Tci Pci(kpa) Ai Bi Ci b=Σbi*yi bi*yi d=Σdi*yi di*yi

0.043834 2.25563
C1 190.56 4599 4.934 8 1.5 0.021207 0.82107
C2 305.41 4800 4.934 8.3 0 0.004587 0.29713
C3 369.77 4240 4.934 8.82 0 0.003143 0.21337
iC4 407.82 3640 4.934 9.3 0 0.002423 0.15347
nC4 425.1 3784 4.934 9.35 0 0.00162 0.11041
iC5 460.35 3381 4.934 9.4 0 0.000982 0.06352
nC5 469.65 3365 4.934 9.5 0 0.001006 0.06588
nC6 506.4 3030 4.934 10 0 0.001205 0.07594
nC7 539.2 2740 4.934 10.5 0 0.001419 0.08588
nC8 568.4 2490 4.934 11 0 0.001646 0.09565
nC9 594.7 2280 4.934 11.2 0 0.00188 0.10386
nC10 617.7 2100 4.934 11.6 0 0.00212 0.11247
CO2 304.11 7374 3.5 6.8 0 0.000297 0.01870
H2S 373.37 8963 4.26 6.5 0 0.0003 0.03827
Total 0.043834 2.25563

Calculate Z follow Redlich Kwong Barxuk Equation

Z^3-Z^2-(m^2+m-d*m)Z-dm^2=0
b=Σbi*yi m=Pb/R/T
d=Σdi*yi
bi=0,0867RTc/Pc
di=Ai+Bi(Tc/T-1)+Ci(Tc/T-1)^2
Note: F(Z)=0
PAGE 18 & 26 CNCBKTNVKDM

Solution is obtained by Goal Seek(see under Tools dropdown menu) by setting the value of the cell P2 at zer

542725744.xls
 m R P(kpa) T(k) yi f(Z) Z MWi Mwi*yi
0.02636 8.3145 2000.000 400.0000 0.000052 0.968261
8.3145 400.0000 0.71 16.043 11.39053
8.3145 400.0000 0.1 30.07 3.007
8.3145 400.0000 0.05 44.097 2.20485
8.3145 400.0000 0.03 58.123 1.74369
8.3145 400.0000 0.02 58.123 1.16246
8.3145 400.0000 0.01 72.15 0.7215
8.3145 400.0000 0.01 72.15 0.7215
8.3145 400.0000 0.01 86.117 0.86117
8.3145 400.0000 0.01 100.204 1.00204
8.3145 400.0000 0.01 114.132 1.14132
8.3145 400.0000 0.01 128.258 1.28258
8.3145 400.0000 0.01 142.258 1.42258
8.3145 400.0000 0.01 44.01 0.4401
8.3145 400.0000 0.01 34.082 0.34082
1 27.44214

the value of the cell P2 at zero while changing cell Q2

542725744.xls
 Mw ρ kg/m3 v (m3/kg)V=RZT/P Pci*yi Tci*yi Pc Tc vci
27.44214 17.04353 0.058673 1.610121 4499.4 249.4025
3265.29 135.2976 0.00617
480 30.541 0.00489
212 18.4885 0.00454
109.2 12.2346 0.00446
75.68 8.502 0.00439
33.81 4.6035 0.00427
33.65 4.6965 0.00434
30.3 5.064 0.00429
27.4 5.392 0.00426
24.9 5.684 0.0042
22.8 5.947 0.00433
21 6.177 0.00439
73.74 3.0411 0.00214
89.63 3.7337 0.00288
4499.4 249.4025

542725744.xls
vci*yi vc
0.005669
0.004381
0.000489
0.000227
0.000134
0.000088
0.000043
0.000043
0.000043
0.000043
0.000042
0.000043
0.000044
0.000021
0.000029
0.005669

542725744.xls