ORDER OF REACTION 1 For a chemical reaction A —»Producis, the rate of disappearance of A is given by, = 5 ha K [Caren } : At low Cy; the reaction of the Ky, Ky are lesser than I), (A) Kv/K2(B) 1, Ky(C) I, Ky/Ka(D) HH, Ki’ +K order with rate constant 2. Fora certain reaction of order ‘n’ the time for half change tia Is given by: tra rate constant and Co is the initial concentration. The value of nis: (A) 1(8) 2(C) 0(D) 0.5 3. Which curve represents zero order reaction? a 4 (a) ‘ - . KK 4, Select the correct statements out of |, Il and Ill for zeroth order reaction |: Quantity of the product formed is directly proportional to time Il: Larger the initial concentration of the reactant, greater the half-life period. Iil: If 50% reaction takes place in 100 minutes, 75% reaction take place in 150 minutes. (A) lonly (B) land! only (C)anditontly — (0) I, and 5 For the elementary step, (CHs)3 . CBr(aq) —+ (CHs):C"(aq) + BF(aq) the molecularity is: (A) zero (8)1 (C2 (D) cannot ascertained 6. Ay + Bp 2AB; ROR. = K(A,T (BT ‘Ay conc. B;cone. ale 0.2 0.2 0.04 0.1 0.4 0.04 0.2 0.4 0.08 Order of reaction with respect to A, and B, are respectively (A)a=1.b= (B)a=2,b=0 (C)a=2,b=1 (0) None 7 A substance ‘A’ is mixed with equal quantities of substances B and C. At the end of 1000 sec. half of the amount of ‘A’ has reacted whal fraction of ‘A’ will be left unreacted at the end of 2000 sec. ifthe reaction is zero order with respect to A. Comprehension For the overall reaction between A and B to yield C and D, two mechanism are proposed: 1 M. A+B —, ABY —,C+D, AA —E, E+B —.C+p, (Species with * are short-lived) ky’ 1x10 Ms kys1x10%st k= 1x 10M" st Rate law of for mechanism | wh i of for m en concentration of each is 0.1 M, is: . (A) 1107 Ms (B)1x10%Ms" (Cc) 1x10Ms* (0) 1x 10" MS"8, Rate lawof mechanism Il when concentration of each 4, M I )ixiotMs — (B)1xt0"Ms" — (C) 1x 10M (0) 1x10" Ms" 10. Atwhat concentration of B, rates of two mechanism are equal: HA) IM (B) 5M (C)7M (0) 10M * Comprehension , ‘At600°C, acetone (CH;COCH:) decomposes to elena (CH, = C = 0) and various hydrocarbons, Initial rate data are given in the table below. Experiment [ initial Rate of a [CH,COCH,} | decomposition 1% 6.0x10> | 5.2x 10% 2 90x10 |7.8x 10% 1. The rate law for the decomposition of acetone to ketene is (A) rate = KCHsCOCHs]"(B) rate = k{CH;COCHS)"(C) rate = K{CHsCOCH,}"(0) rate = K{CH,COCH,)” 12. The rate constant for the decomposition reaction is (A) 8.7x 107s (B) 6.12 x 10% s(C) 28x 10%s" (0) 110x107 s™ 43. Which of the following is the rate of decomposition when the [acetone] is 1.8 x 10 M? (A) 1x10 Ms {B) 1.6 x 10° Mis(C) 2.7 x 10° Ws (D) 3.1.x 10% Ws 14. Consider a reaction aG + BH —+ Products. When concentration of both the reactants G and H is doubled, the rate increases by eight times. However, when concentration of G is doubled keeping the concentration of H fixed, the rate is doubled, The overall order of the reaction is (2007) (A) 0(B) 1(C) 2(D) 3 + 15.Raté of a reaction A +B—»Products, is given below as a function of different initial concentrations of A and B: TA] (moiitre) [8] {mollitre) Initial rate (molfitre/min) 0.01 0.01 0.005 0.02 0.01 0.010 0.01 0.02 0.008 Determine the order of the reaction with respect to A and with respect to B. What is the half-life of A in the reaction? (1982) 16. For the reaction system: [AIEEE 2003) 2NO(Q) + Oz (g) —+ 2NO, (g) volume is suddenly reduced to half its value by increasing the pressure on it. if the reaction is of first order with respect to O; and second order will respect to NO the fate of reaction will (A) increase to four times of its initial value (B) diminish to one-fourth of its inital value (C) diminish to one-eight ofits initial value (0) increase to eight time of its inital value 17. The rate equation for the reaction 2A + B —+ Cis found to be : rate =k (A) [B]. The correct statement in relation to this reactions that the [AIEEE 2004) (A) utit of k must be s™ (8) $ is a constant (C) rate of formation of C is twice the rate of disappearance of A (0) value of k is independent of the Initial concentrations of A and B 18. A reaction was found to be second order with respect to the concentration of carbon monoxide. if the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction wil [AIEEE 2008) (A) increase by afactor of 4 (B) double (CG) remain unchanged (0) tiple 19. Consider the reaction, 2A +B —+ Products [AIEEE 2007] When concentration of B alone was doubled, the half Iie did not change. When the concanisation of A alone was doubled, the rate increased by {wo times. The unit of rate constant for the reaction is. (A) L mor! s* (B) no unit (C) mal Ut st (D) s* 20, ForareactionA + 8 —+ products, the rate of the reaction was doubled when the concentration of was doubled. When the concentrations of A & B were doubled, the rate was again doubled, ine order of the reaction with respect to A & B are21. 23. 26, 2s. 26. 28. nu. Atimes (A) 11 (B) 2,0 (C) 1,0 (0) 0,4 The decomposition of ozone Is believed to occur by the mechanism: 0; == 0, + O (fast) +0, —+0, (slow) When the concentration of 0, is Increased, then the rata (A) increases(B)decreases (C)remains same(D)cannot be predicted In the sequence of the reaction A—L+8—2.C—.4, given that K, C (C) C+D (2) —A——8 Hall life of a chemical reaction at a particular concentration is 50 min. When the concentration of the reactant is doubled, the half fe becomes 100 min, then the order of the reaction is: (A) zero{B) first(C)second{D)third In the sequence of reaction xt y—2 2p Where K, >K, >K,, the rate law of the overall reaction will be @ +21-k71@)-2)-K,09 0 +Flaxm 0+ Elo, +x, +) The rate law for_a reaction between the substances A and B is given by Rate = KAT" [8]” On doubling the concentration of A and halving the concentration of 8, the ratio of the new rate to the earlier ratio of the reaction will be as a Fal {B) (em + n) (C) (a —my(O) 2"-™ The rate of the reaction A+B —+ Productsis given by the equation ¢ = K[AJ[B}. If B is taken in large excess, the order of reaction would be (A) 2(8)1(C)0(0)3 The half-life period for a reaction at initial concentrations of 0.5 and 1.0 mol lit'are 200 sec and 100 sec respectively. The order of the reaction is (A) zero(B)1(C)2(0)3 1 L of 2M acetic acid is mixed with 1 L of 3 M ethyl alcohol to form an ester CH,CO,H + CH,CH,OH—+CH,CO,CH,CH, + H,0 The decrease in the initial rate if each solution is diluted by an equal volume of water would be (A) 0.5 times(B)2 times(C)4 times(D)0.25 times Rate constant data of the following reactions are as given below: 1 2A—+ Products, k = a mor L min" MN DB—>+ Products, k = bmin™ The half-lives of both the reactions are the same equal to 1 hour when molar concentration of reactant is equal to 1.0 mol L“' in each case. If these reactions are carried out simultaneously taking 1 M of the reactant in each case, the ratio (AJB) after a lapse of 3 hours will be (A) 2(8)0.5(C)4(0)1 The rate constant for a zero order reaction is 2 x 10 mol L“' sec"'. If the concentration of tne reactant after 25 sec is 0.5 M, the initial concentration must have been (A) 0.5 M(B) 1.25 tA (C) 12.5 MA(D) 1.0 M. The thermal decomposition of acetaldehyde CHj;CHO ——» CH, + CO, has rate constant of 1.4 « 107 mole"7L'? min” at a given temperature. How would fener will change if concentration of acetaldehyde Is doubled keeping the temperature constant? (A) will increase by 2.828 times(B) will increase by 11.313 tenes (C) will not change(O) will increase by32,” Forreaction Ay + 28 ——» 2D a VA) (8) Rate (M seo") 0.1 0.2 1x 10°? 0.2 02 2x10? 0.2 0.8 4x 107 ‘Then order w.r. tA; and B are respectively (A) 1,2 (B) 2, UC) 1, % (0) 2,2 33, Ifa is the initial concentration of a substance which reacts according to zero order kinetics and K is rate constart, the time for the reaction to go to completion is (A) a/K(B) 2/Ka(C) K/a(D) 2K/a 34. The data given below is for the reaction of NO and Cl, to form NOCI at 295 K [Ch] INO) _] Initial rate (mot I s") 0.05 0.05 4x10" O45 0.05, 3x10? 0.05 0.15, 9x10" Among the following which expression is correct about the above reaction (A) r= K [NOJ[CH](B) ¢ = K{CI} [NO}*(C) r = K [Cla]? [NO](D) ¢ = K[Ch] 35. The rate constant is numerically the same for three reactions of first, second and third orders. respectively. Which one is true for rate of three-reactant concentration of reaction is less than 1M (A) F1=19=13(B) r2r2>4(C) ry inital all~ie) (A) Zero order (8) Firstorder (C) Second order (0) None of these ORDER OF THE REACTION 1B 2/0 3)C 4)D 5)C 6)A 7)ZERO 8A 9)C 1A 118 12)A 13)B 14)D 15) A=0,B=1,Tyq1.386min 16)D 17)D 18)A 19)A 20)C 21)B 22)A 23)A 24)A 25)D 26)B 27)C 28)C 29)A 30)D 31)A 32)C INA 34)B 35) 36)5 37)A