Safety Data Sheet

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ISSUE DATE: 7/8/2016
REVISION DATE: -
EDITION No.: -
1. IDENTIFICATION OF SUBSTANCE
a) Identification of substance: Prestone Antifreeze Coolant 50% Premix (YA956-P50)
b) Use of the substance: Automobile Engine Coolant
c) Manufacturer / Supplier and Emergency telephone :
CCI Automotive Products Co., Ltd. Telephone: +66 (38) 954730-1
Eastern Seaboard Industrial Estate Telefax: +66 (38) 954733
25 Moo 4 Tambon Pluakdaeng, Amphur Pluakdaeng,
Rayong 21140 Thailand
2. HAZARDOUS IDENTIFICATION
a) Hazard designation: Xn Harmful
b) Information pertaining to particular dangers for man and environment: R22 Harmful if swallowed.
c) Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by suppliers.
d) GHS classification
Physical Hazards Explosives Not applicable
Flammable gases Not applicable
Flammable aerosols Not applicable
Oxidizing gases Not applicable
Gases under pressure Not applicable
Flammable liquids Not classified
Flammable solids Not applicable
Self-reactive substances and mixtures Not applicable
Pyrophoric liquids Not classified
Pyrophoric solids Not applicable
Self-heating substances and mixtures Classification not possible
Substance and mixtures which, in contact with water, Not applicable
emits flammable liquids
Oxidizing liquids Classification not possible
Oxidizing solids Not applicable
Organic peroxides Not applicable
Corrosive to metals Classification not possible
Health Hazards Acute toxicity (Oral) Category 5
Acute toxicity (Dermal) Classification not possible
Acute toxicity (Inhalation: Gas) Not applicable
Acute toxicity (Inhalation: Vapor) Classification not possible
Acute toxicity (Inhalation: Dust) Not applicable
Acute toxicity (Inhalation: Mist) Classification not possible
Skin corrosion/irritation Category 3
Serious eye damage/eye irritation Category 2
Respiratory Classification not possible
Skin sensitization Classification not possible
Germ cell mutagenicity Classification
not possible
Carcinogenicity Classification not possible
Reproductive toxicity Category 1
Specific target organ toxicity – Single exposure Category 1
Specific target organ toxicity – Repeated exposure Category 1
Aspiration hazard Classification not possible
Environmental Hazards Hazardous to the aquatic environment – Acute hazard Category 3
Hazardous to the aquatic environment – Chronic hazard Not classified
 Safety Data Sheet
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ISSUE DATE: 7/8/2016
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Identification of substance : Prestone Antifreeze Coolant 50% Premix (YA956-P50)
e) GHS Pictogram

f) GHS Signal word Danger

g) GHS Hazard Statement May be harmful if swallowed
Causes mild skin irritation
Causes serious eye irritation
May damage fertility or the unborn child
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure
Harmful to aquatic life
h) GHS Precautionary statement
[A safety measure] Wear eye/face protection.
Wear protective gloves.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Contaminated work clothing should not be allowed out of the workplace.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Do not breathe mist/vapors.
Use only outdoors or in well-ventilated area.
Avoid release to the environment
[First-aid measures] If skin irritation occurs, get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
If eye irritation persists, get medical advice/attention.
Wash hands after handling.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs, seek medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical attention/advice
IF exposed: Call a POISON CENTER or doctor/physician
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention/advice if you feel unwell.
[Handling and storage] Store locked up.
Store container tightly closed in cool/well-ventilated place
Keep out of reach of children
[Disposal considerations] In the case of the disposal, please confirm local disposal regulation concerned by all means.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Labeling
EINECS No. ELINECS No. CAS No. Chemical name % Classification
R-phrases
203-473-3 107-21-1 Ethylene Glycol 45-55 Xn 22
215-185-5 7732-18-5 Water 45-55
203-872-2 111-46-6 Diethylene Glycol 0-5
2-Ethyl Hexanoic Acid, Sodium
205-743-6 19766-89-3 0-5
Sult
 Safety Data Sheet
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ISSUE DATE: 7/8/2016
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EDITION No.: -
Identification of substance : Prestone Antifreeze Coolant 50% Premix (YA956-P50)
4. FIRST AID MEASURES
a) General information: Symptoms of poisoning may even occur after several hours, therefore, medical observation for at least
48 hours after the accident.
b) After inhalation: Supply fresh air, consult doctor in case of symptoms.
c) After skin contact: Rinse skin for several minutes under running water.
d) After eye contact: Rinse opened eye for several minutes under running water.
e) After swallowing: Instantly call doctor.
5. FIRE FIGHTING MEASURES
a) Suitable extinguishing media: Use water fog, dry powder , foam , or carbon dioxide. Water or foam may cause frothing.
Use water to cool fire-exposed containers. If a leak or spill has not ignited , use water fog to disperse the vapors
and to provide protection for persons attempting.
b) Extinguishing media which must not be used for safety reasons: Water spray, carobondioxide or dry chemical.
c) Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gaze: None.
d) Special protective equipment for fire-fighters: The nature of special protective equipment required will depend upon the size of the fire,
the degree of confinement of the fire and the natural ventilation available.
Fire-resistant clothing and self-contained breathing apparatus is recommended for fires in confined spaces and poorly-ventilated areas.
Full fire-proof clothing is recommended for any large fires involving this product.
6. ACCIDENTAL RELEASE MEASURES
a) Personal precautions: Eliminate all sources of ignition in vicinity the spilled material. About personal protective equipment;
Refer to heading item 8.
b) Environmental precautions: Dilute with much water. Keep away from drains, surface - and ground - water and soil.
c) Methods for cleaning up: Absorb with liquid - binding material ( sand, diatomite , acid binders , universal binders, sawdust ).
Dispose of contaminated material as waste according to item 13.
7. HANDLING AND STORAGE
7.1 Handing
a) Containment: It should be prevented.
b) Local and general ventilation: Normal ventilation recommended.
c) Measures to prevent fire: No fire.
d) Measures required to protect the environment: About disposal ; Refer to heading item 13.
e) Any specific requirement or rules relating to the substance: No special requirements. Use normal precautions
in handling any liquid chemicals.
7.2 Storage
a) Specific design for storage rooms or vessels: In accord with official regulation.
b) Incompatible materials: Strong acid or oxidizing agents.
c) Conditions of storage: Store with container closed in a dry place away from excessive heat. And other condition
in accordance with official regulation.
d) Special electrical equipment and prevention of static electricity: In according to official regulation.
e) The type of material used in the packaging / containers of the substance: Polyethylene , tin , steel covered by iron phosphate
and steel covered by zinc phosphate.
7.3 Specific use (s) This product is Automobile Engine Coolant. For intended product uses please refer to the product
information leaflet.
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ISSUE DATE: 7/8/2016
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Identification of substance : Prestone Antifreeze Coolant 50% Premix (YA956-P50)
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Exposure limit values
CAS No. Chemical Name % Limit Values
107-21-1 Ethylene Glycol (as aerosol) 45-55 100 mg/m3 Ceiling ACGIH TLV
203-872-2 Diethylene Glycol 0-5 10 mg/m3 TWA AIHA WEELs

8.2 Exposure controls

8.2.1 Occupational exposure controls
a) Respiratory protection: Respiratory protection recommended.
b) Hand protection: Protective gloves ( rubber ) recommended.
c) Eye protection: Protective goggles recommended during refilling.
d) Skin protection: Overalls , apron and boots recommended.
8.2.2 Environmental exposure controls: Refer to heading item 6 b). Comply with applicable Community Environmental
protection legislation.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 General information
Item Value / Range
Appearance Organge liquid
Odor Mild odor
9.2 Important safety and environmental information
Item Value / Range
pH 50% solution 8.7
Boiling point / boiling range cdg 109
Flash point (Cleveland Open Cup) cdg 104
Flammability (Ignition temperature) cdg Not established.
Explosive properties cdg Product is not explosive.
Density (20 cdg) g/cm3 1.07
Water Solubility g/100mL Fully miscible
Viscosity mm2/s Not established.
9.3 Other information
Item Value / Range
Melting point / melting range cdg -36
Auto-ignition temperature cdg Product is not auto-igniting.

10. STABILITY AND REACTIVITY

10.1 REACTIVITY: Normally unreactive
10.2 CHEMICAL STABILITY: Stable
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with strong oxidizers will generate heat.
10.4 CONDITIONS TO AVOID: None known
10.5 INCOMPATIBLE MATERIALS: Avoid strong bases at high temperatures, strong acids, strong oxidizing agents, and materials
reactive with hydroxyl compounds.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide.
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ISSUE DATE: 7/8/2016
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Identification of substance : Prestone Antifreeze Coolant 50% Premix (YA956-P50)
11. TOXICOLOGICAL INFORMATION
Toxicological information (Animal toxicity data) Toxicological information of this product is none.
Therefore, reference to specific health effects of certain components provided under heading 2 in preparations.
1) Acute Toxicity: Ethylene Glycol: LD50 Oral Rat: 4700 mg/kg
LD50 Skin Rabbit: 9530 mg/kg
LD50 Oral Rat: 12,565 mg/kg
Diethylene Glycol: LD50 Skin Rabbit: 11,890 mg/kg
2) SKIN CONTACT: No evidence of adverse effects from available information
3) EYE CONTACT: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight excess
redness or conjunctiva. Serious corneal injury is not anticipated.
4) INGESTION: May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, malaise, blurring of vision,
irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including irregular eye
movements, convulsions and coma. Cardiac failure and pulmonary edema may develop. Severe kidney damage which may be
fatal may follow the swallowing of ethylene glycol. A few reports have been published describing the development of
weakness of the facial muscles, diminishing hearing, and difficulty with swallowing, during the late stages of severe poisoning.
5) CHRONIC EFFECTS: Prolonged or repeated inhalation exposure may produce signs of central nervous system involvement,
particularly dizziness and jerking eye movements. Prolonged or repeated skin contact may cause skin sensitization and an
associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects in laboratory animals. The
significance of this finding to humans has not been determined. 2-Ethyl Hexanoic Acid, Sodium Salt is suspected of causing
developmental effects based on animal data.
6) CARCINOGENICITY LISTING: None of the components of these products is listed as a carcinogen or suspected carcinogen
by IARC, NTP, ACGIH, or OSHA.
12. ECOLOGICAL INFORMATION
12.1 Ecotoxicity: Ecotoxicity information of this product is none. Therefore, reference information of certain components provided under
heading 2 in preparations.
Ethylene Glycol: LC50 Fathead Minnow <10,000 mg/L/96 hr.
EC50 Daphnia Magna 100,000 mg/L/48 hr
Bacterial (Pseudomonas putida): 10,000 mg/l
Protozoa (Entosiphon sulcatum and Uronema parduczi; Chatton-Lwoff): >10,000 mg/l
Algae (Microcystis aeruginosa): 2,000 mg/l
Green algae (Scenedesmus quandricauda): >10,000 mg/l
Diethylene Glycol: LC50 western mosquitofish >32,000 mg/L/96 hr
12.2 PERSISTENCE AND DEGRADABILITY:
Ethylene Glycol is readily biodegradable (97-100% in 2-12 days).
Diethylene glycol is readily biodegradable (>70% in 19days).
12.3 BIOACCUMULATIVE POTENTIAL:
Ethylene glycol: A BCF of 10, reported for ethylene glycol in fish, Golden ide (Leuciscus idus melanotus), after 3 days
of exposure suggests the potential for bio concentration in aquatic organisms is low.
Diethylene glycol: An estimated BCF of 3 suggests the potential for bio concentration in aquatic organisms is low.
12.4 MOBILITY IN SOIL: Ethylene glycol and diethylene glycol are highly mobile in soil.
12.5 OTHER ADVERSE EFFECTS: None known
13. DISPOSAL CONSIDERATIONS
13.1 Product
a) Recommendation : Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
13.2 Uncleaned packaging
a) Recommendation : Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
14.1 Sea Transport (IMDG)
a) Class Not Controlled under IMDG
b) Packing group (PG) III
c) UN number UN3082
d) Marine pollutant This product does not contain Marine Polutants as defined in 49 CFR 171.8.
14.2 Air Transport (IATA)
a) Class ―
b) Packing group (PG) Not applicable
c) UN number Not regulated
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ISSUE DATE: 7/8/2016
REVISION DATE: -
EDITION No.: -
Identification of substance : Prestone Antifreeze Coolant 50% Premix (YA956-P50)
15. REGULATORY INFORMATION
a) Designation according to EC Guidelines: The product has been classified and labeled in accordance with
EC Directives/Ordinance on Hazardous Materials (Gefstoffv)
b) Code letter and hazard designation of product: Xn Harmful
c) Hazard-determining components of labeling : Ethanediol
d) Risk phrases: 22 Harmful if swallowed.
e) Safety phrases:
2 Keep out of the reach of children.
46 If swallowed, seek medical advice immediately and show this container or label.
13 Keep away from food, drink and animal feeding stuffs.
36 Wear suitable protective clothing.
f) Ministry of Labor (Thailand) “Hazardous Chemicals Management Ministerial Regulations” 2556
No. 767 Ethanediol (Ethylene Glycol)
g) Department of Industrial Works (Thailand) “Dangerous Chemicals List” 2556:
None
16. OTHER INFORMATION
a) R phrases: 22 Harmful if swallowed.
b) Training advice: In accord with official regulation.
c) Recommended restrictions on use: For intended product uses please refer to the product information leaflet.
d) Technical contact point:
CCI Automotive Products Co., Ltd. Telephone: +66 (38) 954730-1 Telefax: +66 (38) 954733
e) Sources of key data used to compile the data sheet:
1) COMMISSION DIRECTIVE 91/155/EC of March 1991
2) COMMISSION DIRECTIVE 2001/58/EC of 27 July 2001
3) Directive 1999/45/EC
4) NIOSH : Registry of Toxic Effects of Chemical Substance (1998)
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.