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    Yuhu

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    Yuhu

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    16 views9 pages

    Us 6281384

    Uploaded by

    David Berkat H S
    Yuhu

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 9
    2) United States Patent Contracter et al. 10628138481 US 6,281,384 BL Aug. 28, 2001 a0) Patent No.: (45) Date of Patent: (54) VAPOR PI PROPYL! HASE CATALYTIC OXIDATION OF NE TO ACRYLIC ACID (75) Inventors: Rashmikant Maganlal Contracter, Wilmiogton, DE (US); Mark William Andersen, Charlottesville, VA (US); Jean B. Myers, Wilmington, DE (US); erard Heequet, Bethune (FR); Pontpoint (FR); Stojanovic, Paris (FR); lotte Pham, Saverne (FR); Michel (73) Assignees: E. 1. du Pont Nemours and Company, ‘Wilmington, DE (US); Atofina, Paris (FR) (*). Notice: Subject to any disclaimer, the term of this patent is extended or adjusted under 35 USC. 154(b) by 0 days, Appl. No. 09/105,497 Filed: Jun, 26, 1998 (51) Int. CL? VTL, $1/238 References Cited USS, PATENT DOCUMENTS 12/1969 Kurata eta 1971 Eden 2/1972 Kobersicin ol 3,487,109 3,631,009 2001533 260533 N 21837 3,761,424 9/1973 Kobersten eta. 25/437 3700979 © 3/1974 Hensel et al. 2001533 3,875,200 4/1975. White tal 260530 N 4102914 7/1978. ‘Beuther et al 250/405, 4152393 S/1979 Callahan etal ais 4341717 7/1982 Callahan eta 260465.3 4442308 4/1984 Artz eta 68/480 4604370 §/1986.‘Sarumaru eta. 502/38 (List continued on next page.) FOREIGN PATENT DOCUMENTS 0.034442 8/1981 (EP) core sis4 Oss1819 * 2/1998 (ED) ossis21 * 2/1008 (EP) 0861 SID AL * 9/1998 (EP) conc s/8 O81 21AL * 9/1995 (EP) COI STION 2227257 * 4/1974 (FR) COreS7/04 1307936 2/1973 (GB) conc a7/22 Hig0889 11/1977 (GB) corcs7/22 317085 7/1991 UP) eore272 05301051 of 1996 (IP) 1w099/03809* “1/1999. (WO) concasi8 OTHER PUBLICATIONS Advertising, Chemicals Technologies Worldwide, 1973, James L. Callahan et al., Oxidation and Ammoxidation Of Propylene Over Bismuth Molybdate Catalyst, Ind. Eng. Chem. Prod. Res. Develop., val. 9, No. 2, 134-142, 1970, Robert K, Grasselli etal, Selective Oxidation and Ammoxi dation Of Propylene By Heterogeneous Catalysis, Academic Press, Inc. , Vol. 30, 133-163, 1981 G, S. Patience et al., Modelling Of Propylene Oxidation In ‘ACirculating Fluidized-Bed Reactor, Elsevier Science B. V., 1-18, 1994. Primary Examiner—Gary Geist Assistant Examiner—Robert W. Deemie 6 ABSTRACT ‘An improved method for manufacturing acrylic acid by vapor phase oxidation of propylene in a single step or reaction stage using as solid phase oxidant a mixture of two particulate Solids comprising a bismuth molybdate aultim- etal oxide (¢:8..Mo,C03..Bi, ,Fe sWo sSi, «Koos0,) and a molybdenum vanadate mullimetal oxide (e.8.. Mo,2V 4 Sta.

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