Chemistry MCQ PDF

Sabbir Hasan
Ariful Islam Ashik
Pabna Textile Engineering College
1. The order of stability of carbonium ions is
Ans: tertiary>secondary>primary
2. The order of stability of carbanions is
Ans: primary>secondary>tertiary
3. Which of the following carbonium ions will be most
stable? Ans: CH2=CHC+H2
4. The least stable carbanions is
Ans: (CH3)3C-
5. Which alkyl free radical is the most stable?
Ans: tertiary
6. Which of the following is an electrophile?
Ans: CH3C+H2
7. Which of the following is not an electrophile?
Ans: NH3
8. Which of the following statement is correct regarding
nucleophiles?
Ans: they have a lone-pair of electrons
9. Which of the following is a nucleophile?
Ans: CN
10. Which of the following is not a nucleophile?
Ans: AlCl3
11. Which of the following is not a nucleophile?
Ans: BF3
12. Which of the following is a lewis acid?
Ans: AlCl3
13. The following reaction is first order in each of A and B:
A+B=C
What is rate of the reaction if the concentration of A and B are
decreased by 10 times each?
Ans: the rate is decreased 100 times
14. What feature of a free energy diagram reveals whether the
reaction is endothermic or exothermic?
Ans: the relative energies of reactant and product
15. Which is the strongest lewis acid?
Ans: BF3
16. Which molecule or ion plays the role of an acid in the
following reaction?
HNO3+ H2SO4🡪HSO4
-+H2NO3+
Ans: H2SO4
17. What types of orbitals are occupied by the oxygen lone pairs in
the alcohol group?
Ans: sp3-hybrids
18. What types of orbital are involved in C-O bond in alcohols?
Ans: (C)sp3-(O)sp3
19. Which combination of chemicals is known as the lucas
reagent?
Ans:HCl,Zncl2
20. How quickly would a separate layer form if teri- butanol was
submitted to the lucas test?
Ans: less than 1 minute
21. What role does pride play in PCC reagent?
Ans: to make the chromium reagent soluble in nonpolar organic
solvents
22. For which sequence represent the correct ordering with
regard to an increase in the oxidation state?
Ans: alkane<primary alcohol<aldehyde<carboxylic acid 23.
Which sequence shows the correct ordering with regard to an
increase in the oxidation state for the oxidation of methanol? Ans:
methanol<formaldehyde<formic acid<carbon dioxide 24. For
which of the following oxidation reaction does one need to use
pyridinium chlorochromate (PCC)
Ans: ethanol to acetaldehyde
25. Which alcohol is the most acidic?
Ans: 1,1-dichloroethane
26. Alcohols have higher boiling points than alkanes of
comparable molecular weight because of
Ans: hydrogen bonding
27. Which of the following propane derivatives has the highest
boiling point?
Ans: glycerol
28. Which of the following has the highest boiling point?
Ans: CH3-CH2-OH
29. What alcohol has the lowest solubility in water?
Ans: pentanol
30. What is the boiling point of ethanol?
Ans: 780C
31. What are the main components of synthesis gas?
Ans: mixture of CO and H2
32. Suppose you want to prepare the tertiary alcohol3-phenyl
3-pentanol from an acid derivative. Which acid derivative would
you use?
Ans: methyl benzoate
33. Which product is formed in the catalytic hydrogenation of
2,2-dimethyl-4-pentanol?
Ans: 2,2-dimethyl-1-pentanol
34. Which of the following Grignard reaction is not suited for
the preparation of 3-methyl-3-hexanol?
Ans: pentanal and ethylmagnesium bromide
35. Which of the following will not convert 1-butanol into 1-
chlorobutane in one step?
Ans: CCl4
36. Which of following reagent will not be efficient in converting
propanol into a propoxide?
ans: NaOH
37. What reagent best converts an alcohol into the
corresponding alkyl bromide?
Ans: NaBr,H2SO4
38. What oxidative transformation can be accomplished by the
PCC reagent?
Ans: primary alcohol to aldehyde
39. Which one of the following alcohol cannot be oxidized to a
carbonyl compound?
Ans: 3-methyl-3-pentanol
40. Which compound can be reduced readily with sodium
borohydride?
Ans: aldehydes and ketones
41. What type of alcohol is generated in the reaction between
formaldehyde and a Grignard reagent?
Ans: a primary alcohol
42. In the lucas test, one combines an unknown alcohol with the
lucas reagent to determine whether the alcohol is primary
,secondary, or tertiary . which alcohol reacts the fastest and by
what mechanism?
Ans: tertiary alcohol by SN1
43. Consider the reaction mechanism of the dehydration of
cyclohexanol with concentrated sulfuric acid. Which reaction
step is the rate-limiting step?
Ans: loss of water from the protonated alcohol and formation of
the carbocation intermediate
44. Grignard reagents are
Ans: all of the above
45. Which statement about organometallic compound is false? Ans:
they are important source of carbon electrophile 46. Good solvents
for preparing organometallic reagents include all but….?
Ans: water
47. Organomagnesium compound are
Ans: bases
48. Which of the following statement about organometallic
compounds is false?
Ans: an organosodium compound is not very reactive compared
to a Grignard reagent.
49. Which of the following statement about organometallic
compound is false?
Ans: alkyllithium and Grignard reagents do not add to
esters. 50. Grignard reagent react with carbonyl group to
produce? Ans: alcohols
51. The product of the reaction of a Grignard reagent with an
aldehyde is ?
Ans: 20alcohol
52. The product of the reaction of a Grignard reagent with an
ester is ?
ans: 30alcohol
53. Which of the following compounds gives a primary alcohol
upon reaction with phenylmagnesium bromide? Assume the
usual acid workup.
Ans: ethylene oxide
54. Which of the following compound gives a secondary alcohol
upon reaction with methylmagnesium bromide? Assume the
usual acid work up.
Ans: 3-pentanone
55. Which of the following compound does not give a tertiary
alcohol upon reaction with methylmagnesium bromide? Ans:
3-methylpentanal
56. CH3CH2CH2OH is the product of ethyl Grignard and
Ans: oxirane
57. Which of the following compound would not give tert-butyl
alcohol when treated with excess methylmagnesium bromide?
Ans; acetaldehyde
58. Which of the following reagent,when treated with
phenylmagnesium bromide followed by acid workup ,will yield
2-phenylethanol?
Ans: oxirane
59. Organocuprates react with?
Ans: 10alkyl halides to produce alkanes
60. Which of the following carbonyl compounds react most
rapidly with nucleophilic reagent ?
Ans: 3,3-dimethylbutanal
61. Which of the following statement is not generally true? Ans:
alkenes add nucleophiles more rapidly than aldehydes or
ketones of similar structure
62. Predict which of the following compounds will have a lower
boiling point than 1-butanal.
Ans: 1-butene
63. Predict the product of the following reaction.
CH3COOH + NaBH4 🡪
Ans: no reaction
64. Which of the following compound is not oxidized by
pyridinium chlorochromate (PCC)?
Ans: 2-methyl-2-butanol
65. Which of the following reaction is a good method for
preparing an aldehyde?
Ans: PCC and 10alcohol
66. Which of the following reaction would not be a useful way of
preparing 1-phenyl-2-butanol?
Ans:butanal + phenylmegnesium bromine
67. How many compounds with molecular formula C5H10O may
be reduced with NaBH4 to a primary alcohol?
Ans: 4
68. Which of the following is the best pair of starting materials to
make 3-methyl-2-pentene via a witting reaction? Ans:
2-butanone plus CH3-CH=PPh3
69. Which of the following compound does not form an imine
upon reaction with an amine?
Ans: benzamide
70. Predict the product of the following reaction.
Cyclopentanol + PCC 🡪
Ans: cyclopentanone
71. Which of the following compound would not be possible
product from the mixed aldol reaction of acetaldehyde and
butanal?
And: 3-ethyl-2-hydroxyhexanal
72. Which of the following aldehyde ,used alone, will undergo
an aldol reaction?
Ans: butanal,CH3(CH2)2CHO
73. Which of the following amines would be best chosen for
preparing an enamine derivative from cyclohexanone? Ans:
dimethylamine
74. Which of the following compound could not be convert to
pentanal is one or two steps?
Ans: 2-pentanone
75. An unknown compound on ozonolysis give acetaldehyde
and benzophenone. What is the structure of the compound?
Ans: 1,1-diphenylpropene
76. The iodoform test for methyl ketones is not widely used
anymore. Which of the following spectroscopic tools is best for
providing equivalent information?
Ans: 1H NMR
77. A C7H12O2 compound gives a positive Tollens’ silver mirror test
and a positive iodoform test. Which of the following would
satisfy these facts?
Ans:2,2-dimethyl-4-oxopentanal
78. A C5H8 hydrocarbon is reacted with BH3 in THF, followed by
oxidation with alkaline hydrogen peroxide. Treatment of the
resulting product with PCC in CH2Cl3 produces a chiral ketone,
formula C5H8O. what hydrocarbon best fits these facts? Ans:
1-methylcyclobutene
79. A C3H12O compound is optically active, and is oxidized by PCC
in CH2Cl2 to an optically active C5H10O product, which is
recemized in acid or base. Which of the following best fits these
fact?
Ans: 2-methyl-1-butanol
80. Which of the following reagent will reduce a carboxylic acid to
a primary alcohol under mild condition?
Ans: all of these
81. Whats is the function of the acid catalyst in the first step of
the Fischer esterification of a carboxylic acid?
Ans: to protonate the carbonyl oxygen
82. Which compound are soluble in water?
Ans: 1,2,3
83. Arrange the compound in order of increasing solubility in
water?
Ans: 4,1,3,2
84. When comparing the acidity of propanoic acid and
pyruvic,CH3COCO2H,which of the following statement is
correct? Ans: propanoic acid has a higher pKa and a smaller Ka
than pyruvic acid
85. What is the order of increasing acidity for the following
compound ?
Ans: 1<2<3<4
86. A characteristic absorption band occurs in the infrared
spectra of all carboxylic acids at:
Ans: 1690-1710 cm-1
87. Which characteristics of an NMR proton spectrum most
strongly suggests the presence of a carboxylic acid? Ans:
absorption at d 10-13 ppm
88. Which of the following statement is false about primary
amines?
Ans: they do not form salts with acid
89. Which of the following compound react with nitrous acid to
an alcohol?
Ans:CH3CH2NH2
90. Which of the following amines react with nitrous acid to
form nitrosamine?
Ans: diethylamine
91. Which of the following compound will dissolve in aqueous
NaOH after undergoing reaction with hinsberg reagent? Ans:
CH3CH2NH2
92. Which of the following compound does not react with acetyl
chloride?
Ans: methylamine
93. Carbylamine test is given by
Ans: primary amine
94. Which of the following has the highest boiling point?
Ans: CH3CH2CH2CH2NH2
95. What is the hybridization of the orbital containing nitrogen’s
nonbonding electron in CH3-NH-CH2-CH3?
Ans: sp3
96. Which one of the following is not affected by the lone pair of
electron on an amine’s nitrogen?
Ans: melting point
97. Arrange the amines in order of increasing boiling point?
Ans: 3,2,1,4
98. Arrange the amines in order of increasing solubility in water
Ans:4,3,2,1
99. Arrange the amines in order of increasing boiling
point(lowest first)
Ans:1,2,3,4
100. The reaction , benzin-NHCH2CH3 + CH3I🡪? give as final
product
Ans: a quaternary ammonium salt
101. Which of the following is a reagent in the Gabriel amine
synthesis?
Ans: phthalimide
102. What product result from the reaction of acetyl chloride
with methylamine, followed by LiAlH4 and H2O?
Ans: CH3-CH2-NH-CH3
103. What is the product of the reaction of an acid chloride and a
primary amine?
Ans: an amide
104. What product result from the reductive amination of
acetaldehyde with aniline?
Ans: C6H3-NH-CH2-CH3
105. Which convert methyl bromide to ethylamine?
Ans: a large excess of NH3
106. Which offers the best method for the conversion of an
amide to an amine?
Ans: Na, NH3
107. The Hofmann rearrangement of which of the following
produce ethylamine as a product?
Ans: CH3-CH2-CO-NH2
108. What set of reagent is used to convert a secondary amine to
an N-nitrosamine?
Ans: NaNO2 and HCl
109. CH3-CH2-CH2-CH2-NH2 absorbs strongly in the 3200-3500 cm
1region of the infrared. What compound also absorb strongly in
the region?
Ans: ethyl alcohol
110. A substance is soluble in dilute aqueous HCl and has a single
peak in the region 3200-3500 cm-1in it’s IR spectrum. Which of
the following best fit the data?
Ans: benzin-NH2
111. An aqueous solution of glycine is neutral because of the
formation of :
Ans: zwitterions
112. Which of the following reaction is suitable for the
preparation of alpha-amino acid?
Ans: strecker’s synthesis
113. Glycine reacts with nitrous acid to form:
Ans: glycolic acid
114. When glycine is heated ,it forms
Ans: diketopiperazine
115. Proteins are
Ans: polyamides
116. The five element present in most naturally occurring
proteins are:
Ans: N,S,C,H and O
117. The nitrogen content of proteins can be quantitatively
determined by
Ans: Kjeldahl’s method
118. The primary structure of protein refers to : Ans: the
amino acid sequence in the polypeptide chain
119. The alpha-Helix is a common form of
Ans: secondary structure
120. The alpha-Helix is held in a coiled conformation partially
because of :
Ans: hydrogen bonding
121. Irreversible precipitation of proteins caused by heating is
called:
Ans: denaturation
122. Precipitation or coagulation of protein may be caused by
Ans: all of these
123. Ninhydrin test is given by
Ans: proteins
124. Which of the following test is not used for testing protein?
Ans: tollens test
125. Upon hydrolysis, proteins give
Ans: amino acid
126. How many stereoisomers can an aldotetrose have?
Ans: 4
127. How many stereoisomers can an aldopentose have?
Ans: 8
128. How many stereoisomers are possible for a ketohexose?
Ans: 8
129. In the Fischer projection of D-glyceraldehyde, the –OH on
the chiral carbon is drawn
Ans: to the right
130. Which carbon of glucose is the anomeric carbon/
Ans: C-1
131. Which of the following statement about anomers is true?
Ans: anomers are diastereoisomers
132. What is the approximate equilibrium concentration of the
open chain form of D-glucose in an aqueous solution? Ans:
0.02%
133. What product is formed when glyceraldehydes react with an
aqueous solution of Br2?
Ans: 2,3-dihydroxypropanoic acid
134. What is the structural relationship between the osazones of
D-glucose and D-fructose ?
Ans: they are identical
135. Which of the following statement about fructose is not ture?
Ans: it contains one primary alcohol group
136. What set of reagent is used in the Ruff degradation of
aldoses?
Ans: bromine water, then hydrogen peroxide and ferric sulfate
137. In the chain-lengthening kiliani-fischer synthesis, what is the
source of the new carbon atoms?
Ans: HCN
138. The disaccharide sucrose is composed of the
monosaccharides
Ans: D-glucose + D-fructose
139. Which of the following disaccharides contains fructose?
Ans: sucrose
140. In maltose, the glucose molecules are connected by a
Ans: alpha-1, 4-glycosidic bond
141. In amylopectin, the glucose molecule are connect by Ans:
alpha-1, 4-glycosidic bond and alpha-1, 6-glycosidic bond 142.
What monosaccharide is obtained on hydrolysis of cellulose? Ans:
glucose
143. Sodium phenoxide react with CO2 at 1250C under 5 atm
pressure to give salicylic acid. This section is called
Ans: Kolbe reaction
144. Phenol react with excess bromine water to give
Ans: 2,4,6-tribromophenol
145. Bekelite has the following characteristic
Ans: all of these
146. Anisole is formed when phenol is treated with
Ans: CH3I/NaOH
147. Anisole on heating with concentrated HI gives
Ans: phenol + CH3I
148. Which group forms the strongest H-bond to water
molecules?
Ans: phenols
149. The compound which is most capable of hydrogen bonding
is :
Ans: CH3CH2-S-S-CH2CH3
150. How can phenol be distinguished from cyclohexanol ?
Ans: solubility in sodium bicarbonate solution
151. The following mixture was extracted with 1 M HCl, followed
by 1M NaOH, followed by ether. Which compound is recovered
from the base solution?
Ans: 2 (phenol)
152. The following mixture was extracted with 1 M HCl, followed
by 1M NaOH, followed by ether. Which compound is recovered
from the acid solution?
Ans: 1
153. The following mixture was extracted with 1 M HCl, followed
by 1M NaOH, followed by ether. Which compound is recovered
from the ether solution?
Ans: 3
154. Ranking the following molecules in decreasing order of
boiling point:
Ans: 3>2>1
155. The ranking of following compound in order of increasing
boiling point:
Ans: 3<2<1
156. Which of the following compound is most acidic?
Ans: p-nitrophenol
157. Which of the following compound is most acidic?
Ans: m-nitrophenol
158. Which molecule is the most acidic?
Ans: p-nitrophenol
159. Which of the following compound is most acidic?
Ans: p-nitrophenol
160. the reason why materials appear colored is
Ans: all of these
161. which of the following is a chromophore?
Ans: -NO2
162. which of the following is an auxochrome?
Ans: -OH
163. the water-solubility of dyes can be increased by introducing
ans: all of these
164. which dyes become linked to the fiber by chemical reaction?
Ans: acid dyes
165. which of the following is the strongest acid?
Ans: trifluoroacetic acid
166. which of the following is the strongest acid?
Ans: 2-chlorobutanoic acid
167. which of the following is the strongest acid in aqueous
solution?
Ans: Ci2CHCOOH
168. which is the strongest acid?
Ans: Cl3CCOOH
169. which of the following compound is most acidic?
Ans:FCH2COOH
170. which of the following compound is the strongest acidic?
Ans: CF3COOH
171. which of the following compound the least acidic?
Ans: CH3CH2COOH
172. which of the following compound is most acidic?
Ans: CH3-CHF-COOH
173. which of the following will give acetic acid on acid
hydrolysis?
Ans: ethyl acetate
174. propanenitrile undergoes acid-hydrolysis to give
ans: propanoic acid
175. the characteristic reaction of carboxylic acid is
ans: nucleophilic substitution
176. . which of the following compound will react with tollens
reagent to give metallic silver?
Ans: formic acid
177. which of the following compound on treatment with
NaHCO3 will liberate CO2?
Ans: acetic acid
178. which of the following reagent will convert acetic acid into
acetyl chloride?
Ans: SOCl2
179. butyric acid react with PCl5 to give
ans: butyryl chloride
180. acetic acid undergoes reduction with LiAlH4 to give
ans: ethanol
181. acetic acid react with methyl alcohol in the presence of an
acid catalyst to give
ans: methyl acetate
182. calcium acetate on strong heating gives
ans: acetamide
183. which reaction does not yield an ester as one of the
products?
Ans: a Grignard reagent is added to a carboxylic acid 184. silver
acetate react with Br2 to form methyl bromide, carbon dioxide and
AgBr.this is an example of
ans: hunsdiecker reaction
185. hunsdiecker reaction is used for the preparation of
ans: alkyl chloride and bromide
186. which of the following statement is false about primary
amines?
Ans: they do not form salt with acid
187. which of the following statement is false about secondary
amines?
Ans: they react with chloroform and NaOH to form
isocyanides. 188. The hybridization of nitrogen in an amine is
Ans: sp3
189. which of the following compound is a secondary amine?
Ans: CH3CH2NHCH3
190. a simple of pure amine molecule is found to possess no
intermolecular H-bonding. This simple is most likely: ans:
30amine
191. which of the following is least soluble in water?
Ans: aniline
192. which of the following is most soluble in water?
Ans:CH3CH2CH2NH2
193. which amine is not soluble in water?
Ans: all are water soluble
194. consider a 10,20,30amine, all of equivalent molecule weight
.which amine is most likely to have the lowest boiling point?
Ans: 30amnie
195. which of the following will have the highest boiling point?
Ans: triethylamine
196. which compound has the highest boiling point?
CH3CH2CH3 CH3CH2OH CH3CH2NH2
Ans: 2
197. which of the following has the highest boiling point ?
ans: CH3CH2CH2CH2NH2
198. amines are generally classified as
ans: weak base
199. which of the following is most basic?
Ans: dimethylamine
200. acetamide reacts with Br2/NaOH to give
ans: methylamine
201. acetonitrile undergoes reduction with LiAlH4 to form
ans: ethylamine
202. reduction of an imine will give an
ans: amine
203. alkyl halide react with ammonia in the presence of base to
form:
ans: primary amin
204. the major product of the following reaction is
CH3CH2Cl + (CH3)2NH 🡪?
Ans: 30amines
205. aliphatic primary amines react with cold nitrous acid to form
ans: alcohol
206. which types of amine produce N2 when treated with HONO?
Ans: primary
207. methylamine reacts with nitrous acid to form
ans: CH3OH
208. which of the following compound react with nitrous acid to
form an alcohol?
Ans: CH3CH2NH2
209. which of the following amines react with nitrous acid to
form nitrosamine?
Ans: diethylamine
210. which of the following does not react with acyl chloride to
form amides:
ans: 30amine
211. hinsberg reagent is
ans: benzenesulfonic acid
212. which of the following compound will dissolve in aqueous
NaOH after undergoing reaction with hinsberg reagent? Ans:
CH3CH2NH2
213. which of the following compound does not react with acetyl
chloride?
Ans: trimethylamine
214. a primary amine can be identified by using
ans: CHCl3 + KOH
215. carbylamines test is given by
ans: primary amines
216. a zwitterions is
ans: a compound that can ionize both as a base and an acid
217. a zwitterions has which of the following properties
ans: all of these
218. an aqueous solution of glycine is neutral because of the
formation of
ans: zwitterions
219. which of the following compound form zwitterions?
Ans: amino acids
220. the pH at which the amino acid shows no tendency to
migrate when placed in an electric field is known as its:
ans: isoelectric point
221. the isoelectric point of protein is
ans: the pH at which a protein in solution has an equal number
of positive and negative charges
222. which of the following reactions is suitable for the
preparation of alpha-amino acids?
Ans: strecker’s synthesis
223. glycine is
ans: NH2CH2COOH
224. glycine reacts with nitrous acid to form:
ans: glycolic acid
225. when glycine is heated ,it form:
ans: diketopiperazine
226. Select the most stable carbonium ion from the following?
Ans (d)(CH3)3C+
227. Homolytic fission of C-C bond leads to the formation of:
Ans(a)Free radicals
228. Homolytic fission of covalent bond between carbon atoms
will produce:
Answer.(c) Free radicals
229. The order of stability of carbonium ions is
Ans: (a) tertiary>secondary>primary
230. The order of stability of carbanions in
Ans: (a) primary > secondary > tertiary
231. Which of the following carbonium ions will be most stable?
Answer. (d)CH2=CHC +H2
232. The least stable carbanion is :
Ans:b) (CH3)3 C -
233. Which alkyl frec radical is the most stable ?
Ans: (d) tertiary
234. Which of the following is an electrophile ? (
Ans:b)CH3 C +H2
235. Which of the following is not an electrophile ?
Ans:(a) NH3
236. Which of the following statements is correct regarding
nucleophiles ?
Ans:(b) They have a lone-pair of electrons
237. Which of the following is a nucleophile ?
Ans:(d) CN
238. Which of the following is not a nucleophile ?
Ans:(c) AICI3
239. Which of the following is not a nucleophile ?
Ans:(b) BF3
240. Which of the following is a Lewis acid ?
Ans: (a) AICI3
241. Which of the following ranges best represents the strength
of a hydrogen bond ?
Ans:(a) 5-10 kcals
242. 1 Grignard reagents do not show any reaction with
Ans: (a) Alkoxy Alkanes
243. 2 The Grignard reagent,CH3CH2MgBr,can be used to prepare
Ans:(d)Mg,then H2O
244. 3. Which is the best reagent to accomplish the following
conversion?
Answer.(d)CH3CH2Br CH3CH3
245. What is the major product of the following reaction?
Ans:(c) 2-Butanol
246. Ethylmagnesium iodide reacts with formaldehyde to give a
product which on acid-hydrolysis forms:
Ans:(b) a primary alcohols
247. Ketones react with Grignard reagents to form an addition
product which on hydrolysis gives a
Answer.(b) a tertiary alcohols
248. n-PropyL magnesium bromide on treatment with carbon
dioxide and further hydrolysis gives:
Answer (c) Butanoic acid
249. Which of the following compounds will react with
methylmagnesium iodide followed by acid- hydrolysis to give
ethyl alcohols?
Ans:(c) Formaldehyde
250. Which of the following gives a tertiary alcohol when
treated with Grignard reagents ?
O
Ans:(c) CHз-C-CHз
251. Which of the following compounds will react with
methylmagnesium bromide to give tert-butyl alcohol
? Ans:(b)Acetone
252. Phenylmagnesium bromide reacts with acetaldehyde to form
an addition product which undergoes acid-hydrolysis to give
Ans:(c) Methyl Phenyl Carbinol
253. The number of structural isomers of alcohols with molecular
formula C,H,OH is
Ans:Answer. (d) 2
254. The number of structural isomers of alcohols with molecular
formula C4H9OH is
Answer. (b) 4
255. Why do alcohols have boiling points much higher than
hydrocarbons of similar molecular weight?
Answer. (c) Hydrogen bonds must be broken in the process of
volatilization.
256. The high boiling points of alcohols, as compared to the
corresponding alkanes, are due to
Answer. (a) Hydrogen bonding
257. Which of the following has the highest boiling-point?
Answer. (d) n-Butyl alcohol
258. Which of the following has the highest boiling point ?
Answer. (b) HOCH2CH2CH2CH2OH
259. Which of the following compounds has the highest boiling
point?
Answer. (b) CH3CH2CH2OH
260. Which of the following has the highest boiling point ?
Answer. (b) CH3CH2 CH2CH2OH
261. Rank the following substances in order of increasing boiling
point (lowest → highest):
262. (1) CH3CH2 CH2CH2OH (2) (CH3)2CHOCH3 (3) (CH3)3COH
Answer. (c) (2) < (3) < (1)
263. Which of the following compounds is the least soluble in
water ? Answer. (d) CH3CH2 CH2CH2OH
264. Methanol is known as :
Answer. (c) Wood alcohol
265. Rectified spirit is
Answer. (d) 95% Ethanol
266. Grain alcohol is another name for
Answer. (c) Ethyl alcohol
267. Lucas reagents is.
Answer. (c) HCl/ZNCL
268. Lucas test is used to determine the type of
Answer. (a) alcohols
269. Which of the following has the highest boiling point ?
Answer. (b) HOCH2CH2CH2CH2OH
270. Which of the following compounds has the highest boiling
point?
Answer. (b) CH3CH2CH2OH
271. 16.
272. Which of the following gives positive iodoform test
Answer (b) ) 2-Propanol
273. Which of the following reagents will replace -OH group by a
halogen atom?
Answer. (c) SOCI4
274. The compound which reacts most readily with Lucas reagent
is
Answer. (d) (CH3)3COH
275. Which of the following compounds reacts slowest with Lucas
reagent at room temperature?
Answer. (a) 1-butanol
276. Which of the following compounds will react fastest with
Lucas reagent?
Answer. (d) 2-methyl-2-propanol.
277. Which of the following compounds reacts fastest with HBr?
Answer (d) 2-methyl-2-propanol
278. When ethanol is treated with sodium metal:
Answer. (d) All these occur
279. Which of the following alcohols will give a yellow precipitate
of iodoform with iodine and dilute NaOH solution?
Answer. (b)2-Propanol
280. Ethyl alcohol can react with concentrated H2SO4 to give
Answer. (d) All of these
281. Ethanol on heating with concentrated H2SO4 at 170°C gives
Answer. (a) ethylene
282. The major product of acid-catalyzed dehydration of 2-
butanol is:
Answer. (a) 2-Butene
283. Which of the following reaction mixtures will give an organic
product which is ionic?
Answer. (c) CH2CH2OH + Na
284. Hydroboration-oxidation of propene gives:
Answer. (b) n-Propyl alcohol
285. Hydroboration-oxidation of 2-Methylpropene gives
Answer (с) 2-Methyl-1-prорanol
286. Which of the following compounds will not be easily
oxidized?
Answer. (c) Tertiary alcohol
287. Which of the following is most resistant to oxidation?
Answer. (d) (CH)3 СОН
288. Oxidation of a primary alcohol with KMnO4/OH produces
Answer. (a) a carboxylic acid
289. Oxidation of a secondary alcohol with K2Cr2O4/H+produces
Answer. (b) a ketone
290. Isopropyl alcohol reacts with acidic sodium dichromate to
give
Answer. (d) Acetone
291. Isopropyl alcohol can be converted to acetone by treatment
with
Answer (b) Na2Cr2O7/ H2SO4
292. Which of the bonds in Ethyl alcohol (CH3CH2OH) will undergo
heterolytic bond fission most readily?
Answer. (а) О-Н
293. The mechanism of dehydration of an alcohol to give an
alkene involves formation of :
Answer (a) Carbonium ions
294. The mechanism of dehydration of an alcohol to give an ether
involves formation of :
Answer. (a) Carbonium ions
295. The acid-catalyzed dehydration mechanism for alcohols is
best described as a(n):
Answer. (a) El
296. When ethanol is heated with concentrated H2SO4, a gas is
produced. Which of the following compounds is formed when
this gas is treated with bromine in CCl4?
Answer. (b) 1,2-Dibromoethane
297. The carbon atom of a carbonyl group is
Answer (b) sp2 hybridised
298. Which statement about the carbonyl group is NOT true?
Answer. (c) The three atoms attached to the carbonyl carbon
form a nonplanar geometry.
299. Acetone contains
Answer. (a) nine sigma bonds plus one x bond
300. Formalin is
Answer. (c) 40% solution of formaldehyde in water 301.
Which of the following will have the highest boiling point?
Answer (d) 2-Hexanone
302. Which of the following will have the highest boiling point?
Answer. (d) Butanal
303. What property of low-molecular weight aldehydes and
ketones accounts for the magnitude of their boiling points?
Answer. (c) The ability of the polar carbonyl group to
attract other polar molecules.
304. Primary alcohols have boiling points that are.
Answer. (b) Higher than
305. The melting points of aldehydes and ketones tend to:
Answer (b) increase with increasing molecular weight. 306.
Which action best accounts for the solubility of aldehydes and
ketones in water?
Answer. (d) H-bonding between solute and solvent molecules
307. Ketones are prepared by the oxidation of
Answer (b) Secondary alcohol
308. Which of the following do you consider to be suitable for
obtaining acetone (CH,COCH,) ?
Ans:(a) Heating CH,CI;CH,OH with acidic Na,Cr,O,
309. Cyclopentanol undergoes oxidation to give:
Answer. (b) Cyclopentanone
310. Acetone reacts with HCN to form a cyanohydrin. It is an
example
Answer. Nucleophilic addition
311. Which of the following reagents will react readily with both
aldehydes and ketones?
Answer. (a) Grignard reagent
312. The reaction of ethanol with one equivalent of methanol and
a trace of an acid will give
Answer. (b) Hemiacetal
313. Acetone undergoes reduction with hydrazine in the
presence of NaOH to form propane. This reaction is known
as Answer (b) Wolf-Kishner reduction
314. Acetone undergoes reduction with zinc amalgam in HCI to
form propane, This reaction is known as
Answer. (a)Clemmensen reduction
315. Cannizzaro reaction is not given by
Answer. (c) Acetaldehyde
316. When formaldehyde is treated with 50% NOH solution, it
undergoes
Answer. (a) Cannizzaro reaction
317. The reduction of a ketone
Answer (b) always gives a secondary alcohol
318. Reduction of acetaldehyde with H2/Ni gives Answer. (a) Ethyl
alcohol
319. On reduction with LIAIH4 which of the following compounds
could yield an optically active cоmpound?
Answer. (d) Butanone
320. The reduction of cyclohexanone with LIAIH4 (or NaBh,) will
give
Answer (a) an alcohol
321. Aldehydes undergo oxidation wóth KMnO4/H* to give
Answer. (d) Acids
322. Oxidation of acetaldehyde with Na2Cr2O7/H+ gives
Answer. (b) Acetic acid
323. A hydrazone will result from the reaction of hydrazine with
Answer. (b) an aldehyde
324. Aldehydes can be distinguished from ketones by using
Answer. (a) Ammoniacal AgNO3 solution
325. The appearance of a silver mirror in Tollens test indicates
the presence of
Answer(a) an aldehyde
326. Acetaldehyde on treatment with Tollens reagent gives a
precipitato of
Ans:(a) Ag
327. Which of the following compounds will give a positive lest
with Fehling's solution?
Answer. (a) Formaldehyde
328. Acetaldehyde on treatment with Fehling's solution gives a
precipitate of
Answer (b) Cu20
329. Which of the following will react with Fehling\'s solution
giving a red precipitate?
Answer (а) CН2CH2CHO
330. Which of the following compounds will give an iodoform
test?
Answer (b) Ethanal
331. Which of the following compounds does not give a positive
iodoform test with I2 /Na2OH:
Answer(c) Methanol
332. Which of the following compounds does not give iodoform
test on treatment?
Answer (d) Butanone
333. Which of the following compounds will give a positive
iodoform test?
Answer (b) 2-Pentanone
334. An organic compound (A), C3HgO, on oxidation gives (B),
C3H60. The compound (A) could be
Ans:(c) an alcohol
335. An organic compound (A), C3HgO, on oxidation gives (B),
C3H60. The compound (B) could be
Answer. (а) а carbonyl compound
336. An unknown compound gave a positive Tollens' test.
Treatment of the unknown with I2 /Na2OH gave a solid which
was identified as iodoform. The unknown was?
Answer. (a) Ethanal
337. Organic compound (A), C4H8O, does not react with sodium
or PCI5. However, it reduces an alkaline solution of a copper (II)
salt on heating. Compound (A) could be
Answer. (a) an aldehyde
338. Check the incorrect statement : Answer. (a) Acetic acid is
present in sour milk In the conversion of wine to vinegar
Answer. (a) Ethanol is oxidized to acetic acid
339. Vinegar is a
Answer. (a) 5% solution of acetic acid in water
340. In succinic acid, HOOC(CH2)nCOOH, n is equal to
Answer. (d) 4
341. In adipic acid, HO0C(CH2)nCOOH, n is equal to
Answer. (d) 4
342. The compound in which hydrogen bonding is not possible is
Answer. (a) CH3OCH3
343. Which compound has the highest boiling point?
Answer. (d) CH3COOH
344. When carboxylic acids and dicarboxylic acids have similar
molecular weights, how do their melting points compare?
Answer. (b) Dicarboxylic acids have greater melting points.
345. The greater acidity of carboxylic acids compared to alcohols
arises primarily from:
Answer. (d) the resonance stability associated with the
carboxylate ion
346. Which of the following statements is false about the acid
strength of acetic acid?
Answer. (a) Acetic acid is a stronger acid than
monochloroacetic acid.
347. Which of the following is the strongest acid?
Answer. (d) Trifluoroacetic acid
348. Which of the following is the strongest acid?
Answer. (b) 2-Chlorobutanoic acid
349. Which of the following is the strongest acid in aqueous
solution?
Answer. (d) Cl2CHCOOH
350. Which is the strongest acid?
Answer. (d) Cl3CCOOH .
351. Which of the following compounds is most acidic?
Answer (d) FCH2COOH
352. Which of the following compounds is the strongest acid ?
Answer (d) FC2H4COOH
353. Which of the following compounds is least acidic ?
Ans:(a) CH,CH;COOH
354. Which of the following compounds is most acidic ?
Ans: (d) CH,-CH-COOH
355. Which of the following will give acetic acid on acid
hydrolysis ?
Answer (a) Ethyl acetate
356. Propanenitrile undergoes acid-hydrolysis to give
Answer (b) Propionic acid
357. The characteristic reaction of carboxylic acids is:
Ans:(d) nucleophilic substitution
358. Glycine is a unique amino acid because it is
Ans: Has no chiral carbon
359. Which of the following organic ions result when glycine is
treated with concentrated HCl?
Ans: N+HCH2COOH
360. Proteins are
Ans:polyamides
361. The five elements present in most naturally occurring
proteins are
Ans:N, S, C, H and O
362. the nitrogen content of proteins can be quantitatively
determined by
Ans: Kjeldah's method
363. which of the following is the main structural features of
proteins?
Ans:Peptide linkage
364. The linear arrangement of amino acid units in proteins is
called
Ans: primary structure
365. The primary structure of protein refers to:
Ans:the amino acid sequence in the polypeptide chain
366. The alpha Helix is a common form of
Ans:Secondary structure
367. The alpha Helix is held in a coiled conformation partially
because of:
Ans: Hydrogen bonding
368. the double helical structure of DNA is held together by
Ans:Hydrogen bonding
369. Upon hydrolysis protein gives
Ans:amino acid
370. Complete hydrolysis of protein produce
Ans:A mixture of amino acid
371. Digestion of proteins involves
Ans: cleavage of peptide linkage
372. Irreversible precipitation of protein caused by heating is
called:
Ans:denaturation
373. Precipitation or coagulation of proteins may be caused by
Ans: All of these
374. Ninhydrin test is given by
375. Ans: protein
376. Which of the following test is not used for testing proteins?
Ans: tollen's test
377. A protein solution on warming with concentrated HNO May
turn yellow. this test is called:
Ans:xanthoproteic test
378. A compound gives a positive tollens test but negative
ninhydrin test. it is
Ans: A monosaccharide
379. Monosaccharides are classified according to:
Ans: all of the above
380. Which is a monosaccharide?
Ans: galactose
381. Which is a disaccharide
Ans:Maltose
382. Which of the following is not a monosaccharide?
Ans: Sucrose
383. The designation D or L before the name of a
monosaccharide
Ans: Indicates the position of the OH group on the carbon next
to the primary alcohol group
384. The principal sugar in blood is
Ans:glucose
385. Which of the following statements is false about glucose?
Ans:It is a disaccharide
386. Which of the following statement is false about alpha-D
glucose?
Ans: It is the purest form of table sugar
387. Alpha-D glucose is different from beta-D glucose
Ans: In the configuration at C-1
388. Alpha D glucopyranose is a
Ans: hemiacetal
389. The number of asymmetric carbon atoms in the alpha-D
glucopyranose molecule is
Ans: 5
390. Which of the following statement is false about an
aldohexose?
Ans:fructose is an aldohexose
391. All of the following monosaccharides Give the same osazone
except
Ans: Galactose
392. Mutarotation is a term related to
Ans:interconversion of anomers
393. The mutarotation of glucose is characterized by Ans:
The presence of an intramolecular bridge structure 394.
Which of the following statement is false about
glyceraldehyde
Ans: It shows mutarotation
395. Common table sugar is
Ans: sucrose
396. Which of the following carbohydrates is sweeter than
sucrose?
Ans:fructose
397. By approximately what factor is the sweetness saccharin
greater than that of sugar?
Ans: 500
398. Which off the following statement is false about sucrose ?
Ans: it reduce fehling solution
399. The sugar that yield only glucose on hydrolysis is
Ans:maltose
400. A reducing sugar will
Ans: react with fehling test
401. Which of the following carbohydrate is not a reducing
sugar?
Ans:sucrose
402. Which Of the following carbohydrate will not give a red
precipitate Cu2O when heated with Benedict solution?
Ans:sucrose
403. Which of the following compounds reduce tollens reagent?
Ans: glucose
404. The reagent that can be used to differentiate an aldose and
ketose is
Ans:bromine water
405. Starch
Ans:is mixture of amylose + amylopectin
406. The monosaccharide obtained by hydrolysis of starch is
Ans: D-glucose
407. Which of the following statements is false about cellulose?
Ans: It is used in the manufacture of dacron fibres 408. Which of
the following product is not derived from cellulose?
Ans: insulin
409. Coal-tar is the main source of
Ans: aromatic compounds
410. Which of the following fractions of coal-tar distillation
contains benzene?
Ans: light oil
411. Which of the following fraction of coal-tar distillation
contains naphthalene?
Ans: middle oil
412. Aromatic hydrocarbons are also called
Ans: arenes
413. Which of the following is an aromatic compound?
Ans: benzene-CH2CH3
414. Which of the following compounds is not an aromatic
compound?
Ans:
415. Which of the following compounds is known as Aniline?
Ans: benzene-COOH
416. Which of the following structure represent m
dichlorobenzene?
Ans:meta positon
417. Which of the following statement are false about benzene?
Ans:it is immiscible with water forming the lower layer. 418.
Which statement about the structure of benzene is not true?
Ans: the two kekule structure of benzene are in equilibrium
419. The carbon atoms in a benzene ring are
Ans:sp2 hybridized
420. Which of the following compounds use only sp2 hybridized
carbon for bond formation?
Ans: benzene
421. The C-C bond length in benzene is
Ans: Intermediate between C-C bond length in ethane end C-C
bond length in ethylene
422. Characteristics reactions of aromatic hydrocarbon are
initiated by
Ans: electrophiles
423. Phenol On distillation with zinc dust give
Ans: benzene
424. Which of the following reagent will react with methyl group
rather than the benzene ring in methylbenzene?
Ans:chlorine in the presence of uv light
425. Which of the following can be made by the action of CH3Cl
on benzene in the presence of aluminium chloride? Ans:
o-Xylene
426. For reaction of ethylbenzene the ethyl group is considered
Ans:ortho-pera director
427. Toluene react with bromine in the presence of UV light to
give
Ans:benzyl bromide
428. Toluene react with chlorine in the presence of AlCl3 to give
Ans:o-plus p-Chlorotoluene
429. Toluene undergoes oxidation to give
Ans: benzoic acid
430. ethyl benzene undergoes oxidation with acidic potassium
dichromate to give
ans:benzene-COOH
431. Oxidation of cumene with acidic K2Cr2O7 gives
Ans: benzole acid
432. Oxidation of toluene with chromyl chloride gives
benzaldehyde.this reaction is known as
Ans: Etard’s réaction
433. Oxidation of p-xylene acidic potassium dichromate gives
Ans: HOOC-benzene-COOH
434. Cresols on distillation with zinc dust gives
Ans: Toluene
435. benzene undergoes substitution reaction more easily than
addition reaction because
Ans: There is delocalization of electrons
436. Benzene react with concentrated HNO3 in the presence of
concentrated H2 SO4 to give nitrobenzen. this reaction is an
example of
Ans:Electrophilic substitution
437. Which of the following agent is used in order to make
benzene reacts with concentrated nitric acid to give
nitrobenzene ?
Ans: concentrated H2SO4
438. Which of the following agent is used in order to make
benzene react with acetyl chloride to give acetophenone?
Ans: AlCl3 catalyst
439. Which of the following agent is used in order to make
benzene react with bromine to give bromobenzene? Ans:
Fe catalyst
440. The electrophile which is considered to be the active agent
in the nitration of benzene is
Ans: NO2+
441. In chlorination of benzene, FeCl3 is used to generate
Ans: Cl+
442. In sulfonation of benzene the attacking species is
Ans: SO3
443. The catalyst used to complete the above reaction is
Ans:AlCl3
444. Benzene react with H 2 at 1500C at 30 atm in the presence of
Ni catalyst to give
Ans:Cyclohexene
445. Benzene reacts with chlorine in the presence of FeCl3
catalyst to foam
Ans:chlorobenzene
446. Benzene react with acidic anhydride in the presence of AlCl3
to form
Ans: acetophenone
447. Benzene react with benzyl chloride in the presence of
anhydrous aluminium chloride to form
Ans:benzophenone
448. Benzene undergoes Friedel craft reaction with isopropyl
alcohol in the presence of H2SO4 catalyst to give
Ans: Isopropylbenzene
449. Benzene reacts with propane in the presence of H2SO4
catalyst to give
Ans:cumene
450. Ozonolysis of benzene gives
Ans:glyoxal
451. Gammexane is
Ans: hexachlorocyclohexane
452. Which of the following statement is false about aniline?
Ans:It liberates nitrogen on treatment with ice cold nitrous
acid
453. Which of the following statements is correct about aniline
Ans:Diazotises to Benzenediazonium chloride when heated
with ice cold nitrous acid
454. Which of the following is statement is false about
benzylamine?
Ans:Cannot be prepared by reduction of benzamide with LiAlH4
455. Aniline is prepared by
Ans:The reduction of nitrobenzene with Sn/HCl
456. Benzamide react with Br2 and KOH to give
Ans:benzylamine
457. When ammonia is added to an alkyl halide in the presence
of base
Ans:Primary amines form
458. Aniline react with bromine water to form
Ans:2,4,6-tribromoaniline
459. Which of the following will give a precipitate with excess
bromine water
Ans:aniline
460. aniline react with nitrous acid at a low temperature to give
Ans: a diazonium salt
461. When aniline is heated with chloroform and alcoholic KOH2
the product is
Ans: phenylisocyanate
462. Aniline reacts with acetic anhydride to give
Ans:acetanilide
463. Aniline undergoes oxidation with Na2Cr2O7 /H2SO4 to give
Ans: p-benzoquinone
464. Which of the following reagent does not react with aniline?
Ans: ammonia
465. Which of the following compound is most basic
Ans:benzylamine
466. Which of the following is most basic
Ans: (CH3)2NH
467. Which of the following is least basic?
Ans:p-nitrophenol
468. Which of the following compound will be most soluble in
water at room temperature?
Ans: phenylammonium chloride
469. The diazonium salt or the reaction product of the reaction of
nitrous acid with
Ans:Primary aromatic amine
470. Preparation of diazonium salt from a primary aromatic
amine is known as
Ans:diazotization
471. Which of the following reagent is used to prepare
benzenediazonium chloride from amine?
Ans:NaNO2 + HCl
472. Benzenediazonium chloride reacts with warm water to give
Ans:phenol
473. Bromobenzene can be prepared by treating treating aniline
with
Ans:Br2/FeBr3
474. Chlorobenzene can be prepared by treatment of aniline with
Ans:Nitrous acid followed by treatment with CuCl2 475.
Iodobenzene can be prepared by
Ans:Treating benzenediazonium chloride with KI
476. Benzenediazonium chloride react with KI to form
Ans:iodobenzene
477. Benzene diazonium chloride react with hypophosphorous
acid to form
Ans:benzene
478. Benzene diazonium chloride react with phenol to form
Ans: p-hydroxyazobenzene
479. Phenol is used
Ans: as moth repellant
480. Which of the following compound is aspirin
481. Ans:acetylsalicylic acid
482. When phenol is treated with neutral FeCl3 solution, it
develops
Ans:violet color
483. Which of the following compound will react with PCl5 least
vigorously?
Ans:phenol
484. Sodium phenoxide react with CO2 at 1250C under 5 atm
pressure to give salicylic acid. this reaction is called
Ans:kolbe's reaction
485. Phenol reacts with excess bromine water to give
Ans:2,4,6-tribromophenol
486. Resorcinol on distillation with zinc dust gives
Ans:benzene
487. Bakelite has the following characteristics
Ans: all of the above
488. Anisole is formed when phenol is treated with
Ans: CH3I/NaOH
489. Anisole on heating with concentration HI gives
Ans:phenol + CH3I
490. Which group from the strongest H-bond to water molecule?
Ans:phenol
491. The compound which is most capable of hydrogen bonding
is
Ans:benzene-OH
492. Phenol is acidic because of
Ans: resonance
493. Which of the following has the most acidic proton?
Ans: phenol
494. Phenol is
Ans:Weaker acid than acetic acid
495. Which of the following compound is least acidic?
Ans:acetylene
496. Which of the following compound is least acidic?
Ans:ethanol
497. Which of the following compound is most acidic?
Ans: formic acid
498. Which of the following compound is most acidic?
Ans:phenol
499. Which one is most acidic?
Ans:phenol
500. Phenols can be easily distinguished from alcohols because
Ans:phenols are soluble in NaOH, but alcohols are not 501.
Benzoyl chloride reacts with hydrogen in the presence of
Palladium and barium sulfur to give
Ans:benzaldehyde
502. Cinnamaldehyde is prepared by the treatment of
Ans:Benzaldehyde with acetaldehyde in the presence of NaOH
503. Benzaldehyde reacts with methyl magnesium iodide to form
Ans:1-phenylethanol
504. Which of the following will undergo aldol condensation?
Ans:acetone
505. When benzaldehyde is heated with concentrated NaOH, it
gives
Ans:benzyl alcohol + sodium benzoate
506. Benzaldehyde react with acetic anhydride in the presence of
sodium acetate at 180C to give
Ans:cinnamic acid
507. Benzaldehyde react with a mixture of concentrated sulfuric
acid and nitric acid to give
Ans:m-nitrobenzaldehyde
508. Acetophenone react with Br2 in the presence of FeCl3 two
form
Ans:m-bromoacetophenone
509. Which of the following statement is not correct
Ans:Locus test is given by both aliphatic and aromatic
aldehyde
510. Benzaldehyde can be distinguished from acetophenone by
using
Ans:tollen reagent
511. Benzaldehyde does not react with
Ans:fehling solution
512. Which of the following compound yield a yellow precipitate
when warmed with a mixture of iodine in aqueous sodium
hydroxide?
Ans:acetophenone
513. How many isomers containing a benzene ring correspond to
the formula C6H4(COOH)2 ?
Ans:3
514. Which of the following is not a carboxylic acid?
Ans:picric acid
515. Phenylmagnesium bromide react with CO2 followed by acid
hydrolysis to form
Ans:benzoic acid
516. Benzoic acid and diphenyl ketone are both solid insoluble in
water. a mixture of this compounds can be separated if we
Ans:Add the mixture to a solution of filter NaOH in water, and
filter
517. Which of the following reaction does not produce benzene
as one of the product?
Ans:fusing sodium benzenesulfonate with NaOH
518. Which of the following esters produce butyric acid and
phenol on hydrolysis?
Ans:phenyl butyrate
519. Benzoyl chloride on basic hydrolysis gives
Ans:sodium benzoate
520. Sodium benzoate on heating with soda-lime gives
Ans:benzene
521. Methyl benzoate on hydrolysis gjves
Ans:benzoic acid
522. Aspirin is produced by heating salicylic acid with
Ans:Aesthetic anhydride in the presence of phosphoric acid 523.
oil of wintergreen is obtained by treating salicylic acid with
ans:CH3OH and conc. H2SO4
524. Which of the following statement is true
Ans:o-nitrobenzoic acid is more acidic than p-nitrophenol
525. Which of the following is the strongest acid?
Ans:trichloroacetic acid
526. Which of the following is the strongest acid?
Ans:benzoic acid
527. Which acid is weaker than benzoic acid
Ans:p-methylbenzoic acid
528. Which of the following is a chromophore?
Ans: -NO2
529. Which of the following is an auxochrome?
Ans: -OH
530. The water solubility of dyes can be increased by introducing
Ans: all of these
531. Which dyes become linked to the fiber by chemical reaction?
Ans: acid dyes

1. Which is the ‘m’ (meta) directing group?

a. –OH
b. -NH2
c. -NO2
d. -CH3
2. Dry ether is used in the preparation of
a. CH3COCH3
b. RMgX
c. TEL
d. CH3Li
3. Which is the organometallic compound?
a. CH3COCH3
b. CH3CHO
c. (C2H5)4Pb
d. HCHO
4. Which is the most reactive towards nucleophilic substitution
reaction? a. CH3COCH3
b. CH3CH2CHO
c. HCHO
d. CH3CHO
5. Which is an optical active compound?
a. Benzoic acid
b. Acetic acid
c. Formic acid
d. Lactic acid
6. Which is the unsymmetrical ketone?
a. CHC3OCH3
b. CH3CHO
c. CH3CH2COCH3
d. HCHO
7. When n=2 the name of COOH-(CH2)n-COOH is…
a. Adipic acid
b. Oxalic acid
c. Succinic acid
d. Maleic acid
8. Example of dicarboxylic organic acid…
a. Butanoic acid.
b. Acetic acid.
c. Chloro acetic acid
d. Oxalic acid.
9. Which is less reactive organometallic
compound? a. RMgX
b. Methyl Lithium
c. (C2H5)2Zn
d. TEL
10. Write the example of aromatic amine…
a. C6H5Cl
b. C6H5NH2
c. C6H5NO2
d. C2H5NH2
11. How many groups contain in
carboxylic acid?
a. 1
b. 2
c. 3
d. 4
12. Lucas reagent is a mixture of…
a. HCl + AlCl3
b. Conc. HCl + Anhydrous ZnCl2
c. HCl + ZnCl2
d. HNO3 +HSO4
13. Benzene sulphonyl chloride is a
reagent of…
a. Acrolyn test.
b. Heisenberg
c. Hofmann degradation
d. Liebermann test
14. Dehydrogenation method carried out at
temperature? a. 200oC
b. 300oC
c. 100oC
d. 400oC
15. Example of dihydric alcohol?
a. Methanol
b. Glycerin
c. Ethylene glycol
d. Phenol
16. Friedel crafts reaction is
classified into…?
a. 2
b. 4
c. 1
d. 3
17. Example of dicarboxylic organic acid
a. Propanoic acid
b. Succinic acid
c. Acetic acid
d. Formic acid
18. Which is the ‘o/p’ (ortho/para)
directing group?
a. -CH3
b. -NH2
c. -COOH
d. -CHO
19. Common table sugar is…
a. Maltose.
b. Glucose.
c. Sucrose.
d. Fructose.
20.The umber of asymmetric carbon atoms in the alpha D-glucopyranose
molecule is…
a. 1
b. 5
c. 3
d. 2
21. The principal sugar in blood is…
a. Sucrose
b. Glucose
c. Starch
d. Cellulose
22. Aniline and chloroform are detected by…
a. Acrolein test
b. Hofmann degradation reaction
c. Cannizzaro reaction
d. Carbylamine test.
23. Starch is a…
a. Amylopectin
b. Amylose
c. Amylose + Amylopectin.
d. Trisaccharide
24.Which of the following is not a monosaccharide?
a. Ribose
b. Glucose
c. Source
d. Fructose
25.Which of the following is the main structural feature of
proteins?
a. Alpha beta linkage
b. Peptide linkage
c. Ester linkage
d. Ether Linkage
26. The reagent that can be used to differentiate an Aldose and
Ketones is… a. Tollens reagent.
b. Bromine water
c. Fehling’s solution
d. None of these
27. A zwitterion has which of the following properties…
a. A high melting points.
b. No net charge
c. Soluble in water
d. All of these
28.Which is the example of pigment?
a. Indigo
b. Ferrous sulphate
c. Copper phthalocyanine
d. Alizarin
29. A compound gives a positive tollens’ test but negative ninhydrin
test, It is… a. Pyridine
b. An amino acid
c. A protein
d. A Monosaccharide
30.Glucose cannot be classified as…
a. A hexose.
b. A Monosaccharide
c. An Aldose
d. An Oligosaccharide
31. How many hydroxyl groups contain in a glucose
molecule?
a. 8
b. 5
c. 4
d. 6
32. Which is the following is a chromophore?
a. -OH
b. -COOH
c. Sodium amine
d. -NO2
33. Precipitation or Coagulation of proteins may be
caused by
a. Heat
b. Changes of pH
c. Heavy metal salts
d. All of these
34. Alpha D-Glucopyranose is a…
a. Acetal
b. Hemiketal
c. Hemiacetal
d. Ketal
35.Which dyes become linked to the fibre by chemical
reaction?
a. Acid dyes
b. None of these
c. Direct dyes
d. Disperse dyes
36. A monosaccharide obtained by hydrolysis of starch is
a. D-Ribose
b. Maltose
c. D-glucosed.
D.Galactose