10. 11. 12, 13. 14, 15. 16. 17: 18. 19. 21. 22. 23. 24. 25, 26. 27. 28. 29. so. 31. 35. a7. 39. 40, a. 42. 43. a4. 46. 47. 48. 49. Macromolecules are (a) organic molecules (b) high molecular mass molecules (c) natural compounds. (d) rarely occurring molecules The negatively charged particies are called (a) cation (b) radical (c) anion (d) positron a Which of the following is not a separation technique, © | {@) filtration (b)_ sublimation (c) solvent extraction (d) boiling Sublimation is a separation technique used to remove a {a} non volatile component from a volatile component (b) low bailing component from a high boiling component (c), fast moving component from a slow moving component (d) miscible liquid from a solid if allowed to expand, the gases suddenly (a) heat up (b) move randomly (©) react (d) cool down Which one of the following is not postulated in the kinetic molecular theory of gases. (a) molecules of all the gases have same size and same mass (b) molecules are in chaotic motion (e) all molecular collisions are-olastic (d) the volume of the molecules is negligible Which Is the correct order of boiling points: (a) HzO > HF > NH3 > CHa (b) HzO > NH3 > HF > CH, (6) HO = HF = CH, > NHa (d) H20 > NH3 > CH, > HF In which system hydrogen bonding Is not present (a) solution of ethanol in water (b) linking of helix in protein molecule (c) structure of ice (a) solution of NaC! in benzene Splitting of spectral lines when atoms are subjected to strong electric field is called if {a) zeeman effect (b) Stark effect (c) photoelectric effect (d) Compton effect Rutherford’s model of atom failed because (a) the atom did not have a nucleus and electrons (b) it did not account for the attraction between protons and neutrons (c) it did not account for the stability of the atom (d) there is actually no space between the nucleus and the electrons The driving force for making a bond is (a) to attain noble gas electronic configuration {b) to make solid compounds (c) to make different compounds (d) to make gaseous substances Elements have the tendency to attain 8 electrons in their valence shell. This is known as (a) Octet rule (b) Hunds rule (c) Pauli exclusion principio (4) Auf ban principle The branch of science which deals with anergy transformations is known as. ‘ (a) thermochemistry (b) kinetics {c) photochemistry (d). thermodynamics The total energy contained within a chemical system is called its (a) enthalpy (6) intemal energy (¢) kinetic energy (d) potential energy The rate at which the reaction proceeds Is directly proportional to the product of the active masses of the reactants is according to (a) law of mass action (b) Le Chateliers principle (ce) Equilibrium taw (d) Law of constant proportion For the equilibrium expression 2Ajaq) + Biaqy ——~ Crag). Ke is given by ic) ‘C} @) kK = (&) kK, = SL, Keo = TAY (Bi » Ke = tay te1= (e) Kea 52 () Ke=—" ee pore Pa™ Pp PAX Pa Precipitation will occur until the ionic product becomes fa) equal to Ksp (b) Lesser than Ksp. (c) Greater than Kp (d) None of these What Is the molarity of a solution containing 15.0 g urea in 500 cm* of solution (a) 0.5M (b) 1M f (c) 15M fl) 2S oe yh A device which converts electrical energy into chemical energy is called Tiki) {a) a galvanic cell (b) a voltaic con (6) a electrolytic cell ‘ (d) a chemical cell When a nof-spontaneéous reaction takes place at the expense of electrical energy the process is calied (a) electrolysis (b) ionization (c) neutralization (d) electrical conduction Which statementis not correct (a) enzymes catalyst a specitic reaction (b) enzymes show catalytic activity at a specitic temperature () the catalytic activity of enzymes is stopped if optimum pH is changed (a). the catalytic activity is poisoned by a co-enzyme The unit of rate of reaction is (a) mole dm (b) mole Kg’ (c) moles dm sec * (da) grams div The second and third period contain cloments (a) six (b) five (©) eight (d) ten Which is the transition element among the following @) B (Bb). AL (ey Cu (d) Cs The outermost orbital of alkali metal is y (a) p-orbital (b) d-orbital (c) f-orbital (qd) s-orbital Which colour is imparted by sodium. (a) yellow (b) violet (co) ted (d)_crimsen Dolomite is a mineral of carbon‘and magnesium: Its formula is (a) MgCO, - Cac, (b) MgC, fc) CaMgs (SiIO3)4 (@) Mo(HCOa)a Botn carbor dnd Silicon have four electrons in their valence shells and form feur covalent bonds but GO; is a gas and SiO, is hard crystalline Solid) Which statement is not true (a) the silicon atom is much larger than carbon atom (b), COp is a molocular structure whereas SiOz is a giant covalent structure {e) the Si atom is bonded to oxygen atom through 4 single bonds whereas COz has carbon attached to oxygen through 2 double bonds {d) SiOz Is polar compound while GOz is non-polar What is not the use of HpSO, ; (a) in the manufacture of fertilizer tike NHaNOs (b) in the manufacture of HCI and HNOs (c) in electrical batteries and storage cells {d) as a laboratory reagent The halogens are: strong oxidising agents. Which Is the correct order of decreasing power as an oxidising agent (a) Fe> Cle> Bre> le (b) Fz > Bra > Cle > le (c). Bra > Fe > Cle > Ia (d) 12 > Bra > Cl > Fe The oxidising power of halogens depends on various tactors, Which is not the correct reason (a) energy of dissociation (b) electron affinity (e) hydration anergy of lon (d) high atomic number The coinage metals Gu, Ag and Au belong to group (a) 1B {by rect ic) yellow (d) mixture of blue and red or violet Cracking is a process by which higher hydrocarbon are broken down Inte low boiling hydrocarbon. Which one is net generally a procedure for cracking (a) thermal cracking (6) catalytic cracking (c) steam cracking (d)_ normal cracking The use of tetra ethy! lead in petrol as an efficient antiknock agent is being discouraged. Which reason is correct (a) itis costly 4 (b) it damages the engine (c) Pb is difficult to obtain in bulk quantities (d) the combustion product, lead, causes air pollutions What is nota common use ct methane (a) as a fuel tb) for the preparation of haloalkanes (e) for the preparation of methyl alcohol (d) for the preparation of sulphuric acid Hydrocarbons are organic compounds which contain elements such as : {a} hydrogen (6) carbon (e) hydregen and carbon (qd) hatogens Which of the followings is nol aromatic hydrogencarbon (a) benzene (b) naphthalene (c) toluene (d) cyclohexene The carbon, carbon bond length in benzone is (a) 1.5402 (B) 134A (ec) 1.20°A (a) 1.99A° Which of the following is not a characteristic reaction of an alky! halide (a) SNI (b) SNo 5 fc) SE < (d) elimination Grignard reagent is prepared by the reaction of magnesium metal with alkyl halide in the presence of P (a) alcohol (by water » (c) suephuric acid {d)_ dry ether @r - 1 The formula ' CH; — GH — CH; is a (a) primary alkyl halide (b) secondary alkyl halide (¢) tertiary alkyl halide (d) none of these Which Is not the common name of an isomeric alcoho! with formula S400 (a) isobutyl alcohol (b) sec-butyl alcohol (c) ter-buty! alcohol (d) 1-butanat Which is not the enzyme involved in the preparation of ethyl alcohol by fermentation of starch (a) diastase (b) mattase (©) zymase (qd) invertase zs Functional graup for aldehyde is present in the structure °° I (b) H—C—R o il (©) R—C (dy) R—C—OH Which of the.{olfowing compounds will not give hefofenn test ll s _(@) CH, —C—H (b) CHa — CH, — OH fone 2 (ce) GH3— G — CHg . (cd) CHs —CHz—C—H Carboxylic acids can generally be prepared by various methods. Which’ ot the following methods is net suitable for making carboxylic acids. (a) by the oxidation of primary alcohols (b) by the hydrolysis of nitriles (c) by the carbonation of Grignard, reagent (d) by the hydrolysis of p-amines. Oxidic acid is: (a) an aliphatic mono carboxylic acid (b) an alipnatic dicarboxylic acid (c) an aromatic mono carboxylic acid ” {d) an aromatic dicarboxylic acid The mechanism of polymerisation involves free radical addition polymerisation or condensation polymerisation. Which statement is correct (a) polythene is an addition polymer (b) polystyrene is a condensation polymer (c) Poly vingyichloride (PVC) is a condensation polymer (d) polyester is an addition polymer Nylon, 6,6 is a condensation polymer of (a) adipic acid and glycol (b) phthalic acid and glycol (c) adipic acid and hexaethylene diamine (d) phthalic acid and hexaethylene diamine