US03CCHE22 PHYSICAL CHEMISTRY ASSIGNMENT

UNIT-2 CHEMICAL THERMODYNAMICS

Q-1 Prove that work and heat are not state functions.
Q-2 State Hess’ law of constant heat summation and give its applications with suitable
examples.
Q-3 Define heat capacity. Establish relation between Cp and Cv.

Q-4 Derive Kirchhoff’s equation.

UNIT-3 COLLIGATIVE PROPERTIES OF DILUTE SOLUTIONS

Q-1 Explain osmosis and osmotic pressure. Derive an equation correlating osmotic
pressure with solution concentration.
Q- 2 What is depression of freezing point? Derive the relation between depression of
freezing point and molality.
Q-3 What is elevation in boiling point? Derive an equation correlating elevation in
boiling point and molality.
Q-4 Discuss static and dynamic methods for the measurement of vapor pressure
lowering.