Dorner Coordination “aohep ¢ Bwe Cousin TS fonmodton of vip compounds ai Ma ete, Can et exploSn smom tus concept elochonfo tuso ob voleney bid twee tal Oat exploration to explain tus forrmodion ob +0 AS Compounds WOW Simpl. compounds avte borin fogatune Peo Cola GNHa. Algrad Wornax anode a syslemotic. ‘nvemtigadion Gw cobalt amine complexes. Thoas complexes one . ob. A. Coz. CNH, Clute cCobaltic chlorade) bey - Sits 9K,0 Closes Cobble chloride) CPurpwwo cobalstc citorids) C. Coss Sits (viowo cobalt c chloride) d+ Coty Qnty C+ Godly. Sits . Some Obauivotions on hore compounds WLUW follows — © phan Lutes ‘cobaldic Chlardds or iret wd WySOe, Ah tHe C1 one removed an Ha duo Sw umchonge: MU ys tnolaentys arwvod C0, ($Ou), + IZNHa We Whey The AqueDud Sol gh Luteo colette NOs Sol”, throw Ok The mk pene U vod HHs moleude Chtorida 4s PB an akg odoms one prude naynoin unchorgs d- Rosso cobotkic Chloride looses “Ina, mM, oo Orr above Arrcl forms purprwtd Gofer only of 100 pe She Unio the* : . 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"rorveary Valenoy + COI gon 2 Onidedton atela eb madatyn, bene Omnte On Principal or toni salou Voleman b Secomchoriyy yolemey eohith Corresponds do tue CODY do mrodtaw avin bet of eurdrod wedod adorn ar tow, Which th Know Ob Torii sob Valea + th Prvinvony Voluncias ot sotishied *y odivalay dhrorgd tons weds, dws ie yolamneies we podishiad PY magodi ve aoa om Weentss ovr codions» moavdroal mol gadishy. boty | Onion gro Hove to Ob tha mated Scanned with CamScannerBud iy, ayq v 4 or. 2M tnah SFP dour . 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Condirt vil5 Modsunmend ¢ FTG, viola conducts of anv ete compound dopands ow Bs The Conerrdnation of solide be i cus “umber of charges on “the species Which ae Rormed aw dicsolubtory, Molar conduchivils pefodes to a 1M Sel” ounal Hud tus conctdnation, factor: fs removed. Ag Huse Choucges Frnuteorty , tus ano lov conductivity of ™ tomplaares cea Imexacuas » Te dota no ob CNG cn tus gpecias forcmad cohen te complex ts diccolved, com Tbs molec cord dh be Auducted by compariserr Ch ein Asod Gh ceranan sionpla Tork. Compounds, Tee alee KLARSEAE snuonurtneret of covalt fampronso.t chiordre comnplonas sugapat straschaeSaS lor oe Thao Ky + d fo WUCHLT Table t Number o chnorege® alode Birenckwer | Ratmnosty Vorlereys ba comdovery a Tord calsle (chlorcivas Volerery } p * 4 GN, =G i Feocmargriaer 6 i gntigttd 76 mf sar “ Pieced, ‘: 1 Anitgt ou =6 3) ted" Scanned with CamScanneri 2s Cuyoscopic, Measuearnant : f ais re bracing Poird oH a RaWA % lowed > mow voloti le chenicol substance ts dissolved vie Be Guyescorfe, anzoswumoertt involve mensudrg E math tn braeeing poird ts locnred « THe | dttrasciow of fruretng polat obtained depends ov fe Re mos Ob patties prucent. logue ro. Ob tons count [A guotee amount op cepeession, fr husring pott bo Seyescopc oneastoa mans com be wred to find oh % molecule diccocfoles Ke how font ae permed. +4 armolecrte Asso Kos Pinto to tors Uh ail give prurrion for a singe particle usted Fines f Arica tua expected Re! FSy drow Tors co; formed tuss ootll give © Gus txpacted deprsrrion. Thus - Caparticls) Ocrera) ka > st 4a » ) Mach > Mg™ 4 247 ce OG lau, > bet ase Cu > G@>) Beet Abux lop. pace Forres 6 rear, . seals Hid, Baws obrtua dagree friars O% et die mernberos .pordichts porcmac revs ke ais yuurd “nem Aus datetime -o% charges uslieh Cam bt olrtaived ren coe: ViUS, amocaduurmend by Tht dwe Ayypes ob (npore “ ery Comm, lox red togatner to LHe bU ster tas shes chiara » + “conrglane qnoteenls dager grasa, neird Note Molar condirclivities ond euyoscoric emacswtements for? chromium (Wu) peer ee ray Involwing cumrmornto. molecules and dntorddt 1or4, hore Ucomplt, helps fm deamancating dit co-ordination sphuu trom | Tenisotfoy sphuow Mites Scanned with CamScannerTable ¢ Elachdodien of strauchie on tha banks Sb molor conducting and euyoscor THEOL WUL EMD n se 7 hu Compound Wadlewesscanamalg” GiyseensTe, SGU ™ Prosi merle ’ Cos. CNHy GS Ohexges & perdi [or outpon wing Gp ur Cw Us FAH,” GU Onanges a Tents Crys Gn, 2 Onenrger Di Peony eT Co Oy 2 SMM 4 ‘ ee Lee Pee eutts 545] 3. Dipole anowert Mecsuremerst Dipole anormert ananaacennerd TOA) wee eve charcoal tngonmodtor lout era few non -iorh & cae Parr vaxcernpla Tt compe Tot (nits)3 GT] 1s Fine iptonaes aun, coun wish ob Cis om trom bows, The A pote enorme. broom Hot yortous mated -Ugord tobnad’s cence: ou tn tan, Pao how 78 1 HOW ev wr ,% inte Spal: moment isigivem toy tes KH forery. I Na, az” : pd eh lL Sioa ay a— a ; 4 f sKaqroGs : ‘vor Scanned with CamScannerVal ance Bond Thaoky (V6) The A treony wars developed by Part a a: MGGa te evar 4 1 The bend be fOotery 5 t ‘ peony ovis metal & gered t covet vec & Giitola, peng ob metal kaybrie aaiitals and Raprd Bs ee The edie anata Tor ™mevets eval table! a num net amply orbitals (29, 4, Pid oS aquat ois Coordination rum bet ) epic ove JY matal ior wndixgo go che went artes of rare Bap ridisodtin 4 fagontol ot uted & m strom ae und wetter Canby ediaad enbitntee > jaybretdscdion ed (nel 4) avuclagping down daa vacand Roth bile and fulfilled anit, eve 0 Cont” pated pode Nowbshi rast not & Havictadee et ale: ea AGES ghey im pgwedtdor Sooert ectaledviok Fnmnue onviitel complexes Oe c, usually mone ptenrbwle dro Host ob ceteheckeod outer onbitod Complxes + G, Thence OFT due compl, lid ca bited oh mesol nds do horn Tew overtap utr fillect oabitel ob Rae covalent co-ortinche loorech « Scanned with CamScannerah Pda —~¥ ONG Brnplts Fitted hyprid gekite) onlattet corardinetion mum wut a Magnetic amomard ord Basra tot ab covdrcat ematod for oe impentet fer gqromebry Inyrticl cok? ow \ Fnac outer er _ eb ornnngy ref ore aves Com pUxe The nrowladae chrom $ (ue roy) Fdea abovd mumbet ob eenpourad, ate &. Aceorcting, fo Pauling ggers emo oe alassified frto 4e0 classes: a, Stroma Ki goes 1 Thin, Wows. Larclomey to pair wp elechens oh meted fer 2.Q 5, cot atc, b. Wean Gqerchs 2 Thay cerned Rowe fendenvery fo pode Lp jus elacrtoms Ob motel Tow &-9, £5 Ur, Aa Mo, abe, Scanned with CamScannerRide} Wyisdd okies tor commen co-ordtuation chimtotry Coordination Hybridlisction — Geometry umber 2 se Uneore 5 p> _ |. Planest 4 6p? Tehokedso) ay Tahoe dco! aet® Squse Plano 5 ase? Trigerel Bi pyres 6ptd Square (0506429) Pynagsdal Odabadstal dt se? SP 34> Odkabadree! Lromp es Ag osnsds', fag (ends) [aa (e),] *, [vg to)” 2 Bice] , Brows] foe Couodu]” Mndu rceday, promt [eordc] e [recog] oad” [vo (acne): [to cnt" [rn cede] [ReCenlfT lor] feel” [io 6n%]"* Scanned with CamScannerTiustredtion Wo Tha Cry) ay 4 Gat! “amen To) COO Agt ¢ tw [ay Ginysyt ERE SP wyjptdication Als Ginpelaad elacker, Lncat K Diamagnbe Me [ee (ho). ar : i as oP wom oO on ut ae Fe Cie [ecm] 4 FEF OF og 08 Ob. aes 5e3 Tehohedeol . Qiarnag nec Broniva, WO wnpavued alechorn. - Scanned with CamScannerScanned with CamScannerOuter “Owattod ead C : ompbx@s amd “Smnax Onbsted Complenns? To give on Bitar explemodtion abou tus potarnog neki natu x °. ae oe Mees Huggty ugquided Aned dis don titels oe ae : a One Gd owigtels buf rot 3d /Agciny gene ° ha oy ott tus’ Rorve unpaved ale dren, umehongeds tt, do 4, . & Porcamagnelic in nade ae mae eae Cobtin ad | 1 a {tyr ud hh bhi 7] falula ni Teo Fey Ge) Gata Big * Ale] e fe? setae 2 (outer oo bite! Lyoiaisdo) end) oe Teh (M4 aby Aisokion), tr Auger sus on et tos py, vWws Lay nd ence AWS Thx complawas Ke [eof]? undergo “rv Bray ora codt ery OE a vo! fod Complexes + Sinw porrad ~ mamadon “opin: sat cermatacen ome P5Q% SF mrvijods ore called as OM abt oe umpoduid elechors ou past $0 putes spin Brot rauntrobicad + Go Haan crmmeenes ove oso Sx CS) cormplaned: Tpgedn othe cempisue Ave ote peireada]? dese oo teeett? mm teds ore Ob (nd) favel Ue maya abtials, BW, inne Ad orbtiods ara Involved re Wy bridicad on, axe KNCTY Shot CoMmpExe, Cre rocotly ssuch type complexan donot contes sy, aactvens $0, Sete complusces ahs o KUO” om or Wan Spm COs) CmpUnary Umnperest Agi poued Scanned with CamScannerMagnetTe omomerdt ob [MnO Jt io 5:9 bt Predict Us ggomelrey . be [MnBrc]™, due co-orelinos! Inaker vO. Mau 4, By Ame geometry ano tt telxaredstal C573) ove mong be deqione. planar ;Caspi) «Mora tue ragretic enorrand Tor SPP ond Asp? Ay bridization ob Mn ts as folleds— Hn! « ad Us ae rl bw $F? re wba sedfow GEbEH FA [iw (Mn Buh] ee $P3. atl No. eb umpoinad sectors (>) > Jno 6M njexe 8M 69 eM. 3 MagnetFe anoment (M4), Hnt env AS0™ hayortatacl oy . SEED ts | az Or [Me Ora) ges l= | INO. ob Unpovud: etechons =3 > Ini) 2M 2 Jaxg BM =F OM > 38% BM. Scanned with CamScannerNeed) Soom tuk atove caloslations . we Can eandbude Ahed 41a giver onng Hallo momurd 6 [Mn eas AMV shied cokew Mat geht atts adie budread qporralryy. (a, 4us Geometry a4 [Mn erg}? is tebabadead . * Pradkct tis mag netic moment of [Mn cen}, “Len tnisd al and Lu Que, Do yourselhs Stractwu! ae es, ake og Peucrinsdgd > = lgrdined ery Ae, antivits 6° = bar [er CNS GTS tae Aptvaht ow to saree Tad amo 429%, Ary ad ahs St” c ga. goror casey Gat eet Gat Sw peat * fv NS qunna) Gr sige ic es ’ ry { coi < ae ea’ a ho Oa™. ss a pelle re pes’ ash™ 75, Planar) « ae Bs Seek Boe wie Lote et hsypra ang ee { Scanned with CamScannerSiret Iw both hy bridle gastow Cdspr ord $P%) HUE 4d No) op Unpavud cledrow fs 45 Se, from anagaitHe anomend valuit G4 Can not Pradict yr ackual geometry ob A corp” “er ~ $0, fren so7me ote purysscod an patrols toe can way trot fF dosr not ord i+ Acbrovadited Ageiry uy ee suppot & ned Abs ene! 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NE VET comnot sotistactarily explosn the ch OM HD complexes + For axample omd octahedves SP>dt Aras borts disod torr cma otic propo ‘omy fe bot corto TG, fw SPS Wnybrudisodton Mh CoM fume ora tree umparrack elec afte moment 1 3:87 Bu. Bitte tebreohedstad comple 0% Com howe arog metic amomurds tn Aus yaMge, G74 Ho GB BN. COWES fos Ls ob ocdaksdreas complaxen US Get -62 BM. Tds Tnemaare Fn ww volue from te txpected valu’ ean rot be euplein bg YET. Aue axpected mag I, VOT, Se fotlure to. expen yua abnonmel peraviowe of Ni Aur ete (dt aypsten) ko fovem $9, planax an tout rot dus complener Boning Coardinodion no. 4 planar yeomebry per gquerte Com Plax: otras Gude os date hed Bud tuts theory only pref on trigoms Lek pyres howd passibla . 5 ae and % Umabs 4° wapldn, due roke v. Yet Bors oh acompun: eqn Oh He Tene Scanned with CamScannerCadve-Neubralive Principle: gagetdn concent dh olen oa asl 5 oe aac hb chy! eederorry Aus. msholodom By, Dqerde sufhow Brom ome Aapacts. 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Orystalsranrad to tune gare called CF Te Assumptions ob CFT Sn ue expt Bett tuto rg Gollocdimng assumphins CHE made t “Le fle conde mnttal coder Wick Contain atleart ome lone 8g suritownded by Ugonds por ob atechors, ee The, tonite” Aigjomds (2g, FUG on ete) We oqo} avy nagedtive poirct alargen ove simpy pork ener dates qauteal Rgerds (eg, co, nts toto Ot rogordad &) petrd Bipot ove imply Mpoler+ Sheet Ligord bs arsubol mmotecula auch os, Hs, H.0 CC, dus megadive ond oy iota Tntua anolecabe t Aracted tocooreds fue combo matted Ow. dus Whe Thetee %s mo Intexactorny tectaeem omebed orbitals & Mgamd an iitals ix, tnere bo ve awbiteabs ovedap: tw, According to ths dusory , ts ponding buhween Covdread mmetol codon ond Bigovnd i rot covalent but UG qrtdad as pwralsy eleckrosiafic, Tre tht bending fry Complore sendy, eb TonSow adhockien bated cordrod arofol Cotton od magadive Rgonsts sucha CoM ond cr Uh te Wana ty moutrtal hat bonding, mo he ten-dipo adtraciton AUehKoe Gn and Nis on Co LNs tans pot qnomund osidn Hot S-change on NK J? qharge am Hedors Mus “Fn Tekennsyegor, tee So chartgton te Nodom ob cach Nth, molende pstrd dened) drs atten, Scanned with CamScannernN L a NE THR Ah oretSials) on tik amatel alt’ frowd Hue sere Ong Grok dagmurale) fn die free adorns Hoaever. ubfhsrr a ee © bowmad ths Ugounals dertrcoy tue agg ntRBiteg Rr Te, iy tweonkitels pon howe Sifgvand Seni Tsolated gaoeow nmated Yen, dus hive degowreds. OM hove Aet dorm every, ond one torumed arsive 2b S sphwcically Aymmebtcal Held of Oriiads 9 eR? wemoUnd > Hemetal fer » Sut of 2 MEMOS degentcale. Hewever, das enwcg sy of Mee CEOS Ly tol sack’ bacouss ob apulssoyy lakieen AL 1 st atechon’ onitia aeatod «Sn most treenalliin amatol complexey y eidnert Anlgn kota tiarrdn : Aurroumnel tnt metals atime octahedral ove {edna hedlrod Huck: Qn boi ~~ ‘ by Hr Bg oncle & mot epPhUrtcall, pyrrrubrteos « Tht the d mbitals oe rot ol ofjsctads equalin h9 tus Rigemd tiald- : Crystal Fiala’ Splitting of doen bidala, tn : Melohadves Complexes ¢ Qn ap, aclahaddcal tempi, the ‘condred anatod. Coben % of te eardre (onigiw) ob te dctahechcon and tot Ugarcs ane at tee AIX COMTRXS O Tht octahcolrton, os Pkowivi'Tn tub dqwee. Ths. ont %e9, cmd 4 pots to Aires acljacert com mw ob Ht ackahadreon + a. behioo pth v , ; pec yr gros te Sipe te wake tne ae eo fe porn towards fut eordnel ieaie oes’ 7 Scanned with CamScannerme . ee eecatiows 4) forem okt to tals oh tuk Ott « bn cesfew oou napa a ey at Se aa oe wv ¢ by negative and ob tut ie oe tiers tues pera UR males de BROT Gy ob aU doe hive daorteHHho- QUE the Ggemds ors Atpmmebidicaltes positioned CUgerncls. ar of equal atstomee -brom tS OARS g Onbials tm, PME y ob qack ot - ve a onitials colt reatae by Ht sore amourt Cie ett que’ dor biteds, an AN degenerate ) 5 bud now fang coll Lowe Prgnet Energy than before (4x02 preted cofion,)- Tals is onlo & Ly potaticel st tietfor und tks amet Bede bs called . bony erdne on eortte Oh gravis. & ts devious thet moto op toe d-onbhiele ot ee to. tas Bare exjerta The Lobes ob tat 25 outfits (aaiyt and dr) Patek alony que bey x,y &'E > Te Lolars o& Ht ty owbli A (daw, Ave 6 dan) pated tm eatortam tanens Tue deerbiials Wing along dhs aay Chat gh ond dat) eof ll et -anoxe strongly repelled thon tt ow bkitely estén, (oer At rected beteseen He OS? Coby, dae Aer), stun test anergy 6b %y cabitels Cait y & dg>) coll Prcmeore much more tron tot eral tols ny dine kt). Under tue Umfiuence @b Cr octehadrod Rigend Pod Hee deonbftess ovte, tus #PEE Ente te00 Sets with 2, arbftaly od Sgner dns07G thom: Sg, onbtiah + ‘Giniadoe Dane gepalsiow » ponder oT we des qnowars Ww ewergy~ seas Urdu He trbluenee ob ep fedes! gant et die orbit gpltt de 400 5cs & Stood araxgicss ote cond te dagererey Ob ve & eabtiods is aremoved undue te Inplwerret ot tes Ugond : aspoxodt a 5 cartrol we sodion oh Give A-onbfieds ob H+ as Gpitow into tae als Boning, argponed grwcgion 1s called enyetel Beeld gpriing oF avarqy Level Apt ting « anned with CamScannerPr tems ea (Aves, dzt) y + Gq, a" 0: Ao dogpnaxcha rn a-ovbitaly © BE fhe a1 gi! Botgehmtre Ge rw SC , ematol 5 —4 da or — O40 \ a hig (dauy, 342,429) fatd Sptting Yr ockawaditod Guysted sald SpGt ting Iw 0 biad- “We anagy Atjeconce bilotew try and ag elt & Aerobed ty de om 10 Das WAUE O in do atenatting gor oclabadverd: Ae om 10 Dg ts called erupted fiald -opli thing amecgys TH sro ot ds Og evbiteds to 0649/6 Dg Right tow qe le ane Pweg y) siede Clorty derdne Janel enecgy ob te epee & OG Ae (4 Da) loaer Anan Ine dugpoteation amecqo ATT otner tows we Yar sony ded tht dag ma eitdo re id by amour ~0'4 do yeolile to % orbitals ate cesta! 9 0: Gag WitW Hespe to tae EKER erEXgyr steer Faclows offectPg do Loh ayy Modu 6b Metal Coen + a. 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