Primeira

Lista de Exercícios - Termodinâmica Química

Aluno: ￜ­§¸³¶￦ￋ±¥²¹©°￦ￓ¥²ª©¶¶¥¶­￦ￓ©²©¾©·￦ￓ³²¸©­¶³

10.1
  !"  $ $&!  $ ' $ ￈©²¾©²³

# "$% # %'&"& # $ &$' ￚ³°¹©²³

 

 
     
     
# 

( 
 #    
    # 
(a) ￚ­º©￦ µ¹©￦ ¸­¶¥¶￦ ¥￦ ¹²­¨¥¨©￦ ¨¥￦ ¸©±´©¶¥¸¹¶¥Ζ￦ ´³­·￦
) %  %% ©·¸¥g ￦¨©²¸¶³￦¨¥￦©¼´³²©²§­¥°￦©￦³￦ￓ¥¸¬§¥¨￦¨¥g ￦©¶¶³￦
·©￦¨­º­¨­¶￦¥￦¸©±´©¶¥¸¹¶¥￦´³¶￦‫ڵ‬￦‫ר‬￉Κ

* %'
Guess Values

 %% 

 + ) ,
     ) ,
( 

Constraints

) ,
  + * , 

-* 0
./  12 3456 * 7 
Solver

* 8 %'9'
 8 %"% 

(b)
(b)
* %  %%
   8 !%9' 
:;<=
   
    
#   8 9$& 
:;<=#
 #  
   # 

) %
Guess Values

 %% 

 + ) , :;<=    ) , :;<=#

Constraints

) , :;<= + * , 

- ) 0 3456 ) 7

./  12  
Solver

) 8 %&"
 8 "$'& 

(c)
(c) ) %  $% 

* %'
Guess Values

 %%
    ) ,
 #  
#  
 + ) ,
      
          # 
Constraints

 
) ,
      + * , 
     
- * 0 3456 * 7 >
./  12  
Solver

* 8 %'9$  8 %%
(d)
* %
 $% 

) %
Guess Values

 %%
    ) ,
 #  
#  
 + ) ,
      
          # 
Constraints

 
) ,
      + * , 
     
- ) 0 3456 ) 7 >
./  12  
Solver

) 8 %   8 %"

(e)
(e)
 %'
 $% 
) %
Guess Values

* %'
    ) ,
 #  
#  
 + ) ,
      
          # 
Constraints

 
) ,
      + * , 
     
- ) 0 3456 ) 7 ? 
./ * 12   
Solver

) 8 %$!$ * 8 %9!9
(f)
@ % ) 8 %$!$ * 8 %9!9

A %'
Guess Values

B %'

@ + A , )   B , * 
Constraints

A  B +

- A 0 3456 A 7 C
Solver

./ B 12

A 8 % &$ B 8 %$!
(g)

￈©²¾©²³￦ ©￦ ¸³°¹©²³￦ ¥±¦¥·￦ ·¥ ³￦ ±³°©g §¹°¥·￦ ²¥ ³￦ ´³°¥¶©·￦ ©￦ ·­±­°¥¶©·￦ ©±￦ ª³¶±¥¸³￦ ©￦
¸¥±¥²¬³Κ￦ ￖ³¶¸¥²¸³Ζ￦ ©g ￦ ´³··]gº©°￦ ©·´©¶¥¶￦ µ¹©￦ ¬¥®¥￦ ´³¹§¥￦ ­²¸©¶¥s¥ ³￦ µ¹]g±­§¥￦ ©²¸¶©￦ ©··¥·￦
·¹¦·¸¥n ²§­¥·Κ￦ￇ°©g ±￦¨­··³Ζ￦¥￦¸©±´©¶¥¸¹¶¥￦©g ￦¥°¸¥￦³￦·¹ϐ­§­©²¸©￦©￦¥￦´¶©··¥ ³￦¦¥­¼¥￦³￦·¹ϐ­§­©²¸©￦
´¥¶¥￦©·´©¶¥¶±³·￦§³±´³¶¸¥±©²¸³￦­¨©¥°Κ

10.2 (a)
10.2 (a)

  !"  $ $&!  $ ' $ ￈©²¾©²³

# " $& # $'"" # $$%% ￋ¸­°¦©²¾©²³

  

D E
   
 E   
#  

D( E
 #  
 E  # 
ￊ­¥«¶¥±¥￦ￖΟ¼Ο½Ό E "%

  ,
D E     ,
D( E
 ,
D E
?  

ￊ­¥«¶¥±¥￦ￚΟ¼Ο½Ό  "% 
>  FGGE  ,
D E     ,
D( E   7 E
?H    ,
D > 
 ,
D >      ,
D( > 
 % 7 %%' I %

QJK
QSK
QRK
QQK
QKK
PK
OK
NK
 
MK
LK
JK
SK
RK
K KTQ KTR KTS KTJ KTL KTM KTN KTO KTP Q

? 
 QSMTL
QSQ
QRLTL
QRK
QQJTL
QKP
QKSTL
PO > 
PRTL
ON
OQTL
NM
K KTQ KTR KTS KTJ KTL KTM KTN KTO KTP Q

?H 
10.3 (a)

  &&  $9'!!  $$%9 ²Ο´©²¸¥²³

# !&$$ # $"$& # $&9$ ²Ο¬©´¸¥²³

  

D >
   
 >   
#  

D( >
 #  
 >  # 
> ''

D > 
D( > 
 
 $  8 %99" 

) %'
Guess Values

* %'

) ,
D >    ) ,
D( > + 

Constraints

) ,
D > + * , 

- ) 0 3456 ) 7 * 
./ * 12   
Solver
 Solver
) 8 %' * 8 %!"
@ +   U , )  U , *
@ ) 7 )  %% I *
@  )
U @ 
*  )

Q
KTP
KTO
KTN
KTM
KTL U @
KTJ
KTS
KTR
KTQ
K KTL KTLJ KTLO KTMR KTMM KTN KTNJ KTNO KTOR KTOM KTP
@
(b)

 '' V
@ %'

) %'
* %'
Guess Values

D > 
D( > 

  $ 

) ,
D >    ) ,
D( > + 

Constraints

) ,
D > + * , 
@ +   U , )  U , *

W U 3456 ) 7 * 7 

Solver
Solver

 U W U X ? U W U Y
U W U Z
U % 7 %%' I 

KTPQ
KTOS
KTNL
KTMN
KTLP  U
KTLQ
KTJS ? U
KTSL
KTRN
KTQP
KTQQ
K KTQ KTR KTS KTJU KTL KTM KTN KTO KTP Q

QTKLL[QK]
PTP[QK\
PTRL[QK\
OTM[QK\
NTPL[QK\
NTS[QK\
U 
MTML[QK\
M[QK\
LTSL[QK\
JTN[QK\
JTKL[QK\
K KTQ KTR KTS KTJ KTL KTM KTN KTO KTP Q
U

10.7 (a)
10.7 (a)

  !"  $ $&!  $ ' $ ￈©²¾©²³

# " $& # $'"" # $$%% ￋ¸­°¦©²¾©²³

  

D 
   
    
#  

D( 
 #  
   # 
) %' * % %

 &
Guess Values

 $ 

) ,
D     ) ,
D(  + 

Constraints

) ,
D  + * , 

-  0 3456  7 
Solver

./  12

 8 9
 8 $% 9'' 
10.9 (a)

-  !" 0 - $ $&! 0 - $ ' $ 0 ￈©²¾©²³

 . "$% 1  . %'&"& 1  .. $ &$' 11
. 1 . 1 ￚ³°¹©²³
/ " $& 2 / $'"" 2 / $$%% 2 ￋ¸­°¦©²¾©²³

_ 


D ^ 7 
 _  
     ^ % 7  I $
 _ 
 %  "%  @  

 U %'
Guess Values

@ ,
D ^ 7 

Z 
Constraints

` 
D ^ 7    + 

_aX   U ,  
  
U 3456 U
Solver

@ ,
D ^ 7 
 ?_ , 
?_   _ 

D ^ 7  
D ^ 7 
  U ,    
  
- %  0 - %9$ 0
U 8 %!& ? 8 . %" 1  8 .. %%& 11
. 1
/ %$" 2 / %''$ 2
10.13

ￋƵ ￦¥··¹±­¨³￦µ¹©￦¥￦ª¥·©￦º¥´³¶￦´³··¹­￦§³±´³¶¸¥±©²¸³￦¨©￦«¥g ·￦­¨©¥°￦¨©º­¨³￦¥̀￦´¶©··¥ ³￦¦¥­¼¥￦

¨³￦·­·¸©±¥Κ

ￋƵ ￦ ¥··¹±­¨³￦ µ¹©￦ ©g ￦ º¥g °­¨¥￦ ¥￦ ￒ©­￦ ¨©￦ ￘¥³¹°¸￦ ´¥¶¥￦ ¥￦ ©·´©g §­©￦ ‫ڶ‬Ζ￦ ´³­·￦ ¥￦ §³²§©²¸¶¥s¥ ³￦ ¨©￦ ‫ڵ‬￦
´¶©·©²¸©￦ ²¥￦ ª¥·©￦ °]gµ¹­¨¥￦ ©g ￦ ¨©·´¶©¾]gº©°Ζ￦ ·©²¨³￦ §³²·­¨©¶¥¨¥￦ ¥´¶³¼­±¥¨¥±©²¸©￦ §³±³￦
·¹¦·¸¥n ²§­¥￦´¹¶¥Κ

ￋƵ ￦ ¥··¹±­¨³￦µ¹©￦¥￦°©­￦¨©￦ￎ©²¶½￦º¥°©￦ ´¥¶¥￦¥￦©·´©g §­©￦ ‫ڵ‬Ζ￦¹±¥￦ º©¾￦µ¹©￦ ¥￦§³²§©²¸¶¥s¥ ³￦²¥￦

ª¥·©￦°]gµ¹­¨¥￦©g ￦¥´¶³¼­±¥¨¥±©²¸©￦‫ڴ‬Κ￦

  bc  $' V d $%% bc e;<=# %% bc

e;<=# 8 %
*#  *   *# 8 %"

* ,  8 %%%'
) 
d

10.16
 10.16

e;<= $$  e;<=# 9   %& @ %&'

f ) 7 )#
  , )# Z  f( ) 7 )#
  , ) Z 

) 7 )# ) , f ) 7 )# , e;<=  )# , f( ) 7 )# , e;<=#

(a) Cálculo de BOL P:

) @ ) #   )

ghij
) 7 )# 8 '& 9' 

Cálculo de ORV P:

*  @ *#   *

) %'
Guess Values

e;<=  e;<=#
klm;nok  $

* , klm;nok + ) , f ) 7   ) , e;<=

Constraints

klm;nok + ) , f ) 7   ) , e;<=    ) , f( ) 7   ) , e;<=#

- ) 0 3456  7  
./ klm;nok 12   klm;nok
Solver

) 8 %! 9 klm;nok 8 9!&9 

(b)
(b)

) % '
)#   ) 8 %$'

) 7 )# 8 '!"$ 
) , f ) 7 )# , e;<=
? ) 
) 7 )#
U  @  ) 8 % "
? )  )
(c)

f % 7  , e;<= 8 %!&$
p#qr e;<=#
p#q e;<= 8 %$$&
f(  7 % , e;<=#

￉³±³￦³￦¥°ª¥￦²¥ ³￦´¥··¥￦´³¶￦‫ڵ‬Κ‫ڴ‬Ζ￦²¥ ³￦¬¥g ￦¥¾©³g ¸¶³´³Κ

10.17 (c)

e;<= "!  e;<=# 9%'   %"' )#   )

f ) 7 )#
  , )# Z  f( ) 7 )#
  , ) Z 

) 7 )# ) , f ) 7 )# , e;<=  )# , f( ) 7 )# , e;<=#

) , f ) 7 )# , e;<=
? ) 
) 7 )#
 ) %'
Guess Values

* %'
 %% 

) , f ) 7   ) , e;<=

* +  )  s % ) t  )  + *
Constraints


 + ) , f ) 7   ) , e;<=    ) , f( ) 7   ) , e;<=#
- ) 0
. * 1 3456 ) 7 * 7

Solver

. 1
/2

) 8 %!' * 8 %!'  8 !&&