalytic cracked dis- 273-170-9 68952-77-2 Flam. Gas 1 H220 GHS02 H220 HKU
tillate and naphtha stabilizer; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the fractionation of catalytic
cracked naphtha and distillate. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C1 through C4.]
649-109-00-0 Tail gas (petroleum), thermal-cracked dis- 273-175-6 68952-81-8 Flam. Gas 1 H220 GHS02 H220 HKU
tillate, gas oil and naphtha absorber; Press. Gas H350 GHS04 H350
petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the separation of thermal-
cracked distillates, naphtha and gas oil. It
31.12.2008
consists pedrominantly of hydrocarbons
having carbon numbers predominantly in
the range of C1 through C6.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-110-00-6 Tail gas (petroleum), thermal cracked 273-176-1 68952-82-9 Flam. Gas 1 H220 GHS02 H220 HKU
EN
hydrocarbon fractionation stabilizer, petro- Press. Gas H350 GHS04 H350
leum coking; Carc. 1A H340 GHS08 H340
Petroleum gas; Muta. 1B Dgr
[A complex combination of hydrocarbons
obtained from the fractionation stabilization
of thermal cracked hydrocarbons from
petroleum coking process. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C6.]
649-112-00-7 Gases (petroleum), straight-run naphtha 273-270-2 68955-34-0 Flam. Gas 1 H220 GHS02 H220 HKU
catalytic reformer stabilizer overhead; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by the catalytic reforming of
straight-run naphtha and the fractionation
of the total effluent. It consists of saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C2
through C4.]
649-113-00-2 Hydrocarbons, C4; 289-339-5 87741-01-3 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-114-00-8 Alkanes, C1-4, C3-rich; 292-456-4 90622-55-2 Flam. Gas 1 H220 GHS02 H220 HKU
L 353/801
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
L 353/802
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-115-00-3 Gases (petroleum), steam-cracker C3-rich; 295-404-9 92045-22-2 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the distillation of products Muta. 1B Dgr
from a steam cracking process. It consists
predominantly of propylene with some
propane and boils in the range of approxi-
mately - 70 oC to 0 oC (- 94 oF to 32 oF).]
649-116-00-9 Hydrocarbons, C4, steam-cracker distillate; 295-405-4 92045-23-3 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
649-117-00-4 Petroleum gases, liquefied, sweetened, C4 295-463-0 92045-80-2 Flam. Gas 1 H220 GHS02 H220 HKSU
fraction; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by subjecting a liquified petroleum
gas mix to a sweetening process to oxidize
mercaptans or to remove acidic impurities.
It consists predominantly of C4 saturated
and unsaturated hydrocarbons.]
649-118-00-X Hydrocarbons, C4, 1,3-butadiene- and iso- 306-004-1 95465-89-7 Flam. Gas 1 H220 GHS02 H220 HKU
butene-free; Press. Gas H350 GHS04 H350
Petroleum gas Carc. 1B GHS08
Dgr
649-119-00-5 Raffinates (petroleum), steam-cracked C4 307-769-4 97722-19-5 Flam. Gas 1 H220 GHS02 H220 HKU
31.12.2008
fraction cuprous ammonium acetate extn., Press. Gas H350 GHS04 H350
C3-5 and C3-5 unsatd., butadiene-free; Carc. 1A H340 GHS08 H340
Petroleum gas Muta. 1B Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-120-00-0 Gases (petroleum), amine system feed; 270-746-1 68477-65-6 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Refinery gas; Press. Gas H350 GHS04 H350
[The feed gas to the amine system for Carc. 1A H340 GHS08 H340
removal of hydrogen sulfide. It consists of Muta. 1B Dgr
hydrogen. Carbon monoxide, carbon diox-
ide, hydrogen sulfide and aliphatic hydro-
carbons having carbon numbers
predominantly in the range of C1 through C5
may also be present.]
649-122-00-1 Gases (petroleum), benzene unit recycle, 270-748-2 68477-67-8 Flam. Gas 1 H220 GHS02 H220 HKU
hydrogen-rich; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by recycling the gases of the
benzene unit. It consists primarily of
hydrogen with various small amounts of
carbon monoxide and hydrocarbons having
carbon numbers in the range of C1 through
C6.]
649-123-00-7 Gases (petroleum), blend oil, hydrogen- 270-749-8 68477-68-9 Flam. Gas 1 H220 GHS02 H220 HKU
nitrogen-rich; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by distillation of a blend oil. It
consists primarily of hydrogen and nitrogen
with various small amounts of carbon
L 353/803
monoxide, carbon dioxide, and aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C5.]
L 353/804
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-124-00-2 Gases (petroleum), catalytic reformed 270-759-2 68477-77-0 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha stripper overheads; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from stabilization of catalytic
reformed naphtha. Its consists of hydrogen
and saturated hydrocarbons having carbon
numbers predominantly in the range of C1
through C4.]
649-126-00-3 Gases (petroleum), C6-8 catalytic reformer; 270-762-9 68477-81-6 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by distillation of products from Muta. 1B Dgr
catalytic reforming of C6-C8feed. It consists
of hydrocarbons having carbon numbers in
the range of C1 through C5 and hydrogen.]
649-127-00-9 Gases (petroleum), C6-8 catalytic reformer 270-763-4 68477-82-7 Flam. Gas 1 H220 GHS02 H220 HKU
recycle, hydrogen-rich; Press. Gas H350 GHS04 H350
31.12.2008
Refinery gas Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-128-00-4 Gases (petroleum), C2-return stream; 270-766-0 68477-84-9 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
obtained by the extraction of hydrogen from Muta. 1B Dgr
a gas stream which consists primarily of
hydrogen with small amounts of nitrogen,
carbon monoxide, methane, ethane, and
ethylene. It contains predominantly hydro-
carbons such as methane, ethane, and
ethylene with small amounts of hydrogen,
nitrogen and carbon monoxide.]
649-130-00-5 Gases (petroleum), gas concn. reabsorber 270-776-5 68477-93-0 Flam. Gas 1 H220 GHS02 H220 HKU
distn.; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by distillation of products from
combined gas streams in a gas concentration
reabsorber. It consists predominantly of
hydrogen, carbon monoxide, carbon diox-
ide, nitrogen, hydrogen sulfide and hydro-
carbons having carbon numbers in the range
of C1 through C3.]
649-131-00-0 Gases (petroleum), hydrogen absorber off; 270-779-1 68477-96-3 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination obtained by Carc. 1A H340 GHS08 H340
absorbing hydrogen from a hydrogen rich Muta. 1B Dgr
L 353/805
stream. It consists of hydrogen, carbon
monoxide, nitrogen, and methane with
small amounts of C2 hydrocarbons.]
L 353/806
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-132-00-6 Gases (petroleum), hydrogen-rich; 270-780-7 68477-97-4 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination separated as a gas Carc. 1A H340 GHS08 H340
from hydrocarbon gases by chilling. It Muta. 1B Dgr
consists primarily of hydrogen with various
small amounts of carbon monoxide, nitro-
gen, methane, and C2 hydrocarbons.]
649-133-00-1 Gases (petroleum), hydrotreater blend oil 270-781-2 68477-98-5 Flam. Gas 1 H220 GHS02 H220 HKU
649-134-00-7 Gases (petroleum), recycle, hydrogen-rich; 270-783-3 68478-00-2 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination obtained from Carc. 1A H340 GHS08 H340
recycled reactor gases. It consists primarily Muta. 1B Dgr
of hydrogen with various small amounts of
carbon monoxide, carbon dioxide, nitrogen,
hydrogen sulfide, and saturated aliphatic
hydrocarbons having carbon numbers in the
range of C1 through C5.]
649-135-00-2 Gases (petroleum), reformer make-up, 270-784-9 68478-01-3 Flam. Gas 1 H220 GHS02 H220 HKU
hydrogen-rich; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained from the Muta. 1B Dgr
reformers. It consists primarily of hydrogen
with various small amounts of carbon
31.12.2008
monoxide and aliphatic hydrocarbons hav-
ing carbon numbers predominantly in the
range of C1 through C5.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-136-00-8 Gases (petroleum), reforming hydrotreater; 270-785-4 68478-02-4 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination obtained from the Carc. 1A H340 GHS08 H340
reforming hydrotreating process. It consists Muta. 1B Dgr
primarily of hydrogen, methane, and ethane
with various small amounts of hydrogen
sulfide and aliphatic hydrocarbons having
carbon numbers predominantly in the range
of C3 thorugh C5.]
649-138-00-9 Gases (petroleum), reforming hydrotreater 270-788-0 68478-04-6 Flam. Gas 1 H220 GHS02 H220 HKU
make-up, hydrogen-rich; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained from the Muta. 1B Dgr
reforming hydrotreating process. It consists
primarily of hydrogen with various small
amounts of carbon monoxide and aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C5.]
649-139-00-4 Gases (petroleum), thermal cracking distn.; 270-789-6 68478-05-7 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination produced by Carc. 1A H340 GHS08 H340
distillation of products from a thermal Muta. 1B Dgr
cracking process. It consists of hydrogen,
hydrogen sulfide, carbon monoxide, carbon
L 353/807
dioxide and hydrocarbons having carbon
numbers predominantly in the range of C1
through C6.]
L 353/808
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-140-00-X Tail gas (petroleum), catalytic cracker 270-805-1 68478-25-1 Flam. Gas 1 H220 GHS02 H220 HKU
EN
refractionation absorber; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from refractionation of products
from a catalytic cracking process. It consists
of hydrogen and hydrocarbons having
carbon numbers predominantly in the range
of C1 through C3.]
649-142-00-0 Tail gas (petroleum), catalytic reformed 270-808-8 68478-28-4 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha stabilizer; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the stabilization of catalytic
reformed naphtha. It consists of hydrogen
and hydrocarbons having carbon numbers
predominantly in the range of C1 through
C6.]
649-143-00-6 Tail gas (petroleum), cracked distillate 270-809-3 68478-29-5 Flam. Gas 1 H220 GHS02 H220 HKU
hydrotreater separator; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by treating cracked distillates with
hydrogen in the presence of a catalyst. It
31.12.2008
consists of hydrogen and saturated aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C5.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-144-00-1 Tail gas (petroleum), hydrodesulfurized 270-810-9 68478-30-8 Flam. Gas 1 H220 GHS02 H220 HKU
straight-run naphtha separator; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from hydrodesulfurization of
straight-run naphtha. It consists of hydrogen
and saturated aliphatic hydrocarbons having
carbon numbers predominantly in the range
of C1 through C6.]
649-146-00-2 Gases (petroleum), reformer effluent high- 271-003-4 68513-18-8 Flam. Gas 1 H220 GHS02 H220 HKU
pressure flash drum off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by the Muta. 1B Dgr
high-pressure flashing of the effluent from
the reforming reactor. It consists primarily
of hydrogen with various small amounts of
methane, ethane, and propane.]
649-147-00-8 Gases (petroleum), reformer effluent low- 271-005-5 68513-19-9 Flam. Gas 1 H220 GHS02 H220 HKU
pressure flash drum off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by low- Muta. 1B Dgr
pressure flashing of the effluent from the
reforming reactor. It consists primarily of
L 353/809
hydrogen with various small amounts of
methane, ethane, and propane.]
L 353/810
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-148-00-3 Gases (petroleum), oil refinery gas distn. off; 271-258-1 68527-15-1 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination separated by Carc. 1A H340 GHS08 H340
distillation of a gas stream containing Muta. 1B Dgr
hydrogen, carbon monoxide, carbon dioxide
and hydrocarbons having carbon numbers
in the range of C1 through C6 or obtained by
cracking ethane and propane. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C2,
hydrogen, nitrogen, and carbon monoxide.]
649-150-00-4 Gases (petroleum), secondary absorber off, 271-625-6 68602-84-6 Flam. Gas 1 H220 GHS02 H220 HKU
fluidized catalytic cracker overheads fractio- Press. Gas H350 GHS04 H350
nator; Carc. 1A H340 GHS08 H340
Refinery gas; Muta. 1B Dgr
[A complex combination produced by the
fractionation of the overhead products from
the catalytic cracking process in the fluidized
catalytic cracker. It consists of hydrogen,
nitrogen, and hydrocarbons having carbon
numbers predominantly in the range of C1
through C3.]
649-151-00-X Petroleum products, refinery gases; 271-750-6 68607-11-4 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
31.12.2008
[A complex combination which consists Carc. 1A H340 GHS08 H340
primarily of hydrogen with various small Muta. 1B Dgr
amounts of methane, ethane, and propane.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-152-00-5 Gases (petroleum), hydrocracking low-pres- 272-182-1 68783-06-2 Flam. Gas 1 H220 GHS02 H220 HKU
EN
sure separator; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained by the Muta. 1B Dgr
liquid-vapor separation of the hydrocracking
process reactor effluent. It consists predo-
minantly of hydrogen and saturated hydro-
carbons having carbon numbers
predominantly in the range of C1 through
C3.]
649-154-00-6 Gases (petroleum), platformer products 272-343-6 68814-90-4 Flam. Gas 1 H220 GHS02 H220 HKU
separator off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained from the Muta. 1B Dgr
chemical reforming of naphthenes to aro-
matics. It consists of hydrogen and saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C2
through C4.]
649-155-00-1 Gases (petroleum), hydrotreated sour kero- 272-775-5 68911-58-0 Flam. Gas 1 H220 GHS02 H220 HKU
sine depentanizer stabilizer off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[The complex combination obtained from Muta. 1B Dgr
the depentanizer stabilization of hydro-
treated kerosine. It consists primarily of
hydrogen, methane, ethane, and propane
with various small amounts of nitrogen,
L 353/811
hydrogen sulfide, carbon monoxide and
hydrocarbons having carbon numbers pre-
dominantly in the range of C4 through C5.]
L 353/812
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-156-00-7 Gases (petroleum), hydrotreated sour kero- 272-776-0 68911-59-1 Flam. Gas 1 H220 GHS02 H220 HKU
EN
sine flash drum; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained from the Muta. 1B Dgr
flash drum of the unit treating sour kerosine
with hydrogen in the presence of a catalyst.
It consists primarily of hydrogen and
methane with various small amounts of
nitrogen, carbon monoxide, and hydro-
carbons having carbon numbers predomi-
nantly in the range of C2 through C5.]
649-158-00-8 Gases (petroleum), fluidized catalytic cracker 272-874-3 68919-02-8 Flam. Gas 1 H220 GHS02 H220 HKU
fractionation off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by the Muta. 1B Dgr
fractionation of the overhead product of the
fluidized catalytic cracking process. It con-
sists of hydrogen, hydrogen sulfide, nitro-
gen, and hydrocarbons having carbon
numbers predominantly in the range of C1
through C5.]
649-159-00-3 Gases (petroleum), fluidized catalytic cracker 272-875-9 68919-03-9 Flam. Gas 1 H220 GHS02 H220 HKU
scrubbing secondary absorber off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by Muta. 1B Dgr
scrubbing the overhead gas from the
31.12.2008
fluidized catalytic cracker. It consists of
hydrogen, nitrogen, methane, ethane and
propane.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-160-00-9 Gases (petroleum), heavy distillate hydro- 272-876-4 68919-04-0 Flam. Gas 1 H220 GHS02 H220 HKU
treater desulfurization stripper off;
EN
Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination stripped from the Muta. 1B Dgr
liquid product of the heavy distillate hydro-
treater desulfurization process. It consists of
hydrogen, hydrogen sulfide, and saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C1
through C5].
649-161-00-4 Gases (petroleum), platformer stabilizer off, 272-880-6 68919-07-3 Flam. Gas 1 H220 GHS02 H220 HKU
649-162-00-X Gases (petroleum), preflash tower off, crude 272-881-1 68919-08-4 Flam. Gas 1 H220 GHS02 H220 HKU
distn.; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced from the Muta. 1B Dgr
first tower used in the distillation of crude
oil. It consists of nitrogen and saturated
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C1
through C5.]
649-163-00-5 Gases (petroleum), tar stripper off; 272-884-8 68919-11-9 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
[A complex combination obtained by the Carc. 1A H340 GHS08 H340
fractionation of reduced crude oil. It consists Muta. 1B Dgr
of hydrogen and hydrocarbons having
carbon numbers predominantly in the range
of C1 through C4.]
649-164-00-0 Gases (petroleum), unifiner stripper off; 272-885-3 68919-12-0 Flam. Gas 1 H220 GHS02 H220 HKU
Refinery gas; Press. Gas H350 GHS04 H350
L 353/813
[A combination of hydrogen and methane Carc. 1A H340 GHS08 H340
obtained by fractionation of the products Muta. 1B Dgr
from the unifiner unit.]
L 353/814
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-165-00-6 Tail gas (petroleum), catalytic hydrodesul- 273-173-5 68952-79-4 Flam. Gas 1 H220 GHS02 H220 HKU
EN
furized naphtha separator; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the hydrodesulfurization of
naphtha. It consists of hydrogen, methane,
ethane, and propane.]
649-166-00-1 Tail gas (petroleum), straight-run naphtha 273-174-0 68952-80-7 Press. Gas H220 GHS02 H220 HKU
649-167-00-7 Gases (petroleum), sponge absorber off, 273-269-7 68955-33-9 Flam. Gas 1 H220 GHS02 H220 HKU
fluidized catalytic cracker and gas oil Press. Gas H350 GHS04 H350
desulfurizer overhead fractionation; Carc. 1A H340 GHS08 H340
Refinery gas; Muta. 1B Dgr
[A complex combination obtained by the
fractionation of products from the fluidized
catalytic cracker and gas oil desulfurizer. It
consists of hydrogen and hydrocarbons
having carbon numbers predominantly in
the range of C1 through C4.]
649-168-00-2 Gases (petroleum), crude distn. and catalytic 273-563-5 68989-88-8 Flam. Gas 1 H220 GHS02 H220 HKU
cracking; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by crude Muta. 1B Dgr
distillation and catalytic cracking processes.
It consists of hydrogen, hydrogen sulfide,
nitrogen, carbon monoxide and paraffinic
31.12.2008
and olefinic hydrocarbons having carbon
numbers predominantly in the range of C1
through C6.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-169-00-8 Gases (petroleum), gas oil diethanolamine 295-397-2 92045-15-3 Flam. Gas 1 H220 GHS02 H220 HKU
EN
scrubber off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination produced by Muta. 1B Dgr
desulfurization of gas oils with diethanola-
mine. It consists predominantly of hydrogen
sulfide, hydrogen and aliphatic hydrocar-
bons having carbon numbers in the range of
C1 through C5.]
649-171-00-9 Gases (petroleum), gas oil hydrodesulfuriza- 295-399-3 92045-17-5 Flam. Gas 1 H220 GHS02 H220 HKU
tion purge; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of gases obtained Muta. 1B Dgr
from the reformer and from the purges from
the hydrogenation reactor. It consists pre-
dominantly of hydrogen and aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C1 through C4.]
649-172-00-4 Gases (petroleum), hydrogenator effluent 295-400-7 92045-18-6 Flam. Gas 1 H220 GHS02 H220 HKU
flash drum off; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination of gases obtained Muta. 1B Dgr
from flash of the effluents after the hydro-
genation reaction. It consists predominantly
L 353/815
of hydrogen and aliphatic hydrocarbons
having carbon numbers predominantly in
the range of C1 through C6.]
L 353/816
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-173-00-X Gases (petroleum), naphtha steam cracking 295-401-2 92045-19-7 Flam. Gas 1 H220 GHS02 H220 HKU
EN
high-pressure residual; Press. Gas H350 GHS04 H350
Refinery gas; Carc. 1A H340 GHS08 H340
[A complex combination obtained as a Muta. 1B Dgr
mixture of the non-condensable portions
from the product of a naphtha steam
cracking process as well as residual gases
obtained during the preparation of subse-
quent products. It consists predominantly of
hydrogen and paraffinic and olefinic hydro-
carbons having carbon numbers predomi-
nantly in the range of C1 through C5 with
which natural gas may also be mixed.]
649-175-00-0 Foots oil (petroleum), acid-treated; 300-225-7 93924-31-3 Flam. Gas 1 H220 GHS02 H220 HKU
Foots oil; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1B H340 GHS08 H340
obtained by treatment of Foot's oil with Dgr
sulfuric acid. It consists predominantly of
branched-chain hydrocarbons with carbon
numbers predominantly in the range of C20
through C50.]
649-176-00-6 Foots oil (petroleum), clay-treated; 300-226-2 93924-32-4 Flam. Gas 1 H220 GHS02 H220 HKU
Foots oil; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1B H340 GHS08 H340
obtained by treatment of Foot's oil with Dgr
natural or modified clay in either a con-
tacting or percolation process to remove the
trace amounts of polar compounds and
impurities present. It consists predominantly
31.12.2008
of branched chain hydrocarbons with car-
bon numbers predominantly in the range of
C20 through C50.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-177-00-1 Gases (petroleum), C3-4; 268-629-5 68131-75-9 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by distillation of products from Muta. 1B Dgr
the cracking of crude oil. It consists of
hydrocarbons having carbon numbers in the
range of C3 through C4, predominantly of
propane and propylene, and boiling in the
range of approximately - 51 oC to - 1 oC
(-60oF to 30 oF.)]
649-179-00-2 Tail gas (petroleum), catalytic polymn. 269-618-8 68307-99-3 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha fractionation stabilizer; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
from the fractionation stabilization products
from polymerization of naphtha. It consists
predominantly of hydrocarbons having car-
bon numbers in the range of C1 through C4.]
649-180-00-8 Tail gas (petroleum), catalytic reformed 269-619-3 68308-00-9 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha fractionation stabilizer, hydrogen Press. Gas H350 GHS04 H350
sulfide-free; Carc. 1A H340 GHS08 H340
Petroleum gas; Muta. 1B Dgr
[A complex combination of hydrocarbons
obtained from fractionation stabilization of
catalytic reformed naphtha and from which
hydrogen sulfide has been removed by
amine treatment. It consists predominantly
L 353/817
of hydrocarbons having carbon numbers
predominantly in the range of C1 through
C4.]
L 353/818
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-181-00-3 Tail gas (petroleum), cracked distillate 269-620-9 68308-01-0 Flam. Gas 1 H220 GHS02 H220 HKU
EN
hydrotreater stripper; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained by treating thermal cracked dis-
tillates with hydrogen in the presence of a
catalyst. It consists predominantly of satu-
rated hydrocarbons having carbon numbers
predominantly in the range of C1 through
C6.]
649-183-00-4 Tail gas (petroleum), gas oil catalytic crack- 269-623-5 68308-03-2 Flam. Gas 1 H220 GHS02 H220 HKU
ing absorber; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the distillation of products
from the catalytic cracking of gas oil. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C1 through C5.]
649-184-00-X Tail gas (petroleum), gas recovery plant; 269-624-0 68308-04-3 Press. Gas H220 GHS02 H220 HKU
Petroleum gas; Flam. Gas 1 H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
from the distillation of products from Muta. 1B Dgr
miscellaneous hydrocarbon streams. It con-
31.12.2008
sists predominantly of hydrocarbons having
carbon numbers predominantly in the range
of C1 through C5.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-185-00-5 Tail gas (petroleum), gas recovery plant 269-625-6 68308-05-4 Flam. Gas 1 H220 GHS02 H220 HKU
deethanizer; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
from the distillation of products from
miscellaneous hydrocarbon streams. It con-
sists of hydrocarbon having carbon numbers
predominantly in the range of C1 through
C4.]
649-187-00-6 Tail gas (petroleum), hydrodesulfurized 269-627-7 68308-07-6 Flam. Gas 1 H220 GHS02 H220 HKU
vacuum gas oil stripper, hydrogen sulfide- Press. Gas H350 GHS04 H350
free; Carc. 1A H340 GHS08 H340
Petroleum gas; Muta. 1B Dgr
[A complex combination of hydrocarbons
obtained from stripping stabilization of
catalytic hydrodesulfurized vacuum gas oil
and from which hydrogen sulfide has been
removed by amine treatment. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
L 353/819
C1 through C6.]
L 353/820
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-188-00-1 Tail gas (petroleum), light straight-run 269-629-8 68308-09-8 Flam. Gas 1 H220 GHS02 H220 HKU
naphtha stabilizer, hydrogen sulfide-free; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from fractionation stabilization of
light straight run naphtha and from which
hydrogen sulfide has been removed by
amine treatment. It consists predominantly
of hydrocarbons having carbon numbers
predominantly in the range of C1 through
C5.]
649-190-00-2 Tail gas (petroleum), vacuum gas oil hydro- 269-632-4 68308-12-3 Flam. Gas 1 H220 GHS02 H220 HKU
desulfurizer, hydrogen sulfide-free; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from catalytic hydrodesulfurization
of vacuum gas oil and from which hydrogen
sulfide has been removed by amine treat-
ment. It consists predominantly of hydro-
carbons having carbon numbers
predominantly in the range of C1 through
31.12.2008
C6.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-191-00-8 Gases (petroleum), catalytic cracked over- 270-071-2 68409-99-4 Flam. Gas 1 H220 GHS02 H220 HKU
EN
heads; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
produced by the distillation of products
from the catalytic cracking process. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C3
through C5 and boiling in the range of
approximately - 48 oC to 32 oC (- 54 oF to
90 oF).]
649-194-00-4 Alkanes, C2-3; 270-652-0 68475-58-1 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-195-00-X Alkanes, C3-4; 270-653-6 68475-59-2 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-196-00-5 Alkanes, C4-5; 270-654-1 68475-60-5 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-197-00-0 Fuel gases; 270-667-2 68476-26-6 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
L 353/821
[A combination of light gases. It consists Carc. 1A H340 GHS08 H340
predominantly of hydrogen and/or low Muta. 1B Dgr
molecular weight hydrocarbons.]
L 353/822
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-198-00-6 Fuel gases, crude oil of distillates; 270-670-9 68476-29-9 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of light gases Carc. 1A H340 GHS08 H340
produced by distillation of crude oil and by Muta. 1B Dgr
catalytic reforming of naphtha. It consists of
hydrogen and hydrocarbons having carbon
numbers predominantly in the range of C1
through C4 and boiling in the range of
approximately - 217 oC to - 12 oC (- 423 oF
to 10 oF).]
649-200-00-5 Hydrocarbons, C4-5; 270-682-4 68476-42-6 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-201-00-0 Hydrocarbons, C2-4, C3-rich; 270-689-2 68476-49-3 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas Press. Gas H350 GHS04 H350
Carc. 1A H340 GHS08 H340
Muta. 1B Dgr
649-202-00-6 Petroleum gases, liquefied; 270-704-2 68476-85-7 Flam. Gas 1 H220 GHS02 H220 HKSU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the distillation of crude oil. It Muta. 1B Dgr
consists of hydrocarbons having carbon
numbers predominantly in the range of C3
31.12.2008
through C7 and boiling in the range of
approximately - 40 oC to 80 oC (- 40 oF to
176 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-203-00-1 Petroleum gases, liquefied, sweetened; 270-705-8 68476-86-8 Flam. Gas 1 H220 GHS02 H220 HKSU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
obtained by subjecting liquefied petroleum Muta. 1B Dgr
gas mix to a sweetening process to convert
mercaptans or to remove acidic impurities.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C3
through C7 and boiling in the range of
approximately - 40 oC to 80 oC (- 40 oF to
176 oF).]
649-205-00-2 Distillates (petroleum), C3-6, piperylene-rich; 270-726-2 68477-35-0 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
from the distillation of saturated and Muta. 1B Dgr
unsaturated aliphatic hydrocarbons usually
ranging in the carbon numbers C3 through
C6. It consists of saturated and unsaturated
hydrocarbons having carbon numbers in the
range of C3 through C6, predominantly
piperylenes.]
649-206-00-8 Gases (petroleum), butane splitter overheads; 270-750-3 68477-69-0 Flam. Gas 1 H220 GHS02 H220 HKU
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
obtained from the distillation of the butane Muta. 1B Dgr
L 353/823
stream. It consists of aliphatic hydrocarbons
having carbon numbers predominantly in
the range of C3 through C4.]
L 353/824
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-207-00-3 Gases (petroleum), C2-; 270-751-9 68477-70-3 Flam. Gas 1 H220 GHS02 H220 HKU
EN
Petroleum gas; Press. Gas H350 GHS04 H350
[A complex combination of hydrocarbons Carc. 1A H340 GHS08 H340
produced by the distillation of products Muta. 1B Dgr
from a catalytic fractionation process. It
contains predominantly ethane, ethylene,
propane, and propylene.]
649-208-00-9 Gases (petroleum), catalytic-cracked gas oil 270-752-4 68477-71-4 Flam. Gas 1 H220 GHS02 H220 HKU
649-209-00-4 Gases (petroleum), catalytic-cracked naphtha 270-754-5 68477-72-5 Flam. Gas 1 H220 GHS02 H220 HKU
debutanizer bottoms, C3-5-rich; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the stabilization of catalytic
cracked naphtha. It consists of aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C3 through C5.]
649-210-00-X Tail gas (petroleum), isomerized naphtha 269-628-2 68308-08-7 Flam. Gas 1 H220 GHS02 H220 HKU
fractionation stabilizer; Press. Gas H350 GHS04 H350
Petroleum gas; Carc. 1A H340 GHS08 H340
[A complex combination of hydrocarbons Muta. 1B Dgr
obtained from the fractionation stabilization
products from isomerized naphtha. It con-
31.12.2008
sists predominantly of hydrocarbons having
carbon numbers predominantly in the range
of C1 through C4.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-211-00-5 Foots oil (petroleum), carbon-treated; 308-126-0 97862-76-5 Carc. 1B H350 GHS08 H350 HL
EN
Foots oil; Dgr
[A complex combination of hydrocarbons
obtained by the treatment of Foots oil with
activated carbon for the removal of trace
constituents and impurities. It consists
predominantly of saturated straight chain
hydrocarbons having carbon numbers pre-
dominantly greater than C12.]
649-212-00-0 Distillates (petroleum), sweetened middle; 265-088-7 64741-86-2 Carc. 1B H350 GHS08 H350 HN
649-213-00-6 Gas oils (petroleum), solvent-refined; 265-092-9 64741-90-8 Carc. 1B H350 GHS08 H350 HN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists predominantly
of aliphatic hydrocarbons having carbon
numbers predominantly in the range of C11
through C25 and boiling in the range of
approximately 205 oC to 400 oC (401 oF to
752 oF).]
649-214-00-1 Distillates (petroleum), solvent-refined mid- 265-093-4 64741-91-9 Carc. 1B H350 GHS08 H350 HN
dle; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists predominantly
of aliphatic hydrocarbons having carbon
numbers predominantly in the range of C9
L 353/825
through C20 and boiling in the range of
approximately 150 oC to 345 oC (302 oF to
653 oF).]
L 353/826
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-215-00-7 Gas oils (petroleum), acid-treated; 265-112-6 64742-12-7 Carc. 1B H350 GHS08 H350 HN
EN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
treating process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C13 through C25 and boiling in
the range of approximately 230 oC to
400 oC (446 oF to 752 oF).]
649-217-00-8 Distillates (petroleum), acid-treated light; 265-114-7 64742-14-9 Carc. 1B H350 GHS08 H350 HN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
treating process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C9 through C16 and boiling in
the range of approximately 150 oC to
290 oC (302 oF to 554 oF).]
649-218-00-3 Gas oils (petroleum), chemically neutralized; 265-129-9 64742-29-6 Carc. 1B H350 GHS08 H350 HN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
31.12.2008
the range of C13 through C25 and boiling in
the range of approximately 230 oC to
400 oC (446 oF to 752 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-219-00-9 Distillates (petroleum), chemically neutra- 265-130-4 64742-30-9 Carc. 1B H350 GHS08 H350 HN
lized middle; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C11 through C20 and boiling in
the range of approximately 205 oC to
345 oC (401 oF to 653 oF).]
649-221-00-X Distillates (petroleum), hydrotreated middle; 265-148-2 64742-46-7 Carc. 1B H350 GHS08 H350 HN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C11
through C25 and boiling in the range of
approximately 205 oC to 400 oC (401 oF to
L 353/827
752 oF).]
L 353/828
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-222-00-5 Gas oils (petroleum), hydrodesulfurized; 265-182-8 64742-79-6 Carc. 1B H350 GHS08 H350 HN
EN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained from a petroleum stock by treating
with hydrogen to convert organic sulfur to
hydrogen sulfide which is removed. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C13 through C25 and boiling in
the range of approximately 230 oC to
400 oC (446 oF to 752 oF).]
31.12.2008
[A distillate oil having a minimum viscosity
of 32,6 SUS at 37,7 oC (100 oF) to a
maximum of 37,9 SUS at 37,7 oC (100 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Gasoil — unspecified; Wng
[A distillate oil having a minimum viscosity
of 45 SUS at 37,7 oC (100 oF) to a
maximum of 125 SUS at 37,7 oC (100 oF).]
649-228-00-8 Distillates (petroleum), catalytic reformer 270-719-4 68477-29-2 Carc. 1B H350 GHS08 H350 HN
fractionator residue, high-boiling; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
from the distillation of catalytic reformer
fracftionator residue. It boils in the range of
approximately 343 oC to 399 oC (650 oF to
750 oF).]
649-229-00-3 Distillates (petroleum), catalytic reformer 270-721-5 68477-30-5 Carc. 1B H350 GHS08 H350 HN
fractionator residue, intermediate-boiling; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
from the distillation of catalytic reformer
fractionator residue. It boils in the range of
approximately 288 oC to 371 oC (550 oF to
700 oF).]
649-230-00-9 Distillates (petroleum), catalytic reformer 270-722-0 68477-31-6 Carc. 1B H350 GHS08 H350 HN
fractionator residue, low-boiling; Dgr
Gasoil — unspecified;
[The complex combination of hydrocarbons
L 353/829
from the distillation of catalytic reformer
fractionator residue. It boils approximately
below 288 oC (550 oF).]
L 353/830
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-231-00-4 Distillates (petroleum), highly refined mid- 292-615-8 90640-93-0 Carc. 1B H350 GHS08 H350 HN
EN
dle; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained by the subjection of a petroleum
fraction to several of the following steps:
filtration, centrifugation, atmospheric distil-
lation, vacuum distillation, acidification,
neutralization and clay treatment. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C10 through C20.]
649-233-00-5 Gas oils, paraffinic; 300-227-8 93924-33-5 Carc. 1B H350 GHS08 H350 HN
Gasoil — unspecified; Dgr
[A distillate obtained from the redistillation
of a complex combination of hydrocarbons
obtained by the distillation of the effluents
from a severe catalytic hydrotreatment of
paraffins. It boils in the range of approxi-
mately 190 oC to 330 oC (374 oF to
594 oF).]
31.12.2008
649-234-00-0 Naphtha (petroleum), solvent-refined 307-035-3 97488-96-5 Carc. 1B H350 GHS08 H350 HN
hydrodesulfurized heavy; Dgr
Gasoil — unspecified
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-235-00-6 Hydrocarbons, C16-20, hydrotreated middle 307-659-6 97675-85-9 Carc. 1B H350 GHS08 H350 HN
EN
distillate, distn. lights; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained as first runnings from the vacuum
distillation of effluents from the treatment of
a middle distillate with hydrogen. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C16 through C20 and boiling in the range of
approximately 290 oC to 350 oC (554 oF to
662 oF). It produces a finished oil having a
649-236-00-1 Hydrocarbons, C12-20, hydrotreated paraffi- 307-660-1 97675-86-0 Carc. 1B H350 GHS08 H350 HN
nic, distn. lights; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained as first runnings from the vacuum
distillation of effluents from the treatment of
heavy paraffins with hydrogen in the
presence of a catalyst. It consists predomi-
nantly of hydrocarbons having carbon
numbers predominantly in the range of C12
through C20 and boiling in the range of
approximately 230 oC to 350 oC (446 oF to
662 oF). It produces a finished oil having a
viscosity of 2cSt at 100 oC (212 oF).]
649-237-00-7 Hydrocarbons, C11-17, solvent-extd. light 307-757-9 97722-08-2 Carc. 1B H350 GHS08 H350 HN
naphthenic; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained by extraction of the aromatics
from a light naphthenic distillate having a
visciosity of 2.2 cSt at 40 oC (104 oF). It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C11 through C17 and boiling in
L 353/831
the range of approximately 200 oC to
300 oC (392 oF to 572 oF).]
L 353/832
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-238-00-2 Gas oils, hydrotreated; 308-128-1 97862-78-7 Carc. 1B H350 GHS08 H350 HN
EN
Gasoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained from the redistillation of the
effluents from the treatment of paraffins
with hydrogen in the presence of a catalyst.
It consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C17 through C27 and boiling in
the range of approximately 330 oC to
340 oC (626 oF to 644 oF).]
649-240-00-3 Distillates (petroleum), intermediate paraf- 309-668-0 100683-98-5 Carc. 1B H350 GHS08 H350 HN
finic, carbon-treated; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained by the treatment of petroleum with
activated charcoal for the removal of trace
polar constituents and impurities. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C16 through C36.]
649-241-00-9 Distillates (petroleum), intermediate paraf- 309-669-6 100683-99-6 Carc. 1B H350 GHS08 H350 HN
finic, clay-treated; Dgr
Gasoil — unspecified;
[A complex combination of hydrocarbons
obtained by the treatment of petroleum with
bleaching earth for the removal of trace
31.12.2008
polar constituents and impurities. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C16 through C36.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-242-00-4 Alkanes, C12-26-branched and linear 292-454-3 90622-53-0 Carc. 1B H350 GHS08 H350 HN
EN
Dgr
649-245-00-0 Slack wax (petroleum), acid-treated; 292-659-8 90669-77-5 Carc. 1B H350 GHS08 H350 HN
Slack wax; Dgr
[A complex combination of hydrocarbons
obtained as a raffinate by treatment of a
petroleum slack wax fraction with sulfuric
acid treating process. It consists predomi-
nantly of saturated straight and branched
chain hydrocarbons having carbon numbers
predominantly greater than C20.]
649-246-00-6 Slack wax (petroleum), clay-treated; 292-660-3 90669-78-6 Carc. 1B H350 GHS08 H350 HN
Slack wax; Dgr
[A complex combination of hydrocarbons
obtained by treatment of a petroleum slack
wax fraction with natural or modified clay in
either a contacting or percolation process. It
L 353/833
consists predominantly of saturated straight
and branched hydrocarbons having carbon
numbers predominantly greater than C20.]
L 353/834
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-247-00-1 Slack wax (petroleum), hydrotreated; 295-523-6 92062-09-4 Carc. 1B H350 GHS08 H350 HN
EN
Slack wax; Dgr
[A complex combination of hydrocarbons
obtained by treating slack wax with hydro-
gen in the presence of a catalyst. It consists
predominantly of saturated straight and
branched chain hydrocarbons having carbon
numbers predominantly greater than C20.]
649-248-00-7 Slack wax (petroleum), low-melting; 295-524-1 92062-10-7 Carc. 1B H350 GHS08 H350 HN
649-249-00-2 Slack wax (petroleum), low-melting, hydro- 295-525-7 92062-11-8 Carc. 1B H350 GHS08 H350 HN
treated; Dgr
Slack wax;
[A complex combination of hydrocarbons
obtained by treatment of low-melting
petroleum slack wax with hydrogen in the
presence of a catalyst. It consists predomi-
nantly of saturated straight and branched
chain hydrocarbons having carbon numbers
predominantly greater than C12.]
649-250-00-8 Slack wax (petroleum), low-melting, carbon- 308-155-9 97863-04-2 Carc. 1B H350 GHS08 H350 HN
treated; Dgr
Slack wax;
[A complex combination of hydrocarbons
obtained by the treatment of low-melting
slack wax with activated carbon for the
removal of trace polar constituents and
impurities. It consists predominantly of
31.12.2008
saturated straight and branched chain
hydrocarbons having carbon numbers pre-
dominantly greater than C12.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-251-00-3 Slack wax (petroleum), low-melting, clay- 308-156-4 97863-05-3 Carc. 1B H350 GHS08 H350 HN
EN
treated; Dgr
Slack wax;
[A complex combination of hydrocarbons
obtained by the treatment of low-melting
petroleum slack wax with bentonite for
removal of trace polar constituents and
impurities. It consists predominantly of
saturated straight and branched chain
hydrocarbons having carbon numbers pre-
dominantly greater than C12.]
649-253-00-4 Slack wax (petroleum), carbon-treated; 309-723-9 100684-49-9 Carc. 1B H350 GHS08 H350 HN
Slack wax; Dgr
[A complex combination of hydrocarbons
obtained by treatment of petroleum slack
wax with activated charcoal for the removal
of trace polar constituents and impurities.]
L 353/835
nantly of saturated crystalline and liquid
hydrocarbons having carbon numbers pre-
dominantly greater than C25.]
L 353/836
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-255-00-5 Petrolatum (petroleum), oxidized; 265-206-7 64743-01-7 Carc. 1B H350 GHS08 H350 HN
Petrolatum; Dgr
[A complex combination of organic com-
pounds, predominantly high molecular
weight carboxylic acids, obtained by the air
oxidation of petrolatum.]
649-256-00-0 Petrolatum (petroleum), alumina-treated; 285-098-5 85029-74-9 Carc. 1B H350 GHS08 H350 HN
649-257-00-6 Petrolatum (petroleum), hydrotreated; 295-459-9 92045-77-7 Carc. 1B H350 GHS08 H350 HN
Petrolatum; Dgr
[A complex combination of hydrocarbons
obtained as a semi-solid from dewaxed
paraffinic residual oil treated with hydrogen
in the presence of a catalyst. It consists
predominantly of saturated microcrystalline
and liquid hydrocarbons having carbon
numbers predominantly greater than C20.]
649-258-00-1 Petrolatum (petroleum), carbon-treated; 308-149-6 97862-97-0 Carc. 1B H350 GHS08 H350 HN
Petrolatum; Dgr
[A complex combination of hydrocarbons
obtained by the treatment of petroleum
petrolatum with activated carbon for the
removal of trace polar constituents and
31.12.2008
impurities. It consists predominantly of
saturated hydrocarbons having carbon
numbers predominantly greater than C20.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-259-00-7 Petrolatum (petroleum), silicic acid-treated; 308-150-1 97862-98-1 Carc. 1B H350 GHS08 H350 HN
EN
Petrolatum; Dgr
[A complex combination of hydrocarbons
obtained by the treatment of petroleum
petrolatum with silicic acid for the removal
of trace polar constituents and impurities. It
consists predominantly of saturated hydro-
carbons having carbon numbers predomi-
nantly greater than C20.]
L 353/837
of C5 through C6 and boiling in the range of
approximately 100 oC to 200 oC (212 oF to
392 oF).]]
L 353/838
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained by the fractional distillation of
petroleum. This fraction boils in a range of
approximately 20 oC to 135 oC (58 oF to
275 oF).]
649-264-00-4 Naphtha (petroleum), heavy straight-run; 265-041-0 64741-41-9 Carc. 1B H350 GHS08 H350 HP
649-265-00-X Naphtha (petroleum), full-range straight-run; 265-042-6 64741-42-0 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by distillation of crude oil. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C4
through C11 and boiling in the range of
approximately minus 20 oC to 220 oC (- 4 oF
to 428 oF).]
649-266-00-5 Naphtha (petroleum), light straight-run; 265-046-8 64741-46-4 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by distillation of crude oil. It
consists predominantly of aliphatic hydro-
carbons having carbon numbers predomi-
31.12.2008
nantly in the range of C4 through C10 and
boiling in the range of approximately minus
20 oC to 180 oC (- 4 oF to 356 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-267-00-0 Solvent naphtha (petroleum), light aliph.; 265-192-2 64742-89-8 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained from the distillation of crude oil or
natural gasoline. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C5
through C10 and boiling in the range of
approximately 35 oC to 160 oC (95 oF to
320 oF).]
649-270-00-7 Gasoline, straight-run, topping-plant; 271-727-0 68606-11-1 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced from the topping plant by the
distillation of crude oil. It boils in the range
L 353/839
of approximately 36,1 oC to 193,3 oC (97 oF
to 380 oF).]
L 353/840
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-271-00-2 Naphtha (petroleum), unsweetened; 272-186-3 68783-12-0 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced from the distillation of naphtha
streams from various refinery processes. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C5
through C12 and boiling in the range of
approximately 0 oC to 230 oC (25 oF to
446 oF).]
649-273-00-3 Naphtha (petroleum), heavy straight run, 309-945-6 101631-20-3 Carc. 1B H350 GHS08 H350 HP
arom.-contg.; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha;
[A complex combination of hydrocarbons
obtained from a distillation process of crude
petroleum. It consists predominantly of
hydrocarbons having carbon numbers in the
range of C8 through C12 and boiling in the
range of approximately 130 oC to 210 oC
(266 oF to 410 oF).]
649-274-00-9 Naphtha (petroleum), full-range alkylate; 265-066-7 64741-64-6 Carc. 1B H350 GHS08 H350 HP
Low boiling point modified naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by distillation of the reaction
products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon
numbers from C3 through C5. It consist of
predominantly branched chain saturated
hydro-carbons having carbon numbers pre-
31.12.2008
dominantly in the range of C7 through C12
and boiling in the range of approximately
90 oC to 220 oC (194 oF to 428 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-275-00-4 Naphtha (petroleum), heavy alkylate; 265-067-2 64741-65-7 Carc. 1B H350 GHS08 H350 HP
Low boiling point modified naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by distillation of the reaction
products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon
numbers from C3 to C5. It consists of
predominantly branched chain saturated
hydrocarbons having carbon numbers pre-
dominantly in the range of C9 through C12
and boiling in the range of approximately
649-276-00-X Naphtha (petroleum), light alkylate; 265-068-8 64741-66-8 Carc. 1B H350 GHS08 H350 HP
Low boiling point modified naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by distillation of the reaction
products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon
numbers from C3 through C5. It consists of
predominantly branched chain saturated
hydro-carbons having carbon numbers pre-
dominantly in the range of C7 through C10
and boiling in the range of aproximately
90 oC to 160 oC (194 oF to 320 oF).]
649-277-00-5 Naphtha (petroleum), isomerization; 265-073-5 64741-70-4 Carc. 1B H350 GHS08 H350 HP
Low boiling point modified naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained from catalytic isomerization of
straight chain paraffinic C4 through C6
hydrocarbons. It consists predominantly of
saturated hydrocarbons such as isobutane,
isopentane, 2,2-dimethylbutane, 2-methyl-
L 353/841
pentane, and 3-methylpentane.]
L 353/842
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-278-00-0 Naphtha (petroleum), solvent-refined light; 265-086-6 64741-84-0 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point modified naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists predominantly
of aliphatic hydrocarbons having carbon
numbers predominantly in the range of C5
through C11 and boiling in the range of
approximately 35 oC to 190 oC (95 oF to
374 oF).]
649-280-00-1 Raffinates (petroleum), catalytic reformer 270-088-5 68410-71-9 Carc. 1B H350 GHS08 H350 HP
ethylene glycol-water countercurrent exts.; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[A complex combination of hydrocarbons
obtained as the raffinate from the UDEX
extraction process on the catalytic reformer
stream. It consists of saturated hydrocarbons
having carbon numbers predominantly in
the range of C6 through C9.]
649-281-00-7 Raffinates (petroleum), reformer, Lurgi unit- 270-349-3 68425-35-4 Carc. 1B H350 GHS08 H350 HP
sepd.; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[The complex combination of hydrocarbons
obtained as a raffinate from a Lurgi
separation unit. It consists predominantly of
non-aromatic hydrocarbons with various
31.12.2008
small amounts of aromatic hydrocarbons
having carbon numbers predominantly in
the range of C6 through C8.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-282-00-2 Naphtha (petroleum), full-range alkylate, 271-267-0 68527-27-5 Carc. 1B H350 GHS08 H350 HP
butane-contg.; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphta;
[A complex combination of hydrocarbons
produced by the distillation of the reaction
products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon
numbers from C3 through C5. It consists of
predominantly branched chain saturated
hydrocarbons having carbon numbers pre-
dominantly in the range of C7 through C12
649-283-00-8 Distillates (petroleum), naphtha steam 295-315-5 91995-53-8 Carc. 1B H350 GHS08 H350 HP
cracking-derived, solvent-refined light Asp. Tox. 1 H304 Dgr H304
hydrotreated;
Low boiling point modified naphtha;
[A complex combination of hydrocarbons
obtained as the raffinates from a solvent
extraction process of hydrotreated light
distillate from steam-cracked naphtha.]
649-284-00-3 Naphtha (petroleum), C4-12 butane-alkylate, 295-430-0 92045-49-3 Carc. 1B H350 GHS08 H350 HP
isooctane-rich; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[A complex combination of hydrocarbons
obtained by alkylation of butanes. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C4 through C12, rich in isooctane, and
boiling in the range of approximately 35 oC
L 353/843
to 210 oC (95 oF to 410 oF).]
L 353/844
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-285-00-9 Hydrocarbons, hydrotreated light naphtha 295-436-3 92045-55-1 Carc. 1B H350 GHS08 H350 HP
distillates, solvent-refined; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[A combination of hydrocarbons obtained
from the distillation of hydrotreated naphtha
followed by a solvent extraction and dis-
tillation process. It consists predominantly
of saturated hydrocarbons boiling in the
range of approximately 94 oC to 99 oC
(201 oF to 210 oF).]
649-287-00-X Hydrocarbons, C6-7, naphtha-cracking, sol- 295-446-8 92045-64-2 Carc. 1B H350 GHS08 H350 HP
vent-refined; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[A complex combination of hydrocarbons
obtained by the sorption of benzene from a
catalytically fully hydrogenated benzene-rich
hydrocarbon cut that was distillatively
obtained from prehydrogenated cracked
naphtha. It consists predominantly of par-
affinic and naphthenic hydrocarbons having
carbon numbers predominantly in the range
of C6 through C7 and boiling in the range of
31.12.2008
approximately 70 oC to 100 oC (158 oF to
212 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-288-00-5 Hydrocarbons, C6-rich, hydrotreated light 309-871-4 101316-67-0 Carc. 1B H350 GHS08 H350 HP
naphtha distillates, solvent-refined; Asp. Tox. 1 H304 Dgr H304
Low boiling point modified naphtha;
[A complex combination of hydrocarbons
obtained by distillation of hydrotreated
naphtha followed by solvent extraction. It
consists predominantly of saturated hydro-
carbons and boiling in the range of
approximately 65 oC to 70 oC (149 oF to
158 oF).]
649-290-00-6 Naphtha (petroleum), light catalytic cracked; 265-056-2 64741-55-5 Carc. 1B H350 GHS08 H350 HP
Low boiling point cat-cracked naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by the distillation of products
from a catalytic cracking process. It consists
of hydrocarbons having carbon numbers
predominantly in the range of C4 through
C11 and boiling in the range of approxi-
mately minus 20 oC to 190 oC (- 4 oF to
374 oF). It contains a relatively large
L 353/845
proportion of unsaturated hydrocarbons.]
L 353/846
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-291-00-1 Hydrocarbons, C3-11, catalytic cracker dis- 270-686-6 68476-46-0 Carc. 1B H350 GHS08 H350 HP
EN
tillates; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha;
[A complex combination of hydrocarbons
produced by the distillations of products
from a catalytic cracking process. It consists
of hydrocarbons having carbon numbers
predominantly in the range of C3 through
C11 and boiling in a range approximately up
to 204 oC (400 oF).]
649-293-00-2 Distillates (petroleum), naphtha steam 295-311-3 91995-50-5 Carc. 1B H350 GHS08 H350 HP
cracking-derived, hydrotreated light arom.; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha.;
[A complex combination of hydrocarbons
obtained by treating a light distillate from
steam-cracked naphtha. It consists predom-
inantly of aromatic hydrocarbons.]
649-294-00-8 Naphtha (petroleum), heavy catalytic 295-431-6 92045-50-6 Carc. 1B H350 GHS08 H350 HP
cracked, sweetened; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha;
[A complex combination of hydrocarbons
obtained by subjecting a catalytic cracked
petroleum distillate to a sweetening process
to convert mercaptans or to remove acidic
impurities. It consists predominantly of
hydrocarbons having carbon numbers pre-
31.12.2008
dominantly in the range of C6 through C12
and boiling in the range of approximately
60 oC to 200 oC (140 oF to 392 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-295-00-3 Naphtha (petroleum), light catalytic cracked 295-441-0 92045-59-5 Carc. 1B H350 GHS08 H350 HP
EN
sweetened; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha;
[A complex combination of hydrocarbons
obtained by subjecting naphtha from a
catalytic cracking process to a sweetening
process to convert mercaptans or to remove
acidic impurities. It consists predominantly
of hydrocarbons boiling in a range of
approximately 35 oC to 210 oC (95 oF to
410 oF).]
649-297-00-4 Hydrocarbons, C8-12, catalytic cracker dis- 309-974-4 101794-97-2 Carc. 1B H350 GHS08 H350 HP
tillates; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha;
[A complex combination of hydrocarbons
obtained by distillation of products from a
catalytic cracking process. It consists pre-
dominantly of hydrocarbons having carbon
numbers predominantly in the range of C8
through C12 and boiling in the range of
approximately 140 oC to 210 oC (284 oF to
410 oF).]
649-298-00-X Hydrocarbons, C8-12, catalytic cracking, 309-987-5 101896-28-0 Carc. 1B H350 GHS08 H350 HP
L 353/847
chem. neutralized, sweetened; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-cracked naphtha
L 353/848
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-299-00-5 Naphtha (petroleum), light catalytic 265-065-1 64741-63-5 Carc. 1B H350 GHS08 H350 HP
EN
reformed; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
produced from the distillation of products
from a catalytic reforming process. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C5
through C11 and boiling in the range of
approximately 35 oC to 190 oC (95 oF to
374 oF). It contains a relatively large
proportion of aromatic and branched chain
hydrocarbons. This stream may contain
649-300-00-9 Naphtha (petroleum), heavy catalytic 265-070-9 64741-68-0 Carc. 1B H350 GHS08 H350 HP
reformed; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
produced from the distillation of products
from a catalytic reforming process. It
consists of predominantly aromatic hydro-
carbons having numbers predominantly in
the range of C7 through C12 and boiling in
the range of approximately 90 oC to 230 oC
(194 oF to 446 oF).]
649-301-00-4 Distillates (petroleum), catalytic reformed 270-660-4 68475-79-6 Carc. 1B H350 GHS08 H350 HP
depentanizer; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
from the distillation of products from a
catalytic reforming process. It consists pre-
dominantly of aliphatic hydrocarbons hav-
ing carbon numbers predominantly in the
range of C3 through C6 and boiling in the
range of approximately - 49 oC to 63 oC
- 57 oF to 145 oF).]
31.12.2008
649-302-00-X Hydrocarbons, C2-6, C6-8 catalytic reformer; 270-687-1 68476-47-1 Carc. 1B H350 GHS08 H350 HP
Low boiling point cat-reformed naphtha Asp. Tox. 1 H304 Dgr H304
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-303-00-5 Residues (petroleum), C6-8 catalytic reformer; 270-794-3 68478-15-9 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point cat-reformed naphtha'; Asp. Tox. 1 H304 Dgr H304
[A complex residuum from the catalytic
reforming of C6-8 feed. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C2 through C6.]
649-304-00-0 Naphtha (petroleum), light catalytic 270-993-5 68513-03-1 Carc. 1B H350 GHS08 H350 HP
reformed, arom.-free; Asp. Tox. 1 H304 Dgr H304
649-305-00-6 Distillates (petroleum), catalytic reformed 271-008-1 68513-63-3 Carc. 1B H350 GHS08 H350 HP
straight-run naphtha overheads; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
obtained by the catalytic reforming of
straight-run naphtha followed by the frac-
tionation of the total effluent. It consists of
saturated aliphatic hydrocarbons having
carbon numbers predominantly in the range
of C2 through C6.]
649-306-00-1 Petroleum products, hydrofiner-powerfor- 271-058-4 68514-79-4 Carc. 1B H350 GHS08 H350 HP
mer reformates; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[The complex combination of hydrocarbons
L 353/849
obtained in a hydrofiner-powerformer pro-
cess and boiling in a range of approximately
27 oC to 210 oC (80 oF to 410 oF).]
L 353/850
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-307-00-7 Naphtha (petroleum, full-range reformed; 272-895-8 68919-37-9 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point cat-reformed naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by the distillation of the products
from a catalytic reforming process. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C5
through C12 and boiling in the range of
approximately 35 oC to 230 oC (95 oF to
446 oF).]
649-309-00-8 Distillates (petroleum), catalytic reformed 285-509-8 85116-58-1 Carc. 1B H350 GHS08 H350 HP
hydrotreated light, C8-12 arom. fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of alkylbenzenes
obtained by the catalytic reforming of
petroleum naphtha. It consists predomi-
nantly of alkylbenzenes having carbon
numbers predominantly in the range of C8
through C10 and boiling in the range of
approximately 160 oC to 180 oC (320 oF to
356 oF).]
31.12.2008
649-310-00-3 Aromatic hydrocarbons, C8, catalytic 295-279-0 91995-18-5 Carc. 1B H350 GHS08 H350 HP
reforming-derived; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-311-00-9 Aromatic hydrocarbons, C7-12, C8-rich; 297-401-8 93571-75-6 Carc. 1B H350 GHS08 H350 HP
Low boiling point cat-reformed naphtha; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained by separation from the platfor-
mate-containing fraction. It consists pre-
dominantly of aromatic hydrocarbons hav-
ing carbon numbers predominantly in the
range of C7 through C12 (primarily C8) and
can contain nonaromatic hydrocarbons,
both boiling in the range of approximately
130 oC to 200 oC (266 oF to 392 oF).]
649-313-00-X Hydrocarbons, C7-12, C >9-arom.-rich, 297-465-7 93572-35-1 Carc. 1B H350 GHS08 H350 HP
reforming heavy fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
obtained by separation from the platfor-
mate-containing fraction. It consists pre-
dominantly of nonaromatic hydrocarbons
having carbon numbers predominantly in
the range of C7 through C12 and boiling in
the range of approximately 120 oC to
L 353/851
210 oC (248 oF to 380 oF) and C9 and higher
aromatic hydrocarbons.]
L 353/852
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-314-00-5 Hydrocarbons, C5-11, nonaroms.-rich, 297-466-2 93572-36-2 Carc. 1B H350 GHS08 H350 HP
reforming light fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point cat-reformed naphtha;
[A complex combination of hydrocarbons
obtained by separation from the platfor-
mate-containing fraction. It consists pre-
dominantly of nonaromatic hydrocarbons
having carbon numbers predominantly in
the range of C5 to C11 and boiling in the
range of approximately 35 oC to 125 oC (94
o
F to 257 oF), benzene and toluene.]
649-316-00-6 Naphtha (petroleum), light thermal cracked; 265-075-6 64741-74-8 Carc. 1B H350 GHS08 H350 HP
Low boiling point thermally cracked Asp. Tox. 1 H304 Dgr H304
naphtha;
[A complex combination of hydrocarbons
from distillation of products from a thermal
cracking process. It consists predominantly
of unsaturated hydrocarbons having carbon
numbers predominantly in the range of C4
through C8 and boiling in the range of
approximately minus 10 oC to 130 oC (14 oF
31.12.2008
to 266 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-317-00-1 Naphtha (petroleum), heavy thermal 265-085-0 64741-83-9 Carc. 1B H350 GHS08 H350 HP
cracked; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
from distillation of the products from a
thermal cracking process. It consists pre-
dominantly of unsaturated hydrocarbons
having carbon numbers predominantly in
the range of C6 through C12 and boiling in
the range of approximately 65 oC to 220 oC
(148 oF to 428 oF).]
649-319-00-2 Distillates (petroleum), light arom.; 267-565-5 67891-80-9 Carc. 1B H350 GHS08 H350 HP
Low boiling point thermally cracked Asp. Tox. 1 H304 Dgr H304
naphtha;
[The complex combination of hydrocarbons
from the distillation of the products from
the thermal cracking of ethane and propane.
This lower boiling fraction consists pre-
dominantly of C5-C7 aromatic hydrocarbons
with some unsaturated aliphatic hydrocar-
bons having a carbon number predomi-
L 353/853
nantly of C5. This stream may contain
benzene.]
L 353/854
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-320-00-8 Distillates (petroleum), naphtha-raffinate 270-344-6 68425-29-6 Carc. 1B H350 GHS08 H350 HP
pyrolyzate-derived, gasoline-blending; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[The complex combination of hydrocarbons
obtained by the pyrolysis fractionation at
816 oC (1500 oF) of naphtha and raffinate. It
consists predominantly of hydrocarbons
having a carbon number of C9 and boiling at
approximately 204 oC (400 oF).]
649-322-00-9 Distillates (petroleum), thermal cracked 271-631-9 68603-00-9 Carc. 1B H350 GHS08 H350 HP
naphtha and gas oil; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
produced by distillation of thermally cracked
naphtha and/or gas oil. It consists predom-
inantly of olefinic hydrocarbons having a
carbon number of C5 and boiling in the
31.12.2008
range of approximately 33 oC to 60 oC
(91 oF to 140 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-323-00-4 Distillates (petroleum), thermal cracked 271-632-4 68603-01-0 Carc. 1B H350 GHS08 H350 HP
naphtha and gas oil, C5-dimer-contg.; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
produced by the extractive distillation of
thermal cracked naphtha and/or gas oil. It
consists predominantly of hydrocarbons
having a carbon number of C5 with some
dimerized C5 olefins and boiling in the range
of approximately 33 oC to 184 oC (91 oF to
649-324-00-X Distillates (petroleum), thermal cracked 271-634-5 68603-03-2 Carc. 1B H350 GHS08 H350 HP
naphtha and gas oil, extractive; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
produced by the extractive distillation of
thermal cracked naphtha and/or gas oil. It
consists of paraffinic and olefinic hydro-
carbons, predominantly isoamylenes such as
2-methyl-1-butene and 2-methyl-2-butene
and boiling in the range of approximately
31 oC to 40 oC (88 oF to 104 oF).]
649-325-00-5 Distillates (petroleum), light thermal 273-266-0 68955-29-3 Carc. 1B H350 GHS08 H350 HP
cracked, debutanized arom.; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
produced by the distillation of products
from a thermal cracking process. It consists
predominantly of aromatic hydrocarbons,
L 353/855
primarily benzene.]
L 353/856
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-326-00-0 Naphtha (petroleum), light thermal cracked, 295-447-3 92045-65-3 Carc. 1B H350 GHS08 H350 HP
sweetened; Asp. Tox. 1 H304 Dgr H304
Low boiling point thermally cracked
naphtha;
[A complex combination of hydrocarbons
obtained by subjecting a petroleum distillate
from the high temperature thermal cracking
of heavy oil fractions to a sweetening
process to convert mercaptans. It consists
predominantly of aromatics, olefins and
saturated hydrocarbons boiling in the range
of approximately 20 oC to 100 oC (68 oF to
649-327-00-6 Naphtha (petroleum), hydrotreated heavy; 265-150-3 64742-48-9 Carc. 1B H350 GHS08 H350 HP
Low boiling point hydrogen treated Asp. Tox. 1 H304 Dgr H304
naphtha;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C6
through C13 and boiling in the range of
approximately 65 oC to 230 oC (149 oF to
446 oF).]
649-328-00-1 Naphtha (petroleum), hydrotreated light; 265-151-9 64742-49-0 Carc. 1B H350 GHS08 H350 HP
Low boiling point hydrogen treated Asp. Tox. 1 H304 Dgr H304
naphtha;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C4
through C11 and boiling in the range of
31.12.2008
approximately minus 20 oC to 190 oC (- 4 oF
to 374 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-329-00-7 Naphtha (petroleum), hydrodesulfurized 265-178-6 64742-73-0 Carc. 1B H350 GHS08 H350 HP
light; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained from a catalytic hydrodesulfuriza-
tion process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C4 through C11 and boiling in
the range of approximately minus 20 oC to
190 oC (- 4 oF to 374 oF).]
649-331-00-8 Distillates (petroleum), hydrotreated middle, 270-092-7 68410-96-8 Carc. 1B H350 GHS08 H350 HP
intermediate boiling; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by the distillation of products from
a middle distillate hydrotreating process. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C5
through C10 and boiling in the range of
approximately 127 oC to 188 oC (262 oF to
L 353/857
370 oF).]
L 353/858
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-332-00-3 Distillates (petroleum), light distillate 270-093-2 68410-97-9 Carc. 1B H350 GHS08 H350 HP
hydrotreating process, low-boiling; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by the distillation of products from
the light distillate hydrotreating process. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C6
through C9 and boiling in the range of
approximately 3 oC to 194 oC (37 oF to
382 oF).]
649-334-00-4 Solvent naphtha (petroleum), light arom., 270-988-8 68512-78-7 Carc. 1B H350 GHS08 H350 HP
hydrotreated; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists predominantly of aromatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C8 through C10
31.12.2008
and boiling in the range of approximately
135 oC to 210 oC (275 oF to 410 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-335-00-X Naphtha (petroleum), hydrodesulfurized 285-511-9 85116-60-5 Carc. 1B H350 GHS08 H350 HP
EN
thermal cracked light; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by fractionation of hydrodesulfur-
ized thermal cracker distillate. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C5 to C11 and boiling in the range of
approximately 23 oC to 195 oC (73 oF to
383 oF).]
649-337-00-0 Naphtha (petroleum), heavy steam-cracked, 295-432-1 92045-51-7 Carc. 1B H350 GHS08 H350 HP
hydrogenated; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated naphtha
649-338-00-6 Naphtha (petroleum), hydrodesulfurized 295-433-7 92045-52-8 Carc. 1B H350 GHS08 H350 HP
full-range; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained from a catalytic hydrodesulfuriza-
tion process. It consists predominantly of
hydrocarbons having carbon numbers pre-
L 353/859
dominantly in the range of C4 through C11
and boiling in the range of approximately
30 oC to 250 oC (86 oF to 482 oF).]
L 353/860
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-339-00-1 Naphtha (petroleum), hydrotreated light 295-438-4 92045-57-3 Carc. 1B H350 GHS08 H350 HP
steam-cracked; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction,
derived from a pyrolysis process, with
hydrogen in the presence of a catalyst. It
consists predominantly of unsaturated
hydrocarbons having carbon numbers pre-
dominantly in the range of C5 through C11
and boiling in the range of approximately
649-340-00-7 Hydrocarbons, C4-12, naphtha-cracking, 295-443-1 92045-61-9 Carc. 1B H350 GHS08 H350 HP
hydrotreated; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by distillation from the product of
a naphtha steam cracking process and
subsequent catalytic selective hydrogenation
of gum formers. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C4 through C12 and boiling in
the range of approximately 30 oC to 230 oC
(86 oF to 446 oF).]
649-341-00-2 Solvent naphtha (petroleum), hydrotreated 295-529-9 92062-15-2 Carc. 1B H350 GHS08 H350 HP
light naphthenic; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists predominantly of cycloparaffinic
hydrocarbons having carbon numbers pre-
31.12.2008
dominantly in the range of C6 through C7
and boiling in the range of approximately
73 oC to 85 oC (163 oF to 185 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-342-00-8 Naphtha (petroleum), light steam-cracked, 296-942-7 93165-55-0 Carc. 1B H350 GHS08 H350 HP
hydrogenated; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex comination of hydrocarbons
produced from the separation and subse-
quent hydrogenation of the products of a
steam-cracking process to produce ethylene.
It consists predominantly of saturated and
unsaturated paraffins, cyclic paraffins and
cyclic aromatic hydrocarbons having carbon
numbers predominantly in the range of C4
649-343-00-3 Hydrocarbons, C6-11, hydrotreated, dearo- 297-852-0 93763-33-8 Carc. 1B H350 GHS08 H350 HP
matized; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained as solvents which have been
subjected to hydrotreatment in order to
convert aromatics to naphthenes by catalytic
hydrogenation.]
649-344-00-9 Hydrocarbons, C9-12, hydrotreated, dearo- 297-853-6 93763-34-9 Carc. 1B H350 GHS08 H350 HP
matized; Asp. Tox. 1 H304 Dgr H304
Low boiling point hydrogen treated
naphtha;
[A complex combination of hydrocarbons
obtained as solvents which have been
subjected to hydrotreatment in order to
L 353/861
convert aromatics to naphthenes by catalytic
hydrogenation.]
L 353/862
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A colourless, refined petroleum distillate
that is free from rancid or objectionable
odors and that boils in a range of approxi-
mately 300 oF to 400 oF.]
649-346-00-X Natural gas condensates (petroleum); 265-047-3 64741-47-5 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
649-347-00-5 Natural gas (petroleum), raw liq. mix; 265-048-9 64741-48-6 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
separated as a liquid from natural gas in a
gas recycling plant by processes such as
refrigeration or absorption. It consists
mainly of saturated aliphatic hydrocarbons
having carbon numbers in the range of C2
through C8.]
649-348-00-0 Naphtha (petroleum), light hydrocracked; 265-071-4 64741-69-1 Carc. 1B H350 GHS08 H350 HP
Low boiling naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
from distillation of the products from a
hydrocracking process. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers predominantly in the range
31.12.2008
of C4 through C10, and boiling in the range
of approximately minus 20 oC to 180 oC
(- 4 oF to 356 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-349-00-6 Naphtha (petroleum), heavy hydrocracked; 265-079-8 64741-78-2 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
from distillation of the products from a
hydrocracking process. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers predominantly in the range
of C6 through C12, and boiling in the range
of approximately 65 oC to 230 oC (148 oF to
446 oF).]
649-351-00-7 Naphtha (petroleum), acid-treated; 265-115-2 64742-15-0 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained as a raffinate from a sulfuric acid
treating process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C7 through C12 and boiling in
the range of approximately 90 oC to 230 oC
(194 oF to 446 oF).]
649-352-00-2 Naphtha (petroleum), chemically neutralized 265-122-0 64742-22-9 Carc. 1B H350 GHS08 H350 HP
heavy; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
L 353/863
the range of C6 through C12 and boiling in
the range of approximately 65 oC to 230 oC
(149 oF to 446 oF).]
L 353/864
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-353-00-8 Naphtha (petroleum), chemically neutralized 265-123-6 64742-23-0 Carc. 1B H350 GHS08 H350 HP
EN
light; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C4 through C11 and boiling in
the range of approximately minus 20 oC to
190 oC (- 4 oF to 374 oF).]
649-355-00-9 Naphtha (petroleum), light steam-cracked; 265-187-5 64742-83-2 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained by the distillation of the products
from a steam cracking process. It consists
predominantly of unsaturated hydrocarbons
having carbon numbers predominantly in
the range of C4 through C11 and boiling in
the range of approximately minus 20 oC to
190 oC (- 4 oF to 374 oF). This stream is
likely to contain 10 vol.% or more benzene.]
649-356-00-4 Solvent naphtha (petroleum), light arom.; 265-199-0 64742-95-6 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained from distillation of aromatic
streams. It consists predominantly of aro-
matic hydrocarbons having carbon numbers
31.12.2008
predominantly in the range of C8 through
C10 and boiling in the range of approxi-
mately 135 oC to 210 oC (275 oF to
410 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-357-00-X Aromatic hydrocarbons, C6-10, acid-treated, 268-618-5 68131-49-7 Carc. 1B H350 GHS08 H350 HP
EN
neutralized; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified
649-358-00-5 Distillates (petroleum), C3-5, 2-methyl-2- 270-725-7 68477-34-9 Carc. 1B H350 GHS08 H350 HP
butene-rich; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
from the distillation of hydrocarbons usually
ranging in carbon numbers from C3 through
649-359-00-0 Distillates (petroleum), polymd. steam- 270-735-1 68477-50-9 Carc. 1B H350 GHS08 H350 HP
cracked petroleum distillates, C5-12 fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained from the distillation of polymer-
ized steam-cracked petroleum distillate. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C5 through C12.]]
649-360-00-6 Distillates (petroleum), steam-cracked, C5-12 270-736-7 68477-53-2 Carc. 1B H350 GHS08 H350 HP
fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of organic com-
pounds obtained by the distillation of
products from a steam cracking process. It
consists of unsaturated hydrocarbons having
carbon numbers predominantly in the range
of C5 through C12.]
649-361-00-1 Distillates (petroleum), steam-cracked, C5-10 270-738-8 68477-55-4 Carc. 1B H350 GHS08 H350 HP
L 353/865
fraction, mixed with light steam-cracked Asp. Tox. 1 H304 Dgr H304
petroleum naphtha C5 fraction;
Low boiling point naphtha — unspecified
L 353/866
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-362-00-7 Extracts (petroleum), cold-acid, C4-6; 270-741-4 68477-61-2 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of organic com-
pounds produced by cold acid unit extrac-
tion of saturated and unsaturated aliphatic
hydrocarbons usually ranging in carbon
numbers from C3 through C6, predomi-
nantly pentanes and amylenes. It consists
predominantly of saturated and unsaturated
hydrocarbons having carbon numbers in the
range of C4 through C6, predominantly C5.]
649-364-00-8 Residues (petroleum), butane splitter bot- 270-791-7 68478-12-6 Carc. 1B H350 GHS08 H350 HP
toms; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex residuum from the distillation of
butane stream. It consists of aliphatic
hydrocarbons having carbon numbers pre-
dominantly in the range of C4 through C6.]
649-365-00-3 Residual oils (petroleum), deisobutanizer 270-795-9 68478-16-0 Carc. 1B H350 GHS08 H350 HP
tower; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex residuum from the atmospheric
distillation of the butane-butylene stream. It
31.12.2008
consists of aliphatic hydrocarbons having
carbon numbers predominantly in the range
of C4 through C6.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-366-00-9 Naphtha (petroleum), full-range coker; 270-991-4 68513-02-0 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
produced by the distillation of products
from a fluid coker. It consists predominantly
of unsaturated hydrocarbons having carbon
numbers predominantly in the range of C4
through C15 and boiling in the range of
approximately 43 oC to 250 oC (110 oF to
500 oF).]
649-368-00-X Naphtha (petroleum), clay-treated full-range 271-262-3 68527-21-9 Carc. 1B H350 GHS08 H350 HP
straight-run; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of full-range
straight-run naphtha with natural or modi-
fied clay, usually in a percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C4 through C11
L 353/867
and boiling in the range of approximately
- 20 oC to 220 oC (- 4 oF to 429 oF).]
L 353/868
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-369-00-5 Naphtha (petroleum), clay-treated light 271-263-9 68527-22-0 Carc. 1B H350 GHS08 H350 HP
EN
straight-run; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of light straight-
run naphtha with a natural or modified clay,
usually in a percolation process to remove
the trace amounts of polar compounds and
impurities, present. It consists of hydro-
carbons having carbon numbers predomi-
nantly in the range of C7 through C10 and
boiling in the range of approximately 93 oC
to 180 oC (200 oF to 356 oF.]
649-371-00-6 Naphtha (petroleum), light steam-cracked, 271-266-5 68527-26-4 Carc. 1B H350 GHS08 H350 HP
debenzenized; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
produced by distillation of products from a
steam-cracking process. It consists pre-
dominantly of hydrocarbons having carbon
numbers predominantly in the range of C4
through C12 and boiling in the range of
approximately 80 oC to 218 oC (176 oF to
424 oF).]
31.12.2008
649-372-00-1 Naphtha (petroleum), arom.-contg.; 271-635-0 68603-08-7 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified Asp. Tox. 1 H304 Dgr H304
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-373-00-7 Gasoline, pyrolysis, debutanizer bottoms; 271-726-5 68606-10-0 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained from the fractionation of depro-
panizer bottoms. It consists of hydrocarbons
having carbon numbers predominantly
greater than C5.]
649-374-00-2 Naphtha (petroleum), light, sweetened; 272-206-0 68783-66-4 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
649-375-00-8 Natural gas condensates; 272-896-3 68919-39-1 Carc. 1B H350 GHS08 H350 HJ
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
separated and/or condensed from natural
gas during transportation and collected at
the wellhead and/or from the production,
gathering, transmission, and distribution
pipelines in deeps, scrubbers, etc. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C2 through C8.]
649-376-00-3 Distillates (petroleum), naphtha unifiner 272-932-8 68921-09-5 Carc. 1B H350 GHS08 H350 HP
stripper; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
produced by stripping the products from the
naphtha unifiner. It consists of saturated
L 353/869
aliphatic hydrocarbons having carbon
numbers predominantly in the range of C2
through C6.]
L 353/870
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-377-00-9 Naphtha (petroleum), catalytic reformed 285-510-3 85116-59-2 Carc. 1B H350 GHS08 H350 HP
EN
light, arom.-free fraction; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
remaining after removal of aromatic com-
pounds from catalytic reformed light
naphtha in a selective absorption process. It
consists predominantly of paraffinic and
cyclic compounds having carbon numbers
predominantly in the range of C5 to C8 and
boiling in the range of approximately 66 oC
to 121 oC (151 oF to 250 oF).]
649-379-00-X Aromatic hydrocarbons, C7-8, dealkylation 292-698-0 90989-42-7 Carc. 1B H350 GHS08 H350 HP
products, distn. residues; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified
649-380-00-5 Hydrocarbons, C4-6, depentanizer lights, 295-298-4 91995-38-9 Carc. 1B H350 GHS08 H350 HP
arom. hydrotreater; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained as first runnings from the depen-
tanizer column before hydrotreatment of the
aromatic charges. It consists predominantly
of hydrocarbons having carbon numbers
predominantly in the range of C4 through
31.12.2008
C6, predominantly pentanes and pentenes,
and boiling in the range of approximately
25 oC to 40 oC (77 oF to 104 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-381-00-0 Distillates (petroleum), heat-soaked steam- 295-302-4 91995-41-4 Carc. 1B H350 GHS08 H350 HP
cracked naphtha, C5-rich; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by distillation of heat-soaked
steam-cracked naphtha. It consists pre-
dominantly of hydrocarbons having carbon
numbers in the range of C4 through C6,
predominantly C5.]
649-383-00-1 Naphtha (petroleum), hydrodesulfurized 295-434-2 92045-53-9 Carc. 1B H350 GHS08 H350 HP
light, dearomatized; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by distillation of hydrodesulfurized
and dearomatized light petroleum fractions.
It consists predominantly of C7 paraffins and
cycloparaffins boiling in a range of
approximately 90 oC to 100 oC (194 oF to
L 353/871
212 oF).]
L 353/872
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-384-00-7 Naphtha (petroleum), light, C5-rich, sweet- 295-442-6 92045-60-8 Carc. 1B H350 GHS08 H350 HP
ened; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by subjecting a petroleum naphtha
to a sweetening process to convert mercap-
tans or to remove acidic impurities. It
consists of hydrocarbons having carbon
numbers predominantly in the range of C4
through C5, predominantly C5, and boiling
in the range of approximately minus 10 oC
to 35 oC (14 oF to 95 oF).]
649-386-00-8 Hydrocarbons, C4-11, naphtha-cracking, 295-445-2 92045-63-1 Carc. 1B H350 GHS08 H350 HP
arom.-free; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained from prehydrogenated cracked
naphtha after distillative separation of
benzene- and toluene-containing hydrocar-
bon cuts and a higher boiling fraction. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range C4 through C11 and boiling in the
31.12.2008
range of approximately 30 oC to 205 oC
(86 oF to 401 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-387-00-3 Naphtha (petroleum), light heat-soaked, 296-028-8 92201-97-3 Carc. 1B H350 GHS08 H350 HP
EN
steam-cracked; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by the fractionation of steam
cracked naphtha after recovery from a heat
soaking process. It consists predominantly
of hydrocarbons having a carbon numbers
predominantly in the range of C4 through C6
and boiling in the range of approximately
0 oC to 80 oC (32 oF to 176 oF.]
649-389-00-4 Gasoline, pyrolysis, hydrogenated; 302-639-3 94114-03-1 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A distillation fraction from the hydrogena-
tion of pyrolysis gasoline boiling in the
range of approximately 20 oC to 200 oC
(68 oF to 392 oF).]
649-390-00-X Distillates (petroleum), steam-cracked, C8-12 305-750-5 95009-23-7 Carc. 1B H350 GHS08 H350 HP
fraction, polymd., distn. lights; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by distillation of the polymerized
C8 through C12 fraction from steam-cracked
petroleum distillates. It consists predomi-
L 353/873
nantly of aromatic hydrocarbons having
carbon numbers predominantly in the range
of C8 through C12.]
L 353/874
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-391-00-5 Extracts (petroleum) heavy naphtha solvent, 308-261-5 97926-43-7 Carc. 1B H350 GHS08 H350 HP
clay-treated; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by the treatment of heavy naphthic
solvent petroleum extract with bleaching
earth. It consists predominantly of hydro-
carbons having carbon numbers predomi-
nantly in the range of C6 through C18 and
boiling in the range of approximately 80 oC
to 180 oC (175 oF to 356 oF).]
649-393-00-6 Naphtha (petroleum), light steam-cracked, 308-714-7 98219-47-7 Carc. 1B H350 GHS08 H350 HP
thermally treated; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by the treatment and distillation of
light steam-cracked petroleum naphtha. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C5 through C6 and boiling in
31.12.2008
the range of approximately 35 oC to 80 oC
(95 oF to 176 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-394-00-1 Distillates (petroleum), C7-9, C8-rich, hydro- 309-862-5 101316-56-7 Carc. 1B H350 GHS08 H350 HP
desulfurized dearomatized; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by the distillation of petroleum
light fraction, hydrodesulfurized and dear-
omatized. It consists predominantly of
hydrocarbons having carbon numbers in the
range of C7 through C9, predominantly C8
paraffins and cycloparaffins, boiling in the
range of approximately 120 oC to 130 oC
(248 oF to 266 oF).]
649-396-00-2 Naphtha (petroleum), hydrodesulfurized 309-879-8 101316-76-1 Carc. 1B H350 GHS08 H350 HP
full-range coker; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by fractionation from hydrodesul-
furized coker distillate. It consists predomi-
nantly of hydrocarbons having carbon
numbers predominantly in the range of C5
to C11 and boiling in the range of
L 353/875
approximately 23 oC to 196 oC (73 oF to
385 oF).]
L 353/876
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-397-00-8 Naphtha (petroleum), sweetened light; 309-976-5 101795-01-1 Carc. 1B H350 GHS08 H350 HP
EN
Low boiling point naphtha — unspecified; Asp. Tox. 1 H304 Dgr H304
[A complex combination of hydrocarbons
obtained by subjecting a petroleum naphtha
to a sweetening process to convert mercap-
tans or to remove acidic impurities. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C5 through C8 and boiling in
the range of approximately 20 oC to 130 oC
(68 oF to 266 oF).]
649-399-00-9 Hydrocarbons, C5-rich, dicyclopentadiene- 310-013-6 102110-15-6 Carc. 1B H350 GHS08 H350 HP
contg.; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by distillation of the products from
a stream-cracking process. It consists pre-
dominantly of hydrocarbons having carbon
numbers of C5 and dicyclopentadiene and
boiling in the range of approximately 30 oC
to 170 oC (86 oF to 338 oF).]
649-400-00-2 Residues (petroleum), steam-cracked light, 310-057-6 102110-55-4 Carc. 1B H350 GHS08 H350 HP
arom.; Asp. Tox. 1 H304 Dgr H304
Low boiling point naphtha — unspecified;
[A complex combination of hydrocarbons
obtained by the distillation of the products
of steam cracking or similar processes after
taking off the very light products resulting in
a residue starting with hydrocarbons having
carbon numbers greater than C5. It consists
31.12.2008
predominantly of aromatic hydrocarbons
having carbon numbers greater than C5 and
boiling above approximately 40 oC
(104 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
Low boiling point naphtha — unspecified Asp. Tox. 1 H304 Dgr H304
649-403-00-9 Aromatic hydrocarbons, C8-10; 292-695-4 90989-39-2 Carc. 1B H350 GHS08 H350 HP
Low boiling point naphtha — unspecified Asp. Tox. 1 H304 Dgr H304
649-405-00-X Solvent naphtha (petroleum), medium 265-191-7 64742-88-7 Asp. Tox. 1 H304 GHS08 H304 H
aliph.; Dgr
Straight run kerosine;
[A complex combination of hydrocarbons
obtained from the distillation of crude oil or
natural gasoline. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C9
through C12 and boiling in the range of
approximately 140 oC to 220 oC (284 oF to
428 oF).]
649-406-00-5 Solvent naphtha (petroleum) heavy aliph.; 265-200-4 64742-96-7 Asp. Tox. 1 H304 GHS08 H304 H
Straight run kerosine; Dgr
[A complex combination of hydrocarbons
obtained from the distillation of crude oil or
natural gasoline. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C11
L 353/877
through C16 and boiling in the range of
approximately 190 oC to 290 oC (374 oF to
554 oF).]
L 353/878
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-407-00-0 Kerosine (petroleum), straight-run wide-cut; 295-418-5 92045-37-9 Asp. Tox. 1 H304 GHS08 H304 H
EN
Straight run kerosine; Dgr
[A complex combination of hydrocarbons
obtained as a wide cut hydrocarbon fuel cut
from atmospheric distillation and boiling in
the range of approximately 70 oC to 220 oC
(158 oF to 428 oF).]
649-408-00-6 Distillates (petroleum), steam-cracked; 265-194-3 64742-91-2 Asp. Tox. 1 H304 GHS08 H304 H
Cracked kerosine; Dgr
649-409-00-1 Distillates (petroleum), cracked stripped 270-728-3 68477-39-4 Asp. Tox. 1 H304 GHS08 H304 H
steam-cracked petroleum distillates, C8-10 Dgr
fraction;
Cracked kerosine;
[A complex combination of hydrocarbons
obtained by distilling cracked stripped
steam-cracked distillates. It consists of
hydro-carbons having carbon numbers in
the range of C8 through C10 and boiling in
the range of approximately 129 oC to
194 oC (264 oF to 382 oF).]
649-410-00-7 Distillates (petroleum), cracked stripped 270-729-9 68477-40-7 Asp. Tox. 1 H304 GHS08 H304 H
steam-cracked petroleum distillates, C10-12 Dgr
fraction;
Cracked kerosine;
[A complex combination of hydrocarbons
obtained by distilling cracked stripped
steam-cracked distillates. It consists pre-
31.12.2008
dominantly of aromatic hydrocarbons hav-
ing carbon numbers in the range of C10
through C12.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-411-00-2 Distillates (petroleum), steam-cracked, C8-12 270-737-2 68477-54-3 Asp. Tox. 1 H304 GHS08 H304 H
fraction; Dgr
Cracked kerosine;
[A complex combination of organic com-
pounds obtained by the distillation of
products from a steam cracking process. It
consists predominantly of unsaturated
hydrocarbons having carbon numbers pre-
dominantly in the range of C8 through C12.]
649-413-00-3 Aromtic hydrocarbons, C≥10, steam-crack- 292-621-0 90640-98-5 Asp. Tox. 1 H304 GHS08 H304 H
ing, hydrotreated; Dgr
Cracked kerosine;
[A complex combination of hydrocarbons
produced by the distillation of the products
from a steam cracking process treated with
hydrogen in the presence of a catalyst. It
consists predominantly of aromatic hydro-
carbons having carbon numbers predomi-
nantly greater than C10 and boiling in the
range of approximately 150 oC to 320 oC
L 353/879
(302 oF to 608 oF).]
L 353/880
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-414-00-9 Naphtha (petroleum), steam-cracked, 292-637-8 90641-13-7 Asp. Tox. 1 H304 GHS08 H304 H
EN
hydrotreated, C9-10-arom.-rich; Dgr
Cracked kerosine;
[A complex combination of hydrocarbons
produced by the distillation of the products
from a steam cracking process thereafter
treated with hydrogen in the presence of a
catalyst. It consists predominantly of aro-
matic hydrocarbons having carbon numbers
in the range of C9 through C10 and boiling in
the range of approximately 140 oC to
200 oC (284 oF to 392 oF).]
649-416-00-X Distillates (petroleum), catalytic cracked 309-938-8 101631-13-4 Asp. Tox. 1 H304 GHS08 H304 H
heavy tar light; Dgr
Cracked kerosine;
[A complex combination of hydrocarbons
obtained by distillation of catalytic cracking
heavy tars. It consists predominantly of
highly alkylated aromatic hydrocarbons
boiling in the range of approximately
100 oC to 250 oC (212 oF to 482 oF).]
649-417-00-5 Solvent naphtha (petroleum), hydrocracked 309-881-9 101316-80-7 Asp. Tox. 1 H304 GHS08 H304 H
heavy arom.; Dgr
Cracked kerosine;
[A complex combination of hydrocarbons
obtained by the distillation of hydrocracked
petroleum distillate. It consists predomi-
nantly of hydrocarbons having carbon
31.12.2008
numbers predominantly in the range of C9
through C16 and boiling in the range of
approximately 235 oC to 290 oC (455 oF to
554 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-418-00-0 Distillates (petroleum), steam-cracked heavy 309-940-9 101631-15-6 Asp. Tox. 1 H304 GHS08 H304 H
EN
tar light; Dgr
Cracked kerosine;
[A complex combination of hydrocarbons
obtained by distillation of steam cracking
heavy tars. It consists predominantly of
highly alkylated aromatic hydrocarbons
boiling in the range of approximately
100 oC to 250 oC (212 oF to 482 oF).]
649-419-00-6 Distillates (petroleum), alkylate; 265-074-0 64741-73-7 Asp. Tox. 1 H304 GHS08 H304 H
649-420-00-1 Extracts (petroleum), heavy naphtha solvent; 265-099-7 64741-98-6 Asp. Tox. 1 H304 GHS08 H304 H
Kerosine — unspecified; Dgr
[A complex combination of hydrocarbons
obtained as the extract from a solvent
extraction process. It consists predominantly
of aromatic hydrocarbons having carbon
numbers predominantly in the range of C7
through C12 and boiling in the range of
approximately 90 oC to 220 oC (194 oF to
428 oF).]
649-421-00-7 Distillates (petroleum), chemically neutra- 265-132-5 64742-31-0 Asp. Tox. 1 H304 GHS08 H304 H
lized light; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
produced by a treating process to remove
acidic materials. It consists of hydrocarbons
having carbon numbers predominantly in
L 353/881
the range of C9 through C16 and boiling in
the range of approximately 150 oC to
290 oC (302 oF to 554 oF).]
L 353/882
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-422-00-2 Distillates (petroleum), hydrotreated light; 265-149-8 64742-47-8 Asp. Tox. 1 H304 GHS08 H304 H
EN
Kerosine — unspecified; Dgr
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C9
through C16 and boiling in the range of
approximately 150 oC to 290 oC (302 oF to
554 oF).]
649-424-00-3 Solvent naphtha (petroleum), heavy arom.; 265-198-5 64742-94-5 Asp. Tox. 1 H304 GHS08 H304 H
Kerosine — unspecified; Dgr
[A complex combination of hydrocarbons
obtained from distillation of aromatic
streams. It consists predominantly of aro-
matic hydrocarbons having carbon numbers
predominantly in the range of C9 through
C16 and boiling in the range of approxi-
mately 165 oC to 290 oC (330 oF to
554 oF).]
649-425-00-9 Naphtha (petroleum), heavy coker; 269-778-9 68333-23-3 Asp. Tox. 1 H304 GHS08 H304 H
Kerosine — unspecified; Dgr
[A complex combination of hydrocarbons
from the distillation of products from a fluid
coker. It consists predominantly of unsatu-
rated hydrocarbons having carbon numbers
31.12.2008
predominantly in the range of C6 through
C15 and boiling in the range of approxi-
mately 157 oC to 288 oC (315 oF to
550 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-426-00-4 Naphtha (petroleum), catalytic reformed 285-508-2 85116-57-0 Asp. Tox. 1 H304 GHS08 H304 H
EN
hydrodesulfurized heavy, arom. fraction; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
produced by fractionation from catalytically
reformed hydrodesulfurized naphtha. It
consists predominantly of aromatic hydro-
carbons having carbon numbers predomi-
nently in the range of C7 to C 13 and boiling
in the range of approximately 98 oC to
218 oC (208 oF to 424 oF).]
649-428-00-5 Kerosine (petroleum), solvent-refined sweet- 295-416-4 92045-36-8 Asp. Tox. 1 H304 GHS08 H304 H
ened; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
obtained from a petroleum stock by solvent
refining and sweetening and boiling in the
range of approximately 150 oC to 260 oC
(302 oF to 500 oF).]
649-429-00-0 Hydrocarbons, C9-16, hydrotreated, dearo- 297-854-1 93763-35-0 Asp. Tox. 1 H304 GHS08 H304 H
matized; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
obtained as solvents which have been
L 353/883
subjected to hydrotreatment in order to
convert aromatics to naphthenes by catalytic
hydrogenation.]
L 353/884
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-430-00-6 Kerosine (petroleum), solvent-refined 307-033-2 97488-94-3 Asp. Tox. 1 H304 GHS08 H304 H
EN
hydrodesulfurized; Dgr
Kerosine — unspecified
649-431-00-1 Distillates (petroleum), hydrodesulfurized 309-864-6 101316-58-9 Asp. Tox. 1 H304 GHS08 H304 H
full-range middle coker; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
obtained by fractionation from hydrodesul-
649-432-00-7 Solvent naphtha (petroleum), hydrodesul- 309-882-4 101316-81-8 Asp. Tox. 1 H304 GHS08 H304 H
furized heavy arom.; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
obtained by the catalytic hydrodesulfuriza-
tion of a petroleum fraction. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C10 through C13 and boiling in the range of
approximately 180 oC to 240 oC (356 oF to
464 oF).]
649-433-00-2 Solvent naphtha (petroleum), hydrodesul- 309-884-5 101316-82-9 Asp. Tox. 1 H304 GHS08 H304 H
furized medium; Dgr
Kerosine — unspecified;
[A complex combination of hydrocarbons
obtained by the catalytic hydrodesulfuriza-
tion of a petroleum fraction. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
31.12.2008
C10 through C13 and boiling in the range of
approximately 175 oC to 220 oC (347 oF to
428 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-434-00-8 Kerosine (petroleum), hydrotreated; 309-944-0 101631-19-0 Asp. Tox. 1 H304 GHS08 H304 H
Kerosine — unspecified; Dgr
[A complex combination of hydrocarbons
obtained from the distillation of petroleum
and subsequent hydrotreatment. It consists
predominantly of alkanes, cycloalkanes and
alkylbenzenes having carbon numbers pre-
dominantly in the range of C12 through C16
and boiling in the range of approximately
230 oC to 270 oC (446 oF to 518 oF).]
649-436-00-9 Distillates (petroleum), intermediate catalytic 265-062-5 64741-60-2 Carc. 1B H350 GHS08 H350 H
cracked; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
produced by the distillation of products
from a catalytic cracking process. It consists
of hydrocarbons having carbon numbers
predominantly in the range of C11 through
C30 and boiling in the range of approxi-
mately 205 oC to 450 oC (401 oF to 842 oF).
L 353/885
It contains a relatively large proportion of
tricyclic aromatic hydrocarbons.]
L 353/886
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-437-00-4 Distillates (petroleum), light hydrocracked; 265-078-2 64741-77-1 Carc. 2 H351 GHS08 H351 H
Cracked gasoil; Wng
[A complex combination of hydrocarbons
from distillation of the products from a
hydrocracking process. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers predominantly in the range
of C10 through C18 and boiling in the range
of approximately 160 oC to 320 oC (320 oF
to 608 oF).]
649-439-00-5 Distillates (petroleum), hydrodesulfurized 269-781-5 68333-25-5 Carc. 1B H350 GHS08 H350 H
light catalytic cracked; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained by treating light catalytic cracked
distillates with hydrogen to convert organic
sulfur to hydrogen sulfide which is removed.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C9
through C25 and boiling in the range of
approximately 150 oC to 400 oC (302 oF to
752 oF). It contains a relatively large
31.12.2008
proportion of bicyclic aromatic hydrocar-
bons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-440-00-0 Distillates (petroleum), light steam-cracked 270-662-5 68475-80-9 Carc. 1B H350 GHS08 H350 H
EN
naphtha; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
from the multiple distillation of products
from a steam cracking process. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C10 through C18.]
649-441-00-6 Distillates (petroleum), cracked steam- 270-727-8 68477-38-3 Carc. 1B H350 GHS08 H350 H
649-442-00-1 Gas oils (petroleum), steam-cracked; 271-260-2 68527-18-4 Carc. 1B H350 GHS08 H350 H
Cracked gasoil; Dgr
[A complex combination of hydrocarbons
produced by distillation of the products
from a steam cracking process. It consists of
hydrocarbons having carbon numbers pre-
dominantly greater than C9 and boiling in
the range of from approximately 205 oC to
400 oC (400 oF to 752 oF).]
649-443-00-7 Distillates (petroleum), hydrodesulfurized 285-505-6 85116-53-6 Carc. 1B H350 GHS08 H350 H
thermal cracked middle; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained by fractionation from hydrodesul-
furized themal cracker distillate stocks. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
L 353/887
the range of C11 to C25 and boiling in the
range of approximately 205 oC to 400 oC
(401 oF to 752 oF).]
L 353/888
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-444-00-2 Gas oils (petroleum), thermal-cracked, 295-411-7 92045-29-9 Carc. 1B H350 GHS08 H350 H
EN
hydrodesulfurized; Dgr
Cracked gasoil
649-445-00-8 Residues (petroleum), hydrogenated steam- 295-514-7 92062-00-5 Carc. 1B H350 GHS08 H350 H
cracked naphtha; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained as a residual fraction from the
649-446-00-3 Residues (petroleum), steam-cracked 295-517-3 92062-04-9 Carc. 1B H350 GHS08 H350 H
naphtha distn.; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained as a column bottom from the
separation of effluents from steam cracking
naphtha at a high temperature. It boils in the
range of approximately 147 oC to 300 oC
(297 oF to 572 oF) and produces a finished
oil having a viscosity of 18cSt at 50 oC.]
649-447-00-9 Distillates (petroleum), light catalytic 295-991-1 92201-60-0 Carc. 1B H350 GHS08 H350 H
cracked, thermally degraded; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
produced by the distillation of products
from a catalytic cracking process which has
been used as a heat transfer fluid. It consists
predominantly of hydrocarbons boiling in
31.12.2008
the range of approximately 190 oC to
340 oC (374 oF to 644 oF). This stream is
likely to contain organic sulfur compounds.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-448-00-4 Residues (petroleum), steam-cracked heat- 297-905-8 93763-85-0 Carc. 1B H350 GHS08 H350 H
soaked naphtha; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained as residue from the distillation of
steam cracked heat soaked naphtha and
boiling in the range of approximately
150 oC to 350 oC (302 oF to 662 oF).]
649-450-00-5 Gas oils (petroleum), light vacuum, thermal- 308-278-8 97926-59-5 Carc. 1B H350 GHS08 H350 H
cracked hydrodesulfurized; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
obtained by catalytic dehydrosulfurization of
thermal-cracked light vacuum petroleum. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C14 through C20 and boiling in
the range of approximately 270 oC to
L 353/889
370 oC (518 oF to 698 oF).]
L 353/890
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-451-00-0 Distillates (petroleum), hydrodesulfurized 309-865-1 101316-59-0 Carc. 1B H350 GHS08 H350 H
EN
middle coker; Dgr
Cracked gasoil;
[A complex combination of hydrocarbons
by fractionation from hydrodesulfurised
coker distillate stocks. Is consists of hydro-
carbons having carbon numbers predomi-
nantly in the range of C12 through C21 and
boiling in the range of approximately
200 oC to 360 oC (392 oF to 680 oF).]
649-453-00-1 Distillates (petroleum), heavy hydrocracked; 265-077-7 64741-76-0 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified; Dgr
[A complex combination of hydrocarbons
from the distillation of the products from a
hydrocracking process. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers in the range of C15-C39 and
boiling in the range of approximately
260 oC to 600 oC (500 oF to 1112 oF).]
649-454-00-7 Distillates (petroleum), solvent-refined heavy 265-090-8 64741-88-4 Carc. 1B H350 GHS08 H350 HL
paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C20
31.12.2008
through C50 and produces a finished oil with
a viscosity of at least 100 SUS at 100 oF
(19cSt at 40 oC).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-455-00-2 Distillates (petroleum), solvent-refined light 265-091-3 64741-89-5 Carc. 1B H350 GHS08 H350 HL
paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists predominantly
of saturated hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil with
a viscosity of less than 100 SUS at 100 oF
(19cSt at 40 oC).]
649-457-00-3 Distillates (petroleum), solvent-refined heavy 265-097-6 64741-96-4 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists of hydrocar-
bons having carbon numbers predominantly
in the range of C20 through C50 and
produces a finished oil with a viscosity of at
least 100 SUS at 100 oF (19cSt a 40 oC). It
L 353/891
contains relatively few normal paraffins.]
L 353/892
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-458-00-9 Distillates (petroleum), solvent-refined light 265-098-1 64741-97-5 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as the raffinate from a solvent
extraction process. It consists of hydrocar-
bons having carbon numbers predominantly
in the range of C15 through C30 and
produces a finished oil with a viscosity of
less than 100 SUS at 100 oF (19cSt at
40 oC). It contains relatively few normal
paraffins.]
649-460-00-X Distillates (petroleum), clay-treated paraffi- 265-137-2 64742-36-5 Carc. 1B H350 GHS08 H350 HL
nic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of a petroleum
fraction with natural or modified clay in
either a contacting or percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil with a viscosity
of at least 100 SUS at 100 oF (19cSt at
31.12.2008
40 oC). It contains a relatively large propor-
tion of saturated hydrocarbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-461-00-5 Distillates (petroleum), clay-treated light 265-138-8 64742-37-6 Carc. 1B H350 GHS08 H350 HL
EN
paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of a petroleum
fraction with natural or modified clay in
either a contacting or percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C15 through C30
and produces a finished oil with a viscosity
of less than 100 SUS at 100 oF (19cSt at
649-462-00-0 Residual oils (petroleum), clay-treated; 265-143-5 64742-41-2 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained by treatment of a residual oil with a
natural or modified clay in either a con-
tacting or percolation process to remove the
trace amounts of polar compounds and
impurities present. It consists of hydro-
carbons having carbon numbers predomi-
nantly higher than C25 and boiling above
approximately 400 oC (752 oF).]
649-463-00-6 Distillates (petroleum), clay-treated heavy 265-146-1 64742-44-5 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of a petroleum
fraction with natural or modified clay in
either a contacting or percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil with a viscosity
L 353/893
of at least 100 SUS at 100 oF (19cSt at
40 oC). It contains relatively few normal
paraffins.]
L 353/894
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-464-00-1 Distillates (petroleum), clay-treated light 265-147-7 64742-45-6 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
resulting from treatment of a petroleum
fraction with natural or modified clay in
either a contacting or percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C15 through C30
and produces a finished oil with a viscosity
649-465-00-7 Distillates (petroleum), hydrotreated heavy 265-155-0 64742-52-5 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C20
through C50 and produces a finished oil of at
least 100 SUS at 100 oF (19cSt at 40 oC). It
contains relatively few normal paraffins.]
649-466-00-2 Distillates (petroleum), hydrotreated light 265-156-6 64742-53-6 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil with
31.12.2008
a viscosity of less than 100 SUS at 100 oF
(19cSt at 40 oC). It contains relatively few
normal paraffins.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-467-00-8 Distillates (petroleum), hydrotreated heavy 265-157-1 64742-54-7 Carc. 1B H350 GHS08 H350 HL
paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C20
through C50 and produces a finished oil of at
least 100 SUS at 100 oF (19cSt at 40 oC). It
contains a relatively large proportion of
saturated hydrocarbons.]
649-469-00-9 Distillates (petroleum), solvent-dewaxed 265-159-2 64742-56-9 Carc. 1B H350 GHS08 H350 HL
light paraffinic; Dgr
Baseoil — unspecified;
[A complex comination of hydrocarbons
obtained by removal of normal paraffins
from a petroleum fraction by solvent
crystallization. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C15 through C30
and produces a finished oil with a viscosity
L 353/895
of less than 100 SUS at 100 oF (19cSt at
40 oC).]
L 353/896
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-470-00-4 Residual oils (petroleum), hydrotreated; 265-160-8 64742-57-0 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified; Dgr
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst.
It consists of hydrocarbons having carbon
numbers predominantly greater than C25
and boiling above approximately 400 oC
(752 oF).]
649-472-00-5 Distillates (petroleum), solvent-dewaxed 265-167-6 64742-63-8 Carc. 1B H350 GHS08 H350 HL
heavy naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by removal of normal paraffins
from a petroleum fraction by solvent
crystallization. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C20 . through C50 and produces
a finished oil of not less than 100 SUS at
100 oF (19cSt at 40 oC). It contains relatively
31.12.2008
few normal paraffins.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-473-00-0 Distillates (petroleum), solvent-dewaxed 265-168-1 64742-64-9 Carc. 1B H350 GHS08 H350 HL
light naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by removal of normal paraffins
from a petroleum fraction by solvent
crystallization. It consists of hydrocarbons
having carbon numbers predominantly in
the range C15 through C30 and produces a
finished oil with a viscosity of less than
100 SUS at 100 oF (19cSt at 40 oC). It
649-474-00-6 Distillates (petroleum), solvent-dewaxed 265-169-7 64742-65-0 Carc. 1B H350 GHS08 H350 HL
heavy paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by removal of normal paraffins
from a petroleum fraction by solvent
crystallization. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil with a viscosity
not less than 100 SUS at 100 oF (19cSt at
40 oC).]
649-475-00-1 Naphthenic oils (petroleum), catalytic 265-172-3 64742-68-3 Carc. 1B H350 GHS08 H350 HL
dewaxed heavy; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from a catalytic dewaxing process.
It consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50 and produces a
finished oil with a viscosity of at least
L 353/897
100 SUS at 100 oF (19cSt at 40 oC). It
contains relatively few normal paraffins.]
L 353/898
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-476-00-7 Naphthenic oils (petroleum), catalytic 265-173-9 64742-69-4 Carc. 1B H350 GHS08 H350 HL
dewaxed light; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from a catalytic dewaxing process.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil with
a viscosity less than 100 SUS at 100 oF
(19cSt at 40 oC). It contains relatively few
normal paraffins.]
649-478-00-8 Paraffin oils (petroleum), catalytic dewaxed 265-176-5 64742-71-8 Carc. 1B H350 GHS08 H350 HL
light; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from a catalytic dewxing process. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C15 through C30 and produces a
finished oil with a viscosity of less than
31.12.2008
100 SUS at 100 oF (19cSt at 40 oC).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-479-00-3 Naphthenic oils (petroleum), complex 265-179-1 64742-75-2 Carc. 1B H350 GHS08 H350 HL
EN
dewaxed heavy; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by removing straight chain paraffin
hydrocarbons as a solid by treatment with
an agent such as urea. It consists of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil having a
viscosity of at least 100 SUS at 100 oF
(19cSt at 40 oC). It contains relatively few
649-480-00-9 Naphthenic oils (petroleum), complex 265-180-7 64742-76-3 Carc. 1B H350 GHS08 H350 HL
dewaxed light; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from a catalytic dewaxing process.
It consists of hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil
having a viscosity less than 100 SUS at 100
o
F (19cSt at 40 oC). It contains relatively few
normal paraffins.]
649-481-00-4 Lubricating oils (petroleum), C20-50, hydro- 276-736-3 72623-85-9 Carc. 1B H350 GHS08 H350 HL
treated neutral oil-based, high-viscosity; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating light vacuum gas oil,
heavy vacuum gas oil, and solvent deas-
phalted residual oil with hydrogen in the
presence of a catalyst in a two stage process
with dewaxing being carried out between
the two stages. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil having a
viscosity of approximately 112cSt at 40 oC.
L 353/899
It contains a relatively large proportion of
saturated hydrocarbons.]
L 353/900
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-482-00-X Lubricating oils (petroleum), C15-30, hydro- 276-737-9 72623-86-0 Carc. 1B H350 GHS08 H350 HL
EN
treated neutral oil-based; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating light vacuum gas oil
and heavy vacuum gas oil with hydrogen in
the presence of a catalyst in a two stage
process with dewaxing being carried out
between the two stages. It consists predo-
minantly of hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil
649-483-00-5 Lubricating oils (petroleum), C20-50, hydro- 276-738-4 72623-87-1 Carc. 1B H350 GHS08 H350 HL
treated neutral oil-based; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating light vacuum gas oil,
heavy vacuum gas oil and solvent deas-
phalted residual oil with hydrogen in the
presence of a catalyst in a two stage process
with dewaxing being carried out between
the two stages. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil with a viscosity
of approximately 32cSt at 40 oC. It contains
a relatively large proportion of saturated
hydrocarbons.]
31.12.2008
nantly of saturated hydrocarbons having
carbon numbers in the range C15 through
C50.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-485-00-6 Distillates (petroleum), complex dewaxed 292-613-7 90640-91-8 Carc. 1B H350 GHS08 H350 HL
heavy paraffinci; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by dewaxing heavy paraffinic
distillate. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50
and produces a finished oil with a viscosity
of equal to or greater than 100 SUS at
100 oF (19cSt at 40 oC). It contains relatively
649-486-00-1 Distillates (petroleum), complex dewaxed 292-614-2 90640-92-9 Carc. 1B H350 GHS08 H350 HL
light paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by dewaxing light paraffinic dis-
tillate. It consists predominantly of hydro-
carbons having carbon numbers
predominantly in the range of C12 through
C30 and produces a finished oil with a
viscosity of less than 100 SUS at 100 oF
(19cSt at 40 oC). It contains relatively few
normal paraffins.]
649-487-00-7 Distillates (petroleum), solvent dewaxed 292-616-3 90640-94-1 Carc. 1B H350 GHS08 H350 HL
heavy paraffinic, clay-treated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating dewaxed heavy paraf-
finic distillate with neutral or modified clay
in either a contacting or percolation process.
It consists predominantly of hydrocarbons
L 353/901
having carbon numbers predominantly in
the range of C20 through C50.]
L 353/902
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-488-00-2 Hydrocarbons, C20-50, solvent dewaxed 292-617-9 90640-95-2 Carc. 1B H350 GHS08 H350 HL
EN
heavy paraffinic, hydrotreated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
produced by treating dewaxed heavy paraf-
finic distillate with hydrogen in the presence
of a catalyst. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50.]
649-490-00-3 Distillates (petroleum), solvent dewaxed light 292-620-5 90640-97-4 Carc. 1B H350 GHS08 H350 HL
paraffinic, hydrotreated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
produced by treating a dewaxed light
paraffinic distillate with hydrogen in the
presence of a catalyst. It consists predomi-
nantly of hydrocarbons having carbon
numbers predominantly in the range of C15
through C30.]
649-491-00-9 Residual oils (petroleum), hydrotreated sol- 292-656-1 90669-74-2 Carc. 1B H350 GHS08 H350 HL
vent dewaxed; Dgr
Baseoil — unspecified
31.12.2008
649-492-00-4 Residual oils (petroleum), catalytic dewaxed; 294-843-3 91770-57-9 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-493-00-X Distillates (petroleum), dewaxed heavy par- 295-300-3 91995-39-0 Carc. 1B H350 GHS08 H350 HL
affinic, hydrotreated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from an intensive treatment of
dewaxed distillate by hydrogenation in the
presence of a catalyst. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers predominantly in the range
of C25 through C39 and produces a finished
oil with a viscosity of approximately 44 cSt
649-494-00-5 Distillates (petroleum), dewaxed light paraf- 295-301-9 91995-40-3 Carc. 1B H350 GHS08 H350 HL
finic, hydrotreated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from an intensive treatment of
dewaxed distillate by hydrogenation in the
presence of a catalyst. It consists predomi-
nantly of saturated hydrocarbons having
carbon numbers predominantly in the range
of C21 through C29 and produces a finished
oil with a viscosity of approximately 13 cSt
at 50 oC.]
649-495-00-0 Distillates (petroleum), hydrocracked sol- 295-306-6 91995-45-8 Carc. 1B H350 GHS08 H350 HL
vent-refined, dewaxed; Dgr
Baseoil — unspecified;
[A complex combination of liquid hydro-
carbons obtained by recrystallization of
dewaxed hydrocracked solvent-refined
L 353/903
petroleum distillates.]
L 353/904
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-496-00-6 Distillates (petroleum), solvent-refined light 295-316-0 91995-54-9 Carc. 1B H350 GHS08 H350 HL
EN
naphthenic, hydrotreated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treating a petroleum fraction
with hydrogen in the presence of a catalyst
and removing the aromatic hydrocarbons by
solvent extraction. It consists predominantly
of naphthenic hydrocarbons having carbon
numbers predominantly in the range of C15
through C30 and produces a finished oil with
a viscosity of between 13-15cSt at 40 oC.]
649-498-00-7 Lubricating oils (petroleum), hydrocracked 295-424-8 92045-43-7 Carc. 1B H350 GHS08 H350 HL
nonarom. solvent-deparaffined; Dgr
Baseoil — unspecified
649-499-00-2 Residual oils (petroleum), hydrocracked 295-499-7 92061-86-4 Carc. 1B H350 GHS08 H350 HL
acid-treated solvent-dewaxed; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
produced by solvent removal of paraffins
from the residue of the distillation of acid-
treated, hydrocracked heavy paraffins and
boiling approximately above 380 oC
(716 oF).]
649-500-00-6 Paraffin oils (petroleum), solvent-refined 295-810-6 92129-09-4 Carc. 1B H350 GHS08 H350 HL
dewaxed heavy; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained from sulfur-containing paraffinic
31.12.2008
crude oil. It consists predominantly of a
solvent refined deparaffinated lubricating oil
with a viscosity of 65cSt at 50 oC.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-501-00-1 Lubricating oils (petroleum), base oils, 297-474-6 93572-43-1 Carc. 1B H350 GHS08 H350 HL
EN
paraffinic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by refining of crude oil. It consists
predominantly of aromatics, naphthenics
and paraffinics and produces a finished oil
with a viscosity of 120 SUS at 100 oF (23cSt
at 40 oC).]
649-503-00-2 Hydrocarbons, C20-50, residual oil hydroge- 300-257-1 93924-61-9 Carc. 1B H350 GHS08 H350 HL
nation vacuum distillate; Dgr
Baseoil — unspecified
649-504-00-8 Distillates (petroleum), solvent-refined 305-588-5 94733-08-1 Carc. 1B H350 GHS08 H350 HL
hydrotreated heavy; Dgr
hydrogenated;
Baseoil — unspecified
649-505-00-3 Distillates (petroleum), solvent-refined 305-589-0 94733-09-2 Carc. 1B H350 GHS08 H350 HL
hydrocracked light; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by solvent dearomatization of the
residue of hydrocracked petroleum. It con-
sists predominantly of hydrocarbons having
carbon numbers predominantly in the range
of C18 through C27 and boiling in the range
L 353/905
of approximately 370 oC to 450 oC (698 oF
to 842 oF).]
L 353/906
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-506-00-9 Lubricating oils (petroleum), C18-40, solvent- 305-594-8 94733-15-0 Carc. 1B H350 GHS08 H350 HL
EN
dewaxed hydrocracked distillate-based; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by solvent deparaffination of the
distillation residue from hydrocracked
petroleum. It consists predominantly of
hydrocarbons having carbon numbers pre-
dominantly in the range of C18 through C40
and boiling in the range of approximately
370 oC to 550 oC (698 oF to 1022 oF).]
649-508-00-X Hydrocarbons, C13-30, arom.-rich, solvent- 305-971-7 95371-04-3 Carc. 1B H350 GHS08 H350 HL
extd. naphthenic distillate; Dgr
Baseoil — unspecified
649-509-00-5 Hydrocarbons, C16-32, arom. rich, solvent- 305-972-2 95371-05-4 Carc. 1B H350 GHS08 H350 HL
extd. naphthenic distillate; Dgr
Baseoil — unspecified
649-510-00-0 Hydrocarbons, C37-68, dewaxed deasphalted 305-974-3 95371-07-6 Carc. 1B H350 GHS08 H350 HL
hydrotreated vacuum distn. residues; Dgr
Baseoil — unspecified
31.12.2008
649-511-00-6 Hydrocarbons, C37-65, hydrotreated deas- 305-975-9 95371-08-7 Carc. 1B H350 GHS08 H350 HL
phalted vacuum distn. residues; Dgr
Baseoil — unspecified
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-512-00-1 Distillates (petroleum), hydrocracked sol- 307-010-7 97488-73-8 Carc. 1B H350 GHS08 H350 HL
EN
vent-refined light; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by the solvent treatment of a
distillate from hydrocracked petroleum dis-
tillates. It consists predominantly of hydro-
carbons having carbon numbers
predominantly in the range of C18 through
C27 and boiling in the range of approxi-
mately 370 oC to 450 oC (698 oF to 842 oF.]
649-514-00-2 Lubricating oils (petroleum), C18-27, hydro- 307-034-8 97488-95-4 Carc. 1B H350 GHS08 H350 HL
cracked solvent-dewaxed; Dgr
Baseoil — unspecified
649-515-00-8 Hydrocarbons, C17-30, hydrotreated solvent- 307-661-7 97675-87-1 Carc. 1B H350 GHS08 H350 HL
deasphalted atm. distn. residue, distn. lights; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as first runnings from the vacuum
distillation of effluents from the treatment of
a solvent deasphalted short residue with
hydrogen in the presence of a catalyst. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C17 through C30 and boiling in
the range of approximately 300 oC to
L 353/907
400 oC (572 oF to 752 oF). It produces a
finished oil having a viscosity of 4cSt at
approximately 100 oC (212 oF).]
L 353/908
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-516-00-3 Hydrocarbons, C17-40, hydrotreated solvent- 307-755-8 97722-06-0 Carc. 1B H350 GHS08 H350 HL
EN
deasphalted distn. residue, vacuum distn. Dgr
lights;
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained as first runnings from the vacuum
distillation of effluents from the catalytic
hydrotreatment of a solvent deasphalted
short residue having a viscosity of 8cSt at
approximately 100 oC (212 oF). It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C17 through C40 and boiling in the range of
649-517-00-9 Hydrocarbons, C13-27, solvent-extd. light 307-758-4 97722-09-3 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by extraction of the aromatics
from a light naphthenic distillate having a
viscosity of 9.5cSt at 40 oC (104 oF). It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C13 through C27 and boiling in
the range of approximately 240 oC to
400 oC (464 oF to 752 oF).]
649-518-00-4 Hydrocarbons, C14-29, solvent-extd. light 307-760-5 97722-10-6 Carc. 1B H350 GHS08 H350 HL
naphthenic; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by extraction of the aromatics
from a light naphthenic distillate having a
viscosity of 16cSt at 40 oC (104 oF). It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C14 through C29 and boiling in
the range of approximately 250 oC to
425 oC (482 oF to 797 oF).]
31.12.2008
649-519-00-X Hydrocarbons, C27-42, dearomatized; 308-131-8 97862-81-2 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-520-00-5 Hydrocarbons, C17-30, hydrotreated distil- 308-132-3 97862-82-3 Carc. 1B H350 GHS08 H350 HL
EN
lates, distn. lights; Dgr
Baseoil — unspecified
649-521-00-0 Hydrocarbons, C27-45, naphthenic vacuum 308-133-9 97862-83-4 Carc. 1B H350 GHS08 H350 HL
distn.; Dgr
Baseoil — unspecified
649-523-00-1 Hydrocarbons, C20-58, hydrotreated; 308-289-8 97926-70-0 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified Dgr
649-524-00-7 Hydrocarbons, C27-42, naphthenic; 308-290-3 97926-71-1 Carc. 1B H350 GHS08 H350 HL
Baseoil — unspecified Dgr
649-525-00-2 Residual oils (petroleum), carbon-treated 309-710-8 100684-37-5 Carc. 1B H350 GHS08 H350 HL
solvent-dewaxed; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by the treatment of solvent-
dewaxed petroleum residual oils with acti-
vated charcoal for the removal of trace polar
constituents and impurities.]
649-526-00-8 Residual oils (petroleum), clay-treated sol- 309-711-3 100684-38-6 Carc. 1B H350 GHS08 H350 HL
vent-dewaxed; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by treatment of solvent-dewaxed
L 353/909
petroleum residual oils with bleaching earth
for the removal of trace polar constituents
and impurities.]
L 353/910
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-527-00-3 Lubricating oils (petroleum), C>25, solvent- 309-874-0 101316-69-2 Carc. 1B H350 GHS08 H350 HL
extd., deasphalted, dewaxed, hydrogenated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by solvent extraction and hydro-
genation of vacuum distillation residues. It
consists predominantly of hydrocarbons
having carbon numbers predominantly
greater than C25 and produces a finished oil
with a viscosity in the order of 32cSt to
37cSt at 100 oC (212 oF).]
649-529-00-4 Lubricating oils (petroleum), C20-35, solvent- 309-876-1 101316-71-6 Carc. 1B H350 GHS08 H350 HL
extd., dewaxed, hydrogenated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by solvent extraction and hydro-
genation of atmospheric distillation residues.
It consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C20 through C35 and produces a
31.12.2008
finished oil with a viscosity in the order of
37cSt to 44cSt at 40 oC (104 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-530-00-X Lubricating oils (petroleum), C24-50, solvent- 309-877-7 101316-72-7 Carc. 1B H350 GHS08 H350 HL
extd., dewaxed, hydrogenated; Dgr
Baseoil — unspecified;
[A complex combination of hydrocarbons
obtained by solvent extraction and hydro-
genation of atmospheric distillation residues.
It consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C24 through C50 and produces a
finished oil with a viscosity in the order of
16cSt to 75cSt at 40 oC (104 oF).]
649-532-00-0 Extracts (petroleum), solvent-refined heavy 272-180-0 68783-04-0 Carc. 1B H350 GHS08 H350 HL
paraffinic distillate solvent; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained as the extract from the re-extrac-
tion of solvent-refined heavy paraffinic
distillate. It consists of saturated and aro-
matic hydrocarbons having carbon numbers
predominantly in the range of C20 through
C50.]
649-533-00-6 Extracts (petroleum), heavy paraffinic dis- 272-342-0 68814-89-1 Carc. 1B H350 GHS08 H350 HL
tillates, solvent-deasphalted; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
L 353/911
obtained as the extract from a solvent
extraction of heavy paraffinic distillate.]
L 353/912
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-534-00-1 Extracts (petroleum), heavy naphthenic dis- 292-631-5 90641-07-9 Carc. 1B H350 GHS08 H350 HL
tillate solvent, hydrotreated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained by treating a heavy naphthenic
distillate solvent extract with hydrogen in
the presence of a catalyst. It consists
predominantly of aromatic hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50 and produces a
finished oil of at least 19cSt at 40 oC
(100 SUS at 100 oF).]
649-536-00-2 Extracts (petroleum), light paraffinic distil- 292-633-6 90641-09-1 Carc. 1B H350 GHS08 H350 HL
late solvent, hydrotreated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
produced by treating a light paraffinic
distillate solvent extract with hydrogen in
the presence of a catalyst. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C17 through C26 and boiling in the range of
31.12.2008
approximately 280 oC to 400 oC (536 oF to
752 oF).]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-537-00-8 Extracts (petroleum), hydrotreated light par- 295-335-4 91995-73-2 Carc. 1B H350 GHS08 H350 HL
affinic distillate solvent; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained as the extract from solvent extrac-
tion of intermediate paraffinic top solvent
distillate that is treated with hydrogen in the
presence of a catalyst. It consists predomi-
nantly of aromatic hydrocarbons having
carbon numbers predominantly in the range
of C16 through C36.]
649-539-00-9 Extracts (petroleum), light paraffinic distil- 295-339-6 91995-76-5 Carc. 1B H350 GHS08 H350 HL
late solvent, acid-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained as a fraction of the distillation of an
extract from the solvent extraction of light
paraffinic top petroleum distillates that is
subjected to a sulfuric acid refining. It
consists predominantly of aromatic hydro-
L 353/913
carbons having carbon numbers predomi-
nantly in the range of C16 through C32.]
L 353/914
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-540-00-4 Extracts (petroleum), light paraffinic distil- 295-340-1 91995-77-6 Carc. 1B H350 GHS08 H350 HL
late solvent, hydrodesulfurized; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained by solvent extraction of a light
paraffin distillate and treated with hydrogen
to convert the organic sulfur to hydrogen
sulfide which is eliminated. It consists
predominantly of hydrocarbons having car-
bon numbers predominantly in the range of
C15 through C40 and produces a finished oil
with a viscosity of greater than 10cSt at
649-541-00-X Extracts (petroleum), light vacuum gas oil 295-342-2 91995-79-8 Carc. 1B H350 GHS08 H350 HL
solvent, hydrotreated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons,
obtained by solvent extraction from light
vacuum petroleum gas oils and treated with
hydrogen in the presence of a catalyst. It
consists predominantly of aromatic hydro-
carbons having carbon numbers predomi-
nantly in the range of C13 through C30.]
649-542-00-5 Extracts (petroleum), heavy paraffinic dis- 296-437-1 92704-08-0 Carc. 1B H350 GHS08 H350 HL
tillate solvent, clay-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
resulting from treatment of a petroleum
fraction with natural or modified clay in
either a contact or percolation process to
remove the trace amounts of polar com-
pounds and impurities present. It consists
predominantly of aromatic hydrocarbons
having carbon numbers predominantly in
the range of C20 through C50. This stream is
31.12.2008
likely to contain 5 wt.% or more 4-6
membered ring aromatic hydrocarbons.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-543-00-0 Extracts (petroleum), heavy naphthenic dis- 297-827-4 93763-10-1 Carc. 1B H350 GHS08 H350 HL
tillate solvent, hydrodesulfurized; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained from a petroleum stock by treating
with hydrogen to convert organic sulfur to
hydrogen sulfide which is removed. It
consists predominantly of hydrocarbons
having carbon numbers predominantly in
the range of C15 through C50 and produces a
finished oil with a viscosity of greater than
19cSt at 40 oC.]
649-545-00-1 Extracts (petroleum), light paraffinic distil- 309-672-2 100684-02-4 Carc. 1B H350 GHS08 H350 HL
late solvent, carbon-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained as a fraction from distillation of an
extract recovered by solvent extraction of
light paraffinic top petroleum distillate
treated with activated charcoal to remove
traces of polar constituents and impurities. It
consists predominantly of aromatic hydro-
L 353/915
carbons having carbon numbers predomi-
nantly in the range of C16 through C32.]
L 353/916
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
649-546-00-7 Extracts (petroleum), light paraffinic distil- 309-673-8 100684-03-5 Carc. 1B H350 GHS08 H350 HL
late solvent, clay-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained as a fraction from distillation of an
extract recovered by solvent extraction of
light paraffinic top petroleum distillates
treated with bleaching earth to remove
traces of polar constituents and impurities. It
consists predominantly of aromatic hydro-
carbons having carbon numbers predomi-
649-547-00-2 Extracts (petroleum), light vacuum, gas oil 309-674-3 100684-04-6 Carc. 1B H350 GHS08 H350 HL
solvent, carbon-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained by solvent extraction of light
vacuum petroleum gas oil treated with
activated charcoal for the removal of trace
polar constituents and impurities. It consists
predominantly of aromatic hydrocarbons
having carbon numbers predominantly in
the range of C13 through C30.]
649-548-00-8 Extracts (petroleum), light vacuum gas oil 309-675-9 100684-05-7 Carc. 1B H350 GHS08 H350 HL
solvent, clay-treated; Dgr
Distillate aromatic extract (treated);
[A complex combination of hydrocarbons
obtained by solvent extraction of light
vacuum petroleum gas oils treated with
bleaching earth for removal of trace polar
constituents and impurities. It consists
predominantly of aromatic hydrocarbons
31.12.2008
having carbon numbers predominantly in
the range of C13 through C30.]
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
649-549-00-3 Foots oil (petroleum); 265-171-8 64742-67-2 Carc. 1B H350 GHS08 H350 HL
EN
Foots oil; Dgr
[A complex combination of hydrocarbons
obtained as the oil fraction from a solvent
deoiling or a wax sweating process. It
consists predominantly of branched chain
hydrocarbons having carbon numbers pre-
dominantly in the range of C20 through C50.]
650-002-00-6 turpentine, oil 232-350-7 8006-64-2 Flam. Liq. 3 H226 GHS02 H226
Acute Tox. 4 * H332 GHS08 H332
Acute Tox. 4 * H312 GHS07 H312
Acute Tox. 4 * H302 GHS09 H302
Asp. Tox. 1 H304 Dgr H304
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Aquatic H411 H411
Chronic 2
650-003-00-1 fenson (ISO); 201-274-6 80-38-6 Acute Tox. 4 * H302 GHS07 H302
4-chlorophenyl benzenesulphonate; Eye Irrit. 2 H319 GHS09 H319
Aquatic H411 Wng H411
Chronic 2
650-004-00-7 norbormide (ISO); 213-589-6 991-42-4 Acute Tox. 4 * H302 GHS07 H302
5-(α-hydroxy-α-2-pyridylbenzyl)-7-(α-2-pyr- Wng
L 353/917
idylbenzylidene)bicyclo [2.2.1] hept-5-ene-
2,3-dicarboximide
L 353/918
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
2-isopropenyl-8,9-dimethoxychromeno[3,4- Eye Irrit. 2 H319 GHS09 H319
b]furo[2,3-h]chromen-6-one, rotenone STOT SE 3 H335 Dgr H335
Skin Irrit. 2 H315 H315
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
650-006-00-8 benquinox (ISO); 207-807-9 495-73-8 Acute Tox. 3 * H301 GHS06 H301
p-benzoquinone 1-benzoylhydrazone Acute Tox. 4 * H312 Dgr H312
4-oxime
650-008-00-9 drazoxolon (ISO); 227-197-8 5707-69-7 Acute Tox. 3 * H301 GHS06 H301
4-(2-chlorophenylhydrazone)-3-methyl-5- Aquatic Acute 1 H400 GHS09 H410
isoxazolone Aquatic H410 Dgr
Chronic 1
650-010-00-X benzyl violet 4B; 216-901-9 1694-09-3 Carc. 2 H351 GHS08 H351
α-[4-(4-dimethylamino-α-{4-[ethyl(3-sodio- Wng
sulphonatobenzyl)amino] phenyl}benzyli-
dene)cyclohexa-2,5-dienylidene(ethyl)
ammonio]toluene-3-sulphonate
31.12.2008
650-012-00-0 erionite — 12510-42-8 Carc. 1A H350 GHS08 H350
Dgr
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
650-013-00-6 asbestos — 12001-28-4 Carc. 1A H350 GHS08 H350
— 132207-32-0 STOT RE 1 H372 Dgr H372 **
— 12172-73-5 **
— 77536-66-4
— 77536-68-6
— 77536-67-5
— 12001-29-5
650-016-00-2 Mineral wool, with the exception of those — — Carc. 2 H351 GHS08 H351 AQR
specified elsewhere in this Annex; Skin Irrit. 2 H315 GHS07 H315
[Man-made vitreous (silicate) fibres with Wng
random orientation with alkaline oxide and
alkali earth oxide (Na2O+K2O+CaO+MgO+
BaO) content greater than 18 % by weight]
L 353/919
BaO) content less or equal to 18 % by
weight]
L 353/920
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
650-018-00-3 Reaction product of: acetophenone, formal- 406-230-1 — Flam. Liq. 3 H226 GHS02 H226
EN
dehyde, cyclohexylamine, methanol and Carc. 2 H351 GHS08 H351
acetic acid Skin Corr. 1B H314 GHS05 GHS07 H314
Acute Tox. 4 * H332 GHS09 H332
Skin Sens. 1 H317 Dgr H317
Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
650-031-00-4 bis(4-hydroxy-N-methylanilinium) sulphate 200-237-1 55-55-0 Acute Tox. 4 * H302 GHS08 H302
650-042-00-4 reaction product of: polyethylene-polya- 417-450-2 — Eye Irrit. 2 H319 GHS07 H319
mine-(C16-C18)-alkylamides with monothio- Skin Irrit. 2 H315 Wng H315
31.12.2008
(C2)-alkyl phosphonates Skin Sens. 1 H317 H317
Aquatic H412 H412
Chronic 3
31.12.2008
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
650-043-00-X reaction product of: 3,5-bis-tert-butylsa- 420-310-3 — Acute Tox. 4 * H302 GHS07 H302
EN
licylic acid and aluminiumsulfate Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
650-044-00-5 mixed linear and branched C14-15 alcohols 420-480-9 158570-99-1 Skin Irrit. 2 H315 GHS07 H315
ethoxylated, reaction product with epichlor- Skin Sens. 1 H317 GHS09 H317
ohydrin Aquatic Acute 1 H400 Wng H410
Aquatic H410
Chronic 1
**
650-047-00-1 dibenzylphenylsulfonium hexafluoroanti- 417-760-8 134164-24-2 STOT RE 1 H372 GHS08 H372
monate Acute Tox. 4 * ** GHS05 GHS07 H302
Eye Dam. 1 H302 GHS09 H318
Skin Sens. 1 H318 Dgr H317
Aquatic H317 H411
Chronic 2 H411
650-048-00-7 reaction product of: borax, hydrogen per- 420-070-1 — Org. Perox. D **** H242 GHS02 H242
oxide, acetic acid anhydride and acetic acid Acute Tox. 4 * H332 GHS05 GHS07 H332
Acute Tox. 4 * H312 GHS09 H312
Acute Tox. 4 * H302 Dgr H302
L 353/921
Skin Corr. 1A H314 H314
Aquatic Acute 1 H400 H400
L 353/922
Specific Conc. Lim-
Classification Labelling Notes
its, M-factors
Index No International Chemical Identification EC No CAS No Hazard
Suppl.
Hazard Class and state- Pictogram, Signal Hazard state- Hazard state-
Category Code(s) ment Word Code(s) ment Code(s)
ment Code(s)
Code(s)
EN
650-049-00-2 2-alkoyloxyethyl hydrogen maleate, where 417-960-5 — Skin Irrit. 2 H315 GHS05 GHS07 H315
alkoyl represents (by weight) 70 to 85 % Eye Dam. 1 H318 GHS09 H318
unsaturated octadecoyl, 0.5 to 10 % satu- Skin Sens. 1 H317 Dgr H317
rated octadecoyl, and 2 to 18 % saturated
hexadecoyl Aquatic Acute 1 H400 H410
Aquatic H410
Chronic 1
650-055-00-5 silver sodium zirconium hydrogenphosphate 422-570-3 155925-27-2 Aquatic Acute 1 H400 GHS09 H410
Aquatic H410 Wng
Chronic 1
31.12.2008
Table 3.2
31.12.2008
The list of harmonised classification and labelling of hazardous substances from Annex I to Directive 67/548/EEC
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
R: 12
S: (2-)9-16-33
L 353/923
Xi; R36/37/
38
R43
L 353/924
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
004-002-00-2 beryllium compounds with the exception of aluminium — — Carc. Cat. 2; T+; N AE
beryllium silicates, and with those specified elsewhere in this R49 R: 49-25-26-36/37/
Annex T+; R26 38-43-48/23-51/53
T; R25-48/23 S: 53-45-61
Xi; R36/37/
38
EN
R43
N; R51-53
31.12.2008
005-005-00-1 trimethyl borate 204-468-9 121-43-7 R10 Xn
Xn; R21 R: 10-21
S: (2-)23-25
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
005-009-00-3 tetrabutylammonium butyltriphenylborate 418-080-4 120307-06-4 R43 Xi; N
N; R50-53 R: 43-50/53
S: (2-)24-37-56-61
006-005-00-4 thiram (ISO); 205-286-2 137-26-8 Xn; R20/22- Xn; N N; R50-53: C ≥ 2,5 %
tetramethylthiuram disulphide 48/22 R: 20/22-36/38-43- N; R51-53: 0,25 % ≤ C < 2,5 %
L 353/925
Xi; R36/38 48/22-50/53 R52-53: 0,025 % ≤ C < 0,25 %
R43 S: (2-)26-36/37-60-61
N; R50-53
L 353/926
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
006-006-01-7 hydrogen cyanide ...%; 200-821-6 74-90-8 T+; R26/27/ T+; N B
hydrocyanic acid ...% 28 R: 26/27/28-50/53
N; R50-53 S: (1/2-)7/9-36/37-
38-45-60-61
006-007-00-5 salts of hydrogen cyanide with the exception of complex — — T+; R26/27/ T+; N A
cyanides such as ferrocyanides, ferricyanides and mercuric 28 R: 26/27/28-32-50/
oxycyanide R32 53
N; R50-53 S: (1/2-)7-28-29-45-
006-012-00-2 ziram (ISO); 205-288-3 137-30-4 T+; R26 T+; N N; R50-53: C ≥ 0,25 %
zinc bis dimethyldithiocarbamate Xn; R22-48/ R: 22-26-37-41-43- N; R51-53: 0,025 % ≤ C
22 48/22-50/53 < 0,25 %
31.12.2008
Xi; R37-41 S: (1/2-)22-26-28-36/ R52-53: 0,0025 % ≤ C
R43 37/39-45-60-61 < 0,025 %
N; R50-53
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
006-014-00-3 nabam (ISO); 205-547-0 142-59-6 Xn; R22 Xn; N
disodium ethylenebis(N,N'-dithiocarbamate) Xi; R37 R: 22-37-43-50/53
R43 S: (2-)8-24/25-46-60-
N; R50-53 61
L 353/927
006-020-00-6 barban (ISO); 202-930-4 101-27-9 Xn; R22 Xn; N
4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate R43 R: 22-43-50/53
N; R50-53 S: (2-)24-36/37-60-61
L 353/928
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
Xn; R22-48/
22
N; R50-53
31.12.2008
2,3-dihydro-2,2-dimethylbenzofuran-7-yl N-methylcarbamate N; R50-53 R: 26/28-50/53
S: (1/2-)36/37-45-60-
61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
2-(1,3-dioxolan-2-yl)phenyl N-methylcarbamate N; R51-53 R: 25-51/53
S: (1/2-)37-45-61
L 353/929
3-isopropyl-5-methylphenyl N-methylcarbamate N; R50-53 R: 25-50/53
S: (1/2-)24-37-45-60-
61
L 353/930
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
006-039-00-X tri-allate (ISO); 218-962-7 2303-17-5 Xn; R22-48/ Xn; N
S-2,3,3-trichloroallyl diisopropylthiocarbamate 22 R: 22-43-48/22-50/
R43 53
N; R50-53 S: (2-)24-37-60-61
006-041-00-0 dimethylcarbamoyl chloride 201-208-6 79-44-7 Carc. Cat. 2; T Carc. Cat. 2; R45: C ≥ 0,001 % E
006-044-00-7 isoproturon (ISO); 251-835-4 34123-59-6 Carc. Cat. 3; Xn; N N; R50-53: C ≥ 2,5 %
3-(4-isopropylphenyl)-1,1-dimethylurea R40 R: 40-50/53 N; R51-53: 0,25 % ≤ C < 2,5 %
N; R50-53 S: (2-)36/37-60-61 R52-53: 0,025 % ≤ C < 0,25 %
31.12.2008
2,2-dimethyl-1,3-benzodioxol-4-yl N-methylcarbamate Xn; R21 R: 21-23/25-50/53
N; R50-53 S: (1/2-)22-36/37-45-
60-61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
2-(ethylthiomethyl)phenyl N-methylcarbamate N; R50-53 R: 22-50/53
S: (2-)60-61
L 353/931
006-056-00-2 metolcarb (ISO); 214-446-0 1129-41-5 Xn; R22 Xn; N
m-tolyl methylcarbamate; N; R51-53 R: 22-51/53
MTMC S: (2-)61
L 353/932
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
1,1-dimethyl-3-(perhydro-4,7-methanoinden-5-yl)urea R: 22
S: (2-)
31.12.2008
006-066-00-7 vernolate (ISO); 217-681-7 1929-77-7 Xn; R22 Xn; N
S-propyl dipropylthiocarbamate; N; R51-53 R: 22-51/53
S: (2-)61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
R: 45
S: 53-45
L 353/933
006-077-00-7 maneb (ISO) 235-654-8 12427-38-2 Xi; R37 Xi
R43 R: 37-43
S: (2-)8-24/25-46
L 353/934
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
tetraethylthiuramdisulfide 22 R: 22-43-48/22-50/
R43 53
N; R50-53 S: (2-)24-37-60-61
31.12.2008
006-086-00-6 ethyl [2-(4-phenoxyphenoxy)ethyl]carbamate; 276-696-7 72490-01-8 N; R50-53 N
fenoxycarb R: 50/53
S: 60-61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
006-088-00-7 benfuracarb; — 82560-54-1 T; R23/25 T; N
ethyl N-[2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbo- N; R50-53 R: 23/25-50/53
nyl(methyl)aminothio]-N-isopropyl- β-alaninate S: (1/2-)36/37-45-60-
61
007-002-00-0 nitrogen dioxide; [1] 233-272-6 10102-44-0 T+; R26 T+ T+; R26: C ≥ 10 % 5
L 353/935
dinitrogen tetraoxide [2] [1] [1] C; R34 R: 26-34 T; R23: 1 % ≤ C < 10 %
234-126-4 10544-72-6 S: (1/2-)9-26-28-36/ Xn; R20: 0,1 % ≤ C < 1 %
[2] [2] 37/39-45
L 353/936
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
C; R35 R: 8-35 C; R34: 5 % ≤ C < 20 %
S: (1/2-)23-26-36-45 Footnote:
O; R8: C ≥ 70 %
31.12.2008
T; R23/25 S: 53-45-61
C; R34
N; R51-53
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
007-014-00-6 salts of hydrazine — — Carc. Cat. 2; T; N AE
R45 R: 45-23/24/25-43-
T; R23/24/25 50/53
R43 S: 53-45-60-61
N; R50-53
L 353/937
‘amyl nitrite’, mixed isomers [2] [1] 110-46-3 [2] Xn; R20/22 R: 11-20/22
203-770-8 S: (2-)16-24-46
[2]
L 353/938
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
007-022-00-X hydrazine bis(3-carboxy-4-hydroxybenzensulfonate) 405-030-1 — Carc. Cat. 2; T E
R45 R: 45-22-34-43-52/
Xn; R22 53
C; R34 S: 53-45-61
R43
R52-53
31.12.2008
008-001-00-8 oxygen 231-956-9 7782-44-7 O; R8 O
R: 8
S: (2-)17
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
Xi; R36: 5 % ≤ C < 8 %
Footnote:
O; R8: C ≥ 50 %
R5: C ≥ 70 %
009-003-00-1 hydrofluoric acid ... % 231-634-8 7664-39-3 T+; R26/27/ T+; C C; R35: C ≥ 7 % B
28 R: 26/27/28-35 C; R34: 1 % ≤ C < 7 %
C; R35 S: (1/2-)7/9-26-36/ Xi; R36: 0,1 % ≤ C < 1 %
37-45
L 353/939
sodium hydrogen difluoride C; R34 R: 25-34 Xn; R22: 1 % ≤ C < 10 %
S: (1/2-)22-26-37-45 C; R34: C ≥ 1 %
Xi; R36/38: 0,1 % ≤ C < 1 %
L 353/940
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
009-009-00-4 ammonium bifluoride; 215-676-4 1341-49-7 T; R25 T; C T; R25: C ≥ 10 %
ammonium hydrogen difluoride C; R34 R: 25-34 Xn; R22: 1 % ≤ C < 10 %
S: (1/2-)22-26-37-45 C; R34: C ≥ 1 %
Xi; R36/38: 0,1 % ≤ C < 1 %
009-013-00-6 fluorosilicates, with the exception of those specified elsewhere — — Xn; R22 Xn Xn; R22: C ≥ 10 % A
in this annex R: 22
S: (2-)13-24/25
31.12.2008
009-015-00-7 sulphuryl difluoride 220-281-5 2699-79-8 T; R23 T; N
Xn; R48/20 R: 23-48/20-50
N; R50 S: (1/2-)45-63-60-61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
009-017-00-8 potassium mu-fluoro-bis(triethylaluminium) 400-040-2 12091-08-6 F; R11-14/15 F; C
C; R35 R: 11-14/15-20-35
Xn; R20 S: (1/2-)16-30-36/39-
43-45
L 353/941
011-007-00-3 propoxycarbazone-sodium — 181274-15-7 N; R50-53 N N; R50-53: C ≥ 2,5 %
R: 50/53 N; R51-53: 0,25 % ≤ C < 2,5 %
S: 60-61 R52-53: 0,025 % ≤ C < 0,25 %
L 353/942
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
R: 11-15
S: (2-)7/8-43
31.12.2008
013-007-00-9 poly(oxo(2-butoxyethyl-3-oxobutanoato-O'1,O'3)aluminium) 403-430-0 — Xi; R41 Xi
R: 41
S: (2-)26-39
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
013-009-00-X sodium((n-butyl)x(ethyl)y-1,5-dihydro)aluminate) x = 0,5, 418-720-2 — F; R11-15-17 F; C
y = 1,5 R14 R: 11-14/15-17-20-
Xn; R20 35
C; R35 S: (1/2-)6-16-26-30-
36/37/39-43-45
L 353/943
014-007-00-1 triethoxyisobutylsilane 402-810-3 17980-47-1 Xi; R38 Xi
R: 38
S: (2-)24
L 353/944
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
Xi; R38 S: (2-)25-26-36/37
31.12.2008
silane Repr. Cat. 2; S: 53-45-61
R61
Xn; R22
N; R51-53
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
4H-1,2,4-triazole; R40 R: 61-22-40-51/53
1-[[bis-(4-fluorophenyl)methylsilyl]methyl]-1H-1,2,4-triazole Repr. Cat. 2; S: 53-45-61
R61
Xn; R22
N; R51-53
L 353/945
R: 35
S: (1/2-)26-36/37/39-
45
L 353/946
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
014-028-00-6 α-[3-(1-oxoprop-2-eny)l-1-oxypropyl]dimethoxysilyloxy-ω-[3 415-290-8 193159-06-7 R43 Xi
(1-oxoprop-2-enyl)-1-oxypropyl]dimethoxysilyl poly R: 43
(dimethylsiloxane) S: (2-)24-37
31.12.2008
015-003-00-2 calcium phosphide; 215-142-0 1305-99-3 F; R15/29 F; T+; N
tricalcium diphosphide T+; R28 R: 15/29-28-50
N; R50 S: (1/2-)22-43-45-61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-005-00-3 magnesium phosphide; 235-023-7 12057-74-8 F; R15/29 F; T+; N
trimagnesium diphosphide T+; R28 R: 15/29-28-50
N; R50 S: (1/2-)22-43-45-61
L 353/947
015-011-00-6 phosphoric acid ... %, orthophosphoric acid ... % 231-633-2 7664-38-2 C; R34 C C; R34: C ≥ 25 % B
R: 34 Xi; R36/38: 10 % ≤ C < 25 %
S: (1/2-)26-45
L 353/948
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-013-00-7 triethyl phosphate 201-114-5 78-40-0 Xn; R22 Xn
R: 22
S: (2-)25
015-016-00-3 tricresyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-); 201-105-6 78-32-0 Xn; R21/22 Xn; N Xn; R21/22: C ≥ 5 % C
tritolyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-); N; R51-53 R: 21/22-51/53
S: (2-)28-61
015-020-00-5 mevinphos (ISO); 232-095-1 7786-34-7 T+; R27/28 T+; N N; R50-53: C ≥ 0,0025 %
2-methoxycarbonyl-1-methylvinyl dimethyl phosphate N; R50-53 R: 27/28-50/53 N; R51-53: 0,00025 % ≤ C
S: (1/2-)23-28-36/37- < 0,0025 %
45-60-61 R52-53: 0,000025 % ≤ C
< 0,00025 %
015-021-00-0 trichlorfon (ISO); 200-149-3 52-68-6 Xn; R22 Xn; N N; R50-53: C ≥ 0,025 %
dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate R43 R: 22-43-50/53 N; R51-53: 0,0025 % ≤ C
31.12.2008
N; R50-53 S: (2-)24-37-60-61 < 0,025 %
R52-53: 0,00025 % ≤ C
< 0,0025 %
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-023-00-1 pyrazoxon; — 108-34-9 T+; R26/27/ T+
diethyl 3-methylpyrazol-5-yl phosphate 28 R: 26/27/28
S: (1/2-)13-28-45
015-027-00-3 sulfotep (ISO); 222-995-2 3689-24-5 T+; R27/28 T+; N N; R50-53: C ≥ 0,025 %
O,O,O,O-tetraethyl dithiopyrophosphate N; R50-53 R: 27/28-50/53 N; R51-53: 0,0025 % ≤ C
S: (1/2-)23-28-36/37- < 0,025 %
45-60-61 R52-53: 0,00025 % ≤ C
< 0,0025 %
L 353/949
015-030-00-X demeton-O-methyl (ISO); 212-758-1 867-27-6 T; R25 T
O-2-ethylthioethyl O,O-dimethyl phosphorothioate R: 25
S: (1/2-)24-36/37-45
L 353/950
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-032-00-0 prothoate (ISO); 218-893-2 2275-18-5 T+; R27/28 T+
O,O-diethyl isopropylcarbamoylmethyl phosphorodithioate R52-53 R: 27/28-52/53
S: (1/2-)28-36/37-45-
61
015-033-00-6 phorate (ISO); 206-052-2 298-02-2 T+; R27/28 T+; N N; R50-53: C ≥ 0,025 %
O,O-diethyl ethylthiomethyl phosphorodithioate N; R50-53 R: 27/28-50/53 N; R51-53: 0,0025 % ≤ C
S: (1/2-)28-36/37-45- < 0,025 %
60-61 R52-53: 0,00025 % ≤ C
< 0,0025 %
31.12.2008
O-3-chloro-4-methylcoumarin-7-yl O,O-diethyl Xn; R21 R: 21-28-50/53
phosphorothioate N; R50-53 S: (1/2-)28-36/37-45-
60-61
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-040-00-4 diazinon (ISO); 206-373-8 333-41-5 Xn; R22 Xn; N
O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phos- N; R50-53 R: 22-50/53
phorothioate S: (2-)24/25-60-61
015-041-00-X malathion (ISO); 204-497-7 121-75-5 Xn; R22 Xn; N N; R50-53: C ≥ 0,25 %
1,2-bis (ethoxycarbonyl) ethyl O,O-dimethyl phosphoro- N; R50-53 R: 22-50/53 N; R51-53: 0,025 % ≤ C
dithioate S: (2-)24-60-61 < 0,25 %
R52-53: 0,0025 % ≤ C
< 0,025 %
L 353/951
diethion N; R50-53 S: (1/2-)25-36/37-45- < 0,0025 %
60-61 R52-53: 0,000025 % ≤ C
< 0,00025 %
L 353/952
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
015-049-00-3 endothion (ISO); 220-472-3 2778-04-3 T; R24/25 T
S-5-methoxy-4-oxopyran-2-ylmethyl dimethyl phosphoro- R: 24/25
thioate S: (1/2-)36/37-45
015-055-00-6 naled (ISO); 206-098-3 300-76-5 Xn; R21/22 Xn; N N; R50: C ≥ 0,025 %
1,2-dibromo-2,2-dichloroethyl dimethyl phosphate Xi; R36/38 R: 21/22-36/38-50
N; R50 S: (2-)36/37-61
31.12.2008
015-057-00-7 formothion (ISO); 219-818-6 2540-82-1 Xn; R21/22 Xn
N-formyl-N-methylcarbamoylmethyl O,O-dimethyl phos- R: 21/22
phorodithioate S: (2-)36/37
31.12.2008
Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes
EN
O,O-dimethyl S-2-(1-methylcarbamoylethylthio) ethyl phos- Xn; R21 R: 21-25-50
phorothioate N; R50 S: (1/2-)36/37-45-61