GROUP Tt (Az) Theriaad Decomposition ef. Gropp T Corbenates Gerscally, Asst M Cosy > MO) + COrW9) aetek comb once rouctol oid, — Carbon chonicte Eqs 1g CPs , Pet > My Ou -+ Cou, CaCoys, At 5 CaQs, +COat5; SrCOyg, ——Atet —> SrOu, + Cae, RaCOy, beet 5 BQ, + CO,5, te Pevsraprsties sf Gop tacheenta becomes oe a at tanigny ele Gp eosions, ~ (polasaiig ates eilne one of the CHO bonel - Follsontl toby “rainy Ha barrel carbonate onion? — 1aZgn onion Cb:>°( 1 corton atom & 20nypen Ao 4) pee pelatealglly of tia amon ) Polarizing fet] ten 18 dari Ba fe pb chage consity of the cation * [eras sit = as 4a — cation Size (dadne) —> charge dmsly - = pet yTherined Decomposition +f Grp T N }4rectea Geely, 2M (NOs), 1 tet 20 + #NG2 45 tat) ee NAL ERP cae ges 2M CN > 2M4 Os) + RNQag +O2yy, 2Ca (NO) aq, At —> 2CaOry T PNOoyy + Oz ZSHN®)as, —ABt > 2SrOm + BND) Ore LBa (NO3)us) — > DBeOQe) + HNO a) + Onegy Decompesition of gmp TL petrekia haces of-y 9) esp aging affect & Gor — N~O bond is pslon'ses TL cations ol C dishaction of NOG anion) subsegunally, the bond 18 weaken dar te prtonigetin De forthowssat by brnabciy mf the onal b) nitrte anion = fags anion NOS. CI hithingen atom #3 ony afore) — Condibate to polarisabality, of the anion tha neediness $2 be polorisrotThar inek Stobilhy of Grep TL Nitrates ond Coboracts Thermek slebilily th oreases clown Fhe grep be coues:— — Size of cation down the group Cok = > chergs density (sferae: i, — Pelatising Powan of tha eahonyy — Hue rents 14 das polangetion of the N07 C2?" jem by the legen cactions ~ Hsrstern, become mors diftieatt te destpos Hep T combenctes /mitntes “when 4 Ths group : are sings the samc) Polarisabilt Lm carbonate fon COO po [je \* o=c¢ KOs Nov ~ Ye) the dalocalisa electrous ore potlacl towerch ys ‘the positive ook. oe the jon is on ) its wog to this oxygen atom is well oh the way to On bevome Carbon cicnid heeomha an oicle jonSolabiltty of Grow IL Sulfostes Deteriminacl by rebetive mag nts F (M)Latie € 2) Pathelpy chonge of hydlenion of cxtion Sulfite | Lattice en 4 Enthelpy ch Chad mat | ag slg 9 mg so, 2954 4 Cal0o,g 2704 ~lg Sv $0q 2572 —2 BaS% ~2459 +26 Ton lonic radius | Enthalpy change | Cam) | of hydration (Bint) me>* 0.065 —(810 | Ca 0.094 (862 st oll3 14 le Bet O1as -1273 So27 —Ilbo |Stamclard Enth Chonae otecckion (SHbid 2 Definitions The Stonclerct enthalpy change tf hyctration of on fon Is cafituc as the enthalpy change whan one male of the gassme fons is kssolyed ih @ large qrontty of water Unde Stamcdordl condihions + mgs + p> Ngo Hage = -(8Fokdimad”! - - “I SO) + 4 —7 SOK “Hhgd a Mohd iat ingay + So) + myey +S0,, ry Hey 62-3050 nd Hage js alwoys ragchve Lattice Energy The lattice onde! of an jonie Crystal Is fhe heat chee wrrelyed when one mole Of Crystalline solid is Pubmed om ifs seperste gases Vors Unclen Stindard conditions + e- 4 mab) + Sees, > Mg Ss) oH = aac Barly + 80%, —> BaSOus, oH" —ansakoind All (adttice Cneegy is negetive bacosus haat ensroyg Ts ovelved whan the ons farm Lledo velit bowols The higher lottce (the more exothermic), the stronger the _bonelShandorel Change of Sotstton(GHsoe Definition: The stondercl exthalpy chongs of solution 1S defthed ao the excth Change whin ohe burt. ofa substenee dissotues th such a forge veluina of solvent thet addiction of more solvenk produces no Purthen chanys Unilin stenclard conebrtoua , IN g Sets, 94 —F My oy + Spe, “Hat = Abert Ca Stay) + 04 —? Ca bgy FSC SH se = UP KT tral RaW, + 0g —o Beey + SO Gy ells = #2GKI met a[1ey con be positive or Atgotive If aHee is Viny positive ~ insolatate th wetre [pf olf 18 Very negative ~ Soluble th wetherLottie wsrgy desconoling group I, - wsize of the intion * ~ Tate onthelpy Ly Cepposite charged fore pactecl Ling Chosely & charge ainsity my) ~ (size S027 vemoaine comstont) descending L nea lin, ofthe bit en — Erctralpg chonge of bycradion YC woter molesten Can gut (xa closer to Mim dew to lover Change obeesity ) (size S04 consent > olligg meorstat fe ee) Soleil T. seb febes V jdoton the grep Conteh, 5 og hcduale ole eon of ie Dnsraey)—? SH sot = VR MeHg) Mee ry * ee sedan rnb = Down GropT, “Hiya deertsses ih a toate, katt compare cl fo decrease Th Velun of Jothice sv Thuvefore 2 Heel changis Bom —Ve (solwbte salt Wtya,) to ve Chot seth, Ba 5%)