Thermochemistry

ABOUT EDUCATORS

DR. SHARAD KOTHARI

• MSc., PhD, NET, JRF
• 18 year experience of IIT JEE in Organic Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota and Bansal Classes, Kota

PIYUSH MAHESHWARI
• BE (Hons.)
• 11 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota

BRIJESH JINDAL
• BTech Jaipur MNIT
• 11 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota
 THERMOCHEMISTRY

EXERCISE-1 (Subjective Questions)

r ts
ts
ENTHALPY OF FORMATION AND COMBUSTION
Calculate standard enthalpy ofe r
formation ( H°) in KJ/mol of SrCO (s) by given datax
p e
Q.1
x p f

r y E : 3

Sr(s)E
r y
1
+ O (g)  SrO(s) H° = – 600 kJ/mol
i s t
i t
s SrO(s) + CO (g)  SrCO (s) H° = – 200 kJ/mol
2 2

e m
m C(graphite) + O (g)  CO (g) H° = – 400h
e C
2 3

C h 2 kJ/mol 2

Q.2 Calculate enthalpy of formation of H SO (aq) from following data :

2 4

s
1
s
SO2(g) +
r t
O  SO3(g)
2 2
e t
H° = – 100 kJ/mol
r
SO (g) + H e p
x p O(l)  H SO (aq)
3 2 H° = – 230 kJ/mol
2 4
E x
 H = –y
r EkJ/mol 0
t r y
f

i st
300
SO 2 (g )  H (H O ) = – 170 kJ/mol f
i s 2 (l )

e m h ise
m
Chformation, of C H (g) . Given  H for CO (g) & H O (l)Care 395 & 286 kJ respectively.
Q.3 When 2 moles of C H (g) are completely burnt 3120 kJ of heat
2 6 liberated . Calculate the enthalpy of
2 6 f 2 2 - -

Q.4 Calculate standard enthalpies of formation of carbondisulphide (l) . Given the standard enthalpy of

r ts
combustion of carbon (s) , sulphur (s) & carbondisulphide (l) are :  393.4,  293.3 and
ts
e r
xp pe
 1108 kJ mol 1 respectively.

r y E E x
Q.5
st y
From the following data at 25°C, Calculate the standard enthalpy of formation of FeO(s) and of Fe2O3(s).
i tr
e mReaction
i s
 H (kJ/mol) o

m
r

h
C (ii) FeO (s) + C(graphite)  Fe(s) + CO(g) Ch155.5
(i) Fe O (s) + 3C(graphite)  2Fe (s) + 3CO(g)
2 3 e
492.5

(iii) C(graphite) + O (g)  CO (g) 2 –393.5

2
(iv) CO(g) +1/2 O2(g)  CO2(g) –283

Q.6 Given the following data :

r ts
xpe
2ClF(g) + O2(g)  Cl2O(g) + F2O(g)
2ClF3(g) + 2O2(g)  Cl2O(g) + 3F2O(g)
H = 167.4 kJ/mol
H = 341.4 kJ/mol
ts
yE r
r pe
2F2(g) + O2(g)  2F2O(g) H = – 43.4 kJ/mol

is t
Calculate H for the reaction
x
m ClF(g) + F2(g)  ClF3(g)
e the following data : ryE
C h i s t
H = 92 kJ em
Q.7 Given

Ch
2NH3(g)  N2(g) + 3H2(g)
2H2(g) + O2(g)  2H2O(g) H = – 48 kJ
Calculate H for the reaction :
2N2(g) + 6H2O(g)  3O2(g) + 4NH3(g)
Page # 1
 THERMOCHEMISTRY

The enthalpy change for the reaction C3H8(g) + H2(g)  C2H6(g) + CH4(g) at 25º C is
s
Q.8

r t
 55.8 kJ/mol. Calculate the enthalpy of combustion of C2H6(g). The enthalpy of combustion of

e r ts x
H2, & CH4 are 285.8 & 890.0 kJ/mol respectively. Enthalpy of combustion of propane is pe
2220 kJ mol1.
x p r y E
r E
y enthalpies of formation of C H COOH(s), i t
sCO (g) & H O (l) are 
Q.9
i
At 300 K, the t
s& –286 kJ mol respectively .
standard
e m
6 5 2 2

m
– 408, – 393
e
–1

the heat of combustion of benzoic acid at: C

h
C(a)h constant pressure
Calculate
(b) constant volume.

Q.10

ts r ts
Calculate the mass of mercury which can be liberated from HgO at 27º C by the treatment of excess

r pe
HgO with 45.4 kJ of heat at :
(a) constant pressure
p e
(b) constant volume
x
E x
Given : Hfº (HgO, s) =  90.8 kJ mol1 &
y
M (Hg) = 200.6 g mol1 . E
r y tr
i stthat on combustion of 5.6 gm of but - 1-ene(g), 70Kcalmofisheat is liberated in a closed
Q.11 It is observed

e mvessel at 300K. What could be a theoretical value of H he of but-2-ene at same temperature.

Ch


C
rigid combustion

Q.12 Calculate H for the reaction

C4H4(g) + 2H2(g)  C4H8(g)

r t s
Given : CH° (C4H4(g)) = 22340 kJ/mol
CH° (C4H8(g)) = 2286 kJ/mol
CH° (H2(g)) = 22755 kJ/mol

ts
e r
p complete combustion, the following enthalpy values are obtained
e:
x
E(g) + O (g)  2H O(g) H = – 242 kJ/mol
Q.13 When hydrogen gas undergoes
x p
r y
t 2H (g) + O (g)  2H O(l) H = – 286 kJ/mol try
2H
E
s
2 2 2

m i 2 2 2
i s
h e
Calculate H for H O(l)  H O(g)
2 2

e m
C Compound
Q.14 Three isomers with formula C H their enthalpy
4 8
 H(kJ/mol)
of
C h
combustion data is given as :
C
cis-2-butene – 2687.5
tras-2-butene – 2684.2
1-butene –2696.2

r t s
What is the enthalpy change for conversion of cis-2-butene to trans-2-butene?

x peTYPES OF ENTHALPY OF REACTION ts

r E
OTHER
yformation of HCl (g) and Cl (aq) are –92.3 kJ/mol and – 167.3 kJ/mol, e r
t
enthalpyiofssolution of hydrogen chloride gas.
Q.15 If the enthalpy of –

x p find the

e m r y E
h t
s of hydration of Ag (g)
Q.16 The lattice enthalpy of AgF is 958 kJ/mol and AgCl is 905 kJ/mol. Theienthalpy
C is – 446 kJ/mol, that of F is – 506 kJ/mol and that of Cl (g) ise–m +
– – 364 kJ/mol. Calculate the  H of

Ch
sol
AgCl(s) and AgF(s).

Q.17 The enthalpy of solution of anhydrous CuSO4 is – 15.9 kCal and that of CuSO4.5H2O is 2.8 kCal.
Calculate the enthalpy of hydration of CuSO4. Page # 2
 THERMOCHEMISTRY

The enthalpies of neutralization of NaOH & NH4OH by HCl are  13680 Cal and  12270 Cal
s
Q.18

r t
s pe
respectively . What would be the enthalpy change if one gram equivalent of NaOH is added to one gram

e r t x
equivalent of NH4Cl in solution ? Assume that NH4OH and NaCl are quantitatively obtained.
p
x following reactions r yE
E
y (g) — CO(g) ; H = –110 kJ
Q.19 From the data of H of the
r
C(s) +t1/2O i s t
i s+ H O(g) — CO(g) + H (g) ; H = 130 kJ hem
2
and

h e m C(s)
Calculate the mole composition of the mixture of steamC
2 2
and oxygen on being passed over coke at
C1273 K, keeping the reaction temperature constant and their is no heat exchange with surrounding.
Q.20 The polymerisation of ethylene to linear polyethylene is represented by the reaction

ts r ts
r pe
nCH2 = CH2  (–CH2 CH2–)n

p e x
where n has a large integral value . Given that the average enthalpies of bond dissociation for C=C &

E x y E
CC at 298 K are  590 & + 331 kJ mol1 respectively. Calculate the enthalpy of polymerisation

tr y
per mole of ethylene at 298 K .
i s tr
Q.21 Them
i s
enthalpies of neutralization of a weak acid HA & e am
e h weak acid HB by NaOH are

Ch 6900 Cal/equivalent &  2900 Cal/equivalent respectivelyC. When one equivalent of NaOH is added
to a solution containing one equivalent of HA & one equivalent of HB, the enthalpy change was
 3900 Calories . In what ratio is the base distributed between HA & HB ?

r tsBOND ENTHALPY ts
Q.22 Using bond enthalpy data,p e enthalpy of formation of isoprene. Neglect resonance in isoprene.
e r
x calculate
E + 4 H (g)  H C = C| — C| = CH (g)
5yC(s) x p
st r 2 2 2
r y E
m i CH H
i s t
h e 3

e m
C Given : C  H = 98.5 k Cal ;
C  C = 83 k Cal ;
h
H  H = 104 k Cal
Ck Cal &
C = C = 147
;

C(s)  C(g) = 171 k Cal .

Q.23 The enthalpy of atomization of PH3 is 954 kJ mol–1 and that of P2H4 is 1.485 M J mol–1. What is the

r
bond enthalpy of the P–P bond?t s
p e
E x r ts
(g)y C H (g) e
Q.24 Using the bond enthalpy data given below, calculate the enthalpy change for the reaction.
C H (g) + H r
Data: is
2 4 t 2 2 6
x p
e m C–H ry
E
hBond C–C
C Bond Enthalpy 337 kJ/mol 606 kJ/mol e410.4
C=C
s t H–H
ikJ/mol 431.8 kJ/mol
m
Ch
Page # 3
 THERMOCHEMISTRY
Q.25 Compute the enthalpy of formation of liquid methyl alcohol 1
in kJ mol , using the following data.
Enthalpy of vaporisation of liquid CH3OH = 38 kJ/ mol .
r ts
r ts
Enthalpy of formation of gaseous atoms from the elements in their standard states are
e x pe
p E
x try
H  218 kJ / mol ; C 715 kJ / mol ; O  249 kJ / mol.

E s
try
Average Bond energies

s
C  H  415 kJ / mol ;
mi
C  O  356 kJ / mol ; O  H  463 kJ / mol
i e
e m
h of formation of CH CN = 90 kJ/mol
Q.26 From the following data :
Ch
CEnthalpy
Enthalpy of formation of C2H6 = – 85 kJ/mol
3

Enthalpy of sublimation of graphite = 720 kJ/mol

Enthalpy of dissociation of nitrogen = 945 kJ/mol
ts r ts
Enthalpy of dissociation of H2 = 435 kJ/mol

x p er x pe
C–H bond enthalpy = 415 kJ/mol

y E r y E
Calculate the bond enthalpy of (i) C – C ; (ii) C  N
r
stof combustion of acetylene is –312 kCal per mole. If enthalpy
i t
sof formation of CO &
i m
Om e
Q.27 The enthalpy
He are 94.5 & 68 kCal per mole respectively, calculate Ch
2

ChGiven that enthalpy of atomisation of C is 150 kCal per moleCand H – H bond enthalpy and C – H bond
2 C bond enthalpy.

enthalpy are 103 kCal per mole and 93.50 kCal per mole respectively.

Q.28
r ts
Using the given data calculate enthalpy of formation of acetone (g) . [All values in kJ mol1]

ts
bond enthalpy of :
e r
C  H = 415 ;
E xp
C  C = 345 ; (C = O) = 728.0 ;
x pe
r y
(O = O) = 495.0 ; H  H = 436 ;
E
subH of C = 720
y
Q.29 Find the i
st i s tr
e m enthalpy of S–S bond from the following data.
m
C h(i) C H – S – C H (g)
h e
 H = – 147 kJ/mol 

C
2 5 2 5 f


(ii) C H – S – S – C H (g)
2 5 2 H = – 202 kJ/mol
5 f

(iii) S (g)  f H  = 225 kJ/mol

Q.30
r ts
Use the mean bond enthalpy data to calculate the enthalpy of combustion of ethanol.

xpe
CH3CH2OH(g) + 3O2(g)  2CO2(g) + 3H2O(g)

ts
E
[Given : Bond energy (C – H) = 412 kJ/mol ; (C = O) = 743 kJ/mol

r y
(C – C) = 348 kJ/mol ; (C – O) = 360 kJ/mol
per
is t
(O = O) = 496 kJ/mol ; (O – H) = 463 kJ/mol
x
e m ryE
h
C Calculate resonance energy of CO from the following data. emis
RESONANCE ENERGY t
Q.31
h
2(g)
H of CO = –280 kJ / mol H CO = –120 kJ/mol
H OC
combustion f
H of C
atomisation = 720 kJ / mol
(graphite) = O = 500 kJ molBE
–1

H C = O = 710 kJ /mol BE

Page # 4
 THERMOCHEMISTRY

s
Q.32 Calculate the enthalpy of combustion of methyl alcohol at 298 K from the following data
CH CO OH
r t
s pe
Bond O=O C=O

er
Bond Enthalpy(kJ mol1) 415 t 352 465 494
x
710
p E
x try
Resonance energy of CO2 =  143 kJ mol 1

E s
try
Latent heat of vaporisation of methyl alcohol = 35.5 kJ mol1.

s
Latent heat of vaporisation of water = 40.5 kJ mol1.
mi
i e
h e
Q.33 What
m
will be the value of resonance energy of N O if Ch
CH N = N = 400 kJ/mol ;
BDE H of
2

N O = 100 kJ mol
2
–1

HBDE N  N = 950 kJ/mol ; HBDE N = O = 600 kJ mol–1

HBDE O = O = 500 kJ/mol
ts r ts
x
er
p CALORIMETERY x pe
y E r E
y. The temperature of
Q.34 0.16 g of methane
s r was subjected to combustion at 27º C in a bomb Calorimeter
i t
s the heat of combustion of
tsystem (including water) was found to rise by 0.5º C . Calculate
i
Calorimeter
m e m
e h
Ch(a)(b) constant
methane at
constant volume
pressure .
C
25

r ts
The thermal capacity of Calorimeter system is 17.7 kJ K1 . (R =
3
J mol1 K1)

ts
e r
xp pe
Q.35 When 0.2 mol of ethane is burnt completely in a bomb calorimeter, the temperature of calorimeter

r y E E x
system increased by 2 K. What should be the increase in temperature of the same calorimeter system,

[Given :ist = – 200 Kcal/mol] try

when 0.4 mol of CH4 is burnt ?

em
 C U C 2 H 6 g 
= – 400 Kcal/mol and  C U CH 4 g 
i s
Q.36 h
m
Two solutions initially at 25°C were mixed in an adiabatic constantepressure Calorimeter. One contains
h 100 ml of 0.80 M NaOH. After
C 400 ml of 0.2 M weak monoprotic acid solution. The otherCcontain
mixing temperature increased to 26.2 °C. How much heat is evolved in the neutralization of 1 mole of
acid? Assume density of solution 1.0 g/cm3, and specific heat of solution 4.0 J/g-K. Neglect heat capacity
of the Calorimeter.
r ts
Q.37
xpe
Benzoic acid is a common standard used in Bomb calorimeters, which maintain a constant volume. If
ts
E r
1.22 gm of benzoic acid gives off 31.7 J of energy when burned in the presence of just sufficient oxygen
y
tr pe
at an initial temperature of 24.6°C, calculate molar heat capacity at constant volume of final product
is x
em ryE
mixture if all the heat produce is used for increasing temperature of the final product mixture and the final

C h i s t
temperature is 49.6°C. Also calculate, w and U for the given amount, assuming ideal gas behaviour.

hem
C
Page # 5
 THERMOCHEMISTRY

EXERCISE-2 (Objective Questions)

r ts
ts pe
Single correct
Q.1
er
For which of the following change H not equal to E?
p x
E
x try
(A) H2 (g) + I2 (g)  2HI (g) (B) HCl (aq)+ NaOH(aq)  NaCl(aq) + H2O(l)
E s
try i
(C) C(s) + O2(g)  CO2(g) (D) N2 (g)+ 3H2(g)  2NH3(g)

i s e m
m Ch H° = –176 kJ/mol
Find f H° for HCl(g) from the following data:
e
Q.2

Ch
NH3(g) + HCl(g)  NH4Cl(s); r
N2(g) + 3H2(g)  2NH3(g); rH° = –92 kJ/mol
N2(g) + 4H2(g) + Cl2(g)  2NH4Cl(s); rH° = –629 kJ/mol
(A) 536.5 kJ/mol (B) –361 kJ/mol (C) –92.5 kJ/mol (D) None

ts r ts
Q.3

x p er
Calculate H combustion of acetone if H f of acetone = – 250 kJ
x pe
E yE
H combustion of Cgraphite = – 390 kJ/mol & H combustion of H2(g) = – 280 kJ/mol :
y r
s t r
(A) – 1230 kJ/mol (B) – 1760 kJ/mol
i s
(C) – 1370 kJ/molt (D) – 1410 kJ/mol

m i e m
Q.4
e
Calculate
h
C – H Bond energy from the following data :
C h
C (A) 1663.37 kJ (B) 415.84 kJ (C) 179.17 kJ (D) 74.81 kJ
 H(C ) = 716.68 kJ/mol
f (g)  H(H ) = 217.97 kJ/mol
f (g)  H(CH ) = – 74.81 kJ/mol
f 4(g)

Q.5 Identify the options in which H > U. [Assume gases to behave as ideal]

r ts
(A) Polymerisation of ethene(gas) into polythene (gas).
ts
e r
xp
(B) H2O(g)  H2(g) + O2(g)
(C) HCl(g)  H2(g) + Cl2(g)
y E
(D) CH4(g) + O2(g)  CO2(g) + H2O(l)
x pe
r
The reactiontCH (g) + Cl (g)  CH Cl(g) + HCl(g) has H = –25 kCal. y
s r E
Q.6
m i 4 2 3

i s t
e Bond
m
Ch Bond Energy
kCal
C h e
 84
C—Cl

 H—Cl 109
 C—H x

r ts  Cl—Cl
p e y

E x x:y=9:5

r ts
(A) 70 kCal ry (D) 60 kCal pe
From the given data, what is the bond enthalpy of Cl—Cl bond
t
isinvolving gold have been of particular interest to a chemist . ConsiderytheEfollowing
(B) 80 kCal (C) 67.75 kCal
x reactions,
Q.7 m
e Au(OH) + 4 HCl  HAuCl + 3 H O ,
Reactions
h H = s
r
28tkCal
C Au(OH) + 4 HBr HAuBr + 3 H O ,
3 4 2
m i
3 4 2
h eone mole of HAuBr was mixed with
H =  36.8 kCal
In an experiment there was an absorption of 0.44 kCal when
C
4 moles of HCl . What is the percentage conversion of HAuBr into HAuCl ?
4 4
4

(A) 0.5 % (B) 0.6 % (C) 5 % (D) 50 %

Page # 6
 THERMOCHEMISTRY
Q.8 Which of the following reactions defines H f ?
(A) C(diamond) + O2(g)  CO2(g) (B) 1/2 H2(g) + 1/2 F2(g)  HF(g)
r ts
(C) N2(g) + 3H2(g)  2NH3
r t s (D) CO(g) + 1/2O2(g)  CO2(g)
e by the equation C (graphite) ® C (diamond), x pe
Q.9
x p
For the allotropic change represented
r y E DH = 1.9 kJ. If 6
g of diamond and 6 gE
r y i t
s case by 11.4 kJ
of graphite are separately burnt to yield CO , the enthalpy liberated in first case is
t
2

i s in the second case by 0.95 kJ (D) less than inhtheem

(A) less than in the second case by 1.9 kJ (B) more than in the second

h e m
(C) more than
C
second case by 11.4 kJ

Q.10CFind  U° for the reaction 4HCl (g) + O (g) l 2Cl (g) + 2H O (g) at 300 K. Assume all gases are
r 2 2 2
ideal.

s
Given: H2(g) + Cl2(g)  2HCl (g)
t
o
 r H 300
r ts
= – 184.5 kJ/mol
r
2H (g) + O (g) e2H O (g) p e
xp x
o
 H = – 483 kJ/mol (Use R = 8.3 J/mol)
2 2

(A) 111.5 kJ/mol E (B) –109.01 kJ/mol

y
2 r

r y E
300

r
st : 2A + B
(C) –111.5 kJ/mol
t
(D) None
i s= 100 cal/K mol at 300K.
m i e m
h e
Q.11 For a reaction (g) C , U° = 30 Kcal/mol,
(g)  

C h
S°
(g)

C What will be the value of G° at 400K? [R = 2 cal/K mol] [ C

(A) 0
rxn

(B) – 1.2 Kcal

= 0]
(C) – 11.2 Kcal
Prxn

(D) – 10 Kcal

Q.12
r ts
The combustion 1.22g benzoic acid (M = 122) in a bomb calorimeter at 300K caused a temperature

ts
e
rise of 3K, while combustion of 0.88g ethyl ethanoate (M = 88) caused a temperature rise of 2K.

xp
Calculate the enthalpy change of combustion of CH3COOC2H5(l) at 300K.
per
r y E
Given : Internal energy change of combustion for benzoic acid = – 3000kJmol–1 at 300K
E x
i s t
(A) – 2000kJ (B) – 2002.49kJ (C) – 2006.5kJ
y
(D) – 3002.5kJ
t r
e m in nature. Each problem on an average requires 21 Joules of m
Q.13 In order to solve a complex physical chemistry problem, brain requires some is"neural energies" which are
Chamount e energy is obtained from oxidation
electrical neural energy. Calculate minimum

C h
of glucose required to solve 10 such problems if all electrical
of glucose.
1000
[Given : H combustion of glucose = – 2800 kJ/mole, Scombustion of glucose = – J/molK,
3
Temperature = 300K ]
r ts
(A) 14 gm
e
(B) 14 mg (C) 20 gm (D) 120 mg
p yield on combustion of hydrogen atoms to steam to the yield on combustion
E x r ts
r yof hydrogen molecules to steam?
Q.14 What is the ratio of the
t
enthalpy
p e
is
of an equal mass

m E x
h e : H (g) + O (g)  H O(g) H = – 242 kJ istry
Given
1

C B.E. (H – H) = 436 kJ
2 2 2 2

e m
(A) 0.80 : 1 (B) 1 : 0.80 (C) 1.80C:1h (D) 2.80 : 1

Page # 7
 THERMOCHEMISTRY

s
Q.15 The molar heat capacities at constant pressure (assume constant with respect to temperature) of A, B
and C are in ratio of 1.5 : 3.0 : 2.0 . If enthalpy change for the exothermic reaction A + 2B  3C at
r t
e r t s
300 K is – 10 kJ/mol & Cp,m (B) is 300 J/mol then enthalpy change at 310 K is :
x pe
(A) – 8.5 kJ/mol
x p
(B) 8.5 kJ/mol (C) – 11.5 kJ/mol
y E
(D) none of these
r
r E
yof solid NaCl is 772 kJmol and enthalpy of solution i t
s2 kJmol . If the hydration
enthalpy ofiNa
t
Q.16 The lattice enthalpy
e mof hydration of chloride ion?
s & Cl ions are in the ratio of 3:2.5, what is thehenthalpy
–1 is –1

(A)e
h m
–140 kJmol
+
–1
–

(B) –350 kJmol –1

(C) –351.81CkJmol (D) None –1

C
Q.17 H 0f of water is – 285.8 kJ mol–1. If enthalpy of neutralisation of monoacid strong base is

ts r ts
p er
–57.3 kJ mol–1, H 0f of OH– ion will be
p e
(A) – 228.5 kJ mol
x
(B) –1
228.5 kJ mol (C) 114.25–1
kJ mol (D)
E
–114.25 x
kJ mol –1 –1

r y E tr y
(A) H i
st
Q.18 Select the correct option.
i s
e m [H(g)] is equal to H of H (g)
h e m
h
f atomisation 2

C (C) H (H–H) is equal to H of H (g) C

(B) H (H–H) is equal to H of H(g)
BE f
BE atomisation 2
(D) Hcombustion [H2(g)] is equal to Hf [H2(g)]

r ts
H of of atomic B is 134.5 Kcal/mol and H of of atomic F is 118 Kcal/mol. H of of BF3(g) is
ts
e
Q.19

xp
– 271.5 Kcal /mol. Average B – F energy would be
per
ry E
(A) 97.7 Kcal / mol
x
(B) 116.6 Kcal / mol (C) 135.4 Kcal / mol (D) 253.3 Kcal / mol
E
st thermochemical equations:
Q.20 Study theifollowing try
e mA  B ; H = + 100 Kcal i s
h em
C The correct order of enthalpies of formation of A, B and CCis h
B  C ; H = – 80 Kcal

(A) A < B < C (B) A < C < B (C) C < A < B (D) B < C < A

Q.21
s
From following Born Haber cycle, identify incorrect statement :

r t
xpe 872 kJ
C(g) + 4H(g)

ts
yE r
r pe
C(g) + 2H2(g)

is t 715 kJ
x
em
Energy
C(graphite) + 2H2(g)
r y E
C h 75 kJ
i s t
em
CH4(g)
(A) fH(CH4) = – 75 kJ
(C) sublimationH of C = 715 kJ/mol
h
(B) Bond energy of (C–H) = 145 kJ/mol
(D)  C H of H(g) = 218 kJ/mol
formation
s

Page # 8
 THERMOCHEMISTRY
Q.22 Calculate enthalpy of combustion of propane [C3H8 (g)] in kJ/mol at 298 K.
Given : B.E.(O = O) = 498 kJ/mol ; B.E. (C = O) = 804 kJ/mol
r ts
B.E. (C–H) = 410 kJ/mol
er ts ; B.E.(O–H) = 464 kJ/mol
x pe
B.E. (C–C) = 345 kJ/mol
p ; Resosnace energy of CO2(g) = – 143 kJ/mol
E
x try
Hvaporization (H2O, l ) = 41 kJ/mol
E s
try i
(A) –1996 (B) –2669 (C) –2324 (D) None of these

i e mcompound?
sfollowing represent standard formation reaction ofhgiven
h m
Q.23 Which of the
e C 1
C (A) Ag (aq) + Cl (aq)  AgCl(s)
+ – (B) CO(g) + O (g)  CO (g)
2 2 2

1
(C) H (g) + (aq)  H+(aq) + 1e– (D) 2H2(g) + O2(g)  2H2O(l)
2 2
t s r ts
p e r p e
Q.24 0.2 M, 100 ml NaOH is mixed
x
with
E x
0.4 M, 100 ml HCl solution. Determine energy released during the

Given : HE
reaction.

r y (B) 1150 kJ
(aq) + OH¯ (aq)  H O (l)  r y
t2300 kJ
H = – 57.5 kJ
s
+ –1

(A) 1150 Jst

mol
i
2

m i (C) 2300 J
e m (D)

Q.25 h e C h
C HCl
Enthalpy of neutralization of H PO acid is –106.68 kJ/mol using NaOH. If enthalpy of neutralization of

(A) 50.84 kJ/mol (B) 5 kJ/mol

3
by NaOH is –55.84 kJ/mol. Calculate H
3
of H PO into its ions
ionization
(C) 2.5 kJ/mol
3
(D) None
3

r ts
e is mixed with 300 ml 0.1 M HCl then increase in temperatureerists
Q.26 When 100 ml 0.2 M KOH is mixed with 100 ml 0.2 M HCl, temperature of solution increases by t1oC
while when 300 ml 0.1 Mp
E x KOH
x p t o2C

t r y (B) t > t
then which one is correct.(Assuming
y E
density as well as specific heat of final solutions are same)
(A) t = t
1
i s 2 1 (C) t < t
2 1 2

i s r
(D) Can't be
t
predicted

e m m
h
–1

(in kJ) when 0.5 mole of H SO react with 0.75 mole of NaOH iseequal to
Q.27 The enthalpy of neutralisation of HCl and NaOH is –57 kJ mol . The heat evolved at constant pressure

C
(A) 57 ×
3
2

(B) 57 × 0.5
4
Ch
(C) 57 (D) 57 × 0.25
4
More than one may correct
Q.28 From the following data at 25°C
r ts
1
Reaction
1
xpe rH° kJ/mol

ts
E
H (g) + O2(g)  OH (g)
y
42
r
r pe
2 2 2

is 1 t x
em
H2(g) + O2(g)  H2O(g)
2
–242
ryE
C h H2(g)  2H(g) 436
i s t
O2(g)  2O(g) 495
hem
C
Which of the following statement(s) is/are correct :
(A) rH° for the reaction H2O (g)  2H(g) + O(g) is 925.5 kJ/mol
(B) rH° for the reaction OH(g)  H(g) + O(g) is 502 kJ/mol
(C) Enthalpy of formation of H(g) is –218 kJ/mol Page # 9
(D) Enthalpy of formation of OH(g) is 42 kJ/mol
 THERMOCHEMISTRY

Which of the following do(es) not represent H formation of the product.

s
Q.29

r t
ts (B) H (g) + Cl (g) 2HCl x pe
1 1
(A)
2
H2(g) +
2
p e r
Br2(g)  HBr 2 2

x (D) P (black) + 5O (g) rPyO (s)

E
(C) 

y E
NH (g) + Cl (g)
r
– NH Cl(s)
i s t
st representing H of C (graphite). hem
4 4 4 2 4 10

(E)
m i
Reaction combustion

h e Cstandard boiling point?

C(A) G = 0
Q.30 Which of the following is correct for boiling of CCl (l) at its
(B) G° = 0
4
(C) S°>0 (D) H° > 0 vap

Q.31 100 ml 0.25 M H2SO4 (strong acid) is neutralised with 200 ml 0.2M NH4OH in a constant pressure

ts r ts
r pe
Calorimeter which results in temperature rise of 1.4 °C. If heat capacity of Calorimeter content is

p e
1.5 kJ/°C. Which statement is/are correct
x
x E
E try
Given : HCl + NaOH  NaCl + H2O + 57 kJ
ry s
st i
CH3COOH + NH4OH  CH3COONH4 + H2O + 48.1 kJ

mi (A) Enthalpy of neutralisation of HCl v/s NH4OH is – 52.5 kJ/mol

em
e h
Ch
(B) Enthalpy of dissociation (ionization) of NH4OH is 4.5 kJ/mol
(C) Enthalpy of dissociation of CH3COOH is 4.6 kJ/mol C
(D) H for 2H2O(l)  2H+ (aq.) + 2OH¯(aq.) is 114 kJ

Assertion Reason
r ts ts
Q.32 Statement-1 :
e
The enthalpy of neutralization of the reaction between HCl and NaOH is
r
E xp pe
– 13.7 kCal / mol. If the enthalpy of neutralization of oxalic acid (H2C2O4) by a
x
ry E
strong base is – 25.4 kCal / mol, then the enthalpy change ( rH |) of the
y
i st tr
process H2C2O4  2H+ + C2O42– is 11.7 kCal / mol.
i s
em Statement-2 : H2C2O4 is a weak acid.
m
Ch Ch
e
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

r ts
Q.33 Statement-1: Standard enthalpy of isomerisation of an enantiomer into the other is zero.

xpe
Statement-2: The two enantiomers of any chiral compound have the same enthalpy of formation.
ts
E
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
y r
is tr pe
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
x
em
(C) Statement-1 is true, statement-2 is false.
ryE
C h(D) Statement-1 is false, statement-2 is true.
i s t
hem
C
Page # 10
 ANSWER KEY THERMOCHEMISTRY

EXERCISE-1
r ts
tskJ/mol
–r800 p e
Q.1 – 1200 kJ/mol Q.2
p e Q.3
x
– 88 kJ/mol
E
E x –266 kJ/mol and –824 kJ/mol Q.6try–108.7 kJ / mol
Q.4 128 kJ
– 40 kJ/mol tr
y Q.8 –1560 kJ mol
Q.5
i s
Q.7
i s –1

hem
Q.9 (a) e
h m
 3201 kJ/mol; (b)  3199.75 kJ/mol
C
Q.10C(a) 100.3 g; (b) 101.69 g Q.11 – 700 Kcal/mol
Q.12 65564 kJ /mol Q.13 22 kJ/mol
Q.14 Cis-2-butene  Trans-2-butene
ts Hr = ?
r ts
er
p  H of AgF(s) = 6 kJ/mol ; H AgCl = 95E
rH = – 3.3 kJ/mol
x x pe
Q.15 – 75 kJ/mol
ry E Q.16
tr y kJ/mol

st/ mol Q.18  1410 Cal s

sol soln

i
Q.17 – 18.7 kCal i
mQ.20  72 kJ mol
h e m h e
Q.19 mole % O (g) = 37.14, H O(g) = 62.86
C Q.23 213 kJ / mol
–1

C
2 2

Q.21 1 : 3 Q.22 + 23 k Cal

Q.24 – 120 kJ/mol Q.25 - 266 kJ mol–1 Q.26 (i) 340 kJ/mol–1;(ii) 890 kJ/mol–1
s kJ mol
t192.5
r 1
ts
pe 200 kJ
Q.27 EC º C = 161 kCal / mol Q.28 Q.29 280 kJ/mol
Q.30 – 1031 kJ/mol
xQ.31 p e r
Q.32 – 665.5 kJ mol
x
-1

ryE Q.34 E
Q.33
s t
100 kJ / mol
i
(a)  885 kJ/mol (b)  890 kJ/mol
tryQ.35 2K

e m
Q.36 –30 kJ/mol Q.37 i sJ
C = 12.68 J/mole-K, w = 0, U = –31.7
m
Ch Exercise-2
Ch
e
Q.1 D Q.2 C Q.3 B Q.4 B
Q.5 B Q.6 D Q.7 C Q.8 B
Q.9 C
Q.14 rD
ts
Q.10 C Q.11 C Q.12 B
Q.13 B
x pe Q.15 C Q.16 B

ts
Q.17 A
yE Q.22 B
Q.18 C Q.19 D Q.20 B
r
Q.21 B
is tr Q.23 C
xQ.24 A pe
Q.25 B m
e ryE
Q.28 h
C
Q.26 B Q.27 A
i t
sQ.31 ABD
em
AD Q.29 ABCD Q.30 ABCD
Q.32 D Q.33 A
C h
Page # 11