Centre] Number | Candidate Number Candidate Name [TTT I EXAMINATIONS COUNCIL OF ZAMBIA. Examination for School Certificate Ordinary Level 2 Chemistry 5070/2 PAPER 2 Theory . Thursday 15 OCTOBER 2015 CCandisates answar on tne queston paper, Kasitonaimacera " ‘Answer Booktot ‘Matomatea!tabis or excultar (nen programas) Graph paper Time: 2 hours Instructions to candidates Write your name, centre number and candidate number in the spaces at the top of this page and on any separate answer paper used, There are 12 questions in this paper. Section A Answer all questions Write your answers in the spaces provided on the question paper. Section B Answer any three questions. Write your answers in the separate Answer Booklet provided. ‘At he end of the examination, fasten your Answer Booklets securely to the question paper. FOR EXAMINER’ Information for candidates Section A The number of marks is given in brackets [ | atthe end of each Bo qusstion pat question [exe The Periodic Table is printed on page 14 ie " Cell phones are not allowed in the examination room. == => | TOTAL ceczzaisve This question paper consists of 14 printed pages.Page 2 of 14 Section A: [50 marks] Answer all questions in the spaces provided. ‘The kinetic theory of matter explains the way in which solids, liquids and gases behave. AL Describe the movement of particles in fa) (b) «© solids 1 (2] [Total 6] Chemisry/s070/2/z2015Page 3 of 14 A2 The apparatus below was used in the extraction of ethanol from fermented maize rai @) (b) () (a) (e) iin. thermometer Figure 2.1 Name the apparatus labelled Y, . — 11) What improvement can be made to the above arrangement to get pure ethanol? 7 (a) State the purpose of the cold water which passes through Y. Name the separation technique being used above. i ct ia [1] ‘State an industrial application for the technique shown in the diagram above. (4 [Total 5] ‘Chemistry/S070/2/22015 [Turn overPage 4 of 14 A3_—_Anelement has 3 types of atoms. Two of these are shown below: Atom A Atom B Key © Proton + Neutron x Electron Figure 3.4 (a) What is different about these two atoms? (b) What term is used to describe such atoms? (©) What is the difference in nucleon number between atoms A and B? a (d) Atom Bis radioactive. Explain what this means, emstry'so70/2/Z2015Page 5 of 14 A sample of iron filings had partly rusted upon being left under damp conditions. 3,5g of the iron filings were added to 50cm? of aqueous copper (Il) sulphate. All the copper in copper (11) sulphate was displaced according to the equation below CuSO may + Fey) > Clg) + FOSOs a 3.2g of copper was formed. {a) Write the ionic equation for the above equation, 1] (b) __Ifneither the iron nor the copper (II) sulphate was in excess, cakulate (the mass of iron which was present in the iron filings sample. GB] (it) the percentage by mass of rust in the iron filings sample, Rl (iii) the concentration of the copper (II) sulphate solution in moles per dm B) be [Total 9] ‘coemstry/9070/2/22015 [Turn overPage 6 of 14 AS Use the Periodic Table to help you answer the following questions about the element selenium, atomic number 34. f@) (b) © (a) In which Periad is selenium? ~ 0) In an atom of selenium, how many (valency electrons are present? (lt) neutrons are present? sow CLI Would you expect selenium to be @ metal or a non-metal? Give one reason for your answer. PI Write the formula of the compound formed between selenium and calcium. 1 [Total 6] Chemistry S070/2/22015AG Study the diagrams below and answer the questions which follow. Silver ae Silver nitrate Zife sulphate i ‘Magnesium . solution sulphate solution seine a a 3 4 (@) _Inwhich test tube(s) do the following occur? (@) Zine atoms become zinc ions. i) Silver ions [Ag*] become silver atoms. Gi) There is no reaction. (iv) Metal atoms are oxidised. (b) Write a chemical equation for one reaction from any tube. mre [Total 5] cents /SO72/2015, [Turn overPage 8 of 14 A7 (a) _ Diese! and Petrol are used in many different ways. (2) In. which way are the wo similar in their use? (1 (ii) What general term is used to describe such substances. a (b) certain hydrocarbon has molecular mass of 58. 11.69 of this hydrocarbon is completely burnt. (@)___Galaulate the number of moles of the hydrocarbon that were burt. Qi (i) If one mole of this hydrocarbon produced 2880K) of heat on complete combustion, how much energy would 11.6g of the hydrocarbon produce on complete combustion? el ii) Why is it dangerous to burn coal in a limited supply of air? UI [otal 7] ‘Chesty/9070/2/22015Page 9 of 14 AS When chlorine gas is bubbled through iron (II) chloride, the following reaction. ‘occurs: (a) (b) ©) 2 FeCtajaq) + Clay» 2 FeCtr0) What colour change is observed in this reaction? fi) ‘The above reaction is a redox reaction, State with a reason which substance is @ reduced. (i) the oxidising agent. 2 Write an ionic equation for the reaction above, ~ 2] [otal 7] ‘Cremistry/5070)2/2015 [Turn overPage 10 of 14 Section 8 (45 marks) Answer three questions from this section. ‘Write your answers in the Answer Booklet provided. 89 When an acid reacts with an alkali, a salt and water are formed, (a) (b) (c) (a) What term is used to describe a reaction between an acid and an alkat? Write an ionic equation for this reaction, Bl ‘Acids can be classified as weak’ or ‘strong’, Explain what is meant by the terms ‘weak’ and ‘strong’ vihen referred to acids. Give one example of each type of acid. ia The word equation for the reaction used to form the insoluble salt barium sulphate,is shown below. Berium nitrate + Sodium sulphate —+ Barium sulphate + Sodium nitrate (3) Write an ionic ecuation for this reaction. (ii)__Deseribe how a pure, dry sample of Barium sulphate can be obtained from the reaction mixture, (iii) What term is used to describe the method used to prepare the Barium sulphate? [51 Oxides are classified as acidic, basic or amphotenc: (What is an amphoteric oxide? (il) What products are formed when a basic oxide reacts with an acid. (ili) Which of the oxides below is likely to be an acidic oxide? MgO, CuO, SiO:, ALO, Na.O 1 [Total 15] (Cherny S070/2/22015Page 11 of 14 BLO The diagram below shows apparatus used in the silver-plating of an iron article, During the electroplating, a current of 5A was passed through the aqueous electrolyte for 8.0 minutes. (a) (b) (e) (a) te) wo (9) Hifi A iron article -——lectroiyte ¥ (What is meant by electroplating? (ii) State one reason why electroplating is used. (2) State the names of electrode X and electrolyte ¥ which must be used in ‘order for successful plating to occur. By Write equations for the reactions occurring at the electrodes. ea] What mass of silver is deposited on the iron article? BI What change is seen at the anode during the electrolysis of electrolyte ¥? [1] If the iron article was to be coated with copper instead of silver, state the materials needed to be used for electrode X and electrolyte Y. (21 State two ather applications of electrolysis, (21 [Total 15] mien A0702/22015, [Turn overPage 12 of 14 B11 _Ammoria is an essential industrial product which is manufactured by the Haber process. (@) Give two reasons why ammonia is an essential product, 2 (b) Write the equations for the reaction in which ammonia is produced by the Haber Process. Include state symbols, 2 (©) State the raw materials from which the two reactants used to make ammonia are obtained. (2) (@) State the conditions needed to obtain a satisfactory yield of ammonia by the Haber Process. a) (e) Ammonia can be prepared in the laboratory by heating a mixture of calcium hydroxide and ammonium sulphate as shown in the diagram below, emmoria Mixture of calm hydroxide and ‘ammonium sulphate. ay cord t calcium oxide fet (crying agent) (i) Write the equation for the reaction of calcium hydroxide wath ammonium sulphate, (2) (ii) Describe a chemical test for ammonia gas. fea) iii) Explain why concentrated sulphuric acid is not suitable for drying the ammonia gas. 2 [Total 15] ‘Chamiy/S070/2722015Page 13 of 14 B12 The table shows the first four members of a particular homologous series. [Compound | Molecular formula | Relative molecular mass | Methanol HOH 32 Ethanol GHLOH | 46 | Propanoi GHOH 60 Butanol ‘GHLOH -? (a) (@_Name the homologous series to which these compounds belong. [1] (ii) Deduce the general formula of this homologous series. ie8) (ili) State the relative molecular mass of butanol. m (b) Ethanol can be manufactured from either ethene or glucose. (Construct an equation for the production of ethanol from ethene using strucural formulae. [2] State the conditions necessary for the reaction in B(I) above, [2] ‘The fermentation of glucose can be represented by the following ecuation. CH —+ 2GHsOH + 2CO, Calculate the maximum mass of ethanol that can be made from 72 tonnes of glucose. BI (©) State a use of ethanol, other than in alcoholic drinks. a (@)__ Ethanol can be oxidized to form ethanoic acid, (Draw the structure of ethanoie acid, showing all the bonds. 1] Gi) Name the organic compound formed when ethanol reacts with ethanoic acid. ica (iil) Draw the structure of the compound you have named in (ii) above ira} (iv) one condition necessary for the reaction of ethanol with arolc acid ira) [Total 15} creristry/5070/2/22015 [Turn over(073) eunssaid pue e:mevediwey wood ie .wwp $z s} seB Aue jo ejous eu0Je ouInjon ou semana | wat | mont! | iS | al | i qu aun ve 29 47 ON | PW | wy | Sa Yor oe sk SE 2) leas le ‘SquAUIA, OU Jo 21421 S1pOL9q YL 4a3HS Viva 81 JO #T abiegWWW.ECZPASTPAPERS.XYZ DOWNLOAD TEXTBOOKS FOR FREE! www. eczpastpapers.xyz INSTAGRAM : ECZPASTPAPERS FACEBOOK: ECZPASTPAPERS YOUTUBE: ECZPASTPAPERS